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    3 Questions: The Climate Project at MIT

    MIT is preparing a major campus-wide effort to develop technological, behavioral, and policy solutions to some of the toughest problems now impeding an effective global climate response. The Climate Project at MIT, as the new enterprise is known, includes new arrangements for promoting cross-Institute collaborations and new mechanisms for engaging with outside partners to speed the development and implementation of climate solutions.

    MIT News spoke with Richard K. Lester, MIT’s vice provost for international activities, who has helped oversee the development of the project.

    Q: What is the Climate Project at MIT?

    A: In her inaugural address last May, President Kornbluth called on the MIT community to join her in a “bold, tenacious response” to climate change. The Climate Project at MIT is a response to that call. It aims to mobilize every part of MIT to develop, deliver, and scale up practical climate solutions, as quickly as possible.

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    At MIT, well over 300 of our faculty are already working with their students and research staff members on different aspects of the climate problem. Almost all of our academic departments and more than a score of our interdepartmental labs and centers are involved in some way. What they are doing is remarkable, and this decentralized structure reflects the best traditions of MIT as a “bottom up,” entrepreneurial institution. But, as President Kornbluth said, we must do much more. We must be bolder in our research choices and more creative in how we organize ourselves to work with each other and with our partners. The purpose of the Climate Project is to support our community’s efforts to do bigger things faster in the climate domain. We will have succeeded if our work changes the trajectory of global climate outcomes for the better.

    I want to be clear that the clay is still wet here. The Climate Project will continue to take shape as more members of the MIT community bring their excellence, their energy, and their ambition to bear on the climate challenge. But I believe we have a vision and a framework for accelerating and amplifying MIT’s real-world climate impact, and I know that President Kornbluth is eager to share this progress report with the MIT community now to convey the breadth and ambition of what we’re planning.

    Q: How will the project be organized?

    A: The Climate Project will have three core components: the Climate Missions; their offshoots, the Climate Frontier Projects; and Climate HQ. A new vice president for climate will lead the enterprise.

    Initially there will be six missions, which you can read about in the plan. Each will address a different domain of climate impact where new solutions are required and where a critical mass of research excellence exists at MIT. One such mission, of course, is to decarbonize energy and industry, an area where we estimate that about 150 of our faculty are already working.

    The mission leaders will build multidisciplinary problem-solving communities reaching across the Institute and beyond. Each of these will be charged with roadmapping and assessing progress toward its mission, identifying critical gaps and bottlenecks, and launching applied research projects to accelerate progress where the MIT community and our partners are well-positioned to achieve impactful results. These projects — the climate frontier projects — will benefit from active, professional project management, with clear metrics and milestones. We are in a critical decade for responding to climate change, so it’s important that these research projects move quickly, with an eye on producing real-world results.

    The new Climate HQ will drive the overall vision for the Climate Project and support the work of the missions. We’ve talked about a core focus on impact-driven research, but much is still unknown about the Earth’s physical and biogeochemical systems, and there is also much to be learned about the behavior of the social and political systems that led us to the very difficult situation the world now faces. Climate HQ will support fundamental research in the scientific and humanistic disciplines related to climate, and will promote engagement between these disciplines and the missions. We must also advance climate-related education, led by departments and programs, as well as policy work, public outreach, and more, including an MIT-wide student-centric Climate Corps to elevate climate-related, community-focused service in MIT’s culture.

    Q: Why are partners a key part of this project?

    A: It is important to build strong partners right from the very start for our innovations, inventions, and discoveries to have any prospect of achieving scale. And in many cases, with climate change, it’s all about scale.

    One of the aims of this initiative is to strengthen MIT’s climate “scaffolding” — the people and processes connecting what we do on campus to the practical world of climate impact and response. We can build on MIT’s highly developed infrastructure for translation, innovation, and entrepreneurship, even as we promote other important pathways to scale involving communities, municipalities, and other not-for-profit organizations. Working with all these different organizations will help us build a broad infrastructure to help us get traction in the world. On a related note, the Sloan School of Management will be sharing details in the coming days of an exciting new effort to enhance MIT’s contributions in the climate policy arena.

    MIT is committing $75 million, including $25 million from Sloan, at the outset of the project. But we anticipate developing new partnerships, including philanthropic partnerships, to increase that scope dramatically. More

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    New MIT.nano equipment to accelerate innovation in “tough tech” sectors

    A new set of advanced nanofabrication equipment will make MIT.nano one of the world’s most advanced research facilities in microelectronics and related technologies, unlocking new opportunities for experimentation and widening the path for promising inventions to become impactful new products.

    The equipment, provided by Applied Materials, will significantly expand MIT.nano’s nanofabrication capabilities, making them compatible with wafers — thin, round slices of semiconductor material — up to 200 millimeters, or 8 inches, in diameter, a size widely used in industry. The new tools will allow researchers to prototype a vast array of new microelectronic devices using state-of-the-art materials and fabrication processes. At the same time, the 200-millimeter compatibility will support close collaboration with industry and enable innovations to be rapidly adopted by companies and mass produced.

    MIT.nano’s leaders say the equipment, which will also be available to scientists outside of MIT, will dramatically enhance their facility’s capabilities, allowing experts in the region to more efficiently explore new approaches in “tough tech” sectors, including advanced electronics, next-generation batteries, renewable energies, optical computing, biological sensing, and a host of other areas — many likely yet to be imagined.

    “The toolsets will provide an accelerative boost to our ability to launch new technologies that can then be given to the world at scale,” says MIT.nano Director Vladimir Bulović, who is also the Fariborz Maseeh Professor of Emerging Technology. “MIT.nano is committed to its expansive mission — to build a better world. We provide toolsets and capabilities that, in the hands of brilliant researchers, can effectively move the world forward.”

    The announcement comes as part of an agreement between MIT and Applied Materials, Inc. that, together with a grant to MIT from the Northeast Microelectronics Coalition (NEMC) Hub, commits more than $40 million of estimated private and public investment to add advanced nano-fabrication equipment and capabilities at MIT.nano.

    “We don’t believe there is another space in the United States that will offer the same kind of versatility, capability, and accessibility, with 8-inch toolsets integrated right next to more fundamental toolsets for research discoveries,” Bulović says. “It will create a seamless path to accelerate the pace of innovation.”

    Pushing the boundaries of innovation

    Applied Materials is the world’s largest supplier of equipment for manufacturing semiconductors, displays, and other advanced electronics. The company will provide at MIT.nano several state-of-the-art process tools capable of supporting 150- and 200-millimeter wafers and will enhance and upgrade an existing tool owned by MIT. In addition to assisting MIT.nano in the day-to-day operation and maintenance of the equipment, Applied Materials engineers will develop new process capabilities to benefit researchers and students from MIT and beyond.

    “This investment will significantly accelerate the pace of innovation and discovery in microelectronics and microsystems,” says Tomás Palacios, director of MIT’s Microsystems Technology Laboratories and the Clarence J. Lebel Professor in Electrical Engineering. “It’s wonderful news for our community, wonderful news for the state, and, in my view, a tremendous step forward toward implementing the national vision for the future of innovation in microelectronics.”

    Nanoscale research at universities is traditionally conducted on machines that are less compatible with industry, which makes academic innovations more difficult to turn into impactful, mass-produced products. Jorg Scholvin, associate director for MIT.nano’s shared fabrication facility, says the new machines, when combined with MIT.nano’s existing equipment, represent a step-change improvement in that area: Researchers will be able to take an industry-standard wafer and build their technology on top of it to prove to companies it works on existing devices, or to co-fabricate new ideas in close collaboration with industry partners.

    “In the journey from an idea to a fully working device, the ability to begin on a small scale, figure out what you want to do, rapidly debug your designs, and then scale it up to an industry-scale wafer is critical,” Scholvin says. “It means a student can test out their idea on wafer-scale quickly and directly incorporate insights into their project so that their processes are scalable. Providing such proof-of-principle early on will accelerate the idea out of the academic environment, potentially reducing years of added effort. Other tools at MIT.nano can supplement work on the 200-millimeter wafer scale, but the higher throughput and higher precision of the Applied equipment will provide researchers with repeatability and accuracy that is unprecedented for academic research environments. Essentially what you have is a sharper, faster, more precise tool to do your work.”

    Scholvin predicts the equipment will lead to exponential growth in research opportunities.

    “I think a key benefit of these tools is they allow us to push the boundary of research in a variety of different ways that we can predict today,” Scholvin says. “But then there are also unpredictable benefits, which are hiding in the shadows waiting to be discovered by the creativity of the researchers at MIT. With each new application, more ideas and paths usually come to mind — so that over time, more and more opportunities are discovered.”

    Because the equipment is available for use by people outside of the MIT community, including regional researchers, industry partners, nonprofit organizations, and local startups, they will also enable new collaborations.

    “The tools themselves will be an incredible meeting place — a place that can, I think, transpose the best of our ideas in a much more effective way than before,” Bulović says. “I’m extremely excited about that.”

    Palacios notes that while microelectronics is best known for work making transistors smaller to fit on microprocessors, it’s a vast field that enables virtually all the technology around us, from wireless communications and high-speed internet to energy management, personalized health care, and more.

    He says he’s personally excited to use the new machines to do research around power electronics and semiconductors, including exploring promising new materials like gallium nitride, which could dramatically improve the efficiency of electronic devices.

    Fulfilling a mission

    MIT.nano’s leaders say a key driver of commercialization will be startups, both from MIT and beyond.

    “This is not only going to help the MIT research community innovate faster, it’s also going to enable a new wave of entrepreneurship,” Palacios says. “We’re reducing the barriers for students, faculty, and other entrepreneurs to be able to take innovation and get it to market. That fits nicely with MIT’s mission of making the world a better place through technology. I cannot wait to see the amazing new inventions that our colleagues and students will come out with.”

    Bulović says the announcement aligns with the mission laid out by MIT’s leaders at MIT.nano’s inception.

    “We have the space in MIT.nano to accommodate these tools, we have the capabilities inside MIT.nano to manage their operation, and as a shared and open facility, we have methodologies by which we can welcome anyone from the region to use the tools,” Bulović says. “That is the vision MIT laid out as we were designing MIT.nano, and this announcement helps to fulfill that vision.” More

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    Meeting the clean energy needs of tomorrow

    Yuri Sebregts, chief technology officer at Shell, succinctly laid out the energy dilemma facing the world over the rest of this century. On one hand, demand for energy is quickly growing as countries in the developing world modernize and the global population grows, with 100 gigajoules of energy per person needed annually to enable quality-of-life benefits and industrialization around the globe. On the other, traditional energy sources are quickly warming the planet, with the world already seeing the devastating effects of increasingly frequent extreme weather events. 

    While the goals of energy security and energy sustainability are seemingly at odds with one another, the two must be pursued in tandem, Sebregts said during his address at the MIT Energy Initiative Fall Colloquium.

    “An environmentally sustainable energy system that isn’t also a secure energy system is not sustainable,” Sebregts said. “And conversely, a secure energy system that is not environmentally sustainable will do little to ensure long-term energy access and affordability. Therefore, security and sustainability must go hand-in-hand. You can’t trade off one for the other.”

    Sebregts noted that there are several potential pathways to help strike this balance, including investments in renewable energy sources, the use of carbon offsets, and the creation of more efficient tools, products, and processes. However, he acknowledged that meeting growing energy demands while minimizing environmental impacts is a global challenge requiring an unprecedented level of cooperation among countries and corporations across the world. 

    “At Shell, we recognize that this will require a lot of collaboration between governments, businesses, and civil society,” Sebregts said. “That’s not always easy.”

    Global conflict and global warming

    In 2021, Sebregts noted, world leaders gathered in Glasgow, Scotland and collectively promised to deliver on the “stretch goal” of the 2015 Paris Agreement, which would limit global warming to 1.5 degrees Celsius — a level that scientists believe will help avoid the worst potential impacts of climate change. But, just a few months later, Russia invaded Ukraine, resulting in chaos in global energy markets and illustrating the massive impact that geopolitical friction can have on efforts to reduce carbon emissions.

    “Even though global volatility has been a near constant of this century, the situation in Ukraine is proving to be a turning point,” Sebregts said. “The stress it placed on the global supply of energy, food, and other critical materials was enormous.”

    In Europe, Sebregts noted, countries affected by the loss of Russia’s natural gas supply began importing from the Middle East and the United States. This, in turn, drove up prices. While this did result in some efforts to limit energy use, such as Europeans lowering their thermostats in the winter, it also caused some energy buyers to turn to coal. For instance, the German government approved additional coal mining to boost its energy security — temporarily reversing a decades-long transition away from the fuel. To put this into wider perspective, in a single quarter, China increased its coal generation capacity by as much as Germany had reduced its own over the previous 20 years.

    The promise of electrification

    Sebregts noted the strides being made toward electrification, which is expected to have a significant impact on global carbon emissions. To meet net-zero emissions (the point at which humans are adding no more carbon to the atmosphere than they are removing) by 2050, the share of electricity as a portion of total worldwide energy consumption must reach 37 percent by 2030, up from 20 percent in 2020, Sebregts said.

    He pointed out that Shell has become one of the world’s largest electric vehicle charging companies, with more than 30,000 public charge points. By 2025, that number will increase to 70,000, and it is expected to soar to 200,000 by 2030. While demand and infrastructure for electric vehicles are growing, Sebregts said that the “real needle-mover” will be industrial electrification, especially in so-called “hard-to-abate” sectors.

    This progress will depend heavily on global cooperation — Sebregts pointed out that China dominates the international market for many rare elements that are key components of electrification infrastructure. “It shouldn’t be a surprise that the political instability, shifting geopolitical tensions, and environmental and social governance issues are significant risks for the energy transition,” he said. “It is imperative that we reduce, control, and mitigate these risks as much as possible.”

    Two possible paths

    For decades, Sebregts said, Shell has created scenarios to help senior managers think through the long-term challenges facing the company. While Sebregts stressed that these scenarios are not predictions, they do take into account real-world conditions, and they are meant to give leaders the opportunity to grapple with plausible situations.

    With this in mind, Sebregts outlined Shell’s most recent Energy Security Scenarios, describing the potential future consequences of attempts to balance growing energy demand with sustainability — scenarios that envision vastly different levels of global cooperation, with huge differences in projected results. 

    The first scenario, dubbed “Archipelagos,” imagines countries pursuing energy security through self-interest — a fragmented, competitive process that would result in a global temperature increase of 2.2 degrees Celsius by the end of this century. The second scenario, “Sky 2050,” envisions countries around the world collaborating to change the energy system for their mutual benefit. This more optimistic scenario would see a much lower global temperature increase of 1.2 C by 2100.

    “The good news is that in both scenarios, the world is heading for net-zero emissions at some point,” Sebregts said. “The difference is a question of when it gets there. In Sky 2050, it is the middle of the century. In Archipelagos, it is early in the next century.”

    On the other hand, Sebregts added, the average global temperature will increase by more than 1.5 C for some period of time in either scenario. But, in the Archipelagos scenario, this overshoot will be much larger, and will take much longer to come down. “So, two very different futures,” Sebregts said. “Two very different worlds.”

    The work ahead

    Questioned about the costs of transitioning to a net-zero energy ecosystem, Sebregts said that it is “very hard” to provide an accurate answer. “If you impose an additional constraint … you’re going to have to add some level of cost,” he said. “But then, of course, there’s 30 years of technology development pathway that might counteract some of that.”

    In some cases, such as air travel, Sebregts said, it will likely remain impractical to either rely on electrification or sequester carbon at the source of emission. Direct air capture (DAC) methods, which mechanically pull carbon directly from the atmosphere, will have a role to play in offsetting these emissions, he said. Sebregts predicted that the price of DAC could come down significantly by the middle of this century. “I would venture that a price of $200 to $250 a ton of CO2 by 2050 is something that the world would be willing to spend, at least in developed economies, to offset those very hard-to-abate instances.”

    Sebregts noted that Shell is working on demonstrating DAC technologies in Houston, Texas, constructing what will become Europe’s largest hydrogen plant in the Netherlands, and taking other steps to profitably transition to a net-zero emissions energy company by 2050. “We need to understand what can help our customers transition quicker and how we can continue to satisfy their needs,” he said. “We must ensure that energy is affordable, accessible, and sustainable, as soon as possible.” More

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    Cobalt-free batteries could power cars of the future

    Many electric vehicles are powered by batteries that contain cobalt — a metal that carries high financial, environmental, and social costs.

    MIT researchers have now designed a battery material that could offer a more sustainable way to power electric cars. The new lithium-ion battery includes a cathode based on organic materials, instead of cobalt or nickel (another metal often used in lithium-ion batteries).

    In a new study, the researchers showed that this material, which could be produced at much lower cost than cobalt-containing batteries, can conduct electricity at similar rates as cobalt batteries. The new battery also has comparable storage capacity and can be charged up faster than cobalt batteries, the researchers report.

    “I think this material could have a big impact because it works really well,” says Mircea Dincă, the W.M. Keck Professor of Energy at MIT. “It is already competitive with incumbent technologies, and it can save a lot of the cost and pain and environmental issues related to mining the metals that currently go into batteries.”

    Dincă is the senior author of the study, which appears today in the journal ACS Central Science. Tianyang Chen PhD ’23 and Harish Banda, a former MIT postdoc, are the lead authors of the paper. Other authors include Jiande Wang, an MIT postdoc; Julius Oppenheim, an MIT graduate student; and Alessandro Franceschi, a research fellow at the University of Bologna.

    Alternatives to cobalt

    Most electric cars are powered by lithium-ion batteries, a type of battery that is recharged when lithium ions flow from a positively charged electrode, called a cathode, to a negatively electrode, called an anode. In most lithium-ion batteries, the cathode contains cobalt, a metal that offers high stability and energy density.

    However, cobalt has significant downsides. A scarce metal, its price can fluctuate dramatically, and much of the world’s cobalt deposits are located in politically unstable countries. Cobalt extraction creates hazardous working conditions and generates toxic waste that contaminates land, air, and water surrounding the mines.

    “Cobalt batteries can store a lot of energy, and they have all of features that people care about in terms of performance, but they have the issue of not being widely available, and the cost fluctuates broadly with commodity prices. And, as you transition to a much higher proportion of electrified vehicles in the consumer market, it’s certainly going to get more expensive,” Dincă says.

    Because of the many drawbacks to cobalt, a great deal of research has gone into trying to develop alternative battery materials. One such material is lithium-iron-phosphate (LFP), which some car manufacturers are beginning to use in electric vehicles. Although still practically useful, LFP has only about half the energy density of cobalt and nickel batteries.

    Another appealing option are organic materials, but so far most of these materials have not been able to match the conductivity, storage capacity, and lifetime of cobalt-containing batteries. Because of their low conductivity, such materials typically need to be mixed with binders such as polymers, which help them maintain a conductive network. These binders, which make up at least 50 percent of the overall material, bring down the battery’s storage capacity.

    About six years ago, Dincă’s lab began working on a project, funded by Lamborghini, to develop an organic battery that could be used to power electric cars. While working on porous materials that were partly organic and partly inorganic, Dincă and his students realized that a fully organic material they had made appeared that it might be a strong conductor.

    This material consists of many layers of TAQ (bis-tetraaminobenzoquinone), an organic small molecule that contains three fused hexagonal rings. These layers can extend outward in every direction, forming a structure similar to graphite. Within the molecules are chemical groups called quinones, which are the electron reservoirs, and amines, which help the material to form strong hydrogen bonds.

    Those hydrogen bonds make the material highly stable and also very insoluble. That insolubility is important because it prevents the material from dissolving into the battery electrolyte, as some organic battery materials do, thereby extending its lifetime.

    “One of the main methods of degradation for organic materials is that they simply dissolve into the battery electrolyte and cross over to the other side of the battery, essentially creating a short circuit. If you make the material completely insoluble, that process doesn’t happen, so we can go to over 2,000 charge cycles with minimal degradation,” Dincă says.

    Strong performance

    Tests of this material showed that its conductivity and storage capacity were comparable to that of traditional cobalt-containing batteries. Also, batteries with a TAQ cathode can be charged and discharged faster than existing batteries, which could speed up the charging rate for electric vehicles.

    To stabilize the organic material and increase its ability to adhere to the battery’s current collector, which is made of copper or aluminum, the researchers added filler materials such as cellulose and rubber. These fillers make up less than one-tenth of the overall cathode composite, so they don’t significantly reduce the battery’s storage capacity.

    These fillers also extend the lifetime of the battery cathode by preventing it from cracking when lithium ions flow into the cathode as the battery charges.

    The primary materials needed to manufacture this type of cathode are a quinone precursor and an amine precursor, which are already commercially available and produced in large quantities as commodity chemicals. The researchers estimate that the material cost of assembling these organic batteries could be about one-third to one-half the cost of cobalt batteries.

    Lamborghini has licensed the patent on the technology. Dincă’s lab plans to continue developing alternative battery materials and is exploring possible replacement of lithium with sodium or magnesium, which are cheaper and more abundant than lithium. More

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    Shell joins MIT.nano Consortium

    MIT.nano has announced that Shell, a global group of energy and petrochemical companies, has joined the MIT.nano Consortium.

    “With an international perspective on the world’s energy challenges, Shell is an exciting addition to the MIT.nano Consortium,” says Vladimir Bulović, the founding faculty director of MIT.nano and the Fariborz Maseeh (1990) Professor of Emerging Technologies. “The quest to build a sustainable energy future will require creative thinking backed by broad and deep expertise that our Shell colleagues bring. They will be insightful collaborators for the MIT community and for our member companies as we work together to explore innovative technology strategies.”

    Founded in 1907 when Shell Transport and Trading Co. merged with Royal Dutch, Shell has more than a century’s worth of experience in the exploration, production, refining, and marketing of oil and natural gas and the manufacturing and marketing of chemicals. Operating in over 70 countries, Shell has set a target to become a net-zero emissions energy business by 2050. To achieve this, Shell is supporting developments of low-carbon energy solutions such as biofuels, hydrogen, charging for electric vehicles, and electricity generated by solar and wind power.

    “In line with our Powering Progress strategy, our research efforts to become a net-zero emission energy company by 2050 will require intense collaboration with academic leaders across a wide range of disciplines,” says Rolf van Benthem, Shell’s chief scientist for materials science. “We look forward to engaging with the top-notch PIs [principal investigators] at MIT.nano who excel in fields like materials design and nanoscale characterization for use in energy applications and carbon utilization. Together we can work on truly sustainable solutions for our society.”

    Shell has been engaged in research collaborations with MIT since 2002 and is a founding member of the MIT Energy Initiative (MITEI). Recent MIT projects supported by Shell include an urban building energy model with the MIT Sustainable Design Laboratory that explores energy-saving building retrofits, a study of the role and impact of hydrogen-based technology pathways with MITEI, and a materials science and engineering project to design better batteries for electric vehicles.

    The MIT.nano Consortium is a platform for academia-industry collaboration centered around research and innovation emerging from nanoscale science and engineering at MIT. Through activities that include quarterly industry consortium meetings, Shell will gain insight into the work of MIT.nano’s community of users and provide advice to help guide and advance nanoscale innovations at MIT alongside the 11 other consortium companies:

    Analog Devices;
    Draper;
    Edwards;
    Fujikura;
    IBM Research;
    Lam Research;
    NC;
    NEC;
    Raith;
    UpNano; and
    Viavi Solutions.
    MIT.nano continues to welcome new companies as sustaining members. For more details, visit the MIT.nano Consortium page. More

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    MIT researchers outline a path for scaling clean hydrogen production

    Hydrogen is an integral component for the manufacture of steel, fertilizer, and a number of chemicals. Producing hydrogen using renewable electricity offers a way to clean up these and many other hard-to-decarbonize industries.

    But supporting the nascent clean hydrogen industry while ensuring it grows into a true force for decarbonization is complicated, in large part because of the challenges of sourcing clean electricity. To assist regulators and to clarify disagreements in the field, MIT researchers published a paper today in Nature Energy that outlines a path to scale the clean hydrogen industry while limiting emissions.

    Right now, U.S. electric grids are mainly powered by fossil fuels, so if scaling hydrogen production translates to greater electricity use, it could result in a major emissions increase. There is also the risk that “low-carbon” hydrogen projects could end up siphoning renewable energy that would have been built anyway for the grid. It is therefore critical to ensure that low-carbon hydrogen procures electricity from “additional” renewables, especially when hydrogen production is supported by public subsidies. The challenge is allowing hydrogen producers to procure renewable electricity in a cost-effective way that helps the industry grow, while minimizing the risk of high emissions.

    U.S. regulators have been tasked with sorting out this complexity. The Inflation Reduction Act (IRA) is offering generous production tax credits for low-carbon hydrogen. But the law didn’t specify exactly how hydrogen’s carbon footprint should be judged.

    To this end, the paper proposes a phased approach to qualify for the tax credits. In the first phase, hydrogen created from grid electricity can receive the credits under looser standards as the industry gets its footing. Once electricity demand for hydrogen production grows, the industry should be required to adhere to stricter standards for ensuring the electricity is coming from renewable sources. Finally, many years from now when the grid is mainly powered by renewable energy, the standards can loosen again.

    The researchers say the nuanced approach ensures the law supports the growth of clean hydrogen without coming at the expense of emissions.

    “If we can scale low-carbon hydrogen production, we can cut some significant sources of existing emissions and enable decarbonization of other critical industries,” says paper co-author Michael Giovanniello, a graduate student in MIT’s Technology and Policy Program. “At the same time, there’s a real risk of implementing the wrong requirements and wasting lots of money to subsidize carbon-intensive hydrogen production. So, you have to balance scaling the industry with reducing the risk of emissions. I hope there’s clarity and foresight in how this policy is implemented, and I hope our paper makes the argument clear for policymakers.”

    Giovanniello’s co-authors on the paper are MIT Energy Initiative (MITEI) Principal Research Scientist Dharik Mallapragada, MITEI Research Assistant Anna Cybulsky, and MIT Sloan School of Management Senior Lecturer Tim Schittekatte.

    On definitions and disagreements

    When renewable electricity from a wind farm or solar array flows through the grid, it’s mixed with electricity from fossil fuels. The situation raises a question worth billions of dollars in federal tax credits: What are the carbon dioxide emissions of grid users who are also signing agreements to procure electricity from renewables?

    One way to answer this question is via energy system models that can simulate various scenarios related to technology configurations and qualifying requirements for receiving the credit.

    To date, many studies using such models have come up with very different emissions estimates for electrolytic hydrogen production. One source of disagreement is over “time matching,” which refers to how strictly to align the timing of electric hydrogen production with the generation of clean electricity. One proposed approach, known as hourly time matching, would require that electricity consumption to produce hydrogen is accounted for by procured clean electricity at every hour.

    A less stringent approach, called annual time matching, would offer more flexibility in hourly electricity consumption for hydrogen production, so long as the annual consumption matches the annual generation from the procured clean electricity generation. The added flexibility could reduce the cost of hydrogen production, which is critical for scaling its use, but could lead to greater emissions per unit of hydrogen produced.

    Another point of disagreement stems from how hydrogen producers purchase renewable electricity. If an electricity user procures energy from an existing solar farm, it’s simply increasing overall electricity demand and taking clean energy away from other users. But if the tax credits only go to electric hydrogen producers that sign power purchase agreements with new renewable suppliers, they’re supporting clean electricity that wouldn’t have otherwise been contributing to the grid. This concept is known as “additionality.”

    The researchers analyzed previous studies that reached conflicting conclusions, and identified different interpretations of additionality underlying their methodologies. One interpretation of additionality is that new electrolytic hydrogen projects do not compete with nonhydrogen demand for renewable energy resources. The other assumes that they do compete for all newly deployed renewables — and, because of low-carbon hydrogen subsidies, the electrolyzers take priority.

    Using DOLPHYN, an open-source energy systems model, the researchers tested how these two interpretations of additionality (the “compete” and “noncompete” scenarios) impact the cost and emissions of the alternative time-matching requirements (hourly and annual) associated with grid-interconnected hydrogen production. They modeled two regional U.S. grids — in Texas and Florida — which represent the high and low end of renewables deployment. They further tested the interaction of four critical policy factors with the hydrogen tax credits, including renewable portfolio standards, constraints of renewables and energy storage deployment, limits on hydrogen electrolyzer capacity factors, and competition with natural gas-based hydrogen with carbon capture.

    They show that the different modeling interpretations of additionality are the primary factor explaining the vastly different estimates of emissions from electrolyzer hydrogen under annual time-matching.

    Getting policy right

    The paper concludes that the right way to implement the production tax credit qualifying requirements depends on whether you believe we live in a “compete” or “noncompete” world. But reality is not so binary.

    “What framework is more appropriate is going to change with time as we deploy more hydrogen and the grid decarbonizes, so therefore the policy has to be adaptive to those changes,” Mallapragada says. “It’s an evolving story that’s tied to what’s happening in the rest of the energy system, and in particular the electric grid, both from the technological as policy perspective.”

    Today, renewables deployment is driven, in part, by binding factors, such as state renewable portfolio standards and corporate clean-energy commitments, as well as by purely market forces. Since the electrolyzer is so nascent, and today resembles a “noncompete” world, the researchers argue for starting with the less strict annual requirement. But as hydrogen demand for renewable electricity grows, and market competition drives an increasing quantity of renewables deployment, transitioning to hourly matching will be necessary to avoid high emissions.

    This phased approach necessitates deliberate, long-term planning from regulators. “If regulators make a decision and don’t outline when they’ll reassess that decision, they might never reassess that decision, so we might get locked into a bad policy,” Giovanniello explains. In particular, the paper highlights the risk of locking in an annual time-matching requirement that leads to significant emissions in future.

    The researchers hope their findings will contribute to upcoming policy decisions around the Inflation Reduction Act’s tax credits. They started looking into this question around a year ago, making it a quick turnaround by academic standards.

    “There was definitely a sense to be timely in our analysis so as to be responsive to the needs of policy,” Mallapragada says.

    The researchers say the paper can also help policymakers understand the emissions impacts of companies procuring renewable energy credits to meet net-zero targets and electricity suppliers attempting to sell “green” electricity.

    “This question is relevant in a lot of different domains,” Schittekatte says. “Other popular examples are the emission impacts of data centers that procure green power, or even the emission impacts of your own electric car sourcing power from your rooftop solar and the grid. There are obviously differences based on the technology in question, but the underlying research question we’ve answered is the same. This is an extremely important topic for the energy transition.” More

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    Celebrating five years of MIT.nano

    There is vast opportunity for nanoscale innovation to transform the world in positive ways — expressed MIT.nano Director Vladimir Bulović as he posed two questions to attendees at the start of the inaugural Nano Summit: “Where are we heading? And what is the next big thing we can develop?”

    “The answer to that puts into perspective our main purpose — and that is to change the world,” Bulović, the Fariborz Maseeh Professor of Emerging Technologies, told an audience of more than 325 in-person and 150 virtual participants gathered for an exploration of nano-related research at MIT and a celebration of MIT.nano’s fifth anniversary.

    Over a decade ago, MIT embarked on a massive project for the ultra-small — building an advanced facility to support research at the nanoscale. Construction of MIT.nano in the heart of MIT’s campus, a process compared to assembling a ship in a bottle, began in 2015, and the facility launched in October 2018.

    Fast forward five years: MIT.nano now contains nearly 170 tools and instruments serving more than 1,200 trained researchers. These individuals come from over 300 principal investigator labs, representing more than 50 MIT departments, labs, and centers. The facility also serves external users from industry, other academic institutions, and over 130 startup and multinational companies.

    A cross section of these faculty and researchers joined industry partners and MIT community members to kick off the first Nano Summit, which is expected to become an annual flagship event for MIT.nano and its industry consortium. Held on Oct. 24, the inaugural conference was co-hosted by the MIT Industrial Liaison Program.

    Six topical sessions highlighted recent developments in quantum science and engineering, materials, advanced electronics, energy, biology, and immersive data technology. The Nano Summit also featured startup ventures and an art exhibition.

    Watch the videos here.

    Seeing and manipulating at the nanoscale — and beyond

    “We need to develop new ways of building the next generation of materials,” said Frances Ross, the TDK Professor in Materials Science and Engineering (DMSE). “We need to use electron microscopy to help us understand not only what the structure is after it’s built, but how it came to be. I think the next few years in this piece of the nano realm are going to be really amazing.”

    Speakers in the session “The Next Materials Revolution,” chaired by MIT.nano co-director for Characterization.nano and associate professor in DMSE James LeBeau, highlighted areas in which cutting-edge microscopy provides insights into the behavior of functional materials at the nanoscale, from anti-ferroelectrics to thin-film photovoltaics and 2D materials. They shared images and videos collected using the instruments in MIT.nano’s characterization suites, which were specifically designed and constructed to minimize mechanical-vibrational and electro-magnetic interference.

    Later, in the “Biology and Human Health” session chaired by Boris Magasanik Professor of Biology Thomas Schwartz, biologists echoed the materials scientists, stressing the importance of the ultra-quiet, low-vibration environment in Characterization.nano to obtain high-resolution images of biological structures.

    “Why is MIT.nano important for us?” asked Schwartz. “An important element of biology is to understand the structure of biology macromolecules. We want to get to an atomic resolution of these structures. CryoEM (cryo-electron microscopy) is an excellent method for this. In order to enable the resolution revolution, we had to get these instruments to MIT. For that, MIT.nano was fantastic.”

    Seychelle Vos, the Robert A. Swanson (1969) Career Development Professor of Life Sciences, shared CryoEM images from her lab’s work, followed by biology Associate Professor Joey Davis who spoke about image processing. When asked about the next stage for CryoEM, Davis said he’s most excited about in-situ tomography, noting that there are new instruments being designed that will improve the current labor-intensive process.

    To chart the future of energy, chemistry associate professor Yogi Surendranath is also using MIT.nano to see what is happening at the nanoscale in his research to use renewable electricity to change carbon dioxide into fuel.

    “MIT.nano has played an immense role, not only in facilitating our ability to make nanostructures, but also to understand nanostructures through advanced imaging capabilities,” said Surendranath. “I see a lot of the future of MIT.nano around the question of how nanostructures evolve and change under the conditions that are relevant to their function. The tools at MIT.nano can help us sort that out.”

    Tech transfer and quantum computing

    The “Advanced Electronics” session chaired by Jesús del Alamo, the Donner Professor of Science in the Department of Electrical Engineering and Computer Science (EECS), brought together industry partners and MIT faculty for a panel discussion on the future of semiconductors and microelectronics. “Excellence in innovation is not enough, we also need to be excellent in transferring these to the marketplace,” said del Alamo. On this point, panelists spoke about strengthening the industry-university connection, as well as the importance of collaborative research environments and of access to advanced facilities, such as MIT.nano, for these environments to thrive.

    The session came on the heels of a startup exhibit in which eleven START.nano companies presented their technologies in health, energy, climate, and virtual reality, among other topics. START.nano, MIT.nano’s hard-tech accelerator, provides participants use of MIT.nano’s facilities at a discounted rate and access to MIT’s startup ecosystem. The program aims to ease hard-tech startups’ transition from the lab to the marketplace, surviving common “valleys of death” as they move from idea to prototype to scaling up.

    When asked about the state of quantum computing in the “Quantum Science and Engineering” session, physics professor Aram Harrow related his response to these startup challenges. “There are quite a few valleys to cross — there are the technical valleys, and then also the commercial valleys.” He spoke about scaling superconducting qubits and qubits made of suspended trapped ions, and the need for more scalable architectures, which we have the ingredients for, he said, but putting everything together is quite challenging.

    Throughout the session, William Oliver, professor of physics and the Henry Ellis Warren (1894) Professor of Electrical Engineering and Computer Science, asked the panelists how MIT.nano can address challenges in assembly and scalability in quantum science.

    “To harness the power of students to innovate, you really need to allow them to get their hands dirty, try new things, try all their crazy ideas, before this goes into a foundry-level process,” responded Kevin O’Brien, associate professor in EECS. “That’s what my group has been working on at MIT.nano, building these superconducting quantum processors using the state-of-the art fabrication techniques in MIT.nano.”

    Connecting the digital to the physical

    In his reflections on the semiconductor industry, Douglas Carlson, senior vice president for technology at MACOM, stressed connecting the digital world to real-world application. Later, in the “Immersive Data Technology” session, MIT.nano associate director Brian Anthony explained how, at the MIT.nano Immersion Lab, researchers are doing just that.

    “We think about and facilitate work that has the human immersed between hardware, data, and experience,” said Anthony, principal research scientist in mechanical engineering. He spoke about using the capabilities of the Immersion Lab to apply immersive technologies to different areas — health, sports, performance, manufacturing, and education, among others. Speakers in this session gave specific examples in hardware, pediatric health, and opera.

    Anthony connected this third pillar of MIT.nano to the fab and characterization facilities, highlighting how the Immersion Lab supports work conducted in other parts of the building. The Immersion Lab’s strength, he said, is taking novel work being developed inside MIT.nano and bringing it up to the human scale to think about applications and uses.

    Artworks that are scientifically inspired

    The Nano Summit closed with a reception at MIT.nano where guests could explore the facility and gaze through the cleanroom windows, where users were actively conducting research. Attendees were encouraged to visit an exhibition on MIT.nano’s first- and second-floor galleries featuring work by students from the MIT Program in Art, Culture, and Technology (ACT) who were invited to utilize MIT.nano’s tool sets and environments as inspiration for art.

    In his closing remarks, Bulović reflected on the community of people who keep MIT.nano running and who are using the tools to advance their research. “Today we are celebrating the facility and all the work that has been done over the last five years to bring it to where it is today. It is there to function not just as a space, but as an essential part of MIT’s mission in research, innovation, and education. I hope that all of us here today take away a deep appreciation and admiration for those who are leading the journey into the nano age.” More

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    Engineers develop an efficient process to make fuel from carbon dioxide

    The search is on worldwide to find ways to extract carbon dioxide from the air or from power plant exhaust and then make it into something useful. One of the more promising ideas is to make it into a stable fuel that can replace fossil fuels in some applications. But most such conversion processes have had problems with low carbon efficiency, or they produce fuels that can be hard to handle, toxic, or flammable.

    Now, researchers at MIT and Harvard University have developed an efficient process that can convert carbon dioxide into formate, a liquid or solid material that can be used like hydrogen or methanol to power a fuel cell and generate electricity. Potassium or sodium formate, already produced at industrial scales and commonly used as a de-icer for roads and sidewalks, is nontoxic, nonflammable, easy to store and transport, and can remain stable in ordinary steel tanks to be used months, or even years, after its production.

    The new process, developed by MIT doctoral students Zhen Zhang, Zhichu Ren, and Alexander H. Quinn; Harvard University doctoral student Dawei Xi; and MIT Professor Ju Li, is described this week in an open-access paper in Cell Reports Physical Science. The whole process — including capture and electrochemical conversion of the gas to a solid formate powder, which is then used in a fuel cell to produce electricity — was demonstrated at a small, laboratory scale. However, the researchers expect it to be scalable so that it could provide emissions-free heat and power to individual homes and even be used in industrial or grid-scale applications.

    Other approaches to converting carbon dioxide into fuel, Li explains, usually involve a two-stage process: First the gas is chemically captured and turned into a solid form as calcium carbonate, then later that material is heated to drive off the carbon dioxide and convert it to a fuel feedstock such as carbon monoxide. That second step has very low efficiency, typically converting less than 20 percent of the gaseous carbon dioxide into the desired product, Li says.

    By contrast, the new process achieves a conversion of well over 90 percent and eliminates the need for the inefficient heating step by first converting the carbon dioxide into an intermediate form, liquid metal bicarbonate. That liquid is then electrochemically converted into liquid potassium or sodium formate in an electrolyzer that uses low-carbon electricity, e.g. nuclear, wind, or solar power. The highly concentrated liquid potassium or sodium formate solution produced can then be dried, for example by solar evaporation, to produce a solid powder that is highly stable and can be stored in ordinary steel tanks for up to years or even decades, Li says.

    Several steps of optimization developed by the team made all the difference in changing an inefficient chemical-conversion process into a practical solution, says Li, who holds joint appointments in the departments of Nuclear Science and Engineering and of Materials Science and Engineering.

    The process of carbon capture and conversion involves first an alkaline solution-based capture that concentrates carbon dioxide, either from concentrated streams such as from power plant emissions or from very low-concentration sources, even open air, into the form of a liquid metal-bicarbonate solution. Then, through the use of a cation-exchange membrane electrolyzer, this bicarbonate is electrochemically converted into solid formate crystals with a carbon efficiency of greater than 96 percent, as confirmed in the team’s lab-scale experiments.

    These crystals have an indefinite shelf life, remaining so stable that they could be stored for years, or even decades, with little or no loss. By comparison, even the best available practical hydrogen storage tanks allow the gas to leak out at a rate of about 1 percent per day, precluding any uses that would require year-long storage, Li says. Methanol, another widely explored alternative for converting carbon dioxide into a fuel usable in fuel cells, is a toxic substance that cannot easily be adapted to use in situations where leakage could pose a health hazard. Formate, on the other hand, is widely used and considered benign, according to national safety standards.

    Several improvements account for the greatly improved efficiency of this process. First, a careful design of the membrane materials and their configuration overcomes a problem that previous attempts at such a system have encountered, where a buildup of certain chemical byproducts changes the pH, causing the system to steadily lose efficiency over time. “Traditionally, it is difficult to achieve long-term, stable, continuous conversion of the feedstocks,” Zhang says. “The key to our system is to achieve a pH balance for steady-state conversion.”

    To achieve that, the researchers carried out thermodynamic modeling to design the new process so that it is chemically balanced and the pH remains at a steady state with no shift in acidity over time. It can therefore continue operating efficiently over long periods. In their tests, the system ran for over 200 hours with no significant decrease in output. The whole process can be done at ambient temperatures and relatively low pressures (about five times atmospheric pressure).

    Another issue was that unwanted side reactions produced other chemical products that were not useful, but the team figured out a way to prevent these side reactions by the introduction of an extra “buffer” layer of bicarbonate-enriched fiberglass wool that blocked these reactions.

    The team also built a fuel cell specifically optimized for the use of this formate fuel to produce electricity. The stored formate particles are simply dissolved in water and pumped into the fuel cell as needed. Although the solid fuel is much heavier than pure hydrogen, when the weight and volume of the high-pressure gas tanks needed to store hydrogen is considered, the end result is an electricity output near parity for a given storage volume, Li says.

    The formate fuel can potentially be adapted for anything from home-sized units to large scale industrial uses or grid-scale storage systems, the researchers say. Initial household applications might involve an electrolyzer unit about the size of a refrigerator to capture and convert the carbon dioxide into formate, which could be stored in an underground or rooftop tank. Then, when needed, the powdered solid would be mixed with water and fed into a fuel cell to provide power and heat. “This is for community or household demonstrations,” Zhang says, “but we believe that also in the future it may be good for factories or the grid.”

    “The formate economy is an intriguing concept because metal formate salts are very benign and stable, and a compelling energy carrier,” says Ted Sargent, a professor of chemistry and of electrical and computer engineering at Northwestern University, who was not associated with this work. “The authors have demonstrated enhanced efficiency in liquid-to-liquid conversion from bicarbonate feedstock to formate, and have demonstrated these fuels can be used later to produce electricity,” he says.

    The work was supported by the U.S. Department of Energy Office of Science. More