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Integrated assessment of irrigation water quality and wastewater reuse under hydrochemical, microbiological, and metal contamination constraints in a Mediterranean semi-arid basin

Abstract

Water scarcity in semi-arid Mediterranean regions increasingly drives wastewater reuse for agriculture. In northeastern Algeria, the Middle Seybouse basin faces pressures from urban effluents and agricultural runoff, which can impair water quality and threaten ecosystems, soils, crops, and public health. Studies on the environmental impacts of the Guelma wastewater treatment plant (WWTP) are lacking. This study provides the first multiparametric assessment of Guelma WWTP effluent and its irrigation suitability. Seasonal samples were collected in 2024 from three sites: WWTP effluent, the Seybouse river mixing zone, and a downstream station. Physicochemical parameters, nutrients, bacteriological indicators, and heavy metals (Cr, Cd, Fe, Pb, Zn) were analyzed. Irrigation suitability was assessed using sodium adsorption ratio (SAR), sodium percentage (Na%), residual sodium carbonate (RSC), magnesium hazard (MH), permeability index (PI), Kelly’s ratio (KR), and the irrigation water quality index (IWQI), while seasonal and spatial variations were explored with analysis of variance (ANOVA) and principal component analysis (PCA). Results showed seasonal variability, with ranges of total suspended solids = 5–124 mg/L, 5-day biological oxygen demand (BOD₅) = 5.6–36 mg/L, chemical oxygen demand (COD) = 28–169 mg/L, electrical conductivity (EC) ≈ 1271 µS/cm, and total dissolved solids (TDS) ≈ 635 mg/L. IWQI (range: 46–74) indicated generally good to moderate irrigation suitability, though seasonal sodicity risks were noted. Treated wastewater could support irrigation of salt-tolerant crops using drip irrigation and soil management. These results provide guidance for water managers, policymakers, and farmers to safely reuse treated wastewater and reduce environmental and health risks

Abbreviations

ANOVA:

Analysis of variance

BOD₅:

5-day biological oxygen demand

Ca2⁺:

Calcium ion

Cd:

Cadmium

CFU:

Colony-forming units

Cl⁻:

Chloride ion

COD:

Chemical oxygen demand

Cr:

Chromium

DO:

Dissolved oxygen

EC:

Electrical conductivity

FAO:

Food and agriculture organization

Fe:

Iron

IP:

Irrigation pollution index

IWQI:

Irrigation water quality index

KR:

Kelley Ratio

Mg2⁺:

Magnesium ion

MH:

Magnesium hazard

MPI:

Metal pollution index

Na%:

Sodium percentage

Na⁺:

Sodium ion

Pb:

Lead

PCA:

Principal component analysis

PI:

Permeability index

RSC:

Residual sodium carbonate

SAR:

Sodium adsorption ratio

SEYDs:

Seybouse downstream site

SEYMZ:

Seybouse mixing zone

TDS:

Total dissolved solids

TSS:

Total suspended solids

WHO:

World health organization

WWTP:

Wastewater treatment plant

Zn:

Zinc

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Correspondence to
Haroun Chenchouni.

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Yalles-Satha, A., Bennacer, L., Guettaf, M. et al. Integrated assessment of irrigation water quality and wastewater reuse under hydrochemical, microbiological, and metal contamination constraints in a Mediterranean semi-arid basin.
Sci Rep (2026). https://doi.org/10.1038/s41598-026-65169-1

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  • DOI: https://doi.org/10.1038/s41598-026-65169-1

Keywords

  • Treated wastewater
  • Irrigation water quality
  • IWQI
  • Heavy metals
  • Seybouse basin
  • Semi-arid regions
  • Microbial contamination
  • Wadi system


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