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      in Environment

      Technologies for water conservation and treatment move closer to commercialization

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      The Abdul Latif Jameel Water and Food Systems Lab (J-WAFS) provides Solutions Grants to help MIT researchers launch startup companies or products to commercialize breakthrough technologies in water and food systems. The Solutions Grant Program began in 2015 and is supported by Community Jameel. In addition to one-year, renewable grants of up to $150,000, the program also matches grantees with industry mentors and facilitates introductions to potential investors. Since its inception, the J-WAFS Solutions Program has awarded over $3 million in funding to the MIT community. Numerous startups and products, including a portable desalination device and a company commercializing a novel food safety sensor, have spun out of this support.

      The 2023 J-WAFS Solutions Grantees are Professor C. Cem Tasan of the Department of Materials Science and Engineering and Professor Andrew Whittle of the Department of Civil and Environmental Engineering. Tasan’s project involves reducing water use in steel manufacturing and Whittle’s project tackles harmful algal blooms in water. Project work commences this September.

      “This year’s Solutions Grants are being award to professors Tasan and Whittle to help commercialize technologies they have been developing at MIT,” says J-WAFS executive director Renee J. Robins. “With J-WAFS’ support, we hope to see the teams move their technologies from the lab to the market, so they can have a beneficial impact on water use and water quality challenges,” Robins adds.

      Reducing water consumption by solid-state steelmaking

      Water is a major requirement for steel production. The steel industry ranks fourth in industrial freshwater consumption worldwide, since large amounts of water are needed mainly for cooling purposes in the process. Unfortunately, a strong correlation has also been shown to exist between freshwater use in steelmaking and water contamination. As the global demand for steel increases and freshwater availability decreases due to climate change, improved methods for more sustainable steel production are needed.

      A strategy to reduce the water footprint of steelmaking is to explore steel recycling processes that avoid liquid metal processing. With this motivation, Cem Tasan, the Thomas B. King Associate Professor of Metallurgy in the Department of Materials Science and Engineering, and postdoc Onur Guvenc PhD created a new process called Scrap Metal Consolidation (SMC). SMC is based on a well-established metal forming process known as roll bonding. Conventionally, roll bonding requires intensive prior surface treatment of the raw material, specific atmospheric conditions, and high deformation levels. Tasan and Guvenc’s research revealed that SMC can overcome these restrictions by enabling the solid-state bonding of scrap into a sheet metal form, even when the surface quality, atmospheric conditions, and deformation levels are suboptimal. Through lab-scale proof-of-principle investigations, they have already identified SMC process conditions and validated the mechanical formability of resulting steel sheets, focusing on mild steel, the most common sheet metal scrap.

      The J-WAFS Solutions Grant will help the team to build customer product prototypes, design the processing unit, and develop a scale-up strategy and business model. By simultaneously decreasing water usage, energy demand, contamination risk, and carbon dioxide burden, SMC has the potential to decrease the energy need for steel recycling by up to 86 percent, as well as reduce the linked carbon dioxide emissions and safeguard the freshwater resources that would otherwise be directed to industrial consumption. 

      Detecting harmful algal blooms in water before it’s too late

      Harmful algal blooms (HABs) are a growing problem in both freshwater and saltwater environments worldwide, causing an estimated $13 billion in annual damage to drinking water, water for recreational use, commercial fishing areas, and desalination activities. HABs pose a threat to both human health and aquaculture, thereby threatening the food supply. Toxins in HABs are produced by some cyanobacteria, or blue-green algae, whose communities change in composition in response to eutrophication from agricultural runoff, sewer overflows, or other events. Mitigation of risks from HABs are most effective when there is advance warning of these changes in algal communities. 

      Most in situ measurements of algae are based on fluorescence spectroscopy that is conducted with LED-induced fluorescence (LEDIF) devices, or probes that induce fluorescence of specific algal pigments using LED light sources. While LEDIFs provide reasonable estimates of concentrations of individual pigments, they lack resolution to discriminate algal classes within complex mixtures found in natural water bodies. In prior research, Andrew Whittle, the Edmund K. Turner Professor of Civil and Environmental Engineering, worked with colleagues to design REMORA, a low-cost, field-deployable prototype spectrofluorometer for measuring induced fluorescence. This research was part of a collaboration between MIT and the AMS Institute. Whittle and the team successfully trained a machine learning model to discriminate and quantify cell concentrations for mixtures of different algal groups in water samples through an extensive laboratory calibration program using various algae cultures. The group demonstrated these capabilities in a series of field measurements at locations in Boston and Amsterdam. 

      Whittle will work with Fábio Duarte of the Department of Urban Studies and Planning, the Senseable City Lab, and MIT’s Center for Real Estate to refine the design of REMORA. They will develop software for autonomous operation of the sensor that can be deployed remotely on mobile vessels or platforms to enable high-resolution spatiotemporal monitoring for harmful algae. Sensor commercialization will hopefully be able to exploit the unique capabilities of REMORA for long-term monitoring applications by water utilities, environmental regulatory agencies, and water-intensive industries.  More

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      in Energy

      Study suggests energy-efficient route to capturing and converting CO2

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      In the race to draw down greenhouse gas emissions around the world, scientists at MIT are looking to carbon-capture technologies to decarbonize the most stubborn industrial emitters.

      Steel, cement, and chemical manufacturing are especially difficult industries to decarbonize, as carbon and fossil fuels are inherent ingredients in their production. Technologies that can capture carbon emissions and convert them into forms that feed back into the production process could help to reduce the overall emissions from these “hard-to-abate” sectors.

      But thus far, experimental technologies that capture and convert carbon dioxide do so as two separate processes, that themselves require a huge amount of energy to run. The MIT team is looking to combine the two processes into one integrated and far more energy-efficient system that could potentially run on renewable energy to both capture and convert carbon dioxide from concentrated, industrial sources.

      In a study appearing today in ACS Catalysis, the researchers reveal the hidden functioning of how carbon dioxide can be both captured and converted through a single electrochemical process. The process involves using an electrode to attract carbon dioxide released from a sorbent, and to convert it into a reduced, reusable form.

      Others have reported similar demonstrations, but the mechanisms driving the electrochemical reaction have remained unclear. The MIT team carried out extensive experiments to determine that driver, and found that, in the end, it came down to the partial pressure of carbon dioxide. In other words, the more pure carbon dioxide that makes contact with the electrode, the more efficiently the electrode can capture and convert the molecule.

      Knowledge of this main driver, or “active species,” can help scientists tune and optimize similar electrochemical systems to efficiently capture and convert carbon dioxide in an integrated process.

      The study’s results imply that, while these electrochemical systems would probably not work for very dilute environments (for instance, to capture and convert carbon emissions directly from the air), they would be well-suited to the highly concentrated emissions generated by industrial processes, particularly those that have no obvious renewable alternative.

      “We can and should switch to renewables for electricity production. But deeply decarbonizing industries like cement or steel production is challenging and will take a longer time,” says study author Betar Gallant, the Class of 1922 Career Development Associate Professor at MIT. “Even if we get rid of all our power plants, we need some solutions to deal with the emissions from other industries in the shorter term, before we can fully decarbonize them. That’s where we see a sweet spot, where something like this system could fit.”

      The study’s MIT co-authors are lead author and postdoc Graham Leverick and graduate student Elizabeth Bernhardt, along with Aisyah Illyani Ismail, Jun Hui Law, Arif Arifutzzaman, and Mohamed Kheireddine Aroua of Sunway University in Malaysia.

      Breaking bonds

      Carbon-capture technologies are designed to capture emissions, or “flue gas,” from the smokestacks of power plants and manufacturing facilities. This is done primarily using large retrofits to funnel emissions into chambers filled with a “capture” solution — a mix of amines, or ammonia-based compounds, that chemically bind with carbon dioxide, producing a stable form that can be separated out from the rest of the flue gas.

      High temperatures are then applied, typically in the form of fossil-fuel-generated steam, to release the captured carbon dioxide from its amine bond. In its pure form, the gas can then be pumped into storage tanks or underground, mineralized, or further converted into chemicals or fuels.

      “Carbon capture is a mature technology, in that the chemistry has been known for about 100 years, but it requires really large installations, and is quite expensive and energy-intensive to run,” Gallant notes. “What we want are technologies that are more modular and flexible and can be adapted to more diverse sources of carbon dioxide. Electrochemical systems can help to address that.”

      Her group at MIT is developing an electrochemical system that both recovers the captured carbon dioxide and converts it into a reduced, usable product. Such an integrated system, rather than a decoupled one, she says, could be entirely powered with renewable electricity rather than fossil-fuel-derived steam.

      Their concept centers on an electrode that would fit into existing chambers of carbon-capture solutions. When a voltage is applied to the electrode, electrons flow onto the reactive form of carbon dioxide and convert it to a product using protons supplied from water. This makes the sorbent available to bind more carbon dioxide, rather than using steam to do the same.

      Gallant previously demonstrated this electrochemical process could work to capture and convert carbon dioxide into a solid carbonate form.

      “We showed that this electrochemical process was feasible in very early concepts,” she says. “Since then, there have been other studies focused on using this process to attempt to produce useful chemicals and fuels. But there’s been inconsistent explanations of how these reactions work, under the hood.”

      Solo CO2

      In the new study, the MIT team took a magnifying glass under the hood to tease out the specific reactions driving the electrochemical process. In the lab, they generated amine solutions that resemble the industrial capture solutions used to extract carbon dioxide from flue gas. They methodically altered various properties of each solution, such as the pH, concentration, and type of amine, then ran each solution past an electrode made from silver — a metal that is widely used in electrolysis studies and known to efficiently convert carbon dioxide to carbon monoxide. They then measured the concentration of carbon monoxide that was converted at the end of the reaction, and compared this number against that of every other solution they tested, to see which parameter had the most influence on how much carbon monoxide was produced.

      In the end, they found that what mattered most was not the type of amine used to initially capture carbon dioxide, as many have suspected. Instead, it was the concentration of solo, free-floating carbon dioxide molecules, which avoided bonding with amines but were nevertheless present in the solution. This “solo-CO2” determined the concentration of carbon monoxide that was ultimately produced.

      “We found that it’s easier to react this ‘solo’ CO2, as compared to CO2 that has been captured by the amine,” Leverick offers. “This tells future researchers that this process could be feasible for industrial streams, where high concentrations of carbon dioxide could efficiently be captured and converted into useful chemicals and fuels.”

      “This is not a removal technology, and it’s important to state that,” Gallant stresses. “The value that it does bring is that it allows us to recycle carbon dioxide some number of times while sustaining existing industrial processes, for fewer associated emissions. Ultimately, my dream is that electrochemical systems can be used to facilitate mineralization, and permanent storage of CO2 — a true removal technology. That’s a longer-term vision. And a lot of the science we’re starting to understand is a first step toward designing those processes.”

      This research is supported by Sunway University in Malaysia. More

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      in Energy

      Q&A: Three Tata Fellows on the program’s impact on themselves and the world

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      The Tata Fellowship at MIT gives graduate students the opportunity to pursue interdisciplinary research and work with real-world applications in developing countries. Part of the MIT Tata Center for Technology and Design, this fellowship contributes to the center’s goal of designing appropriate, practical solutions for resource-constrained communities. Three Tata Fellows — Serena Patel, Rameen Hayat Malik, and Ethan Harrison — discuss the impact of this program on their research, perspectives, and time at MIT.

      Serena Patel

      Serena Patel graduated from the University of California at Berkeley with a degree in energy engineering and a minor in energy and resources. She is currently pursuing her SM in technology and policy at MIT and is a Tata Fellow focusing on decarbonization in India using techno-economic modeling. Her interest in the intersection of technology, policy, economics, and social justice led her to attend COP27, where she experienced decision-maker and activist interactions firsthand.

      Q: How did you become interested in the Tata Fellowship, and how has it influenced your time at MIT?

      A: The Tata Center appealed to my interest in searching for creative, sustainable energy technologies that center collaboration with local-leading organizations. It has also shaped my understanding of the role of technology in sustainable development planning. Our current energy system disproportionately impacts marginalized communities, and new energy systems have the potential to perpetuate and/or create inequities. I am broadly interested in how we can put people at the core of our technological solutions and support equitable energy transitions. I specifically work on techno-economic modeling to analyze the potential for an early retirement of India’s large coal fleet and conversion to long-duration thermal energy storage. This could mitigate job losses from rapid transitions, support India’s energy system decarbonization plan, and provide a cost-effective way to retire stranded assets.

      Q: Why is interdisciplinary study important to real-world solutions for global communities, and how has working at the intersection of technology and policy influenced your research?

      A: Technology and policy work together in mediating and regulating the world around us. Technological solutions can be disruptive in all the good ways, but they can also do a lot of harm and perpetuate existing inequities. Interdisciplinary studies are important to mitigate these interrelated issues so innovative ideas in the ivory towers of Western academia do not negatively impact marginalized communities. For real-world solutions to positively impact individuals, marginalized communities need to be centered within the research design process. I think the research community’s perspective on real-world, global solutions is shifting to achieve these goals, but much work remains for resources to reach the right communities.

      The energy space is especially fascinating because it impacts everyone’s quality of life in overt or nuanced ways. I’ve had the privilege of taking classes that sit at the intersection of energy technology and policy, involving land-use law, geographic representation, energy regulation, and technology policy. In general, working at the intersection of technology and policy has shaped my perspective on how regulation influences widespread technology adoption and the overall research directions and assumptions in our energy models.

      Q: How has your experience at COP27 influenced your approach to your research?

      A: Attending COP27 at Sharm El-Sheikh, Egypt, last November influenced my understanding of the role of science, research, and activism in climate negotiations and action. Science and research are often promoted as necessary for sharing knowledge at the higher levels, but they were also used as a delay tactic by negotiators. I heard how institutional bodies meant to support fair science and research often did not reach intended stakeholders. Lofty goals or financial commitments to ensure global climate stability and resilience still lacked implementation and coordination with deep technology transfer and support. On the face of it, these agreements have impact and influence, but I heard many frustrations over the lack of tangible, local support. This has driven my research to be as context-specific as possible, to provide actionable insights and leverage different disciplines.

      I also observed the role of activism in the negotiations. Decision-makers are accountable to their country, and activists are spreading awareness and bringing transparency to the COP process. As a U.S. citizen, I suddenly became more aware of how political engagement and awareness in the country could push the boundaries of international climate agreements if the government were more aligned on climate action.

      Rameen Hayat Malik

      Rameen Hayat Malik graduated from the University of Sydney with a bachelor’s degree in chemical and biomolecular engineering and a Bachelor of Laws. She is currently pursuing her SM in technology and policy and is a Tata Fellow researching the impacts of electric vehicle (EV) battery production in Indonesia. Originally from Australia, she first became interested in the geopolitical landscape of resources trade and its implications for the clean energy transition while working in her native country’s Department of Climate Change, Energy, the Environment and Water.

      Q: How did you become interested in the Tata Fellowship, and how has it influenced your time at MIT?

      A: I came across the Tata Fellowship while looking for research opportunities that aligned with my interest in understanding how a just energy transition will occur in a global context, with a particular focus on emerging economies. My research explores the techno-economic, social, and environmental impacts of nickel mining in Indonesia as it seeks to establish itself as a major producer of EV batteries. The fellowship’s focus on community-driven research has given me the freedom to guide the scope of my research. It has allowed me to integrate a community voice into my work that seeks to understand the impact of this mining on forest-dependent communities, Indigenous communities, and workforce development.

      Q: Battery technology and production are highly discussed in the energy sector. How does your research on Indonesia’s battery production contribute to the current discussion around batteries, and what drew you to this topic?

      A: Indonesia is one of the world’s largest exporters of coal, while also having one of the largest nickel reserves in the world — a key mineral for EV battery production. This presents an exciting opportunity for Indonesia to be a leader in the energy transition, as it both seeks to phase out coal production and establish itself as a key supplier of critical minerals. It is also an opportunity to actually apply principles of a just transition to the region, which seeks to repurpose and re-skill existing coal workforces, to bring Indigenous communities into the conversation around the future of their lands, and to explore whether it is actually possible to sustainably and ethically produce nickel for EV battery production.

      I’ve always seen battery technologies and EVs as products that, at least today, are accessible to a small, privileged customer base that can afford such technologies. I’m interested in understanding how we can make such products more widely affordable and provide our lowest-income communities with the opportunities to actively participate in the transition — especially since access to transportation is a key driver of social mobility. With nickel prices impacting EV prices in such a dramatic way, unlocking more nickel supply chains presents an opportunity to make EV batteries more accessible and affordable.

      Q: What advice would you give to new students who want to be a part of real-world solutions to the climate crisis?

      A: Bring your whole self with you when engaging these issues. Quite often we get caught up with the technology or modeling aspect of addressing the climate crisis and forget to bring people and their experiences into our work. Think about your positionality: Who is your community, what are the avenues you have to bring that community along, and what privileges do you hold to empower and amplify voices that need to be heard? Find a piece of this complex puzzle that excites you, and find opportunities to talk and listen to people who are directly impacted by the solutions you are looking to explore. It can get quite overwhelming working in this space, which carries a sense of urgency, politicization, and polarization with it. Stay optimistic, keep advocating, and remember to take care of yourself while doing this important work.

      Ethan Harrison

      After earning his degree in economics and applied science from the College of William and Mary, Ethan Harrison worked at the United Nations Development Program in its Crisis Bureau as a research officer focused on conflict prevention and predictive analysis. He is currently pursuing his SM in technology and policy at MIT. In his Tata Fellowship, he focuses on the impacts of the Ukraine-Russia conflict on global vulnerability and the global energy market.

      Q: How did you become interested in the Tata Fellowship, and how has it influenced your time at MIT?

      A: Coming to MIT, one of my chief interests was figuring out how we can leverage gains from technology to improve outcomes and build pro-poor solutions in developing and crisis contexts. The Tata Fellowship aligned with many of the conclusions I drew while working in crisis contexts and some of the outstanding questions that I was hoping to answer during my time at MIT, specifically: How can we leverage technology to build sustainable, participatory, and ethically grounded interventions in these contexts?

      My research currently examines the secondary impacts of the Ukraine-Russia conflict on low- and middle-income countries — especially fragile states — with a focus on shocks in the global energy market. This includes the development of a novel framework that systematically identifies factors of vulnerability — such as in energy, food systems, and trade dependence — and quantitatively ranks countries by their level of vulnerability. By identifying the specific mechanisms by which these countries are vulnerable, we can develop a map of global vulnerability and identify key policy solutions that can insulate countries from current and future shocks.

      Q: I understand that your research deals with the relationship between oil and gas price fluctuation and political stability. What has been the most surprising aspect of this relationship, and what are its implications for global decarbonization?

      A: One surprising aspect is the degree to which citizen grievances regarding price fluctuations can quickly expand to broader democratic demands and destabilization. In Sri Lanka last year and in Egypt during the Arab spring, initial protests around fuel prices and power outages eventually led to broader demands and the loss of power by heads of state. Another surprising aspect is the popularity of fuel subsidies despite the fact that they are economically regressive: They often comprise a large proportion of GDP in poor countries, disproportionately benefit higher-income populations, and leave countries vulnerable to fiscal stress during price spikes.

      Regarding implications for global decarbonization, one project we are pursuing examines the implications of directing financing from fuel subsidies toward investments in renewable energy. Countries that rely on fossil fuels for electricity have been hit especially hard 
by price spikes from the Ukraine-Russia conflict, especially since many were carrying costly fuel subsidies to keep the price of fuel and energy artificially low. Much of the international community is advocating for low-income countries to invest in renewables and reduce their fossil fuel burden, but it’s important to explore how global decarbonization can align with efforts to end energy poverty and other Sustainable Development Goals.

      Q: How does your research impact the Tata Center’s goal of transforming policy research into real-world solutions, and why is this important?

      A: The crisis in Ukraine has shifted the international community’s focus away from other countries in crisis, such as Yemen and Lebanon. By developing a global map of vulnerability, we’re building a large evidence base on which countries have been most impacted by this crisis. Most importantly, by identifying individual channels of vulnerability for each country, we can also identify the most effective policy solutions to insulate vulnerable populations from shocks. Whether that’s advocating for short-term social protection programs or identifying more medium-term policy solutions — like fuel banks or investment in renewables — we hope providing a detailed map of sources of vulnerability can help inform the global response to shocks imposed by the Russia-Ukraine conflict and post-Covid recovery. More

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      in Energy

      Alumnus’ thermal battery helps industry eliminate fossil fuels

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      The explosion of renewable energy projects around the globe is leading to a saturation problem. As more renewable power contributes to the grid, the value of electricity is plummeting during the times of day when wind and solar hit peak productivity. The problem is limiting renewable energy investments in some of the sunniest and windiest places in the world.

      Now Antora Energy, co-founded by David Bierman SM ’14, PhD ’17, is addressing the intermittent nature of wind and solar with a low-cost, highly efficient thermal battery that stores electricity as heat to allow manufacturers and other energy-hungry businesses to eliminate their use of fossil fuels.

      “We take electricity when it’s cheapest, meaning when wind gusts are strongest and the sun is shining brightest,” Bierman explains. “We run that electricity through a resistive heater to drive up the temperature of a very inexpensive material — we use carbon blocks, which are extremely stable, produced at incredible scales, and are some of the cheapest materials on Earth. When you need to pull energy from the battery, you open a large shutter to extract thermal radiation, which is used to generate process heat or power using our thermophotovoltaic, or TPV, technology. The end result is a zero-carbon, flexible, combined heat and power system for industry.”

      Antora’s battery could dramatically expand the application of renewable energy by enabling its use in industry, a sector of the U.S. economy that accounted for nearly a quarter of all greenhouse gas emissions in 2021.

      Antora says it is able to deliver on the long-sought promise of heat-to-power TPV technology because it has achieved new levels of efficiency and scalability with its cells. Earlier this year, Antora opened a new manufacturing facility that will be capable of producing 2 megawatts of its TPV cells each year — which the company says makes it the largest TPV production facility in the world.

      Antora’s thermal battery manufacturing facilities and demonstration unit are located in sun-soaked California, where renewables make up close to a third of all electricity. But Antora’s team says its technology holds promise in other regions as increasingly large renewable projects connect to grids across the globe.

      “We see places today [with high renewables] as a sign of where things are going,” Bierman says. “If you look at the tailwinds we have in the renewable industry, there’s a sense of inevitability about solar and wind, which will need to be deployed at incredible scales to avoid a climate catastrophe. We’ll see terawatts and terawatts of new additions of these renewables, so what you see today in California or Texas or Kansas, with significant periods of renewable overproduction, is just the tip of the iceberg.”

      Bierman has been working on thermal energy storage and thermophotovoltaics since his time at MIT, and Antora’s ties to MIT are especially strong because its progress is the result of two MIT startups becoming one.

      Alumni join forces

      Bierman did his masters and doctoral work in MIT’s Department of Mechanical Engineering, where he worked on solid-state solar thermal energy conversion systems. In 2016, while taking course 15.366 (Climate and Energy Ventures), he met Jordan Kearns SM ’17, then a graduate student in the Technology and Policy Program and the Department of Nuclear Science and Engineering. The two were studying renewable energy when they began to think about the intermittent nature of wind and solar as an opportunity rather than a problem.

      “There are already places in the U.S. where we have more wind and solar at times than we know what to do with,” Kearns says. “That is an opportunity for not only emissions reductions but also for reducing energy costs. What’s the application? I don’t think the overproduction of energy was being talked about as much as the intermittency problem.”

      Kearns did research through the MIT Energy Initiative and the researchers received support from MIT’s Venture Mentoring Service and the MIT Sandbox Innovation Fund to further explore ways to capitalize on fluctuating power prices.

      Kearns officially founded a company called Medley Thermal in 2017 to help companies that use natural gas switch to energy produced by renewables when the price was right. To accomplish that, he combined an off-the-shelf electric boiler with novel control software so the companies could switch energy sources seamlessly from fossil fuel to electricity at especially windy or sunny times. Medley went on to become a finalist for the MIT Clean Energy Prize, and Kearns wanted Bierman to join him as a co-founder, but Bierman had received a fellowship to commercialize a thermal energy storage solution and decided to pursue that after graduation.

      The split ended up working out for both alumni. In the ensuing years, Kearns led Medley Thermal through a number of projects in which gradually larger companies switched from relying on natural gas or propane sources to renewable electricity from the grid. The work culminated in an installment at the Jay Peak resort in Vermont that Kearns says is one of the largest projects in the U.S. using renewable energy to produce heat. The project is expected to reduce about 2,500 tons of carbon dioxide per year.

      Bierman, meanwhile, further developed a thermal energy storage solution for industrial decarbonization, which works by using renewable electricity to heat blocks of carbon, which are stored in insulation to retain energy for long periods of time. The heat from those blocks can then be used to deliver electricity or heat to customers, at temperatures that can exceed 1,500 C. When Antora raised a $50 million Series A funding round last year, Bierman asked Kearns if he could buy out Medley’s team, and the researchers finally became co-workers.

      “Antora and Medley Thermal have a similar value prop: There’s low-cost electricity, and we want to connect that to the industrial sector,” Kearns explains. “But whereas Medley used renewables on an as-available basis, and then when the winds stop we went back to burning fossil fuel with a boiler, Antora has a thermal battery that takes in the electricity, converts it to heat, but also stores it as heat so even when the wind stops blowing we have a reservoir of heat that we can continue to pull from to make steam or power or whatever the facility needs. So, we can now further reduce energy costs by offsetting more fuel and offer a 100 percent clean energy solution.”

      United we scale

      Today, Kearns runs the project development arm of Antora.

      “There are other, much larger projects in the pipeline,” Kearns says. “The Jay Peak project is about 3 megawatts of power, but some of the ones we’re working on now are 30, 60 megawatt projects. Those are more industrial focused, and they’re located in places where we have a strong industrial base and an abundance of renewables, everywhere from Texas to Kansas to the Dakotas — that heart of the country that our team lovingly calls the Wind Belt.”

      Antora’s future projects will be with companies in the chemicals, mining, food and beverage, and oil and gas industries. Some of those projects are expected to come online as early as 2025.          

      The company’s scaling strategy is centered on the inexpensive production process for its batteries.

      “We constantly ask ourselves, ‘What is the best product we can make here?’” Bierman says. “We landed on a compact, containerized, modular system that gets shipped to sites and is easily integrated into industrial processes. It means we don’t have huge construction projects, timelines, and budget overruns. Instead, it’s all about scaling up the factory that builds these thermal batteries and just churning them out.”

      It was a winding journey for Kearns and Bierman, but they now believe they’re positioned to help huge companies become carbon-free while promoting the growth of the solar and wind industries.

      “The more I dig into this, the more shocked I am at how important a piece of the decarbonization puzzle this is today,” Bierman says. “The need has become super real since we first started talking about this in 2016. The economic opportunity has grown, but more importantly the awareness from industries that they need to decarbonize is totally different. Antora can help with that, so we’re scaling up as rapidly as possible to meet the demand we see in the market.” More

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      in Environment

      3 Questions: Boosting concrete’s ability to serve as a natural “carbon sink”

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      Damian Stefaniuk is a postdoc at the MIT Concrete Sustainability Hub (CSHub). He works with MIT professors Franz-Josef Ulm and Admir Masic of the MIT Department of Civil and Environmental Engineering (CEE) to investigate multifunctional concrete. Here, he provides an overview of carbonation in cement-based products, a brief explanation of why understanding carbonation in the life cycle of cement products is key for assessing their environmental impact, and an update on current research to bolster the process.

      Q: What is carbonation and why is it important for thinking about concrete from a life-cycle perspective?

      A: Carbonation is the reaction between carbon dioxide (CO2) and certain compounds in cement-based products, occurring during their use phase and end of life. It forms calcium carbonate (CaCO3) and has important implications for neutralizing the GHG [greenhouse gas] emissions and achieving carbon neutrality in the life cycle of concrete.

      Firstly, carbonation causes cement-based products to act as natural carbon sinks, sequestering CO2 from the air and storing it permanently. This helps mitigate the carbon emissions associated with the production of cement, reducing their overall carbon footprint.

      Secondly, carbonation affects concrete properties. Early-stage carbonation may increase the compressive strength of cement-based products, enhancing their durability and structural performance. However, late-stage carbonation can impact corrosion resistance in steel-reinforced concrete due to reduced alkalinity.

      Considering carbonation in the life cycle of cement-based products is crucial for accurately assessing their environmental impact. Understanding and leveraging carbonation can help industry reduce carbon emissions and maximize carbon sequestration potential. Paying close attention to it in the design process aids in creating durable and corrosion-resistant structures, contributing to longevity and overall sustainability.

      Q: What are some ongoing global efforts to force carbonation?

      A: Some ongoing efforts to force carbonation in concrete involve artificially increasing the amount of CO2 gas present during the early-stage hydration of concrete. This process, known as forced carbonation, aims to accelerate the carbonation reaction and its associated benefits.

      Forced carbonation is typically applied to precast concrete elements that are produced in artificially CO2-rich environments. By exposing fresh concrete to higher concentrations of CO2 during curing, the carbonation process can be expedited, resulting in potential improvements in strength, reduced water absorption, improved resistance to chloride permeability, and improved performance during freeze-thaw. At the same time, it can be difficult to quantify how much CO2 is absorbed and released because of the process.

      These efforts to induce early-stage carbonation through forced carbonation represent the industry’s focus on optimizing concrete performance and environmental impacts. By exploring methods to enhance the carbonation process, researchers and practitioners seek to more efficiently harness its benefits, such as increasing strength and sequestering CO2.

      It is important to note that forced carbonation requires careful implementation and monitoring to ensure desired outcomes. The specific procedures and conditions vary based on the application and intended goals, highlighting the need for expertise and controlled environments.

      Overall, ongoing efforts in forced carbonation contribute to the continuous development of concrete technology, aiming to improve its properties and reduce its carbon footprint throughout the life cycle of the material.

      Q: What is chemically-induced pre-cure carbonation, and what implications does it have?

      A: Chemically-induced pre-cure carbonation (CIPCC) is a method developed by the MIT CSHub to mineralize and permanently store CO2 in cement. Unlike traditional forced carbonation methods, CIPCC introduces CO2 into the concrete mix as a solid powder, specifically sodium bicarbonate. This approach addresses some of the limitations of current carbon capture and utilization technologies.

      The implications of CIPCC are significant. Firstly, it offers convenience for cast-in-place applications, making it easier to incorporate CO2 use in concrete projects. Unlike some other approaches, CIPCC allows for precise control over the quantity of CO2 sequestered in the concrete. This ensures accurate carbonation and facilitates better management of the storage process. CIPCC also builds on previous research regarding amorphous hydration phases, providing an additional mechanism for CO2 sequestration in cement-based products. These phases carbonate through CIPCC, contributing to the overall carbon sequestration capacity of the material.

      Furthermore, early-stage pre-cure carbonation shows promise as a pathway for concrete to permanently sequester a controlled and precise quantity of CO2. Our recent paper in PNAS Nexus suggests that it could theoretically offset at least 40 percent of the calcination emissions associated with cement production, when anticipating advances in the lower-emissions production of sodium bicarbonate. We also found that up to 15 percent of cement (by weight) could be substituted with sodium bicarbonate without compromising the mechanical performance of a given mix. Further research is needed to evaluate long-term effects of this process to explore the potential life-cycle savings and impacts of carbonation.

      CIPCC offers not only environmental benefits by reducing carbon emissions, but also practical advantages. The early-stage strength increase observed in real-world applications could expedite construction timelines by allowing concrete to reach its full strength faster.

      Overall, CIPCC demonstrates the potential for more efficient and controlled CO2 sequestration in concrete. It represents an important development in concrete sustainability, emphasizing the need for further research and considering the material’s life-cycle impacts.

      This research was carried out by MIT CSHub, which is sponsored by the Concrete Advancement Foundation and the Portland Cement Association. More

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      in Energy

      MIT engineers create an energy-storing supercapacitor from ancient materials

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      Two of humanity’s most ubiquitous historical materials, cement and carbon black (which resembles very fine charcoal), may form the basis for a novel, low-cost energy storage system, according to a new study. The technology could facilitate the use of renewable energy sources such as solar, wind, and tidal power by allowing energy networks to remain stable despite fluctuations in renewable energy supply.

      The two materials, the researchers found, can be combined with water to make a supercapacitor — an alternative to batteries — that could provide storage of electrical energy. As an example, the MIT researchers who developed the system say that their supercapacitor could eventually be incorporated into the concrete foundation of a house, where it could store a full day’s worth of energy while adding little (or no) to the cost of the foundation and still providing the needed structural strength. The researchers also envision a concrete roadway that could provide contactless recharging for electric cars as they travel over that road.

      The simple but innovative technology is described this week in the journal PNAS, in a paper by MIT professors Franz-Josef Ulm, Admir Masic, and Yang-Shao Horn, and four others at MIT and at the Wyss Institute for Biologically Inspired Engineering.

      Capacitors are in principle very simple devices, consisting of two electrically conductive plates immersed in an electrolyte and separated by a membrane. When a voltage is applied across the capacitor, positively charged ions from the electrolyte accumulate on the negatively charged plate, while the positively charged plate accumulates negatively charged ions. Since the membrane in between the plates blocks charged ions from migrating across, this separation of charges creates an electric field between the plates, and the capacitor becomes charged. The two plates can maintain this pair of charges for a long time and then deliver them very quickly when needed. Supercapacitors are simply capacitors that can store exceptionally large charges.

      The amount of power a capacitor can store depends on the total surface area of its conductive plates. The key to the new supercapacitors developed by this team comes from a method of producing a cement-based material with an extremely high internal surface area due to a dense, interconnected network of conductive material within its bulk volume. The researchers achieved this by introducing carbon black — which is highly conductive — into a concrete mixture along with cement powder and water, and letting it cure. The water naturally forms a branching network of openings within the structure as it reacts with cement, and the carbon migrates into these spaces to make wire-like structures within the hardened cement. These structures have a fractal-like structure, with larger branches sprouting smaller branches, and those sprouting even smaller branchlets, and so on, ending up with an extremely large surface area within the confines of a relatively small volume. The material is then soaked in a standard electrolyte material, such as potassium chloride, a kind of salt, which provides the charged particles that accumulate on the carbon structures. Two electrodes made of this material, separated by a thin space or an insulating layer, form a very powerful supercapacitor, the researchers found.

      The two plates of the capacitor function just like the two poles of a rechargeable battery of equivalent voltage: When connected to a source of electricity, as with a battery, energy gets stored in the plates, and then when connected to a load, the electrical current flows back out to provide power.

      “The material is fascinating,” Masic says, “because you have the most-used manmade material in the world, cement, that is combined with carbon black, that is a well-known historical material — the Dead Sea Scrolls were written with it. You have these at least two-millennia-old materials that when you combine them in a specific manner you come up with a conductive nanocomposite, and that’s when things get really interesting.”

      As the mixture sets and cures, he says, “The water is systematically consumed through cement hydration reactions, and this hydration fundamentally affects nanoparticles of carbon because they are hydrophobic (water repelling).” As the mixture evolves, “the carbon black is self-assembling into a connected conductive wire,” he says. The process is easily reproducible, with materials that are inexpensive and readily available anywhere in the world. And the amount of carbon needed is very small — as little as 3 percent by volume of the mix — to achieve a percolated carbon network, Masic says.

      Supercapacitors made of this material have great potential to aid in the world’s transition to renewable energy, Ulm says. The principal sources of emissions-free energy, wind, solar, and tidal power, all produce their output at variable times that often do not correspond to the peaks in electricity usage, so ways of storing that power are essential. “There is a huge need for big energy storage,” he says, and existing batteries are too expensive and mostly rely on materials such as lithium, whose supply is limited, so cheaper alternatives are badly needed. “That’s where our technology is extremely promising, because cement is ubiquitous,” Ulm says.

      The team calculated that a block of nanocarbon-black-doped concrete that is 45 cubic meters (or yards) in size — equivalent to a cube about 3.5 meters across — would have enough capacity to store about 10 kilowatt-hours of energy, which is considered the average daily electricity usage for a household. Since the concrete would retain its strength, a house with a foundation made of this material could store a day’s worth of energy produced by solar panels or windmills and allow it to be used whenever it’s needed. And, supercapacitors can be charged and discharged much more rapidly than batteries.

      After a series of tests used to determine the most effective ratios of cement, carbon black, and water, the team demonstrated the process by making small supercapacitors, about the size of some button-cell batteries, about 1 centimeter across and 1 millimeter thick, that could each be charged to 1 volt, comparable to a 1-volt battery. They then connected three of these to demonstrate their ability to light up a 3-volt light-emitting diode (LED). Having proved the principle, they now plan to build a series of larger versions, starting with ones about the size of a typical 12-volt car battery, then working up to a 45-cubic-meter version to demonstrate its ability to store a house-worth of power.

      There is a tradeoff between the storage capacity of the material and its structural strength, they found. By adding more carbon black, the resulting supercapacitor can store more energy, but the concrete is slightly weaker, and this could be useful for applications where the concrete is not playing a structural role or where the full strength-potential of concrete is not required. For applications such as a foundation, or structural elements of the base of a wind turbine, the “sweet spot” is around 10 percent carbon black in the mix, they found.

      Another potential application for carbon-cement supercapacitors is for building concrete roadways that could store energy produced by solar panels alongside the road and then deliver that energy to electric vehicles traveling along the road using the same kind of technology used for wirelessly rechargeable phones. A related type of car-recharging system is already being developed by companies in Germany and the Netherlands, but using standard batteries for storage.

      Initial uses of the technology might be for isolated homes or buildings or shelters far from grid power, which could be powered by solar panels attached to the cement supercapacitors, the researchers say.

      Ulm says that the system is very scalable, as the energy-storage capacity is a direct function of the volume of the electrodes. “You can go from 1-millimeter-thick electrodes to 1-meter-thick electrodes, and by doing so basically you can scale the energy storage capacity from lighting an LED for a few seconds, to powering a whole house,” he says.

      Depending on the properties desired for a given application, the system could be tuned by adjusting the mixture. For a vehicle-charging road, very fast charging and discharging rates would be needed, while for powering a home “you have the whole day to charge it up,” so slower-charging material could be used, Ulm says.

      “So, it’s really a multifunctional material,” he adds. Besides its ability to store energy in the form of supercapacitors, the same kind of concrete mixture can be used as a heating system, by simply applying electricity to the carbon-laced concrete.

      Ulm sees this as “a new way of looking toward the future of concrete as part of the energy transition.”

      The research team also included postdocs Nicolas Chanut and Damian Stefaniuk at MIT’s Department of Civil and Environmental Engineering, James Weaver at the Wyss Institute, and Yunguang Zhu in MIT’s Department of Mechanical Engineering. The work was supported by the MIT Concrete Sustainability Hub, with sponsorship by the Concrete Advancement Foundation. More

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      in Environment

      Harnessing synthetic biology to make sustainable alternatives to petroleum products

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      Reducing our reliance on fossil fuels is going to require a transformation in the way we make things. That’s because the hydrocarbons found in fuels like crude oil, natural gas, and coal are also in everyday items like plastics, clothing, and cosmetics.

      Now Visolis, founded by Deepak Dugar SM ’11, MBA ’13, PhD ’13, is combining synthetic biology with chemical catalysis to reinvent the way the world makes things — and reducing gigatons of greenhouse gas emissions in the process.

      The company — which uses a microbe to ferment biomass waste like wood chips and create a molecular building block called mevalonic acid — is more sustainably producing everything from car tires and cosmetics to aviation fuels by tweaking the chemical processes involved to make different byproducts.

      “We started with [the rubber component] isoprene as the main molecule we produce [from mevalonic acid], but we’ve expanded our platform with this unique combination of chemistry and biology that allows us to decarbonize multiple supply chains very rapidly and efficiently,” Dugar explains. “Imagine carbon-negative yoga pants. We can make that happen. Tires can be carbon-negative, personal care can lower its footprint — and we’re already selling into personal care. So in everything from personal care to apparel to industrial goods, our platform is enabling decarbonization of manufacturing.”

      “Carbon-negative” is a term Dugar uses a lot. Visolis has already partnered with some of the world’s largest consumers of isoprene, a precursor to rubber, and now Dugar wants to prove out the company’s process in other emissions-intensive industries.

      “Our process is carbon-negative because plants are taking CO2 from the air, and we take that plant matter and process it into something structural, like synthetic rubber, which is used for things like roofing, tires, and other applications,” Dugar explains. “Generally speaking, most of that material at the end of its life gets recycled, for example to tarmac or road, or, worst-case scenario, it ends up in a landfill, so the CO2 that was captured by the plant matter stays captured in the materials. That means our production can be carbon-negative depending on the emissions of the production process. That allows us to not only reduce climate change but start reversing it. That was an insight I had about 10 years ago at MIT.”

      Finding a path

      For his PhD, Dugar explored the economics of using microbes to make high-octane gas additives. He also took classes at the MIT Sloan School of Management on sustainability and entrepreneurship, including the particularly influential course 15.366 (Climate and Energy Ventures). The experience inspired him to start a company.

      “I wanted to work on something that could have the largest climate impact, and that was replacing petroleum,” Dugar says. “It was about replacing petroleum not just as a fuel but as a material as well. Everything from the clothes we wear to the furniture we sit on is often made using petroleum.”

      By analyzing recent advances in synthetic biology and making some calculations from first principles, Dugar decided that a microbial approach to cleaning up the production of rubber was viable. He participated in the MIT Clean Energy Prize and worked with others at MIT to prove out the idea. But it was still just an idea. After graduation, he took a consulting job at a large company, spending his nights and weekends renting lab space to continue trying to make his sustainable rubber a reality.

      After 18 months, by applying engineering concepts like design-for-scale to synthetic biology, Dugar was able to develop a microbe that met 80 percent of his criteria for making an intermediate molecule called mevalonic acid. From there, he developed a chemical catalysis process that converted mevalonic acid to isoprene, the main component of natural rubber. Visolis has since patented other chemical conversion processes that turn mevalonic acid to aviation fuel, polymers, and fabrics.

      Dugar left his consulting job in 2014 and was awarded a fellowship to work on Visolis full-time at the Lawrence Berkeley National Lab via Activate, an incubator empowering scientists to reinvent the world.

      From rubber to jet fuels

      Today, in addition to isoprene, Visolis is selling skin care products through the brand Ameva Bio, which produces mevalonic acid-based creams by recycling plant byproducts created in other processes. The company offers refillable bottles and even offsets emissions from the shipping of its products.

      “We are working throughout the supply chain,” Dugar says. “It made sense to clean up the isoprene part of the rubber supply chain rather than the entire supply chain. But we’re also producing molecules for skin that are better for you, so you can put something much more sustainable and healthier on your body instead of petrochemicals. We launched Ameva to demonstrate that brands can leverage synthetic biology to turn carbon-negative ingredients into high-performing products.”

      Visolis is also starting the process of gaining regulatory approval for its sustainable aviation fuel, which Dugar believes could have the biggest climate impact of any of the company’s products by cleaning up the production of fuels for commercial flight.

      “We’re working with leading companies to help them decarbonize aviation” Dugar says. “If you look at the lifecycle of fuel, the current petroleum-based approach is we dig out hydrocarbons from the ground and burn it, emitting CO2 into the air. In our process, we take plant matter, which affixes to CO2 and captures renewable energy in those bonds, and then we transfer that into aviation fuel plus things like synthetic rubber, yoga pants, and other things that continue to hold the carbon. So, our factories can still operate at net zero carbon emissions.”

      Visolis is already generating millions of dollars in revenue, and Dugar says his goal is to scale the company rapidly now that its platform molecule has been validated.

      “We have been scaling our technology by 10 times every two to three years and are now looking to increase deployment of our technology at the same pace, which is very exciting.” Dugar says. “If you extrapolate that, very quickly you get to massive impact. That’s our goal.” More

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      in Energy

      MIT welcomes Brian Deese as its next Institute Innovation Fellow

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      MIT has appointed former White House National Economic Council (NEC) director Brian Deese as an MIT Innovation Fellow, focusing on the impact of economic policies that strengthen the United States’ industrial capacity and on accelerating climate investment and innovation. Deese will begin his appointment this summer. 

      “From climate change to U.S. industrial strategy, the people of MIT strive to make serious positive change at scale — and in Brian Deese, we have found a brilliant ally, guide, and inspiration,“ says MIT President Sally Kornbluth. “He pairs an easy command of technological questions with a rare grasp of contemporary policy and the politics it takes for such policies to succeed. We are extremely fortunate to have Brian with us for this pivotal year.” 

      Deese is an accomplished public policy innovator. As President Joe Biden’s top economic advisor, he was instrumental in shaping several pieces of legislation — the bipartisan Infrastructure Investment and Jobs Act, the CHIPS and Science Act, and the Inflation Reduction Act  — that together are expected to yield more than $3 trillion over the next decade in public and private investments in physical infrastructure, semiconductors, and clean energy, as well as a major expansion of scientific research. 

      “I was attracted to MIT by its combination of extraordinary capabilities in engineering, science, and economics, and the desire and enthusiasm to translate those capabilities into real-world outcomes,” says Deese. 

      Climate and economic policy expertise

      Deese’s public service career has spanned multiple periods of global economic crisis. He has helped shape policies ranging from clean energy infrastructure investments to addressing supply chain disruptions triggered by the pandemic and the war in Ukraine. 

      As NEC director in the Biden White House, Deese oversaw the development of domestic and international economic policy. Previously, he served as the global head of sustainable investing at BlackRock, Inc., one of the world’s leading asset management firms; before that, he held several key posts in the Obama White House, serving as the president’s top advisor on climate policy; deputy director of the Office of Management and Budget; and deputy director of the NEC. Early in the Obama Administration, Deese played a key role in developing and implementing the rescue of the U.S. auto industry during the Great Recession. Deese earned a bachelor of arts degree from Middlebury College and his JD from Yale Law School.

      Despite recent legislative progress, the world still faces daunting climate and energy challenges, including the need to reduce greenhouse gas emissions, increase energy capacity, and fill infrastructure gaps, Deese notes.

      “Our biggest challenge is our biggest opportunity,” he says. “We need to build at a speed not seen in generations.”  

      Deese is also thinking about how to effectively design and implement industrial strategy approaches that build on recent efforts to restore the U.S. semiconductor industry. What’s needed, he says, is an approach that can foster innovation and build manufacturing capacity — especially in economically disadvantaged areas of the country — while learning lessons from previous successes and failures in this field. 

      “This is a timely and important appointment because Brian has enormous experience at the top levels of government in shaping public policies for climate, technology, manufacturing, and energy, and the consequences for  shared prosperity nationally and globally — all subjects of intense interest to the MIT community,” says MIT Associate Provost Richard Lester. “I fully expect that faculty and student engagement with Brian while he is with us will help advance MIT research, innovation, and impact in these critical areas.”

      Innovation fellowship

      Previous MIT Innovation Fellows, typically in residence for a year or more, have included luminaries from industry and government, including most recently Virginia M. “Ginny” Rometty, former chair, president, and CEO of IBM; Eric Schmidt, former executive chair of Google’s parent company, Alphabet; the late Ash Carter, former U.S. secretary of defense; and former Massachusetts Governor Deval Patrick.

      During his time at MIT, Deese will work on a project detailing and mapping private investment in clean energy and other climate-related activities. He will also interact with students, staff, and faculty from across the Institute. 

      “I hope my role at MIT can largely be about forging partnerships within the Institute and outside of the Institute to significantly reduce the time between innovation and outcomes into the world,” says Deese. More