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    Recycling plastics from research labs

    In 2019, MIT’s Environment, Health, and Safety (EHS) Office collaborated with several research labs in the Department of Biology to determine the feasibility of recycling clean lab plastics. Based on early successes with waste isolation and plastics collection, EHS collaborated with GreenLabs Recycling, a local startup, to remove and recycle lab plastics from campus. It was a huge success.

    Today, EHS spearheads the campus Lab Plastics Recycling Program, and its EHS technicians regularly gather clean lab plastics from 212 MIT labs, transferring them to GreenLabs for recycling. Since its pilot stage, the number of labs participating in the program has grown, increasing the total amount of plastic gathered and recycled. In 2020, EHS collected 170 pounds of plastic waste per week from participating labs. That increased to 250 pounds per week in 2021. In 2022, EHS collected a total of 19,000 pounds, or 280 pounds of plastic per week.

    Joanna Buchthal, a research assistant with the MIT Media Lab, indicates that, prior to joining the EHS Lab Plastics Recycling Program, “our laboratory was continuously troubled by the substantial volume of plastic waste we produced and disheartened by our inability to recycle it. We frequently addressed this issue during our group meetings and explored various ways to repurpose our waste, yet we never arrived at a viable solution.”

    The EHS program now provides a solution to labs facing similar challenges with plastics use. After pickup and removal, the plastics are shredded and sold as free stock for injection mold product manufacturing. Buchthal says, “My entire lab is delighted to recycle our used tip boxes and transform them into useful items for other labs!”

    Recently, GreenLabs presented EHS with a three-gallon bucket that local manufacturers produced from 100 percent recycled plastic gathered from MIT labs. No fillers or additives were used in its production.

    Keeping it clean

    The now-growing EHS service and operation started as a pilot. In June 2019, MIT restricted which lab-generated items could be placed in single-stream recycling. MIT’s waste vendors were no longer accepting possibly contaminated waste, such as gloves, pipette tip boxes, bottles, and other plastic waste typically generated in biological research labs. The waste vendors would audit MIT’s single-stream recycling and reject items if they observed any contamination.

    Facing these challenges, the EHS coordinator for biology, John Fucillo, and several EHS representatives from the department met with EHS staff to brainstorm potential recycling solutions. Ensuring the decontamination of the plastic and coordinating its removal in an efficient way were the primary challenges for the labs, says Fucillo, who shared his and lab members’ concerns about the amount of plastic being thrown away with Mitch Galanek, EHS associate director for the Radiation Protection Program. Galanek says, “I immediately recognized the frustration expressed by John and other lab contacts as an opportunity to collaborate.”

    In July 2019, Galanek and a team of EHS technicians began segregating and collecting clean plastic waste from several labs within the biology department. EHS provided the labs with collection containers, and its technicians managed the waste removal over a four-month period, which produced a snapshot of the volume and type of waste generated. An audit of the waste determined that approximately 80 percent of the clean plastic waste generated was empty pipette tip boxes and conical tube racks.

    Based on these data, EHS launched a lab plastics recycling pilot program in November 2019. Labs from the Department of Biology and the Koch Institute for Integrative Cancer Research were invited to participate by recycling their clean, uncontaminated pipette tip boxes and conical tube racks. In addition to providing these labs with collection boxes and plastic liners, EHS also developed an online waste collection request tool to submit plastic pickup requests. EHS also collected the waste containers once they were full.

    Assistant professor of biology Seychelle Vos joined the pilot program as soon as she started her lab in fall 2019. Vos shares that “we already use pipette tips boxes that produce minimal waste, and this program allows us to basically recycle any part of the box except for tips. Pipette boxes are a significant source of plastic waste. This program helps us to be more environmentally and climate friendly.” 

    Given the increased participation in the program, EHS technician Dave Pavone says that plastic pickup is now a “regular component of our work schedules.”

    Together, the EHS technicians, commonly known as “techs,” manage the pickup of nearly 300 plastic collection containers across campus. Normand Desrochers, one of the EHS techs, shares that each morning he plans his pickup route “to get the job done efficiently.” While weekly pickups are a growing part of their schedules, Desrochers notes that everyone has been “super appreciative in what we do for their labs. And what we do makes their job that much easier, being able to focus on their research.”

    Barbara Karampalas, a lab operations manager within the Department of Biological Engineering, is one of many to express appreciation for the program: “We have a fairly large lab with 35 researchers, so we generate a lot of plastic waste … [and] knowing how many tip boxes we were using concerned me. I really appreciate the effort EHS has made to implement this program to help us reduce our impact on the environment.” The program also “makes people in the lab more aware of the issue of plastic waste and MIT’s commitment to reduce its impact on the environment,” says Karampalas.

    Looking ahead

    MIT labs continue to enthusiastically embrace the EHS Lab Plastics Recycling Program: 112 faculty across 212 labs are currently participating in the program. While only empty pipette tip boxes and conical tube racks are currently collected, EHS is exploring which lab plastics could be manufactured into products for use in the labs and repeatedly recycled. Specifically, the EHS Office is considering whether recycled plastic could be used to produce secondary containers for collecting hazardous waste and benchtop transfer containers used for collecting medical waste. As Seychelle notes, “Most plastics cannot be recycled in the current schemes due to their use in laboratory science.”

    Says Fucillo, “Our hope is that this program can be expanded to include other products which could be recycled from the wet labs.” John MacFarlane, research engineer and EHS coordinator for civil and environmental engineering, echoes this sentiment: “With plastic recycling facing economic constraints, this effort by the Institute deserves to be promoted and, hopefully, expanded.”

    “Having more opportunities to recycle ’biologically clean’ plastics would help us have a smaller carbon footprint,” agrees Vos. “We love this program and hope it expands further!”

    MIT labs interested in participating in the EHS Lab Plastics Recycling Program can contact pipetip@mit.edu to learn more. More

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    Engineering for social impact

    A desire to make meaningful contributions to society has influenced Runako Gentles’ path in life. Gentles grew up in Jamaica with a supportive extended family that instilled in him his connection to his faith and his aspiration to aim for greatness.

    “While growing up, I was encouraged to live a life that could potentially bring about major positive changes in my family and many other people’s lives,” says the MIT junior.

    One of those pathways his parents encouraged is pursuing excellence in academics.

    Gentles attended Campion College, a Jesuit high school in Jamaica for academically high-achieving students. Gentles was valedictorian and even won an award “for the member of the valedictory class who most closely resembles the ideal of intellectual competence, openness to growth, and commitment to social justice.”

    Although he did well in all subjects, he naturally gravitated toward biology and chemistry. “There are certain subjects people just make sense of material much faster, and high school biology and chemistry were those subjects for me,” he says. His love of learning often surprised friends and classmates when he could recall science concepts and definitions years later.  

    For several years Gentles wanted to pursue the field of medicine. He remembers becoming more excited about the career of a surgeon after reading a book on the story of retired neurosurgeon Ben Carson. During his advanced studies at Campion, he attended a career event and met with a neurosurgeon who invited him and other classmates to watch a surgical procedure. Gentles had the unique learning experience to observe a spinal operation. Around that same time another learning opportunity presented itself. His biology teacher recommended he apply to a Caribbean Science Foundation initiative called Student Program for Innovation, Science, and Engineering (SPISE) to explore careers in science, technology, engineering, and math. The intensive residential summer program for Caribbean students is modeled after the Minority Introduction to Engineering and Science (MITES) program at MIT. Cardinal Warde, a professor of electrical engineering at MIT who is also from the Caribbean, serves as the faculty director for both MITES and SPISE. The program was Gentles’ first major exposure to engineering.

    “I felt like I was in my first year of college at SPISE. It was an amazing experience and it helped me realize the opportunities that an engineering career path offers,” Gentles says. He excelled in the SPISE program, even winning one of the program’s highest honors for demonstrating overall excellence and leadership.

    SPISE was profoundly impactful to Gentles and he decided to pursue engineering at MIT. While further exploring his engineering interests before his first year at MIT, he remembers reading an article that piqued his interest in industry sectors that met basic human and societal needs.

    “I started thinking more about engineering and ethics,” says Gentles. He wanted to spend his time learning how to use science and engineering to make meaningful change in society.  “I think back to wanting to be a doctor for many years to help sick people, but I took it a step further. I wanted to get closer to addressing some of the root causes of deaths, illnesses, and the poor quality of life for billions of people,” he says of his decision to pursue a degree in civil and environmental engineering.

    Gentles spent his first semester at MIT working as a remote student when the Covid pandemic shut down in-person learning. He participated in 1.097 (Introduction to Civil and Environmental Engineering Research) during the January Independent Activities Period, in which undergraduates work one-on-one with graduate students or postdoc mentors on research projects that align with their interests. Gentles worked in the lab of Ruben Juanes exploring the use of machine learning to analyze earthquake data to determine whether different geologic faults in Puerto Rico resulted in distinguishable earthquake clusters. He joined the lab of Desiree Plata in the summer of his sophomore year on another undergraduate research opportunity (UROP) project, analyzing diesel range organic compounds in water samples collected from shallow groundwater sources near hydraulic fracking sites in West Virginia. The experience even led Gentles to be a co-author in his graduate student mentor’s abstract proposal for the American Geophysical Union Fall Meeting 2022 conference.  

    Gentles says he found the Department of Civil and Environmental Engineering a place for him to have the big-picture mindset of thinking about how technology is going to affect the environment, which ultimately affects society. “Choosing this department was not just about gaining the technical knowledge that most interested me. I wanted to be in a space where I would significantly develop my mindset of using innovation to bring more harmony between society and the environment,” says Gentles.

    Outside of the classroom, learning acoustic guitar is a passion for Gentles. He plays at social events for Cru, a Christian community at MIT, where he serves as a team leader. He credits Cru with helping him feel connected to a lot of different people, even outside of MIT.

    He’s also a member of the Bernard M. Gordon-MIT Engineering Leadership Program, which helps undergraduates gain and hone leadership skills to prepare them for careers in engineering. After learning and exploring more UROPs and classes in civil and environmental engineering, he aspires to hold a position of leadership where he can use his environmental knowledge to impact human lives.

    “Mitigating environmental issues can sometimes be a very complicated endeavor involving many stakeholders,” Gentles says. “We need more bright minds to be thinking of creative ways to address these pressing problems. We need more leaders helping to make society more harmonious with our planet.” More

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    Fieldwork class examines signs of climate change in Hawaii

    When Joy Domingo-Kameenui spent two weeks in her native Hawaii as part of MIT class 1.091 (Traveling Research Environmental eXperiences), she was surprised to learn about the number of invasive and endangered species. “I knew about Hawaiian ecology from middle and high school but wasn’t fully aware to the extent of how invasive species and diseases have resulted in many of Hawaii’s endemic species becoming threatened,” says Domingo-Kameenui.  

    Domingo-Kameenui was part of a group of MIT students who conducted field research on the Big Island of Hawaii in the Traveling Research Environmental eXperiences (TREX) class offered by the Department of Civil and Environmental Engineering. The class provides undergraduates an opportunity to gain hands-on environmental fieldwork experience using Hawaii’s geology, chemistry, and biology to address two main topics of climate change concern: sulfur dioxide (SO2) emissions and forest health.

    “Hawaii is this great system for studying the effects of climate change,” says David Des Marais, the Cecil and Ida Green Career Development Professor of Civil and Environmental Engineering and lead instructor of TREX. “Historically, Hawaii has had occasional mild droughts that are related to El Niño, but the droughts are getting stronger and more frequent. And we know these types of extreme weather events are going to happen worldwide.”

    Climate change impacts on forests

    The frequency and intensity of extreme events are also becoming more of a problem for forests and plant life. Forests have a certain distribution of vegetation and as you get higher in elevation, the trees gradually turn into shrubs, and then rock. Trees don’t grow above the timberline, where the temperature and precipitation changes dramatically at the high elevations. “But unlike the Sierra Nevada or the Rockies, where the trees gradually change as you go up the mountains, in Hawaii, they gradually change, and then they just stop,” says Des Marais.

    “Why this is an interesting model for climate change,” explains Des Marais, “is that line where trees stop [growing] is going to move, and it’s going to become more unstable as the trade winds are affected by global patterns of air circulation, which are changing because of climate change.”

    The research question that Des Marais asks students to explore — How is the Hawaiian forest going to be affected by climate change? — uses Hawaii as a model for broader patterns in climate change for forests.

    To dive deeper into this question, students trekked up the mountain taking ground-level measurements of canopy cover with a camera app on their cellphones, estimating how much tree coverage blankets the sky when looking up, and observing how the canopy cover thins until they see no tree coverage at all as they go further up the mountain. Drones also flew above the forest to measure chlorophyll and how much plant matter remains. And then satellite data products from NASA and the European Space Agency were used to measure the distribution of chlorophyll, climate, and precipitation data from space.

    They also worked directly with community stakeholders at three locations around the island to access the forests and use technology to assess the ecology and biodiversity challenges. One of those stakeholders was the Kamehameha Schools Natural and Cultural Ecosystems Division, whose mission is to preserve the land and manage it in a sustainable way. Students worked with their plant biologists to help address and think about what management decisions will support the future health of their forests.

    “Across the island, rising temperatures and abnormal precipitation patterns are the main drivers of drought, which really has significant impacts on biodiversity, and overall human health,” says Ava Gillikin, a senior in civil and environmental engineering.

    Gillikin adds that “a good proportion of the island’s water system relies on rainwater catchment, exposing vulnerabilities to fluctuations in rain patterns that impact many people’s lives.”

    Deadly threats to native plants

    The other threats to Hawaii’s forests are invasive species causing ecological harm, from the prevalence of non-indigenous mosquitoes leading to increases in avian malaria and native bird death that threaten the native ecosystem, to a plant called strawberry guava.

    Strawberry guava is taking over Hawaii’s native ōhiʻa trees, which Domingo-Kameenui says is also contributing to Hawaii’s water production. “The plants absorb water quickly so there’s less water runoff for groundwater systems.”

    A fungal pathogen is also infecting native ōhiʻa trees. The disease, called rapid ʻohiʻa death (ROD), kills the tree within a few days to weeks. The pathogen was identified by researchers on the island in 2014 from the fungal genus, Ceratocystis. The fungal pathogen was likely carried into the forests by humans on their shoes, or contaminated tools, gear, and vehicles traveling from one location to another. The fungal disease is also transmitted by beetles that bore into trees and create a fine powder-like dust. This dust from an infected tree is then mixed with the fungal spores and can easily spread to other trees by wind, or contaminated soil.

    For Gillikin, seeing the effects of ROD in the field highlighted the impact improper care and preparation can have on native forests. “The ‘ohi’a tree is one of the most prominent native trees, and ROD can kill the trees very rapidly by putting a strain on its vascular system and preventing water from reaching all parts of the tree,” says Gillikin.

    Before entering the forests, students sprayed their shoes and gear with ethanol frequently to prevent the spread.

    Uncovering chemical and particle formation

    A second research project in TREX studied volcanic smog (vog) that plagues the air, making visibility problematic at times and causing a lot of health problems for people in Hawaii. The active Kilauea volcano releases SO2 into the atmosphere. When the SO2 mixes with other gasses emitted from the volcano and interacts with sunlight and the atmosphere, particulate matter forms.

    Students in the Kroll Group, led by Jesse Kroll, professor of civil and environmental engineering and chemical engineering, have been studying SO2 and particulate matter over the years, but not the chemistry directly in how those chemical transformations occur.

    “There’s a hypothesis that there is a functional connection between the SO2 and particular matter, but that’s never been directly demonstrated,” says Des Marais.

    Testing that hypothesis, the students were able to measure two different sizes of particulate matter formed from the SO2 and develop a model to show how much vog is generated downstream of the volcano.

    They spent five days at two sites from sunrise to late morning measuring particulate matter formation as the sun comes up and starts creating new particles. Using a combination of data sources for meteorology, such as UV index, wind speed, and humidity, the students built a model that demonstrates all the pieces of an equation that can calculate when new particles are formed.

    “You can build what you think that equation is based on first-principle understanding of the chemical composition, but what they did was measured it in real time with measurements of the chemical reagents,” says Des Marias.

    The students measured what was going to catalyze the chemical reaction of particulate matter — for instance, things like sunlight and ozone — and then calculated numbers to the outputs.

    “What they found, and what seems to be happening, is that the chemical reagents are accumulating overnight,” says Des Marais. “Then as soon as the sun rises in the morning all the transformation happens in the atmosphere. A lot of the reagents are used up and the wind blows everything away, leaving the other side of the island with polluted air,” adds Des Marais.

    “I found the vog particle formation fieldwork a surprising research learning,” adds Domingo-Kameenui who did some atmospheric chemistry research in the Kroll Group. “I just thought particle formation happened in the air, but we found wind direction and wind speed at a certain time of the day was extremely important to particle formation. It’s not just chemistry you need to look at, but meteorology and sunlight,” she adds.

    Both Domingo-Kameenui and Gillikin found the fieldwork class an important and memorable experience with new insight that they will carry with them beyond MIT.  

    How Gillikin approaches fieldwork or any type of community engagement in another culture is what she will remember most. “When entering another country or culture, you are getting the privilege to be on their land, to learn about their history and experiences, and to connect with so many brilliant people,” says Gillikin. “Everyone we met in Hawaii had so much passion for their work, and approaching those environments with respect and openness to learn is what I experienced firsthand and will take with me throughout my career.” More

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    An education in climate change

    Several years ago, Christopher Knittel’s father, then a math teacher, shared a mailing he had received at his high school. When he opened the packet, alarm bells went off for Knittel, who is the George P. Shultz Professor of Energy Economics at the MIT Sloan School of Management and the deputy director for policy at the MIT Energy Initiative (MITEI). “It was a slickly produced package of materials purporting to show how to teach climate change,” he says. “In reality, it was a thinly veiled attempt to kindle climate change denial.”

    Knittel was especially concerned to learn that this package had been distributed to schools nationwide. “Many teachers in search of information on climate change might use this material because they are not in a position to judge its scientific validity,” says Knittel, who is also the faculty director of the MIT Center for Energy and Environmental Policy Research (CEEPR). “I decided that MIT, which is committed to true science, was in the perfect position to develop its own climate change curriculum.”

    Today, Knittel is spearheading the Climate Action Through Education (CATE) program, a curriculum rolling out in pilot form this year in more than a dozen Massachusetts high schools, and eventually in high schools across the United States. To spur its broad adoption, says Knittel, the CATE curriculum features a unique suite of attributes: the creation of climate-based lessons for a range of disciplines beyond science, adherence to state-based education standards to facilitate integration into established curricula, material connecting climate change impacts to specific regions, and opportunities for students to explore climate solutions.

    CATE aims to engage both students and teachers in a subject that can be overwhelming. “We will be honest about the threats posed by climate change but also give students a sense of agency that they can do something about this,” says Knittel. “And for the many teachers — especially non-science teachers — starved for knowledge and background material, CATE offers resources to give them confidence to implement our curriculum.”

    Partnering with teachers

    From the outset, CATE sought guidance and hands-on development help from educators. Project manager Aisling O’Grady surveyed teachers to learn about their experiences teaching about climate and to identify the kinds of resources they lacked. She networked with MIT’s K-12 education experts and with Antje Danielson, MITEI director of education, “bouncing ideas off of them to shape the direction of our effort,” she says.

    O’Grady gained two critical insights from this process: “I realized that we needed practicing high school teachers as curriculum developers and that they had to represent different subject areas, because climate change is inherently interdisciplinary,” she says. This echoes the philosophy behind MITEI’s Energy Studies minor, she remarks, which includes classes from MIT’s different schools. “While science helps us understand and find solutions for climate change, it touches so many other areas, from economics, policy, environmental justice and politics, to history and literature.”

    In line with this thinking, CATE recruited Massachusetts teachers representing key subject areas in the high school curriculum: Amy Block, a full-time math teacher, and Lisa Borgatti, a full-time science teacher, both at the Governor’s Academy in Byfield; and Kathryn Teissier du Cros, a full-time language arts teacher at Newton North High School.

    The fourth member of this cohort, Michael Kozuch, is a full-time history teacher at Newton South High School, where he has worked for 24 years. Kozuch became engaged with environmental issues 15 years ago, introducing an elective in sustainability at Newton South. He serves on the coordinating committee for the Climate Action Network at the Massachusetts Teachers Association. He also is president of Earth Day Boston and organized Boston’s 50th anniversary celebration of Earth Day. When he learned that MIT was seeking teachers to help develop a climate education curriculum, he immediately applied.

    “I’ve heard time and again from teachers across the state that they want to incorporate climate change into the curriculum but don’t know how to make it work, given lesson plans and schedules geared toward preparing students for specific tests,” says Kozuch. “I knew that for a climate curriculum to succeed, it had to be part of an integrated approach.”

    Using climate as a lens

    Over the course of a year, Kozuch and fellow educators created units that fit into their pre-existing syllabi but were woven through with relevant climate change themes. Kozuch already had some experience in this vein, describing the role of the Industrial Revolution in triggering the use of fossil fuels and the greenhouse gas emissions that resulted. For CATE, Kozuch explored additional ways of shifting focus in covering U.S. history. There are, for instance, lessons looking at westward expansion in terms of land use, expulsion of Indigenous people, and environmental justice, and at the Baby Boom period and the emergence of the environmental movement.

    In English/language arts, there are units dedicated to explaining terms used by scientists and policymakers, such as “anthropogenic,” as well as lessons devoted to climate change fiction and to student-originated sustainability projects.

    The science and math classes work independently but also dovetail. For instance, there are science lessons that demystify the greenhouse effect, utilizing experiments to track fossil fuel emissions, which link to math lessons that calculate and graph the average rate of change of global carbon emissions. To make these classes even more relevant, there are labs where students compare carbon emissions in Massachusetts to those of a neighboring state, and where they determine the environmental and economic costs of plugging in electric devices in their own homes.

    Throughout this curriculum-shaping process, O’Grady and the teachers sought feedback from MIT faculty from a range of disciplines, including David McGee, associate professor in the Department of Earth, Atmospheric and Planetary Sciences. With the help of CATE undergraduate researcher Heidi Li ’22, the team held a focus group with the Sustainable Energy Alliance, an undergraduate student club. In spring 2022, CATE convened a professional development workshop in collaboration with the Massachusetts Teachers Association Climate Action Network, Earth Day Boston, and MIT’s Office of Government and Community Relations, sponsored by the Beker Foundation, to evaluate 15 discrete CATE lessons. One of the workshop participants, Gary Smith, a teacher from St. John’s Preparatory School in Danvers, Massachusetts, signed on as a volunteer science curriculum developer.

    “We had a diverse pool of teachers who thought the lessons were fantastic, but among their suggestions noted that their student cohorts included new English speakers, who needed simpler language and more pictures,” says O’Grady. “This was extremely useful to us, and we revised the curriculum because we want to reach students at every level of learning.”

    Reaching all the schools

    Now, the CATE curriculum is in the hands of a cohort of Massachusetts teachers. Each of these educators will test one or more of the lessons and lab activities over the next year, checking in regularly with MIT partners to report on their classroom experiences. The CATE team is building a Climate Education Resource Network of MIT graduate students, postdocs, and research staff who can answer teachers’ specific climate questions and help them find additional resources or datasets. Additionally, teachers will have the opportunity to attend two in-person cohort meetings and be paired with graduate student “climate advisors.”

    In spring 2023, in honor of Earth Day, O’Grady and Knittel want to bring CATE first adopters — high school teachers, students, and their families — to campus. “We envision professors giving mini lectures, youth climate groups discussing how to get involved in local actions, and our team members handing out climate change packets to students to spark conversations with their families at home,” says O’Grady.

    By creating a positive experience around their curriculum in these pilot schools, the CATE team hopes to promote its dissemination to many more Massachusetts schools in 2023. The team plans on enhancing lessons, offering more paths to integration in high school studies, and creating a companion resource website for teachers. Knittel wants to establish footholds in school after school, in Massachusetts and beyond.

    “I plan to spend a lot of my time convincing districts and states to adopt,” he says. “If one teacher tells another that the curriculum is useful, with touchpoints in different disciplines, that’s how we get a foot in the door.”

    Knittel is not shying away from places where “climate change is a politicized topic.” He hopes to team up with universities in states where there might be resistance to including such lessons in schools to develop the curriculum. Although his day job involves computing household-level carbon footprints, determining the relationship between driving behavior and the price of gasoline, and promoting wise climate policy, Knittel plans to push CATE as far as he can. “I want this curriculum to be adopted by everybody — that’s my goal,” he says.

    “In one sense, I’m not the natural person for this job,” he admits. “But I share the mission and passion of MITEI and CEEPR for decarbonizing our economy in ways that are socially equitable and efficient, and part of doing that is educating Americans about the actual costs and consequences of climate change.”

    The CATE program is sponsored by MITEI, CEEPR, and the MIT Vice President for Research.

    This article appears in the Winter 2023 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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    Shrinky Dinks, nail polish, and smelly bacteria

    In a lab on the fourth floor of MIT’s Building 56, a group of Massachusetts high school students gathered around a device that measures conductivity.

    Vincent Nguyen, 15, from Saugus, thought of the times the material on their sample electrode flaked off the moment they took it out of the oven. Or how the electrode would fold weirdly onto itself. The big fails were kind of funny, but discouraging. The students had worked for a month, experimenting with different materials, and 17-year-old Brianna Tong of Malden wondered if they’d finally gotten it right: Would their electrode work well enough to power a microbial fuel cell?

    The students secured their electrode with alligator clips, someone hit start, and the teens watched anxiously as the device searched for even the faintest electrical current.

    Capturing electrons from bacteria

    Last July, Tong, Nguyen, and six other students from Malden Catholic High School commuted between the lab of MIT chemical engineer Ariel L. Furst and their school’s chemistry lab. Their goal was to fashion electrodes for low-cost microbial fuel cells — miniature bioreactors that generate small amounts of electricity by capturing electrons transferred from living microbes. These devices can double as electrochemical sensors.

    Furst, the Paul M. Cook Career Development Professor of Chemical Engineering, uses a mix of electrochemistry, microbial engineering, and materials science to address challenges in human health and clean energy. “The goal of all of our projects is to increase sustainability, clean energy, and health equity globally,” she says.

    Electrochemical sensors are powerful, sensitive detection and measurement tools. Typically, their electrodes need to be built in precisely engineered environments. “Thinking about ways of making devices without needing a cleanroom is important for coming up with inexpensive devices that can be deployed in low-resource settings under non-ideal conditions,” Furst says.

    For 17-year-old Angelina Ang of Everett, the project illuminated the significance of “coming together to problem-solve for a healthier and more sustainable earth,” she says. “It made me realize that we hold the answers to fix our dying planet.”

    With the help of a children’s toy called Shrinky Dinks, carbon-based materials, nail polish, and a certain smelly bacterium, the students got — literally — a trial-by-fire introduction to the scientific method. At one point, one of their experimental electrodes burst into flames. Other results were more promising.

    The students took advantage of the electrical properties of a bacterium — Shewanella oneidensis — that’s been called nature’s microscopic power plant. As part of their metabolism, Shewanella oneidensis generate electricity by oxidizing organic matter. In essence, they spit out electrons. Put enough together, and you get a few milliamps.

    To build bacteria-friendly electrodes, one of the first things the students did was culture Shewanella. They learned how to pour a growth medium into petri dishes where the reddish, normally lake-living bacteria could multiply. The microbes, Furst notes, are a little stinky, like cabbage. “But we think they’re really cool,” she says.

    With the right engineering, Shewanella can produce electric current when they detect toxins in water or soil. They could be used for bioremediation of wastewater. Low-cost versions could be useful for areas with limited or no access to reliable electricity and clean water.

    Next-generation chemists

    The Malden Catholic-MIT program resulted from a fluke encounter between Furst and a Malden Catholic parent.

    Mary-Margaret O’Donnell-Zablocki, then a medicinal chemist at a Kendall Square biotech startup, met Furst through a mutual friend. She asked Furst if she’d consider hosting high school chemistry students in her lab for the summer.

    Furst was intrigued. She traces her own passion for science to a program she’d happened upon between her junior and senior years in high school in St. Louis. The daughter of a software engineer and a businesswoman, Furst was casting around for potential career interests when she came across a summer program that enlisted scientists in academia and private research to introduce high school students and teachers to aspects of the scientific enterprise.

    “That’s when I realized that research is not like a lab class where there’s an expected outcome,” Furst recalls. “It’s so much cooler than that.”

    Using startup funding from an MIT Energy Initiative seed grant, Furst developed a curriculum with Malden Catholic chemistry teacher Seamus McGuire, and students were invited to apply. In addition to Tong, Ang, and Nguyen, participants included Chengxiang Lou, 18, from China; Christian Ogata, 14, of Wakefield; Kenneth Ramirez, 17, of Everett; Isaac Toscano, 17, of Medford; and MaryKatherine Zablocki, 15, of Revere and Wakefield. O’Donnell-Zablocki was surprised — and pleased — when her daughter applied to the program and was accepted.

    Furst notes that women are still underrepresented in chemical engineering. She was particularly excited to mentor young women through the program.

    A conductive ink

    The students were charged with identifying materials that had high conductivity, low resistance, were a bit soluble, and — with the help of a compatible “glue” — were able to stick to a substrate.

    Furst showed the Malden Catholic crew Shrinky Dinks — a common polymer popularized in the 1970s as a craft material that, when heated in a toaster oven, shrinks to a third of its size and becomes thicker and more rigid. Electrodes based on Shrinky Dinks would cost pennies, making it an ideal, inexpensive material for microbial fuel cells that could monitor, for instance, soil health in low- and middle-income countries.

    “Right now, monitoring soil health is problematic,” Furst says. “You have to collect a sample and bring it back to the lab to analyze in expensive equipment. But if we have these little devices that cost a couple of bucks each, we can monitor soil health remotely.”

    After a crash course in conductive carbon-based inks and solvent glues, the students went off to Malden Catholic to figure out what materials they wanted to try.

    Tong rattled them off: carbon nanotubes, carbon nanofibers, graphite powder, activated carbon. Potential solvents to help glue the carbon to the Shrinky Dinks included nail polish, corn syrup, and embossing ink, to name a few. They tested and retested. When they hit a dead end, they revised their hypotheses.

    They tried using a 3D printed stencil to daub the ink-glue mixture onto the Shrinky Dinks. They hand-painted them. They tried printing stickers. They worked with little squeegees. They tried scooping and dragging the material. Some of their electro-materials either flaked off or wouldn’t stick in the heating process.

    “Embossing ink never dried after baking the Shrinky Dink,” Ogata recalls. “In fact, it’s probably still liquid! And corn syrup had a tendency to boil. Seeing activated carbon ignite or corn syrup boiling in the convection oven was quite the spectacle.”

    “After the electrode was out of the oven and cooled down, we would check the conductivity,” says Tong, who plans to pursue a career in science. “If we saw there was a high conductivity, we got excited and thought those materials worked.”

    The moment of truth came in Furst’s MIT lab, where the students had access to more sophisticated testing equipment. Would their electrodes conduct electricity?

    Many of them didn’t. Tong says, “At first, we were sad, but then Dr. Furst told us that this is what science is, testing repeatedly and sometimes not getting the results we wanted.” Lou agrees. “If we just copy the data left by other scholars and don’t collect and figure it out by ourselves, then it is difficult to be a qualified researcher,” he says.

    Some of the students plan to continue the project one afternoon a week at MIT and as an independent study at Malden Catholic. The long-term goal is to create a field-based soil sensor that employs a bacterium like Shewanella.

    By chance, the students’ very first electrode — made of graphite powder ink and nail polish glue — generated the most current. One of the team’s biggest surprises was how much better black nail polish worked than clear nail polish. It turns out black nail polish contains iron-based pigment — a conductor. The unexpected win took some of the sting out of the failures.

    “They learned a very hard lesson: Your results might be awesome, and things are exciting, but then nothing else might work. And that’s totally fine,” Furst says.

    This article appears in the Winter 2023 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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    3 Questions: Antje Danielson on energy education and its role in climate action

    The MIT Energy Initiative (MITEI) leads energy education at MIT, developing and implementing a robust educational toolkit for MIT graduate and undergraduate students, online learners around the world, and high school students who want to contribute to the energy transition. As MITEI’s director of education, Antje Danielson manages a team devoted to training the next generation of energy innovators, entrepreneurs, and policymakers. Here, she discusses new initiatives in MITEI’s education program and how they are preparing students to take an active role in climate action.

    Q: What role are MITEI’s education efforts playing in climate action initiatives at MIT, and what more could we be doing?

    A: This is a big question. The carbon emissions from energy are such an important factor in climate mitigation; therefore, what we do in energy education is practically synonymous with climate education. This is well illustrated in a 2018 Nature Energy paper by Fuso Nerini, which outlines that affordable, clean energy is related to many of the United Nations Sustainable Development Goals (SDGs) — not just SDG 7, which specifically calls for “affordable, reliable, sustainable, and modern energy for all” by 2030. There are 17 SDGs containing 169 targets, of which 113 (65 percent) require actions to be taken concerning energy systems.

    Now, can we equate education with action? The answer is yes, but only if it is done correctly. From the behavioral change literature, we know that knowledge alone is not enough to change behavior. So, one important part of our education program is practice and experience through research, internships, stakeholder engagement, and other avenues. At a minimum, education must give the learner the knowledge, skills, and courage to be ready to jump into action, but ideally, practice is a part of the offering. We also want our learners to go out into the world and share what they know and do. If done right, education is an energy transition accelerator.

    At MITEI, our learners are not just MIT students. We are creating online offerings based on residential MIT courses to train global professionals, policymakers, and students in research methods and tools to support and accelerate the energy transition. These are free and open to learners worldwide. We have five courses available now, with more to come.

    Our latest program is a collaboration with MIT’s Center for Energy and Environmental Policy Research (CEEPR): Climate Action through Education, or CATE. This is a teach-the-teacher program for high school curriculum and is a part of the MIT Climate Action Plan. The aim is to develop interdisciplinary, solutions-focused climate change curricula for U.S. high school teachers with components in history/social science, English/language arts, math, science, and computer science.

    We are rapidly expanding our programming. In the online space, for our global learners, we are bundling courses for professional development certificates; for our undergraduates, we are redesigning the energy studies minor to reflect what we have learned over the past 12 years; and for our graduate students, we are adding a new program that allows them to garner industry experience related to the energy transition. Meanwhile, CATE is creating a support network for the teachers who adopt the curriculum. We are also working on creating an energy and climate alliance with other universities around the world.

    On the Institute level, I am a member of the Climate Education Working Group, a subgroup of the Climate Nucleus, where we discuss and will soon recommend further climate action the Institute can take. Stay tuned for that.

    Q: You mentioned that you are leading an effort to create a consortium of energy and climate education programs at universities around the world. How does this effort fit into MITEI’s educational mission?

    A: Yes, we are currently calling it the “Energy and Climate Education Alliance.” The background to this is that the problem we are facing — transitioning the entire global energy system from high carbon emissions to low, no, and negative carbon emissions — is global, huge, and urgent. Following the proverbial “many hands make light work,” we believe that the success of this very complex task is accomplished quicker with more participants. There is, of course, more to this as well. The complexity of the problem is such that (1) MIT doesn’t have all the expertise needed to accomplish the educational needs of the climate and energy crisis, (2) there is a definite local and regional component to capacity building, and (3) collaborations with universities around the world will make our mission-driven work more efficient. Finally, these collaborations will be advantageous for our students as they will be able to learn from real-world case studies that are not U.S.-based and maybe even visit other universities abroad, do internships, and engage in collaborative research projects. Also, students from those universities will be able to come here and experience MIT’s unique intellectual environment.

    Right now, we are very much in the beginning stages of creating the alliance. We have signed a collaboration agreement with the Technical University of Berlin, Germany, and are engaged in talks with other European and Southeast Asian universities. Some of the collaborations we are envisioning relate to course development, student exchange, collaborative research, and course promotion. We are very excited about this collaboration. It fits well into MIT’s ambition to take climate action outside of the university, while still staying within our educational mission.

    Q: It is clear to me from this conversation that MITEI’s education program is undertaking a number of initiatives to prepare MIT students and interested learners outside of the Institute to take an active role in climate action. But, the reality is that despite our rapidly changing climate and the immediate need to decarbonize our global economy, climate denialism and a lack of climate and energy understanding persist in the greater global population. What do you think must be done, and what can MITEI do, to increase climate and energy literacy broadly?

    A: I think the basic problem is not necessarily a lack of understanding but an abundance of competing issues that people are dealing with every day. Poverty, personal health, unemployment, inflation, pandemics, housing, wars — all are very immediate problems people have. And climate change is perceived to be in the future.

    The United States is a very bottom-up country, where corporations offer what people buy, and politicians advocate for what voters want and what money buys. Of course, this is overly simplified, but as long as we don’t come up with mechanisms to achieve a monumental shift in consumer and voter behavior, we are up against these immediate pressures. However, we are seeing some movement in this area due to rising gas and heating oil prices and the many natural disasters we are encountering now. People are starting to understand that climate change will hit their pocketbook, whether or not we have a carbon tax. The recent Florida hurricane damage, wildfires in the west, extreme summer temperatures, frequent droughts, increasing numbers of poisonous and disease-carrying insects — they all illustrate the relationship between climate change, health, and financial damage. Fewer and fewer people will be able to deny the existence of climate change because they will either be directly affected or know someone who is.

    The question is one of speed and scale. The more we can help to make the connections even more visible and understood, the faster we get to the general acceptance that this is real. Research projects like CEEPR’s Roosevelt Project, which develops action plans to help communities deal with industrial upheaval in the context of the energy transition, are contributing to this effect, as are studies related to climate change and national security. This is a fast-moving world, and our research findings need to be translated as we speak. A real problem in education is that we have the tendency to teach the tried and true. Our education programs have to become much nimbler, which means curricula have to be updated frequently, and that is expensive. And of course, the speed and magnitude of our efforts are dependent on the funding we can attract, and fundraising for education is more difficult than fundraising for research.

    However, let me pivot: You alluded to the fact that this is a global problem. The immediate pressures of poverty and hunger are a matter of survival in many parts of the world, and when it comes to surviving another day, who cares if climate change will render your fields unproductive in 20 years? Or if the weather turns your homeland into a lake, will you think about lobbying your government to reduce carbon emissions, or will you ask for help to rebuild your existence? On the flip side, politicians and government authorities in those areas have to deal with extremely complex situations, balancing local needs with global demands. We should learn from them. What we need is to listen. What do these areas of the world need most, and how can climate action be included in the calculations? The Global Commission to End Energy Poverty, a collaboration between MITEI and the Rockefeller Foundation to bring electricity to the billion people across the globe who currently live without it, is a good example of what we are already doing. Both our online education program and the Energy and Climate Education Alliance aim to go in this direction.

    The struggle and challenge to solve climate change can be pretty depressing, and there are many days when I feel despondent about the speed and progress we are making in saving the future of humanity. But, the prospect of contributing to such a large mission, even if the education team can only nudge us a tiny bit away from the business-as-usual scenario, is exciting. In particular, working on an issue like this at MIT is amazing. So much is happening here, and there don’t seem to be intellectual limits; in fact, thinking big is encouraged. It is very refreshing when one has encountered the old “you can’t do this” too often in the past. I want our students to take this attitude with them and go out there and think big. More

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    Taking the long view: The Deep Time Project

    How would we design and build differently if we learned to live at multiple time scales? How would human communities respond to global challenges if the short-term mindset of contemporary life was expanded to encompass new dimensions of past and future — diving into the depths of geological history and projecting forward to imagine the consequences of our actions today?

    These are questions that Cristina Parreño Alonso addresses in her practice as an architect, artist, and senior lecturer in the MIT Department of Architecture. Her field of research, which she has termed “Transtectonics,” explores the cultural and environmental implications of expanded temporal sensibilities in architectural material practice. A building, Parreño argues, is a “material event,” part of a process of construction and deconstruction that is shaped by the past and directly impacts the future — an impact that has become all the more apparent in the epoch of the Anthropocene, in which humans have become the dominant force influencing the physical composition and regulating systems of the planet.

    Parreño’s classes at MIT have included design studios that position architecture in relation to geological processes, and historical surveys of building practices that embrace traces of time and rhythms of maintenance. She recently devised a new class, 4.181 (The Deep Time Project), which launched in fall 2022 with the support of a 2022 Cross Disciplinary Class Grant from the MIT Center for Art, Science and Technology (CAST), in addition to the d’Arbeloff Fund for Excellence in Education.

    Learning deep time literacy

    “The course proposes that architects must develop deep-time literacy if we are to become true planetary stewards,” says Parreño. “Rather than attempting to identify solutions, the course is intended to provoke new ways of thinking that lead to greater accountability — a recognition that we, as architects, are intervening in something larger than ourselves, and that the consequences of our actions extend far beyond the timescales of our human lives and civilizations.” The class, which was offered to master’s students in the School of Architecture and Planning and the Harvard Graduate School of Design, culminated in a series of “material essays” that seek to bring deep time into contemporary consciousness. These multimedia projects — which include physical prototypes, text components, sound, and video  — are on display until March 24 at the Wiesner Student Art Gallery.

    “Being part of the exhibition has made me realize the advantages of belonging to a collective that recognizes the urgency of addressing the idea of time at different scales,” says architecture master’s student Christina Battikha, whose material essay “Plastic Time” imagines a future when plastic is integral to the geological structure of the Earth. Envisioned as a jagged plastic “rock,” the sculpture interprets the ubiquitous synthetic material as a natural phenomenon, a human-made product that far outlasts a human lifespan.

    Taking the form of a clay “Rosetta Stone” inscribed with multiple languages, architecture student Tatiana Victorovna Estrina’s material essay explores how the evolution of language impacts the built environment. “My project identifies a gap of imagination in deep time research,” she explains. “The installation became a futuristic exploration of opportunities for the adaptive relationship between the human body and its prosthetic additions of language and architecture.”

    Provocative perspectives

    “Developing the class here at MIT grants us the capacity to hold conversations across disciplines,” says Parreño. “That’s all the more necessary, because deep time literacy requires a very holistic way of thinking; it raises awareness of the fact that we are inherently interconnected, and makes it clear that we can’t afford to operate in compartments.”

    This attention to interdisciplinarity is exemplified by the guest speakers invited to share their ideas with the class, each providing a new way of accessing the deep time paradigm. Among the speakers were Marcia Bjornerud, a structural geologist and educator who argues that a geologist’s temporal perspective can empower us to make decisions for a more sustainable future. Richard Fisher, a senior journalist at the BBC, and Bina Venkataraman, journalist and author of “The Optimist’s Telescope: Thinking Ahead in a Reckless Age,” both shared their experiences of engaging the public in the perils of short-term-ism and the positive effects of taking the long view in daily life. The historian of science Jimena Canales provided a philosophical background to the conundrums of time perception, citing the renowned debate between Albert Einstein and the philosopher Henri Bergson.

    Alongside these large-scale thinkers and academic researchers were practitioners who directly apply planetary perspectives at a local level. Joseph Bagley is Boston’s city architect, investigating the layers of time that constitute the urban fabric. Faries Gray, the sagamore of the Massachusett Tribe at Ponkapoag, advocates for Indigenous ways of knowing that recognize the continuity between human cultures and the living history of the land. Together, these different ways of relating to deep time offer a toolkit for contemplating a concept too large to be held in the human mind.

    Thinking through art

    Parreño’s own way of conceptualizing deep time is informed by her artistic and philosophical inquiry into the paradoxes of time, tectonics, and materiality. Exhibited at the Schusev State Museum of Architecture in Moscow, her installation Tectonics of Wisdom focused on the typology of the library as a way of demonstrating how architecture is intertwined with geological and civilizational history. Carbon to Rock, shown at the 2021 Venice Architecture Biennale, explores new artificial manipulations of the geological timescales of the carbon cycle, rethinking igneous rocks as a resilient material for high-carbon-capture architecture. In addition, Parreño has published several essays on the subject of deep time for journals including Strelka Magazine, Log, and JAE Journal of Architectural Education. Her work as a writer and theorist is complemented by her art installations — or material essays — that serve as a research methodology and a means of communication.

    Likewise, the exhibition component of the Deep Time Project is a way of giving thoughts physical form. Estrina’s installation was initially prompted by the need to communicate the presence of buried nuclear waste to future generations — or even future species. Battikha’s sculpture is a response to the vast buildup of plastic generated by cycles of supply and demand. However, rather than making value judgements or condemning human actions, these works are intended to disrupt conventional patterns of perception, experimenting with longer-term perspectives that have the potential to change ingrained assumptions and daily habits. “There needs to be a paradigm shift before we can effectively address the enormity of the challenges ahead,” says Parreño. “The Deep Time Project is about taking a step back, reframing these problems in ways that will allow us to ask the right questions.” More

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    Preparing students for the new nuclear

    As nuclear power has gained greater recognition as a zero-emission energy source, the MIT Leaders for Global Operations (LGO) program has taken notice.

    Two years ago, LGO began a collaboration with MIT’s Department of Nuclear Science and Engineering (NSE) as a way to showcase the vital contribution of both business savvy and scientific rigor that LGO’s dual-degree graduates can offer this growing field.

    “We saw that the future of fission and fusion required business acumen and management acumen,” says Professor Anne White, NSE department head. “People who are going to be leaders in our discipline, and leaders in the nuclear enterprise, are going to need all of the technical pieces of the puzzle that our engineering department can provide in terms of education and training. But they’re also going to need a much broader perspective on how the technology connects with society through the lens of business.”

    The resulting response has been positive: “Companies are seeing the value of nuclear technology for their operations,” White says, and this often happens in unexpected ways.

    For example, graduate student Santiago Andrade recently completed a research project at Caterpillar Inc., a preeminent manufacturer of mining and construction equipment. Caterpillar is one of more than 20 major companies that partner with the LGO program, offering six-month internships to each student. On the surface, it seemed like an improbable pairing; what could Andrade, who was pursuing his master’s in nuclear science and engineering, do for a manufacturing company? However, Caterpillar wanted to understand the technical and commercial feasibility of using nuclear energy to power mining sites and data centers when wind and solar weren’t viable.

    “They are leaving no stone unturned in the search of financially smart solutions that can support the transition to a clean energy dependency,” Andrade says. “My project, along with many others’, is part of this effort.”

    “The research done through the LGO program with Santiago is enabling Caterpillar to understand how alternative technologies, like the nuclear microreactor, could participate in these markets in the future,” says Brian George, product manager for large electric power solutions at Caterpillar. “Our ability to connect our customers with the research will provide for a more accurate understanding of the potential opportunity, and helps provide exposure for our customers to emerging technologies.”

    With looming threats of climate change, White says, “We’re going to require more opportunities for nuclear technologies to step in and be part of those solutions. A cohort of LGO graduates will come through this program with technical expertise — a master’s degree in nuclear engineering — and an MBA. There’s going to be a tremendous talent pool out there to help companies and governments.”

    Andrade, who completed an undergraduate degree in chemical engineering and had a strong background in thermodynamics, applied to LGO unsure of which track to choose, but he knew he wanted to confront the world’s energy challenge. When MIT Admissions suggested that he join LGO’s new nuclear track, he was intrigued by how it could further his career.

    “Since the NSE department offers opportunities ranging from energy to health care and from quantum engineering to regulatory policy, the possibilities of career tracks after graduation are countless,” he says.

    He was also inspired by the fact that, as he says, “Nuclear is one of the less-popular solutions in terms of our energy transition journey. One of the things that attracted me is that it’s not one of the most popular, but it’s one of the most useful.”

    In addition to his work at Caterpillar, Andrade connected deeply with professors. He worked closely with professors Jacopo Buongiorno and John Parsons as a research assistant, helping them develop a business model to successfully support the deployment of nuclear microreactors. After graduation, he plans to work in the clean energy sector with an eye to innovations in the nuclear energy technology space.

    His LGO classmate, Lindsey Kennington, a control systems engineer, echoes his sentiments: This is a revolutionary time for nuclear technology.

    “Before MIT, I worked on a lot of nuclear waste or nuclear weapons-related projects. All of them were fission-related. I got disillusioned because of all the bureaucracy and the regulation,” Kennington says. “However, now there are a lot of new nuclear technologies coming straight out of MIT. Commonwealth Fusion Systems, a fusion startup, represents a prime example of MIT’s close relationship to new nuclear tech. Small modular reactors are another emerging technology being developed by MIT. Exposure to these cutting-edge technologies was the main sell factor for me.”

    Kennington conducted an internship with National Grid, where she used her expertise to evaluate how existing nuclear power plants could generate hydrogen. At MIT, she studied nuclear and energy policy, which offered her additional perspective that traditional engineering classes might not have provided. Because nuclear power has long been a hot-button issue, Kennington was able to gain nuanced insight about the pathways and roadblocks to its implementation.

    “I don’t think that other engineering departments emphasize that focus on policy quite as much. [Those classes] have been one of the most enriching parts of being in the nuclear department,” she says.

    Most of all, she says, it’s a pivotal time to be part of a new, blossoming program at the forefront of clean energy, especially as fusion research grows more prevalent.

    “We’re at an inflection point,” she says. “Whether or not we figure out fusion in the next five, 10, or 20 years, people are going to be working on it — and it’s a really exciting time to not only work on the science but to actually help the funding and business side grow.”

    White puts it simply.

    “This is not your parents’ nuclear,” she says. “It’s something totally different. Our discipline is evolving so rapidly that people who have technical expertise in nuclear will have a huge advantage in this next generation.” More