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    A better way to separate gases

    Industrial processes for chemical separations, including natural gas purification and the production of oxygen and nitrogen for medical or industrial uses, are collectively responsible for about 15 percent of the world’s energy use. They also contribute a corresponding amount to the world’s greenhouse gas emissions. Now, researchers at MIT and Stanford University have developed a new kind of membrane for carrying out these separation processes with roughly 1/10 the energy use and emissions.

    Using membranes for separation of chemicals is known to be much more efficient than processes such as distillation or absorption, but there has always been a tradeoff between permeability — how fast gases can penetrate through the material — and selectivity — the ability to let the desired molecules pass through while blocking all others. The new family of membrane materials, based on “hydrocarbon ladder” polymers, overcomes that tradeoff, providing both high permeability and extremely good selectivity, the researchers say.

    The findings are reported today in the journal Science, in a paper by Yan Xia, an associate professor of chemistry at Stanford; Zachary Smith, an assistant professor of chemical engineering at MIT; Ingo Pinnau, a professor at King Abdullah University of Science and Technology, and five others.

    Gas separation is an important and widespread industrial process whose uses include removing impurities and undesired compounds from natural gas or biogas, separating oxygen and nitrogen from air for medical and industrial purposes, separating carbon dioxide from other gases for carbon capture, and producing hydrogen for use as a carbon-free transportation fuel. The new ladder polymer membranes show promise for drastically improving the performance of such separation processes. For example, separating carbon dioxide from methane, these new membranes have five times the selectivity and 100 times the permeability of existing cellulosic membranes for that purpose. Similarly, they are 100 times more permeable and three times as selective for separating hydrogen gas from methane.

    The new type of polymers, developed over the last several years by the Xia lab, are referred to as ladder polymers because they are formed from double strands connected by rung-like bonds, and these linkages provide a high degree of rigidity and stability to the polymer material. These ladder polymers are synthesized via an efficient and selective chemistry the Xia lab developed called CANAL, an acronym for catalytic arene-norbornene annulation, which stitches readily available chemicals into ladder structures with hundreds or even thousands of rungs. The polymers are synthesized in a solution, where they form rigid and kinked ribbon-like strands that can easily be made into a thin sheet with sub-nanometer-scale pores by using industrially available polymer casting processes. The sizes of the resulting pores can be tuned through the choice of the specific hydrocarbon starting compounds. “This chemistry and choice of chemical building blocks allowed us to make very rigid ladder polymers with different configurations,” Xia says.

    To apply the CANAL polymers as selective membranes, the collaboration made use of Xia’s expertise in polymers and Smith’s specialization in membrane research. Holden Lai, a former Stanford doctoral student, carried out much of the development and exploration of how their structures impact gas permeation properties. “It took us eight years from developing the new chemistry to finding the right polymer structures that bestow the high separation performance,” Xia says.

    The Xia lab spent the past several years varying the structures of CANAL polymers to understand how their structures affect their separation performance. Surprisingly, they found that adding additional kinks to their original CANAL polymers significantly improved the mechanical robustness of their membranes and boosted their selectivity  for molecules of similar sizes, such as oxygen and nitrogen gases, without losing permeability of the more permeable gas. The selectivity actually improves as the material ages. The combination of high selectivity and high permeability makes these materials outperform all other polymer materials in many gas separations, the researchers say.

    Today, 15 percent of global energy use goes into chemical separations, and these separation processes are “often based on century-old technologies,” Smith says. “They work well, but they have an enormous carbon footprint and consume massive amounts of energy. The key challenge today is trying to replace these nonsustainable processes.” Most of these processes require high temperatures for boiling and reboiling solutions, and these often are the hardest processes to electrify, he adds.

    For the separation of oxygen and nitrogen from air, the two molecules only differ in size by about 0.18 angstroms (ten-billionths of a meter), he says. To make a filter capable of separating them efficiently “is incredibly difficult to do without decreasing throughput.” But the new ladder polymers, when manufactured into membranes produce tiny pores that achieve high selectivity, he says. In some cases, 10 oxygen molecules permeate for every nitrogen, despite the razor-thin sieve needed to access this type of size selectivity. These new membrane materials have “the highest combination of permeability and selectivity of all known polymeric materials for many applications,” Smith says.

    “Because CANAL polymers are strong and ductile, and because they are soluble in certain solvents, they could be scaled for industrial deployment within a few years,” he adds. An MIT spinoff company called Osmoses, led by authors of this study, recently won the MIT $100K entrepreneurship competition and has been partly funded by The Engine to commercialize the technology.

    There are a variety of potential applications for these materials in the chemical processing industry, Smith says, including the separation of carbon dioxide from other gas mixtures as a form of emissions reduction. Another possibility is the purification of biogas fuel made from agricultural waste products in order to provide carbon-free transportation fuel. Hydrogen separation for producing a fuel or a chemical feedstock, could also be carried out efficiently, helping with the transition to a hydrogen-based economy.

    The close-knit team of researchers is continuing to refine the process to facilitate the development from laboratory to industrial scale, and to better understand the details on how the macromolecular structures and packing result in the ultrahigh selectivity. Smith says he expects this platform technology to play a role in multiple decarbonization pathways, starting with hydrogen separation and carbon capture, because there is such a pressing need for these technologies in order to transition to a carbon-free economy.

    “These are impressive new structures that have outstanding gas separation performance,” says Ryan Lively, am associate professor of chemical and biomolecular engineering at Georgia Tech, who was not involved in this work. “Importantly, this performance is improved during membrane aging and when the membranes are challenged with concentrated gas mixtures. … If they can scale these materials and fabricate membrane modules, there is significant potential practical impact.”

    The research team also included Jun Myun Ahn and Ashley Robinson at Stanford, Francesco Benedetti at MIT, now the chief executive officer at Osmoses, and Yingge Wang at King Abdullah University of Science and Technology in Saudi Arabia. The work was supported by the Stanford Natural Gas Initiative, the Sloan Research Fellowship, the U.S. Department of Energy Office of Basic Energy Sciences, and the National Science Foundation. More

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    Setting carbon management in stone

    Keeping global temperatures within limits deemed safe by the Intergovernmental Panel on Climate Change means doing more than slashing carbon emissions. It means reversing them.

    “If we want to be anywhere near those limits [of 1.5 or 2 C], then we have to be carbon neutral by 2050, and then carbon negative after that,” says Matěj Peč, a geoscientist and the Victor P. Starr Career Development Assistant Professor in the Department of Earth, Atmospheric, and Planetary Sciences (EAPS).

    Going negative will require finding ways to radically increase the world’s capacity to capture carbon from the atmosphere and put it somewhere where it will not leak back out. Carbon capture and storage projects already suck in tens of million metric tons of carbon each year. But putting a dent in emissions will mean capturing many billions of metric tons more. Today, people emit around 40 billion tons of carbon each year globally, mainly by burning fossil fuels.

    Because of the need for new ideas when it comes to carbon storage, Peč has created a proposal for the MIT Climate Grand Challenges competition — a bold and sweeping effort by the Institute to support paradigm-shifting research and innovation to address the climate crisis. Called the Advanced Carbon Mineralization Initiative, his team’s proposal aims to bring geologists, chemists, and biologists together to make permanently storing carbon underground workable under different geological conditions. That means finding ways to speed-up the process by which carbon pumped underground is turned into rock, or mineralized.

    “That’s what the geology has to offer,” says Peč, who is a lead on the project, along with Ed Boyden, professor of biological engineering, brain and cognitive sciences, and media arts and sciences, and Yogesh Surendranath, professor of chemistry. “You look for the places where you can safely and permanently store these huge volumes of CO2.”

    Peč‘s proposal is one of 27 finalists selected from a pool of almost 100 Climate Grand Challenge proposals submitted by collaborators from across the Institute. Each finalist team received $100,000 to further develop their research proposals. A subset of finalists will be announced in April, making up a portfolio of multiyear “flagship” projects receiving additional funding and support.

    Building industries capable of going carbon negative presents huge technological, economic, environmental, and political challenges. For one, it’s expensive and energy-intensive to capture carbon from the air with existing technologies, which are “hellishly complicated,” says Peč. Much of the carbon capture underway today focuses on more concentrated sources like coal- or gas-burning power plants.

    It’s also difficult to find geologically suitable sites for storage. To keep it in the ground after it has been captured, carbon must either be trapped in airtight reservoirs or turned to stone.

    One of the best places for carbon capture and storage (CCS) is Iceland, where a number of CCS projects are up and running. The island’s volcanic geology helps speed up the mineralization process, as carbon pumped underground interacts with basalt rock at high temperatures. In that ideal setting, says Peč, 95 percent of carbon injected underground is mineralized after just two years — a geological flash.

    But Iceland’s geology is unusual. Elsewhere requires deeper drilling to reach suitable rocks at suitable temperature, which adds costs to already expensive projects. Further, says Peč, there’s not a complete understanding of how different factors influence the speed of mineralization.

    Peč‘s Climate Grand Challenge proposal would study how carbon mineralizes under different conditions, as well as explore ways to make mineralization happen more rapidly by mixing the carbon dioxide with different fluids before injecting it underground. Another idea — and the reason why there are biologists on the team — is to learn from various organisms adept at turning carbon into calcite shells, the same stuff that makes up limestone.

    Two other carbon management proposals, led by EAPS Cecil and Ida Green Professor Bradford Hager, were also selected as Climate Grand Challenge finalists. They focus on both the technologies necessary for capturing and storing gigatons of carbon as well as the logistical challenges involved in such an enormous undertaking.

    That involves everything from choosing suitable sites for storage, to regulatory and environmental issues, as well as how to bring disparate technologies together to improve the whole pipeline. The proposals emphasize CCS systems that can be powered by renewable sources, and can respond dynamically to the needs of different hard-to-decarbonize industries, like concrete and steel production.

    “We need to have an industry that is on the scale of the current oil industry that will not be doing anything but pumping CO2 into storage reservoirs,” says Peč.

    For a problem that involves capturing enormous amounts of gases from the atmosphere and storing it underground, it’s no surprise EAPS researchers are so involved. The Earth sciences have “everything” to offer, says Peč, including the good news that the Earth has more than enough places where carbon might be stored.

    “Basically, the Earth is really, really large,” says Peč. “The reasonably accessible places, which are close to the continents, store somewhere on the order of tens of thousands to hundreds thousands of gigatons of carbon. That’s orders of magnitude more than we need to put back in.” More

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    Building communities, founding a startup with people in mind

    MIT postdoc Francesco Benedetti admits he wasn’t always a star student. But the people he met along his educational journey inspired him to strive, which led him to conduct research at MIT, launch a startup, and even lead the team that won the 2021 MIT $100K Entrepreneurship Competition. Now he is determined to make sure his company, Osmoses, succeeds in boosting the energy efficiency of traditional and renewable natural gas processing, hydrogen production, and carbon capture — thus helping to address climate change.

    “I can’t be grateful enough to MIT for bringing together a community of people who want to change the world,” Benedetti says. “Now we have a technology that can solve one of the big problems of our society.”

    Benedetti and his team have developed an innovative way to separate molecules using a membrane fine enough to extract impurities such as carbon dioxide or hydrogen sulfide from raw natural gas to obtain higher-quality fuel, fulfilling a crucial need in the energy industry. “Natural gas now provides about 40 percent of the energy used to power homes and industry in the United States,” Benedetti says. Using his team’s technology to upgrade natural gas more efficiently could reduce emissions of greenhouse gases while saving enough energy to power the equivalent of 7 million additional U.S. homes for a year, he adds.

    The MIT community

    Benedetti first came to MIT in 2017 as a visiting student from the University of Bologna in Italy, where he was working on membranes for gas separation for his PhD in chemical engineering. Having completed a master’s thesis on water desalination at the University of Texas (UT) at Austin, he connected with UT alumnus Zachary P. Smith, the Robert N. Noyce Career Development Professor of Chemical Engineering at MIT, and the two discovered they shared a vision. “We found ourselves very much aligned on the need for new technology in industry to lower the energy consumption of separating components,” Benedetti says.

    Although Benedetti had always been interested in making a positive impact on the world, particularly the environment, he says it was his university studies that first sparked his interest in more efficient separation technologies. “When you study chemical engineering, you understand hundreds of ways the field can have a positive impact in the world. But we learn very early that 15 percent of the world’s energy is wasted because of inefficient chemical separation — because we still rely on centuries-old technology,” he says. Most separation processes still use heat or toxic solvents to separate components, he explains.

    Still, Benedetti says, his main drive comes from the joy of working with terrific mentors and colleagues. “It’s the people I’ve met that really inspired me to tackle the biggest challenges and find that intrinsic motivation,” he says.

    To help build his community at MIT and provide support for international students, Benedetti co-founded the MIT Visiting Student Association (VISTA) in September 2017. By February 2018, the organization had hundreds of members and official Institute recognition. In May 2018, the group won two Institute awards, including the Golden Beaver Award for enhancing the campus environment. “VISTA gave me a sense of belonging; I loved it,” Benedetti says.

    Membrane technology

    Benedetti also published two papers on membrane research during his stint as a visiting student at MIT, so he was delighted to return in 2019 for postdoctoral work through the MIT Energy Initiative, where he was a 2019-20 ExxonMobil-MIT Energy Fellow. “I came back because the research was extremely exciting, but also because I got extremely passionate about the energy I found on campus and with the people,” he says.

    Returning to MIT enabled Benedetti to continue his work with Smith and Holden Lai, both of whom helped co-found Osmoses. Lai, a recent Stanford PhD in chemistry who was also a visiting student at MIT in 2018, is now the chief technology officer at Osmoses. Co-founder Katherine Mizrahi Rodriguez ’17, an MIT PhD candidate, joined the team more recently.

    Together, the Osmoses team has developed polymer membranes with microporosities capable of filtering gases by separating out molecules that differ by as little as a fraction of an angstrom — a unit of length equal to one hundred-millionth of a centimeter. “We can get up to five times higher selectivity than commercially available technology for methane upgrading, and this has been observed operating the membranes in industrially relevant environments,” Benedetti says.

    Today, methane upgrading — removing carbon dioxide (CO2) from raw natural gas to obtain a higher-grade fuel — is often accomplished using amine absorption, a process that uses toxic solvents to capture CO2 and burns methane to fuel the regeneration of those solvents for reuse. Using Osmoses’ filters would eliminate the need for such solvents while reducing CO2 emissions by up to 16 million metric tons per year in the United States alone, Benedetti says.

    The technology has a wide range of applications — in oxygen and nitrogen generation, hydrogen purification, and carbon capture, for example — but Osmoses plans to start with the $5 billion market for natural gas upgrading because the need to bring innovation and sustainability to that space is urgent, says Benedetti, who received guidance in bringing technology to market from MIT’s Deshpande Center for Technological Innovation. The Osmoses team has also received support from the MIT Sandbox Innovation Fund Program.

    The next step for the startup is to build an industrial-scale prototype, and Benedetti says the company got a huge boost toward that goal in May when it won the MIT $100K Entrepreneurship Competition, a student-run contest that has launched more than 160 companies since it began in 1990. Ninety teams began the competition by pitching their startup ideas; 20 received mentorship and development funding; then eight finalists presented business plans to compete for the $100,000 prize. “Because of this, we’re getting a lot of interest from venture capital firms, investors, companies, corporate funds, et cetera, that want to partner with us or to use our product,” he says. In June, the Osmoses team received a two-year Activate Fellowship, which will support moving its research to market; in October, it won the Northeast Regional and Carbon Sequestration Prizes at the Cleantech Open Accelerator; and in November, the team closed a $3 million pre-seed round of financing.

    FAIL!

    Naturally, Benedetti hopes Osmoses is on the path to success, but he wants everyone to know that there is no shame in failures that come from best efforts. He admits it took him three years longer than usual to finish his undergraduate and master’s degrees, and he says, “I have experienced the pressure you feel when society judges you like a book by its cover and how much a lack of inspired leaders and a supportive environment can kill creativity and the will to try.”

    That’s why in 2018 he, along with other MIT students and VISTA members, started FAIL!–Inspiring Resilience, an organization that provides a platform for sharing unfiltered stories and the lessons leaders have gleaned from failure. “We wanted to help de-stigmatize failure, appreciate vulnerabilities, and inspire humble leadership, eventually creating better communities,” Benedetti says. “If we can make failures, big and small, less intimidating and all-consuming, individuals with great potential will be more willing to take risks, think outside the box, and try things that may push new boundaries. In this way, more breakthrough discoveries are likely to follow, without compromising anyone’s mental health.”

    Benedetti says he will strive to create a supportive culture at Osmoses, because people are central to success. “What drives me every day is the people. I would have no story without the people around me,” he says. “The moment you lose touch with people, you lose the opportunity to create something special.”

    This article appears in the Autumn 2021 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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    How to clean solar panels without water

    Solar power is expected to reach 10 percent of global power generation by the year 2030, and much of that is likely to be located in desert areas, where sunlight is abundant. But the accumulation of dust on solar panels or mirrors is already a significant issue — it can reduce the output of photovoltaic panels by as much as 30 percent in just one month — so regular cleaning is essential for such installations.

    But cleaning solar panels currently is estimated to use about 10 billion gallons of water per year — enough to supply drinking water for up to 2 million people. Attempts at waterless cleaning are labor intensive and tend to cause irreversible scratching of the surfaces, which also reduces efficiency. Now, a team of researchers at MIT has devised a way of automatically cleaning solar panels, or the mirrors of solar thermal plants, in a waterless, no-contact system that could significantly reduce the dust problem, they say.

    The new system uses electrostatic repulsion to cause dust particles to detach and virtually leap off the panel’s surface, without the need for water or brushes. To activate the system, a simple electrode passes just above the solar panel’s surface, imparting an electrical charge to the dust particles, which are then repelled by a charge applied to the panel itself. The system can be operated automatically using a simple electric motor and guide rails along the side of the panel. The research is described today in the journal Science Advances, in a paper by MIT graduate student Sreedath Panat and professor of mechanical engineering Kripa Varanasi.

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    Despite concerted efforts worldwide to develop ever more efficient solar panels, Varanasi says, “a mundane problem like dust can actually put a serious dent in the whole thing.” Lab tests conducted by Panat and Varanasi showed that the dropoff of energy output from the panels happens steeply at the very beginning of the process of dust accumulation and can easily reach 30 percent reduction after just one month without cleaning. Even a 1 percent reduction in power, for a 150-megawatt solar installation, they calculated, could result in a $200,000 loss in annual revenue. The researchers say that globally, a 3 to 4 percent reduction in power output from solar plants would amount to a loss of between $3.3 billion and $5.5 billion.

    “There is so much work going on in solar materials,” Varanasi says. “They’re pushing the boundaries, trying to gain a few percent here and there in improving the efficiency, and here you have something that can obliterate all of that right away.”

    Many of the largest solar power installations in the world, including ones in China, India, the U.A.E., and the U.S., are located in desert regions. The water used for cleaning these solar panels using pressurized water jets has to be trucked in from a distance, and it has to be very pure to avoid leaving behind deposits on the surfaces. Dry scrubbing is sometimes used but is less effective at cleaning the surfaces and can cause permanent scratching that also reduces light transmission.

    Water cleaning makes up about 10 percent of the operating costs of solar installations. The new system could potentially reduce these costs while improving the overall power output by allowing for more frequent automated cleanings, the researchers say.

    “The water footprint of the solar industry is mind boggling,” Varanasi says, and it will be increasing as these installations continue to expand worldwide. “So, the industry has to be very careful and thoughtful about how to make this a sustainable solution.”

    Other groups have tried to develop electrostatic based solutions, but these have relied on a layer called an electrodynamic screen, using interdigitated electrodes. These screens can have defects that allow moisture in and cause them to fail, Varanasi says. While they might be useful on a place like Mars, he says, where moisture is not an issue, even in desert environments on Earth this can be a serious problem.

    The new system they developed only requires an electrode, which can be a simple metal bar, to pass over the panel, producing an electric field that imparts a charge to the dust particles as it goes. An opposite charge applied to a transparent conductive layer just a few nanometers thick deposited on the glass covering of the the solar panel then repels the particles, and by calculating the right voltage to apply, the researchers were able to find a voltage range sufficient to overcome the pull of gravity and adhesion forces, and cause the dust to lift away.

    Using specially prepared laboratory samples of dust with a range of particle sizes, experiments proved that the process works effectively on a laboratory-scale test installation, Panat says. The tests showed that humidity in the air provided a thin coating of water on the particles, which turned out to be crucial to making the effect work. “We performed experiments at varying humidities from 5 percent to 95 percent,” Panat says. “As long as the ambient humidity is greater than 30 percent, you can remove almost all of the particles from the surface, but as humidity decreases, it becomes harder.”

    Varanasi says that “the good news is that when you get to 30 percent humidity, most deserts actually fall in this regime.” And even those that are typically drier than that tend to have higher humidity in the early morning hours, leading to dew formation, so the cleaning could be timed accordingly.

    “Moreover, unlike some of the prior work on electrodynamic screens, which actually do not work at high or even moderate humidity, our system can work at humidity even as high as 95 percent, indefinitely,” Panat says.

    In practice, at scale, each solar panel could be fitted with railings on each side, with an electrode spanning across the panel. A small electric motor, perhaps using a tiny portion of the output from the panel itself, would drive a belt system to move the electrode from one end of the panel to the other, causing all the dust to fall away. The whole process could be automated or controlled remotely. Alternatively, thin strips of conductive transparent material could be permanently arranged above the panel, eliminating the need for moving parts.

    By eliminating the dependency on trucked-in water, by eliminating the buildup of dust that can contain corrosive compounds, and by lowering the overall operational costs, such systems have the potential to significantly improve the overall efficiency and reliability of solar installations, Varanasi says.

    The research was supported by Italian energy firm Eni. S.p.A. through the MIT Energy Initiative. More

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    Q&A: Randolph Kirchain on how cool pavements can mitigate climate change

    As cities search for climate change solutions, many have turned to one burgeoning technology: cool pavements. By reflecting a greater proportion of solar radiation, cool pavements can offer an array of climate change mitigation benefits, from direct radiative forcing to reduced building energy demand.

    Yet, scientists from the MIT Concrete Sustainability Hub (CSHub) have found that cool pavements are not just a summertime solution. Here, Randolph Kirchain, a principal research scientist at CSHub, discusses how implementing cool pavements can offer myriad greenhouse gas reductions in cities — some of which occur even in the winter.

    Q: What exactly are cool pavements? 

    A: There are two ways to make a cool pavement: changing the pavement formulation to make the pavement porous like a sponge (a so-called “pervious pavement”), or paving with reflective materials. The latter method has been applied extensively because it can be easily adopted on the current road network with different traffic volumes while sustaining — and sometimes improving — the road longevity. To the average observer, surface reflectivity usually corresponds to the color of a pavement — the lighter, the more reflective. 

    We can quantify this surface reflectivity through a measurement called albedo, which refers to the percentage of light a surface reflects. Typically, a reflective pavement has an albedo of 0.3 or higher, meaning that it reflects 30 percent of the light it receives.

    To attain this reflectivity, there are a number of techniques at our disposal. The most common approach is to simply paint a brighter coating atop existing pavements. But it’s also possible to pave with materials that possess naturally greater reflectivity, such as concrete or lighter-colored binders and aggregates.

    Q: How can cool pavements mitigate climate change?

    A: Cool pavements generate several, often unexpected, effects. The most widely known is a reduction in surface and local air temperatures. This occurs because cool pavements absorb less radiation and, consequently, emit less of that radiation as heat. In the summer, this means they can lower urban air temperatures by several degrees Fahrenheit.

    By changing air temperatures or reflecting light into adjacent structures, cool pavements can also alter the need for heating and cooling in those structures, which can change their energy demand and, therefore, mitigate the climate change impacts associated with building energy demand.

    However, depending on how dense the neighborhood is built, a proportion of the radiation cool pavements reflect doesn’t strike buildings; instead, it travels back into the atmosphere and out into space. This process, called a radiative forcing, shifts the Earth’s energy balance and effectively offsets some of the radiation trapped by greenhouse gases (GHGs).

    Perhaps the least-known impact of cool pavements is on vehicle fuel consumption. Certain cool pavements, namely concrete, possess a combination of structural properties and longevity that can minimize the excess fuel consumption of vehicles caused by road quality. Over the lifetime of a pavement, these fuel savings can add up — often offsetting the higher initial footprint of paving with more durable materials.

    Q: With these impacts in mind, how do the effects of cool pavements vary seasonally and by location?

    A: Many view cool pavements as a solution to summer heat. But research has shown that they can offer climate change benefits throughout the year.

    In high-volume traffic roads, the most prominent climate change benefit of cool pavements is not their reflectivity but their impact on vehicle fuel consumption. As such, cool pavement alternatives that minimize fuel consumption can continue to cut GHG emissions in winter, assuming traffic is constant.

    Even in winter, pavement reflectivity still contributes greatly to the climate change mitigation benefits of cool pavements. We found that roughly a third of the annual CO2-equivalent emissions reductions from the radiative forcing effects of cool pavements occurred in the fall and winter.

    It’s important to note, too, that the direction — not just the magnitude — of cool pavement impacts also vary seasonally. The most prominent seasonal variation is the changes to building energy demand. As they lower air temperatures, cool pavements can lessen the demand for cooling in buildings in the summer, while, conversely, they can cause buildings to consume more energy and generate more emissions due to heating in the winter.

    Interestingly, the radiation reflected by cool pavements can also strike adjacent buildings, heating them up. In the summer, this can increase building energy demand significantly, yet in the winter it can also warm structures and reduce their need for heating. In that sense, cool pavements can warm — as well as cool — their surroundings, depending on the building insolation [solar exposure] systems and neighborhood density.

    Q: How can cities manage these many impacts?

    A: As you can imagine, such different and often competing impacts can complicate the implementation of cool pavements. In some contexts, for instance, a cool pavement might even generate more emissions over its life than a conventional pavement — despite lowering air temperatures.

    To ensure that the lowest-emitting pavement is selected, then, cities should use a life-cycle perspective that considers all potential impacts. When they do, research has shown that they can reap sizeable benefits. The city of Phoenix, for instance, could see its projected emissions fall by as much as 6 percent, while Boston would experience a reduction of up to 3 percent.

    These benefits don’t just demonstrate the potential of cool pavements: they also reflect the outsized impact of pavements on our built environment and, moreover, our climate. As cities move to fight climate change, they should know that one of their most extensive assets also presents an opportunity for greater sustainability.

    The MIT Concrete Sustainability Hub is a team of researchers from several departments across MIT working on concrete and infrastructure science, engineering, and economics. Its research is supported by the Portland Cement Association and the Ready Mixed Concrete Research and Education Foundation. More

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    MIT Center for Real Estate launches the Asia Real Estate Initiative

    To appreciate the explosive urbanization taking place in Asia, consider this analogy: Every 40 days, a city the equivalent size of Boston is built in Asia. Of the $24.7 trillion real estate investment opportunities predicted by 2030 in emerging cities, $17.8 trillion (72 percent) will be in Asia. While this growth is exciting to the real estate industry, it brings with it the attendant social and environmental issues.

    To promote a sustainable and innovative approach to this growth, leadership at the MIT Center for Real Estate (MIT CRE) recently established the Asia Real Estate Initiative (AREI), which aims to become a platform for industry leaders, entrepreneurs, and the academic community to find solutions to the practical concerns of real estate development across these countries.

    “Behind the creation of this initiative is the understanding that Asia is a living lab for the study of future global urban development,” says Hashim Sarkis, dean of the MIT School of Architecture and Planning.

    An investment in cities of the future

    One of the areas in AREI’s scope of focus is connecting sustainability and technology in real estate.

    “We believe the real estate sector should work cooperatively with the energy, science, and technology sectors to solve the climate challenges,” says Richard Lester, the Institute’s associate provost for international activities. “AREI will engage academics and industry leaders, nongovernment organizations, and civic leaders globally and in Asia, to advance sharing knowledge and research.”

    In its effort to understand how trends and new technologies will impact the future of real estate, AREI has received initial support from a prominent alumnus of MIT CRE who wishes to remain anonymous. The gift will support a cohort of researchers working on innovative technologies applicable to advancing real estate sustainability goals, with a special focus on the global and Asia markets. The call for applications is already under way, with AREI seeking to collaborate with scholars who have backgrounds in economics, finance, urban planning, technology, engineering, and other disciplines.

    “The research on real estate sustainability and technology could transform this industry and help invent global real estate of the future,” says Professor Siqi Zheng, faculty director of MIT CRE and AREI faculty chair. “The pairing of real estate and technology often leads to innovative and differential real estate development strategies such as buildings that are green, smart, and healthy.”

    The initiative arrives at a key time to make a significant impact and cement a leadership role in real estate development across Asia. MIT CRE is positioned to help the industry increase its efficiency and social responsibility, with nearly 40 years of pioneering research in the field. Zheng, an established scholar with expertise on urban growth in fast-urbanizing regions, is the former president of the Asia Real Estate Society and sits on the Board of American Real Estate and Urban Economics Association. Her research has been supported by international institutions including the World Bank, the Asian Development Bank, and the Lincoln Institute of Land Policy.

    “The researchers in AREI are now working on three interrelated themes: the future of real estate and live-work-play dynamics; connecting sustainability and technology in real estate; and innovations in real estate finance and business,” says Zheng.

    The first theme has already yielded a book — “Toward Urban Economic Vibrancy: Patterns and Practices in Asia’s New Cities” — recently published by SA+P Press.

    Engaging thought leaders and global stakeholders

    AREI also plans to collaborate with counterparts in Asia to contribute to research, education, and industry dialogue to meet the challenges of sustainable city-making across the continent and identify areas for innovation. Traditionally, real estate has been a very local business with a lengthy value chain, according to Zhengzhen Tan, director of AREI. Most developers focused their career on one particular product type in one particular regional market. AREI is working to change that dynamic.

    “We want to create a cross-border dialogue within Asia and among Asia, North America, and European leaders to exchange knowledge and practices,” says Tan. “The real estate industry’s learning costs are very high compared to other sectors. Collective learning will reduce the cost of failure and have a significant impact on these global issues.”

    The 2021 United Nations Climate Change Conference in Glasgow shed additional light on environmental commitments being made by governments in Asia. With real estate representing 40 percent of global greenhouse gas emissions, the Asian real estate market is undergoing an urgent transformation to deliver on this commitment.

    “One of the most pressing calls is to get to net-zero emissions for real estate development and operation,” says Tan. “Real estate investors and developers are making short- and long-term choices that are locking in environmental footprints for the ‘decisive decade.’ We hope to inspire developers and investors to think differently and get out of their comfort zone.” More

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    Can the world meet global climate targets without coordinated global action?

    Like many of its predecessors, the 2021 United Nations Climate Change Conference (COP26) in Glasgow, Scotland concluded with bold promises on international climate action aimed at keeping global warming well below 2 degrees Celsius, but few concrete plans to ensure that those promises will be kept. While it’s not too late for the Paris Agreement’s nearly 200 signatory nations to take concerted action to cap global warming at 2 C — if not 1.5 C — there is simply no guarantee that they will do so. If they fail, how much warming is the Earth likely to see in the 21st century and beyond?

    A new study by researchers at the MIT Joint Program on the Science and Policy of Global Change and the Shell Scenarios Team projects that without a globally coordinated mitigation effort to reduce greenhouse gas emissions, the planet’s average surface temperature will reach 2.8 C, much higher than the “well below 2 C” level to which the Paris Agreement aspires, but a lot lower than what many widely used “business-as-usual” scenarios project.  

    Recognizing the limitations of such scenarios, which generally assume that historical trends in energy technology choices and climate policy inaction will persist for decades to come, the researchers have designed a “Growing Pressures” scenario that accounts for mounting social, technological, business, and political pressures that are driving a transition away from fossil-fuel use and toward a low-carbon future. Such pressures have already begun to expand low-carbon technology and policy options, which, in turn, have escalated demand to utilize those options — a trend that’s expected to self-reinforce. Under this scenario, an array of future actions and policies cause renewable energy and energy storage costs to decline; fossil fuels to be phased out; electrification to proliferate; and emissions from agriculture and industry to be sharply reduced.

    Incorporating these growing pressures in the MIT Joint Program’s integrated model of Earth and human systems, the study’s co-authors project future energy use, greenhouse gas emissions, and global average surface temperatures in a world that fails to implement coordinated, global climate mitigation policies, and instead pursues piecemeal actions at mostly local and national levels.

    “Few, if any, previous studies explore scenarios of how piecemeal climate policies might plausibly unfold into the future and impact global temperature,” says MIT Joint Program research scientist Jennifer Morris, the study’s lead author. “We offer such a scenario, considering a future in which the increasingly visible impacts of climate change drive growing pressure from voters, shareholders, consumers, and investors, which in turn drives piecemeal action by governments and businesses that steer investments away from fossil fuels and toward low-carbon alternatives.”

    In the study’s central case (representing the mid-range climate response to greenhouse gas emissions), fossil fuels persist in the global energy mix through 2060 and then slowly decline toward zero by 2130; global carbon dioxide emissions reach near-zero levels by 2130 (total greenhouse gas emissions decline to near-zero by 2150); and global surface temperatures stabilize at 2.8 C by 2150, 2.5 C lower than a widely used “business-as-usual” projection. The results appear in the journal Environmental Economics and Policy Studies.

    Such a transition could bring the global energy system to near-zero emissions, but more aggressive climate action would be needed to keep global temperatures well below 2 C in alignment with the Paris Agreement.

    “While we fully support the need to decarbonize as fast as possible, it is critical to assess realistic alternative scenarios of world development,” says Joint Program Deputy Director Sergey Paltsev, a co-author of the study. “We investigate plausible actions that could bring society closer to the long-term goals of the Paris Agreement. To actually meet those goals will require an accelerated transition away from fossil energy through a combination of R&D, technology deployment, infrastructure development, policy incentives, and business practices.”

    The study was funded by government, foundation, and industrial sponsors of the MIT Joint Program, including Shell International Ltd. More

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    Reducing methane emissions at landfills

    The second-largest driver of global warming is methane, a greenhouse gas 28 times more potent than carbon dioxide. Landfills are a major source of methane, which is created when organic material decomposes underground.

    Now a startup that began at MIT is aiming to significantly reduce methane emissions from landfills with a system that requires no extra land, roads, or electric lines to work. The company, Loci Controls, has developed a solar-powered system that optimizes the collection of methane from landfills so more of it can be converted into natural gas.

    At the center of Loci’s (pronounced “low-sigh”) system is a lunchbox-sized device that attaches to methane collection wells, which vacuum the methane up to the surface for processing. The optimal vacuum force changes with factors like atmospheric pressure and temperature. Loci’s system monitors those factors and adjusts the vacuum force at each well far more frequently than is possible with field technicians making manual adjustments.

    “We expect to reduce methane emissions more than any other company in the world over the next five years,” Loci Controls CEO Peter Quigley ’85 says. The company was founded by Melinda Hale Sims SM ’09, PhD ’12 and Andrew Campanella ’05, SM ’13.

    The reason for Quigley’s optimism is the high concentration of landfill methane emissions. Most landfill emissions in the U.S. come from about 1,000 large dumps. Increasing collection of methane at those sites could make a significant dent in the country’s overall emissions.

    In one landfill where Loci’s system was installed, for instance, the company says it increased methane sales at an annual rate of 180,000 metric tons of carbon dioxide equivalent. That’s about the same as removing 40,000 cars from the road for a year.

    Loci’s system is currently installed on wells in 15 different landfills. Quigley says only about 70 of the 1,000 big landfills in the U.S. sell gas profitably. Most of the others burn the gas. But Loci’s team believes increasing public and regulatory pressure will help expands its potential customer base.

    Uncovering a major problem

    The idea for Loci came from a revelation by Sims’ father, serial entrepreneur Michael Hale SM ’85, PhD ’89. The elder Hale was working in wastewater management when he was contacted by a landfill in New York that wanted help using its excess methane gas.

    “He realized if he could help that particular landfill with the problem, it would apply to almost any landfill,” Sims says.

    At the time, Sims was pursuing her PhD in mechanical engineering at MIT and minoring in entrepreneurship.

    Her father didn’t have time to work on the project, but Sims began exploring technology solutions to improve methane capture at landfills in her business classes. The work was unrelated to her PhD, but her advisor, David Hardt, the Ralph E. and Eloise F. Cross Professor in Manufacturing at MIT, was understanding. (Hardt had also served as PhD advisor for Sim’s father, who was, after all, the person to blame for Sim’s new side project.)

    Sims partnered with Andrew Campanella, then a master’s student focused on electrical engineering, and the two went through the delta v summer accelerator program hosted by the Martin Trust Center for MIT Entrepreneurship.

    Quigley was retired but serving on multiple visiting committees at MIT when he began mentoring Loci’s founders. He’d spent his career commercializing reinforced plastic through two companies, one in the high-performance sporting goods industry and the other in oil field services.

    “What captured my imagination was the emissions-reduction opportunity,” Quigley says.

    Methane is generated in landfills when organic waste decomposes. Some landfill operators capture the methane by drilling hundreds of collection wells. The vacuum pressure of those wells needs to be adjusted to maximize the amount of methane collected, but Quigley says technicians can only make those adjustments manually about once a month.

    Loci’s devices monitor gas composition, temperature, and environmental factors like barometric pressure to optimize vacuum power every hour. The data the controllers collect is aggregated in an analytics platform for technicians to monitor remotely. That data can also be used to pinpoint well failure events, such as flooding during rain, and otherwise improve operations to increase the amount of methane captured.

    “We can adjust the valves automatically, but we also have data that allows on-site operators to identify and remedy problems much more quickly,” Quigley explains.

    Furthering a high-impact mission

    Methane capture at landfills is becoming more urgent as improvements in detection technologies are revealing discrepancies between methane emission estimates and reality in the industry. A new airborne methane sensor deployed by NASA, for instance, found that California landfills have been leaking methane at rates as much as six times greater than estimates from the U.S. Environmental Protection Agency. The difference has major implications for the Earth’s atmosphere.

    A reckoning will have to occur to motivate more waste management companies to start collecting methane and to optimize methane capture. That could come in the form of new collection standards or an increased emphasis on methane collection from investors. (Funds controlled by billionaires Bill Gates and Larry Fink are major investors in waste management companies.)

    For now, Loci’s team, including co-founder and current senior advisor Sims, believes it’s on the road to making a meaningful impact under current market conditions.

    “When I was in grad school, the majority of the focus on emissions was on CO2,” Sims says. “I think methane is a really high-impact place to be focused, and I think it’s been underestimated how valuable it could be to apply technology to the industry.” More