The next time you cook pasta, imagine that you are cooking spaghetti, rigatoni, and seven other varieties all together, and they need to be separated onto 10 different plates before serving. A colander can remove the water — but you still have a mound of unsorted noodles. Now imagine that this had to be done for thousands of tons of pasta a day. That gives you an idea of the scale of the problem facing Brendan Smith PhD ’18, co-founder and CEO of SiTration, a startup formed out of MIT’s Department of Materials Science and Engineering (DMSE) in 2020. SiTration, which raised $11.8 million in seed capital led by venture capital firm 2150 earlier this month, is revolutionizing the extraction and refining of copper, cobalt, nickel, lithium, precious metals, and other materials critical to manufacturing clean-energy technologies such as electric motors, wind turbines, and batteries. Its initial target applications are recovering the materials from complex mining feed streams, spent lithium-ion batteries from electric vehicles, and various metals refining processes. The company’s breakthrough lies in a new silicon membrane technology that can be adjusted to efficiently recover disparate materials, providing a more sustainable and economically viable alternative to conventional, chemically intensive processes. Think of a colander with adjustable pores to strain different types of pasta. SiTration’s technology has garnered interest from industry players, including mining giant Rio Tinto. Some observers may question whether targeting such different industries could cause the company to lose focus. “But when you dig into these markets, you discover there is actually a significant overlap in how all of these materials are recovered, making it possible for a single solution to have impact across verticals,” Smith says.Powering up materials recoveryConventional methods of extracting critical materials in mining, refining, and recycling lithium-ion batteries involve heavy use of chemicals and heat, which harm the environment. Typically, raw ore from mines or spent batteries are ground into fine particles before being dissolved in acid or incinerated in a furnace. Afterward, they undergo intensive chemical processing to separate and purify the valuable materials. “It requires as much as 10 tons of chemical input to produce one ton of critical material recovered from the mining or battery recycling feedstock,” says Smith. Operators can then sell the recaptured materials back into the supply chain, but suffer from wide swings in profitability due to uncertain market prices. Lithium prices have been the most volatile, having surged more than 400 percent before tumbling back to near-original levels in the past two years. Despite their poor economics and negative environmental impact, these processes remain the state of the art today. By contrast, SiTration is electrifying the critical-materials recovery process, improving efficiency, producing less chemical waste, and reducing the use of chemicals and heat. What’s more, the company’s processing technology is built to be highly adaptable, so it can handle all kinds of materials. The core technology is based on work done at MIT to develop a novel type of membrane made from silicon, which is durable enough to withstand harsh chemicals and high temperatures while conducting electricity. It’s also highly tunable, meaning it can be modified or adjusted to suit different conditions or target specific materials. SiTration’s technology also incorporates electro-extraction, a technique that uses electrochemistry to further isolate and extract specific target materials. This powerful combination of methods in a single system makes it more efficient and effective at isolating and recovering valuable materials, Smith says. So depending on what needs to be separated or extracted, the filtration and electro-extraction processes are adjusted accordingly. “We can produce membranes with pore sizes from the molecular scale up to the size of a human hair in diameter, and everything in between. Combined with the ability to electrify the membrane and separate based on a material’s electrochemical properties, this tunability allows us to target a vast array of different operations and separation applications across industrial fields,” says Smith. Efficient access to materials like lithium, cobalt, and copper — and precious metals like platinum, gold, silver, palladium, and rare-earth elements — is key to unlocking innovation in business and sustainability as the world moves toward electrification and away from fossil fuels.“This is an era when new materials are critical,” says Professor Jeffrey Grossman, co-founder and chief scientist of SiTration and the Morton and Claire Goulder and Family Professor in Environmental Systems at DMSE. “For so many technologies, they’re both the bottleneck and the opportunity, offering tremendous potential for non-incremental advances. And the role they’re having in commercialization and in entrepreneurship cannot be overstated.”SiTration’s commercial frontierSmith became interested in separation technology in 2013 as a PhD student in Grossman’s DMSE research group, which has focused on the design of new membrane materials for a range of applications. The two shared a curiosity about separation of critical materials and a hunger to advance the technology. After years of study under Grossman’s mentorship, and with support from several MIT incubators and foundations including the Abdul Latif Jameel Water and Food Systems Lab’s Solutions Program, the Deshpande Center for Technological Innovation, the Kavanaugh Fellowship, MIT Sandbox, and Venture Mentoring Service, Smith was ready to officially form SiTration in 2020. Grossman has a seat on the board and plays an active role as a strategic and technical advisor. Grossman is involved in several MIT spinoffs and embraces the different imperatives of research versus commercialization. “At SiTration, we’re driving this technology to work at scale. There’s something super exciting about that goal,” he says. “The challenges that come with scaling are very different than the challenges that come in a university lab.” At the same time, although not every research breakthrough becomes a commercial product, open-ended, curiosity-driven knowledge pursuit holds its own crucial value, he adds.It has been rewarding for Grossman to see his technically gifted student and colleague develop a host of other skills the role of CEO demands. Getting out to the market and talking about the technology with potential partners, putting together a dynamic team, discovering the challenges facing industry, drumming up support, early on — those became the most pressing activities on Smith’s agenda. “What’s most fun to me about being a CEO of an early-stage startup is that there are 100 different factors, most people-oriented, that you have to navigate every day. Each stakeholder has different motivations and objectives. And you basically try to fit that all together, to create value for our partners and customers, the company, and for society,” says Smith. “You start with just an idea, and you have to keep leveraging that to form a more and more tangible product, to multiply and progress commercial relationships, and do it all at an ever-expanding scale.” MIT DNA runs deep in the nine-person company, with DMSE grad and former Grossman student Jatin Patil as director of product; Ahmed Helal, from MIT’s Department of Mechanical Engineering, as vice president of research and development; Daniel Bregante, from the Department of Chemistry, as VP of technology; and Sarah Melvin, from the departments of Physics and Political Science, as VP of strategy and operations. Melvin is the first hire devoted to business development. Smith plans to continue expanding the team following the closing of the company’s seed round.  Strategic alliancesBeing a good communicator was important when it came to securing funding, Smith says. SiTration received $2.35 million in pre-seed funding in 2022 led by Azolla Ventures, which reserves its $239 million in investment capital for startups that would not otherwise easily obtain funding. “We invest only in solution areas that can achieve gigaton-scale climate impact by 2050,” says Matthew Nordan, a general partner at Azolla and now SiTration board member. The MIT-affiliated E14 Fund also contributed to the pre-seed round; Azolla and E14 both participated in the recent seed funding round. “Brendan demonstrated an extraordinary ability to go from being a thoughtful scientist to a business leader and thinker who has punched way above his weight in engaging with customers and recruiting a well-balanced team and navigating tricky markets,” says Nordan. One of SiTration’s first partnerships is with Rio Tinto, one of the largest mining companies in the world. As SiTration evaluated various uses cases in its early days, identifying critical materials as its target market, Rio Tinto was looking for partners to recover valuable metals such as cobalt and copper from the wastewater generated at mines. These metals were typically trapped in the water, creating harmful waste and resulting in lost revenue. “We thought this was a great innovation challenge and posted it on our website to scout for companies to partner with who can help us solve this water challenge,” said Nick Gurieff, principal advisor for mine closure, in an interview with MIT’s Industrial Liaison Program in 2023. At SiTration, mining was not yet a market focus, but Smith couldn’t help noticing that Rio Tinto’s needs were in alignment with what his young company offered. SiTration submitted its proposal in August 2022. Gurieff said SiTration’s tunable membrane set it apart. The companies formed a business partnership in June 2023, with SiTration adjusting its membrane to handle mine wastewater and incorporating Rio Tinto feedback to refine the technology. After running tests with water from mine sites, SiTration will begin building a small-scale critical-materials recovery unit, followed by larger-scale systems processing up to 100 cubic meters of water an hour.SiTration’s focused technology development with Rio Tinto puts it in a good position for future market growth, Smith says. “Every ounce of effort and resource we put into developing our product is geared towards creating real-world value. Having an industry-leading partner constantly validating our progress is a tremendous advantage.”It’s a long time from the days when Smith began tinkering with tiny holes in silicon in Grossman’s DMSE lab. Now, they work together as business partners who are scaling up technology to meet a global need. Their joint passion for applying materials innovation to tough problems has served them well. “Materials science and engineering is an engine for a lot of the innovation that is happening today,” Grossman says. “When you look at all of the challenges we face to make the transition to a more sustainable planet, you realize how many of these are materials challenges.” More

Lithium-ion batteries have had a poor recycling record for years, however a new report shows lithium-ion battery recycling is advancing much more than we think. Lithium-ion batteries have become crucial to our daily lives, powering electric cars, smartphones, laptops and other electronic devices and machinery. While the production of lithium-ion batteries is set to explode […] More

The winners of this year’s MADMEC competition identified a class of materials that could offer a more efficient way to keep greenhouses cool.

After Covid-19 put the materials science competition on pause for two years, on Tuesday SmartClime, a team made up of three MIT graduate students, took home the first place, $10,000 prize.

The team showed that a type of material that changes color in response to an electric voltage could reduce energy usage and save money if coated onto the panes of glass in greenhouses.

“This project came out of our love of gardening,” said SmartClime team member and PhD candidate Isabella Caruso in the winning presentation. “Greenhouses let you grow things year-round, even in New England, but even greenhouse pros need to use heating furnaces in the winter and ventilation in the summer. All of that can be very labor- and energy-intensive.”

Current options to keep greenhouses cool include traditional air conditioning units, venting and fans, and simple cloth. To develop a better solution, the team looked through scientific papers to find materials with the right climate control properties.

Two classes of materials that looked promising were thermochromic coatings, which change color based on temperature, and electrochromic solutions, which change color based on electric voltage.

Creating both the thermochromic and electrochromic solutions required the team to assemble nanoparticles and spin-coat them onto glass substrates. In lab tests, the electrochromic material performed well, turning a deep bluish hue to reduce the heat coming into the greenhouse while also letting in enough light for plants. Specifically, the electrochromic cell kept its test box about 1 to 3 degrees Celsius cooler than the test box coated in regular glass.

The team estimated that greenhouse owners could make back the added costs of the electrochromic paneling through savings on other climate-control measures. Additional benefits of using the material include reducing heat-related crop losses, increasing crop yields, and reducing water requirements.

Hosted by MIT’s Department of Materials Science and Engineering (DMSE), the competition was the culmination of team projects that began last spring and included a series of design challenges throughout the summer. Each team received guidance, access to equipment and labs, and up to $1,000 in funding to build and test their prototypes.

“It’s great to be back and to have everyone here in person,” Mike Tarkanian, a senior lecturer in DMSE and coordinator of MADMEC, said at the event. “I’ve enjoyed getting back to normal, doing the design challenges over the summer and celebrating with everyone here today.”

The second-place prize was split between YarnZ, which identified a nanofiber yarn that is more sustainable than traditional textile fibers, and WasteAway, which has developed a waste bin monitoring device that can identify the types of items thrown into trash and recycling bins and flag misplaced items.

YarnZ (which stands for Yarns Are Really NanofiberZ), developed a nanofiber yarn that is more degradable than traditional microfiber yarns without sacrificing on performance.

A large chunk of the waste and emissions in the clothing industry come from polyester, a slow-degrading polymer that requires an energy-intensive melt spinning process before it’s spun into the fibers of our clothes.

“The biggest thing I want to impress upon you today is that the textile industry is a major greenhouse gas-producing entity and also produces a huge amount of waste,” YarnZ member and PhD candidate Natalie Mamrol said in the presentation.

To replace polyester, the team developed a continuous process in which a type of nanofiber film collects in a water bath before being twisted into yarn. In subsequent tests, the nanofiber-based yarn degraded more quicky than traditional microfibers and showed comparable durability. YarnZ believes this early data should encourage others to explore nanofibers as a viable replacement in the clothing industry and to invest in scaling the approach for industrial settings.

WasteAway’s system includes a camera that sits on top of trash bins and uses artificial intelligence to recognize items that people throw away.

Of the 300 million tons of waste generated in the U.S. each year, more than half ends up in landfills. A lot of that waste could have been composted or recycled but was misplaced during disposal.

“When someone throws something into the bin, our sensor detects the motion and captures an image,” explains WasteAway’s Melissa Stok, an undergraduate at MIT. “Those images are then processed by our machine-learning algorithm to find contamination.”

Each device costs less than $30, and the team says that cost could go down as parts are bought at larger scales. The insights gleaned from the device could help waste management officials identify contaminated trash piles as well as inform education efforts by revealing common mistakes people make.

Overall, Tarkanian believes the competition was a success not only because of the final results, but because of the experience the students got throughout the MADMEC program, which included several smaller, hands-on competitions involving laser cutters, 3-D printers, soldering irons, and other equipment many students said they had never used before.

“They end up getting into the lab through these design challenges, which have them compete in various engineering tasks,” Tarkanian says. “It helps them get comfortable designing and prototyping, and they often end up using those tools in their research later.” More

April 22 marks the arrival of Earth Day, which provides all of us with a good reason to think of ways to live more sustainably. For more than 20 years, the MIT Working Green Committee has helped community members do just that by encouraging the reuse and recycling of possessions.

Made up entirely of volunteers, the committee has played an important role in promoting more sustainable operations at MIT and raising awareness of the importance of conservation.

“We try to provide a place for people to learn how to live and work in a more environmentally friendly way,” says committee co-chair Rebecca Fowler, a senior administrative assistant in MIT’s Office of Sustainability.

The committee hosts regular Choose to Reuse events to give MIT’s community members a chance to donate unwanted items — or find free things that just might become prized possessions. It also provides resources to help host more sustainable events, make more sustainable purchasing decisions, and learn more about recycling.

“The recycling industry is very frustrating, so people are always asking what to do,” Fowler says. “They feel like they make the wrong decisions and just want to know how to do it. We get a lot of questions, and we’re always there to help find answers.”

Committee members say they’ve realized devoting a little time each month to things like recycling education, and hosting events can make a big difference in reducing waste. In last month’s Choose to Reuse event, more than 100 people dropped off thousands of items including clothing, housewares, and office supplies. MIT’s always-active Reuse email lists, which the committee encourages community members to join, are another great way to pass gently used items to others who can give them new life.

“The goal is to keep things out of landfills, and the Choose to Reuse event shows you immediate results,” says committee co-chair Gianna Hernandez-Figueroa, who is the assistant to the director at the MIT AgeLab. “It’s inspiring because people are excited to put things in the hands of someone who is going to repurpose it. It’s a circular event that’s really beautiful.”

Choose to Reuse events are typically on the third Thursday of every other month, although the next one — the last for the spring semester — is on Monday, April 24.

The committee is one of the only groups on campus run by support staff, whose responsibilities involve clerical duties, data processing, and library and accounting functions, among other things. It is a subcommittee of the Working Group for Support Staff.

The committee began as the Working Group on Recycling in 2000 at a time when MIT’s recycling rate was around 11 percent. By 2006, MIT had reached a 40 percent recycling rate and received a Go Green Award from the City of Cambridge. That year the committee earned an MIT Excellence Awards for its work.

Around 2011, the group started hosting Choose to Reuse events, which became an instant success.

“I really believe in the gift economy, specifically in academic settings where you have a lot of international students,” Hernandez-Figueroa says. “Plus, Boston is an expensive city!”

For a long time, the group was run by Ruth Davis, who served as MIT’s manager for recycling and materials management and retired last year. Since Davis left, others have stepped up.

“A lot of the volunteers have been around since the first Choose to Reuse event 13 years ago,” Fowler says, adding that the committee is always looking for more volunteers. “They’re all very committed to the event and to the cause.”

The organization is also a way for support staff to gain new skills. Fowler credits her experience working on the committee with improving her project management and website design abilities.

“We really emphasize capacity building,” Fowler says. “If there’s a skill a volunteer would like to develop, we can explore ways to do that through the committee. That’s something I’d like to continue: finding people’s strengths and helping them build their careers.”

Overall, Fowler says the committee aligns with MIT’s commitment to make an impact.

The group’s long history “shows a commitment to environmentalism and sustainability and a yearning to do more beyond what is in your job responsibilities,” she says. “It really shows the commitment to volunteerism of MIT’s staff members.” More

Australia’s peak recycling body has called for a national battery recycling scheme to tackle the growing problem seriously and prevent batteries from exploding in recycling facilities. The Australian Council of Recycling (ACOR) has urged the national and state governments to take immediate action and establish a national product stewardship and recycling scheme for handheld batteries. […] More