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      in Environment

      High-energy and hungry for the hardest problems

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      A high school track star and valedictorian, Anne White has always relished moving fast and clearing high hurdles. Since joining the Department of Nuclear Science and Engineering (NSE) in 2009 she has produced path-breaking fusion research, helped attract a more diverse cohort of students and scholars into the discipline, and, during a worldwide pandemic, assumed the role of department head as well as co-lead of an Institute-wide initiative to address climate change. For her exceptional leadership, innovation, and accomplishments in education and research, White was named the School of Engineering Distinguished Professor of Engineering in July 2020.

      But White declares little interest in recognition or promotions. “I don’t care about all that stuff,” she says. She’s in the race for much bigger stakes. “I want to find ways to save the world with nuclear,” she says.

      Tackling turbulence

      It was this goal that drew White to MIT. Her research, honed during graduate studies at the University of California at Los Angeles, involved developing a detailed understanding of conditions inside fusion devices, and resolving issues critical to realizing the vision of fusion energy — a carbon-free, nearly limitless source of power generated by 150-million-degree plasma.

      Harnessing this superheated, gaseous form of matter requires a special donut-shaped device called a tokamak, which contains the plasma within magnetic fields. When White entered fusion around the turn of the millennium, models of plasma behavior in tokamaks didn’t reliably match observed or experimental conditions. She was determined to change that picture, working with MIT’s state-of-the-art research tokamak, Alcator C-Mod.

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      Alcator C-Mod Tokamak Tour

      White believed solving the fusion puzzle meant getting a handle on plasma turbulence — the process by which charged atomic particles, breaking out of magnetic confinement, transport heat from the core to the cool edges of the tokamak. Although researchers knew that fusion energy depends on containing and controlling the heat of plasma reactions, White recalls that when she began grad school, “it was not widely accepted that turbulence was important, and that it was central to heat transport. She “felt it was critical to compare experimental measurements to first principles physics models, so we could demonstrate the significance of turbulence and give tokamak models better predictive ability.”

      In a series of groundbreaking studies, White’s team created the tools for measuring turbulence in different conditions, and developed computational models that could account for variations in turbulence, all validated by experiments. She was one of the first fusion scientists both to perform experiments and conduct simulations. “We lived in the domain between these two worlds,” she says.

      White’s turbulence models opened up approaches for managing turbulence and maximizing tokamak performance, paving the way for net-energy fusion energy devices, including ITER, the world’s largest fusion experiment, and SPARC, a compact, high-magnetic-field tokamak, a collaboration between MIT’s Plasma Science and Fusion Center and Commonwealth Fusion Systems.

      Laser-focused on turbulence

      Growing up in the desert city of Yuma, Arizona, White spent her free time outdoors, hiking and camping. “I was always in the space of protecting the environment,” she says. The daughter of two lawyers who taught her “to argue quickly and efficiently,” she excelled in math and physics in high school. Awarded a full ride at the University of Arizona, she was intent on a path in science, one where she could tackle problems like global warming, as it was known then. Physics seemed like the natural concentration for her.

      But there was unexpected pushback. The physics advisor believed her physics grades were lackluster. “I said, ‘Who cares what this guy thinks; I’ll take physics classes anyway,’” recalls White. Being tenacious and “thick skinned,” says White, turned out to be life-altering. “I took nuclear physics, which opened my eyes to fission, which then set me off on a path of understanding nuclear power and advanced nuclear systems,” she says. Math classes introduced her to chaotic systems, and she decided she wanted to study turbulence. Then, at a Society of Physics Students meeting White says she attended for the free food, she learned about fusion.

      “I realized this was what I wanted to do,” says White. “I became totally laser focused on turbulence and tokamaks.”

      At UCLA, she began to develop instruments and methods for measuring and modeling plasma turbulence, working on three different fusion research reactors, and earning fellowships from the Department of Energy (DOE) during her graduate and post-graduate years in fusion energy science. At MIT, she received a DOE Early Career Award that enabled her to build a research team that she now considers her “legacy.”

      As she expanded her research portfolio, White was also intent on incorporating fusion into the NSE curriculum at the undergraduate and graduate level, and more broadly, on making NSE a destination for students concerned about climate change. In recognition of her efforts, she received the 2014 Junior Bose Teaching Award. She also helped design the EdX course, Nuclear Engineering: Science, Systems and Society, introducing thousands of online learners to the potential of the field. “I have to be in the classroom,” she says. “I have to be with students, interacting, and sharing knowledge and lines of inquiry with them.”

      But even as she deepened her engagement with teaching and with her fusion research, which was helping spur development of new fusion energy technologies, White could not resist leaping into a consequential new undertaking: chairing the department. “It sounds cheesy, but I did it for my kid,” she says. “I can be helpful working on fusion, but I thought, what if I can help more by enabling other people across all areas of nuclear? This department gave me so much, I wanted to give back.”

      Although the pandemic struck just months after she stepped into the role in 2019, White propelled the department toward a new strategic plan. “It captures all the urgency and passion of the faculty, and is attractive to new students, with more undergraduates enrolling and more graduate students applying,” she says. White sees the department advancing the broader goals of the field, “articulating why nuclear is fundamentally important across many dimensions for carbon-free electricity and generation.” This means getting students involved in advanced fission technologies such as nuclear batteries and small modular reactors, as well as giving them an education in fusion that will help catalyze a nascent energy industry.

      Restless for a challenge

      White feels she’s still growing into the leadership role. “I’m really enthusiastic and sometimes too intense for people, so I have to dial it back during challenging conversations,” she says. She recently completed a Harvard Business School course on leadership.

      As the recently named co-chair of MIT’s Climate Nucleus (along with Professor Noelle Selin), charged with overseeing MIT’s campus initiatives around climate change, White says she draws on a repertoire of skills that come naturally to her: listening carefully, building consensus, and seeing value in the diversity of opinion. She is optimistic about mobilizing the Institute around goals to lower MIT’s carbon footprint, “using the entire campus as a research lab,” she says.

      In the midst of this push, White continues to advance projects of concern to her, such as making nuclear physics education more accessible. She developed an in-class module involving a simple particle detector for measuring background radiation. “Any high school or university student could build this experiment in 10 minutes and see alpha particle clusters and muons,” she says.

      White is also planning to host “Rising Stars,” an international conference intended to help underrepresented groups break barriers to entry in the field of nuclear science and engineering. “Grand intellectual challenges like saving the world appeal to all genders and backgrounds,” she says.

      These projects, her departmental and institutional duties, and most recently a new job chairing DOE’s Fusion Energy Sciences Advisory Committee leave her precious little time for a life outside work. But she makes time for walks and backpacking with her husband and toddler son, and reading the latest books by female faculty colleagues, such as “The New Breed,” by Media Lab robotics researcher Kate Darling, and “When People Want Punishment,” by Lily Tsai, Ford Professor of Political Science. “There are so many things I don’t know and want to understand,” says White.

      Yet even at leisure, White doesn’t slow down. “It’s restlessness: I love to learn, and anytime someone says a problem is hard, or impossible, I want to tackle it,” she says. There’s no time off, she believes, when the goal is “solving climate change and amplifying the work of other people trying to solve it.” More

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      in Energy

      Bridging careers in aerospace manufacturing and fusion energy, with a focus on intentional inclusion

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      “A big theme of my life has been focusing on intentional inclusion and how I can create environments where people can really bring their whole authentic selves to work,” says Joy Dunn ’08. As the vice president of operations at Commonwealth Fusion Systems, an MIT spinout working to achieve commercial fusion energy, Dunn looks for solutions to the world’s greatest climate challenges — while creating an open and equitable work environment where everyone can succeed.

      This theme has been cultivated throughout her professional and personal life, including as a Young Global Leader at the World Economic Forum and as a board member at Out for Undergrad, an organization that works with LGBTQ+ college students to help them achieve their personal and professional goals. Through her careers both in aerospace and energy, Dunn has striven to instill a sense of equity and inclusion from the inside out.

      Developing a love for space

      Dunn’s childhood was shaped by space. “I was really inspired as a kid to be an astronaut,” she says, “and for me that never stopped.” Dunn’s parents — both of whom had careers in the aerospace industry — encouraged her from an early age to pursue her interests, from building model rockets to visiting the National Air and Space Museum to attending space camp. A large inspiration for this passion arose when she received a signed photo from Sally Ride — the first American woman in space — that read, “To Joy, reach for the stars.”

      As her interests continued to grow in middle school, she and her mom looked to see what it would take to become an astronaut, asking questions such as “what are the common career paths?” and “what schools did astronauts typically go to?” They quickly found that MIT was at the top of that list, and by seventh grade, Dunn had set her sights on the Institute. 

      After years of hard work, Dunn entered MIT in fall 2004 with a major in aeronautical and astronautical engineering (AeroAstro). At MIT, she remained fully committed to her passion while also expanding into other activities such as varsity softball, the MIT Undergraduate Association, and the Alpha Chi Omega sorority.

      One of the highlights of Dunn’s college career was Unified Engineering, a year-long course required for all AeroAstro majors that provides a foundational knowledge of aerospace engineering — culminating in a team competition where students design and build remote-controlled planes to be pitted against each other. “My team actually got first place, which was very exciting,” she recalls. “And I honestly give a lot of that credit to our pilot. He did a very good job of not crashing!” In fact, that pilot was Warren Hoburg ’08, a former assistant professor in AeroAstro and current NASA astronaut training for a mission on the International Space Station.

      Pursuing her passion at SpaceX

      Dunn’s undergraduate experience culminated with an internship at the aerospace manufacturing company SpaceX in summer 2008. “It was by far my favorite internship of the ones that I had in college. I got to work on really hands-on projects and had the same amount of responsibility as a full-time employee,” she says.

      By the end of the internship, she was hired as a propulsion development engineer for the Dragon spacecraft, where she helped to build the thrusters for the first Dragon mission. Eventually, she transferred to the role of manufacturing engineer. “A lot of what I’ve done in my life is building things and looking for process improvements,” so it was a natural fit. From there, she rose through the ranks, eventually becoming the senior manager of spacecraft manufacturing engineering, where she oversaw all the manufacturing, test, and integration engineers working on Dragon. “It was pretty incredible to go from building thrusters to building the whole vehicle,” she says.

      During her tenure, Dunn also co-founded SpaceX’s Women’s Network and its LGBT affinity group, Out and Allied. “It was about providing spaces for employees to get together and provide a sense of community,” she says. Through these groups, she helped start mentorship and community outreach programs, as well as helped grow the pipeline of women in leadership roles for the company.

      In spite of all her successes at SpaceX, she couldn’t help but think about what came next. “I had been at SpaceX for almost a decade and had these thoughts of, ‘do I want to do another tour of duty or look at doing something else?’ The main criteria I set for myself was to do something that is equally or more world-changing than SpaceX.”

      A pivot to fusion

      It was at this time in 2018 that Dunn received an email from a former mentor asking if she had heard about a fusion energy startup called Commonwealth Fusion Systems (CFS) that worked with the MIT Plasma Science and Fusion Center. “I didn’t know much about fusion at all,” she says. “I had heard about it as a science project that was still many, many years away as a viable energy source.”

      After learning more about the technology and company, “I was just like, ‘holy cow, this has the potential to be even more world-changing than what SpaceX is doing.’” She adds, “I decided that I wanted to spend my time and brainpower focusing on cleaning up the planet instead of getting off it.”

      After connecting with CFS CEO Bob Mumgaard SM ’15, PhD ’15, Dunn joined the company and returned to Cambridge as the head of manufacturing. While moving from the aerospace industry to fusion energy was a large shift, she said her first project — building a fusion-relevant, high-temperature superconducting magnet capable of achieving 20 tesla — tied back into her life of being a builder who likes to get her hands on things.

      Over the course of two years, she oversaw the production and scaling of the magnet manufacturing process. When she first came in, the magnets were being constructed in a time-consuming and manual way. “One of the things I’m most proud of from this project is teaching MIT research scientists how to think like manufacturing engineers,” she says. “It was a great symbiotic relationship. The MIT folks taught us the physics and science behind the magnets, and we came in to figure out how to make them into a more manufacturable product.”

      In September 2021, CFS tested this high-temperature superconducting magnet and achieved its goal of 20 tesla. This was a pivotal moment for the company that brought it one step closer to achieving its goal of producing net-positive fusion power. Now, CFS has begun work on a new campus in Devens, Massachusetts, to house their manufacturing operations and SPARC fusion device. Dunn plays a pivotal role in this expansion as well. In March 2021, she was promoted to the head of operations, which expanded her responsibilities beyond managing manufacturing to include facilities, construction, safety, and quality. “It’s been incredible to watch the campus grow from a pile of dirt … into full buildings.”

      In addition to the groundbreaking work, Dunn highlights the culture of inclusiveness as something that makes CFS stand apart to her. “One of the main reasons that drew me to CFS was hearing from the company founders about their thoughts on diversity, equity, and inclusion, and how they wanted to make that a key focus for their company. That’s been so important in my career, and I’m really excited to see how much that’s valued at CFS.” The company has carried this out through programs such as Fusion Inclusion, an initiative that aims to build a strong and inclusive community from the inside out.

      Dunn stresses “the impact that fusion can have on our world and for addressing issues of environmental injustice through an equitable distribution of power and electricity.” Adding, “That’s a huge lever that we have. I’m excited to watch CFS grow and for us to make a really positive impact on the world in that way.”

      This article appears in the Spring 2022 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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      in Energy

      Solving a longstanding conundrum in heat transfer

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      It is a problem that has beguiled scientists for a century. But, buoyed by a $625,000 Distinguished Early Career Award from the U.S. Department of Energy (DoE), Matteo Bucci, an associate professor in the Department of Nuclear Science and Engineering (NSE), hopes to be close to an answer.

      Tackling the boiling crisis

      Whether you’re heating a pot of water for pasta or are designing nuclear reactors, one phenomenon — boiling — is vital for efficient execution of both processes.

      “Boiling is a very effective heat transfer mechanism; it’s the way to remove large amounts of heat from the surface, which is why it is used in many high-power density applications,” Bucci says. An example use case: nuclear reactors.

      To the layperson, boiling appears simple — bubbles form and burst, removing heat. But what if so many bubbles form and coalesce that they form a band of vapor that prevents further heat transfer? Such a problem is a known entity and is labeled the boiling crisis. It would lead to runaway heat, and a failure of fuel rods in nuclear reactors. So “understanding and determining under which conditions the boiling crisis is likely to happen is critical to designing more efficient and cost-competitive nuclear reactors,” Bucci says.

      Early work on the boiling crisis dates back nearly a century ago, to 1926. And while much work has been done, “it is clear that we haven’t found an answer,” Bucci says. The boiling crisis remains a challenge because while models abound, the measurement of related phenomena to prove or disprove these models has been difficult. “[Boiling] is a process that happens on a very, very small length scale and over very, very short times,” Bucci says. “We are not able to observe it at the level of detail necessary to understand what really happens and validate hypotheses.”

      But, over the past few years, Bucci and his team have been developing diagnostics that can measure the phenomena related to boiling and thereby provide much-needed answers to a classic problem. Diagnostics are anchored in infrared thermometry and a technique using visible light. “By combining these two techniques I think we’re going to be ready to answer standing questions related to heat transfer, we can make our way out of the rabbit hole,” Bucci says. The grant award from the U.S. DoE for Nuclear Energy Projects will aid in this and Bucci’s other research efforts.

      An idyllic Italian childhood

      Tackling difficult problems is not new territory for Bucci, who grew up in the small town of Città di Castello near Florence, Italy. Bucci’s mother was an elementary school teacher. His father used to have a machine shop, which helped develop Bucci’s scientific bent. “I liked LEGOs a lot when I was a kid. It was a passion,” he adds.

      Despite Italy going through a severe pullback from nuclear engineering during his formative years, the subject fascinated Bucci. Job opportunities in the field were uncertain but Bucci decided to dig in. “If I have to do something for the rest of my life, it might as well be something I like,” he jokes. Bucci attended the University of Pisa for undergraduate and graduate studies in nuclear engineering.

      His interest in heat transfer mechanisms took root during his doctoral studies, a research subject he pursued in Paris at the French Alternative Energies and Atomic Energy Commission (CEA). It was there that a colleague suggested work on the boiling water crisis. This time Bucci set his sights on NSE at MIT and reached out to Professor Jacopo Buongiorno to inquire about research at the institution. Bucci had to fundraise at CEA to conduct research at MIT. He arrived just a couple of days before the Boston Marathon bombing in 2013 with a round-trip ticket. But Bucci has stayed ever since, moving on to become a research scientist and then associate professor at NSE.

      Bucci admits he struggled to adapt to the environment when he first arrived at MIT, but work and friendships with colleagues — he counts NSE’s Guanyu Su and Reza Azizian as among his best friends — helped conquer early worries.

      The integration of artificial intelligence

      In addition to diagnostics for boiling, Bucci and his team are working on ways of integrating artificial intelligence and experimental research. He is convinced that “the integration of advanced diagnostics, machine learning, and advanced modeling tools will blossom in a decade.”

      Bucci’s team is developing an autonomous laboratory for boiling heat transfer experiments. Running on machine learning, the setup decides which experiments to run based on a learning objective the team assigns. “We formulate a question and the machine will answer by optimizing the kinds of experiments that are necessary to answer those questions,” Bucci says, “I honestly think this is the next frontier for boiling,” he adds.

      “It’s when you climb a tree and you reach the top, that you realize that the horizon is much more vast and also more beautiful,” Bucci says of his zeal to pursue more research in the field.

      Even as he seeks new heights, Bucci has not forgotten his origins. Commemorating Italy’s hosting of the World Cup in 1990, a series of posters showcasing a soccer field fitted into the Roman Colosseum occupies pride of place in his home and office. Created by Alberto Burri, the posters are of sentimental value: The (now deceased) Italian artist also hailed from Bucci’s hometown — Città di Castello. More

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      in Energy

      Fusion’s newest ambassador

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      When high school senior Tuba Balta emailed MIT Plasma Science and Fusion Center (PSFC) Director Dennis Whyte in February, she was not certain she would get a response. As part of her final semester at BASIS Charter School, in Washington, she had been searching unsuccessfully for someone to sponsor an internship in fusion energy, a topic that had recently begun to fascinate her because “it’s not figured out yet.” Time was running out if she was to include the internship as part of her senior project.

      “I never say ‘no’ to a student,” says Whyte, who felt she could provide a youthful perspective on communicating the science of fusion to the general public.

      Posters explaining the basics of fusion science were being considered for the walls of a PSFC lounge area, a space used to welcome visitors who might not know much about the center’s focus: What is fusion? What is plasma? What is magnetic confinement fusion? What is a tokamak?

      Why couldn’t Balta be tasked with coming up with text for these posters, written specifically to be understandable, even intriguing, to her peers?

      Meeting the team

      Although most of the internship would be virtual, Balta visited MIT to meet Whyte and others who would guide her progress. A tour of the center showed her the past and future of the PSFC, one lab area revealing on her left the remains of the decades-long Alcator C-Mod tokamak and on her right the testing area for new superconducting magnets crucial to SPARC, designed in collaboration with MIT spinoff Commonwealth Fusion Systems.

      With Whyte, graduate student Rachel Bielajew, and Outreach Coordinator Paul Rivenberg guiding her content and style, Balta focused on one of eight posters each week. Her school also required her to keep a weekly blog of her progress, detailing what she was learning in the process of creating the posters.

      Finding her voice

      Balta admits that she was not looking forward to this part of the school assignment. But she decided to have fun with it, adopting an enthusiastic and conversational tone, as if she were sitting with friends around a lunch table. Each week, she was able to work out what she was composing for her posters and her final project by trying it out on her friends in the blog.

      Her posts won praise from her schoolmates for their clarity, as when in Week 3 she explained the concept of turbulence as it relates to fusion research, sending her readers to their kitchen faucets to experiment with the pressure and velocity of running tap water.

      The voice she found through her blog served her well during her final presentation about fusion at a school expo for classmates, parents, and the general public.

      “Most people are intimidated by the topic, which they shouldn’t be,” says Balta. “And it just made me happy to help other people understand it.”

      Her favorite part of the internship? “Getting to talk to people whose papers I was reading and ask them questions. Because when it comes to fusion, you can’t just look it up on Google.”

      Awaiting her first year at the University of Chicago, Balta reflects on the team spirit she experienced in communicating with researchers at the PSFC.

      “I think that was one of my big takeaways,” she says, “that you have to work together. And you should, because you’re always going to be missing some piece of information; but there’s always going to be somebody else who has that piece, and we can all help each other out.” More

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      in Energy

      Explained: Why perovskites could take solar cells to new heights

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      Perovskites hold promise for creating solar panels that could be easily deposited onto most surfaces, including flexible and textured ones. These materials would also be lightweight, cheap to produce, and as efficient as today’s leading photovoltaic materials, which are mainly silicon. They’re the subject of increasing research and investment, but companies looking to harness their potential do have to address some remaining hurdles before perovskite-based solar cells can be commercially competitive.

      The term perovskite refers not to a specific material, like silicon or cadmium telluride, other leading contenders in the photovoltaic realm, but to a whole family of compounds. The perovskite family of solar materials is named for its structural similarity to a mineral called perovskite, which was discovered in 1839 and named after Russian mineralogist L.A. Perovski.

      The original mineral perovskite, which is calcium titanium oxide (CaTiO3), has a distinctive crystal configuration. It has a three-part structure, whose components have come to be labeled A, B and X, in which lattices of the different components are interlaced. The family of perovskites consists of the many possible combinations of elements or molecules that can occupy each of the three components and form a structure similar to that of the original perovskite itself. (Some researchers even bend the rules a little by naming other crystal structures with similar elements “perovskites,” although this is frowned upon by crystallographers.)

      “You can mix and match atoms and molecules into the structure, with some limits. For instance, if you try to stuff a molecule that’s too big into the structure, you’ll distort it. Eventually you might cause the 3D crystal to separate into a 2D layered structure, or lose ordered structure entirely,” says Tonio Buonassisi, professor of mechanical engineering at MIT and director of the Photovoltaics Research Laboratory. “Perovskites are highly tunable, like a build-your-own-adventure type of crystal structure,” he says.

      That structure of interlaced lattices consists of ions or charged molecules, two of them (A and B) positively charged and the other one (X) negatively charged. The A and B ions are typically of quite different sizes, with the A being larger. 

      Within the overall category of perovskites, there are a number of types, including metal oxide perovskites, which have found applications in catalysis and in energy storage and conversion, such as in fuel cells and metal-air batteries. But a main focus of research activity for more than a decade has been on lead halide perovskites, according to Buonassisi says.

      Within that category, there is still a legion of possibilities, and labs around the world are racing through the tedious work of trying to find the variations that show the best performance in efficiency, cost, and durability — which has so far been the most challenging of the three.

      Many teams have also focused on variations that eliminate the use of lead, to avoid its environmental impact. Buonassisi notes, however, that “consistently over time, the lead-based devices continue to improve in their performance, and none of the other compositions got close in terms of electronic performance.” Work continues on exploring alternatives, but for now none can compete with the lead halide versions.

      One of the great advantages perovskites offer is their great tolerance of defects in the structure, he says. Unlike silicon, which requires extremely high purity to function well in electronic devices, perovskites can function well even with numerous imperfections and impurities.

      Searching for promising new candidate compositions for perovskites is a bit like looking for a needle in a haystack, but recently researchers have come up with a machine-learning system that can greatly streamline this process. This new approach could lead to a much faster development of new alternatives, says Buonassisi, who was a co-author of that research.

      While perovskites continue to show great promise, and several companies are already gearing up to begin some commercial production, durability remains the biggest obstacle they face. While silicon solar panels retain up to 90 percent of their power output after 25 years, perovskites degrade much faster. Great progress has been made — initial samples lasted only a few hours, then weeks or months, but newer formulations have usable lifetimes of up to a few years, suitable for some applications where longevity is not essential.

      From a research perspective, Buonassisi says, one advantage of perovskites is that they are relatively easy to make in the lab — the chemical constituents assemble readily. But that’s also their downside: “The material goes together very easily at room temperature,” he says, “but it also comes apart very easily at room temperature. Easy come, easy go!”

      To deal with that issue, most researchers are focused on using various kinds of protective materials to encapsulate the perovskite, protecting it from exposure to air and moisture. But others are studying the exact mechanisms that lead to that degradation, in hopes of finding formulations or treatments that are more inherently robust. A key finding is that a process called autocatalysis is largely to blame for the breakdown.

      In autocatalysis, as soon as one part of the material starts to degrade, its reaction products act as catalysts to start degrading the neighboring parts of the structure, and a runaway reaction gets underway. A similar problem existed in the early research on some other electronic materials, such as organic light-emitting diodes (OLEDs), and was eventually solved by adding additional purification steps to the raw materials, so a similar solution may be found in the case of perovskites, Buonassisi suggests.

      Buonassisi and his co-researchers recently completed a study showing that once perovskites reach a usable lifetime of at least a decade, thanks to their much lower initial cost that would be sufficient to make them economically viable as a substitute for silicon in large, utility-scale solar farms.

      Overall, progress in the development of perovskites has been impressive and encouraging, he says. With just a few years of work, it has already achieved efficiencies comparable to levels that cadmium telluride (CdTe), “which has been around for much longer, is still struggling to achieve,” he says. “The ease with which these higher performances are reached in this new material are almost stupefying.” Comparing the amount of research time spent to achieve a 1 percent improvement in efficiency, he says, the progress on perovskites has been somewhere between 100 and 1000 times faster than that on CdTe. “That’s one of the reasons it’s so exciting,” he says. More

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      in Energy

      Getting the carbon out of India’s heavy industries

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      The world’s third largest carbon emitter after China and the United States, India ranks seventh in a major climate risk index. Unless India, along with the nearly 200 other signatory nations of the Paris Agreement, takes aggressive action to keep global warming well below 2 degrees Celsius relative to preindustrial levels, physical and financial losses from floods, droughts, and cyclones could become more severe than they are today. So, too, could health impacts associated with the hazardous air pollution levels now affecting more than 90 percent of its population.  

      To address both climate and air pollution risks and meet its population’s escalating demand for energy, India will need to dramatically decarbonize its energy system in the coming decades. To that end, its initial Paris Agreement climate policy pledge calls for a reduction in carbon dioxide intensity of GDP by 33-35 percent by 2030 from 2005 levels, and an increase in non-fossil-fuel-based power to about 40 percent of cumulative installed capacity in 2030. At the COP26 international climate change conference, India announced more aggressive targets, including the goal of achieving net-zero emissions by 2070.

      Meeting its climate targets will require emissions reductions in every economic sector, including those where emissions are particularly difficult to abate. In such sectors, which involve energy-intensive industrial processes (production of iron and steel; nonferrous metals such as copper, aluminum, and zinc; cement; and chemicals), decarbonization options are limited and more expensive than in other sectors. Whereas replacing coal and natural gas with solar and wind could lower carbon dioxide emissions in electric power generation and transportation, no easy substitutes can be deployed in many heavy industrial processes that release CO2 into the air as a byproduct.

      However, other methods could be used to lower the emissions associated with these processes, which draw upon roughly 50 percent of India’s natural gas, 25 percent of its coal, and 20 percent of its oil. Evaluating the potential effectiveness of such methods in the next 30 years, a new study in the journal Energy Economics led by researchers at the MIT Joint Program on the Science and Policy of Global Change is the first to explicitly explore emissions-reduction pathways for India’s hard-to-abate sectors.

      Using an enhanced version of the MIT Economic Projection and Policy Analysis (EPPA) model, the study assesses existing emissions levels in these sectors and projects how much they can be reduced by 2030 and 2050 under different policy scenarios. Aimed at decarbonizing industrial processes, the scenarios include the use of subsidies to increase electricity use, incentives to replace coal with natural gas, measures to improve industrial resource efficiency, policies to put a price on carbon, carbon capture and storage (CCS) technology, and hydrogen in steel production.

      The researchers find that India’s 2030 Paris Agreement pledge may still drive up fossil fuel use and associated greenhouse gas emissions, with projected carbon dioxide emissions from hard-to-abate sectors rising by about 2.6 times from 2020 to 2050. But scenarios that also promote electrification, natural gas support, and resource efficiency in hard-to-abate sectors can lower their CO2 emissions by 15-20 percent.

      While appearing to move the needle in the right direction, those reductions are ultimately canceled out by increased demand for the products that emerge from these sectors. So what’s the best path forward?

      The researchers conclude that only the incentive of carbon pricing or the advance of disruptive technology can move hard-to-abate sector emissions below their current levels. To achieve significant emissions reductions, they maintain, the price of carbon must be high enough to make CCS economically viable. In that case, reductions of 80 percent below current levels could be achieved by 2050.

      “Absent major support from the government, India will be unable to reduce carbon emissions in its hard-to-abate sectors in alignment with its climate targets,” says MIT Joint Program deputy director Sergey Paltsev, the study’s lead author. “A comprehensive government policy could provide robust incentives for the private sector in India and generate favorable conditions for foreign investments and technology advances. We encourage decision-makers to use our findings to design efficient pathways to reduce emissions in those sectors, and thereby help lower India’s climate and air pollution-related health risks.” More

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      in Energy

      Making hydrogen power a reality

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      For decades, government and industry have looked to hydrogen as a potentially game-changing tool in the quest for clean energy. As far back as the early days of the Clinton administration, energy sector observers and public policy experts have extolled the virtues of hydrogen — to the point that some people have joked that hydrogen is the energy of the future, “and always will be.”

      Even as wind and solar power have become commonplace in recent years, hydrogen has been held back by high costs and other challenges. But the fuel may finally be poised to have its moment. At the MIT Energy Initiative Spring Symposium — entitled “Hydrogen’s role in a decarbonized energy system” — experts discussed hydrogen production routes, hydrogen consumption markets, the path to a robust hydrogen infrastructure, and policy changes needed to achieve a “hydrogen future.”

      During one panel, “Options for producing low-carbon hydrogen at scale,” four experts laid out existing and planned efforts to leverage hydrogen for decarbonization. 

      “The race is on”

      Huyen N. Dinh, a senior scientist and group manager at the National Renewable Energy Laboratory (NREL), is the director of HydroGEN, a consortium of several U.S. Department of Energy (DOE) national laboratories that accelerates research and development of innovative and advanced water splitting materials and technologies for clean, sustainable, and low-cost hydrogen production.

      For the past 14 years, Dinh has worked on fuel cells and hydrogen production for NREL. “We think that the 2020s is the decade of hydrogen,” she said. Dinh believes that the energy carrier is poised to come into its own over the next few years, pointing to several domestic and international activities surrounding the fuel and citing a Hydrogen Council report that projected the future impacts of hydrogen — including 30 million jobs and $2.5 trillion in global revenue by 2050.

      “Now is the time for hydrogen, and the global race is on,” she said.

      Dinh also explained the parameters of the Hydrogen Shot — the first of the DOE’s “Energy Earthshots” aimed at accelerating breakthroughs for affordable and reliable clean energy solutions. Hydrogen fuel currently costs around $5 per kilogram to produce, and the Hydrogen Shot’s stated goal is to bring that down by 80 percent to $1 per kilogram within a decade.

      The Hydrogen Shot will be facilitated by $9.5 billion in funding for at least four clean hydrogen hubs located in different parts of the United States, as well as extensive research and development, manufacturing, and recycling from last year’s bipartisan infrastructure law. Still, Dinh noted that it took more than 40 years for solar and wind power to become cost competitive, and now industry, government, national lab, and academic leaders are hoping to achieve similar reductions in hydrogen fuel costs over a much shorter time frame. In the near term, she said, stakeholders will need to improve the efficiency, durability, and affordability of hydrogen production through electrolysis (using electricity to split water) using today’s renewable and nuclear power sources. Over the long term, the focus may shift to splitting water more directly through heat or solar energy, she said.

      “The time frame is short, the competition is intense, and a coordinated effort is critical for domestic competitiveness,” Dinh said.

      Hydrogen across continents

      Wambui Mutoru, principal engineer for international commercial development, exploration, and production international at the Norwegian global energy company Equinor, said that hydrogen is an important component in the company’s ambitions to be carbon-neutral by 2050. The company, in collaboration with partners, has several hydrogen projects in the works, and Mutoru laid out the company’s Hydrogen to Humber project in Northern England. Currently, the Humber region emits more carbon dioxide than any other industrial cluster in the United Kingdom — 50 percent more, in fact, than the next-largest carbon emitter.   

      “The ambition here is for us to deploy the world’s first at-scale hydrogen value chain to decarbonize the Humber industrial cluster,” Mutoru said.

      The project consists of three components: a clean hydrogen production facility, an onshore hydrogen and carbon dioxide transmission network, and offshore carbon dioxide transportation and storage operations. Mutoru highlighted the importance of carbon capture and storage in hydrogen production. Equinor, she said, has captured and sequestered carbon offshore for more than 25 years, storing more than 25 million tons of carbon dioxide during that time.

      Mutoru also touched on Equinor’s efforts to build a decarbonized energy hub in the Appalachian region of the United States, covering territory in Ohio, West Virginia, and Pennsylvania. By 2040, she said, the company’s ambition is to produce about 1.5 million tons of clean hydrogen per year in the region — roughly equivalent to 6.8 gigawatts of electricity — while also storing 30 million tons of carbon dioxide.

      Mutoru acknowledged that the biggest challenge facing potential hydrogen producers is the current lack of viable business models. “Resolving that challenge requires cross-industry collaboration, and supportive policy frameworks so that the market for hydrogen can be built and sustained over the long term,” she said.

      Confronting barriers

      Gretchen Baier, executive external strategy and communications leader for Dow, noted that the company already produces hydrogen in multiple ways. For one, Dow operates the world’s largest ethane cracker, in Texas. An ethane cracker heats ethane to break apart molecular bonds to form ethylene, with hydrogen one of the byproducts of the process. Also, Baier showed a slide of the 1891 patent for the electrolysis of brine water, which also produces hydrogen. The company still engages in this practice, but Dow does not have an effective way of utilizing the resulting hydrogen for their own fuel.

      “Just take a moment to think about that,” Baier said. “We’ve been talking about hydrogen production and the cost of it, and this is basically free hydrogen. And it’s still too much of a barrier to somewhat recycle that and use it for ourselves. The environment is clearly changing, and we do have plans for that, but I think that kind of sets some of the challenges that face industry here.”

      However, Baier said, hydrogen is expected to play a significant role in Dow’s future as the company attempts to decarbonize by 2050. The company, she said, plans to optimize hydrogen allocation and production, retrofit turbines for hydrogen fueling, and purchase clean hydrogen. By 2040, Dow expects more than 60 percent of its sites to be hydrogen-ready.

      Baier noted that hydrogen fuel is not a “panacea,” but rather one among many potential contributors as industry attempts to reduce or eliminate carbon emissions in the coming decades. “Hydrogen has an important role, but it’s not the only answer,” she said.

      “This is real”

      Colleen Wright is vice president of corporate strategy for Constellation, which recently separated from Exelon Corporation. (Exelon now owns the former company’s regulated utilities, such as Commonwealth Edison and Baltimore Gas and Electric, while Constellation owns the competitive generation and supply portions of the business.) Wright stressed the advantages of nuclear power in hydrogen production, which she said include superior economics, low barriers to implementation, and scalability.

      “A quarter of emissions in the world are currently from hard-to-decarbonize sectors — the industrial sector, steel making, heavy-duty transportation, aviation,” she said. “These are really challenging decarbonization sectors, and as we continue to expand and electrify, we’re going to need more supply. We’re also going to need to produce clean hydrogen using emissions-free power.”

      “The scale of nuclear power plants is uniquely suited to be able to scale hydrogen production,” Wright added. She mentioned Constellation’s Nine Mile Point site in the State of New York, which received a DOE grant for a pilot program that will see a proton exchange membrane electrolyzer installed at the site.

      “We’re very excited to see hydrogen go from a [research and development] conversation to a commercial conversation,” she said. “We’ve been calling it a little bit of a ‘middle-school dance.’ Everybody is standing around the circle, waiting to see who’s willing to put something at stake. But this is real. We’re not dancing around the edges. There are a lot of people who are big players, who are willing to put skin in the game today.” More

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      Evan Leppink: Seeking a way to better stabilize the fusion environment

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      “Fusion energy was always one of those kind-of sci-fi technologies that you read about,” says nuclear science and engineering PhD candidate Evan Leppink. He’s recalling the time before fusion became a part of his daily hands-on experience at MIT’s Plasma Science and Fusion Center, where he is studying a unique way to drive current in a tokamak plasma using radiofrequency (RF) waves. 

      Now, an award from the U.S. Department of Energy’s (DOE) Office of Science Graduate Student Research (SCGSR) Program will support his work with a 12-month residency at the DIII-D National Fusion Facility in San Diego, California.

      Like all tokamaks, DIII-D generates hot plasma inside a doughnut-shaped vacuum chamber wrapped with magnets. Because plasma will follow magnetic field lines, tokamaks are able to contain the turbulent plasma fuel as it gets hotter and denser, keeping it away from the edges of the chamber where it could damage the wall materials. A key part of the tokamak concept is that part of the magnetic field is created by electrical currents in the plasma itself, which helps to confine and stabilize the configuration. Researchers often launch high-power RF waves into tokamaks to drive that current.

      Leppink will be contributing to research, led by his MIT advisor Steve Wukitch, that pursues launching RF waves in DIII-D using a unique compact antenna placed on the tokamak center column. Typically, antennas are placed inside the tokamak on the outer edge of the doughnut, farthest from the central hole (or column), primarily because access and installation are easier there. This is known as the “low-field side,” because the magnetic field is lower there than at the central column, the “high-field side.” This MIT-led experiment, for the first time, will mount an antenna on the high-field side. There is some theoretical evidence that placing the wave launcher there could improve power penetration and current drive efficiency. And because the plasma environment is less harsh on this side, the antenna will survive longer, a factor important for any future power-producing tokamak.

      Leppink’s work on DIII-D focuses specifically on measuring the density of plasmas generated in the tokamak, for which he developed a “reflectometer.” This small antenna launches microwaves into the plasma, which reflect back to the antenna to be measured. The time that it takes for these microwaves to traverse the plasma provides information about the plasma density, allowing researchers to build up detailed density profiles, data critical for injecting RF power into the plasma.

      “Research shows that when we try to inject these waves into the plasma to drive the current, they can lose power as they travel through the edge region of the tokamak, and can even have problems entering the core of the plasma, where we would most like to direct them,” says Leppink. “My diagnostic will measure that edge region on the high-field side near the launcher in great detail, which provides us a way to directly verify calculations or compare actual results with simulation results.”

      Although focused on his own research, Leppink has excelled at priming other students for success in their studies and research. In 2021 he received the NSE Outstanding Teaching Assistant and Mentorship Award.

      “The highlights of TA’ing for me were the times when I could watch students go from struggling with a difficult topic to fully understanding it, often with just a nudge in the right direction and then allowing them to follow their own intuition the rest of the way,” he says.

      The right direction for Leppink points toward San Diego and RF current drive experiments on DIII-D. He is grateful for the support from the SCGSR, a program created to prepare graduate students like him for science, technology, engineering, or mathematics careers important to the DOE Office of Science mission. It provides graduate thesis research opportunities through extended residency at DOE national laboratories. He has already made several trips to DIII-D, in part to install his reflectometer, and has been impressed with the size of the operation.

      “It takes a little while to kind of compartmentalize everything and say, ‘OK, well, here’s my part of the machine. This is what I’m doing.’ It can definitely be overwhelming at times. But I’m blessed to be able to work on what has been the workhorse tokamak of the United States for the past few decades.” More