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      MIT engineers design tiny batteries for powering cell-sized robots

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      A tiny battery designed by MIT engineers could enable the deployment of cell-sized, autonomous robots for drug delivery within in the human body, as well as other applications such as locating leaks in gas pipelines.The new battery, which is 0.1 millimeters long and 0.002 millimeters thick — roughly the thickness of a human hair — can capture oxygen from air and use it to oxidize zinc, creating a current of up to 1 volt. That is enough to power a small circuit, sensor, or actuator, the researchers showed.“We think this is going to be very enabling for robotics,” says Michael Strano, the Carbon P. Dubbs Professor of Chemical Engineering at MIT and the senior author of the study. “We’re building robotic functions onto the battery and starting to put these components together into devices.”Ge Zhang PhD ’22 and Sungyun Yang, an MIT graduate student, are the lead author of the paper, which appears in Science Robotics.Powered by batteriesFor several years, Strano’s lab has been working on tiny robots that can sense and respond to stimuli in their environment. One of the major challenges in developing such tiny robots is making sure that they have enough power.Other researchers have shown that they can power microscale devices using solar power, but the limitation to that approach is that the robots must have a laser or another light source pointed at them at all times. Such devices are known as “marionettes” because they are controlled by an external power source. Putting a power source such as a battery inside these tiny devices could free them to roam much farther.“The marionette systems don’t really need a battery because they’re getting all the energy they need from outside,” Strano says. “But if you want a small robot to be able to get into spaces that you couldn’t access otherwise, it needs to have a greater level of autonomy. A battery is essential for something that’s not going to be tethered to the outside world.”To create robots that could become more autonomous, Strano’s lab decided to use a type of battery known as a zinc-air battery. These batteries, which have a longer lifespan than many other types of batteries due to their high energy density, are often used in hearing aids.The battery that they designed consists of a zinc electrode connected to a platinum electrode, embedded into a strip of a polymer called SU-8, which is commonly used for microelectronics. When these electrodes interact with oxygen molecules from the air, the zinc becomes oxidized and releases electrons that flow to the platinum electrode, creating a current.In this study, the researchers showed that this battery could provide enough energy to power an actuator — in this case, a robotic arm that can be raised and lowered. The battery could also power a memristor, an electrical component that can store memories of events by changing its electrical resistance, and a clock circuit, which allows robotic devices to keep track of time.The battery also provides enough power to run two different types of sensors that change their electrical resistance when they encounter chemicals in the environment. One of the sensors is made from atomically thin molybdenum disulfide and the other from carbon nanotubes.“We’re making the basic building blocks in order to build up functions at the cellular level,” Strano says.Robotic swarmsIn this study, the researchers used a wire to connect their battery to an external device, but in future work they plan to build robots in which the battery is incorporated into a device.“This is going to form the core of a lot of our robotic efforts,” Strano says. “You can build a robot around an energy source, sort of like you can build an electric car around the battery.”One of those efforts revolves around designing tiny robots that could be injected into the human body, where they could seek out a target site and then release a drug such as insulin. For use in the human body, the researchers envision that the devices would be made of biocompatible materials that would break apart once they were no longer needed.The researchers are also working on increasing the voltage of the battery, which may enable additional applications.The research was funded by the U.S. Army Research Office, the U.S. Department of Energy, the National Science Foundation, and a MathWorks Engineering Fellowship. More

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      H2 underground

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      In 1987 in a village in Mali, workers were digging a water well when they felt a rush of air. One of the workers was smoking a cigarette, and the air caught fire, burning a clear blue flame. The well was capped at the time, but in 2012, it was tapped to provide energy for the village, powering a generator for nine years.The fuel source: geologic hydrogen.For decades, hydrogen has been discussed as a potentially revolutionary fuel. But efforts to produce “green” hydrogen (splitting water into hydrogen and oxygen using renewable electricity), “grey” hydrogen (making hydrogen from methane and releasing the biproduct carbon dioxide (CO2) into the atmosphere), “brown” hydrogen (produced through the gasification of coal), and “blue” hydrogen (making hydrogen from methane but capturing the CO2) have thus far proven either expensive and/or energy-intensive. Enter geologic hydrogen. Also known as “orange,” “gold,” “white,” “natural,” and even “clear” hydrogen, geologic hydrogen is generated by natural geochemical processes in the Earth’s crust. While there is still much to learn, a growing number of researchers and industry leaders are hopeful that it may turn out to be an abundant and affordable resource lying right beneath our feet.“There’s a tremendous amount of uncertainty about this,” noted Robert Stoner, the founding director of the MIT Tata Center for Technology and Design, in his opening remarks at the MIT Energy Initiative (MITEI) Spring Symposium. “But the prospect of readily producible clean hydrogen showing up all over the world is a potential near-term game changer.”A new hope for hydrogenThis April, MITEI gathered researchers, industry leaders, and academic experts from around MIT and the world to discuss the challenges and opportunities posed by geologic hydrogen in a daylong symposium entitled “Geologic hydrogen: Are orange and gold the new green?” The field is so new that, until a year ago, the U.S. Department of Energy (DOE)’s website incorrectly claimed that hydrogen only occurs naturally on Earth in compound forms, chemically bonded to other elements.“There’s a common misconception that hydrogen doesn’t occur naturally on Earth,” said Geoffrey Ellis, a research geologist with the U.S. Geological Survey. He noted that natural hydrogen production tends to occur in different locations from where oil and natural gas are likely to be discovered, which explains why geologic hydrogen discoveries have been relatively rare, at least until recently.“Petroleum exploration is not targeting hydrogen,” Ellis said. “Companies are simply not really looking for it, they’re not interested in it, and oftentimes they don’t measure for it. The energy industry spends billions of dollars every year on exploration with very sophisticated technology, and still they drill dry holes all the time. So I think it’s naive to think that we would suddenly be finding hydrogen all the time when we’re not looking for it.”In fact, the number of researchers and startup energy companies with targeted efforts to characterize geologic hydrogen has increased over the past several years — and these searches have uncovered new prospects, said Mary Haas, a venture partner at Breakthrough Energy Ventures. “We’ve seen a dramatic uptick in exploratory activity, now that there is a focused effort by a small community worldwide. At Breakthrough Energy, we are excited about the potential of this space, as well as our role in accelerating its progress,” she said. Haas noted that if geologic hydrogen could be produced at $1 per kilogram, this would be consistent with the DOE’s targeted “liftoff” point for the energy source. “If that happens,” she said, “it would be transformative.”Haas noted that only a small portion of identified hydrogen sites are currently under commercial exploration, and she cautioned that it’s not yet clear how large a role the resource might play in the transition to green energy. But, she said, “It’s worthwhile and important to find out.”Inventing a new energy subsectorGeologic hydrogen is produced when water reacts with iron-rich minerals in rock. Researchers and industry are exploring how to stimulate this natural production by pumping water into promising deposits.In any new exploration area, teams must ask a series of questions to qualify the site, said Avon McIntyre, the executive director of HyTerra Ltd., an Australian company focused on the exploration and production of geologic hydrogen. These questions include: Is the geology favorable? Does local legislation allow for exploration and production? Does the site offer a clear path to value? And what are the carbon implications of producing hydrogen at the site?“We have to be humble,” McIntyre said. “We can’t be too prescriptive and think that we’ll leap straight into success. We have a unique opportunity to stop and think about what this industry will look like, how it will work, and how we can bring together various disciplines.” This was a theme that arose multiple times over the course of the symposium: the idea that many different stakeholders — including those from academia, industry, and government — will need to work together to explore the viability of geologic hydrogen and bring it to market at scale.In addition to the potential for hydrogen production to give rise to greenhouse gas emissions (in cases, for instance, where hydrogen deposits are contaminated with natural gas), researchers and industry must also consider landscape deformation and even potential seismic implications, said Bradford Hager, the Cecil and Ida Green Professor of Earth Sciences in the MIT Department of Earth, Atmospheric and Planetary Sciences.The surface impacts of hydrogen exploration and production will likely be similar to those caused by the hydro-fracturing process (“fracking”) used in oil and natural gas extraction, Hager said.“There will be unavoidable surface deformation. In most places, you don’t want this if there’s infrastructure around,” Hager said. “Seismicity in the stimulated zone itself should not be a problem, because the areas are tested first. But we need to avoid stressing surrounding brittle rocks.”McIntyre noted that the commercial case for hydrogen remains a challenge to quantify, without even a “spot” price that companies can use to make economic calculations. Early on, he said, capturing helium at hydrogen exploration sites could be a path to early cash flow, but that may ultimately serve as a “distraction” as teams attempt to scale up to the primary goal of hydrogen production. He also noted that it is not even yet clear whether hard rock, soft rock, or underwater environments hold the most potential for geologic hydrogen, but all show promise.“If you stack all of these things together,” McIntyre said, “what we end up doing may look very different from what we think we’re going to do right now.”The path aheadWhile the long-term prospects for geologic hydrogen are shrouded in uncertainty, most speakers at the symposium struck a tone of optimism. Ellis noted that the DOE has dedicated $20 million in funding to a stimulated hydrogen program. Paris Smalls, the co-founder and CEO of Eden GeoPower Inc., said “we think there is a path” to producing geologic hydrogen below the $1 per kilogram threshold. And Iwnetim Abate, an assistant professor in the MIT Department of Materials Science and Engineering, said that geologic hydrogen opens up the idea of Earth as a “factory to produce clean fuels,” utilizing the subsurface heat and pressure instead of relying on burning fossil fuels or natural gas for the same purpose.“Earth has had 4.6 billion years to do these experiments,” said Oliver Jagoutz, a professor of geology in the MIT Department of Earth, Atmospheric and Planetary Sciences. “So there is probably a very good solution out there.”Alexis Templeton, a professor of geological sciences at the University of Colorado at Boulder, made the case for moving quickly. “Let’s go to pilot, faster than you might think,” she said. “Why? Because we do have some systems that we understand. We could test the engineering approaches and make sure that we are doing the right tool development, the right technology development, the right experiments in the lab. To do that, we desperately need data from the field.”“This is growing so fast,” Templeton added. “The momentum and the development of geologic hydrogen is really quite substantial. We need to start getting data at scale. And then, I think, more people will jump off the sidelines very quickly.”  More

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      Seizing solar’s bright future

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      Consider the dizzying ascent of solar energy in the United States: In the past decade, solar capacity increased nearly 900 percent, with electricity production eight times greater in 2023 than in 2014. The jump from 2022 to 2023 alone was 51 percent, with a record 32 gigawatts (GW) of solar installations coming online. In the past four years, more solar has been added to the grid than any other form of generation. Installed solar now tops 179 GW, enough to power nearly 33 million homes. The U.S. Department of Energy (DOE) is so bullish on the sun that its decarbonization plans envision solar satisfying 45 percent of the nation’s electricity demands by 2050.But the continued rapid expansion of solar requires advances in technology, notably to improve the efficiency and durability of solar photovoltaic (PV) materials and manufacturing. That’s where Optigon, a three-year-old MIT spinout company, comes in.“Our goal is to build tools for research and industry that can accelerate the energy transition,” says Dane deQuilettes, the company’s co-founder and chief science officer. “The technology we have developed for solar will enable measurements and analysis of materials as they are being made both in lab and on the manufacturing line, dramatically speeding up the optimization of PV.”With roots in MIT’s vibrant solar research community, Optigon is poised for a 2024 rollout of technology it believes will drastically pick up the pace of solar power and other clean energy projects.Beyond siliconSilicon, the material mainstay of most PV, is limited by the laws of physics in the efficiencies it can achieve converting photons from the sun into electrical energy. Silicon-based solar cells can theoretically reach power conversion levels of just 30 percent, and real-world efficiency levels hover in the low 20s. But beyond the physical limitations of silicon, there is another issue at play for many researchers and the solar industry in the United States and elsewhere: China dominates the silicon PV market, from supply chains to manufacturing.Scientists are eagerly pursuing alternative materials, either for enhancing silicon’s solar conversion capacity or for replacing silicon altogether.In the past decade, a family of crystal-structured semiconductors known as perovskites has risen to the fore as a next-generation PV material candidate. Perovskite devices lend themselves to a novel manufacturing process using printing technology that could circumvent the supply chain juggernaut China has built for silicon. Perovskite solar cells can be stacked on each other or layered atop silicon PV, to achieve higher conversion efficiencies. Because perovskite technology is flexible and lightweight, modules can be used on roofs and other structures that cannot support heavier silicon PV, lowering costs and enabling a wider range of building-integrated solar devices.But these new materials require testing, both during R&D and then on assembly lines, where missing or defective optical, electrical, or dimensional properties in the nano-sized crystal structures can negatively impact the end product.“The actual measurement and data analysis processes have been really, really slow, because you have to use a bunch of separate tools that are all very manual,” says Optigon co-founder and chief executive officer Anthony Troupe ’21. “We wanted to come up with tools for automating detection of a material’s properties, for determining whether it could make a good or bad solar cell, and then for optimizing it.”“Our approach packed several non-contact, optical measurements using different types of light sources and detectors into a single system, which together provide a holistic, cross-sectional view of the material,” says Brandon Motes ’21, ME ’22, co-founder and chief technical officer.“This breakthrough in achieving millisecond timescales for data collection and analysis means we can take research-quality tools and actually put them on a full production system, getting extremely detailed information about products being built at massive, gigawatt scale in real-time,” says Troupe.This streamlined system takes measurements “in the snap of the fingers, unlike the traditional tools,” says Joseph Berry, director of the US Manufacturing of Advanced Perovskites Consortium and a senior research scientist at the National Renewable Energy Laboratory. “Optigon’s techniques are high precision and allow high throughput, which means they can be used in a lot of contexts where you want rapid feedback and the ability to develop materials very, very quickly.”According to Berry, Optigon’s technology may give the solar industry not just better materials, but the ability to pump out high-quality PV products at a brisker clip than is currently possible. “If Optigon is successful in deploying their technology, then we can more rapidly develop the materials that we need, manufacturing with the requisite precision again and again,” he says. “This could lead to the next generation of PV modules at a much, much lower cost.”Measuring makes the differenceWith Small Business Innovation Research funding from DOE to commercialize its products and a grant from the Massachusetts Clean Energy Center, Optigon has settled into a space at the climate technology incubator Greentown Labs in Somerville, Massachusetts. Here, the team is preparing for this spring’s launch of its first commercial product, whose genesis lies in MIT’s GridEdge Solar Research Program.Led by Vladimir Bulović, a professor of electrical engineering and the director of MIT.nano, the GridEdge program was established with funding from the Tata Trusts to develop lightweight, flexible, and inexpensive solar cells for distribution to rural communities around the globe. When deQuilettes joined the group in 2017 as a postdoc, he was tasked with directing the program and building the infrastructure to study and make perovskite solar modules.“We were trying to understand once we made the material whether or not it was good,” he recalls. “There were no good commercial metrology [the science of measurements] tools for materials beyond silicon, so we started to build our own.” Recognizing the group’s need for greater expertise on the problem, especially in the areas of electrical, software, and mechanical engineering, deQuilettes put a call out for undergraduate researchers to help build metrology tools for new solar materials.“Forty people inquired, but when I met Brandon and Anthony, something clicked; it was clear we had a complementary skill set,” says deQuilettes. “We started working together, with Anthony coming up with beautiful designs to integrate multiple measurements, and Brandon creating boards to control all of the hardware, including different types of lasers. We started filing multiple patents and that was when we saw it all coming together.”“We knew from the start that metrology could vastly improve not just materials, but production yields,” says Troupe. Adds deQuilettes, “Our goal was getting to the highest performance orders of magnitude faster than it would ordinarily take, so we developed tools that would not just be useful for research labs but for manufacturing lines to give live feedback on quality.”The device Optigon designed for industry is the size of a football, “with sensor packages crammed into a tiny form factor, taking measurements as material flows directly underneath,” says Motes. “We have also thought carefully about ways to make interaction with this tool as seamless and, dare I say, as enjoyable as possible, streaming data to both a dashboard an operator can watch and to a custom database.”Photovoltaics is just the startThe company may have already found its market niche. “A research group paid us to use our in-house prototype because they have such a burning need to get these sorts of measurements,” says Troupe, and according to Motes, “Potential customers ask us if they can buy the system now.” deQuilettes says, “Our hope is that we become the de facto company for doing any sort of characterization metrology in the United States and beyond.”Challenges lie ahead for Optigon: product launches, full-scale manufacturing, technical assistance, and sales. Greentown Labs offers support, as does MIT’s own rich community of solar researchers and entrepreneurs. But the founders are already thinking about next phases.“We are not limiting ourselves to the photovoltaics area,” says deQuilettes. “We’re planning on working in other clean energy materials such as batteries and fuel cells.”That’s because the team wants to make the maximum impact on the climate challenge. “We’ve thought a lot about the potential our tools will have on reducing carbon emissions, and we’ve done a really in-depth analysis looking at how our system can increase production yields of solar panels and other energy technologies, reducing materials and energy wasted in conventional optimization,” deQuilettes says. “If we look across all these sectors, we can expect to offset about 1,000 million metric tons of CO2 [carbon dioxide] per year in the not-too-distant future.”The team has written scale into its business plan. “We want to be the key enabler for bringing these new energy technologies to market,” says Motes. “We envision being deployed on every manufacturing line making these types of materials. It’s our goal to walk around and know that if we see a solar panel deployed, there’s a pretty high likelihood that it will be one we measured at some point.” More

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      Extracting hydrogen from rocks

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      It’s commonly thought that the most abundant element in the universe, hydrogen, exists mainly alongside other elements — with oxygen in water, for example, and with carbon in methane. But naturally occurring underground pockets of pure hydrogen are punching holes in that notion — and generating attention as a potentially unlimited source of carbon-free power. One interested party is the U.S. Department of Energy, which last month awarded $20 million in research grants to 18 teams from laboratories, universities, and private companies to develop technologies that can lead to cheap, clean fuel from the subsurface. Geologic hydrogen, as it’s known, is produced when water reacts with iron-rich rocks, causing the iron to oxidize. One of the grant recipients, MIT Assistant Professor Iwnetim Abate’s research group, will use its $1.3 million grant to determine the ideal conditions for producing hydrogen underground — considering factors such as catalysts to initiate the chemical reaction, temperature, pressure, and pH levels. The goal is to improve efficiency for large-scale production, meeting global energy needs at a competitive cost. The U.S. Geological Survey estimates there are potentially billions of tons of geologic hydrogen buried in the Earth’s crust. Accumulations have been discovered worldwide, and a slew of startups are searching for extractable deposits. Abate is looking to jump-start the natural hydrogen production process, implementing “proactive” approaches that involve stimulating production and harvesting the gas.                                                                                                                         “We aim to optimize the reaction parameters to make the reaction faster and produce hydrogen in an economically feasible manner,” says Abate, the Chipman Development Professor in the Department of Materials Science and Engineering (DMSE). Abate’s research centers on designing materials and technologies for the renewable energy transition, including next-generation batteries and novel chemical methods for energy storage. 

      Sparking innovation

      Interest in geologic hydrogen is growing at a time when governments worldwide are seeking carbon-free energy alternatives to oil and gas. In December, French President Emmanuel Macron said his government would provide funding to explore natural hydrogen. And in February, government and private sector witnesses briefed U.S. lawmakers on opportunities to extract hydrogen from the ground. Today commercial hydrogen is manufactured at $2 a kilogram, mostly for fertilizer and chemical and steel production, but most methods involve burning fossil fuels, which release Earth-heating carbon. “Green hydrogen,” produced with renewable energy, is promising, but at $7 per kilogram, it’s expensive. “If you get hydrogen at a dollar a kilo, it’s competitive with natural gas on an energy-price basis,” says Douglas Wicks, a program director at Advanced Research Projects Agency – Energy (ARPA-E), the Department of Energy organization leading the geologic hydrogen grant program. Recipients of the ARPA-E grants include Colorado School of Mines, Texas Tech University, and Los Alamos National Laboratory, plus private companies including Koloma, a hydrogen production startup that has received funding from Amazon and Bill Gates. The projects themselves are diverse, ranging from applying industrial oil and gas methods for hydrogen production and extraction to developing models to understand hydrogen formation in rocks. The purpose: to address questions in what Wicks calls a “total white space.” “In geologic hydrogen, we don’t know how we can accelerate the production of it, because it’s a chemical reaction, nor do we really understand how to engineer the subsurface so that we can safely extract it,” Wicks says. “We’re trying to bring in the best skills of each of the different groups to work on this under the idea that the ensemble should be able to give us good answers in a fairly rapid timeframe.” Geochemist Viacheslav Zgonnik, one of the foremost experts in the natural hydrogen field, agrees that the list of unknowns is long, as is the road to the first commercial projects. But he says efforts to stimulate hydrogen production — to harness the natural reaction between water and rock — present “tremendous potential.” “The idea is to find ways we can accelerate that reaction and control it so we can produce hydrogen on demand in specific places,” says Zgonnik, CEO and founder of Natural Hydrogen Energy, a Denver-based startup that has mineral leases for exploratory drilling in the United States. “If we can achieve that goal, it means that we can potentially replace fossil fuels with stimulated hydrogen.”

      “A full-circle moment”

      For Abate, the connection to the project is personal. As a child in his hometown in Ethiopia, power outages were a usual occurrence — the lights would be out three, maybe four days a week. Flickering candles or pollutant-emitting kerosene lamps were often the only source of light for doing homework at night. “And for the household, we had to use wood and charcoal for chores such as cooking,” says Abate. “That was my story all the way until the end of high school and before I came to the U.S. for college.” In 1987, well-diggers drilling for water in Mali in Western Africa uncovered a natural hydrogen deposit, causing an explosion. Decades later, Malian entrepreneur Aliou Diallo and his Canadian oil and gas company tapped the well and used an engine to burn hydrogen and power electricity in the nearby village. Ditching oil and gas, Diallo launched Hydroma, the world’s first hydrogen exploration enterprise. The company is drilling wells near the original site that have yielded high concentrations of the gas. “So, what used to be known as an energy-poor continent now is generating hope for the future of the world,” Abate says. “Learning about that was a full-circle moment for me. Of course, the problem is global; the solution is global. But then the connection with my personal journey, plus the solution coming from my home continent, makes me personally connected to the problem and to the solution.”

      Experiments that scale

      Abate and researchers in his lab are formulating a recipe for a fluid that will induce the chemical reaction that triggers hydrogen production in rocks. The main ingredient is water, and the team is testing “simple” materials for catalysts that will speed up the reaction and in turn increase the amount of hydrogen produced, says postdoc Yifan Gao. “Some catalysts are very costly and hard to produce, requiring complex production or preparation,” Gao says. “A catalyst that’s inexpensive and abundant will allow us to enhance the production rate — that way, we produce it at an economically feasible rate, but also with an economically feasible yield.” The iron-rich rocks in which the chemical reaction happens can be found across the United States and the world. To optimize the reaction across a diversity of geological compositions and environments, Abate and Gao are developing what they call a high-throughput system, consisting of artificial intelligence software and robotics, to test different catalyst mixtures and simulate what would happen when applied to rocks from various regions, with different external conditions like temperature and pressure. “And from that we measure how much hydrogen we are producing for each possible combination,” Abate says. “Then the AI will learn from the experiments and suggest to us, ‘Based on what I’ve learned and based on the literature, I suggest you test this composition of catalyst material for this rock.’” The team is writing a paper on its project and aims to publish its findings in the coming months. The next milestones for the project, after developing the catalyst recipe, is designing a reactor that will serve two purposes. First, fitted with technologies such as Raman spectroscopy, it will allow researchers to identify and optimize the chemical conditions that lead to improved rates and yield of hydrogen production. The lab-scale device will also inform the design of a real-world reactor that can accelerate hydrogen production in the field. “That would be a plant-scale reactor that would be implanted into the subsurface,” Abate says. The cross-disciplinary project is also tapping the expertise of Yang Shao-Horn, of MIT’s Department of Mechanical Engineering and DMSE, for computational analysis of the catalyst, and Esteban Gazel, a Cornell University scientist who will lend his expertise in geology and geochemistry. He’ll focus on understanding the iron-rich ultramafic rock formations across the United States and the globe and how they react with water. For Wicks at ARPA-E, the questions Abate and the other grant recipients are asking are just the first, critical steps in uncharted energy territory. “If we can understand how to stimulate these rocks into generating hydrogen, safely getting it up, it really unleashes the potential energy source,” he says. Then the emerging industry will look to oil and gas for the drilling, piping, and gas extraction know-how. “As I like to say, this is enabling technology that we hope to, in a very short term, enable us to say, ‘Is there really something there?’” More

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      With just a little electricity, MIT researchers boost common catalytic reactions

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      A simple technique that uses small amounts of energy could boost the efficiency of some key chemical processing reactions, by up to a factor of 100,000, MIT researchers report. These reactions are at the heart of petrochemical processing, pharmaceutical manufacturing, and many other industrial chemical processes.

      The surprising findings are reported today in the journal Science, in a paper by MIT graduate student Karl Westendorff, professors Yogesh Surendranath and Yuriy Roman-Leshkov, and two others.

      “The results are really striking,” says Surendranath, a professor of chemistry and chemical engineering. Rate increases of that magnitude have been seen before but in a different class of catalytic reactions known as redox half-reactions, which involve the gain or loss of an electron. The dramatically increased rates reported in the new study “have never been observed for reactions that don’t involve oxidation or reduction,” he says.

      The non-redox chemical reactions studied by the MIT team are catalyzed by acids. “If you’re a first-year chemistry student, probably the first type of catalyst you learn about is an acid catalyst,” Surendranath says. There are many hundreds of such acid-catalyzed reactions, “and they’re super important in everything from processing petrochemical feedstocks to making commodity chemicals to doing transformations in pharmaceutical products. The list goes on and on.”

      “These reactions are key to making many products we use daily,” adds Roman-Leshkov, a professor of chemical engineering and chemistry.

      But the people who study redox half-reactions, also known as electrochemical reactions, are part of an entirely different research community than those studying non-redox chemical reactions, known as thermochemical reactions. As a result, even though the technique used in the new study, which involves applying a small external voltage, was well-known in the electrochemical research community, it had not been systematically applied to acid-catalyzed thermochemical reactions.

      People working on thermochemical catalysis, Surendranath says, “usually don’t consider” the role of the electrochemical potential at the catalyst surface, “and they often don’t have good ways of measuring it. And what this study tells us is that relatively small changes, on the order of a few hundred millivolts, can have huge impacts — orders of magnitude changes in the rates of catalyzed reactions at those surfaces.”

      “This overlooked parameter of surface potential is something we should pay a lot of attention to because it can have a really, really outsized effect,” he says. “It changes the paradigm of how we think about catalysis.”

      Chemists traditionally think about surface catalysis based on the chemical binding energy of molecules to active sites on the surface, which influences the amount of energy needed for the reaction, he says. But the new findings show that the electrostatic environment is “equally important in defining the rate of the reaction.”

      The team has already filed a provisional patent application on parts of the process and is working on ways to apply the findings to specific chemical processes. Westendorff says their findings suggest that “we should design and develop different types of reactors to take advantage of this sort of strategy. And we’re working right now on scaling up these systems.”

      While their experiments so far were done with a two-dimensional planar electrode, most industrial reactions are run in three-dimensional vessels filled with powders. Catalysts are distributed through those powders, providing a lot more surface area for the reactions to take place. “We’re looking at how catalysis is currently done in industry and how we can design systems that take advantage of the already existing infrastructure,” Westendorff says.

      Surendranath adds that these new findings “raise tantalizing possibilities: Is this a more general phenomenon? Does electrochemical potential play a key role in other reaction classes as well? In our mind, this reshapes how we think about designing catalysts and promoting their reactivity.”

      Roman-Leshkov adds that “traditionally people who work in thermochemical catalysis would not associate these reactions with electrochemical processes at all. However, introducing this perspective to the community will redefine how we can integrate electrochemical characteristics into thermochemical catalysis. It will have a big impact on the community in general.”

      While there has typically been little interaction between electrochemical and thermochemical catalysis researchers, Surendranath says, “this study shows the community that there’s really a blurring of the line between the two, and that there is a huge opportunity in cross-fertilization between these two communities.”

      Westerndorff adds that to make it work, “you have to design a system that’s pretty unconventional to either community to isolate this effect.” And that helps explain why such a dramatic effect had never been seen before. He notes that even their paper’s editor asked them why this effect hadn’t been reported before. The answer has to do with “how disparate those two ideologies were before this,” he says. “It’s not just that people don’t really talk to each other. There are deep methodological differences between how the two communities conduct experiments. And this work is really, we think, a great step toward bridging the two.”

      In practice, the findings could lead to far more efficient production of a wide variety of chemical materials, the team says. “You get orders of magnitude changes in rate with very little energy input,” Surendranath says. “That’s what’s amazing about it.”

      The findings, he says, “build a more holistic picture of how catalytic reactions at interfaces work, irrespective of whether you’re going to bin them into the category of electrochemical reactions or thermochemical reactions.” He adds that “it’s rare that you find something that could really revise our foundational understanding of surface catalytic reactions in general. We’re very excited.”

      “This research is of the highest quality,” says Costas Vayenas, a professor of engineering at the university of Patras, in Greece, who was not associated with the study. The work “is very promising for practical applications, particularly since it extends previous related work in redox catalytic systems,” he says.

      The team included MIT postdoc Max Hulsey PhD ’22 and graduate student Thejas Wesley PhD ’23, and was supported by the Air Force Office of Scientific Research and the U.S. Department of Energy Basic Energy Sciences. More

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      Working to beat the clock on climate change

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      “There’s so much work ahead of us and so many obstacles in the way,” said Raisa Lee, director of project development with Clearway Energy Group, an independent clean power producer. But, added Lee, “It’s most important to focus on finding spaces and people so we can foster growth and support each other — the power of belonging!”

      These sentiments captured the spirit of the 12th annual Women in Clean Energy Education and Empowerment (C3E) Symposium and Awards, held recently at MIT. The conference is part of the C3E Initiative, which aims to connect women in clean energy, recognize the accomplishments of leaders across different fields, and engage more women in the enterprise of decarbonization.

      The conference topic, “Clearing hurdles to achieve net zero by 2050: Moving quickly, eliminating risks, and leaving no one behind,” spoke to the shared sense of urgency and commitment to community-building among the several hundred participants attending in person and online.

      As symposium speakers attested, the task of saving the world doesn’t seem as daunting when someone has your back.

      Melinda Baglio, chief investment officer and general counsel of the renewable energy finance firm  CleanCapital, said “I have several groups of women in my life … and whenever I am doing something really difficult, I like to close my eyes for a minute and imagine their hands right on my shoulders and just giving me that support and pushing me forward to do the thing that I need to do.”

      The C3E symposium was hosted by the MIT Energy Initiative (MITEI), which partners in the C3E Initiative with the U.S. Department of Energy (DoE), Stanford University’s Precourt Institute for Energy, and the Texas A&M Energy Institute.

      Gender diversity and emissions

      “Time is not on our side in the race to achieve net zero by 2050,” said Martha Broad, executive director of MITEI, in her opening remarks.“However, by increasing the gender diversity of the energy sector, we’re putting our best team forward to tackle this challenge.”

      Closing a pronounced gender gap in corporate leadership and legislative bodies would also help, she said. Research has demonstrated that improving gender diversity in the energy sector leads to stronger climate governance and innovation. In addition, Broad noted, a recent study showed that increasing gender diversity in legislative bodies results in stronger climate policy and “hence lowers CO2 emissions.”

      There was wide agreement that beating the clock on climate change means recruiting, training, and retaining a vast and diverse workforce. In talks and panels, symposium participants described their wide-ranging roles as leaders in this enterprise.

      “This is a very exciting time to be working in clean energy, and an exciting time to be doubling down on the work that C3E does, because clean energy technologies are ready,” said Kathleen Hogan, principal undersecretary for infrastructure at DoE. In her keynote address, Hogan highlighted “the amazing, historic funding through the bipartisan infrastructure law and Inflation Reduction Act, where we are putting ultimately trillions of dollars into clean energy.” This presents a “tremendous opportunity to grow the clean energy workforce … to pull in the next generation of women to advance this field of work, and to figure out how to deliver the maximum impact.”

      Gina McCarthy, who received the C3E Lifetime Achievement Award, rallied symposium participants to remain hopeful and engaged. “It’s all about a world of new possibilities, new partnerships we can create together,” said the former White House national climate advisor and Environmental Protection Agency administrator. “Use each milestone as an opportunity to pat ourselves on the back and be more passionate than ever before — that is how change happens.”

      “You belong”

      Other speakers provided ample evidence of passion and persistence in their pursuit of clean energy goals.

      C3E advocacy award winner and climate justice policy leader Jameka Hodnett works to ensure that historically underfunded Black communities benefit from decarbonization programs. Not all of her community contacts share her concerns about climate change or recognize the necessity of an energy transition. “This is difficult work, where I must be willing to stick my neck out and build relationships with others across differences,” she said.

      Remote and often marginalized communities in the United States and around the world pose other kinds of challenges. Wahleah Johns, director of DoE’s Office of Indian Energy Policy and Programs, described the loss of jobs on tribal lands as fossil fuel companies shut down, and the problem of developing trust with local groups. She believes energy justice in these communities must draw “on Indigenous, traditional knowledge of design, building, and planning” and demonstrate “value for future generations.”

      Evangelina Galvan Shreeve, daughter of immigrant farm workers, is tapping the talent of diverse communities to build the next generation’s clean energy workforce. The C3E education award winner, chief diversity officer, and director of STEM education at the Pacific Northwest National Laboratory tells young people: “You are worthy of joining places you dream about, you are brilliant, and we need both to pursue the clean energy future. You belong.”

      Reducing the carbon budget

      In her keynote address, Sally M. Benson, the Precourt Family Professor of Energy Science Engineering at Stanford University’s School of Earth, Energy, and Environmental Sciences, warned of the hazards of not acting quickly to reduce the global carbon budget. “It’s starting to cost us lots of money: In some years we are getting half a trillion dollars in damage,” she said. “We need all hands on deck, and to do that we need to align people’s views to give us the speed and scale to beat incredibly short timelines.”

      Benson’s strategies include generating community- and city-scale, rather than individual-scale actions; streamlining the process for approving renewable energy projects; and advancing technological innovations based on “which would have the largest, transformational impact, the kind that could meet our 2050 [net-zero carbon emissions] goals.”

      The symposium offered examples of innovations that could play out at the scale and speed that Benson recommends. 

      Elise Strobach SM ’17, PhD ’20 developed a nanoporous nanogel coating for windows that can cut energy losses — estimated at $40 billion a year — in half. Her spinout company, AeroShield Materials, aims to make windows light, thin, and affordable.

      Claire Woo’s startup employer, Form Energy, has designed an iron-air battery that could bolster the electric grid as renewable sources such as sun and wind fuel more of the world’s energy needs. Stacked like so many blocks in giant arrays, the batteries provide 100-hour energy backup for multi-day power outages due to storms or other emergencies.

      Grids and energy equity

      Panelists discussed the requirements for resilient electric grids in the clean energy transition. Peggy Heeg, a corporate board member of the Electric Reliability Council of Texas (ERCOT), celebrated her state’s top-ranked status in solar and wind production but cautioned that “the shift is creating some real problems with our operations of the grid.” She believes that, currently, the only viable backup when heat or storms cause demand peaks is natural gas generation.

      Caroline Choi, the senior vice president of corporate affairs at Edison International and Southern California Edison, described “unprecedented grid expansion” under way in California, as more solar and wind suppliers plug in. This will require “a significant acceleration in the pace of deployment of transmission systems,” said Julie Mulvaney Kemp, a research scientist at Lawrence Berkeley National Laboratory. Such expansion is complicated by fragmented regional planning, high costs, and local siting issues.

      Not all power systems are super-sized. “I flew in small bush planes with my baby daughter in order to shadow Alaska microgrid operators,” said Piper Foster Wilder, founder and CEO of 60Hertz Energy and the C3E entrepreneurship award winner. Her software enables energy suppliers in even the most inaccessible places to monitor and protect utilities and infrastructure.

      “Given the fundamental aspects of energy for life, the widely entrenched nature of the energy system, and the intersecting challenges with other priorities, everyone has a vital role to play,” said Kathleen Araújo, a professor of sustainable energy systems, innovation, and policy at Boise State University. In a panel devoted to energy justice, speakers hammered home the centrality of historically marginalized groups in achieving a global energy transition.

      In the United States, communities must play a vital role in shaping their clean energy futures, whether former mining counties in Pennsylvania, Indian tribes whose lands have been exploited for fossil fuel production, or diesel-importing regions in Alaska, said Araújo. “Inclusive engagement, knowledge sharing, and other forms of collaboration can strengthen the legitimacy and [lead to] more enduring outcomes.”

      Worldwide, 675 million people lack access to electricity, and 590 million of them live in sub-Saharan Africa, according to Rhonda Jordan Antoine, a senior energy specialist at The World Bank. The bank is committed to providing the populace of this vast region with reliable, renewable energy sources, customizing solutions to specific countries and communities. “Africa’s not just about connecting households to power but also supporting activities, agricultural productivity, and provision of essential services such as health care and education,” she said.

      Whether confronting environmental injustice, supply chain gridlock, financing difficulties or communities resistant to addressing decarbonization, symposium participants candidly shared their challenges and frustrations. “I personally find this is really hard work,” Sally Benson acknowledged. “It took us 100 years or more to build the energy system that we have today and now we’re saying that we want to change it in the next 20 years.”

      But the words of Gina McCarthy were invoked repeatedly over the two-day conference, lifting spirits in the room: “I am hugely optimistic,” she said. “The clean energy future isn’t just around, it isn’t just possible, it is already under way. And it is the opportunity of a lifetime.” More

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      How to decarbonize the world, at scale

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      The world in recent years has largely been moving on from debates about the need to curb carbon emissions and focusing more on action — the development, implementation, and deployment of the technological, economic, and policy measures to spur the scale of reductions needed by mid-century. That was the message Robert Stoner, the interim director of the MIT Energy Initiative (MITEI), gave in his opening remarks at the 2023 MITEI Annual Research Conference.

      Attendees at the two-day conference included faculty members, researchers, industry and financial leaders, government officials, and students, as well as more than 50 online participants from around the world.

      “We are at an extraordinary inflection point. We have this narrow window in time to mitigate the worst effects of climate change by transforming our entire energy system and economy,” said Jonah Wagner, the chief strategist of the U.S. Department of Energy’s (DOE) Loan Programs Office, in one of the conference’s keynote speeches.

      Yet the solutions exist, he said. “Most of the technologies that we need to deploy to stay close to the international target of 1.5 degrees Celsius warming are proven and ready to go,” he said. “We have over 80 percent of the technologies we will need through 2030, and at least half of the technologies we will need through 2050.”

      For example, Wagner pointed to the newly commissioned advanced nuclear power plant near Augusta, Georgia — the first new nuclear reactor built in the United States in a generation, partly funded through DOE loans. “It will be the largest source of clean power in America,” he said. Though implementing all the needed technologies in the United States through mid-century will cost an estimated $10 trillion, or about $300 billion a year, most of that money will come from the private sector, he said.

      As the United States faces what he describes as “a tsunami of distributed energy production,” one key example of the strategy that’s needed going forward, he said, is encouraging the development of virtual power plants (VPPs). The U.S. power grid is growing, he said, and will add 200 gigawatts of peak demand by 2030. But rather than building new, large power plants to satisfy that need, much of the increase can be accommodated by VPPs, he said — which are “aggregations of distributed energy resources like rooftop solar with batteries, like electric vehicles (EVs) and chargers, like smart appliances, commercial and industrial loads on the grid that can be used together to help balance supply and demand just like a traditional power plant.” For example, by shifting the time of demand for some applications where the timing is not critical, such as recharging EVs late at night instead of right after getting home from work when demand may be peaking, the need for extra peak power can be alleviated.

      Such programs “offer a broad range of benefits,” including affordability, reliability and resilience, decarbonization, and emissions reductions. But implementing such systems on a wide scale requires some up-front help, he explained. Payment for consumers to enroll in programs that allow such time adjustments “is the majority of the cost” of establishing VPPs, he says, “and that means most of the money spent on VPPs goes back into the pockets of American consumers.” But to make that happen, there is a need for standardization of VPP operations “so that we are not recreating the wheel every single time we deploy a pilot or an effort with a utility.”

      The conference’s other keynote speaker, Anne White, the vice provost and associate vice president for research administration at MIT, cited devastating recent floods, wildfires, and many other extreme weather-related crises around the world that have been exacerbated by climate change. “We saw in myriad ways that energy concerns and climate concerns are one and the same,” she said. “So, we must urgently develop and scale low-carbon and zero-carbon solutions to prevent future warming. And we must do this with a practical, systems-based approach that considers efficiency, affordability, equity, and sustainability for how the world will meet its energy needs.”

      White added that at MIT, “we are mobilizing everything.” People at MIT feel a strong sense of responsibility for dealing with these global issues, she said, “and I think it’s because we believe we have tools that can really make a difference.”

      Among the specific promising technologies that have sprung from MIT’s labs, she pointed out, is the rapid development of fusion technology that led to MIT spinoff company Commonwealth Fusion Systems, which aims to build a demonstration unit of a practical fusion power reactor by the decade’s end. That’s an outcome of decades of research, she emphasized — the kinds of early-stage risky work that only academic labs, with help from government grants, can carry out.

      For example, she pointed to the more than 200 projects that MITEI has provided seed funds of $150,000 each for two years, totaling over $28 million to date. Such early support is “a key part of producing the kind of transformative innovation we know we all need.” In addition, MIT’s The Engine has also helped launch not only Commonwealth Fusion Systems, but also Form Energy, a company building a plant in West Virginia to manufacture advanced iron-air batteries for renewable energy storage, and many others.

      Following that theme of supporting early innovation, the conference featured two panels that served to highlight the work of students and alumni and their energy-related startup companies. First, a startup showcase, moderated by Catarina Madeira, the director of MIT’s Startup Exchange, featured presentations about seven recent spinoff companies that are developing cutting-edge technologies that emerged from MIT research. These included:

      Aeroshield, developing a new kind of highly-insulated window using a unique aerogel material;
      Sublime, which is developing a low-emissions concrete;
      Found Energy, developing a way to use recycled aluminum as a fuel;
      Veir, developing superconducting power lines;
      Emvolom, developing inexpensive green fuels from waste gases;
      Boston Metal, developing low-emissions production processes for steel and other metals;
      Transaera, with a new kind of efficient air conditioning; and
      Carbon Recycling International, producing cheap hydrogen fuel and syngas.
      Later in the conference, a “student slam competition” featured presentations by 11 students who described results of energy projects they had been working on this past summer. The projects were as diverse as analyzing opposition to wind farms in Maine, how best to allocate EV charging stations, optimizing bioenergy production, recycling the lithium from batteries, encouraging adoption of heat pumps, and conflict analysis about energy project siting. Attendees voted on the quality of the student presentations, and electrical engineering and computer science student Tori Hagenlocker was declared first-place winner for her talk on heat pump adoption.

      Students were also featured in a first-time addition to the conference: a panel discussion among five current or recent students, giving their perspective on today’s energy issues and priorities, and how they are working toward trying to make a difference. Andres Alvarez, a recent graduate in nuclear engineering, described his work with a startup focused on identifying and supporting early-stage ideas that have potential. Graduate student Dyanna Jaye of urban studies and planning spoke about her work helping to launch a group called the Sunrise Movement to try to drive climate change as a top priority for the country, and her work helping to develop the Green New Deal.

      Peter Scott, a graduate student in mechanical engineering who is studying green hydrogen production, spoke of the need for a “very drastic and rapid phaseout of current, existing fossil fuels” and a halt on developing new sources. Amar Dayal, an MBA candidate at the MIT Sloan School of Management, talked about the interplay between technology and policy, and the crucial role that legislation like the Inflation Reduction Act can have in enabling new energy technology to make the climb to commercialization. And Shreyaa Raghavan, a doctoral student in the Institute of Data, Systems, and Society, talked about the importance of multidisciplinary approaches to climate issues, including the important role of computer science. She added that MIT does well on this compared to other institutions, and “sustainability and decarbonization is a pillar in a lot of the different departments and programs that exist here.”

      Some recent recipients of MITEI’s Seed Fund grants reported on their progress in a panel discussion moderated by MITEI Executive Director Martha Broad. Seed grant recipient Ariel Furst, a professor of chemical engineering, pointed out that access to electricity is very much concentrated in the global North and that, overall, one in 10 people worldwide lacks access to electricity and some 2.5 billion people “rely on dirty fuels to heat their homes and cook their food,” with impacts on both health and climate. The solution her project is developing involves using DNA molecules combined with catalysts to passively convert captured carbon dioxide into ethylene, a widely used chemical feedstock and fuel. Kerri Cahoy, a professor of aeronautics and astronautics, described her work on a system for monitoring methane emissions and power-line conditions by using satellite-based sensors. She and her team found that power lines often begin emitting detectable broadband radio frequencies long before they actually fail in a way that could spark fires.

      Admir Masic, an associate professor of civil and environmental engineering, described work on mining the ocean for minerals such as magnesium hydroxide to be used for carbon capture. The process can turn carbon dioxide into solid material that is stable over geological times and potentially usable as a construction material. Kripa Varanasi, a professor of mechanical engineering, said that over the years MITEI seed funding helped some of his projects that “went on to become startup companies, and some of them are thriving.” He described ongoing work on a new kind of electrolyzer for green hydrogen production. He developed a system using bubble-attracting surfaces to increase the efficiency of bioreactors that generate hydrogen fuel.

      A series of panel discussions over the two days covered a range of topics related to technologies and policies that could make a difference in combating climate change. On the technological side, one panel led by Randall Field, the executive director of MITEI’s Future Energy Systems Center, looked at large, hard-to-decarbonize industrial processes. Antoine Allanore, a professor of metallurgy, described progress in developing innovative processes for producing iron and steel, among the world’s most used commodities, in a way that drastically reduces greenhouse gas emissions. Greg Wilson of JERA Americas described the potential for ammonia produced from renewable sources to substitute for natural gas in power plants, greatly reducing emissions. Yet-Ming Chiang, a professor in materials science and engineering, described ways to decarbonize cement production using a novel low-temperature process. And Guiyan Zang, a research scientist at MITEI, spoke of efforts to reduce the carbon footprint of producing ethylene, a major industrial chemical, by using an electrochemical process.

      Another panel, led by Jacopo Buongiorno, professor of nuclear science and engineering, explored the brightening future for expansion of nuclear power, including new, small, modular reactors that are finally emerging into commercial demonstration. “There is for the first time truly here in the U.S. in at least a decade-and-a-half, a lot of excitement, a lot of attention towards nuclear,” Buongiorno said. Nuclear power currently produces 45 to 50 percent of the nation’s carbon-free electricity, the panelists said, and with the first new nuclear power plant in decades now in operation, the stage is set for significant growth.

      Carbon capture and sequestration was the subject of a panel led by David Babson, the executive director of MIT’s Climate Grand Challenges program. MIT professors Betar Gallant and Kripa Varanasi and industry representatives Elisabeth Birkeland from Equinor and Luc Huyse from Chevron Technology Ventures described significant progress in various approaches to recovering carbon dioxide from power plant emissions, from the air, and from the ocean, and converting it into fuels, construction materials, or other valuable commodities.

      Some panel discussions also addressed the financial and policy side of the climate issue. A panel on geopolitical implications of the energy transition was moderated by MITEI Deputy Director of Policy Christopher Knittel, who said “energy has always been synonymous with geopolitics.” He said that as concerns shift from where to find the oil and gas to where is the cobalt and nickel and other elements that will be needed, “not only are we worried about where the deposits of natural resources are, but we’re going to be more and more worried about how governments are incentivizing the transition” to developing this new mix of natural resources. Panelist Suzanne Berger, an Institute professor, said “we’re now at a moment of unique openness and opportunity for creating a new American production system,” one that is much more efficient and less carbon-producing.

      One panel dealt with the investor’s perspective on the possibilities and pitfalls of emerging energy technologies. Moderator Jacqueline Pless, an assistant professor in MIT Sloan, said “there’s a lot of momentum now in this space. It’s a really ripe time for investing,” but the risks are real. “Tons of investment is needed in some very big and uncertain technologies.”

      The role that large, established companies can play in leading a transition to cleaner energy was addressed by another panel. Moderator J.J. Laukatis, MITEI’s director of member services, said that “the scale of this transformation is massive, and it will also be very different from anything we’ve seen in the past. We’re going to have to scale up complex new technologies and systems across the board, from hydrogen to EVs to the electrical grid, at rates we haven’t done before.” And doing so will require a concerted effort that includes industry as well as government and academia. More

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      Engineers develop an efficient process to make fuel from carbon dioxide

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      The search is on worldwide to find ways to extract carbon dioxide from the air or from power plant exhaust and then make it into something useful. One of the more promising ideas is to make it into a stable fuel that can replace fossil fuels in some applications. But most such conversion processes have had problems with low carbon efficiency, or they produce fuels that can be hard to handle, toxic, or flammable.

      Now, researchers at MIT and Harvard University have developed an efficient process that can convert carbon dioxide into formate, a liquid or solid material that can be used like hydrogen or methanol to power a fuel cell and generate electricity. Potassium or sodium formate, already produced at industrial scales and commonly used as a de-icer for roads and sidewalks, is nontoxic, nonflammable, easy to store and transport, and can remain stable in ordinary steel tanks to be used months, or even years, after its production.

      The new process, developed by MIT doctoral students Zhen Zhang, Zhichu Ren, and Alexander H. Quinn; Harvard University doctoral student Dawei Xi; and MIT Professor Ju Li, is described this week in an open-access paper in Cell Reports Physical Science. The whole process — including capture and electrochemical conversion of the gas to a solid formate powder, which is then used in a fuel cell to produce electricity — was demonstrated at a small, laboratory scale. However, the researchers expect it to be scalable so that it could provide emissions-free heat and power to individual homes and even be used in industrial or grid-scale applications.

      Other approaches to converting carbon dioxide into fuel, Li explains, usually involve a two-stage process: First the gas is chemically captured and turned into a solid form as calcium carbonate, then later that material is heated to drive off the carbon dioxide and convert it to a fuel feedstock such as carbon monoxide. That second step has very low efficiency, typically converting less than 20 percent of the gaseous carbon dioxide into the desired product, Li says.

      By contrast, the new process achieves a conversion of well over 90 percent and eliminates the need for the inefficient heating step by first converting the carbon dioxide into an intermediate form, liquid metal bicarbonate. That liquid is then electrochemically converted into liquid potassium or sodium formate in an electrolyzer that uses low-carbon electricity, e.g. nuclear, wind, or solar power. The highly concentrated liquid potassium or sodium formate solution produced can then be dried, for example by solar evaporation, to produce a solid powder that is highly stable and can be stored in ordinary steel tanks for up to years or even decades, Li says.

      Several steps of optimization developed by the team made all the difference in changing an inefficient chemical-conversion process into a practical solution, says Li, who holds joint appointments in the departments of Nuclear Science and Engineering and of Materials Science and Engineering.

      The process of carbon capture and conversion involves first an alkaline solution-based capture that concentrates carbon dioxide, either from concentrated streams such as from power plant emissions or from very low-concentration sources, even open air, into the form of a liquid metal-bicarbonate solution. Then, through the use of a cation-exchange membrane electrolyzer, this bicarbonate is electrochemically converted into solid formate crystals with a carbon efficiency of greater than 96 percent, as confirmed in the team’s lab-scale experiments.

      These crystals have an indefinite shelf life, remaining so stable that they could be stored for years, or even decades, with little or no loss. By comparison, even the best available practical hydrogen storage tanks allow the gas to leak out at a rate of about 1 percent per day, precluding any uses that would require year-long storage, Li says. Methanol, another widely explored alternative for converting carbon dioxide into a fuel usable in fuel cells, is a toxic substance that cannot easily be adapted to use in situations where leakage could pose a health hazard. Formate, on the other hand, is widely used and considered benign, according to national safety standards.

      Several improvements account for the greatly improved efficiency of this process. First, a careful design of the membrane materials and their configuration overcomes a problem that previous attempts at such a system have encountered, where a buildup of certain chemical byproducts changes the pH, causing the system to steadily lose efficiency over time. “Traditionally, it is difficult to achieve long-term, stable, continuous conversion of the feedstocks,” Zhang says. “The key to our system is to achieve a pH balance for steady-state conversion.”

      To achieve that, the researchers carried out thermodynamic modeling to design the new process so that it is chemically balanced and the pH remains at a steady state with no shift in acidity over time. It can therefore continue operating efficiently over long periods. In their tests, the system ran for over 200 hours with no significant decrease in output. The whole process can be done at ambient temperatures and relatively low pressures (about five times atmospheric pressure).

      Another issue was that unwanted side reactions produced other chemical products that were not useful, but the team figured out a way to prevent these side reactions by the introduction of an extra “buffer” layer of bicarbonate-enriched fiberglass wool that blocked these reactions.

      The team also built a fuel cell specifically optimized for the use of this formate fuel to produce electricity. The stored formate particles are simply dissolved in water and pumped into the fuel cell as needed. Although the solid fuel is much heavier than pure hydrogen, when the weight and volume of the high-pressure gas tanks needed to store hydrogen is considered, the end result is an electricity output near parity for a given storage volume, Li says.

      The formate fuel can potentially be adapted for anything from home-sized units to large scale industrial uses or grid-scale storage systems, the researchers say. Initial household applications might involve an electrolyzer unit about the size of a refrigerator to capture and convert the carbon dioxide into formate, which could be stored in an underground or rooftop tank. Then, when needed, the powdered solid would be mixed with water and fed into a fuel cell to provide power and heat. “This is for community or household demonstrations,” Zhang says, “but we believe that also in the future it may be good for factories or the grid.”

      “The formate economy is an intriguing concept because metal formate salts are very benign and stable, and a compelling energy carrier,” says Ted Sargent, a professor of chemistry and of electrical and computer engineering at Northwestern University, who was not associated with this work. “The authors have demonstrated enhanced efficiency in liquid-to-liquid conversion from bicarbonate feedstock to formate, and have demonstrated these fuels can be used later to produce electricity,” he says.

      The work was supported by the U.S. Department of Energy Office of Science. More