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    Engineers find a new way to convert carbon dioxide into useful products

    MIT chemical engineers have devised an efficient way to convert carbon dioxide to carbon monoxide, a chemical precursor that can be used to generate useful compounds such as ethanol and other fuels.

    If scaled up for industrial use, this process could help to remove carbon dioxide from power plants and other sources, reducing the amount of greenhouse gases that are released into the atmosphere.

    “This would allow you to take carbon dioxide from emissions or dissolved in the ocean, and convert it into profitable chemicals. It’s really a path forward for decarbonization because we can take CO2, which is a greenhouse gas, and turn it into things that are useful for chemical manufacture,” says Ariel Furst, the Paul M. Cook Career Development Assistant Professor of Chemical Engineering and the senior author of the study.

    The new approach uses electricity to perform the chemical conversion, with help from a catalyst that is tethered to the electrode surface by strands of DNA. This DNA acts like Velcro to keep all the reaction components in close proximity, making the reaction much more efficient than if all the components were floating in solution.

    Furst has started a company called Helix Carbon to further develop the technology. Former MIT postdoc Gang Fan is the lead author of the paper, which appears in the Journal of the American Chemical Society Au. Other authors include Nathan Corbin PhD ’21, Minju Chung PhD ’23, former MIT postdocs Thomas Gill and Amruta Karbelkar, and Evan Moore ’23.

    Breaking down CO2

    Converting carbon dioxide into useful products requires first turning it into carbon monoxide. One way to do this is with electricity, but the amount of energy required for that type of electrocatalysis is prohibitively expensive.

    To try to bring down those costs, researchers have tried using electrocatalysts, which can speed up the reaction and reduce the amount of energy that needs to be added to the system. One type of catalyst used for this reaction is a class of molecules known as porphyrins, which contain metals such as iron or cobalt and are similar in structure to the heme molecules that carry oxygen in blood. 

    During this type of electrochemical reaction, carbon dioxide is dissolved in water within an electrochemical device, which contains an electrode that drives the reaction. The catalysts are also suspended in the solution. However, this setup isn’t very efficient because the carbon dioxide and the catalysts need to encounter each other at the electrode surface, which doesn’t happen very often.

    To make the reaction occur more frequently, which would boost the efficiency of the electrochemical conversion, Furst began working on ways to attach the catalysts to the surface of the electrode. DNA seemed to be the ideal choice for this application.

    “DNA is relatively inexpensive, you can modify it chemically, and you can control the interaction between two strands by changing the sequences,” she says. “It’s like a sequence-specific Velcro that has very strong but reversible interactions that you can control.”

    To attach single strands of DNA to a carbon electrode, the researchers used two “chemical handles,” one on the DNA and one on the electrode. These handles can be snapped together, forming a permanent bond. A complementary DNA sequence is then attached to the porphyrin catalyst, so that when the catalyst is added to the solution, it will bind reversibly to the DNA that’s already attached to the electrode — just like Velcro.

    Once this system is set up, the researchers apply a potential (or bias) to the electrode, and the catalyst uses this energy to convert carbon dioxide in the solution into carbon monoxide. The reaction also generates a small amount of hydrogen gas, from the water. After the catalysts wear out, they can be released from the surface by heating the system to break the reversible bonds between the two DNA strands, and replaced with new ones.

    An efficient reaction

    Using this approach, the researchers were able to boost the Faradaic efficiency of the reaction to 100 percent, meaning that all of the electrical energy that goes into the system goes directly into the chemical reactions, with no energy wasted. When the catalysts are not tethered by DNA, the Faradaic efficiency is only about 40 percent.

    This technology could be scaled up for industrial use fairly easily, Furst says, because the carbon electrodes the researchers used are much less expensive than conventional metal electrodes. The catalysts are also inexpensive, as they don’t contain any precious metals, and only a small concentration of the catalyst is needed on the electrode surface.

    By swapping in different catalysts, the researchers plan to try making other products such as methanol and ethanol using this approach. Helix Carbon, the company started by Furst, is also working on further developing the technology for potential commercial use.

    The research was funded by the U.S. Army Research Office, the CIFAR Azrieli Global Scholars Program, the MIT Energy Initiative, and the MIT Deshpande Center. More

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    Artificial reef designed by MIT engineers could protect marine life, reduce storm damage

    The beautiful, gnarled, nooked-and-crannied reefs that surround tropical islands serve as a marine refuge and natural buffer against stormy seas. But as the effects of climate change bleach and break down coral reefs around the world, and extreme weather events become more common, coastal communities are left increasingly vulnerable to frequent flooding and erosion.

    An MIT team is now hoping to fortify coastlines with “architected” reefs — sustainable, offshore structures engineered to mimic the wave-buffering effects of natural reefs while also providing pockets for fish and other marine life.

    The team’s reef design centers on a cylindrical structure surrounded by four rudder-like slats. The engineers found that when this structure stands up against a wave, it efficiently breaks the wave into turbulent jets that ultimately dissipate most of the wave’s total energy. The team has calculated that the new design could reduce as much wave energy as existing artificial reefs, using 10 times less material.

    The researchers plan to fabricate each cylindrical structure from sustainable cement, which they would mold in a pattern of “voxels” that could be automatically assembled, and would provide pockets for fish to explore and other marine life to settle in. The cylinders could be connected to form a long, semipermeable wall, which the engineers could erect along a coastline, about half a mile from shore. Based on the team’s initial experiments with lab-scale prototypes, the architected reef could reduce the energy of incoming waves by more than 95 percent.

    “This would be like a long wave-breaker,” says Michael Triantafyllou, the Henry L. and Grace Doherty Professor in Ocean Science and Engineering in the Department of Mechanical Engineering. “If waves are 6 meters high coming toward this reef structure, they would be ultimately less than a meter high on the other side. So, this kills the impact of the waves, which could prevent erosion and flooding.”

    Details of the architected reef design are reported today in a study appearing in the open-access journal PNAS Nexus. Triantafyllou’s MIT co-authors are Edvard Ronglan SM ’23; graduate students Alfonso Parra Rubio, Jose del Auila Ferrandis, and Erik Strand; research scientists Patricia Maria Stathatou and Carolina Bastidas; and Professor Neil Gershenfeld, director of the Center for Bits and Atoms; along with Alexis Oliveira Da Silva at the Polytechnic Institute of Paris, Dixia Fan of Westlake University, and Jeffrey Gair Jr. of Scinetics, Inc.

    Leveraging turbulence

    Some regions have already erected artificial reefs to protect their coastlines from encroaching storms. These structures are typically sunken ships, retired oil and gas platforms, and even assembled configurations of concrete, metal, tires, and stones. However, there’s variability in the types of artificial reefs that are currently in place, and no standard for engineering such structures. What’s more, the designs that are deployed tend to have a low wave dissipation per unit volume of material used. That is, it takes a huge amount of material to break enough wave energy to adequately protect coastal communities.

    The MIT team instead looked for ways to engineer an artificial reef that would efficiently dissipate wave energy with less material, while also providing a refuge for fish living along any vulnerable coast.

    “Remember, natural coral reefs are only found in tropical waters,” says Triantafyllou, who is director of the MIT Sea Grant. “We cannot have these reefs, for instance, in Massachusetts. But architected reefs don’t depend on temperature, so they can be placed in any water, to protect more coastal areas.”

    MIT researchers test the wave-breaking performance of two artificial reef structures in the MIT Towing Tank.Credit: Courtesy of the researchers

    The new effort is the result of a collaboration between researchers in MIT Sea Grant, who developed the reef structure’s hydrodynamic design, and researchers at the Center for Bits and Atoms (CBA), who worked to make the structure modular and easy to fabricate on location. The team’s architected reef design grew out of two seemingly unrelated problems. CBA researchers were developing ultralight cellular structures for the aerospace industry, while Sea Grant researchers were assessing the performance of blowout preventers in offshore oil structures — cylindrical valves that are used to seal off oil and gas wells and prevent them from leaking.

    The team’s tests showed that the structure’s cylindrical arrangement generated a high amount of drag. In other words, the structure appeared to be especially efficient in dissipating high-force flows of oil and gas. They wondered: Could the same arrangement dissipate another type of flow, in ocean waves?

    The researchers began to play with the general structure in simulations of water flow, tweaking its dimensions and adding certain elements to see whether and how waves changed as they crashed against each simulated design. This iterative process ultimately landed on an optimized geometry: a vertical cylinder flanked by four long slats, each attached to the cylinder in a way that leaves space for water to flow through the resulting structure. They found this setup essentially breaks up any incoming wave energy, causing parts of the wave-induced flow to spiral to the sides rather than crashing ahead.

    “We’re leveraging this turbulence and these powerful jets to ultimately dissipate wave energy,” Ferrandis says.

    Standing up to storms

    Once the researchers identified an optimal wave-dissipating structure, they fabricated a laboratory-scale version of an architected reef made from a series of the cylindrical structures, which they 3D-printed from plastic. Each test cylinder measured about 1 foot wide and 4 feet tall. They assembled a number of cylinders, each spaced about a foot apart, to form a fence-like structure, which they then lowered into a wave tank at MIT. They then generated waves of various heights and measured them before and after passing through the architected reef.

    “We saw the waves reduce substantially, as the reef destroyed their energy,” Triantafyllou says.

    The team has also looked into making the structures more porous, and friendly to fish. They found that, rather than making each structure from a solid slab of plastic, they could use a more affordable and sustainable type of cement.

    “We’ve worked with biologists to test the cement we intend to use, and it’s benign to fish, and ready to go,” he adds.

    They identified an ideal pattern of “voxels,” or microstructures, that cement could be molded into, in order to fabricate the reefs while creating pockets in which fish could live. This voxel geometry resembles individual egg cartons, stacked end to end, and appears to not affect the structure’s overall wave-dissipating power.

    “These voxels still maintain a big drag while allowing fish to move inside,” Ferrandis says.

    The team is currently fabricating cement voxel structures and assembling them into a lab-scale architected reef, which they will test under various wave conditions. They envision that the voxel design could be modular, and scalable to any desired size, and easy to transport and install in various offshore locations. “Now we’re simulating actual sea patterns, and testing how these models will perform when we eventually have to deploy them,” says Anjali Sinha, a graduate student at MIT who recently joined the group.

    Going forward, the team hopes to work with beach towns in Massachusetts to test the structures on a pilot scale.

    “These test structures would not be small,” Triantafyllou emphasizes. “They would be about a mile long, and about 5 meters tall, and would cost something like 6 million dollars per mile. So it’s not cheap. But it could prevent billions of dollars in storm damage. And with climate change, protecting the coasts will become a big issue.”

    This work was funded, in part, by the U.S. Defense Advanced Research Projects Agency. More

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    Think globally, rebuild locally

    Building construction accounts for a huge chunk of greenhouse gas emissions: About 36 percent of carbon dioxide emissions and 40 percent of energy consumption in Europe, for instance. That’s why the European Union has developed regulations about the reuse of building materials.

    Some cities are adding more material reuse into construction already. Amsterdam, for example, is attempting to slash its raw material use by half by 2030. The Netherlands as a whole aims for a “circular economy” of completely reused materials by 2050.

    But the best way to organize the reuse of construction waste is still being determined. For one thing: Where should reusable building materials be stored before they are reused? A newly published study focusing on Amsterdam finds the optimal material reuse system for construction has many local storage “hubs” that keep materials within a few miles of where they will be needed.

    “Our findings provide a starting point for policymakers in Amsterdam to strategize land use effectively,” says Tanya Tsui, a postdoc at MIT and a co-author of the new paper. “By identifying key locations repeatedly favored across various hub scenarios, we underscore the importance of prioritizing these areas for future circular economy endeavors in Amsterdam.”

    The study adds to an emerging research area that connects climate change and urban planning.

    “The issue is where you put material in between demolition and new construction,” says Fábio Duarte, a principal researcher at MIT’s Senseable City Lab and a co-author of the new paper. “It will have huge impacts in terms of transportation. So you have to define the best sites. Should there be only one? Should we hold materials across a wide number of sites? Or is there an optimal number, even if it changes over time? This is what we examined in the paper.”

    The paper, “Spatial optimization of circular timber hubs,” is published in NPJ Nature Urban Sustainability. The authors are Tsui, who is a postdoc at the MIT Senseable Amsterdam Lab in the Amsterdam Institute for Advanced Metropolitan Solutions (AMS); Titus Venverloo, a research fellow at MIT Senseable Amsterdam Lab and AMS; Tom Benson, a researcher at the Senseable City Lab; and Duarte, who is also a lecturer in MIT’s Department of Urban Studies and Planning and the MIT Center for Real Estate.

    Numerous experts have previously studied at what scale the “circular economy” of reused materials might best operate. Some have suggested that very local circuits of materials recycling make the most sense; others have proposed that building-materials recycling will work best at a regional scale, with a radius of distribution covering 30 or more miles. Some analyses contend that global-scale reuse will be necessary to an extent.

    The current study adds to this examination of the best geographic scale for using construction materials again. Currently the storage hubs that do exist for such reused materials are chosen by individual companies, but those locations might not be optimal either economically or environmentally. 

    To conduct the study, the researchers essentially conducted a series of simulations of the Amsterdam metropolitan area, focused exclusively on timber reuse. The simulations examined how the system would work if anywhere from one to 135 timber storage hubs existed in greater Amsterdam. The modeling accounted for numerous variables, such as emissions reductions, logistical factors, and even how changing supply-and-demand scenarios would affect the viability of the reusehubs.

    Ultimately, the research found that Amsterdam’s optimal system would have 29 timber hubs, each serving a radius of about 2 miles. That setup generated 95 percent of the maximum reduction in CO2 emissions, while retaining logistical and economic benefits.

    That results also lands firmly on the side of having more localized networks for keeping construction materials in use.

    “If we have demolition happening in certain sites, then we can project where the best spots around the city are to have these circular economy hubs, as we call them,” Duarte says. “It’s not only one big hub — or one hub per construction site.”

    The study seeks to identify not only the optimal number of storage sites, but to identify where those sites might be.

    “[We hope] our research sparks discussions regarding the location and scale of circular hubs,” Tsui says. “While much attention has been given to governance aspects of the circular economy in cities, our study demonstrates the potential of utilizing location data on materials to inform decisions in urban planning.”

    The simulations also illuminated the dynamics of materials reuse. In scenarios where Amsterdam had from two to 20 timber recycling hubs, the costs involved lowered as the number of hubs increased — because having more hubs reduces transportation costs. But when the number of hubs went about 40, the system as a whole became more expensive — because each timber depot was not storing enough material to justify the land use.

    As such, the results may be of interest to climate policymakers, urban planners, and business interests getting involved in implementing the circular economy in the construction industry.

    “Ultimately,” Tsui says, “we envision our research catalyzing meaningful discussions and guiding policymakers toward more informed decisions in advancing the circular economy agenda in urban contexts.”

    The research was supported, in part, by the European Union’s Horizon 2020 research and innovation program. More

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    Understanding the impacts of mining on local environments and communities

    Hydrosocial displacement refers to the idea that resolving water conflict in one area can shift the conflict to a different area. The concept was coined by Scott Odell, a visiting researcher in MIT’s Environmental Solutions Initiative (ESI). As part of ESI’s Program on Mining and the Circular Economy, Odell researches the impacts of extractive industries on local environments and communities, especially in Latin America. He discovered that hydrosocial displacements are often in regions where the mining industry is vying for use of precious water sources that are already stressed due to climate change.

    Odell is working with John Fernández, ESI director and professor in the Department of Architecture, on a project that is examining the converging impacts of climate change, mining, and agriculture in Chile. The work is funded by a seed grant from MIT’s Abdul Latif Jameel Water and Food Systems Lab (J-WAFS). Specifically, the project seeks to answer how the expansion of seawater desalination by the mining industry is affecting local populations, and how climate change and mining affect Andean glaciers and the agricultural communities dependent upon them.By working with communities in mining areas, Odell and Fernández are gaining a sense of the burden that mining minerals needed for the clean energy transition is placing on local populations, and the types of conflicts that arise when water sources become polluted or scarce. This work is of particular importance considering over 100 countries pledged a commitment to the clean energy transition at the recent United Nations climate change conference, known as COP28.

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    J-WAFS Community Spotlight on Scott Odell

    Water, humanity’s lifebloodAt the March 2023 United Nations (U.N.) Water Conference in New York, U.N. Secretary-General António Guterres warned “water is in deep trouble. We are draining humanity’s lifeblood through vampiric overconsumption and unsustainable use and evaporating it through global heating.” A quarter of the world’s population already faces “extremely high water stress,” according to the World Resources Institute. In an effort to raise awareness of major water-related issues and inspire action for innovative solutions, the U.N. created World Water Day, observed every year on March 22. This year’s theme is “Water for Peace,” underscoring the fact that even though water is a basic human right and intrinsic to every aspect of life, it is increasingly fought over as supplies dwindle due to problems including drought, overuse, or mismanagement.  

    The “Water for Peace” theme is exemplified in Fernández and Odell’s J-WAFS project, where findings are intended to inform policies to reduce social and environmental harms inflicted on mining communities and their limited water sources.“Despite broad academic engagement with mining and climate change separately, there has been a lack of analysis of the societal implications of the interactions between mining and climate change,” says Odell. “This project is helping to fill the knowledge gap. Results will be summarized in Spanish and English and distributed to interested and relevant parties in Chile, ensuring that the results can be of benefit to those most impacted by these challenges,” he adds.

    The effects of mining for the clean energy transition

    Global climate change is understood to be the most pressing environmental issue facing humanity today. Mitigating climate change requires reducing carbon emissions by transitioning away from conventional energy derived from burning fossil fuels, to more sustainable energy sources like solar and wind power. Because copper is an excellent conductor of electricity, it will be a crucial element in the clean energy transition, in which more solar panels, wind turbines, and electric vehicles will be manufactured. “We are going to see a major increase in demand for copper due to the clean energy transition,” says Odell.

    In 2021, Chile produced 26 percent of the world’s copper, more than twice as much as any other country, Odell explains. Much of Chile’s mining is concentrated in and around the Atacama Desert — the world’s driest desert. Unfortunately, mining requires large amounts of water for a variety of processes, including controlling dust at the extraction site, cooling machinery, and processing and transporting ore.

    Chile is also one of the world’s largest exporters of agricultural products. Farmland is typically situated in the valleys downstream of several mines in the high Andes region, meaning mines get first access to water. This can lead to water conflict between mining operations and agricultural communities. Compounding the problem of mining for greener energy materials to combat climate change, are the very effects of climate change. According to the Chilean government, the country has suffered 13 years of the worst drought in history. While this is detrimental to the mining industry, it is also concerning for those working in agriculture, including the Indigenous Atacameño communities that live closest to the Escondida mine, the largest copper mine in the world. “There was never a lot of water to go around, even before the mine,” Odell says. The addition of Escondida stresses an already strained water system, leaving Atacameño farmers and individuals vulnerable to severe water insecurity.

    What’s more, waste from mining, known as tailings, includes minerals and chemicals that can contaminate water in nearby communities if not properly handled and stored. Odell says the secure storage of tailings is a high priority in earthquake-prone Chile. “If an earthquake were to hit and damage a tailings dam, it could mean toxic materials flowing downstream and destroying farms and communities,” he says.

    Chile’s treasured glaciers are another piece of the mining, climate change, and agricultural puzzle. Caroline White-Nockleby, a PhD candidate in MIT’s Program in Science, Technology, and Society, is working with Odell and Fernández on the J-WAFS project and leading the research specifically on glaciers. “These may not be the picturesque bright blue glaciers that you might think of, but they are, nonetheless, an important source of water downstream,” says White-Nockleby. She goes on to explain that there are a few different ways that mines can impact glaciers.

    In some cases, mining companies have proposed to move or even destroy glaciers to get at the ore beneath. Other impacts include dust from mining that falls on glaciers. White-Nockleby says, “this makes the glaciers a darker color, so, instead of reflecting the sun’s rays away, [the glacier] may absorb the heat and melt faster.” This shows that even when not directly intervening with glaciers, mining activities can cause glacial decline, adding to the threat glaciers already face due to climate change. She also notes that “glaciers are an important water storage facility,” describing how, on an annual cycle, glaciers freeze and melt, allowing runoff that downstream agricultural communities can utilize. If glaciers suddenly melt too quickly, flooding of downstream communities can occur.

    Desalination offers a possible, but imperfect, solution

    Chile’s extensive coastline makes it uniquely positioned to utilize desalination — the removal of salts from seawater — to address water insecurity. Odell says that “over the last decade or so, there’s been billions of dollars of investments in desalination in Chile.”

    As part of his dissertation work at Clark University, Odell found broad optimism in Chile for solving water issues in the mining industry through desalination. Not only was the mining industry committed to building desalination plants, there was also political support, and support from some community members in highland communities near the mines. Yet, despite the optimism and investment, desalinated water was not replacing the use of continental water. He concluded that “desalination can’t solve water conflict if it doesn’t reduce demand for continental water supplies.”

    However, after publishing those results, Odell learned that new estimates at the national level showed that desalination operations had begun to replace the use of continental water after 2018. In two case studies that he currently focuses on — the Escondida and Los Pelambres copper mines — the mining companies have expanded their desalination objectives in order to reduce extraction from key continental sources. This seems to be due to a variety of factors. For one thing, in 2022, Chile’s water code was reformed to prioritize human water consumption and environmental protection of water during scarcity and in the allocation of future rights. It also shortened the granting of water rights from “in perpetuity” to 30 years. Under this new code, it is possible that the mining industry may have expanded its desalination efforts because it viewed continental water resources as less secure, Odell surmises.

    As part of the J-WAFS project, Odell has found that recent reactions have been mixed when it comes to the rapid increase in the use of desalination. He spent over two months doing fieldwork in Chile by conducting interviews with members of government, industry, and civil society at the Escondida, Los Pelambres, and Andina mining sites, as well as in Chile’s capital city, Santiago. He has spoken to local and national government officials, leaders of fishing unions, representatives of mining and desalination companies, and farmers. He observed that in the communities where the new desalination plants are being built, there have been concerns from community members as to whether they will get access to the desalinated water, or if it will belong solely to the mines.

    Interviews at the Escondida and Los Pelambres sites, in which desalination operations are already in place or under construction, indicate acceptance of the presence of desalination plants combined with apprehension about unknown long-term environmental impacts. At a third mining site, Andina, there have been active protests against a desalination project that would supply water to a neighboring mine, Los Bronces. In that community, there has been a blockade of the desalination operation by the fishing federation. “They were blockading that operation for three months because of concerns over what the desalination plant would do to their fishing grounds,” Odell says. And this is where the idea of hydrosocial displacement comes into the picture, he explains. Even though desalination operations are easing tensions with highland agricultural communities, new issues are arising for the communities on the coast. “We can’t just look to desalination to solve our problems if it’s going to create problems somewhere else” Odell advises.

    Within the process of hydrosocial displacement, interacting geographical, technical, economic, and political factors constrain the range of responses to address the water conflict. For example, communities that have more political and financial power tend to be better equipped to solve water conflict than less powerful communities. In addition, hydrosocial concerns usually follow the flow of water downstream, from the highlands to coastal regions. Odell says that this raises the need to look at water from a broader perspective.

    “We tend to address water concerns one by one and that can, in practice, end up being kind of like whack-a-mole,” says Odell. “When we think of the broader hydrological system, water is very much linked, and we need to look across the watershed. We can’t just be looking at the specific community affected now, but who else is affected downstream, and will be affected in the long term. If we do solve a water issue by moving it somewhere else, like moving a tailings dam somewhere else, or building a desalination plant, resources are needed in the receiving community to respond to that,” suggests Odell.

    The company building the desalination plant and the fishing federation ultimately reached an agreement and the desalination operation will be moving forward. But Odell notes, “the protest highlights concern about the impacts of the operation on local livelihoods and environments within the much larger context of industrial pollution in the area.”

    The power of communities

    The protest by the fishing federation is one example of communities coming together to have their voices heard. Recent proposals by mining companies that would affect glaciers and other water sources used by agriculture communities have led to other protests that resulted in new agreements to protect local water supplies and the withdrawal of some of the mining proposals.Odell observes that communities have also gone to the courts to raise their concerns. The Atacameño communities, for example, have drawn attention to over-extraction of water resources by the Escondida mine. “Community members are also pursuing education in these topics so that there’s not such a power imbalance between mining companies and local communities,” Odell remarks. This demonstrates the power local communities can have to protect continental water resources.The political and social landscape of Chile may also be changing in favor of local communities. Beginning with what is now referred to as the Estallido Social (social outburst) over inequality in 2019, Chile has undergone social upheaval that resulted in voters calling for a new constitution. Gabriel Boric, a progressive candidate, whose top priorities include social and environmental issues, was elected president during this period. These trends have brought major attention to issues of economic inequality, environmental harms of mining, and environmental justice, which is putting pressure on the mining industry to make a case for its operations in the country, and to justify the environmental costs of mining.

    What happens after the mine dries up?

    From his fieldwork interviews, Odell has learned that the development of mines within communities can offer benefits. Mining companies typically invest directly in communities through employment, road construction, and sometimes even by building or investing in schools, stadiums, or health clinics. Indirectly, mines can have spillover effects in the economy since miners might support local restaurants, hotels, or stores. But what happens when the mine closes? As one community member Odell interviewed stated: “When the mine is gone, what are we going to have left besides a big hole in the ground?”

    Odell suggests that a multi-pronged approach should be taken to address the future state of water and mining. First, he says we need to have broader conversations about the nature of our consumption and production at domestic and global scales. “Mining is driven indirectly by our consumption of energy and directly by our consumption of everything from our buildings to devices to cars,” Odell states. “We should be looking for ways to moderate our consumption and consume smarter through both policy and practice so that we don’t solve climate change while creating new environmental harms through mining.”One of the main ways we can do this is by advancing the circular economy by recycling metals already in the system, or even in landfills, to help build our new clean energy infrastructure. Even so, the clean energy transition will still require mining, but according to Odell, that mining can be done better. “Mining companies and government need to do a better job of consulting with communities. We need solid plans and financing for mine closures in place from the beginning of mining operations, so that when the mine dries up, there’s the money needed to secure tailings dams and protect the communities who will be there forever,” Odell concludes.Overall, it will take an engaged society — from the mining industry to government officials to individuals — to think critically about the role we each play in our quest for a more sustainable planet, and what that might mean for the most vulnerable populations among us. More

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    Lessons from Fukushima: Prepare for the unlikely

    When a devastating earthquake and tsunami overwhelmed the protective systems at the Fukushima Dai’ichi nuclear power plant complex in Japan in March 2011, it triggered a sequence of events leading to one of the worst releases of radioactive materials in the world to date. Although nuclear energy is having a revival as a low-emissions energy source to mitigate climate change, the Fukushima accident is still cited as a reason for hesitancy in adopting it.

    A new study synthesizes information from multidisciplinary sources to understand how the Fukushima Dai’ichi disaster unfolded, and points to the importance of mitigation measures and last lines of defense — even against accidents considered highly unlikely. These procedures have received relatively little attention, but they are critical in determining how severe the consequences of a reactor failure will be, the researchers say.

    The researchers note that their synthesis is one of the few attempts to look at data across disciplinary boundaries, including: the physics and engineering of what took place within the plant’s systems, the plant operators’ actions throughout the emergency, actions by emergency responders, the meteorology of radionuclide releases and transport, and the environmental and health consequences documented since the event.

    The study appears in the journal iScience, in an open-access paper by postdoc Ali Ayoub and Professor Haruko Wainwright at MIT, along with others in Switzerland, Japan, and New Mexico.

    Since 2013, Wainwright has been leading the research to integrate all the radiation monitoring data in the Fukushima region into integrated maps. “I was staring at the contamination map for nearly 10 years, wondering what created the main plume extending in the northwest direction, but I could not find exact information,” Wainwright says. “Our study is unique because we started from the consequence, the contamination map, and tried to identify the key factors for the consequence. Other people study the Fukushima accident from the root cause, the tsunami.”

    One thing they found was that while all the operating reactors, units 1, 2, and 3, suffered core meltdowns as a result of the failure of emergency cooling systems, units 1 and 3 — although they did experience hydrogen explosions — did not release as much radiation to the environment because their venting systems essentially worked to relieve pressure inside the containment vessels as intended. But the same system in unit 2 failed badly.

    “People think that the hydrogen explosion or the core meltdown were the worst things, or the major driver of the radiological consequences of the accident,” Wainright says, “but our analysis found that’s not the case.” Much more significant in terms of the radiological release was the failure of the one venting mechanism.

    “There is a pressure-release mechanism that goes through water where a lot of the radionuclides get filtered out,” she explains. That system was effective in units 1 and 3, filtering out more than 90 percent of the radioactive elements before the gas was vented. However, “in unit 2, that pressure release mechanism got stuck, and the operators could not manually open it.” A hydrogen explosion in unit 1 had damaged the pressure relief mechanism of unit 2. This led to a breach of the containment structure and direct, unfiltered venting to the atmosphere, which, according to the new study, was what produced the greatest amount of contamination from the whole weeks-long event.

    Another factor was the timing of the attempt to vent the pressure buildup in the reactor. Guidelines at the time, and to this day in many reactors, specified that no venting should take place until the pressure inside the reactor containment vessel reached a specified threshold, with no regard to the wind directions at the time. In the case of Fukushima, an earlier venting could have dramatically reduced the impact: Much of the release happened when winds were blowing directly inland, but earlier the wind had been blowing offshore.

    “That pressure-release mechanism has not been a major focus of the engineering community,” she says. While there is appropriate attention to measures that prevent a core meltdown in the first place, “this sort of last line of defense has not been the main focus and should get more attention.”

    Wainwright says the study also underlines several successes in the management of the Fukushima accident. Many of the safety systems did work as they were designed. For example, even though the oldest reactor, unit 1, suffered the greatest internal damage, it released little radioactive material. Most people were able to evacuate from the 20-kilometer (12-mile) zone before the largest release happened. The mitigation measures were “somewhat successful,” Wainwright says. But there was tremendous confusion and anger during and after the accident because there were no preparations in place for such an event.

    Much work has focused on ways to prevent the kind of accidents that happened at Fukushima — for example, in the U.S. reactor operators can deploy portable backup power supplies to maintain proper reactor cooling at any reactor site. But the ongoing situation at the Zaporizhzhia nuclear complex in Ukraine, where nuclear safety is challenged by acts of war, demonstrates that despite engineers’ and operators’ best efforts to prevent it, “the totally unexpected could still happen,” Wainwright says.

    “The big-picture message is that we should have equal attention to both prevention and mitigation of accidents,” she says. “This is the essence of resilience, and it applies beyond nuclear power plants to all essential infrastructure of a functioning society, for example, the electric grid, the food and water supply, the transportation sector, etc.”

    One thing the researchers recommend is that in designing evacuation protocols, planners should make more effort to learn from much more frequent disasters such as wildfires and hurricanes. “We think getting more interdisciplinary, transdisciplinary knowledge from other kinds of disasters would be essential,” she says. Most of the emergency response strategies presently in place, she says, were designed in the 1980s and ’90s, and need to be modernized. “Consequences can be mitigated. A nuclear accident does not have to be a catastrophe, as is often portrayed in popular culture,” Wainright says.

    The research team included Giovanni Sansavini at ETH Zurich in Switzerland; Randall Gauntt at Sandia National Laboratories in New Mexico; and Kimiaki Saito at the Japan Atomic Energy Agency. More

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    Optimizing nuclear fuels for next-generation reactors

    In 2010, when Ericmoore Jossou was attending college in northern Nigeria, the lights would flicker in and out all day, sometimes lasting only for a couple of hours at a time. The frustrating experience reaffirmed Jossou’s realization that the country’s sporadic energy supply was a problem. It was the beginning of his path toward nuclear engineering.

    Because of the energy crisis, “I told myself I was going to find myself in a career that allows me to develop energy technologies that can easily be scaled to meet the energy needs of the world, including my own country,” says Jossou, an assistant professor in a shared position between the departments of Nuclear Science and Engineering (NSE), where is the John Clark Hardwick (1986) Professor, and of Electrical Engineering and Computer Science.

    Today, Jossou uses computer simulations for rational materials design, AI-aided purposeful development of cladding materials and fuels for next-generation nuclear reactors. As one of the shared faculty hires between the MIT Schwarzman College of Computing and departments across MIT, his appointment recognizes his commitment to computing for climate and the environment.

    A well-rounded education in Nigeria

    Growing up in Lagos, Jossou knew education was about more than just bookish knowledge, so he was eager to travel and experience other cultures. He would start in his own backyard by traveling across the Niger river and enrolling in Ahmadu Bello University in northern Nigeria. Moving from the south was a cultural education with a different language and different foods. It was here that Jossou got to try and love tuwo shinkafa, a northern Nigerian rice-based specialty, for the first time.

    After his undergraduate studies, armed with a bachelor’s degree in chemistry, Jossou was among a small cohort selected for a specialty master’s training program funded by the World Bank Institute and African Development Bank. The program at the African University of Science and Technology in Abuja, Nigeria, is a pan-African venture dedicated to nurturing homegrown science talent on the continent. Visiting professors from around the world taught intensive three-week courses, an experience which felt like drinking from a fire hose. The program widened Jossou’s views and he set his sights on a doctoral program with an emphasis on clean energy systems.

    A pivot to nuclear science

    While in Nigeria, Jossou learned of Professor Jerzy Szpunar at the University of Saskatchewan in Canada, who was looking for a student researcher to explore fuels and alloys for nuclear reactors. Before then, Jossou was lukewarm on nuclear energy, but the research sounded fascinating. The Fukushima, Japan, incident was recently in the rearview mirror and Jossou remembered his early determination to address his own country’s energy crisis. He was sold on the idea and graduated with a doctoral degree from the University of Saskatchewan on an international dean’s scholarship.

    Jossou’s postdoctoral work registered a brief stint at Brookhaven National Laboratory as staff scientist. He leaped at the opportunity to join MIT NSE as a way of realizing his research interest and teaching future engineers. “I would really like to conduct cutting-edge research in nuclear materials design and to pass on my knowledge to the next generation of scientists and engineers and there’s no better place to do that than at MIT,” Jossou says.

    Merging material science and computational modeling

    Jossou’s doctoral work on designing nuclear fuels for next-generation reactors forms the basis of research his lab is pursuing at MIT NSE. Nuclear reactors that were built in the 1950s and ’60s are getting a makeover in terms of improved accident tolerance. Reactors are not confined to one kind, either: We have micro reactors and are now considering ones using metallic nuclear fuels, Jossou points out. The diversity of options is enough to keep researchers busy testing materials fit for cladding, the lining that prevents corrosion of the fuel and release of radioactive fission products into the surrounding reactor coolant.

    The team is also investigating fuels that improve burn-up efficiencies, so they can last longer in the reactor. An intriguing approach has been to immobilize the gas bubbles that arise from the fission process, so they don’t grow and degrade the fuel.

    Since joining MIT in July 2023, Jossou is setting up a lab that optimizes the composition of accident-tolerant nuclear fuels. He is leaning on his materials science background and looping computer simulations and artificial intelligence in the mix.

    Computer simulations allow the researchers to narrow down the potential field of candidates, optimized for specific parameters, so they can synthesize only the most promising candidates in the lab. And AI’s predictive capabilities guide researchers on which materials composition to consider next. “We no longer depend on serendipity to choose our materials, our lab is based on rational materials design,” Jossou says, “we can rapidly design advanced nuclear fuels.”

    Advancing energy causes in Africa

    Now that he is at MIT, Jossou admits the view from the outside is different. He now harbors a different perspective on what Africa needs to address some of its challenges. “The starting point to solve our problems is not money; it needs to start with ideas,” he says, “we need to find highly skilled people who can actually solve problems.” That job involves adding economic value to the rich arrays of raw materials that the continent is blessed with. It frustrates Jossou that Niger, a country rich in raw material for uranium, has no nuclear reactors of its own. It ships most of its ore to France. “The path forward is to find a way to refine these materials in Africa and to be able to power the industries on that continent as well,” Jossou says.

    Jossou is determined to do his part to eliminate these roadblocks.

    Anchored in mentorship, Jossou’s solution aims to train talent from Africa in his own lab. He has applied for a MIT Global Experiences MISTI grant to facilitate travel and research studies for Ghanaian scientists. “The goal is to conduct research in our facility and perhaps add value to indigenous materials,” Jossou says.

    Adding value has been a consistent theme of Jossou’s career. He remembers wanting to become a neurosurgeon after reading “Gifted Hands,” moved by the personal story of the author, Ben Carson. As Jossou grew older, however, he realized that becoming a doctor wasn’t necessarily what he wanted. Instead, he was looking to add value. “What I wanted was really to take on a career that allows me to solve a societal problem.” The societal problem of clean and safe energy for all is precisely what Jossou is working on today. More

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    Making the clean energy transition work for everyone

    The clean energy transition is already underway, but how do we make sure it happens in a manner that is affordable, sustainable, and fair for everyone?

    That was the overarching question at this year’s MIT Energy Conference, which took place March 11 and 12 in Boston and was titled “Short and Long: A Balanced Approach to the Energy Transition.”

    Each year, the student-run conference brings together leaders in the energy sector to discuss the progress and challenges they see in their work toward a greener future. Participants come from research, industry, government, academia, and the investment community to network and exchange ideas over two whirlwind days of keynote talks, fireside chats, and panel discussions.

    Several participants noted that clean energy technologies are already cost-competitive with fossil fuels, but changing the way the world works requires more than just technology.

    “None of this is easy, but I think developing innovative new technologies is really easy compared to the things we’re talking about here, which is how to blend social justice, soft engineering, and systems thinking that puts people first,” Daniel Kammen, a distinguished professor of energy at the University of California at Berkeley, said in a keynote talk. “While clean energy has a long way to go, it is more than ready to transition us from fossil fuels.”

    The event also featured a keynote discussion between MIT President Sally Kornbluth and MIT’s Kyocera Professor of Ceramics Yet-Ming Chiang, in which Kornbluth discussed her first year at MIT as well as a recently announced, campus-wide effort to solve critical climate problems known as the Climate Project at MIT.

    “The reason I wanted to come to MIT was I saw that MIT has the potential to solve the world’s biggest problems, and first among those for me was the climate crisis,” Kornbluth said. “I’m excited about where we are, I’m excited about the enthusiasm of the community, and I think we’ll be able to make really impactful discoveries through this project.”

    Fostering new technologies

    Several panels convened experts in new or emerging technology fields to discuss what it will take for their solutions to contribute to deep decarbonization.

    “The fun thing and challenging thing about first-of-a-kind technologies is they’re all kind of different,” said Jonah Wagner, principal assistant director for industrial innovation and clean energy in the U.S. Office of Science and Technology Policy. “You can map their growth against specific challenges you expect to see, but every single technology is going to face their own challenges, and every single one will have to defy an engineering barrier to get off the ground.”

    Among the emerging technologies discussed was next-generation geothermal energy, which uses new techniques to extract heat from the Earth’s crust in new places.

    A promising aspect of the technology is that it can leverage existing infrastructure and expertise from the oil and gas industry. Many newly developed techniques for geothermal production, for instance, use the same drills and rigs as those used for hydraulic fracturing.

    “The fact that we have a robust ecosystem of oil and gas labor and technology in the U.S. makes innovation in geothermal much more accessible compared to some of the challenges we’re seeing in nuclear or direct-air capture, where some of the supply chains are disaggregated around the world,” said Gabrial Malek, chief of staff at the geothermal company Fervo Energy.

    Another technology generating excitement — if not net energy quite yet — is fusion, the process of combining, or fusing, light atoms together to form heavier ones for a net energy gain, in the same process that powers the sun. MIT spinout Commonwealth Fusion Systems (CFS) has already validated many aspects of its approach for achieving fusion power, and the company’s unique partnership with MIT was discussed in a panel on the industry’s progress.

    “We’re standing on the shoulders of decades of research from the scientific community, and we want to maintain those ties even as we continue developing our technology,” CFS Chief Science Officer Brandon Sorbom PhD ’17 said, noting that CFS is one of the largest company sponsors of research at MIT and collaborates with institutions around the world. “Engaging with the community is a really valuable lever to get new ideas and to sanity check our own ideas.”

    Sorbom said that as CFS advances fusion energy, the company is thinking about how it can replicate its processes to lower costs and maximize the technology’s impact around the planet.

    “For fusion to work, it has to work for everyone,” Sorbom said. “I think the affordability piece is really important. We can’t just build this technological jewel that only one class of nations can afford. It has to be a technology that can be deployed throughout the entire world.”

    The event also gave students — many from MIT — a chance to learn more about careers in energy and featured a startup showcase, in which dozens of companies displayed their energy and sustainability solutions.

    “More than 700 people are here from every corner of the energy industry, so there are so many folks to connect with and help me push my vision into reality,” says GreenLIB CEO Fred Rostami, whose company recycles lithium-ion batteries. “The good thing about the energy transition is that a lot of these technologies and industries overlap, so I think we can enable this transition by working together at events like this.”

    A focused climate strategy

    Kornbluth noted that when she came to MIT, a large percentage of students and faculty were already working on climate-related technologies. With the Climate Project at MIT, she wanted to help ensure the whole of those efforts is greater than the sum of its parts.

    The project is organized around six distinct missions, including decarbonizing energy and industry, empowering frontline communities, and building healthy, resilient cities. Kornbluth says the mission areas will help MIT community members collaborate around multidisciplinary challenges. Her team, which includes a committee of faculty advisors, has begun to search for the leads of each mission area, and Kornbluth said she is planning to appoint a vice president for climate at the Institute.

    “I want someone who has the purview of the whole Institute and will report directly to me to help make sure this project stays on track,” Kornbluth explained.

    In his conversation about the initiative with Kornbluth, Yet-Ming Chiang said projects will be funded based on their potential to reduce emissions and make the planet more sustainable at scale.

    “Projects should be very high risk, with very high impact,” Chiang explained. “They should have a chance to prove themselves, and those efforts should not be limited by resources, only by time.”

    In discussing her vision of the climate project, Kornbluth alluded to the “short and long” theme of the conference.

    “It’s about balancing research and commercialization,” Kornbluth said. “The climate project has a very variable timeframe, and I think universities are the sector that can think about the things that might be 30 years out. We have to think about the incentives across the entire innovation pipeline and how we can keep an eye on the long term while making sure the short-term things get out rapidly.” More

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    Study finds lands used for grazing can worsen or help climate change

    When it comes to global climate change, livestock grazing can be either a blessing or a curse, according to a new study, which offers clues on how to tell the difference.

    If managed properly, the study shows, grazing can actually increase the amount of carbon from the air that gets stored in the ground and sequestered for the long run. But if there is too much grazing, soil erosion can result, and the net effect is to cause more carbon losses, so that the land becomes a net carbon source, instead of a carbon sink. And the study found that the latter is far more common around the world today.

    The new work, published today in the journal Nature Climate Change, provides ways to determine the tipping point between the two, for grazing lands in a given climate zone and soil type. It also provides an estimate of the total amount of carbon that has been lost over past decades due to livestock grazing, and how much could be removed from the atmosphere if grazing optimization management implemented. The study was carried out by Cesar Terrer, an assistant professor of civil and environmental engineering at MIT; Shuai Ren, a PhD student at the Chinese Academy of Sciences whose thesis is co-supervised by Terrer; and four others.

    “This has been a matter of debate in the scientific literature for a long time,” Terrer says. “In general experiments, grazing decreases soil carbon stocks, but surprisingly, sometimes grazing increases soil carbon stocks, which is why it’s been puzzling.”

    What happens, he explains, is that “grazing could stimulate vegetation growth through easing resource constraints such as light and nutrients, thereby increasing root carbon inputs to soils, where carbon can stay there for centuries or millennia.”

    But that only works up to a certain point, the team found after a careful analysis of 1,473 soil carbon observations from different grazing studies from many locations around the world. “When you cross a threshold in grazing intensity, or the amount of animals grazing there, that is when you start to see sort of a tipping point — a strong decrease in the amount of carbon in the soil,” Terrer explains.

    That loss is thought to be primarily from increased soil erosion on the denuded land. And with that erosion, Terrer says, “basically you lose a lot of the carbon that you have been locking in for centuries.”

    The various studies the team compiled, although they differed somewhat, essentially used similar methodology, which is to fence off a portion of land so that livestock can’t access it, and then after some time take soil samples from within the enclosure area, and from comparable nearby areas that have been grazed, and compare the content of carbon compounds.

    “Along with the data on soil carbon for the control and grazed plots,” he says, “we also collected a bunch of other information, such as the mean annual temperature of the site, mean annual precipitation, plant biomass, and properties of the soil, like pH and nitrogen content. And then, of course, we estimate the grazing intensity — aboveground biomass consumed, because that turns out to be the key parameter.”  

    With artificial intelligence models, the authors quantified the importance of each of these parameters, those drivers of intensity — temperature, precipitation, soil properties — in modulating the sign (positive or negative) and magnitude of the impact of grazing on soil carbon stocks. “Interestingly, we found soil carbon stocks increase and then decrease with grazing intensity, rather than the expected linear response,” says Ren.

    Having developed the model through AI methods and validated it, including by comparing its predictions with those based on underlying physical principles, they can then apply the model to estimating both past and future effects. “In this case,” Terrer says, “we use the model to quantify the historical loses in soil carbon stocks from grazing. And we found that 46 petagrams [billion metric tons] of soil carbon, down to a depth of one meter, have been lost in the last few decades due to grazing.”

    By way of comparison, the total amount of greenhouse gas emissions per year from all fossil fuels is about 10 petagrams, so the loss from grazing equals more than four years’ worth of all the world’s fossil emissions combined.

    What they found was “an overall decline in soil carbon stocks, but with a lot of variability.” Terrer says. The analysis showed that the interplay between grazing intensity and environmental conditions such as temperature could explain the variability, with higher grazing intensity and hotter climates resulting in greater carbon loss. “This means that policy-makers should take into account local abiotic and biotic factors to manage rangelands efficiently,” Ren notes. “By ignoring such complex interactions, we found that using IPCC [Intergovernmental Panel on Climate Change] guidelines would underestimate grazing-induced soil carbon loss by a factor of three globally.”

    Using an approach that incorporates local environmental conditions, the team produced global, high-resolution maps of optimal grazing intensity and the threshold of intensity at which carbon starts to decrease very rapidly. These maps are expected to serve as important benchmarks for evaluating existing grazing practices and provide guidance to local farmers on how to effectively manage their grazing lands.

    Then, using that map, the team estimated how much carbon could be captured if all grazing lands were limited to their optimum grazing intensity. Currently, the authors found, about 20 percent of all pasturelands have crossed the thresholds, leading to severe carbon losses. However, they found that under the optimal levels, global grazing lands would sequester 63 petagrams of carbon. “It is amazing,” Ren says. “This value is roughly equivalent to a 30-year carbon accumulation from global natural forest regrowth.”

    That would be no simple task, of course. To achieve optimal levels, the team found that approximately 75 percent of all grazing areas need to reduce grazing intensity. Overall, if the world seriously reduces the amount of grazing, “you have to reduce the amount of meat that’s available for people,” Terrer says.

    “Another option is to move cattle around,” he says, “from areas that are more severely affected by grazing intensity, to areas that are less affected. Those rotations have been suggested as an opportunity to avoid the more drastic declines in carbon stocks without necessarily reducing the availability of meat.”

    This study didn’t delve into these social and economic implications, Terrer says. “Our role is to just point out what would be the opportunity here. It shows that shifts in diets can be a powerful way to mitigate climate change.”

    “This is a rigorous and careful analysis that provides our best look to date at soil carbon changes due to livestock grazing practiced worldwide,” say Ben Bond-Lamberty, a terrestrial ecosystem research scientist at Pacific Northwest National Laboratory, who was not associated with this work. “The authors’ analysis gives us a unique estimate of soil carbon losses due to grazing and, intriguingly, where and how the process might be reversed.”

    He adds: “One intriguing aspect to this work is the discrepancies between its results and the guidelines currently used by the IPCC — guidelines that affect countries’ commitments, carbon-market pricing, and policies.” However, he says, “As the authors note, the amount of carbon historically grazed soils might be able to take up is small relative to ongoing human emissions. But every little bit helps!”

    “Improved management of working lands can be a powerful tool to combat climate change,” says Jonathan Sanderman, carbon program director of the Woodwell Climate Research Center in Falmouth, Massachusetts, who was not associated with this work. He adds, “This work demonstrates that while, historically, grazing has been a large contributor to climate change, there is significant potential to decrease the climate impact of livestock by optimizing grazing intensity to rebuild lost soil carbon.”

    Terrer states that for now, “we have started a new study, to evaluate the consequences of shifts in diets for carbon stocks. I think that’s the million-dollar question: How much carbon could you sequester, compared to business as usual, if diets shift to more vegan or vegetarian?” The answers will not be simple, because a shift to more vegetable-based diets would require more cropland, which can also have different environmental impacts. Pastures take more land than crops, but produce different kinds of emissions. “What’s the overall impact for climate change? That is the question we’re interested in,” he says.

    The research team included Juan Li, Yingfao Cao, Sheshan Yang, and Dan Liu, all with the  Chinese Academy of Sciences. The work was supported by the Second Tibetan Plateau Scientific Expedition and Research Program, and the Science and Technology Major Project of Tibetan Autonomous Region of China. More