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    MIT students combat climate anxiety through extracurricular teams

    Climate anxiety affects nearly half of young people aged 16-25. Students like second-year Rachel Mohammed find hope and inspiration through her involvement in innovative climate solutions, working alongside peers who share her determination. “I’ve met so many people at MIT who are dedicated to finding climate solutions in ways that I had never imagined, dreamed of, or heard of. That is what keeps me going, and I’m doing my part,” she says.Hydrogen-fueled enginesHydrogen offers the potential for zero or near-zero emissions, with the ability to reduce greenhouse gases and pollution by 29 percent. However, the hydrogen industry faces many challenges related to storage solutions and costs.Mohammed leads the hydrogen team on MIT’s Electric Vehicle Team (EVT), which is dedicated to harnessing hydrogen power to build a cleaner, more sustainable future. EVT is one of several student-led build teams at the Edgerton Center focused on innovative climate solutions. Since its founding in 1992, the Edgerton Center has been a hub for MIT students to bring their ideas to life.Hydrogen is mostly used in large vehicles like trucks and planes because it requires a lot of storage space. EVT is building their second iteration of a motorcycle based on what Mohammed calls a “goofy hypothesis” that you can use hydrogen to power a small vehicle. The team employs a hydrogen fuel cell system, which generates electricity by combining hydrogen with oxygen. However, the technology faces challenges, particularly in storage, which EVT is tackling with innovative designs for smaller vehicles.Presenting at the 2024 World Hydrogen Summit reaffirmed Mohammed’s confidence in this project. “I often encounter skepticism, with people saying it’s not practical. Seeing others actively working on similar initiatives made me realize that we can do it too,” Mohammed says.The team’s first successful track test last October allowed them to evaluate the real-world performance of their hydrogen-powered motorcycle, marking a crucial step in proving the feasibility and efficiency of their design.MIT’s Sustainable Engine Team (SET), founded by junior Charles Yong, uses the combustion method to generate energy with hydrogen. This is a promising technology route for high-power-density applications, like aviation, but Yong believes it hasn’t received enough attention. Yong explains, “In the hydrogen power industry, startups choose fuel cell routes instead of combustion because gas turbine industry giants are 50 years ahead. However, these giants are moving very slowly toward hydrogen due to its not-yet-fully-developed infrastructure. Working under the Edgerton Center allows us to take risks and explore advanced tech directions to demonstrate that hydrogen combustion can be readily available.”Both EVT and SET are publishing their research and providing detailed instructions for anyone interested in replicating their results.Running on sunshineThe Solar Electric Vehicle Team powers a car built from scratch with 100 percent solar energy.The team’s single-occupancy car Nimbus won the American Solar Challenge two years in a row. This year, the team pushed boundaries further with Gemini, a multiple-occupancy vehicle that challenges conventional perceptions of solar-powered cars.Senior Andre Greene explains, “the challenge comes from minimizing how much energy you waste because you work with such little energy. It’s like the equivalent power of a toaster.”Gemini looks more like a regular car and less like a “spaceship,” as NBC’s 1st Look affectionately called Nimbus. “It more resembles what a fully solar-powered car could look like versus the single-seaters. You don’t see a lot of single-seater cars on the market, so it’s opening people’s minds,” says rising junior Tessa Uviedo, team captain.All-electric since 2013The MIT Motorsports team switched to an all-electric powertrain in 2013. Captain Eric Zhou takes inspiration from China, the world’s largest market for electric vehicles. “In China, there is a large government push towards electric, but there are also five or six big companies almost as large as Tesla size, building out these electric vehicles. The competition drives the majority of vehicles in China to become electric.”The team is also switching to four-wheel drive and regenerative braking next year, which reduces the amount of energy needed to run. “This is more efficient and better for power consumption because the torque from the motors is applied straight to the tires. It’s more efficient than having a rear motor that must transfer torque to both rear tires. Also, you’re taking advantage of all four tires in terms of producing grip, while you can only rely on the back tires in a rear-wheel-drive car,” Zhou says.Zhou adds that Motorsports wants to help prepare students for the electric vehicle industry. “A large majority of upperclassmen on the team have worked, or are working, at Tesla or Rivian.”Former Motorsports powertrain lead Levi Gershon ’23, SM ’24 recently founded CRABI Robotics — a fully autonomous marine robotic system designed to conduct in-transit cleaning of marine vessels by removing biofouling, increasing vessels’ fuel efficiency.An Indigenous approach to sustainable rocketsFirst Nations Launch, the all-Indigenous student rocket team, recently won the Grand Prize in the 2024 NASA First Nations Launch High-Power Rocket Competition. Using Indigenous methodologies, this team considers the environment in the materials and methods they employ.“The environmental impact is always something that we consider when we’re making design decisions and operational decisions. We’ve thought about things like biodegradable composites and parachutes,” says rising junior Hailey Polson, team captain. “Aerospace has been a very wasteful industry in the past. There are huge leaps and bounds being made with forward progress in regard to reusable rockets, which is definitely lowering the environmental impact.”Collecting climate change data with autonomous boatsArcturus, the recent first-place winner in design at the 16th Annual RoboBoat Competition, is developing autonomous surface vehicles that can greatly aid in marine research. “The ocean is one of our greatest resources to combat climate change; thus, the accessibility of data will help scientists understand climate patterns and predict future trends. This can help people learn how to prepare for potential disasters and how to reduce each of our carbon footprints,” says Arcturus captain and rising junior Amy Shi.“We are hoping to expand our outreach efforts to incorporate more sustainability-related programs. This can include more interactions with local students to introduce them to how engineering can make a positive impact in the climate space or other similar programs,” Shi says.Shi emphasizes that hope is a crucial force in the battle against climate change. “There are great steps being taken every day to combat this seemingly impending doom we call the climate crisis. It’s important to not give up hope, because this hope is what’s driving the leaps and bounds of innovation happening in the climate community. The mainstream media mostly reports on the negatives, but the truth is there is a lot of positive climate news every day. Being more intentional about where you seek your climate news can really help subside this feeling of doom about our planet.” More

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    Study: EV charging stations boost spending at nearby businesses

    Charging stations for electric vehicles are essential for cleaning up the transportation sector. A new study by MIT researchers suggests they’re good for business, too.The study found that, in California, opening a charging station boosted annual spending at each nearby business by an average of about $1,500 in 2019 and about $400 between January 2021 and June 2023. The spending bump amounts to thousands of extra dollars annually for nearby businesses, with the increase particularly pronounced for businesses in underresourced areas.The study’s authors hope the research paints a more holistic picture of the benefits of EV charging stations, beyond environmental factors.“These increases are equal to a significant chunk of the cost of installing an EV charger, and I hope this study sheds light on these economic benefits,” says lead author Yunhan Zheng MCP ’21, SM ’21, PhD ’24, a postdoc at the Singapore-MIT Alliance for Research and Technology (SMART). “The findings could also diversify the income stream for charger providers and site hosts, and lead to more informed business models for EV charging stations.”Zheng’s co-authors on the paper, which was published today in Nature Communications, are David Keith, a senior lecturer at the MIT Sloan School of Management; Jinhua Zhao, an MIT professor of cities and transportation; and alumni Shenhao Wang MCP ’17, SM ’17, PhD ’20 and Mi Diao MCP ’06, PhD ’10.Understanding the EV effectIncreasing the number of electric vehicle charging stations is seen as a key prerequisite for the transition to a cleaner, electrified transportation sector. As such, the 2021 U.S. Infrastructure Investment and Jobs Act committed $7.5 billion to build a national network of public electric vehicle chargers across the U.S.But a large amount of private investment will also be needed to make charging stations ubiquitous.“The U.S. is investing a lot in EV chargers and really encouraging EV adoption, but many EV charging providers can’t make enough money at this stage, and getting to profitability is a major challenge,” Zheng says.EV advocates have long argued that the presence of charging stations brings economic benefits to surrounding communities, but Zheng says previous studies on their impact relied on surveys or were small-scale. Her team of collaborators wanted to make advocates’ claims more empirical.For their study, the researchers collected data from over 4,000 charging stations in California and 140,000 businesses, relying on anonymized credit and debit card transactions to measure changes in consumer spending. The researchers used data from 2019 through June of 2023, skipping the year 2020 to minimize the impact of the pandemic.To judge whether charging stations caused customer spending increases, the researchers compared data from businesses within 500 meters of new charging stations before and after their installation. They also analyzed transactions from similar businesses in the same time frame that weren’t near charging stations.Supercharging nearby businessesThe researchers found that installing a charging station boosted annual spending at nearby establishments by an average of 1.4 percent in 2019 and 0.8 percent from January 2021 to June 2023.While that might sound like a small amount per business, it amounts to thousands of dollars in overall consumer spending increases. Specifically, those percentages translate to almost $23,000 in cumulative spending increases in 2019 and about $3,400 per year from 2021 through June 2023.Zheng says the decline in spending increases over the two time periods might be due to a saturation of EV chargers, leading to lower utilization, as well as an overall decrease in spending per business after the Covid-19 pandemic and a reduced number of businesses served by each EV charging station in the second period. Despite this decline, the annual impact of a charging station on all its surrounding businesses would still cover approximately 11.2 percent of the average infrastructure and installation cost of a standard charging station.Through both time frames, the spending increases were highest for businesses within about a football field’s distance from the new stations. They were also significant for businesses in disadvantaged and low-income areas, as designated by California and the Justice40 Initiative.“The positive impacts of EV charging stations on businesses are not constrained solely to some high-income neighborhoods,” Wang says. “It highlights the importance for policymakers to develop EV charging stations in marginalized areas, because they not only foster a cleaner environment, but also serve as a catalyst for enhancing economic vitality.”Zheng believes the findings hold a lesson for charging station developers seeking to improve the profitability of their projects.“The joint gas station and convenience store business model could also be adopted to EV charging stations,” Zheng says. “Traditionally, many gas stations are affiliated with retail store chains, which enables owners to both sell fuel and attract customers to diversify their revenue stream. EV charging providers could consider a similar approach to internalize the positive impact of EV charging stations.”Zheng also says the findings could support the creation of new funding models for charging stations, such as multiple businesses sharing the costs of construction so they can all benefit from the added spending.Those changes could accelerate the creation of charging networks, but Zheng cautions that further research is needed to understand how much the study’s findings can be extrapolated to other areas. She encourages other researchers to study the economic effects of charging stations and hopes future research includes states beyond California and even other countries.“A huge number of studies have focused on retail sales effects from traditional transportation infrastructure, such as rail and subway stations, bus stops, and street configurations,” Zhao says. “This research provides evidence for an important, emerging piece of transportation infrastructure and shows a consistently positive effect on local businesses, paving the way for future research in this area.”The research was supported, in part, by the Singapore-MIT Alliance for Research and Technology (SMART) and the Singapore National Research Foundation. Diao was partially supported by the Natural Science Foundation of Shanghai and the Fundamental Research Funds for the Central Universities of China. More

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    Study of disordered rock salts leads to battery breakthrough

    For the past decade, disordered rock salt has been studied as a potential breakthrough cathode material for use in lithium-ion batteries and a key to creating low-cost, high-energy storage for everything from cell phones to electric vehicles to renewable energy storage.A new MIT study is making sure the material fulfills that promise.Led by Ju Li, the Tokyo Electric Power Company Professor in Nuclear Engineering and professor of materials science and engineering, a team of researchers describe a new class of partially disordered rock salt cathode, integrated with polyanions — dubbed disordered rock salt-polyanionic spinel, or DRXPS — that delivers high energy density at high voltages with significantly improved cycling stability.“There is typically a trade-off in cathode materials between energy density and cycling stability … and with this work we aim to push the envelope by designing new cathode chemistries,” says Yimeng Huang, a postdoc in the Department of Nuclear Science and Engineering and first author of a paper describing the work published today in Nature Energy. “(This) material family has high energy density and good cycling stability because it integrates two major types of cathode materials, rock salt and polyanionic olivine, so it has the benefits of both.”Importantly, Li adds, the new material family is primarily composed of manganese, an earth-abundant element that is significantly less expensive than elements like nickel and cobalt, which are typically used in cathodes today.“Manganese is at least five times less expensive than nickel, and about 30 times less expensive than cobalt,” Li says. “Manganese is also the one of the keys to achieving higher energy densities, so having that material be much more earth-abundant is a tremendous advantage.”A possible path to renewable energy infrastructureThat advantage will be particularly critical, Li and his co-authors wrote, as the world looks to build the renewable energy infrastructure needed for a low- or no-carbon future.Batteries are a particularly important part of that picture, not only for their potential to decarbonize transportation with electric cars, buses, and trucks, but also because they will be essential to addressing the intermittency issues of wind and solar power by storing excess energy, then feeding it back into the grid at night or on calm days, when renewable generation drops.Given the high cost and relative rarity of materials like cobalt and nickel, they wrote, efforts to rapidly scale up electric storage capacity would likely lead to extreme cost spikes and potentially significant materials shortages.“If we want to have true electrification of energy generation, transportation, and more, we need earth-abundant batteries to store intermittent photovoltaic and wind power,” Li says. “I think this is one of the steps toward that dream.”That sentiment was shared by Gerbrand Ceder, the Samsung Distinguished Chair in Nanoscience and Nanotechnology Research and a professor of materials science and engineering at the University of California at Berkeley.“Lithium-ion batteries are a critical part of the clean energy transition,” Ceder says. “Their continued growth and price decrease depends on the development of inexpensive, high-performance cathode materials made from earth-abundant materials, as presented in this work.”Overcoming obstacles in existing materialsThe new study addresses one of the major challenges facing disordered rock salt cathodes — oxygen mobility.While the materials have long been recognized for offering very high capacity — as much as 350 milliampere-hour per gram — as compared to traditional cathode materials, which typically have capacities of between 190 and 200 milliampere-hour per gram, it is not very stable.The high capacity is contributed partially by oxygen redox, which is activated when the cathode is charged to high voltages. But when that happens, oxygen becomes mobile, leading to reactions with the electrolyte and degradation of the material, eventually leaving it effectively useless after prolonged cycling.To overcome those challenges, Huang added another element — phosphorus — that essentially acts like a glue, holding the oxygen in place to mitigate degradation.“The main innovation here, and the theory behind the design, is that Yimeng added just the right amount of phosphorus, formed so-called polyanions with its neighboring oxygen atoms, into a cation-deficient rock salt structure that can pin them down,” Li explains. “That allows us to basically stop the percolating oxygen transport due to strong covalent bonding between phosphorus and oxygen … meaning we can both utilize the oxygen-contributed capacity, but also have good stability as well.”That ability to charge batteries to higher voltages, Li says, is crucial because it allows for simpler systems to manage the energy they store.“You can say the quality of the energy is higher,” he says. “The higher the voltage per cell, then the less you need to connect them in series in the battery pack, and the simpler the battery management system.”Pointing the way to future studiesWhile the cathode material described in the study could have a transformative impact on lithium-ion battery technology, there are still several avenues for study going forward.Among the areas for future study, Huang says, are efforts to explore new ways to fabricate the material, particularly for morphology and scalability considerations.“Right now, we are using high-energy ball milling for mechanochemical synthesis, and … the resulting morphology is non-uniform and has small average particle size (about 150 nanometers). This method is also not quite scalable,” he says. “We are trying to achieve a more uniform morphology with larger particle sizes using some alternate synthesis methods, which would allow us to increase the volumetric energy density of the material and may allow us to explore some coating methods … which could further improve the battery performance. The future methods, of course, should be industrially scalable.”In addition, he says, the disordered rock salt material by itself is not a particularly good conductor, so significant amounts of carbon — as much as 20 weight percent of the cathode paste — were added to boost its conductivity. If the team can reduce the carbon content in the electrode without sacrificing performance, there will be higher active material content in a battery, leading to an increased practical energy density.“In this paper, we just used Super P, a typical conductive carbon consisting of nanospheres, but they’re not very efficient,” Huang says. “We are now exploring using carbon nanotubes, which could reduce the carbon content to just 1 or 2 weight percent, which could allow us to dramatically increase the amount of the active cathode material.”Aside from decreasing carbon content, making thick electrodes, he adds, is yet another way to increase the practical energy density of the battery. This is another area of research that the team is working on.“This is only the beginning of DRXPS research, since we only explored a few chemistries within its vast compositional space,” he continues. “We can play around with different ratios of lithium, manganese, phosphorus, and oxygen, and with various combinations of other polyanion-forming elements such as boron, silicon, and sulfur.”With optimized compositions, more scalable synthesis methods, better morphology that allows for uniform coatings, lower carbon content, and thicker electrodes, he says, the DRXPS cathode family is very promising in applications of electric vehicles and grid storage, and possibly even in consumer electronics, where the volumetric energy density is very important.This work was supported with funding from the Honda Research Institute USA Inc. and the Molecular Foundry at Lawrence Berkeley National Laboratory, and used resources of the National Synchrotron Light Source II at Brookhaven National Laboratory and the Advanced Photon Source at Argonne National Laboratory.  More

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    MIT engineers’ new theory could improve the design and operation of wind farms

    The blades of propellers and wind turbines are designed based on aerodynamics principles that were first described mathematically more than a century ago. But engineers have long realized that these formulas don’t work in every situation. To compensate, they have added ad hoc “correction factors” based on empirical observations.Now, for the first time, engineers at MIT have developed a comprehensive, physics-based model that accurately represents the airflow around rotors even under extreme conditions, such as when the blades are operating at high forces and speeds, or are angled in certain directions. The model could improve the way rotors themselves are designed, but also the way wind farms are laid out and operated. The new findings are described today in the journal Nature Communications, in an open-access paper by MIT postdoc Jaime Liew, doctoral student Kirby Heck, and Michael Howland, the Esther and Harold E. Edgerton Assistant Professor of Civil and Environmental Engineering.“We’ve developed a new theory for the aerodynamics of rotors,” Howland says. This theory can be used to determine the forces, flow velocities, and power of a rotor, whether that rotor is extracting energy from the airflow, as in a wind turbine, or applying energy to the flow, as in a ship or airplane propeller. “The theory works in both directions,” he says.Because the new understanding is a fundamental mathematical model, some of its implications could potentially be applied right away. For example, operators of wind farms must constantly adjust a variety of parameters, including the orientation of each turbine as well as its rotation speed and the angle of its blades, in order to maximize power output while maintaining safety margins. The new model can provide a simple, speedy way of optimizing those factors in real time.“This is what we’re so excited about, is that it has immediate and direct potential for impact across the value chain of wind power,” Howland says.Modeling the momentumKnown as momentum theory, the previous model of how rotors interact with their fluid environment — air, water, or otherwise — was initially developed late in the 19th century. With this theory, engineers can start with a given rotor design and configuration, and determine the maximum amount of power that can be derived from that rotor — or, conversely, if it’s a propeller, how much power is needed to generate a given amount of propulsive force.Momentum theory equations “are the first thing you would read about in a wind energy textbook, and are the first thing that I talk about in my classes when I teach about wind power,” Howland says. From that theory, physicist Albert Betz calculated in 1920 the maximum amount of energy that could theoretically be extracted from wind. Known as the Betz limit, this amount is 59.3 percent of the kinetic energy of the incoming wind.But just a few years later, others found that the momentum theory broke down “in a pretty dramatic way” at higher forces that correspond to faster blade rotation speeds or different blade angles, Howland says. It fails to predict not only the amount, but even the direction of changes in thrust force at higher rotation speeds or different blade angles: Whereas the theory said the force should start going down above a certain rotation speed or blade angle, experiments show the opposite — that the force continues to increase. “So, it’s not just quantitatively wrong, it’s qualitatively wrong,” Howland says.The theory also breaks down when there is any misalignment between the rotor and the airflow, which Howland says is “ubiquitous” on wind farms, where turbines are constantly adjusting to changes in wind directions. In fact, in an earlier paper in 2022, Howland and his team found that deliberately misaligning some turbines slightly relative to the incoming airflow within a wind farm significantly improves the overall power output of the wind farm by reducing wake disturbances to the downstream turbines.In the past, when designing the profile of rotor blades, the layout of wind turbines in a farm, or the day-to-day operation of wind turbines, engineers have relied on ad hoc adjustments added to the original mathematical formulas, based on some wind tunnel tests and experience with operating wind farms, but with no theoretical underpinnings.Instead, to arrive at the new model, the team analyzed the interaction of airflow and turbines using detailed computational modeling of the aerodynamics. They found that, for example, the original model had assumed that a drop in air pressure immediately behind the rotor would rapidly return to normal ambient pressure just a short way downstream. But it turns out, Howland says, that as the thrust force keeps increasing, “that assumption is increasingly inaccurate.”And the inaccuracy occurs very close to the point of the Betz limit that theoretically predicts the maximum performance of a turbine — and therefore is just the desired operating regime for the turbines. “So, we have Betz’s prediction of where we should operate turbines, and within 10 percent of that operational set point that we think maximizes power, the theory completely deteriorates and doesn’t work,” Howland says.Through their modeling, the researchers also found a way to compensate for the original formula’s reliance on a one-dimensional modeling that assumed the rotor was always precisely aligned with the airflow. To do so, they used fundamental equations that were developed to predict the lift of three-dimensional wings for aerospace applications.The researchers derived their new model, which they call a unified momentum model, based on theoretical analysis, and then validated it using computational fluid dynamics modeling. In followup work not yet published, they are doing further validation using wind tunnel and field tests.Fundamental understandingOne interesting outcome of the new formula is that it changes the calculation of the Betz limit, showing that it’s possible to extract a bit more power than the original formula predicted. Although it’s not a significant change — on the order of a few percent — “it’s interesting that now we have a new theory, and the Betz limit that’s been the rule of thumb for a hundred years is actually modified because of the new theory,” Howland says. “And that’s immediately useful.” The new model shows how to maximize power from turbines that are misaligned with the airflow, which the Betz limit cannot account for.The aspects related to controlling both individual turbines and arrays of turbines can be implemented without requiring any modifications to existing hardware in place within wind farms. In fact, this has already happened, based on earlier work from Howland and his collaborators two years ago that dealt with the wake interactions between turbines in a wind farm, and was based on the existing, empirically based formulas.“This breakthrough is a natural extension of our previous work on optimizing utility-scale wind farms,” he says, because in doing that analysis, they saw the shortcomings of the existing methods for analyzing the forces at work and predicting power produced by wind turbines. “Existing modeling using empiricism just wasn’t getting the job done,” he says.In a wind farm, individual turbines will sap some of the energy available to neighboring turbines, because of wake effects. Accurate wake modeling is important both for designing the layout of turbines in a wind farm, and also for the operation of that farm, determining moment to moment how to set the angles and speeds of each turbine in the array.Until now, Howland says, even the operators of wind farms, the manufacturers, and the designers of the turbine blades had no way to predict how much the power output of a turbine would be affected by a given change such as its angle to the wind without using empirical corrections. “That’s because there was no theory for it. So, that’s what we worked on here. Our theory can directly tell you, without any empirical corrections, for the first time, how you should actually operate a wind turbine to maximize its power,” he says.Because the fluid flow regimes are similar, the model also applies to propellers, whether for aircraft or ships, and also for hydrokinetic turbines such as tidal or river turbines. Although they didn’t focus on that aspect in this research, “it’s in the theoretical modeling naturally,” he says.The new theory exists in the form of a set of mathematical formulas that a user could incorporate in their own software, or as an open-source software package that can be freely downloaded from GitHub. “It’s an engineering model developed for fast-running tools for rapid prototyping and control and optimization,” Howland says. “The goal of our modeling is to position the field of wind energy research to move more aggressively in the development of the wind capacity and reliability necessary to respond to climate change.”The work was supported by the National Science Foundation and Siemens Gamesa Renewable Energy. More

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    More durable metals for fusion power reactors

    For many decades, nuclear fusion power has been viewed as the ultimate energy source. A fusion power plant could generate carbon-free energy at a scale needed to address climate change. And it could be fueled by deuterium recovered from an essentially endless source — seawater.Decades of work and billions of dollars in research funding have yielded many advances, but challenges remain. To Ju Li, the TEPCO Professor in Nuclear Science and Engineering and a professor of materials science and engineering at MIT, there are still two big challenges. The first is to build a fusion power plant that generates more energy than is put into it; in other words, it produces a net output of power. Researchers worldwide are making progress toward meeting that goal.The second challenge that Li cites sounds straightforward: “How do we get the heat out?” But understanding the problem and finding a solution are both far from obvious.Research in the MIT Energy Initiative (MITEI) includes development and testing of advanced materials that may help address those challenges, as well as many other challenges of the energy transition. MITEI has multiple corporate members that have been supporting MIT’s efforts to advance technologies required to harness fusion energy.The problem: An abundance of helium, a destructive forceKey to a fusion reactor is a superheated plasma — an ionized gas — that’s reacting inside a vacuum vessel. As light atoms in the plasma combine to form heavier ones, they release fast neutrons with high kinetic energy that shoot through the surrounding vacuum vessel into a coolant. During this process, those fast neutrons gradually lose their energy by causing radiation damage and generating heat. The heat that’s transferred to the coolant is eventually used to raise steam that drives an electricity-generating turbine.The problem is finding a material for the vacuum vessel that remains strong enough to keep the reacting plasma and the coolant apart, while allowing the fast neutrons to pass through to the coolant. If one considers only the damage due to neutrons knocking atoms out of position in the metal structure, the vacuum vessel should last a full decade. However, depending on what materials are used in the fabrication of the vacuum vessel, some projections indicate that the vacuum vessel will last only six to 12 months. Why is that? Today’s nuclear fission reactors also generate neutrons, and those reactors last far longer than a year.The difference is that fusion neutrons possess much higher kinetic energy than fission neutrons do, and as they penetrate the vacuum vessel walls, some of them interact with the nuclei of atoms in the structural material, giving off particles that rapidly turn into helium atoms. The result is hundreds of times more helium atoms than are present in a fission reactor. Those helium atoms look for somewhere to land — a place with low “embedding energy,” a measure that indicates how much energy it takes for a helium atom to be absorbed. As Li explains, “The helium atoms like to go to places with low helium embedding energy.” And in the metals used in fusion vacuum vessels, there are places with relatively low helium embedding energy — namely, naturally occurring openings called grain boundaries.Metals are made up of individual grains inside which atoms are lined up in an orderly fashion. Where the grains come together there are gaps where the atoms don’t line up as well. That open space has relatively low helium embedding energy, so the helium atoms congregate there. Worse still, helium atoms have a repellent interaction with other atoms, so the helium atoms basically push open the grain boundary. Over time, the opening grows into a continuous crack, and the vacuum vessel breaks.That congregation of helium atoms explains why the structure fails much sooner than expected based just on the number of helium atoms that are present. Li offers an analogy to illustrate. “Babylon is a city of a million people. But the claim is that 100 bad persons can destroy the whole city — if all those bad persons work at the city hall.” The solution? Give those bad persons other, more attractive places to go, ideally in their own villages.To Li, the problem and possible solution are the same in a fusion reactor. If many helium atoms go to the grain boundary at once, they can destroy the metal wall. The solution? Add a small amount of a material that has a helium embedding energy even lower than that of the grain boundary. And over the past two years, Li and his team have demonstrated — both theoretically and experimentally — that their diversionary tactic works. By adding nanoscale particles of a carefully selected second material to the metal wall, they’ve found they can keep the helium atoms that form from congregating in the structurally vulnerable grain boundaries in the metal.Looking for helium-absorbing compoundsTo test their idea, So Yeon Kim ScD ’23 of the Department of Materials Science and Engineering and Haowei Xu PhD ’23 of the Department of Nuclear Science and Engineering acquired a sample composed of two materials, or “phases,” one with a lower helium embedding energy than the other. They and their collaborators then implanted helium ions into the sample at a temperature similar to that in a fusion reactor and watched as bubbles of helium formed. Transmission electron microscope images confirmed that the helium bubbles occurred predominantly in the phase with the lower helium embedding energy. As Li notes, “All the damage is in that phase — evidence that it protected the phase with the higher embedding energy.”Having confirmed their approach, the researchers were ready to search for helium-absorbing compounds that would work well with iron, which is often the principal metal in vacuum vessel walls. “But calculating helium embedding energy for all sorts of different materials would be computationally demanding and expensive,” says Kim. “We wanted to find a metric that is easy to compute and a reliable indicator of helium embedding energy.”They found such a metric: the “atomic-scale free volume,” which is basically the maximum size of the internal vacant space available for helium atoms to potentially settle. “This is just the radius of the largest sphere that can fit into a given crystal structure,” explains Kim. “It is a simple calculation.” Examination of a series of possible helium-absorbing ceramic materials confirmed that atomic free volume correlates well with helium embedding energy. Moreover, many of the ceramics they investigated have higher free volume, thus lower embedding energy, than the grain boundaries do.However, in order to identify options for the nuclear fusion application, the screening needed to include some other factors. For example, in addition to the atomic free volume, a good second phase must be mechanically robust (able to sustain a load); it must not get very radioactive with neutron exposure; and it must be compatible — but not too cozy — with the surrounding metal, so it disperses well but does not dissolve into the metal. “We want to disperse the ceramic phase uniformly in the bulk metal to ensure that all grain boundary regions are close to the dispersed ceramic phase so it can provide protection to those regions,” says Li. “The two phases need to coexist, so the ceramic won’t either clump together or totally dissolve in the iron.”Using their analytical tools, Kim and Xu examined about 50,000 compounds and identified 750 potential candidates. Of those, a good option for inclusion in a vacuum vessel wall made mainly of iron was iron silicate.Experimental testingThe researchers were ready to examine samples in the lab. To make the composite material for proof-of-concept demonstrations, Kim and collaborators dispersed nanoscale particles of iron silicate into iron and implanted helium into that composite material. She took X-ray diffraction (XRD) images before and after implanting the helium and also computed the XRD patterns. The ratio between the implanted helium and the dispersed iron silicate was carefully controlled to allow a direct comparison between the experimental and computed XRD patterns. The measured XRD intensity changed with the helium implantation exactly as the calculations had predicted. “That agreement confirms that atomic helium is being stored within the bulk lattice of the iron silicate,” says Kim.To follow up, Kim directly counted the number of helium bubbles in the composite. In iron samples without the iron silicate added, grain boundaries were flanked by many helium bubbles. In contrast, in the iron samples with the iron silicate ceramic phase added, helium bubbles were spread throughout the material, with many fewer occurring along the grain boundaries. Thus, the iron silicate had provided sites with low helium-embedding energy that lured the helium atoms away from the grain boundaries, protecting those vulnerable openings and preventing cracks from opening up and causing the vacuum vessel to fail catastrophically.The researchers conclude that adding just 1 percent (by volume) of iron silicate to the iron walls of the vacuum vessel will cut the number of helium bubbles in half and also reduce their diameter by 20 percent — “and having a lot of small bubbles is OK if they’re not in the grain boundaries,” explains Li.Next stepsThus far, Li and his team have gone from computational studies of the problem and a possible solution to experimental demonstrations that confirm their approach. And they’re well on their way to commercial fabrication of components. “We’ve made powders that are compatible with existing commercial 3D printers and are preloaded with helium-absorbing ceramics,” says Li. The helium-absorbing nanoparticles are well dispersed and should provide sufficient helium uptake to protect the vulnerable grain boundaries in the structural metals of the vessel walls. While Li confirms that there’s more scientific and engineering work to be done, he, along with Alexander O’Brien PhD ’23 of the Department of Nuclear Science and Engineering and Kang Pyo So, a former postdoc in the same department, have already developed a startup company that’s ready to 3D print structural materials that can meet all the challenges faced by the vacuum vessel inside a fusion reactor.This research was supported by Eni S.p.A. through the MIT Energy Initiative. Additional support was provided by a Kwajeong Scholarship; the U.S. Department of Energy (DOE) Laboratory Directed Research and Development program at Idaho National Laboratory; U.S. DOE Lawrence Livermore National Laboratory; and Creative Materials Discovery Program through the National Research Foundation of Korea. More

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    MIT engineers design tiny batteries for powering cell-sized robots

    A tiny battery designed by MIT engineers could enable the deployment of cell-sized, autonomous robots for drug delivery within in the human body, as well as other applications such as locating leaks in gas pipelines.The new battery, which is 0.1 millimeters long and 0.002 millimeters thick — roughly the thickness of a human hair — can capture oxygen from air and use it to oxidize zinc, creating a current of up to 1 volt. That is enough to power a small circuit, sensor, or actuator, the researchers showed.“We think this is going to be very enabling for robotics,” says Michael Strano, the Carbon P. Dubbs Professor of Chemical Engineering at MIT and the senior author of the study. “We’re building robotic functions onto the battery and starting to put these components together into devices.”Ge Zhang PhD ’22 and Sungyun Yang, an MIT graduate student, are the lead author of the paper, which appears in Science Robotics.Powered by batteriesFor several years, Strano’s lab has been working on tiny robots that can sense and respond to stimuli in their environment. One of the major challenges in developing such tiny robots is making sure that they have enough power.Other researchers have shown that they can power microscale devices using solar power, but the limitation to that approach is that the robots must have a laser or another light source pointed at them at all times. Such devices are known as “marionettes” because they are controlled by an external power source. Putting a power source such as a battery inside these tiny devices could free them to roam much farther.“The marionette systems don’t really need a battery because they’re getting all the energy they need from outside,” Strano says. “But if you want a small robot to be able to get into spaces that you couldn’t access otherwise, it needs to have a greater level of autonomy. A battery is essential for something that’s not going to be tethered to the outside world.”To create robots that could become more autonomous, Strano’s lab decided to use a type of battery known as a zinc-air battery. These batteries, which have a longer lifespan than many other types of batteries due to their high energy density, are often used in hearing aids.The battery that they designed consists of a zinc electrode connected to a platinum electrode, embedded into a strip of a polymer called SU-8, which is commonly used for microelectronics. When these electrodes interact with oxygen molecules from the air, the zinc becomes oxidized and releases electrons that flow to the platinum electrode, creating a current.In this study, the researchers showed that this battery could provide enough energy to power an actuator — in this case, a robotic arm that can be raised and lowered. The battery could also power a memristor, an electrical component that can store memories of events by changing its electrical resistance, and a clock circuit, which allows robotic devices to keep track of time.The battery also provides enough power to run two different types of sensors that change their electrical resistance when they encounter chemicals in the environment. One of the sensors is made from atomically thin molybdenum disulfide and the other from carbon nanotubes.“We’re making the basic building blocks in order to build up functions at the cellular level,” Strano says.Robotic swarmsIn this study, the researchers used a wire to connect their battery to an external device, but in future work they plan to build robots in which the battery is incorporated into a device.“This is going to form the core of a lot of our robotic efforts,” Strano says. “You can build a robot around an energy source, sort of like you can build an electric car around the battery.”One of those efforts revolves around designing tiny robots that could be injected into the human body, where they could seek out a target site and then release a drug such as insulin. For use in the human body, the researchers envision that the devices would be made of biocompatible materials that would break apart once they were no longer needed.The researchers are also working on increasing the voltage of the battery, which may enable additional applications.The research was funded by the U.S. Army Research Office, the U.S. Department of Energy, the National Science Foundation, and a MathWorks Engineering Fellowship. More

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    D-Lab off-grid brooder saves chicks and money using locally manufactured thermal batteries

    MIT D-Lab students and instructors are improving the efficacy and economics of a brooder technology for newborn chicks that utilizes a practical, local resource: beeswax.Developed through participatory design with agricultural partners in Cameroon, their Off-Grid Brooder is a solution aimed at improving the profitability of the African nation’s small- and medium-scale poultry farms. Since it is common for smallholders in places with poor electricity supply to tend open fires overnight to keep chicks warm, the invention might also let farmers catch up on their sleep.“The target is eight hours. If farmers can sustain the warmth for eight hours, then they get to sleep,” says D-Lab instructor and former student Ahmad (Zak) Zakka SM ’23, who traveled to Cameroon in May to work on implementing brooder improvements tested at the D-Lab, along with D-Lab students, collaborators from African Solar Generation (ASG), and the African Diaspora Council of Switzerland – Branch Cameroon (CDAS–BC).Poultry farming is heavily concentrated in lower- and middle-income countries, where it is an important component of rural economies and provides an inexpensive source of protein for residents. Raising chickens is fraught with economic risk, however, largely because it is hard for small-scale farmers to keep newborn chicks warm enough to survive (33 to 35 degrees Celsius, or 91 to 95 degrees Fahrenheit, depending on age). After the cost of feed, firewood used to heat the chick space is the biggest input for rural poultry farmers.According to D-Lab researchers, an average smallholder in Cameroon using traditional brooding methods spends $17 per month on firewood, achieves a 10 percent profit margin, and experiences chick mortality that can be as high as a total loss due to overheating or insufficient heat. The Off-Grid Brooder is designed to replace open fires with inexpensive, renewable, and locally available beeswax — a phase-change material used to make thermal batteries.ASG initially developed a brooder technology, the SolarBox, that used photovoltaic panels and electric batteries to power incandescent bulbs. While this provided effective heating, it was prohibitively expensive and difficult to maintain. In 2020, students from the D-Lab Energy class took on the challenge of reducing the cost and complexity of the SolarBox heating system to make it more accessible to small farmers in Cameroon. Through participatory design — a collaborative approach that involves all stakeholders in early stages of the design process — the team discovered a unique solution. Beeswax stored in a used glass container (such as a mayonnaise jar) is melted using a double boiler over a fire and then installed inside insulated brooder boxes alongside the chicks. As the beeswax cools and solidifies, it releases heat for several hours, keeping the brooder within the temperature range that chicks need to grow and develop. Farmers can then recharge the cooled wax batteries and repeat the process again and again. “The big challenge was how to get heat,” says D-Lab Research Scientist Daniel Sweeney, who, with Zakka, co-teaches two D-Lab classes, 2.651/EC.711 (Introduction to Energy in Global Development), and 2.652/EC.712 (Applications of Energy in Global Development). “Decoupling the heat supplied by biomass (wood) from the heat the chicks need at night in the brooder, that’s the core of the innovation here.”D-Lab instructors, researchers, and students have tested and tuned the system with partners in Cameroon. A research box constructed during a D-Lab trip to Cameroon in January 2023 worked well, but was “very expensive to build,” Zakka says. “The research box was a proof of concept in the field. The next step was to figure out how to make it affordable,” he continues.A new brooder box, made entirely of locally sourced recycled materials at 5 percent of the cost of the research prototype, was developed during D-Lab’s January 2024 trip to Cameroon. Designed and produced in collaboration with CDAS-BC, the new brooder is much more affordable, but its functionality still needs fine-tuning. From late-May through mid-June, the D-Lab team, led by Zakka, worked with Cameroonian collaborators to improve the system again. This time, they assessed the efficacy of using straw, a readily available and low-cost material, arranged in panels to insulate the brooder box.The MIT team was hosted by CDAS-BC, including its president and founder Carole Erlemann Mengue and secretary and treasurer Kathrin Witschi, who operate an organic poultry farm in Afambassi, Cameroon. “The students will experiment with the box and try to improve the insulation of the box without neglecting that the chicks will need ventilation,” they say.In addition, the CDAS-BC partners say that they hoped to explore increasing the number of chicks that the box can keep warm. “If the system could heat 500 to 1,000 chicks at a time,” they note, “it would help farmers save firewood, to sleep through the night, and to minimize the risk of fire in the building and the risk of stepping on chicks while replacing firewood.” Earlier this spring, Erlemann Mengue and Witschi tested the low-cost Off-Grid Brooder Box, which can hold 30 to 40 chicks in its current design.“They were very interested in partnering with us to evaluate the technology. They are running the tests and doing a lot of technical measurement to track the temperature inside the brooder over time,” says Sweeney, adding that the CDAS-BC partners are amassing datasets that they send to the MIT D-Lab team. Sweeney and Zakka, along with PhD candidate Aly Kombargi, who worked on the research box in Cameroon last year, hope to not only improve the functionality of the Off-Grid Poultry Brooder but also broaden its use beyond Cameroon.“The goal of our trip was to have a working prototype, and the goal since then has been to scale this up,” Kombargi says. “It’s absolutely scalable.”Concurring that “the technology should work across developing countries in small-scale poultry sectors,” Zakka says this spring’s D-Lab trip included workshops for area poultry farmers to teach them about benefits of the Off-Grid Brooder and how to make their own. “I’m excited to see if we can get people excited about pushing this as a business … to see if they would build and sell it to other people in the community,” Zakka says.Adds Sweeney, “This isn’t rocket science. If we have some guidance and some open-source information we could share, I’m pretty sure (farmers) could put them together on their own.”Already, he says, partners identified through MIT’s networks in Zambia and Uganda are building their own brooders based on the D-Lab design.MIT’s Abdul Latif Jameel Water and Food Systems Lab (J-WAFS), which supports research, innovation, and cross-disciplinary collaborations involving water and food systems, awarded the Off-Grid Brooder project a $25,000 research and development grant in 2022. The program is “pleased that the project’s approach was grounded in engagement with MIT students and community collaborators,” says Executive Director Renee Robins. “The participatory design process helped produce innovative prototypes that are already making positive impacts for smallholder poultry farmers.”That process and the very real impact on communities in Cameroon is what draws students to the project and keeps them committed.Sweeney says a recent D-Lab design review for the chick brooder highlighted that the project continued to attract the attention and curiosity of students who participated in earlier stages and still want to be involved.“There’s something about this project. There’s this whole tribe of students that are still active on the broader project,” he says. “There’s something about it.” More

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    Going Dutch on climate

    When MIT senior Rudiba Laiba saw that stores in the Netherlands eschewed plastic bags to save the planet, her first thought was, “that doesn’t happen in Bangladesh.”Laiba is one of eight MIT students who traveled to the Netherlands in June as part of an MIT Energy Initiative (MITEI)-sponsored trip to experience first-hand the country’s approach to the energy transition. The Netherlands aims to be carbon neutral by 2050, making it one of the top 10 countries leading the charge on climate change, according to U.S. News and World Report.MITEI sponsored the week-long trip to allow undergraduate and graduate students to collaboratively explore clean energy efforts with researchers, corporate leaders, and nongovernmental organizations. The students heard about projects ranging from creating hydrogen pipelines in the North Sea to climate-proofing a fuel-guzzling, asphalt-dense neighborhood.Felipe Abreu from Kissimmee, Florida, a rising second-year student studying materials science and engineering, is working this summer on ways to melt and reuse metal scraps discarded in manufacturing processes. “When MITEI put out this notice about visiting the Netherlands, I wanted to see if there were more advanced approaches to renewable energy that I’d never been exposed to,” Abreu says.Laiba notes that her native Bangladesh has not yet achieved the Netherlands’ nearly universal buy-in to tackling climate change, even though this South Asian country, like the Netherlands, is particularly vulnerable to rising sea levels due to topography and high population density.Laiba, who spent part of her childhood in New York City and lived in Bangladesh from ages 8 to 18, calls Bangladesh “on the front lines of climate change.“Even if I didn’t want to care about climate change, I had to, because I would see the effects of it,” she says.Key playersThe MIT students conducted hands-on exercises on how to switch from traditional energy sources to zero-carbon technologies. “We talked a lot about infrastructure, particularly how to repurpose natural gas infrastructure for hydrogen,” says Antje Danielson, director of education at MITEI, who led the trip with Em Schule, MITEI research and programming assistant. “The students were challenged to grapple with real-world decision-making.”The northern section of the Netherlands is known as the “hydrogen valley” of Europe. At the University of Groningen and Hanze University School of Applied Sciences, also in Groningen, the students heard about how the region profiles itself as a world capital for the energy transition through its push toward a hydrogen-based economy and its state-of-the-art global climate models.Erick Liang, a rising junior from Boston’s Roslindale neighborhood pursuing a dual major in nuclear science and engineering and physics, was intrigued by a massive wind farm in the port city of Eemshaven, one of the group’s first stops in the north of the country. “It was impressive as an engineering challenge, because they must have figured out ways to cheaply and effectively manufacture all these wind turbines,” he says.They visited German energy company RWE, which is generating 15 percent of Eemshaven’s electricity from biomass, replacing coal.Laiba, who is majoring in molecular biology and electrical engineering and computer science with a minor in business management, was intrigued by a presentation on biofuels. “It piqued my interest to see if they would use biomass on a large scale” because of the challenges and unpredictability associated with it as a fuel source.In Paddepoel, the students toured the first of several neighborhoods that once lacked greenery and used fossil fuel-based heating systems and now aim to generate more energy than they consume.“The students got to see what the size of the district heating pipes would be, and how they go through people’s gardens into the houses. We talked about the physical impact on the neighborhood of installing these pipes, as well as the potential social and political implications connected to a really difficult transition like this,” Danielson says.Going greenGreen hydrogen promises to be a key player in the energy transition, and Netherlands officials say they have committed to the new infrastructure and business models needed to move ahead with hydrogen as a fuel source.The students explored how green hydrogen differs from fossil fuel-generated hydrogen. They saw how Dutch companies grappled with siting hydrogen production facilities and handling hydrogen as a gas, which, unlike natural gas, does not yet have a detectable artificial odor. The students heard from energy network operator Gasunie about the science and engineering behind repurposing existing natural gas pipelines for a hydrogen network in the North Sea, and were challenged to solve the puzzle of combining hydrogen production with offshore wind energy. In the port of Rotterdam, they saw how the startup Battolyser Systems — which is working with Delft University of Technology on an electrolysis device that splits water into hydrogen and oxygen and doubles as a battery — is transitioning from lab bench to market.Laiba was impressed by how much capital was going into high-risk ventures and startups, “not only because they’re trying to make something revolutionary, but also because society needs to accept and use” their products.Abreu says that at Battolyser Systems, “I saw people my age on the forefront of green hydrogen, trying to make a difference.”The students visited the Global Center on Adaptation’s carbon-neutral floating offices and learned how this international organization supports climate adaptation actions around the world and the practice of mitigation.Also in Rotterdam, international marine contractor Van Oord took students to view a ship that installs wind turbines and explained how their new technology reduces the sound shockwave impact of the installations on marine life.At the Port of Rotterdam, the students heard about the challenges faced by Europe’s largest port in terms of global shipping and choosing the fuels of the future. The speaker tasked the MIT students with coming up with a plan to transition the privately owned, owner-inhabited barges that ply the region’s inland waterways to a zero-carbon system.“The Port Authority uses this exercise to illustrate the enormous complexity faced by companies in the energy transition,” Danielson says. “The fact that our students performed really well on the spot shows that we are doing something right at MIT.”Defining a path forwardLiang, Abreu, and Laiba were struck by how the Netherlands has come together as a country over climate change. “In the U.S., a lot of people disagree with the concept of climate change as a whole,” Liang says. “But in the Netherlands, everyone is on the same page that this is an issue that we should be working toward. They’re capable of seeing a path forward and trying to take action whenever possible.”Liang, a member of the MIT Solar Electric Vehicle Team, is doing undergraduate research sponsored by MITEI this summer, working to accelerate fusion manufacturing and development at the MIT Plasma Science and Fusion Center. He’s improving 3D printing processes to manufacture components that can accommodate the high temperatures and small space within a tokamak reactor, which uses magnetic fields to confine plasma and produce controlled thermonuclear fusion.“I personally would like to try finding a new solution” to achieving carbon neutrality, he says. That solution, to Liang, is fusion energy, with some entities hoping to demonstrate net energy gain through fusion in the next five years.Laiba is a researcher with the MIT Office of Sustainability, looking at ways to quantify and reduce the level of MIT’s Scope 3 greenhouse gas emissions. Scope 3 emissions are tied to the purchase of goods that use fossil fuels in their manufacture. She says, ​“Whatever I decide to do in the future will involve making a more sustainable future. And to me, renewable energy is the driving force behind that.”In the Netherlands, she says, “what we learned through the entire trip was that renewable energy powers the country to a large amount. Things I could see tangibly was Starbucks having paper cups even for our iced drinks, which I think would flop very hard in the U.S. I don’t think society’s ready for that yet.”Abreu says, “In America, sustainability has always been in the back seat while other things take the forefront. So going to a country where everybody you talk to has a stake (in sustainability) and actually cares, and they’re all pushing together for this common goal, it was inspiring. It gave me hope.” More