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      in Energy

      Celebrating five years of MIT.nano

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      There is vast opportunity for nanoscale innovation to transform the world in positive ways — expressed MIT.nano Director Vladimir Bulović as he posed two questions to attendees at the start of the inaugural Nano Summit: “Where are we heading? And what is the next big thing we can develop?”

      “The answer to that puts into perspective our main purpose — and that is to change the world,” Bulović, the Fariborz Maseeh Professor of Emerging Technologies, told an audience of more than 325 in-person and 150 virtual participants gathered for an exploration of nano-related research at MIT and a celebration of MIT.nano’s fifth anniversary.

      Over a decade ago, MIT embarked on a massive project for the ultra-small — building an advanced facility to support research at the nanoscale. Construction of MIT.nano in the heart of MIT’s campus, a process compared to assembling a ship in a bottle, began in 2015, and the facility launched in October 2018.

      Fast forward five years: MIT.nano now contains nearly 170 tools and instruments serving more than 1,200 trained researchers. These individuals come from over 300 principal investigator labs, representing more than 50 MIT departments, labs, and centers. The facility also serves external users from industry, other academic institutions, and over 130 startup and multinational companies.

      A cross section of these faculty and researchers joined industry partners and MIT community members to kick off the first Nano Summit, which is expected to become an annual flagship event for MIT.nano and its industry consortium. Held on Oct. 24, the inaugural conference was co-hosted by the MIT Industrial Liaison Program.

      Six topical sessions highlighted recent developments in quantum science and engineering, materials, advanced electronics, energy, biology, and immersive data technology. The Nano Summit also featured startup ventures and an art exhibition.

      Watch the videos here.

      Seeing and manipulating at the nanoscale — and beyond

      “We need to develop new ways of building the next generation of materials,” said Frances Ross, the TDK Professor in Materials Science and Engineering (DMSE). “We need to use electron microscopy to help us understand not only what the structure is after it’s built, but how it came to be. I think the next few years in this piece of the nano realm are going to be really amazing.”

      Speakers in the session “The Next Materials Revolution,” chaired by MIT.nano co-director for Characterization.nano and associate professor in DMSE James LeBeau, highlighted areas in which cutting-edge microscopy provides insights into the behavior of functional materials at the nanoscale, from anti-ferroelectrics to thin-film photovoltaics and 2D materials. They shared images and videos collected using the instruments in MIT.nano’s characterization suites, which were specifically designed and constructed to minimize mechanical-vibrational and electro-magnetic interference.

      Later, in the “Biology and Human Health” session chaired by Boris Magasanik Professor of Biology Thomas Schwartz, biologists echoed the materials scientists, stressing the importance of the ultra-quiet, low-vibration environment in Characterization.nano to obtain high-resolution images of biological structures.

      “Why is MIT.nano important for us?” asked Schwartz. “An important element of biology is to understand the structure of biology macromolecules. We want to get to an atomic resolution of these structures. CryoEM (cryo-electron microscopy) is an excellent method for this. In order to enable the resolution revolution, we had to get these instruments to MIT. For that, MIT.nano was fantastic.”

      Seychelle Vos, the Robert A. Swanson (1969) Career Development Professor of Life Sciences, shared CryoEM images from her lab’s work, followed by biology Associate Professor Joey Davis who spoke about image processing. When asked about the next stage for CryoEM, Davis said he’s most excited about in-situ tomography, noting that there are new instruments being designed that will improve the current labor-intensive process.

      To chart the future of energy, chemistry associate professor Yogi Surendranath is also using MIT.nano to see what is happening at the nanoscale in his research to use renewable electricity to change carbon dioxide into fuel.

      “MIT.nano has played an immense role, not only in facilitating our ability to make nanostructures, but also to understand nanostructures through advanced imaging capabilities,” said Surendranath. “I see a lot of the future of MIT.nano around the question of how nanostructures evolve and change under the conditions that are relevant to their function. The tools at MIT.nano can help us sort that out.”

      Tech transfer and quantum computing

      The “Advanced Electronics” session chaired by Jesús del Alamo, the Donner Professor of Science in the Department of Electrical Engineering and Computer Science (EECS), brought together industry partners and MIT faculty for a panel discussion on the future of semiconductors and microelectronics. “Excellence in innovation is not enough, we also need to be excellent in transferring these to the marketplace,” said del Alamo. On this point, panelists spoke about strengthening the industry-university connection, as well as the importance of collaborative research environments and of access to advanced facilities, such as MIT.nano, for these environments to thrive.

      The session came on the heels of a startup exhibit in which eleven START.nano companies presented their technologies in health, energy, climate, and virtual reality, among other topics. START.nano, MIT.nano’s hard-tech accelerator, provides participants use of MIT.nano’s facilities at a discounted rate and access to MIT’s startup ecosystem. The program aims to ease hard-tech startups’ transition from the lab to the marketplace, surviving common “valleys of death” as they move from idea to prototype to scaling up.

      When asked about the state of quantum computing in the “Quantum Science and Engineering” session, physics professor Aram Harrow related his response to these startup challenges. “There are quite a few valleys to cross — there are the technical valleys, and then also the commercial valleys.” He spoke about scaling superconducting qubits and qubits made of suspended trapped ions, and the need for more scalable architectures, which we have the ingredients for, he said, but putting everything together is quite challenging.

      Throughout the session, William Oliver, professor of physics and the Henry Ellis Warren (1894) Professor of Electrical Engineering and Computer Science, asked the panelists how MIT.nano can address challenges in assembly and scalability in quantum science.

      “To harness the power of students to innovate, you really need to allow them to get their hands dirty, try new things, try all their crazy ideas, before this goes into a foundry-level process,” responded Kevin O’Brien, associate professor in EECS. “That’s what my group has been working on at MIT.nano, building these superconducting quantum processors using the state-of-the art fabrication techniques in MIT.nano.”

      Connecting the digital to the physical

      In his reflections on the semiconductor industry, Douglas Carlson, senior vice president for technology at MACOM, stressed connecting the digital world to real-world application. Later, in the “Immersive Data Technology” session, MIT.nano associate director Brian Anthony explained how, at the MIT.nano Immersion Lab, researchers are doing just that.

      “We think about and facilitate work that has the human immersed between hardware, data, and experience,” said Anthony, principal research scientist in mechanical engineering. He spoke about using the capabilities of the Immersion Lab to apply immersive technologies to different areas — health, sports, performance, manufacturing, and education, among others. Speakers in this session gave specific examples in hardware, pediatric health, and opera.

      Anthony connected this third pillar of MIT.nano to the fab and characterization facilities, highlighting how the Immersion Lab supports work conducted in other parts of the building. The Immersion Lab’s strength, he said, is taking novel work being developed inside MIT.nano and bringing it up to the human scale to think about applications and uses.

      Artworks that are scientifically inspired

      The Nano Summit closed with a reception at MIT.nano where guests could explore the facility and gaze through the cleanroom windows, where users were actively conducting research. Attendees were encouraged to visit an exhibition on MIT.nano’s first- and second-floor galleries featuring work by students from the MIT Program in Art, Culture, and Technology (ACT) who were invited to utilize MIT.nano’s tool sets and environments as inspiration for art.

      In his closing remarks, Bulović reflected on the community of people who keep MIT.nano running and who are using the tools to advance their research. “Today we are celebrating the facility and all the work that has been done over the last five years to bring it to where it is today. It is there to function not just as a space, but as an essential part of MIT’s mission in research, innovation, and education. I hope that all of us here today take away a deep appreciation and admiration for those who are leading the journey into the nano age.” More

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      in Security

      Microbes could help reduce the need for chemical fertilizers

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      Production of chemical fertilizers accounts for about 1.5 percent of the world’s greenhouse gas emissions. MIT chemists hope to help reduce that carbon footprint by replacing some chemical fertilizer with a more sustainable source — bacteria.

      Bacteria that can convert nitrogen gas to ammonia could not only provide nutrients that plants need, but also help regenerate soil and protect plants from pests. However, these bacteria are sensitive to heat and humidity, so it’s difficult to scale up their manufacture and ship them to farms.

      To overcome that obstacle, MIT chemical engineers have devised a metal-organic coating that protects bacterial cells from damage without impeding their growth or function. In a new study, they found that these coated bacteria improved the germination rate of a variety of seeds, including vegetables such as corn and bok choy.

      This coating could make it much easier for farmers to deploy microbes as fertilizers, says Ariel Furst, the Paul M. Cook Career Development Assistant Professor of Chemical Engineering at MIT and the senior author of the study.

      “We can protect them from the drying process, which would allow us to distribute them much more easily and with less cost because they’re a dried powder instead of in liquid,” she says. “They can also withstand heat up to 132 degrees Fahrenheit, which means that you wouldn’t have to use cold storage for these microbes.”

      Benjamin Burke ’23 and postdoc Gang Fan are the lead authors of the open-access paper, which appears in the Journal of the American Chemical Society Au. MIT undergraduate Pris Wasuwanich and Evan Moore ’23 are also authors of the study.

      Protecting microbes

      Chemical fertilizers are manufactured using an energy-intensive process known as Haber-Bosch, which uses extremely high pressures to combine nitrogen from the air with hydrogen to make ammonia.

      In addition to the significant carbon footprint of this process, another drawback to chemical fertilizers is that long-term use eventually depletes the nutrients in the soil. To help restore soil, some farmers have turned to “regenerative agriculture,” which uses a variety of strategies, including crop rotation and composting, to keep soil healthy. Nitrogen-fixing bacteria, which convert nitrogen gas to ammonia, can aid in this approach.

      Some farmers have already begun deploying these “microbial fertilizers,” growing them in large onsite fermenters before applying them to the soil. However, this is cost-prohibitive for many farmers.

      Shipping these bacteria to rural areas is not currently a viable option, because they are susceptible to heat damage. The microbes are also too delicate to survive the freeze-drying process that would make them easier to transport.

      To protect the microbes from both heat and freeze-drying, Furst decided to apply a coating called a metal-phenol network (MPN), which she has previously developed to encapsulate microbes for other uses, such as protecting therapeutic bacteria delivered to the digestive tract.

      The coatings contain two components — a metal and an organic compound called a polyphenol — that can self-assemble into a protective shell. The metals used for the coatings, including iron, manganese, aluminum, and zinc, are considered safe as food additives. Polyphenols, which are often found in plants, include molecules such as tannins and other antioxidants. The FDA classifies many of these polyphenols as GRAS (generally regarded as safe).

      “We are using these natural food-grade compounds that are known to have benefits on their own, and then they form these little suits of armor that protect the microbes,” Furst says.

      For this study, the researchers created 12 different MPNs and used them to encapsulate Pseudomonas chlororaphis, a nitrogen-fixing bacterium that also protects plants against harmful fungi and other pests. They found that all of the coatings protected the bacteria from temperatures up to 50 degrees Celsius (122 degrees Fahrenheit), and also from relative humidity up to 48 percent. The coatings also kept the microbes alive during the freeze-drying process.

      A boost for seeds

      Using microbes coated with the most effective MPN — a combination of manganese and a polyphenol called epigallocatechin gallate (EGCG) — the researchers tested their ability to help seeds germinate in a lab dish. They heated the coated microbes to 50 C before placing them in the dish, and compared them to fresh uncoated microbes and freeze-dried uncoated microbes.

      The researchers found that the coated microbes improved the seeds’ germination rate by 150 percent, compared to seeds treated with fresh, uncoated microbes. This result was consistent across several different types of seeds, including dill, corn, radishes, and bok choy.

      Furst has started a company called Seia Bio to commercialize the coated bacteria for large-scale use in regenerative agriculture. She hopes that the low cost of the manufacturing process will help make microbial fertilizers accessible to small-scale farmers who don’t have the fermenters needed to grow such microbes.

      “When we think about developing technology, we need to intentionally design it to be inexpensive and accessible, and that’s what this technology is. It would help democratize regenerative agriculture,” she says.

      The research was funded by the Army Research Office, a National Institutes of Health New Innovator Award, a National Institute for Environmental Health Sciences Core Center Grant, the CIFAR Azrieli Global Scholars Program, the MIT J-WAFS Program, the MIT Climate and Sustainability Consortium, and the MIT Deshpande Center. More

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      in Energy

      The power of knowledge

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      In his early career at MIT, Josh Kuffour’s academic interests spanned mathematics, engineering, and physics. He decided to major in chemical engineering, figuring it would draw on all three areas. Then, he found himself increasingly interested in the mathematical components of his studies and added a second major, applied mathematics.

      Now, with a double major and energy studies minor, Kuffour is still seeking to learn even more. He has made it a goal to take classes from as many different departments as he can before he graduates. So far, he has taken classes from 17 different departments, ranging from Civil and Environmental Engineering to Earth, Atmospheric, and Planetary Sciences to Linguistics and Philosophy.

      “It’s taught me about valuing different ways of thinking,” he says about this wide-ranging approach to the course catalog. “It’s also taught me to value blending disciplines as a whole. Learning about how other people think about the same problems from different perspectives allows for better solutions to be developed.”

      After graduation, Kuffour plans to pursue a master’s degree at MIT, either in the Technology and Policy Program or in the Department of Chemical Engineering. He intends to make renewable energy, and its role in addressing societal inequalities, the focus of his career after graduating, and eventually plans to become a teacher.

      Serving the public

      Recognizing the power of knowledge, Kuffour says he enjoys helping to educate others “in any way I can.” He is involved with several extracurriculars in which he can be a mentor for both peers and high school students.

      Kuffour has volunteered with the Educational Studies Program since his first semester at MIT. This club runs Splash, “a weekend-long learning extravaganza,” as Kuffour puts it, in which MIT students teach over 400 free classes on a huge variety of topics for local high school students.

      For his peers, Kuffour also participates in the Gordon Engineering Leadership Program (GEL). Here, he teaches first-year GEL students leadership skills that engineers may require in their future careers. In doing this, Kuffour says he develops his own leadership skills as well. He is also working as a teaching assistant for multivariable calculus this semester.

      Kuffour has also served as an advisor for the Concourse learning community; as president of his fraternity, Beta Theta Pi; as a student representative on the HASS requirement subcommittee; and as a publicist for the Reason for God series, which invites the MIT community to discuss the intersections of religion with various facets of human life.

      Renewable energy

      Kuffour’s interest in energy issues has grown and evolved in recent years. He first learned about the ecological condition of the world in the eighth grade after watching the climate change documentary “Earth 2100” in school. Going into high school and college, Kuffour says he started reading books, taking classes, watching documentaries, participating in beach and city clean ups, to learn as much as possible about the environment and      global warming.

      During the summer of 2023, Kuffour worked as an energy and climate analysis intern for the consulting company Keylogic and has continued helping the company shift programming languages to Python for evaluating the economics of different methods of decarbonizing electricity sectors in the U.S. He has also assisted in analyzing trends in U.S. natural gas imports, exports, production, and consumption since the early 2000s.            

      In his time as an undergraduate, Kuffour’s interest in renewable energy has taken on a more justice-focused perspective. He’s learned over the course of his that due to historical inequalities in the U.S., pollution and other environmental problems have disproportionately impacted people of lower economic status and people of color. Since global warming will exacerbate these impacts, Kuffour seeks to address these growing inequalities through his work in energy data analysis.        

      Translating interests into activity

      Kuffour’s pursuit to expand his worldview never rests, even outside of the classroom. In his free time, he enjoys listening to podcasts or watching documentaries on any subject. When attempting to list all his favorite podcasts, he cuts himself off, saying, “This could go on for a while.”

      In 2022, Kuffour participated on a whim with a group of friends in an American Institute of Chemical Engineers competition, where he was tasked with creating a 1-by-1 foot cube that could filter water to specifications provided by the competition. He says it was fun to apply what he was learning at MIT to a project all the way in Arizona. 

      Kuffour enjoys discovering new things with friends as much as on his own. Three years ago, he started an intramural soccer team with friends from the Interphase EDGE program, which attracted many people he had never interacted with before. The team has been playing nearly every week since and Kuffour says the experience has been, “very enriching.”

      Kuffour hopes other students will also seek out knowledge and experiences from a wide range of sources during their undergraduate years. He offers: “Try as many things as possible even if you think you know what you want to do, and appreciate everything life has to offer.” More

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      in Energy

      Ayomikun Ayodeji ’22 named a 2024 Rhodes Scholar

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      Ayomikun “Ayo” Ayodeji ’22 from Lagos, Nigeria, has been selected as a Rhodes Scholar for West Africa. He will begin fully funded postgraduate studies at Oxford University in the U.K. next fall.

      Ayodeji was supported by Associate Dean Kim Benard and the Distinguished Fellowships team in Career Advising and Professional Development, and received additional mentorship from the Presidential Committee on Distinguished Fellowships.

      “Ayo has worked hard to develop his vision and to express it in ways that will capture the imagination of the broader world. It is a thrill to see him recognized this year as a Rhodes Scholar,” says Professor Nancy Kanwisher, who co-chairs the committee along with Professor Will Broadhead.

      Ayodeji graduated from MIT in 2022 with BS degrees in chemical engineering and management. He is currently an associate at Boston Consulting Group.

      He is passionate about championing reliable energy access across the African landscape and fostering culturally inclusive communities. As a Rhodes Scholar, he will pursue an MSc in energy systems and an MSc in global governance and diplomacy.

      During his time at MIT, Ayodeji’s curiosity for energy innovations was fueled by his research on perovskite solar cells under the MIT Energy Initiative. He then went on to intern at Pioneer Natural Resources where he explored the boundless applications of machine learning tools in completions. At BCG, Ayodeji supports both public and private sector clients on a variety of renewable energy topics including clean energy transition, decarbonization roadmaps, and workforce development.

      Ayodeji’s community-oriented mindset led him to team up with a group of friends and partner with the Northeast Children’s Trust (NECT), an organization that helps children affected by the Boko Haram insurgency in northeastern Nigeria. The project, sponsored by Davis Projects for Peace and MIT’s PKG Center, expanded NECT’s programs via an offline, portable classroom server.

      Ayodeji served as an undergraduate representative on the MIT Department of Chemical Engineering’s Diversity, Equity, and Inclusion Committee. He was also vice president of the MIT African Students’ Association and a coordinator for the annual MIT International Students Orientation. More

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      in Energy

      MIT startup has big plans to pull carbon from the air

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      In order to avoid the worst effects of climate change, the United Nations has said we’ll need to not only reduce emissions but also remove carbon dioxide from the atmosphere. One method for achieving carbon removal is direct air capture and storage. Such technologies are still in their infancy, but many efforts are underway to scale them up quickly in hopes of heading off the most catastrophic effects of climate change.

      The startup Noya, founded by Josh Santos ’14, is working to accelerate direct-air carbon removal with a low-power, modular system that can be mass manufactured and deployed around the world. The company plans to power its system with renewable energy and build its facilities near injection wells to store carbon underground.

      Using third-party auditors to verify the amount of carbon dioxide captured and stored, Noya is selling carbon credits to help organizations reach net-zero emissions targets.

      “Think of our systems for direct air capture like solar panels for carbon negativity,” says Santos, who formerly played a role in Tesla’s much-publicized manufacturing scale-up for its Model 3 electric sedan. “We can stack these boxes in a LEGO-like fashion to achieve scale in the field.”

      The three-year old company is currently building its first commercial pilot facility, and says its first full-scale commercial facility will have the capacity to pull millions of tons of carbon from the air each year. Noya has already secured millions of dollars in presales to help build its first facilities from organizations including Shopify, Watershed, and a university endowment.

      Santos says the ambitious approach, which is driven by the urgent need to scale carbon removal solutions, was influenced by his time at MIT.

      “I need to thank all of my MIT professors,” Santos says. “I don’t think any of this would be possible without the way in which MIT opened up my horizons by showing me what’s possible when you work really hard.”

      Finding a purpose

      Growing up in the southeastern U.S., Santos says he first recognized climate change as an issue by experiencing the increasing intensity of hurricanes in his neighborhood. One year a hurricane forced his family to evacuate their town. When they returned, their church was gone.

      “The storm left a really big mark on me and how I thought about the world,” Santos says. “I realized how much climate change can impact people.”

      When Santos came to MIT as an undergraduate, he took coursework related to climate change and energy systems, eventually majoring in chemical engineering. He also learned about startups through courses he took at the MIT Sloan School of Management and by taking part in MIT’s Undergraduate Research Opportunities Program (UROP), which exposed him to researchers in the early stages of commercializing research from MIT labs.

      More than the coursework, though, Santos says MIT instilled in him a desire to make a positive impact on the world, in part through a four-day development workshop called LeaderShape that he took one January during the Institute’s Independent Activities Period (IAP).

      “LeaderShape teaches students how to lead with integrity, and the core lesson is that any privilege you have you should try to leverage to improve the lives of other people,” Santos says. “That really stuck with me. Going to MIT is a huge privilege, and it makes me feel like I have a responsibility to put that privilege to work to the betterment of society. It shaped a lot of how I view my career.”

      After graduation, Santos worked at Tesla, then at Harley Davidson, where he worked on electric powertrains. Eventually he decided electric vehicle technology couldn’t solve climate change on its own, so in the spring of 2020 he founded Noya with friend Daniel Cavaro.

      The initial idea for Noya was to attach carbon capture devices to cooling towers to keep equipment costs low. The founders pivoted in response to the passage of the Inflation Reduction Act in 2022 because their machines weren’t big enough to qualify for the new tax credits in the law, which required each system to capture at least 1,000 tons of CO2 per year.

      Noya’s new systems will combine thousands of its modular units to create massive facilities that can capture millions of tons of CO2 right next to existing injection wells.

      Each of Noya’s units is about the size of a solar panel at about 6 feet wide, 4.5 feet tall, and 1 foot thick. A fan blows air through tiny channels in each unit that contain Noya’s carbon capture material. The company’s material solution consists of an activated carbon monolith and a proprietary chemical feedstock that binds to the carbon in the air. When the material becomes saturated with carbon, electricity is applied to the material and a light vacuum collects a pure stream of carbon.

      The goal is for each of Noya’s modules to remove about 60 tons of CO2 from the atmosphere per year.

      “Other direct air capture companies need a big hot piece of equipment — like an oven, steam generator, or kiln — that takes electricity and converts it to get heat to the material,” Santos says. “Any lost heat into the surrounding environment is excess cost. We skip the need for the excess equipment and their inefficiencies by adding the electricity directly to the material itself.”

      Scaling with urgency

      From its office in Oakland, California, Noya is putting an experimental module through tests to optimize its design. Noya will launch its first testing facility, which should remove about 350 tons of CO2 per year, in 2024. It has already secured renewable energy and injection storage partners for that facility. Over the next few years Noya plans to capture and remove thousands of tons of CO2, and the company’s first commercial-scale facility will aim to remove about 3 million tons of carbon annually.

      “That design is what we’ll replicate across the world to grow our planetary impact,” Santos says. “We’re trying to scale up as fast as possible.”

      Noya has already sold all of the carbon credits it expects to generate in its first five years, and the founders believe the growing demand from companies and governments to purchase high-quality carbon credits will outstrip supply for at least the next 10 years in the nascent carbon removal industry, which also includes approaches like enhanced rock weathering, biomass carbon storage, and ocean alkalinity enhancement.

      “We’re going to need something like 30 companies the size of Shell to achieve the scale we need,” Santos says. “I think there will be large companies in each of those verticals. We’re in the early innings here.”

      Santos believes the carbon removal market can scale without government mandates, but he also sees increasing government and public support for carbon removal technologies around the world.

      “Carbon removal is a waste management problem,” Santos says. “You can’t just throw trash in the middle of the street. The way we currently deal with trash is polluters pay to clean up their waste. Carbon removal should be like that. CO2 is a waste product, and we should have regulations in place that are requiring polluters, like businesses, to clean up their waste emissions. It’s a public good to provide cleaner air.” More

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      in Energy

      Pixel-by-pixel analysis yields insights into lithium-ion batteries

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      By mining data from X-ray images, researchers at MIT, Stanford University, SLAC National Accelerator, and the Toyota Research Institute have made significant new discoveries about the reactivity of lithium iron phosphate, a material used in batteries for electric cars and in other rechargeable batteries.

      The new technique has revealed several phenomena that were previously impossible to see, including variations in the rate of lithium intercalation reactions in different regions of a lithium iron phosphate nanoparticle.

      The paper’s most significant practical finding — that these variations in reaction rate are correlated with differences in the thickness of the carbon coating on the surface of the particles — could lead to improvements in the efficiency of charging and discharging such batteries.

      “What we learned from this study is that it’s the interfaces that really control the dynamics of the battery, especially in today’s modern batteries made from nanoparticles of the active material. That means that our focus should really be on engineering that interface,” says Martin Bazant, the E.G. Roos Professor of Chemical Engineering and a professor of mathematics at MIT, who is the senior author of the study.

      This approach to discovering the physics behind complex patterns in images could also be used to gain insights into many other materials, not only other types of batteries but also biological systems, such as dividing cells in a developing embryo.

      “What I find most exciting about this work is the ability to take images of a system that’s undergoing the formation of some pattern, and learning the principles that govern that,” Bazant says.

      Hongbo Zhao PhD ’21, a former MIT graduate student who is now a postdoc at Princeton University, is the lead author of the new study, which appears today in Nature. Other authors include Richard Bratz, the Edwin R. Gilliland Professor of Chemical Engineering at MIT; William Chueh, an associate professor of materials science and engineering at Stanford and director of the SLAC-Stanford Battery Center; and Brian Storey, senior director of Energy and Materials at the Toyota Research Institute.

      “Until now, we could make these beautiful X-ray movies of battery nanoparticles at work, but it was challenging to measure and understand subtle details of how they function because the movies were so information-rich,” Chueh says. “By applying image learning to these nanoscale movies, we can extract insights that were not previously possible.”

      Modeling reaction rates

      Lithium iron phosphate battery electrodes are made of many tiny particles of lithium iron phosphate, surrounded by an electrolyte solution. A typical particle is about 1 micron in diameter and about 100 nanometers thick. When the battery discharges, lithium ions flow from the electrolyte solution into the material by an electrochemical reaction known as ion intercalation. When the battery charges, the intercalation reaction is reversed, and ions flow in the opposite direction.

      “Lithium iron phosphate (LFP) is an important battery material due to low cost, a good safety record, and its use of abundant elements,” Storey says. “We are seeing an increased use of LFP in the EV market, so the timing of this study could not be better.”

      Before the current study, Bazant had done a great deal of theoretical modeling of patterns formed by lithium-ion intercalation. Lithium iron phosphate prefers to exist in one of two stable phases: either full of lithium ions or empty. Since 2005, Bazant has been working on mathematical models of this phenomenon, known as phase separation, which generates distinctive patterns of lithium-ion flow driven by intercalation reactions. In 2015, while on sabbatical at Stanford, he began working with Chueh to try to interpret images of lithium iron phosphate particles from scanning tunneling X-ray microscopy.

      Using this type of microscopy, the researchers can obtain images that reveal the concentration of lithium ions, pixel-by-pixel, at every point in the particle. They can scan the particles several times as the particles charge or discharge, allowing them to create movies of how lithium ions flow in and out of the particles.

      In 2017, Bazant and his colleagues at SLAC received funding from the Toyota Research Institute to pursue further studies using this approach, along with other battery-related research projects.

      By analyzing X-ray images of 63 lithium iron phosphate particles as they charged and discharged, the researchers found that the movement of lithium ions within the material could be nearly identical to the computer simulations that Bazant had created earlier. Using all 180,000 pixels as measurements, the researchers trained the computational model to produce equations that accurately describe the nonequilibrium thermodynamics and reaction kinetics of the battery material.
      By analyzing X-ray images of lithium iron phosphate particles as they charged and discharged, researchers have shown that the movement of lithium ions within the material was nearly identical to computer simulations they had created earlier.  In each pair, the actual particles are on the left and the simulations are on the right.Courtesy of the researchers

      “Every little pixel in there is jumping from full to empty, full to empty. And we’re mapping that whole process, using our equations to understand how that’s happening,” Bazant says.

      The researchers also found that the patterns of lithium-ion flow that they observed could reveal spatial variations in the rate at which lithium ions are absorbed at each location on the particle surface.

      “It was a real surprise to us that we could learn the heterogeneities in the system — in this case, the variations in surface reaction rate — simply by looking at the images,” Bazant says. “There are regions that seem to be fast and others that seem to be slow.”

      Furthermore, the researchers showed that these differences in reaction rate were correlated with the thickness of the carbon coating on the surface of the lithium iron phosphate particles. That carbon coating is applied to lithium iron phosphate to help it conduct electricity — otherwise the material would conduct too slowly to be useful as a battery.

      “We discovered at the nano scale that variation of the carbon coating thickness directly controls the rate, which is something you could never figure out if you didn’t have all of this modeling and image analysis,” Bazant says.

      The findings also offer quantitative support for a hypothesis Bazant formulated several years ago: that the performance of lithium iron phosphate electrodes is limited primarily by the rate of coupled ion-electron transfer at the interface between the solid particle and the carbon coating, rather than the rate of lithium-ion diffusion in the solid.

      Optimized materials

      The results from this study suggest that optimizing the thickness of the carbon layer on the electrode surface could help researchers to design batteries that would work more efficiently, the researchers say.

      “This is the first study that’s been able to directly attribute a property of the battery material with a physical property of the coating,” Bazant says. “The focus for optimizing and designing batteries should be on controlling reaction kinetics at the interface of the electrolyte and electrode.”

      “This publication is the culmination of six years of dedication and collaboration,” Storey says. “This technique allows us to unlock the inner workings of the battery in a way not previously possible. Our next goal is to improve battery design by applying this new understanding.”  

      In addition to using this type of analysis on other battery materials, Bazant anticipates that it could be useful for studying pattern formation in other chemical and biological systems.

      This work was supported by the Toyota Research Institute through the Accelerated Materials Design and Discovery program. More

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      in Environment

      Harnessing hydrogen’s potential to address long-haul trucking emissions

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      The transportation of goods forms the basis of today’s globally distributed supply chains, and long-haul trucking is a central and critical link in this complex system. To meet climate goals around the world, it is necessary to develop decarbonized solutions to replace diesel powertrains, but given trucking’s indispensable and vast role, these solutions must be both economically viable and practical to implement. While hydrogen-based options, as an alternative to diesel, have the potential to become a promising decarbonization strategy, hydrogen has significant limitations when it comes to delivery and refueling.These roadblocks, combined with hydrogen’s compelling decarbonization potential, are what motivated a team of MIT researchers led by William H. Green, the Hoyt Hottel Professor in Chemical Engineering, to explore a cost-effective way to transport and store hydrogen using liquid organic hydrogen carriers (LOHCs). The team is developing a disruptive technology that allows LOHCs to not only deliver the hydrogen to the trucks, but also store the hydrogen onboard.Their findings were recently published in Energy and Fuels, a peer-reviewed journal of the American Chemical Society, in a paper titled “Perspective on Decarbonizing Long-Haul Trucks Using Onboard Dehydrogenation of Liquid Organic Hydrogen Carriers.” The MIT team is led by Green, and includes graduate students Sayandeep Biswas and Kariana Moreno Sader. Their research is supported by the MIT Climate and Sustainability Consortium (MCSC) through its Seed Awards program and MathWorks, and ties into the work within the MCSC’s Tough Transportation Modes focus area.An “onboard” approachCurrently, LOHCs, which work within existing retail fuel distribution infrastructure, are used to deliver hydrogen gas to refueling stations, where it is then compressed and delivered onto trucks equipped with hydrogen fuel cell or combustion engines.“This current approach incurs significant energy loss due to endothermic hydrogen release and compression at the retail station” says Green. “To address this, our work is exploring a more efficient application, with LOHC-powered trucks featuring onboard dehydrogenation.”To implement such a design, the team aims to modify the truck’s powertrain (the system inside a vehicle that produces the energy to propel it forward) to allow onboard hydrogen release from the LOHCs, using waste heat from the engine exhaust to power the “dehydrogenation” process. 

      Proposed process flow diagram for onboard dehydrogenation. Component sizes are not to scale and have been enlarged for illustrative purposes.

      Image courtesy of the Green Group.

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      The dehydrogenation process happens within a high-temperature reactor, which continually receives hydrogen-rich LOHCs from the fuel storage tank. Hydrogen released from the reactor is fed to the engine, after passing through a separator to remove any lingering LOHC. On its way to the engine, some of the hydrogen gets diverted to a burner to heat the reactor, which helps to augment the reactor heating provided by the engine exhaust gases.Acknowledging and addressing hydrogen’s drawbacksThe team’s paper underscores that current uses of hydrogen, including LOHC systems, to decarbonize the trucking sector have drawbacks. Regardless of technical improvements, these existing options remain prohibitively expensive due to the high cost of retail hydrogen delivery.“We present an alternative option that addresses a lot of the challenges and seems to be a viable way in which hydrogen can be used in this transportation context,” says Biswas, who was recently elected to the MIT Martin Family Society of Fellows for Sustainability for his work in this area. “Hydrogen, when used through LOHCs, has clear benefits for long-hauling, such as scalability and fast refueling time. There is also an enormous potential to improve delivery and refueling to further reduce cost, and our system is working to do that.”“Utilizing hydrogen is an option that is globally accessible, and could be extended to countries like the one where I am from,” says Moreno Sader, who is originally from Colombia. “Since it synergizes with existing infrastructure, large upfront investments are not necessary. The global applicability is huge.”Moreno Sader is a MathWorks Fellow, and, along with the rest of the team, has been using MATLAB tools to develop models and simulations for this work.Different sectors coming togetherDecarbonizing transportation modes, including long-haul trucking, requires expertise and perspectives from different industries — an approach that resonates with the MCSC’s mission.The team’s groundbreaking research into LOHC-powered trucking is among several projects supported by the MCSC within its Tough Transportation Modes focus area, led by postdoc Impact Fellow Danika MacDonell. The MCSC-supported projects were chosen to tackle a complementary set of societally important and industry-relevant challenges to decarbonizing heavy-duty transportation, which span a range of sectors and solution pathways. Other projects focus, for example, on logistics optimization for electrified trucking fleets, or air quality and climate impacts of ammonia-powered shipping.The MCSC works to support and amplify the impact of these projects by engaging the research teams with industry partners from a variety of sectors. In addition, the MCSC pursues a collective multisectoral approach to decarbonizing transportation by facilitating shared learning across the different projects through regular cross-team discussion.The research led by Green celebrates this cross-sector theme by integrating industry-leading computing tools provided by MathWorks with cutting-edge developments in chemical engineering, as well as industry-leading commercial LOHC reactor demonstrations, to build a compelling vision for cost-effective LOHC-powered trucking.The review and research conducted in the Energy and Fuels article lays the groundwork for further investigations into LOHC-powered truck design. The development of such a vehicle — with a power-dense, efficient, and robust onboard hydrogen release system — requires dedicated investigations and further optimization of core components geared specifically toward the trucking application. More

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      Making aviation fuel from biomass

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      In 2021, nearly a quarter of the world’s carbon dioxide emissions came from the transportation sector, with aviation being a significant contributor. While the growing use of electric vehicles is helping to clean up ground transportation, today’s batteries can’t compete with fossil fuel-derived liquid hydrocarbons in terms of energy delivered per pound of weight — a major concern when it comes to flying. Meanwhile, based on projected growth in travel demand, consumption of jet fuel is projected to double between now and 2050 — the year by which the international aviation industry has pledged to be carbon neutral.

      Many groups have targeted a 100 percent sustainable hydrocarbon fuel for aircraft, but without much success. Part of the challenge is that aviation fuels are so tightly regulated. “This is a subclass of fuels that has very specific requirements in terms of the chemistry and the physical properties of the fuel, because you can’t risk something going wrong in an airplane engine,” says Yuriy Román-Leshkov, the Robert T. Haslam Professor of Chemical Engineering. “If you’re flying at 30,000 feet, it’s very cold outside, and you don’t want the fuel to thicken or freeze. That’s why the formulation is very specific.”

      Aviation fuel is a combination of two large classes of chemical compounds. Some 75 to 90 percent of it is made up of “aliphatic” molecules, which consist of long chains of carbon atoms linked together. “This is similar to what we would find in diesel fuels, so it’s a classic hydrocarbon that is out there,” explains Román-Leshkov. The remaining 10 to 25 percent consists of “aromatic” molecules, each of which includes at least one ring made up of six connected carbon atoms.

      In most transportation fuels, aromatic hydrocarbons are viewed as a source of pollution, so they’re removed as much as possible. However, in aviation fuels, some aromatic molecules must remain because they set the necessary physical and combustion properties of the overall mixture. They also perform one more critical task: They ensure that seals between various components in the aircraft’s fuel system are tight. “The aromatics get absorbed by the plastic seals and make them swell,” explains Román-Leshkov. “If for some reason the fuel changes, so can the seals, and that’s very dangerous.”

      As a result, aromatics are a necessary component — but they’re also a stumbling block in the move to create sustainable aviation fuels, or SAFs. Companies know how to make the aliphatic fraction from inedible parts of plants and other renewables, but they haven’t yet developed an approved method of generating the aromatic fraction from sustainable sources. As a result, there’s a “blending wall,” explains Román-Leshkov. “Since we need that aromatic content — regardless of its source — there will always be a limit on how much of the sustainable aliphatic hydrocarbons we can use without changing the properties of the mixture.” He notes a similar blending wall with gasoline. “We have a lot of ethanol, but we can’t add more than 10 percent without changing the properties of the gasoline. In fact, current engines can’t handle even 15 percent ethanol without modification.”

      No shortage of renewable source material — or attempts to convert it

      For the past five years, understanding and solving the SAF problem has been the goal of research by Román-Leshkov and his MIT team — Michael L. Stone PhD ’21, Matthew S. Webber, and others — as well as their collaborators at Washington State University, the National Renewable Energy Laboratory (NREL), and the Pacific Northwest National Laboratory. Their work has focused on lignin, a tough material that gives plants structural support and protection against microbes and fungi. About 30 percent of the carbon in biomass is in lignin, yet when ethanol is generated from biomass, the lignin is left behind as a waste product.

      Despite valiant efforts, no one has found an economically viable, scalable way to turn lignin into useful products, including the aromatic molecules needed to make jet fuel 100 percent sustainable. Why not? As Román-Leshkov says, “It’s because of its chemical recalcitrance.” It’s difficult to make it chemically react in useful ways. As a result, every year millions of tons of waste lignin are burned as a low-grade fuel, used as fertilizer, or simply thrown away.

      Understanding the problem requires understanding what’s happening at the atomic level. A single lignin molecule — the starting point of the challenge — is a big “macromolecule” made up of a network of many aromatic rings connected by oxygen and hydrogen atoms. Put simply, the key to converting lignin into the aromatic fraction of SAF is to break that macromolecule into smaller pieces while in the process getting rid of all of the oxygen atoms.

      In general, most industrial processes begin with a chemical reaction that prevents the subsequent upgrading of lignin: As the lignin is extracted from the biomass, the aromatic molecules in it react with one another, linking together to form strong networks that won’t react further. As a result, the lignin is no longer useful for making aviation fuels.

      To avoid that outcome, Román-Leshkov and his team utilize another approach: They use a catalyst to induce a chemical reaction that wouldn’t normally occur during extraction. By reacting the biomass in the presence of a ruthenium-based catalyst, they are able to remove the lignin from the biomass and produce a black liquid called lignin oil. That product is chemically stable, meaning that the aromatic molecules in it will no longer react with one another.

      So the researchers have now successfully broken the original lignin macromolecule into fragments that contain just one or two aromatic rings each. However, while the isolated fragments don’t chemically react, they still contain oxygen atoms. Therefore, one task remains: finding a way to remove the oxygen atoms.

      In fact, says Román-Leshkov, getting from the molecules in the lignin oil to the targeted aromatic molecules required them to accomplish three things in a single step: They needed to selectively break the carbon-oxygen bonds to free the oxygen atoms; they needed to avoid incorporating noncarbon atoms into the aromatic rings (for example, atoms from the hydrogen gas that must be present for all of the chemical transformations to occur); and they needed to preserve the carbon backbone of the molecule — that is, the series of linked carbon atoms that connect the aromatic rings that remain.

      Ultimately, Román-Leshkov and his team found a special ingredient that would do the trick: a molybdenum carbide catalyst. “It’s actually a really amazing catalyst because it can perform those three actions very well,” says Román-Leshkov. “In addition to that, it’s extremely resistant to poisons. Plants can contain a lot of components like proteins, salts, and sulfur, which often poison catalysts so they don’t work anymore. But molybdenum carbide is very robust and isn’t strongly influenced by such impurities.”

      Trying it out on lignin from poplar trees

      To test their approach in the lab, the researchers first designed and built a specialized “trickle-bed” reactor, a type of chemical reactor in which both liquids and gases flow downward through a packed bed of catalyst particles. They then obtained biomass from a poplar, a type of tree known as an “energy crop” because it grows quickly and doesn’t require a lot of fertilizer.

      To begin, they reacted the poplar biomass in the presence of their ruthenium-based catalyst to extract the lignin and produce the lignin oil. They then flowed the oil through their trickle-bed reactor containing the molybdenum carbide catalyst. The mixture that formed contained some of the targeted product but also a lot of others that still contained oxygen atoms.

      Román-Leshkov notes that in a trickle-bed reactor, the time during which the lignin oil is exposed to the catalyst depends entirely on how quickly it drips down through the packed bed. To increase the exposure time, they tried passing the oil through the same catalyst twice. However, the distribution of products that formed in the second pass wasn’t as they had predicted based on the outcome of the first pass.

      With further investigation, they figured out why. The first time the lignin oil drips through the reactor, it deposits oxygen onto the catalyst. The deposition of the oxygen changes the behavior of the catalyst such that certain products appear or disappear — with the temperature being critical. “The temperature and oxygen content set the condition of the catalyst in the first pass,” says Román-Leshkov. “Then, on the second pass, the oxygen content in the flow is lower, and the catalyst can fully break the remaining carbon-oxygen bonds.” The process can thus operate continuously: Two separate reactors containing independent catalyst beds would be connected in series, with the first pretreating the lignin oil and the second removing any oxygen that remains.

      Based on a series of experiments involving lignin oil from poplar biomass, the researchers determined the operating conditions yielding the best outcome: 350 degrees Celsius in the first step and 375 C in the second step. Under those optimized conditions, the mixture that forms is dominated by the targeted aromatic products, with the remainder consisting of small amounts of other jet-fuel aliphatic molecules and some remaining oxygen-containing molecules. The catalyst remains stable while generating more than 87 percent (by weight) of aromatic molecules.

      “When we do our chemistry with the molybdenum carbide catalyst, our total carbon yields are nearly 85 percent of the theoretical carbon yield,” says Román-Leshkov. “In most lignin-conversion processes, the carbon yields are very low, on the order of 10 percent. That’s why the catalysis community got very excited about our results — because people had not seen carbon yields as high as the ones we generated with this catalyst.”

      There remains one key question: Does the mixture of components that forms have the properties required for aviation fuel? “When we work with these new substrates to make new fuels, the blend that we create is different from standard jet fuel,” says Román-Leshkov. “Unless it has the exact properties required, it will not qualify for certification as jet fuel.”

      To check their products, Román-Leshkov and his team send samples to Washington State University, where a team operates a combustion lab devoted to testing fuels. Results from initial testing of the composition and properties of the samples have been encouraging. Based on the composition and published prescreening tools and procedures, the researchers have made initial property predictions for their samples, and they looked good. For example, the freezing point, viscosity, and threshold sooting index are predicted to be lower than the values for conventional aviation aromatics. (In other words, their material should flow more easily and be less likely to freeze than conventional aromatics while also generating less soot in the atmosphere when they burn.) Overall, the predicted properties are near to or more favorable than those of conventional fuel aromatics.

      Next steps

      The researchers are continuing to study how their sample blends behave at different temperatures and, in particular, how well they perform that key task: soaking into and swelling the seals inside jet engines. “These molecules are not the typical aromatic molecules that you use in jet fuel,” says Román-Leshkov. “Preliminary tests with sample seals show that there’s no difference in how our lignin-derived aromatics swell the seals, but we need to confirm that. There’s no room for error.”

      In addition, he and his team are working with their NREL collaborators to scale up their methods. NREL has much larger reactors and other infrastructure needed to produce large quantities of the new sustainable blend. Based on the promising results thus far, the team wants to be prepared for the further testing required for the certification of jet fuels. In addition to testing samples of the fuel, the full certification procedure calls for demonstrating its behavior in an operating engine — “not while flying, but in a lab,” clarifies Román-Leshkov. In addition to requiring large samples, that demonstration is both time-consuming and expensive — which is why it’s the very last step in the strict testing required for a new sustainable aviation fuel to be approved.

      Román-Leshkov and his colleagues are now exploring the use of their approach with other types of biomass, including pine, switchgrass, and corn stover (the leaves, stalks, and cobs left after corn is harvested). But their results with poplar biomass are promising. If further testing confirms that their aromatic products can replace the aromatics now in jet fuel, “the blending wall could disappear,” says Román-Leshkov. “We’ll have a means of producing all the components in aviation fuel from renewable material, potentially leading to aircraft fuel that’s 100 percent sustainable.”

      This research was initially funded by the Center for Bioenergy Innovation, a U.S. Department of Energy (DOE) Research Center supported by the Office of Biological and Environmental Research in the DOE Office of Science. More recent funding came from the DOE Bioenergy Technologies Office and from Eni S.p.A. through the MIT Energy Initiative. Michael L. Stone PhD ’21 is now a postdoc in chemical engineering at Stanford University. Matthew S. Webber is a graduate student in the Román-Leshkov group, now on leave for an internship at the National Renewable Energy Laboratory.

      This article appears in the Spring 2023 issue of Energy Futures, the magazine of the MIT Energy Initiative. More