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    To decarbonize the chemical industry, electrify it

    The chemical industry is the world’s largest industrial energy consumer and the third-largest source of industrial emissions, according to the International Energy Agency. In 2019, the industrial sector as a whole was responsible for 24 percent of global greenhouse gas emissions. And yet, as the world races to find pathways to decarbonization, the chemical industry has been largely untouched.

    “When it comes to climate action and dealing with the emissions that come from the chemical sector, the slow pace of progress is partly technical and partly driven by the hesitation on behalf of policymakers to overly impact the economic competitiveness of the sector,” says Dharik Mallapragada, a principal research scientist at the MIT Energy Initiative.

    With so many of the items we interact with in our daily lives — from soap to baking soda to fertilizer — deriving from products of the chemical industry, the sector has become a major source of economic activity and employment for many nations, including the United States and China. But as the global demand for chemical products continues to grow, so do the industry’s emissions.

    New sustainable chemical production methods need to be developed and deployed and current emission-intensive chemical production technologies need to be reconsidered, urge the authors of a new paper published in Joule. Researchers from DC-MUSE, a multi-institution research initiative, argue that electrification powered by low-carbon sources should be viewed more broadly as a viable decarbonization pathway for the chemical industry. In this paper, they shine a light on different potential methods to do just that.

    “Generally, the perception is that electrification can play a role in this sector — in a very narrow sense — in that it can replace fossil fuel combustion by providing the heat that the combustion is providing,” says Mallapragada, a member of DC-MUSE. “What we argue is that electrification could be much more than that.”

    The researchers outline four technological pathways — ranging from more mature, near-term options to less technologically mature options in need of research investment — and present the opportunities and challenges associated with each.

    The first two pathways directly replace fossil fuel-produced heat (which facilitates the reactions inherent in chemical production) with electricity or electrochemically generated hydrogen. The researchers suggest that both options could be deployed now and potentially be used to retrofit existing facilities. Electrolytic hydrogen is also highlighted as an opportunity to replace fossil fuel-produced hydrogen (a process that emits carbon dioxide) as a critical chemical feedstock. In 2020, fossil-based hydrogen supplied nearly all hydrogen demand (90 megatons) in the chemical and refining industries — hydrogen’s largest consumers.

    The researchers note that increasing the role of electricity in decarbonizing the chemical industry will directly affect the decarbonization of the power grid. They stress that to successfully implement these technologies, their operation must coordinate with the power grid in a mutually beneficial manner to avoid overburdening it. “If we’re going to be serious about decarbonizing the sector and relying on electricity for that, we have to be creative in how we use it,” says Mallapragada. “Otherwise we run the risk of having addressed one problem, while creating a massive problem for the grid in the process.”

    Electrified processes have the potential to be much more flexible than conventional fossil fuel-driven processes. This can reduce the cost of chemical production by allowing producers to shift electricity consumption to times when the cost of electricity is low. “Process flexibility is particularly impactful during stressed power grid conditions and can help better accommodate renewable generation resources, which are intermittent and are often poorly correlated with daily power grid cycles,” says Yury Dvorkin, an associate research professor at the Johns Hopkins Ralph O’Connor Sustainable Energy Institute. “It’s beneficial for potential adopters because it can help them avoid consuming electricity during high-price periods.”

    Dvorkin adds that some intermediate energy carriers, such as hydrogen, can potentially be used as highly efficient energy storage for day-to-day operations and as long-term energy storage. This would help support the power grid during extreme events when traditional and renewable generators may be unavailable. “The application of long-duration storage is of particular interest as this is a key enabler of a low-emissions society, yet not widespread beyond pumped hydro units,” he says. “However, as we envision electrified chemical manufacturing, it is important to ensure that the supplied electricity is sourced from low-emission generators to prevent emissions leakages from the chemical to power sector.” 

    The next two pathways introduced — utilizing electrochemistry and plasma — are less technologically mature but have the potential to replace energy- and carbon-intensive thermochemical processes currently used in the industry. By adopting electrochemical processes or plasma-driven reactions instead, chemical transformations can occur at lower temperatures and pressures, potentially enhancing efficiency. “These reaction pathways also have the potential to enable more flexible, grid-responsive plants and the deployment of modular manufacturing plants that leverage distributed chemical feedstocks such as biomass waste — further enhancing sustainability in chemical manufacturing,” says Miguel Modestino, the director of the Sustainable Engineering Initiative at the New York University Tandon School of Engineering.

    A large barrier to deep decarbonization of chemical manufacturing relates to its complex, multi-product nature. But, according to the researchers, each of these electricity-driven pathways supports chemical industry decarbonization for various feedstock choices and end-of-life disposal decisions. Each should be evaluated in comprehensive techno-economic and environmental life cycle assessments to weigh trade-offs and establish suitable cost and performance metrics.

    Regardless of the pathway chosen, the researchers stress the need for active research and development and deployment of these technologies. They also emphasize the importance of workforce training and development running in parallel to technology development. As André Taylor, the director of DC-MUSE, explains, “There is a healthy skepticism in the industry regarding electrification and adoption of these technologies, as it involves processing chemicals in a new way.” The workforce at different levels of the industry hasn’t necessarily been exposed to ideas related to the grid, electrochemistry, or plasma. The researchers say that workforce training at all levels will help build greater confidence in these different solutions and support customer-driven industry adoption.

    “There’s no silver bullet, which is kind of the standard line with all climate change solutions,” says Mallapragada. “Each option has pros and cons, as well as unique advantages. But being aware of the portfolio of options in which you can use electricity allows us to have a better chance of success and of reducing emissions — and doing so in a way that supports grid decarbonization.”

    This work was supported, in part, by the Alfred P. Sloan Foundation. More

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    Evan Leppink: Seeking a way to better stabilize the fusion environment

    “Fusion energy was always one of those kind-of sci-fi technologies that you read about,” says nuclear science and engineering PhD candidate Evan Leppink. He’s recalling the time before fusion became a part of his daily hands-on experience at MIT’s Plasma Science and Fusion Center, where he is studying a unique way to drive current in a tokamak plasma using radiofrequency (RF) waves. 

    Now, an award from the U.S. Department of Energy’s (DOE) Office of Science Graduate Student Research (SCGSR) Program will support his work with a 12-month residency at the DIII-D National Fusion Facility in San Diego, California.

    Like all tokamaks, DIII-D generates hot plasma inside a doughnut-shaped vacuum chamber wrapped with magnets. Because plasma will follow magnetic field lines, tokamaks are able to contain the turbulent plasma fuel as it gets hotter and denser, keeping it away from the edges of the chamber where it could damage the wall materials. A key part of the tokamak concept is that part of the magnetic field is created by electrical currents in the plasma itself, which helps to confine and stabilize the configuration. Researchers often launch high-power RF waves into tokamaks to drive that current.

    Leppink will be contributing to research, led by his MIT advisor Steve Wukitch, that pursues launching RF waves in DIII-D using a unique compact antenna placed on the tokamak center column. Typically, antennas are placed inside the tokamak on the outer edge of the doughnut, farthest from the central hole (or column), primarily because access and installation are easier there. This is known as the “low-field side,” because the magnetic field is lower there than at the central column, the “high-field side.” This MIT-led experiment, for the first time, will mount an antenna on the high-field side. There is some theoretical evidence that placing the wave launcher there could improve power penetration and current drive efficiency. And because the plasma environment is less harsh on this side, the antenna will survive longer, a factor important for any future power-producing tokamak.

    Leppink’s work on DIII-D focuses specifically on measuring the density of plasmas generated in the tokamak, for which he developed a “reflectometer.” This small antenna launches microwaves into the plasma, which reflect back to the antenna to be measured. The time that it takes for these microwaves to traverse the plasma provides information about the plasma density, allowing researchers to build up detailed density profiles, data critical for injecting RF power into the plasma.

    “Research shows that when we try to inject these waves into the plasma to drive the current, they can lose power as they travel through the edge region of the tokamak, and can even have problems entering the core of the plasma, where we would most like to direct them,” says Leppink. “My diagnostic will measure that edge region on the high-field side near the launcher in great detail, which provides us a way to directly verify calculations or compare actual results with simulation results.”

    Although focused on his own research, Leppink has excelled at priming other students for success in their studies and research. In 2021 he received the NSE Outstanding Teaching Assistant and Mentorship Award.

    “The highlights of TA’ing for me were the times when I could watch students go from struggling with a difficult topic to fully understanding it, often with just a nudge in the right direction and then allowing them to follow their own intuition the rest of the way,” he says.

    The right direction for Leppink points toward San Diego and RF current drive experiments on DIII-D. He is grateful for the support from the SCGSR, a program created to prepare graduate students like him for science, technology, engineering, or mathematics careers important to the DOE Office of Science mission. It provides graduate thesis research opportunities through extended residency at DOE national laboratories. He has already made several trips to DIII-D, in part to install his reflectometer, and has been impressed with the size of the operation.

    “It takes a little while to kind of compartmentalize everything and say, ‘OK, well, here’s my part of the machine. This is what I’m doing.’ It can definitely be overwhelming at times. But I’m blessed to be able to work on what has been the workhorse tokamak of the United States for the past few decades.” More

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    How the universe got its magnetic field

    When we look out into space, all of the astrophysical objects that we see are embedded in magnetic fields. This is true not only in the neighborhood of stars and planets, but also in the deep space between galaxies and galactic clusters. These fields are weak — typically much weaker than those of a refrigerator magnet — but they are dynamically significant in the sense that they have profound effects on the dynamics of the universe. Despite decades of intense interest and research, the origin of these cosmic magnetic fields remains one of the most profound mysteries in cosmology.

    In previous research, scientists came to understand how turbulence, the churning motion common to fluids of all types, could amplify preexisting magnetic fields through the so-called dynamo process. But this remarkable discovery just pushed the mystery one step deeper. If a turbulent dynamo could only amplify an existing field, where did the “seed” magnetic field come from in the first place?

    We wouldn’t have a complete and self-consistent answer to the origin of astrophysical magnetic fields until we understood how the seed fields arose. New work carried out by MIT graduate student Muni Zhou, her advisor Nuno Loureiro, a professor of nuclear science and engineering at MIT, and colleagues at Princeton University and the University of Colorado at Boulder provides an answer that shows the basic processes that generate a field from a completely unmagnetized state to the point where it is strong enough for the dynamo mechanism to take over and amplify the field to the magnitudes that we observe.

    Magnetic fields are everywhere

    Naturally occurring magnetic fields are seen everywhere in the universe. They were first observed on Earth thousands of years ago, through their interaction with magnetized minerals like lodestone, and used for navigation long before people had any understanding of their nature or origin. Magnetism on the sun was discovered at the beginning of the 20th century by its effects on the spectrum of light that the sun emitted. Since then, more powerful telescopes looking deep into space found that the fields were ubiquitous.

    And while scientists had long learned how to make and use permanent magnets and electromagnets, which had all sorts of practical applications, the natural origins of magnetic fields in the universe remained a mystery. Recent work has provided part of the answer, but many aspects of this question are still under debate.

    Amplifying magnetic fields — the dynamo effect

    Scientists started thinking about this problem by considering the way that electric and magnetic fields were produced in the laboratory. When conductors, like copper wire, move in magnetic fields, electric fields are created. These fields, or voltages, can then drive electrical currents. This is how the electricity that we use every day is produced. Through this process of induction, large generators or “dynamos” convert mechanical energy into the electromagnetic energy that powers our homes and offices. A key feature of dynamos is that they need magnetic fields in order to work.

    But out in the universe, there are no obvious wires or big steel structures, so how do the fields arise? Progress on this problem began about a century ago as scientists pondered the source of the Earth’s magnetic field. By then, studies of the propagation of seismic waves showed that much of the Earth, below the cooler surface layers of the mantle, was liquid, and that there was a core composed of molten nickel and iron. Researchers theorized that the convective motion of this hot, electrically conductive liquid and the rotation of the Earth combined in some way to generate the Earth’s field.

    Eventually, models emerged that showed how the convective motion could amplify an existing field. This is an example of “self-organization” — a feature often seen in complex dynamical systems — where large-scale structures grow spontaneously from small-scale dynamics. But just like in a power station, you needed a magnetic field to make a magnetic field.

    A similar process is at work all over the universe. However, in stars and galaxies and in the space between them, the electrically conducting fluid is not molten metal, but plasma — a state of matter that exists at extremely high temperatures where the electrons are ripped away from their atoms. On Earth, plasmas can be seen in lightning or neon lights. In such a medium, the dynamo effect can amplify an existing magnetic field, provided it starts at some minimal level.

    Making the first magnetic fields

    Where does this seed field come from? That’s where the recent work of Zhou and her colleagues, published May 5 in PNAS, comes in. Zhou developed the underlying theory and performed numerical simulations on powerful supercomputers that show how the seed field can be produced and what fundamental processes are at work. An important aspect of the plasma that exists between stars and galaxies is that it is extraordinarily diffuse — typically about one particle per cubic meter. That is a very different situation from the interior of stars, where the particle density is about 30 orders of magnitude higher. The low densities mean that the particles in cosmological plasmas never collide, which has important effects on their behavior that had to be included in the model that these researchers were developing.   

    Calculations performed by the MIT researchers followed the dynamics in these plasmas, which developed from well-ordered waves but became turbulent as the amplitude grew and the interactions became strongly nonlinear. By including detailed effects of the plasma dynamics at small scales on macroscopic astrophysical processes, they demonstrated that the first magnetic fields can be spontaneously produced through generic large-scale motions as simple as sheared flows. Just like the terrestrial examples, mechanical energy was converted into magnetic energy.

    An important output of their computation was the amplitude of the expected spontaneously generated magnetic field. What this showed was that the field amplitude could rise from zero to a level where the plasma is “magnetized” — that is, where the plasma dynamics are strongly affected by the presence of the field. At this point, the traditional dynamo mechanism can take over and raise the fields to the levels that are observed. Thus, their work represents a self-consistent model for the generation of magnetic fields at cosmological scale.

    Professor Ellen Zweibel of the University of Wisconsin at Madison notes that “despite decades of remarkable progress in cosmology, the origin of magnetic fields in the universe remains unknown. It is wonderful to see state-of-the-art plasma physics theory and numerical simulation brought to bear on this fundamental problem.”

    Zhou and co-workers will continue to refine their model and study the handoff from the generation of the seed field to the amplification phase of the dynamo. An important part of their future research will be to determine if the process can work on a time scale consistent with astronomical observations. To quote the researchers, “This work provides the first step in the building of a new paradigm for understanding magnetogenesis in the universe.”

    This work was funded by the National Science Foundation CAREER Award and the Future Investigators of NASA Earth and Space Science Technology (FINESST) grant. More

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    Helping to make nuclear fusion a reality

    Up until she served in the Peace Corps in Malawi, Rachel Bielajew was open to a career reboot. Having studied nuclear engineering as an undergraduate at the University of Michigan at Ann Arbor, graduate school had been on her mind. But seeing the drastic impacts of climate change play out in real-time in Malawi — the lives of the country’s subsistence farmers swing wildly, depending on the rains — convinced Bielajew of the importance of nuclear engineering. Bielajew was struck that her high school students in the small town of Chisenga had a shaky understanding of math, but universally understood global warming. “The concept of the changing world due to human impact was evident, and they could see it,” Bielajew says.

    Bielajew was looking to work on solutions that could positively impact global problems and feed her love of physics. Nuclear engineering, especially the study of fusion as a carbon-free energy source, checked off both boxes. Bielajew is now a fourth-year doctoral candidate in the Department of Nuclear Science and Engineering (NSE). She researches magnetic confinement fusion in the Plasma Science and Fusion Center (PSFC) with Professor Anne White.

    Researching fusion’s big challenge

    You need to confine plasma effectively in order to generate the extremely high temperatures (100 million degrees Celsius) fusion needs, without melting the walls of the tokamak, the device that hosts these reactions. Magnets can do the job, but “plasmas are weird, they behave strangely and are challenging to understand,” Bielajew says. Small instabilities in plasma can coalesce into fluctuating turbulence that can drive heat and particles out of the machine.

    In high-confinement mode, the edges of the plasma have less tolerance for such unruly behavior. “The turbulence gets damped out and sheared apart at the edge,” Bielajew says. This might seem like a good thing, but high-confinement plasmas have their own challenges. They are so tightly bound that they create edge-localized modes (ELMs), bursts of damaging particles and energy, that can be extremely damaging to the machine.

    The questions Bielajew is looking to answer: How do we get high confinement without ELMs? How do turbulence and transport play a role in plasmas? “We do not fully understand turbulence, even though we have studied it for a long time,” Bielajew says, “It is a big and important problem to solve for fusion to be a reality. I like that challenge,” Bielajew adds.

    A love of science

    Confronting such challenges head-on has been part of Bielajew’s toolkit since she was a child growing up in Ann Arbor, Michigan. Her father, Alex Bielajew, is a professor of nuclear engineering at the University of Michigan, and Bielajew’s mother also pursued graduate studies.

    Bielajew’s parents encouraged her to follow her own path and she found it led to her father’s chosen profession: nuclear engineering. Once she decided to pursue research in fusion, MIT stood out as a school she could set her sights on. “I knew that MIT had an extensive program in fusion and a lot of faculty in the field,” Bielajew says. The mechanics of the application were challenging: Chisenga had limited internet access, so Bielajew had to ride on the back of a pickup truck to meet a friend in a city a few hours away and use his phone as a hotspot to send the documents.

    A similar tenacity has surfaced in Bielajew’s approach to research during the Covid-19 pandemic. Working off a blueprint, Bielajew built the Correlation Cyclotron Emission Diagnostic, which measures turbulent electron temperature fluctuations. Through a collaboration, Bielajew conducts her plasma research at the ASDEX Upgrade tokamak in Germany. Traditionally, Bielajew would ship the diagnostic to Germany, follow and install it, and conduct the research in person. The pandemic threw a wrench in the plans, so Bielajew shipped the diagnostic and relied on team members to install it. She Zooms into the control room and trusts others to run the plasma experiments.

    DEI advocate

    Bielajew is very hands-on with another endeavor: improving diversity, equity, and inclusion (DEI) in her own backyard. Having grown up with parental encouragement and in an environment that never doubted her place as a woman in engineering, Bielajew realizes not everyone has the same opportunities. “I wish that the world was in a place where all I had to do was care about my research, but it’s not,” Bielajew says. While science can solve many problems, more fundamental ones about equity need humans to act in specific ways, she points out. “I want to see more women represented, more people of color. Everyone needs a voice in building a better world,” Bielajew says.

    To get there, Bielajew co-launched NSE’s Graduate Application Assistance Program, which connects underrepresented student applicants with NSE mentors. She has been the DEI officer with NSE’s student group, ANS, and is very involved in the department’s DEI committee.

    As for future research, Bielajew hopes to concentrate on the experiments that make her question existing paradigms about plasmas under high confinement. Bielajew has registered more head-scratching “hmm” moments than “a-ha” ones. Measurements from her experiments drive the need for more intensive study.

    Bielajew’s dogs, Dobby and Winky, keep her company through it all. They came home with her from Malawi. More