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    Pioneering the future of materials extraction

    The next time you cook pasta, imagine that you are cooking spaghetti, rigatoni, and seven other varieties all together, and they need to be separated onto 10 different plates before serving. A colander can remove the water — but you still have a mound of unsorted noodles. Now imagine that this had to be done for thousands of tons of pasta a day. That gives you an idea of the scale of the problem facing Brendan Smith PhD ’18, co-founder and CEO of SiTration, a startup formed out of MIT’s Department of Materials Science and Engineering (DMSE) in 2020. SiTration, which raised $11.8 million in seed capital led by venture capital firm 2150 earlier this month, is revolutionizing the extraction and refining of copper, cobalt, nickel, lithium, precious metals, and other materials critical to manufacturing clean-energy technologies such as electric motors, wind turbines, and batteries. Its initial target applications are recovering the materials from complex mining feed streams, spent lithium-ion batteries from electric vehicles, and various metals refining processes. The company’s breakthrough lies in a new silicon membrane technology that can be adjusted to efficiently recover disparate materials, providing a more sustainable and economically viable alternative to conventional, chemically intensive processes. Think of a colander with adjustable pores to strain different types of pasta. SiTration’s technology has garnered interest from industry players, including mining giant Rio Tinto. Some observers may question whether targeting such different industries could cause the company to lose focus. “But when you dig into these markets, you discover there is actually a significant overlap in how all of these materials are recovered, making it possible for a single solution to have impact across verticals,” Smith says.Powering up materials recoveryConventional methods of extracting critical materials in mining, refining, and recycling lithium-ion batteries involve heavy use of chemicals and heat, which harm the environment. Typically, raw ore from mines or spent batteries are ground into fine particles before being dissolved in acid or incinerated in a furnace. Afterward, they undergo intensive chemical processing to separate and purify the valuable materials. “It requires as much as 10 tons of chemical input to produce one ton of critical material recovered from the mining or battery recycling feedstock,” says Smith. Operators can then sell the recaptured materials back into the supply chain, but suffer from wide swings in profitability due to uncertain market prices. Lithium prices have been the most volatile, having surged more than 400 percent before tumbling back to near-original levels in the past two years. Despite their poor economics and negative environmental impact, these processes remain the state of the art today. By contrast, SiTration is electrifying the critical-materials recovery process, improving efficiency, producing less chemical waste, and reducing the use of chemicals and heat. What’s more, the company’s processing technology is built to be highly adaptable, so it can handle all kinds of materials. The core technology is based on work done at MIT to develop a novel type of membrane made from silicon, which is durable enough to withstand harsh chemicals and high temperatures while conducting electricity. It’s also highly tunable, meaning it can be modified or adjusted to suit different conditions or target specific materials. SiTration’s technology also incorporates electro-extraction, a technique that uses electrochemistry to further isolate and extract specific target materials. This powerful combination of methods in a single system makes it more efficient and effective at isolating and recovering valuable materials, Smith says. So depending on what needs to be separated or extracted, the filtration and electro-extraction processes are adjusted accordingly. “We can produce membranes with pore sizes from the molecular scale up to the size of a human hair in diameter, and everything in between. Combined with the ability to electrify the membrane and separate based on a material’s electrochemical properties, this tunability allows us to target a vast array of different operations and separation applications across industrial fields,” says Smith. Efficient access to materials like lithium, cobalt, and copper — and precious metals like platinum, gold, silver, palladium, and rare-earth elements — is key to unlocking innovation in business and sustainability as the world moves toward electrification and away from fossil fuels.“This is an era when new materials are critical,” says Professor Jeffrey Grossman, co-founder and chief scientist of SiTration and the Morton and Claire Goulder and Family Professor in Environmental Systems at DMSE. “For so many technologies, they’re both the bottleneck and the opportunity, offering tremendous potential for non-incremental advances. And the role they’re having in commercialization and in entrepreneurship cannot be overstated.”SiTration’s commercial frontierSmith became interested in separation technology in 2013 as a PhD student in Grossman’s DMSE research group, which has focused on the design of new membrane materials for a range of applications. The two shared a curiosity about separation of critical materials and a hunger to advance the technology. After years of study under Grossman’s mentorship, and with support from several MIT incubators and foundations including the Abdul Latif Jameel Water and Food Systems Lab’s Solutions Program, the Deshpande Center for Technological Innovation, the Kavanaugh Fellowship, MIT Sandbox, and Venture Mentoring Service, Smith was ready to officially form SiTration in 2020. Grossman has a seat on the board and plays an active role as a strategic and technical advisor. Grossman is involved in several MIT spinoffs and embraces the different imperatives of research versus commercialization. “At SiTration, we’re driving this technology to work at scale. There’s something super exciting about that goal,” he says. “The challenges that come with scaling are very different than the challenges that come in a university lab.” At the same time, although not every research breakthrough becomes a commercial product, open-ended, curiosity-driven knowledge pursuit holds its own crucial value, he adds.It has been rewarding for Grossman to see his technically gifted student and colleague develop a host of other skills the role of CEO demands. Getting out to the market and talking about the technology with potential partners, putting together a dynamic team, discovering the challenges facing industry, drumming up support, early on — those became the most pressing activities on Smith’s agenda. “What’s most fun to me about being a CEO of an early-stage startup is that there are 100 different factors, most people-oriented, that you have to navigate every day. Each stakeholder has different motivations and objectives. And you basically try to fit that all together, to create value for our partners and customers, the company, and for society,” says Smith. “You start with just an idea, and you have to keep leveraging that to form a more and more tangible product, to multiply and progress commercial relationships, and do it all at an ever-expanding scale.” MIT DNA runs deep in the nine-person company, with DMSE grad and former Grossman student Jatin Patil as director of product; Ahmed Helal, from MIT’s Department of Mechanical Engineering, as vice president of research and development; Daniel Bregante, from the Department of Chemistry, as VP of technology; and Sarah Melvin, from the departments of Physics and Political Science, as VP of strategy and operations. Melvin is the first hire devoted to business development. Smith plans to continue expanding the team following the closing of the company’s seed round.  Strategic alliancesBeing a good communicator was important when it came to securing funding, Smith says. SiTration received $2.35 million in pre-seed funding in 2022 led by Azolla Ventures, which reserves its $239 million in investment capital for startups that would not otherwise easily obtain funding. “We invest only in solution areas that can achieve gigaton-scale climate impact by 2050,” says Matthew Nordan, a general partner at Azolla and now SiTration board member. The MIT-affiliated E14 Fund also contributed to the pre-seed round; Azolla and E14 both participated in the recent seed funding round. “Brendan demonstrated an extraordinary ability to go from being a thoughtful scientist to a business leader and thinker who has punched way above his weight in engaging with customers and recruiting a well-balanced team and navigating tricky markets,” says Nordan. One of SiTration’s first partnerships is with Rio Tinto, one of the largest mining companies in the world. As SiTration evaluated various uses cases in its early days, identifying critical materials as its target market, Rio Tinto was looking for partners to recover valuable metals such as cobalt and copper from the wastewater generated at mines. These metals were typically trapped in the water, creating harmful waste and resulting in lost revenue. “We thought this was a great innovation challenge and posted it on our website to scout for companies to partner with who can help us solve this water challenge,” said Nick Gurieff, principal advisor for mine closure, in an interview with MIT’s Industrial Liaison Program in 2023. At SiTration, mining was not yet a market focus, but Smith couldn’t help noticing that Rio Tinto’s needs were in alignment with what his young company offered. SiTration submitted its proposal in August 2022. Gurieff said SiTration’s tunable membrane set it apart. The companies formed a business partnership in June 2023, with SiTration adjusting its membrane to handle mine wastewater and incorporating Rio Tinto feedback to refine the technology. After running tests with water from mine sites, SiTration will begin building a small-scale critical-materials recovery unit, followed by larger-scale systems processing up to 100 cubic meters of water an hour.SiTration’s focused technology development with Rio Tinto puts it in a good position for future market growth, Smith says. “Every ounce of effort and resource we put into developing our product is geared towards creating real-world value. Having an industry-leading partner constantly validating our progress is a tremendous advantage.”It’s a long time from the days when Smith began tinkering with tiny holes in silicon in Grossman’s DMSE lab. Now, they work together as business partners who are scaling up technology to meet a global need. Their joint passion for applying materials innovation to tough problems has served them well. “Materials science and engineering is an engine for a lot of the innovation that is happening today,” Grossman says. “When you look at all of the challenges we face to make the transition to a more sustainable planet, you realize how many of these are materials challenges.” More

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    Two MIT films nominated for New England Emmy Awards

    Two films produced by MIT were honored with Emmy nominations by the National Academy of Television Arts & Sciences Boston/New England Chapter. Both “We Are the Forest” and “No Drop to Spare” illustrate international conversations the MIT community is having about the environment and climate change.“We Are the Forest,” produced by MIT Video Productions (MVP) at MIT Open Learning, was one of six nominees in the Education/Schools category. The documentary highlights the cultural and scientific exchange of the MIT Festival Jazz Ensemble, MIT Wind Ensemble, and MIT Vocal Jazz Ensemble in the Brazilian Amazon. The excursion depicted in the film was part of the ongoing work of Frederick Harris Jr., MIT director of wind and jazz ensembles and senior lecturer in music, to combine Brazilian music and environmental research.“No Drop to Spare,” created by the Department of Mechanical Engineering (MechE), was nominated in the Environment/Science and Video Essayist categories. The film, produced by John Freidah, MechE senior producer and creative lead, follows a team of researchers from the K. Lisa Yang Global Engineering and Research (GEAR) Center working in Kenya, Morocco, and Jordan to deploy affordable, user-driven smart irrigation technology.“We Are the Forest” tells the story of 80 MIT student musicians who traveled to Manaus, Brazil in March 2023. Together with Indigenous Brazilian musicians and activists, the students played music, created instruments with found objects from the rainforest, and connected their musical practice to nature and culture. The trip and the documentary culminated with the concert “Hearing Amazônia: Art and Resistance.”“We have an amazing team who are excited to tell the stories of so many great things that happen at MIT,” says Clayton Hainsworth, director for MVP. “It’s a true pleasure when we get to partner with the Institute’s community on these video projects — from Fred [Harris], with his desire for outreach of the music curriculum, giving students new perspectives and getting beyond the lab; to students getting to experience the world and seeing how that affects their next steps as they go out and make an impact.”The documentary was produced by Hainsworth, directed by Jean Dunoyer, staff editor at MVP, and filmed by Myles Lowery, field production videographer at MVP. Hainsworth credits Dunoyer with refining the story’s main themes: the universality of music as a common human language, and the ways that Indigenous communities can teach and inform the rest of the globe about the environment and the challenges we are all facing.“The film highlights the reach of how MIT touches the world and, more importantly, how the world touches MIT,” says Hainsworth, adding that the work was generously supported by A. Neil Pappalardo ’64 and Jane Pappalardo. “No Drop to Spare” evoked a similar sentiment from Freidah. “What I liked about this story was the potential for great impact,” says Freidah, discussing the MechE film’s production process. “It was global, it was being piloted in three different places in the world, with three different end users, and had three different applications. You sort of go in with an idea in mind of what the story might be, then things bubble up. In this story, as with so many stories, what rose to the top was the students and the impact they were having on the real world and end users.” Freidah has worked with Amos Winter SM ’05, PhD ’11, associate professor of mechanical engineering and MIT GEAR Center principal investigator, to highlight other impact global projects in the past, including producing a video in 2016. That film, “Water is Life,” explores the development of low-cost desalination systems in India. While the phrase “it’s an honor to be nominated” might seem cliched, it remains often used because the sentiment almost always rings true. Although neither film triumphed at this year’s awards ceremony, Freidah says there’s much to be celebrated in the final product. “Seeing the effect this piece had, and how it highlighted our students, that’s the success story — but it’s always nice also to receive recognition from outside.”The 47th Boston/New England Emmy Awards Ceremony took place on June 8 at the Marriott Boston Copley Place. A list of nominees and winners can be found on the National Academy of Television Arts and Sciences Boston/New England Chapter website.  More

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    Sophia Chen: It’s our duty to make the world better through empathy, patience, and respect

    Sophia Chen, a fifth-year senior double majoring in mechanical engineering and art and design, learned about MIT D-Lab when she was a Florida middle schooler. She drove with her family from their home in Clearwater to Tampa to an MIT informational open house for prospective students. There, she heard about a moringa seed press that had been developed by D-Lab students. Those students, Kwami Williams ’12 and Emily Cunningham (a cross-registered Harvard University student), went on to found MoringaConnect with a goal of increasing Ghanaian farmer incomes. Over the past 12 years, the company has done just that, sometimes by a factor of 10 or more, by selling to wholesalers and establishing their own line of moringa skin and hair care products, as well as nutritional supplements and teas.“I remember getting chills,” says Sophia. “I was so in awe. MIT had always been my dream college growing up, but hearing this particular story truly cemented that dream. I even talked about D-Lab during my admissions interview. Once I came to MIT, I knew I had to take a D-Lab class — and now, at the end of my five years, I’ve taken four.”Taking four D-Lab classes during her undergraduate years may make Sophia exceptional, though not unusual. Of the nearly 4,000 enrollments in D-Lab classes over the past 22 years, as many as 20 percent took at least two classes, and many take three or more by the time the graduate. For Sophia, her D-Lab classes were a logical progression that both confirmed and expanded her career goals in global medicine.Centering the role of project community partnersSophia’s first D-Lab class was 2.722J / EC.720 (D-Lab: Design). Like all D-Lab classes, D-Lab: Design is project-based and centers the knowledge and contributions of each project’s community partner. Her team worked with a group in Uganda called Safe Water Harvesters on a project aimed at creating a solar-powered atmospheric water harvester using desiccants. They focused on early research and development for the desiccant technology by running tests for vapor absorption. Safe Water Harvesters designed the parameters and goals of the project and collaborated with the students remotely throughout the semester.Safe Water Harvesters’ role in the project was key to the project’s success. “At D-Lab, I learned the importance of understanding that solutions in international development must come from the voices and needs of people whom the intervention is trying to serve,” she says. “Some of the first questions we were taught to ask are ‘what materials and manufacturing processes are available?’ and ‘how is this technology going to be maintained by the community?’”The link between water access and gender inequityElecting to join the water harvesting project in Uganda was no accident. The previous summer, Sophia had interned with a startup targeting the spread of cholera in developing areas by engineering a new type of rapid detection technology that would sample from users’ local water sources. From there, she joined Professor Amos Winter’s Global Engineering and Research (GEAR) Lab as an Undergraduate Research Opportunities Program student and worked on a point-of-use desalination unit for households in India. Taking EC.715 (D-Lab: Water, Sanitation, and Hygiene) was a logical next step for Sophia. “This class was life-changing,” she says. “I was already passionate about clean water access and global resource equity, but I quickly discovered the complexity of WASH not just as an issue of poverty but as an issue of gender.” She joined a project spearheaded by a classmate from Nepal, which aimed to address the social taboos surrounding menstruation among Nepalese schoolgirls.“This class and project helped me realize that water insecurity and gender inequality — especially gender-based violence — ​are highly intertwined,” comments Sophia. This plays out in a variety of ways. Where there is poor sanitation infrastructure in schools, girls often miss classes or drop out altogether when menstruating. And where water is scarce, women and girls often walk miles to collect water to accommodate daily drinking, cooking, and hygiene needs. During this trek, they are vulnerable to assault and the pressure to engage in transactional sex at water access points.“It became clear to me that women are disproportionately affected by water insecurity, and that water is key to understanding women’s empowerment,” comments Sophia, “and that I wanted to keep learning about the field of development and how it intersects with gender!”So, in fall 2023, Sophia took both 11.025/EC.701 (D-Lab: Development) and WGS.277/EC.718 (D-Lab: Gender and Development). In D-Lab: Development, her team worked with Tatirano, a nongovernmental organization in Madagascar, to develop a vapor-condensing chamber for a water desalination system, a prototype they were able to test and iterate in Madagascar at the end of the semester.Getting out into the world through D-Lab fieldwork“Fieldwork with D-Lab is an eye-opening experience that anyone could benefit from,” says Sophia. “It’s easy to get lost in the MIT and tech bubble. But there’s a whole world out there with people who live such different lives than many of us, and we can learn even more from them than we can from our psets.”For Sophia’s D-Lab: Gender and Development class, she worked with the Society Empowerment Project in Kenya, ultimately traveling there during MIT’s Independent Activities Period last January. In Kenya, she worked with her team to run a workshop with teen parents to identify risk factors prior to pregnancy and postpartum challenges, in order to then ideate and develop solutions such as social programs. “Through my fieldwork in Kenya and Madagascar,” says Sophia, “it became clear how important it is to create community-based solutions that are led and maintained by community members. Solutions need community input, leadership, and trust. Ultimately, this is the only way to have long-lasting, high-impact, sustainable change. One of my D-Lab trip leaders said that you cannot import solutions. I hope all engineers recognize the significance of this statement. It is our duty as engineers and scientists to make the world a better place while carrying values of empathy, patience, and respect.”Pursuing passion and purpose at the intersection of medicine, technology, and policyAfter graduation in June, Sophia will be traveling to South Africa through MISTI Africa to help with a clinical trial and community outreach. She then intends to pursue a master’s in global health and apply to medical school, with the goal of working in global health at the intersection of medicine, technology, and policy.“It is no understatement to say that D-Lab has played a central role in helping me discover what I’m passionate about and what my purpose is in life,” she says. “I hope to dedicate my career towards solving global health inequity and gender inequality.” ​ More

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    Two MIT PhD students awarded J-WAFS fellowships for their research on water

    Since 2014, the Abdul Latif Jameel Water and Food Systems Lab (J-WAFS) has advanced interdisciplinary research aimed at solving the world’s most pressing water and food security challenges to meet human needs. In 2017, J-WAFS established the Rasikbhai L. Meswani Water Solutions Fellowship and the J-WAFS Graduate Student Fellowship. These fellowships provide support to outstanding MIT graduate students who are pursuing research that has the potential to improve water and food systems around the world. Recently, J-WAFS awarded the 2024-25 fellowships to Jonathan Bessette and Akash Ball, two MIT PhD students dedicated to addressing water scarcity by enhancing desalination and purification processes. This work is of important relevance since the world’s freshwater supply has been steadily depleting due to the effects of climate change. In fact, one-third of the global population lacks access to safe drinking water. Bessette and Ball are focused on designing innovative solutions to enhance the resilience and sustainability of global water systems. To support their endeavors, J-WAFS will provide each recipient with funding for one academic semester for continued research and related activities.“This year, we received many strong fellowship applications,” says J-WAFS executive director Renee J. Robins. “Bessette and Ball both stood out, even in a very competitive pool of candidates. The award of the J-WAFS fellowships to these two students underscores our confidence in their potential to bring transformative solutions to global water challenges.”2024-25 Rasikbhai L. Meswani Fellowship for Water SolutionsThe Rasikbhai L. Meswani Fellowship for Water Solutions is a doctoral fellowship for students pursuing research related to water and water supply at MIT. The fellowship is made possible by Elina and Nikhil Meswani and family. Jonathan Bessette is a doctoral student in the Global Engineering and Research (GEAR) Center within the Department of Mechanical Engineering at MIT, advised by Professor Amos Winter. His research is focused on water treatment systems for the developing world, mainly desalination, or the process in which salts are removed from water. Currently, Bessette is working on designing and constructing a low-cost, deployable, community-scale desalination system for humanitarian crises.In arid and semi-arid regions, groundwater often serves as the sole water source, despite its common salinity issues. Many remote and developing areas lack reliable centralized power and water systems, making brackish groundwater desalination a vital, sustainable solution for global water scarcity. “An overlooked need for desalination is inland groundwater aquifers, rather than in coastal areas,” says Bessette. “This is because much of the population lives far enough from a coast that seawater desalination could never reach them. My work involves designing low-cost, sustainable, renewable-powered desalination technologies for highly constrained situations, such as drinking water for remote communities,” he adds.To achieve this goal, Bessette developed a batteryless, renewable electrodialysis desalination system. The technology is energy-efficient, conserves water, and is particularly suited for challenging environments, as it is decentralized and sustainable. The system offers significant advantages over the conventional reverse osmosis method, especially in terms of reduced energy consumption for treating brackish water. Highlighting Bessette’s capacity for engineering insight, his advisor noted the “simple and elegant solution” that Bessette and a staff engineer, Shane Pratt, devised that negated the need for the system to have large batteries. Bessette is now focusing on simplifying the system’s architecture to make it more reliable and cost-effective for deployment in remote areas.Growing up in upstate New York, Bessette completed a bachelor’s degree at the State University of New York at Buffalo. As an undergrad, he taught middle and high school students in low-income areas of Buffalo about engineering and sustainability. However, he cited his junior-year travel to India and his experience there measuring water contaminants in rural sites as cementing his dedication to a career addressing food, water, and sanitation challenges. In addition to his doctoral research, his commitment to these goals is further evidenced by another project he is pursuing, funded by a J-WAFS India grant, that uses low-cost, remote sensors to better understand water fetching practices. Bessette is conducting this work with fellow MIT student Gokul Sampath in order to help families in rural India gain access to safe drinking water.2024-25 J-WAFS Graduate Student Fellowship for Water and Food SolutionsThe J-WAFS Graduate Student Fellowship is supported by the J-WAFS Research Affiliate Program, which offers companies the opportunity to engage with MIT on water and food research. Current fellowship support was provided by two J-WAFS Research Affiliates: Xylem, a leading U.S.-based provider of water treatment and infrastructure solutions, and GoAigua, a Spanish company at the forefront of digital transformation in the water industry through innovative solutions. Akash Ball is a doctoral candidate in the Department of Chemical Engineering, advised by Professor Heather Kulik. His research focuses on the computational discovery of novel functional materials for energy-efficient ion separation membranes with high selectivity. Advanced membranes like these are increasingly needed for applications such as water desalination, battery recycling, and removal of heavy metals from industrial wastewater. “Climate change, water pollution, and scarce freshwater reserves cause severe water distress for about 4 billion people annually, with 2 billion in India and China’s semiarid regions,” Ball notes. “One potential solution to this global water predicament is the desalination of seawater, since seawater accounts for 97 percent of all water on Earth.”Although several commercial reverse osmosis membranes are currently available, these membranes suffer several problems, like slow water permeation, permeability-selectivity trade-off, and high fabrication costs. Metal-organic frameworks (MOFs) are porous crystalline materials that are promising candidates for highly selective ion separation with fast water transport due to high surface area, the presence of different pore windows, and the tunability of chemical functionality.In the Kulik lab, Ball is developing a systematic understanding of how MOF chemistry and pore geometry affect water transport and ion rejection rates. By the end of his PhD, Ball plans to identify existing, best-performing MOFs with unparalleled water uptake using machine learning models, propose novel hypothetical MOFs tailored to specific ion separations from water, and discover experimental design rules that enable the synthesis of next-generation membranes.  Ball’s advisor praised the creativity he brings to his research, and his leadership skills that benefit her whole lab. Before coming to MIT, Ball obtained a master’s degree in chemical engineering from the Indian Institute of Technology (IIT) Bombay and a bachelor’s degree in chemical engineering from Jadavpur University in India. During a research internship at IIT Bombay in 2018, he worked on developing a technology for in situ arsenic detection in water. Like Bessette, he noted the impact of this prior research experience on his interest in global water challenges, along with his personal experience growing up in an area in India where access to safe drinking water was not guaranteed. More

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    Exploring frontiers of mechanical engineering

    From cutting-edge robotics, design, and bioengineering to sustainable energy solutions, ocean engineering, nanotechnology, and innovative materials science, MechE students and their advisors are doing incredibly innovative work. The graduate students highlighted here represent a snapshot of the great work in progress this spring across the Department of Mechanical Engineering, and demonstrate the ways the future of this field is as limitless as the imaginations of its practitioners.Democratizing design through AILyle RegenwetterHometown: Champaign, IllinoisAdvisor: Assistant Professor Faez AhmedInterests: Food, climbing, skiing, soccer, tennis, cookingLyle Regenwetter finds excitement in the prospect of generative AI to “democratize” design and enable inexperienced designers to tackle complex design problems. His research explores new training methods through which generative AI models can be taught to implicitly obey design constraints and synthesize higher-performing designs. Knowing that prospective designers often have an intimate knowledge of the needs of users, but may otherwise lack the technical training to create solutions, Regenwetter also develops human-AI collaborative tools that allow AI models to interact and support designers in popular CAD software and real design problems. Solving a whale of a problem Loïcka BailleHometown: L’Escale, FranceAdvisor: Daniel ZitterbartInterests: Being outdoors — scuba diving, spelunking, or climbing. Sailing on the Charles River, martial arts classes, and playing volleyballLoïcka Baille’s research focuses on developing remote sensing technologies to study and protect marine life. Her main project revolves around improving onboard whale detection technology to prevent vessel strikes, with a special focus on protecting North Atlantic right whales. Baille is also involved in an ongoing study of Emperor penguins. Her team visits Antarctica annually to tag penguins and gather data to enhance their understanding of penguin population dynamics and draw conclusions regarding the overall health of the ecosystem.Water, water anywhereCarlos Díaz-MarínHometown: San José, Costa RicaAdvisor: Professor Gang Chen | Former Advisor: Professor Evelyn WangInterests: New England hiking, biking, and dancingCarlos Díaz-Marín designs and synthesizes inexpensive salt-polymer materials that can capture large amounts of humidity from the air. He aims to change the way we generate potable water from the air, even in arid conditions. In addition to water generation, these salt-polymer materials can also be used as thermal batteries, capable of storing and reusing heat. Beyond the scientific applications, Díaz-Marín is excited to continue doing research that can have big social impacts, and that finds and explains new physical phenomena. As a LatinX person, Díaz-Marín is also driven to help increase diversity in STEM.Scalable fabrication of nano-architected materialsSomayajulu DhulipalaHometown: Hyderabad, IndiaAdvisor: Assistant Professor Carlos PortelaInterests: Space exploration, taekwondo, meditation.Somayajulu Dhulipala works on developing lightweight materials with tunable mechanical properties. He is currently working on methods for the scalable fabrication of nano-architected materials and predicting their mechanical properties. The ability to fine-tune the mechanical properties of specific materials brings versatility and adaptability, making these materials suitable for a wide range of applications across multiple industries. While the research applications are quite diverse, Dhulipala is passionate about making space habitable for humanity, a crucial step toward becoming a spacefaring civilization.Ingestible health-care devicesJimmy McRaeHometown: Woburn, MassachusettsAdvisor: Associate Professor Giovani TraversoInterests: Anything basketball-related: playing, watching, going to games, organizing hometown tournaments Jimmy McRae aims to drastically improve diagnostic and therapeutic capabilities through noninvasive health-care technologies. His research focuses on leveraging materials, mechanics, embedded systems, and microfabrication to develop novel ingestible electronic and mechatronic devices. This ranges from ingestible electroceutical capsules that modulate hunger-regulating hormones to devices capable of continuous ultralong monitoring and remotely triggerable actuations from within the stomach. The principles that guide McRae’s work to develop devices that function in extreme environments can be applied far beyond the gastrointestinal tract, with applications for outer space, the ocean, and more.Freestyle BMX meets machine learningEva NatesHometown: Narberth, Pennsylvania Advisor: Professor Peko HosoiInterests: Rowing, running, biking, hiking, bakingEva Nates is working with the Australian Cycling Team to create a tool to classify Bicycle Motocross Freestyle (BMX FS) tricks. She uses a singular value decomposition method to conduct a principal component analysis of the time-dependent point-tracking data of an athlete and their bike during a run to classify each trick. The 2024 Olympic team hopes to incorporate this tool in their training workflow, and Nates worked alongside the team at their facilities on the Gold Coast of Australia during MIT’s Independent Activities Period in January.Augmenting Astronauts with Wearable Limbs Erik BallesterosHometown: Spring, TexasAdvisor: Professor Harry AsadaInterests: Cosplay, Star Wars, Lego bricksErik Ballesteros’s research seeks to support astronauts who are conducting planetary extravehicular activities through the use of supernumerary robotic limbs (SuperLimbs). His work is tailored toward design and control manifestation to assist astronauts with post-fall recovery, human-leader/robot-follower quadruped locomotion, and coordinated manipulation between the SuperLimbs and the astronaut to perform tasks like excavation and sample handling.This article appeared in the Spring 2024 edition of the Department of Mechanical Engineering’s magazine, MechE Connects.  More

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    How light can vaporize water without the need for heat

    It’s the most fundamental of processes — the evaporation of water from the surfaces of oceans and lakes, the burning off of fog in the morning sun, and the drying of briny ponds that leaves solid salt behind. Evaporation is all around us, and humans have been observing it and making use of it for as long as we have existed.

    And yet, it turns out, we’ve been missing a major part of the picture all along.

    In a series of painstakingly precise experiments, a team of researchers at MIT has demonstrated that heat isn’t alone in causing water to evaporate. Light, striking the water’s surface where air and water meet, can break water molecules away and float them into the air, causing evaporation in the absence of any source of heat.

    The astonishing new discovery could have a wide range of significant implications. It could help explain mysterious measurements over the years of how sunlight affects clouds, and therefore affect calculations of the effects of climate change on cloud cover and precipitation. It could also lead to new ways of designing industrial processes such as solar-powered desalination or drying of materials.

    The findings, and the many different lines of evidence that demonstrate the reality of the phenomenon and the details of how it works, are described today in the journal PNAS, in a paper by Carl Richard Soderberg Professor of Power Engineering Gang Chen, postdocs Guangxin Lv and Yaodong Tu, and graduate student James Zhang.

    The authors say their study suggests that the effect should happen widely in nature— everywhere from clouds to fogs to the surfaces of oceans, soils, and plants — and that it could also lead to new practical applications, including in energy and clean water production. “I think this has a lot of applications,” Chen says. “We’re exploring all these different directions. And of course, it also affects the basic science, like the effects of clouds on climate, because clouds are the most uncertain aspect of climate models.”

    A newfound phenomenon

    The new work builds on research reported last year, which described this new “photomolecular effect” but only under very specialized conditions: on the surface of specially prepared hydrogels soaked with water. In the new study, the researchers demonstrate that the hydrogel is not necessary for the process; it occurs at any water surface exposed to light, whether it’s a flat surface like a body of water or a curved surface like a droplet of cloud vapor.

    Because the effect was so unexpected, the team worked to prove its existence with as many different lines of evidence as possible. In this study, they report 14 different kinds of tests and measurements they carried out to establish that water was indeed evaporating — that is, molecules of water were being knocked loose from the water’s surface and wafted into the air — due to the light alone, not by heat, which was long assumed to be the only mechanism involved.

    One key indicator, which showed up consistently in four different kinds of experiments under different conditions, was that as the water began to evaporate from a test container under visible light, the air temperature measured above the water’s surface cooled down and then leveled off, showing that thermal energy was not the driving force behind the effect.

    Other key indicators that showed up included the way the evaporation effect varied depending on the angle of the light, the exact color of the light, and its polarization. None of these varying characteristics should happen because at these wavelengths, water hardly absorbs light at all — and yet the researchers observed them.

    The effect is strongest when light hits the water surface at an angle of 45 degrees. It is also strongest with a certain type of polarization, called transverse magnetic polarization. And it peaks in green light — which, oddly, is the color for which water is most transparent and thus interacts the least.

    Chen and his co-researchers have proposed a physical mechanism that can explain the angle and polarization dependence of the effect, showing that the photons of light can impart a net force on water molecules at the water surface that is sufficient to knock them loose from the body of water. But they cannot yet account for the color dependence, which they say will require further study.

    They have named this the photomolecular effect, by analogy with the photoelectric effect that was discovered by Heinrich Hertz in 1887 and finally explained by Albert Einstein in 1905. That effect was one of the first demonstrations that light also has particle characteristics, which had major implications in physics and led to a wide variety of applications, including LEDs. Just as the photoelectric effect liberates electrons from atoms in a material in response to being hit by a photon of light, the photomolecular effect shows that photons can liberate entire molecules from a liquid surface, the researchers say.

    “The finding of evaporation caused by light instead of heat provides new disruptive knowledge of light-water interaction,” says Xiulin Ruan, professor of mechanical engineering at Purdue University, who was not involved in the study. “It could help us gain new understanding of how sunlight interacts with cloud, fog, oceans, and other natural water bodies to affect weather and climate. It has significant potential practical applications such as high-performance water desalination driven by solar energy. This research is among the rare group of truly revolutionary discoveries which are not widely accepted by the community right away but take time, sometimes a long time, to be confirmed.”

    Solving a cloud conundrum

    The finding may solve an 80-year-old mystery in climate science. Measurements of how clouds absorb sunlight have often shown that they are absorbing more sunlight than conventional physics dictates possible. The additional evaporation caused by this effect could account for the longstanding discrepancy, which has been a subject of dispute since such measurements are difficult to make.

    “Those experiments are based on satellite data and flight data,“ Chen explains. “They fly an airplane on top of and below the clouds, and there are also data based on the ocean temperature and radiation balance. And they all conclude that there is more absorption by clouds than theory could calculate. However, due to the complexity of clouds and the difficulties of making such measurements, researchers have been debating whether such discrepancies are real or not. And what we discovered suggests that hey, there’s another mechanism for cloud absorption, which was not accounted for, and this mechanism might explain the discrepancies.”

    Chen says he recently spoke about the phenomenon at an American Physical Society conference, and one physicist there who studies clouds and climate said they had never thought about this possibility, which could affect calculations of the complex effects of clouds on climate. The team conducted experiments using LEDs shining on an artificial cloud chamber, and they observed heating of the fog, which was not supposed to happen since water does not absorb in the visible spectrum. “Such heating can be explained based on the photomolecular effect more easily,” he says.

    Lv says that of the many lines of evidence, “the flat region in the air-side temperature distribution above hot water will be the easiest for people to reproduce.” That temperature profile “is a signature” that demonstrates the effect clearly, he says.

    Zhang adds: “It is quite hard to explain how this kind of flat temperature profile comes about without invoking some other mechanism” beyond the accepted theories of thermal evaporation. “It ties together what a whole lot of people are reporting in their solar desalination devices,” which again show evaporation rates that cannot be explained by the thermal input.

    The effect can be substantial. Under the optimum conditions of color, angle, and polarization, Lv says, “the evaporation rate is four times the thermal limit.”

    Already, since publication of the first paper, the team has been approached by companies that hope to harness the effect, Chen says, including for evaporating syrup and drying paper in a paper mill. The likeliest first applications will come in the areas of solar desalinization systems or other industrial drying processes, he says. “Drying consumes 20 percent of all industrial energy usage,” he points out.

    Because the effect is so new and unexpected, Chen says, “This phenomenon should be very general, and our experiment is really just the beginning.” The experiments needed to demonstrate and quantify the effect are very time-consuming. “There are many variables, from understanding water itself, to extending to other materials, other liquids and even solids,” he says.

    “The observations in the manuscript points to a new physical mechanism that foundationally alters our thinking on the kinetics of evaporation,” says Shannon Yee, an associate professor of mechanical engineering at Georgia Tech, who was not associated with this work. He adds, “Who would have thought that we are still learning about something as quotidian as water evaporating?”

    “I think this work is very significant scientifically because it presents a new mechanism,” says University of Alberta Distinguished Professor Janet A.W. Elliott, who also was not associated with this work. “It may also turn out to be practically important for technology and our understanding of nature, because evaporation of water is ubiquitous and the effect appears to deliver significantly higher evaporation rates than the known thermal mechanism. …  My overall impression is this work is outstanding. It appears to be carefully done with many precise experiments lending support for one another.”

    The work was partly supported by an MIT Bose Award. More

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    Advancing technology for aquaculture

    According to the National Oceanic and Atmospheric Administration, aquaculture in the United States represents a $1.5 billion industry annually. Like land-based farming, shellfish aquaculture requires healthy seed production in order to maintain a sustainable industry. Aquaculture hatchery production of shellfish larvae — seeds — requires close monitoring to track mortality rates and assess health from the earliest stages of life. 

    Careful observation is necessary to inform production scheduling, determine effects of naturally occurring harmful bacteria, and ensure sustainable seed production. This is an essential step for shellfish hatcheries but is currently a time-consuming manual process prone to human error. 

    With funding from MIT’s Abdul Latif Jameel Water and Food Systems Lab (J-WAFS), MIT Sea Grant is working with Associate Professor Otto Cordero of the MIT Department of Civil and Environmental Engineering, Professor Taskin Padir and Research Scientist Mark Zolotas at the Northeastern University Institute for Experiential Robotics, and others at the Aquaculture Research Corporation (ARC), and the Cape Cod Commercial Fishermen’s Alliance, to advance technology for the aquaculture industry. Located on Cape Cod, ARC is a leading shellfish hatchery, farm, and wholesaler that plays a vital role in providing high-quality shellfish seed to local and regional growers.

    Two MIT students have joined the effort this semester, working with Robert Vincent, MIT Sea Grant’s assistant director of advisory services, through the Undergraduate Research Opportunities Program (UROP). 

    First-year student Unyime Usua and sophomore Santiago Borrego are using microscopy images of shellfish seed from ARC to train machine learning algorithms that will help automate the identification and counting process. The resulting user-friendly image recognition tool aims to aid aquaculturists in differentiating and counting healthy, unhealthy, and dead shellfish larvae, improving accuracy and reducing time and effort.

    Vincent explains that AI is a powerful tool for environmental science that enables researchers, industry, and resource managers to address challenges that have long been pinch points for accurate data collection, analysis, predictions, and streamlining processes. “Funding support from programs like J-WAFS enable us to tackle these problems head-on,” he says. 

    ARC faces challenges with manually quantifying larvae classes, an important step in their seed production process. “When larvae are in their growing stages they are constantly being sized and counted,” explains Cheryl James, ARC larval/juvenile production manager. “This process is critical to encourage optimal growth and strengthen the population.” 

    Developing an automated identification and counting system will help to improve this step in the production process with time and cost benefits. “This is not an easy task,” says Vincent, “but with the guidance of Dr. Zolotas at the Northeastern University Institute for Experiential Robotics and the work of the UROP students, we have made solid progress.” 

    The UROP program benefits both researchers and students. Involving MIT UROP students in developing these types of systems provides insights into AI applications that they might not have considered, providing opportunities to explore, learn, and apply themselves while contributing to solving real challenges.

    Borrego saw this project as an opportunity to apply what he’d learned in class 6.390 (Introduction to Machine Learning) to a real-world issue. “I was starting to form an idea of how computers can see images and extract information from them,” he says. “I wanted to keep exploring that.”

    Usua decided to pursue the project because of the direct industry impacts it could have. “I’m pretty interested in seeing how we can utilize machine learning to make people’s lives easier. We are using AI to help biologists make this counting and identification process easier.” While Usua wasn’t familiar with aquaculture before starting this project, she explains, “Just hearing about the hatcheries that Dr. Vincent was telling us about, it was unfortunate that not a lot of people know what’s going on and the problems that they’re facing.”

    On Cape Cod alone, aquaculture is an $18 million per year industry. But the Massachusetts Division of Marine Fisheries estimates that hatcheries are only able to meet 70–80 percent of seed demand annually, which impacts local growers and economies. Through this project, the partners aim to develop technology that will increase seed production, advance industry capabilities, and help understand and improve the hatchery microbiome.

    Borrego explains the initial challenge of having limited data to work with. “Starting out, we had to go through and label all of the data, but going through that process helped me learn a lot.” In true MIT fashion, he shares his takeaway from the project: “Try to get the best out of what you’re given with the data you have to work with. You’re going to have to adapt and change your strategies depending on what you have.”

    Usua describes her experience going through the research process, communicating in a team, and deciding what approaches to take. “Research is a difficult and long process, but there is a lot to gain from it because it teaches you to look for things on your own and find your own solutions to problems.”

    In addition to increasing seed production and reducing the human labor required in the hatchery process, the collaborators expect this project to contribute to cost savings and technology integration to support one of the most underserved industries in the United States. 

    Borrego and Usua both plan to continue their work for a second semester with MIT Sea Grant. Borrego is interested in learning more about how technology can be used to protect the environment and wildlife. Usua says she hopes to explore more projects related to aquaculture. “It seems like there’s an infinite amount of ways to tackle these issues.” More

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    Extracting hydrogen from rocks

    It’s commonly thought that the most abundant element in the universe, hydrogen, exists mainly alongside other elements — with oxygen in water, for example, and with carbon in methane. But naturally occurring underground pockets of pure hydrogen are punching holes in that notion — and generating attention as a potentially unlimited source of carbon-free power. One interested party is the U.S. Department of Energy, which last month awarded $20 million in research grants to 18 teams from laboratories, universities, and private companies to develop technologies that can lead to cheap, clean fuel from the subsurface. Geologic hydrogen, as it’s known, is produced when water reacts with iron-rich rocks, causing the iron to oxidize. One of the grant recipients, MIT Assistant Professor Iwnetim Abate’s research group, will use its $1.3 million grant to determine the ideal conditions for producing hydrogen underground — considering factors such as catalysts to initiate the chemical reaction, temperature, pressure, and pH levels. The goal is to improve efficiency for large-scale production, meeting global energy needs at a competitive cost. The U.S. Geological Survey estimates there are potentially billions of tons of geologic hydrogen buried in the Earth’s crust. Accumulations have been discovered worldwide, and a slew of startups are searching for extractable deposits. Abate is looking to jump-start the natural hydrogen production process, implementing “proactive” approaches that involve stimulating production and harvesting the gas.                                                                                                                         “We aim to optimize the reaction parameters to make the reaction faster and produce hydrogen in an economically feasible manner,” says Abate, the Chipman Development Professor in the Department of Materials Science and Engineering (DMSE). Abate’s research centers on designing materials and technologies for the renewable energy transition, including next-generation batteries and novel chemical methods for energy storage. 

    Sparking innovation

    Interest in geologic hydrogen is growing at a time when governments worldwide are seeking carbon-free energy alternatives to oil and gas. In December, French President Emmanuel Macron said his government would provide funding to explore natural hydrogen. And in February, government and private sector witnesses briefed U.S. lawmakers on opportunities to extract hydrogen from the ground. Today commercial hydrogen is manufactured at $2 a kilogram, mostly for fertilizer and chemical and steel production, but most methods involve burning fossil fuels, which release Earth-heating carbon. “Green hydrogen,” produced with renewable energy, is promising, but at $7 per kilogram, it’s expensive. “If you get hydrogen at a dollar a kilo, it’s competitive with natural gas on an energy-price basis,” says Douglas Wicks, a program director at Advanced Research Projects Agency – Energy (ARPA-E), the Department of Energy organization leading the geologic hydrogen grant program. Recipients of the ARPA-E grants include Colorado School of Mines, Texas Tech University, and Los Alamos National Laboratory, plus private companies including Koloma, a hydrogen production startup that has received funding from Amazon and Bill Gates. The projects themselves are diverse, ranging from applying industrial oil and gas methods for hydrogen production and extraction to developing models to understand hydrogen formation in rocks. The purpose: to address questions in what Wicks calls a “total white space.” “In geologic hydrogen, we don’t know how we can accelerate the production of it, because it’s a chemical reaction, nor do we really understand how to engineer the subsurface so that we can safely extract it,” Wicks says. “We’re trying to bring in the best skills of each of the different groups to work on this under the idea that the ensemble should be able to give us good answers in a fairly rapid timeframe.” Geochemist Viacheslav Zgonnik, one of the foremost experts in the natural hydrogen field, agrees that the list of unknowns is long, as is the road to the first commercial projects. But he says efforts to stimulate hydrogen production — to harness the natural reaction between water and rock — present “tremendous potential.” “The idea is to find ways we can accelerate that reaction and control it so we can produce hydrogen on demand in specific places,” says Zgonnik, CEO and founder of Natural Hydrogen Energy, a Denver-based startup that has mineral leases for exploratory drilling in the United States. “If we can achieve that goal, it means that we can potentially replace fossil fuels with stimulated hydrogen.”

    “A full-circle moment”

    For Abate, the connection to the project is personal. As a child in his hometown in Ethiopia, power outages were a usual occurrence — the lights would be out three, maybe four days a week. Flickering candles or pollutant-emitting kerosene lamps were often the only source of light for doing homework at night. “And for the household, we had to use wood and charcoal for chores such as cooking,” says Abate. “That was my story all the way until the end of high school and before I came to the U.S. for college.” In 1987, well-diggers drilling for water in Mali in Western Africa uncovered a natural hydrogen deposit, causing an explosion. Decades later, Malian entrepreneur Aliou Diallo and his Canadian oil and gas company tapped the well and used an engine to burn hydrogen and power electricity in the nearby village. Ditching oil and gas, Diallo launched Hydroma, the world’s first hydrogen exploration enterprise. The company is drilling wells near the original site that have yielded high concentrations of the gas. “So, what used to be known as an energy-poor continent now is generating hope for the future of the world,” Abate says. “Learning about that was a full-circle moment for me. Of course, the problem is global; the solution is global. But then the connection with my personal journey, plus the solution coming from my home continent, makes me personally connected to the problem and to the solution.”

    Experiments that scale

    Abate and researchers in his lab are formulating a recipe for a fluid that will induce the chemical reaction that triggers hydrogen production in rocks. The main ingredient is water, and the team is testing “simple” materials for catalysts that will speed up the reaction and in turn increase the amount of hydrogen produced, says postdoc Yifan Gao. “Some catalysts are very costly and hard to produce, requiring complex production or preparation,” Gao says. “A catalyst that’s inexpensive and abundant will allow us to enhance the production rate — that way, we produce it at an economically feasible rate, but also with an economically feasible yield.” The iron-rich rocks in which the chemical reaction happens can be found across the United States and the world. To optimize the reaction across a diversity of geological compositions and environments, Abate and Gao are developing what they call a high-throughput system, consisting of artificial intelligence software and robotics, to test different catalyst mixtures and simulate what would happen when applied to rocks from various regions, with different external conditions like temperature and pressure. “And from that we measure how much hydrogen we are producing for each possible combination,” Abate says. “Then the AI will learn from the experiments and suggest to us, ‘Based on what I’ve learned and based on the literature, I suggest you test this composition of catalyst material for this rock.’” The team is writing a paper on its project and aims to publish its findings in the coming months. The next milestones for the project, after developing the catalyst recipe, is designing a reactor that will serve two purposes. First, fitted with technologies such as Raman spectroscopy, it will allow researchers to identify and optimize the chemical conditions that lead to improved rates and yield of hydrogen production. The lab-scale device will also inform the design of a real-world reactor that can accelerate hydrogen production in the field. “That would be a plant-scale reactor that would be implanted into the subsurface,” Abate says. The cross-disciplinary project is also tapping the expertise of Yang Shao-Horn, of MIT’s Department of Mechanical Engineering and DMSE, for computational analysis of the catalyst, and Esteban Gazel, a Cornell University scientist who will lend his expertise in geology and geochemistry. He’ll focus on understanding the iron-rich ultramafic rock formations across the United States and the globe and how they react with water. For Wicks at ARPA-E, the questions Abate and the other grant recipients are asking are just the first, critical steps in uncharted energy territory. “If we can understand how to stimulate these rocks into generating hydrogen, safely getting it up, it really unleashes the potential energy source,” he says. Then the emerging industry will look to oil and gas for the drilling, piping, and gas extraction know-how. “As I like to say, this is enabling technology that we hope to, in a very short term, enable us to say, ‘Is there really something there?’” More