More stories

  • in

    MIT engineers develop a magnetic transistor for more energy-efficient electronics

    Transistors, the building blocks of modern electronics, are typically made of silicon. Because it’s a semiconductor, this material can control the flow of electricity in a circuit. But silicon has fundamental physical limits that restrict how compact and energy-efficient a transistor can be.MIT researchers have now replaced silicon with a magnetic semiconductor, creating a magnetic transistor that could enable smaller, faster, and more energy-efficient circuits. The material’s magnetism strongly influences its electronic behavior, leading to more efficient control of the flow of electricity. The team used a novel magnetic material and an optimization process that reduces the material’s defects, which boosts the transistor’s performance.The material’s unique magnetic properties also allow for transistors with built-in memory, which would simplify circuit design and unlock new applications for high-performance electronics.“People have known about magnets for thousands of years, but there are very limited ways to incorporate magnetism into electronics. We have shown a new way to efficiently utilize magnetism that opens up a lot of possibilities for future applications and research,” says Chung-Tao Chou, an MIT graduate student in the departments of Electrical Engineering and Computer Science (EECS) and Physics, and co-lead author of a paper on this advance.Chou is joined on the paper by co-lead author Eugene Park, a graduate student in the Department of Materials Science and Engineering (DMSE); Julian Klein, a DMSE research scientist; Josep Ingla-Aynes, a postdoc in the MIT Plasma Science and Fusion Center; Jagadeesh S. Moodera, a senior research scientist in the Department of Physics; and senior authors Frances Ross, TDK Professor in DMSE; and Luqiao Liu, an associate professor in EECS, and a member of the Research Laboratory of Electronics; as well as others at the University of Chemistry and Technology in Prague. The paper appears today in Physical Review Letters.Overcoming the limitsIn an electronic device, silicon semiconductor transistors act like tiny light switches that turn a circuit on and off, or amplify weak signals in a communication system. They do this using a small input voltage.But a fundamental physical limit of silicon semiconductors prevents a transistor from operating below a certain voltage, which hinders its energy efficiency.To make more efficient electronics, researchers have spent decades working toward magnetic transistors that utilize electron spin to control the flow of electricity. Electron spin is a fundamental property that enables electrons to behave like tiny magnets.So far, scientists have mostly been limited to using certain magnetic materials. These lack the favorable electronic properties of semiconductors, constraining device performance.“In this work, we combine magnetism and semiconductor physics to realize useful spintronic devices,” Liu says.The researchers replace the silicon in the surface layer of a transistor with chromium sulfur bromide, a two-dimensional material that acts as a magnetic semiconductor.Due to the material’s structure, researchers can switch between two magnetic states very cleanly. This makes it ideal for use in a transistor that smoothly switches between “on” and “off.”“One of the biggest challenges we faced was finding the right material. We tried many other materials that didn’t work,” Chou says.They discovered that changing these magnetic states modifies the material’s electronic properties, enabling low-energy operation. And unlike many other 2D materials, chromium sulfur bromide remains stable in air.To make a transistor, the researchers pattern electrodes onto a silicon substrate, then carefully align and transfer the 2D material on top. They use tape to pick up a tiny piece of material, only a few tens of nanometers thick, and place it onto the substrate.“A lot of researchers will use solvents or glue to do the transfer, but transistors require a very clean surface. We eliminate all those risks by simplifying this step,” Chou says.Leveraging magnetismThis lack of contamination enables their device to outperform existing magnetic transistors. Most others can only create a weak magnetic effect, changing the flow of current by a few percent or less. Their new transistor can switch or amplify the electric current by a factor of 10.They use an external magnetic field to change the magnetic state of the material, switching the transistor using significantly less energy than would usually be required.The material also allows them to control the magnetic states with electric current. This is important because engineers cannot apply magnetic fields to individual transistors in an electronic device. They need to control each one electrically.The material’s magnetic properties could also enable transistors with built-in memory, simplifying the design of logic or memory circuits.A typical memory device has a magnetic cell to store information and a transistor to read it out. Their method can combine both into one magnetic transistor.“Now, not only are transistors turning on and off, they are also remembering information. And because we can switch the transistor with greater magnitude, the signal is much stronger so we can read out the information faster, and in a much more reliable way,” Liu says.Building on this demonstration, the researchers plan to further study the use of electrical current to control the device. They are also working to make their method scalable so they can fabricate arrays of transistors.This research was supported, in part, by the Semiconductor Research Corporation, the U.S. Defense Advanced Research Projects Agency (DARPA), the U.S. National Science Foundation (NSF), the U.S. Department of Energy, the U.S. Army Research Office, and the Czech Ministry of Education, Youth, and Sports. The work was partially carried out at the MIT.nano facilities. More

  • in

    New self-assembling material could be the key to recyclable EV batteries

    Today’s electric vehicle boom is tomorrow’s mountain of electronic waste. And while myriad efforts are underway to improve battery recycling, many EV batteries still end up in landfills.A research team from MIT wants to help change that with a new kind of self-assembling battery material that quickly breaks apart when submerged in a simple organic liquid. In a new paper published in Nature Chemistry, the researchers showed the material can work as the electrolyte in a functioning, solid-state battery cell and then revert back to its original molecular components in minutes.The approach offers an alternative to shredding the battery into a mixed, hard-to-recycle mass. Instead, because the electrolyte serves as the battery’s connecting layer, when the new material returns to its original molecular form, the entire battery disassembles to accelerate the recycling process.“So far in the battery industry, we’ve focused on high-performing materials and designs, and only later tried to figure out how to recycle batteries made with complex structures and hard-to-recycle materials,” says the paper’s first author Yukio Cho PhD ’23. “Our approach is to start with easily recyclable materials and figure out how to make them battery-compatible. Designing batteries for recyclability from the beginning is a new approach.”Joining Cho on the paper are PhD candidate Cole Fincher, Ty Christoff-Tempesta PhD ’22, Kyocera Professor of Ceramics Yet-Ming Chiang, Visiting Associate Professor Julia Ortony, Xiaobing Zuo, and Guillaume Lamour.Better batteriesThere’s a scene in one of the “Harry Potter” films where Professor Dumbledore cleans a dilapidated home with the flick of the wrist and a spell. Cho says that image stuck with him as a kid. (What better way to clean your room?) When he saw a talk by Ortony on engineering molecules so that they could assemble into complex structures and then revert back to their original form, he wondered if it could be used to make battery recycling work like magic.That would be a paradigm shift for the battery industry. Today, batteries require harsh chemicals, high heat, and complex processing to recycle. There are three main parts of a battery: the positively charged cathode, the negatively charged electrode, and the electrolyte that shuttles lithium ions between them. The electrolytes in most lithium-ion batteries are highly flammable and degrade over time into toxic byproducts that require specialized handling.To simplify the recycling process, the researchers decided to make a more sustainable electrolyte. For that, they turned to a class of molecules that self-assemble in water, named aramid amphiphiles (AAs), whose chemical structures and stability mimic that of Kevlar. The researchers further designed the AAs to contain polyethylene glycol (PEG), which can conduct lithium ions, on one end of each molecule. When the molecules are exposed to water, they spontaneously form nanoribbons with ion-conducting PEG surfaces and bases that imitate the robustness of Kevlar through tight hydrogen bonding. The result is a mechanically stable nanoribbon structure that conducts ions across its surface.“The material is composed of two parts,” Cho explains. “The first part is this flexible chain that gives us a nest, or host, for lithium ions to jump around. The second part is this strong organic material component that is used in the Kevlar, which is a bulletproof material. Those make the whole structure stable.”When added to water, the nanoribbons self-assemble to form millions of nanoribbons that can be hot-pressed into a solid-state material.“Within five minutes of being added to water, the solution becomes gel-like, indicating there are so many nanofibers formed in the liquid that they start to entangle each other,” Cho says. “What’s exciting is we can make this material at scale because of the self-assembly behavior.”The team tested the material’s strength and toughness, finding it could endure the stresses associated with making and running the battery. They also constructed a solid-state battery cell that used lithium iron phosphate for the cathode and lithium titanium oxide as the anode, both common materials in today’s batteries. The nanoribbons moved lithium ions successfully between the electrodes, but a side-effect known as polarization limited the movement of lithium ions into the battery’s electrodes during fast bouts of charging and discharging, hampering its performance compared to today’s gold-standard commercial batteries.“The lithium ions moved along the nanofiber all right, but getting the lithium ion from the nanofibers to the metal oxide seems to be the most sluggish point of the process,” Cho says.When they immersed the battery cell into organic solvents, the material immediately dissolved, with each part of the battery falling away for easier recycling. Cho compared the materials’ reaction to cotton candy being submerged in water.“The electrolyte holds the two battery electrodes together and provides the lithium-ion pathways,” Cho says. “So, when you want to recycle the battery, the entire electrolyte layer can fall off naturally and you can recycle the electrodes separately.”Validating a new approachCho says the material is a proof of concept that demonstrates the recycle-first approach.“We don’t want to say we solved all the problems with this material,” Cho says. “Our battery performance was not fantastic because we used only this material as the entire electrolyte for the paper, but what we’re picturing is using this material as one layer in the battery electrolyte. It doesn’t have to be the entire electrolyte to kick off the recycling process.”Cho also sees a lot of room for optimizing the material’s performance with further experiments.Now, the researchers are exploring ways to integrate these kinds of materials into existing battery designs as well as implementing the ideas into new battery chemistries.“It’s very challenging to convince existing vendors to do something very differently,” Cho says. “But with new battery materials that may come out in five or 10 years, it could be easier to integrate this into new designs in the beginning.”Cho also believes the approach could help reshore lithium supplies by reusing materials from batteries that are already in the U.S.“People are starting to realize how important this is,” Cho says. “If we can start to recycle lithium-ion batteries from battery waste at scale, it’ll have the same effect as opening lithium mines in the U.S. Also, each battery requires a certain amount of lithium, so extrapolating out the growth of electric vehicles, we need to reuse this material to avoid massive lithium price spikes.”The work was supported, in part, by the National Science Foundation and the U.S. Department of Energy. More

  • in

    Confronting the AI/energy conundrum

    The explosive growth of AI-powered computing centers is creating an unprecedented surge in electricity demand that threatens to overwhelm power grids and derail climate goals. At the same time, artificial intelligence technologies could revolutionize energy systems, accelerating the transition to clean power.“We’re at a cusp of potentially gigantic change throughout the economy,” said William H. Green, director of the MIT Energy Initiative (MITEI) and Hoyt C. Hottel Professor in the MIT Department of Chemical Engineering, at MITEI’s Spring Symposium, “AI and energy: Peril and promise,” held on May 13. The event brought together experts from industry, academia, and government to explore solutions to what Green described as both “local problems with electric supply and meeting our clean energy targets” while seeking to “reap the benefits of AI without some of the harms.” The challenge of data center energy demand and potential benefits of AI to the energy transition is a research priority for MITEI.AI’s startling energy demandsFrom the start, the symposium highlighted sobering statistics about AI’s appetite for electricity. After decades of flat electricity demand in the United States, computing centers now consume approximately 4 percent of the nation’s electricity. Although there is great uncertainty, some projections suggest this demand could rise to 12-15 percent by 2030, largely driven by artificial intelligence applications.Vijay Gadepally, senior scientist at MIT’s Lincoln Laboratory, emphasized the scale of AI’s consumption. “The power required for sustaining some of these large models is doubling almost every three months,” he noted. “A single ChatGPT conversation uses as much electricity as charging your phone, and generating an image consumes about a bottle of water for cooling.”Facilities requiring 50 to 100 megawatts of power are emerging rapidly across the United States and globally, driven both by casual and institutional research needs relying on large language programs such as ChatGPT and Gemini. Gadepally cited congressional testimony by Sam Altman, CEO of OpenAI, highlighting how fundamental this relationship has become: “The cost of intelligence, the cost of AI, will converge to the cost of energy.”“The energy demands of AI are a significant challenge, but we also have an opportunity to harness these vast computational capabilities to contribute to climate change solutions,” said Evelyn Wang, MIT vice president for energy and climate and the former director at the Advanced Research Projects Agency-Energy (ARPA-E) at the U.S. Department of Energy.Wang also noted that innovations developed for AI and data centers — such as efficiency, cooling technologies, and clean-power solutions — could have broad applications beyond computing facilities themselves.Strategies for clean energy solutionsThe symposium explored multiple pathways to address the AI-energy challenge. Some panelists presented models suggesting that while artificial intelligence may increase emissions in the short term, its optimization capabilities could enable substantial emissions reductions after 2030 through more efficient power systems and accelerated clean technology development.Research shows regional variations in the cost of powering computing centers with clean electricity, according to Emre Gençer, co-founder and CEO of Sesame Sustainability and former MITEI principal research scientist. Gençer’s analysis revealed that the central United States offers considerably lower costs due to complementary solar and wind resources. However, achieving zero-emission power would require massive battery deployments — five to 10 times more than moderate carbon scenarios — driving costs two to three times higher.“If we want to do zero emissions with reliable power, we need technologies other than renewables and batteries, which will be too expensive,” Gençer said. He pointed to “long-duration storage technologies, small modular reactors, geothermal, or hybrid approaches” as necessary complements.Because of data center energy demand, there is renewed interest in nuclear power, noted Kathryn Biegel, manager of R&D and corporate strategy at Constellation Energy, adding that her company is restarting the reactor at the former Three Mile Island site, now called the “Crane Clean Energy Center,” to meet this demand. “The data center space has become a major, major priority for Constellation,” she said, emphasizing how their needs for both reliability and carbon-free electricity are reshaping the power industry.Can AI accelerate the energy transition?Artificial intelligence could dramatically improve power systems, according to Priya Donti, assistant professor and the Silverman Family Career Development Professor in MIT’s Department of Electrical Engineering and Computer Science and the Laboratory for Information and Decision Systems. She showcased how AI can accelerate power grid optimization by embedding physics-based constraints into neural networks, potentially solving complex power flow problems at “10 times, or even greater, speed compared to your traditional models.”AI is already reducing carbon emissions, according to examples shared by Antonia Gawel, global director of sustainability and partnerships at Google. Google Maps’ fuel-efficient routing feature has “helped to prevent more than 2.9 million metric tons of GHG [greenhouse gas] emissions reductions since launch, which is the equivalent of taking 650,000 fuel-based cars off the road for a year,” she said. Another Google research project uses artificial intelligence to help pilots avoid creating contrails, which represent about 1 percent of global warming impact.AI’s potential to speed materials discovery for power applications was highlighted by Rafael Gómez-Bombarelli, the Paul M. Cook Career Development Associate Professor in the MIT Department of Materials Science and Engineering. “AI-supervised models can be trained to go from structure to property,” he noted, enabling the development of materials crucial for both computing and efficiency.Securing growth with sustainabilityThroughout the symposium, participants grappled with balancing rapid AI deployment against environmental impacts. While AI training receives most attention, Dustin Demetriou, senior technical staff member in sustainability and data center innovation at IBM, quoted a World Economic Forum article that suggested that “80 percent of the environmental footprint is estimated to be due to inferencing.” Demetriou emphasized the need for efficiency across all artificial intelligence applications.Jevons’ paradox, where “efficiency gains tend to increase overall resource consumption rather than decrease it” is another factor to consider, cautioned Emma Strubell, the Raj Reddy Assistant Professor in the Language Technologies Institute in the School of Computer Science at Carnegie Mellon University. Strubell advocated for viewing computing center electricity as a limited resource requiring thoughtful allocation across different applications.Several presenters discussed novel approaches for integrating renewable sources with existing grid infrastructure, including potential hybrid solutions that combine clean installations with existing natural gas plants that have valuable grid connections already in place. These approaches could provide substantial clean capacity across the United States at reasonable costs while minimizing reliability impacts.Navigating the AI-energy paradoxThe symposium highlighted MIT’s central role in developing solutions to the AI-electricity challenge.Green spoke of a new MITEI program on computing centers, power, and computation that will operate alongside the comprehensive spread of MIT Climate Project research. “We’re going to try to tackle a very complicated problem all the way from the power sources through the actual algorithms that deliver value to the customers — in a way that’s going to be acceptable to all the stakeholders and really meet all the needs,” Green said.Participants in the symposium were polled about priorities for MIT’s research by Randall Field, MITEI director of research. The real-time results ranked “data center and grid integration issues” as the top priority, followed by “AI for accelerated discovery of advanced materials for energy.”In addition, attendees revealed that most view AI’s potential regarding power as a “promise,” rather than a “peril,” although a considerable portion remain uncertain about the ultimate impact. When asked about priorities in power supply for computing facilities, half of the respondents selected carbon intensity as their top concern, with reliability and cost following. More

  • in

    AI stirs up the recipe for concrete in MIT study

    For weeks, the whiteboard in the lab was crowded with scribbles, diagrams, and chemical formulas. A research team across the Olivetti Group and the MIT Concrete Sustainability Hub (CSHub) was working intensely on a key problem: How can we reduce the amount of cement in concrete to save on costs and emissions? The question was certainly not new; materials like fly ash, a byproduct of coal production, and slag, a byproduct of steelmaking, have long been used to replace some of the cement in concrete mixes. However, the demand for these products is outpacing supply as industry looks to reduce its climate impacts by expanding their use, making the search for alternatives urgent. The challenge that the team discovered wasn’t a lack of candidates; the problem was that there were too many to sort through.On May 17, the team, led by postdoc Soroush Mahjoubi, published an open-access paper in Nature’s Communications Materials outlining their solution. “We realized that AI was the key to moving forward,” notes Mahjoubi. “There is so much data out there on potential materials — hundreds of thousands of pages of scientific literature. Sorting through them would have taken many lifetimes of work, by which time more materials would have been discovered!”With large language models, like the chatbots many of us use daily, the team built a machine-learning framework that evaluates and sorts candidate materials based on their physical and chemical properties. “First, there is hydraulic reactivity. The reason that concrete is strong is that cement — the ‘glue’ that holds it together — hardens when exposed to water. So, if we replace this glue, we need to make sure the substitute reacts similarly,” explains Mahjoubi. “Second, there is pozzolanicity. This is when a material reacts with calcium hydroxide, a byproduct created when cement meets water, to make the concrete harder and stronger over time.  We need to balance the hydraulic and pozzolanic materials in the mix so the concrete performs at its best.”Analyzing scientific literature and over 1 million rock samples, the team used the framework to sort candidate materials into 19 types, ranging from biomass to mining byproducts to demolished construction materials. Mahjoubi and his team found that suitable materials were available globally — and, more impressively, many could be incorporated into concrete mixes just by grinding them. This means it’s possible to extract emissions and cost savings without much additional processing. “Some of the most interesting materials that could replace a portion of cement are ceramics,” notes Mahjoubi. “Old tiles, bricks, pottery — all these materials may have high reactivity. That’s something we’ve observed in ancient Roman concrete, where ceramics were added to help waterproof structures. I’ve had many interesting conversations on this with Professor Admir Masic, who leads a lot of the ancient concrete studies here at MIT.”The potential of everyday materials like ceramics and industrial materials like mine tailings is an example of how materials like concrete can help enable a circular economy. By identifying and repurposing materials that would otherwise end up in landfills, researchers and industry can help to give these materials a second life as part of our buildings and infrastructure.Looking ahead, the research team is planning to upgrade the framework to be capable of assessing even more materials, while experimentally validating some of the best candidates. “AI tools have gotten this research far in a short time, and we are excited to see how the latest developments in large language models enable the next steps,” says Professor Elsa Olivetti, senior author on the work and member of the MIT Department of Materials Science and Engineering. She serves as an MIT Climate Project mission director, a CSHub principal investigator, and the leader of the Olivetti Group.“Concrete is the backbone of the built environment,” says Randolph Kirchain, co-author and CSHub director. “By applying data science and AI tools to material design, we hope to support industry efforts to build more sustainably, without compromising on strength, safety, or durability.In addition to Mahjoubi, Olivetti, and Kirchain, co-authors on the work include MIT postdoc Vineeth Venugopal, Ipek Bensu Manav SM ’21, PhD ’24; and CSHub Deputy Director Hessam AzariJafari. More

  • in

    New fuel cell could enable electric aviation

    Batteries are nearing their limits in terms of how much power they can store for a given weight. That’s a serious obstacle for energy innovation and the search for new ways to power airplanes, trains, and ships. Now, researchers at MIT and elsewhere have come up with a solution that could help electrify these transportation systems.Instead of a battery, the new concept is a kind of fuel cell — which is similar to a battery but can be quickly refueled rather than recharged. In this case, the fuel is liquid sodium metal, an inexpensive and widely available commodity. The other side of the cell is just ordinary air, which serves as a source of oxygen atoms. In between, a layer of solid ceramic material serves as the electrolyte, allowing sodium ions to pass freely through, and a porous air-facing electrode helps the sodium to chemically react with oxygen and produce electricity.In a series of experiments with a prototype device, the researchers demonstrated that this cell could carry more than three times as much energy per unit of weight as the lithium-ion batteries used in virtually all electric vehicles today. Their findings are being published today in the journal Joule, in a paper by MIT doctoral students Karen Sugano, Sunil Mair, and Saahir Ganti-Agrawal; professor of materials science and engineering Yet-Ming Chiang; and five others.“We expect people to think that this is a totally crazy idea,” says Chiang, who is the Kyocera Professor of Ceramics. “If they didn’t, I’d be a bit disappointed because if people don’t think something is totally crazy at first, it probably isn’t going to be that revolutionary.”And this technology does appear to have the potential to be quite revolutionary, he suggests. In particular, for aviation, where weight is especially crucial, such an improvement in energy density could be the breakthrough that finally makes electrically powered flight practical at significant scale.“The threshold that you really need for realistic electric aviation is about 1,000 watt-hours per kilogram,” Chiang says. Today’s electric vehicle lithium-ion batteries top out at about 300 watt-hours per kilogram — nowhere near what’s needed. Even at 1,000 watt-hours per kilogram, he says, that wouldn’t be enough to enable transcontinental or trans-Atlantic flights.That’s still beyond reach for any known battery chemistry, but Chiang says that getting to 1,000 watts per kilogram would be an enabling technology for regional electric aviation, which accounts for about 80 percent of domestic flights and 30 percent of the emissions from aviation.The technology could be an enabler for other sectors as well, including marine and rail transportation. “They all require very high energy density, and they all require low cost,” he says. “And that’s what attracted us to sodium metal.”A great deal of research has gone into developing lithium-air or sodium-air batteries over the last three decades, but it has been hard to make them fully rechargeable. “People have been aware of the energy density you could get with metal-air batteries for a very long time, and it’s been hugely attractive, but it’s just never been realized in practice,” Chiang says.By using the same basic electrochemical concept, only making it a fuel cell instead of a battery, the researchers were able to get the advantages of the high energy density in a practical form. Unlike a battery, whose materials are assembled once and sealed in a container, with a fuel cell the energy-carrying materials go in and out.The team produced two different versions of a lab-scale prototype of the system. In one, called an H cell, two vertical glass tubes are connected by a tube across the middle, which contains a solid ceramic electrolyte material and a porous air electrode. Liquid sodium metal fills the tube on one side, and air flows through the other, providing the oxygen for the electrochemical reaction at the center, which ends up gradually consuming the sodium fuel. The other prototype uses a horizontal design, with a tray of the electrolyte material holding the liquid sodium fuel. The porous air electrode, which facilitates the reaction, is affixed to the bottom of the tray. Tests using an air stream with a carefully controlled humidity level produced a level of more than 1,500 watt-hours per kilogram at the level of an individual “stack,” which would translate to over 1,000 watt-hours at the full system level, Chiang says.The researchers envision that to use this system in an aircraft, fuel packs containing stacks of cells, like racks of food trays in a cafeteria, would be inserted into the fuel cells; the sodium metal inside these packs gets chemically transformed as it provides the power. A stream of its chemical byproduct is given off, and in the case of aircraft this would be emitted out the back, not unlike the exhaust from a jet engine.But there’s a very big difference: There would be no carbon dioxide emissions. Instead the emissions, consisting of sodium oxide, would actually soak up carbon dioxide from the atmosphere. This compound would quickly combine with moisture in the air to make sodium hydroxide — a material commonly used as a drain cleaner — which readily combines with carbon dioxide to form a solid material, sodium carbonate, which in turn forms sodium bicarbonate, otherwise known as baking soda.“There’s this natural cascade of reactions that happens when you start with sodium metal,” Chiang says. “It’s all spontaneous. We don’t have to do anything to make it happen, we just have to fly the airplane.”As an added benefit, if the final product, the sodium bicarbonate, ends up in the ocean, it could help to de-acidify the water, countering another of the damaging effects of greenhouse gases.Using sodium hydroxide to capture carbon dioxide has been proposed as a way of mitigating carbon emissions, but on its own, it’s not an economic solution because the compound is too expensive. “But here, it’s a byproduct,” Chiang explains, so it’s essentially free, producing environmental benefits at no cost.Importantly, the new fuel cell is inherently safer than many other batteries, he says. Sodium metal is extremely reactive and must be well-protected. As with lithium batteries, sodium can spontaneously ignite if exposed to moisture. “Whenever you have a very high energy density battery, safety is always a concern, because if there’s a rupture of the membrane that separates the two reactants, you can have a runaway reaction,” Chiang says. But in this fuel cell, one side is just air, “which is dilute and limited. So you don’t have two concentrated reactants right next to each other. If you’re pushing for really, really high energy density, you’d rather have a fuel cell than a battery for safety reasons.”While the device so far exists only as a small, single-cell prototype, Chiang says the system should be quite straightforward to scale up to practical sizes for commercialization. Members of the research team have already formed a company, Propel Aero, to develop the technology. The company is currently housed in MIT’s startup incubator, The Engine.Producing enough sodium metal to enable widespread, full-scale global implementation of this technology should be practical, since the material has been produced at large scale before. When leaded gasoline was the norm, before it was phased out, sodium metal was used to make the tetraethyl lead used as an additive, and it was being produced in the U.S. at a capacity of 200,000 tons a year. “It reminds us that sodium metal was once produced at large scale and safely handled and distributed around the U.S.,” Chiang says.What’s more, sodium primarily originates from sodium chloride, or salt, so it is abundant, widely distributed around the world, and easily extracted, unlike lithium and other materials used in today’s EV batteries.The system they envisage would use a refillable cartridge, which would be filled with liquid sodium metal and sealed. When it’s depleted, it would be returned to a refilling station and loaded with fresh sodium. Sodium melts at 98 degrees Celsius, just below the boiling point of water, so it is easy to heat to the melting point to refuel the cartridges.Initially, the plan is to produce a brick-sized fuel cell that can deliver about 1,000 watt-hours of energy, enough to power a large drone, in order to prove the concept in a practical form that could be used for agriculture, for example. The team hopes to have such a demonstration ready within the next year.Sugano, who conducted much of the experimental work as part of her doctoral thesis and will now work at the startup, says that a key insight was the importance of moisture in the process. As she tested the device with pure oxygen, and then with air, she found that the amount of humidity in the air was crucial to making the electrochemical reaction efficient. The humid air resulted in the sodium producing its discharge products in liquid rather than solid form, making it much easier for these to be removed by the flow of air through the system. “The key was that we can form this liquid discharge product and remove it easily, as opposed to the solid discharge that would form in dry conditions,” she says.Ganti-Agrawal notes that the team drew from a variety of different engineering subfields. For example, there has been much research on high-temperature sodium, but none with a system with controlled humidity. “We’re pulling from fuel cell research in terms of designing our electrode, we’re pulling from older high-temperature battery research as well as some nascent sodium-air battery research, and kind of mushing it together,” which led to the “the big bump in performance” the team has achieved, he says.The research team also included Alden Friesen, an MIT summer intern who attends Desert Mountain High School in Scottsdale, Arizona; Kailash Raman and William Woodford of Form Energy in Somerville, Massachusetts; Shashank Sripad of And Battery Aero in California, and Venkatasubramanian Viswanathan of the University of Michigan. The work was supported by ARPA-E, Breakthrough Energy Ventures, and the National Science Foundation, and used facilities at MIT.nano. More

  • in

    Workshop explores new advanced materials for a growing world

    It is clear that humankind needs increasingly more resources, from computing power to steel and concrete, to meet the growing demands associated with data centers, infrastructure, and other mainstays of society. New, cost-effective approaches for producing the advanced materials key to that growth were the focus of a two-day workshop at MIT on March 11 and 12.A theme throughout the event was the importance of collaboration between and within universities and industries. The goal is to “develop concepts that everybody can use together, instead of everybody doing something different and then trying to sort it out later at great cost,” said Lionel Kimerling, the Thomas Lord Professor of Materials Science and Engineering at MIT.The workshop was produced by MIT’s Materials Research Laboratory (MRL), which has an industry collegium, and MIT’s Industrial Liaison Program. The program included an address by Javier Sanfelix, lead of the Advanced Materials Team for the European Union. Sanfelix gave an overview of the EU’s strategy to developing advanced materials, which he said are “key enablers of the green and digital transition for European industry.”That strategy has already led to several initiatives. These include a material commons, or shared digital infrastructure for the design and development of advanced materials, and an advanced materials academy for educating new innovators and designers. Sanfelix also described an Advanced Materials Act for 2026 that aims to put in place a legislative framework that supports the entire innovation cycle.Sanfelix was visiting MIT to learn more about how the Institute is approaching the future of advanced materials. “We see MIT as a leader worldwide in technology, especially on materials, and there is a lot to learn about [your] industry collaborations and technology transfer with industry,” he said.Innovations in steel and concreteThe workshop began with talks about innovations involving two of the most common human-made materials in the world: steel and cement. We’ll need more of both but must reckon with the huge amounts of energy required to produce them and their impact on the environment due to greenhouse-gas emissions during that production.One way to address our need for more steel is to reuse what we have, said C. Cem Tasan, the POSCO Associate Professor of Metallurgy in the Department of Materials Science and Engineering (DMSE) and director of the Materials Research Laboratory.But most of the existing approaches to recycling scrap steel involve melting the metal. “And whenever you are dealing with molten metal, everything goes up, from energy use to carbon-dioxide emissions. Life is more difficult,” Tasan said.The question he and his team asked is whether they could reuse scrap steel without melting it. Could they consolidate solid scraps, then roll them together using existing equipment to create new sheet metal? From the materials-science perspective, Tasan said, that shouldn’t work, for several reasons.But it does. “We’ve demonstrated the potential in two papers and two patent applications already,” he said. Tasan noted that the approach focuses on high-quality manufacturing scrap. “This is not junkyard scrap,” he said.Tasan went on to explain how and why the new process works from a materials-science perspective, then gave examples of how the recycled steel could be used. “My favorite example is the stainless-steel countertops in restaurants. Do you really need the mechanical performance of stainless steel there?” You could use the recycled steel instead.Hessam Azarijafari addressed another common, indispensable material: concrete. This year marks the 16th anniversary of the MIT Concrete Sustainability Hub (CSHub), which began when a set of industry leaders and politicians reached out to MIT to learn more about the benefits and environmental impacts of concrete.The hub’s work now centers around three main themes: working toward a carbon-neutral concrete industry; the development of a sustainable infrastructure, with a focus on pavement; and how to make our cities more resilient to natural hazards through investment in stronger, cooler construction.Azarijafari, the deputy director of the CSHub, went on to give several examples of research results that have come out of the CSHub. These include many models to identify different pathways to decarbonize the cement and concrete sector. Other work involves pavements, which the general public thinks of as inert, Azarijafari said. “But we have [created] a state-of-the-art model that can assess interactions between pavement and vehicles.” It turns out that pavement surface characteristics and structural performance “can influence excess fuel consumption by inducing an additional rolling resistance.”Azarijafari emphasized  the importance of working closely with policymakers and industry. That engagement is key “to sharing the lessons that we have learned so far.”Toward a resource-efficient microchip industryConsider the following: In 2020 the number of cell phones, GPS units, and other devices connected to the “cloud,” or large data centers, exceeded 50 billion. And data-center traffic in turn is scaling by 1,000 times every 10 years.But all of that computation takes energy. And “all of it has to happen at a constant cost of energy, because the gross domestic product isn’t changing at that rate,” said Kimerling. The solution is to either produce much more energy, or make information technology much more energy-efficient. Several speakers at the workshop focused on the materials and components behind the latter.Key to everything they discussed: adding photonics, or using light to carry information, to the well-established electronics behind today’s microchips. “The bottom line is that integrating photonics with electronics in the same package is the transistor for the 21st century. If we can’t figure out how to do that, then we’re not going to be able to scale forward,” said Kimerling, who is director of the MIT Microphotonics Center.MIT has long been a leader in the integration of photonics with electronics. For example, Kimerling described the Integrated Photonics System Roadmap – International (IPSR-I), a global network of more than 400 industrial and R&D partners working together to define and create photonic integrated circuit technology. IPSR-I is led by the MIT Microphotonics Center and PhotonDelta. Kimerling began the organization in 1997.Last year IPSR-I released its latest roadmap for photonics-electronics integration, “which  outlines a clear way forward and specifies an innovative learning curve for scaling performance and applications for the next 15 years,” Kimerling said.Another major MIT program focused on the future of the microchip industry is FUTUR-IC, a new global alliance for sustainable microchip manufacturing. Begun last year, FUTUR-IC is funded by the National Science Foundation.“Our goal is to build a resource-efficient microchip industry value chain,” said Anuradha Murthy Agarwal, a principal research scientist at the MRL and leader of FUTUR-IC. That includes all of the elements that go into manufacturing future microchips, including workforce education and techniques to mitigate potential environmental effects.FUTUR-IC is also focused on electronic-photonic integration. “My mantra is to use electronics for computation, [and] shift to photonics for communication to bring this energy crisis in control,” Agarwal said.But integrating electronic chips with photonic chips is not easy. To that end, Agarwal described some of the challenges involved. For example, currently it is difficult to connect the optical fibers carrying communications to a microchip. That’s because the alignment between the two must be almost perfect or the light will disperse. And the dimensions involved are minuscule. An optical fiber has a diameter of only millionths of a meter. As a result, today each connection must be actively tested with a laser to ensure that the light will come through.That said, Agarwal went on to describe a new coupler between the fiber and chip that could solve the problem and allow robots to passively assemble the chips (no laser needed). The work, which was conducted by researchers including MIT graduate student Drew Wenninger, Agarwal, and Kimerling, has been patented, and is reported in two papers. A second recent breakthrough in this area involving a printed micro-reflector was described by Juejun “JJ” Hu, John F. Elliott Professor of Materials Science and Engineering.FUTUR-IC is also leading educational efforts for training a future workforce, as well as techniques for detecting — and potentially destroying — the perfluroalkyls (PFAS, or “forever chemicals”) released during microchip manufacturing. FUTUR-IC educational efforts, including virtual reality and game-based learning, were described by Sajan Saini, education director for FUTUR-IC. PFAS detection and remediation were discussed by Aristide Gumyusenge, an assistant professor in DMSE, and Jesus Castro Esteban, a postdoc in the Department of Chemistry.Other presenters at the workshop included Antoine Allanore, the Heather N. Lechtman Professor of Materials Science and Engineering; Katrin Daehn, a postdoc in the Allanore lab; Xuanhe Zhao, the Uncas (1923) and Helen Whitaker Professor in the Department of Mechanical Engineering; Richard Otte, CEO of Promex; and Carl Thompson, the Stavros V. Salapatas Professor in Materials Science and Engineering. More

  • in

    J-WAFS: Supporting food and water research across MIT

    MIT’s Abdul Latif Jameel Water and Food Systems Lab (J-WAFS) has transformed the landscape of water and food research at MIT, driving faculty engagement and catalyzing new research and innovation in these critical areas. With philanthropic, corporate, and government support, J-WAFS’ strategic approach spans the entire research life cycle, from support for early-stage research to commercialization grants for more advanced projects.Over the past decade, J-WAFS has invested approximately $25 million in direct research funding to support MIT faculty pursuing transformative research with the potential for significant impact. “Since awarding our first cohort of seed grants in 2015, it’s remarkable to look back and see that over 10 percent of the MIT faculty have benefited from J-WAFS funding,” observes J-WAFS Executive Director Renee J. Robins ’83. “Many of these professors hadn’t worked on water or food challenges before their first J-WAFS grant.” By fostering interdisciplinary collaborations and supporting high-risk, high-reward projects, J-WAFS has amplified the capacity of MIT faculty to pursue groundbreaking research that addresses some of the world’s most pressing challenges facing our water and food systems.Drawing MIT faculty to water and food researchJ-WAFS open calls for proposals enable faculty to explore bold ideas and develop impactful approaches to tackling critical water and food system challenges. Professor Patrick Doyle’s work in water purification exemplifies this impact. “Without J-WAFS, I would have never ventured into the field of water purification,” Doyle reflects. While previously focused on pharmaceutical manufacturing and drug delivery, exposure to J-WAFS-funded peers led him to apply his expertise in soft materials to water purification. “Both the funding and the J-WAFS community led me to be deeply engaged in understanding some of the key challenges in water purification and water security,” he explains.Similarly, Professor Otto Cordero of the Department of Civil and Environmental Engineering (CEE) leveraged J-WAFS funding to pivot his research into aquaculture. Cordero explains that his first J-WAFS seed grant “has been extremely influential for my lab because it allowed me to take a step in a new direction, with no preliminary data in hand.” Cordero’s expertise is in microbial communities. He was previous unfamiliar with aquaculture, but he saw the relevance of microbial communities the health of farmed aquatic organisms.Supporting early-career facultyNew assistant professors at MIT have particularly benefited from J-WAFS funding and support. J-WAFS has played a transformative role in shaping the careers and research trajectories of many new faculty members by encouraging them to explore novel research areas, and in many instances providing their first MIT research grant.Professor Ariel Furst reflects on how pivotal J-WAFS’ investment has been in advancing her research. “This was one of the first grants I received after starting at MIT, and it has truly shaped the development of my group’s research program,” Furst explains. With J-WAFS’ backing, her lab has achieved breakthroughs in chemical detection and remediation technologies for water. “The support of J-WAFS has enabled us to develop the platform funded through this work beyond the initial applications to the general detection of environmental contaminants and degradation of those contaminants,” she elaborates. Karthish Manthiram, now a professor of chemical engineering and chemistry at Caltech, explains how J-WAFS’ early investment enabled him and other young faculty to pursue ambitious ideas. “J-WAFS took a big risk on us,” Manthiram reflects. His research on breaking the nitrogen triple bond to make ammonia for fertilizer was initially met with skepticism. However, J-WAFS’ seed funding allowed his lab to lay the groundwork for breakthroughs that later attracted significant National Science Foundation (NSF) support. “That early funding from J-WAFS has been pivotal to our long-term success,” he notes. These stories underscore the broad impact of J-WAFS’ support for early-career faculty, and its commitment to empowering them to address critical global challenges and innovate boldly.Fueling follow-on funding J-WAFS seed grants enable faculty to explore nascent research areas, but external funding for continued work is usually necessary to achieve the full potential of these novel ideas. “It’s often hard to get funding for early stage or out-of-the-box ideas,” notes J-WAFS Director Professor John H. Lienhard V. “My hope, when I founded J-WAFS in 2014, was that seed grants would allow PIs [principal investigators] to prove out novel ideas so that they would be attractive for follow-on funding. And after 10 years, J-WAFS-funded research projects have brought more than $21 million in subsequent awards to MIT.”Professor Retsef Levi led a seed study on how agricultural supply chains affect food safety, with a team of faculty spanning the MIT schools Engineering and Science as well as the MIT Sloan School of Management. The team parlayed their seed grant research into a multi-million-dollar follow-on initiative. Levi reflects, “The J-WAFS seed funding allowed us to establish the initial credibility of our team, which was key to our success in obtaining large funding from several other agencies.”Dave Des Marais was an assistant professor in the Department of CEE when he received his first J-WAFS seed grant. The funding supported his research on how plant growth and physiology are controlled by genes and interact with the environment. The seed grant helped launch his lab’s work addressing enhancing climate change resilience in agricultural systems. The work led to his Faculty Early Career Development (CAREER) Award from the NSF, a prestigious honor for junior faculty members. Now an associate professor, Des Marais’ ongoing project to further investigate the mechanisms and consequences of genomic and environmental interactions is supported by the five-year, $1,490,000 NSF grant. “J-WAFS providing essential funding to get my new research underway,” comments Des Marais.Stimulating interdisciplinary collaborationDes Marais’ seed grant was also key to developing new collaborations. He explains, “the J-WAFS grant supported me to develop a collaboration with Professor Caroline Uhler in EECS/IDSS [the Department of Electrical Engineering and Computer Science/Institute for Data, Systems, and Society] that really shaped how I think about framing and testing hypotheses. One of the best things about J-WAFS is facilitating unexpected connections among MIT faculty with diverse yet complementary skill sets.”Professors A. John Hart of the Department of Mechanical Engineering and Benedetto Marelli of CEE also launched a new interdisciplinary collaboration with J-WAFS funding. They partnered to join expertise in biomaterials, microfabrication, and manufacturing, to create printed silk-based colorimetric sensors that detect food spoilage. “The J-WAFS Seed Grant provided a unique opportunity for multidisciplinary collaboration,” Hart notes.Professors Stephen Graves in the MIT Sloan School of Management and Bishwapriya Sanyal in the Department of Urban Studies and Planning (DUSP) partnered to pursue new research on agricultural supply chains. With field work in Senegal, their J-WAFS-supported project brought together international development specialists and operations management experts to study how small firms and government agencies influence access to and uptake of irrigation technology by poorer farmers. “We used J-WAFS to spur a collaboration that would have been improbable without this grant,” they explain. Being part of the J-WAFS community also introduced them to researchers in Professor Amos Winter’s lab in the Department of Mechanical Engineering working on irrigation technologies for low-resource settings. DUSP doctoral candidate Mark Brennan notes, “We got to share our understanding of how irrigation markets and irrigation supply chains work in developing economies, and then we got to contrast that with their understanding of how irrigation system models work.”Timothy Swager, professor of chemistry, and Rohit Karnik, professor of mechanical engineering and J-WAFS associate director, collaborated on a sponsored research project supported by Xylem, Inc. through the J-WAFS Research Affiliate program. The cross-disciplinary research, which targeted the development of ultra-sensitive sensors for toxic PFAS chemicals, was conceived following a series of workshops hosted by J-WAFS. Swager and Karnik were two of the participants, and their involvement led to the collaborative proposal that Xylem funded. “J-WAFS funding allowed us to combine Swager lab’s expertise in sensing with my lab’s expertise in microfluidics to develop a cartridge for field-portable detection of PFAS,” says Karnik. “J-WAFS has enriched my research program in so many ways,” adds Swager, who is now working to commercialize the technology.Driving global collaboration and impactJ-WAFS has also helped MIT faculty establish and advance international collaboration and impactful global research. By funding and supporting projects that connect MIT researchers with international partners, J-WAFS has not only advanced technological solutions, but also strengthened cross-cultural understanding and engagement.Professor Matthew Shoulders leads the inaugural J-WAFS Grand Challenge project. In response to the first J-WAFS call for “Grand Challenge” proposals, Shoulders assembled an interdisciplinary team based at MIT to enhance and provide climate resilience to agriculture by improving the most inefficient aspect of photosynthesis, the notoriously-inefficient carbon dioxide-fixing plant enzyme RuBisCO. J-WAFS funded this high-risk/high-reward project following a competitive process that engaged external reviewers through a several rounds of iterative proposal development. The technical feedback to the team led them to researchers with complementary expertise from the Australian National University. “Our collaborative team of biochemists and synthetic biologists, computational biologists, and chemists is deeply integrated with plant biologists and field trial experts, yielding a robust feedback loop for enzyme engineering,” Shoulders says. “Together, this team will be able to make a concerted effort using the most modern, state-of-the-art techniques to engineer crop RuBisCO with an eye to helping make meaningful gains in securing a stable crop supply, hopefully with accompanying improvements in both food and water security.”Professor Leon Glicksman and Research Engineer Eric Verploegen’s team designed a low-cost cooling chamber to preserve fruits and vegetables harvested by smallholder farmers with no access to cold chain storage. J-WAFS’ guidance motivated the team to prioritize practical considerations informed by local collaborators, ensuring market competitiveness. “As our new idea for a forced-air evaporative cooling chamber was taking shape, we continually checked that our solution was evolving in a direction that would be competitive in terms of cost, performance, and usability to existing commercial alternatives,” explains Verploegen. Following the team’s initial seed grant, the team secured a J-WAFS Solutions commercialization grant, which Verploegen say “further motivated us to establish partnerships with local organizations capable of commercializing the technology earlier in the project than we might have done otherwise.” The team has since shared an open-source design as part of its commercialization strategy to maximize accessibility and impact.Bringing corporate sponsored research opportunities to MIT facultyJ-WAFS also plays a role in driving private partnerships, enabling collaborations that bridge industry and academia. Through its Research Affiliate Program, for example, J-WAFS provides opportunities for faculty to collaborate with industry on sponsored research, helping to convert scientific discoveries into licensable intellectual property (IP) that companies can turn into commercial products and services.J-WAFS introduced professor of mechanical engineering Alex Slocum to a challenge presented by its research affiliate company, Xylem: how to design a more energy-efficient pump for fluctuating flows. With centrifugal pumps consuming an estimated 6 percent of U.S. electricity annually, Slocum and his then-graduate student Hilary Johnson SM ’18, PhD ’22 developed an innovative variable volute mechanism that reduces energy usage. “Xylem envisions this as the first in a new category of adaptive pump geometry,” comments Johnson. The research produced a pump prototype and related IP that Xylem is working on commercializing. Johnson notes that these outcomes “would not have been possible without J-WAFS support and facilitation of the Xylem industry partnership.” Slocum adds, “J-WAFS enabled Hilary to begin her work on pumps, and Xylem sponsored the research to bring her to this point … where she has an opportunity to do far more than the original project called for.”Swager speaks highly of the impact of corporate research sponsorship through J-WAFS on his research and technology translation efforts. His PFAS project with Karnik described above was also supported by Xylem. “Xylem was an excellent sponsor of our research. Their engagement and feedback were instrumental in advancing our PFAS detection technology, now on the path to commercialization,” Swager says.Looking forwardWhat J-WAFS has accomplished is more than a collection of research projects; a decade of impact demonstrates how J-WAFS’ approach has been transformative for many MIT faculty members. As Professor Mathias Kolle puts it, his engagement with J-WAFS “had a significant influence on how we think about our research and its broader impacts.” He adds that it “opened my eyes to the challenges in the field of water and food systems and the many different creative ideas that are explored by MIT.” This thriving ecosystem of innovation, collaboration, and academic growth around water and food research has not only helped faculty build interdisciplinary and international partnerships, but has also led to the commercialization of transformative technologies with real-world applications. C. Cem Taşan, the POSCO Associate Professor of Metallurgy who is leading a J-WAFS Solutions commercialization team that is about to launch a startup company, sums it up by noting, “Without J-WAFS, we wouldn’t be here at all.”  As J-WAFS looks to the future, its continued commitment — supported by the generosity of its donors and partners — builds on a decade of success enabling MIT faculty to advance water and food research that addresses some of the world’s most pressing challenges. More

  • in

    For clean ammonia, MIT engineers propose going underground

    Ammonia is the most widely produced chemical in the world today, used primarily as a source for nitrogen fertilizer. Its production is also a major source of greenhouse gas emissions — the highest in the whole chemical industry.Now, a team of researchers at MIT has developed an innovative way of making ammonia without the usual fossil-fuel-powered chemical plants that require high heat and pressure. Instead, they have found a way to use the Earth itself as a geochemical reactor, producing ammonia underground. The processes uses Earth’s naturally occurring heat and pressure, provided free of charge and free of emissions, as well as the reactivity of minerals already present in the ground.The trick the team devised is to inject water underground, into an area of iron-rich subsurface rock. The water carries with it a source of nitrogen and particles of a metal catalyst, allowing the water to react with the iron to generate clean hydrogen, which in turn reacts with the nitrogen to make ammonia. A second well is then used to pump that ammonia up to the surface.The process, which has been demonstrated in the lab but not yet in a natural setting, is described today in the journal Joule. The paper’s co-authors are MIT professors of materials science and engineering Iwnetim Abate and Ju Li, graduate student Yifan Gao, and five others at MIT.“When I first produced ammonia from rock in the lab, I was so excited,” Gao recalls. “I realized this represented an entirely new and never-reported approach to ammonia synthesis.’”The standard method for making ammonia is called the Haber-Bosch process, which was developed in Germany in the early 20th century to replace natural sources of nitrogen fertilizer such as mined deposits of bat guano, which were becoming depleted. But the Haber-Bosch process is very energy intensive: It requires temperatures of 400 degrees Celsius and pressures of 200 atmospheres, and this means it needs huge installations in order to be efficient. Some areas of the world, such as sub-Saharan Africa and Southeast Asia, have few or no such plants in operation.  As a result, the shortage or extremely high cost of fertilizer in these regions has limited their agricultural production.The Haber-Bosch process “is good. It works,” Abate says. “Without it, we wouldn’t have been able to feed 2 out of the total 8 billion people in the world right now, he says, referring to the portion of the world’s population whose food is grown with ammonia-based fertilizers. But because of the emissions and energy demands, a better process is needed, he says.Burning fuel to generate heat is responsible for about 20 percent of the greenhouse gases emitted from plants using the Haber-Bosch process. Making hydrogen accounts for the remaining 80 percent.  But ammonia, the molecule NH3, is made up only of nitrogen and hydrogen. There’s no carbon in the formula, so where do the carbon emissions come from? The standard way of producing the needed hydrogen is by processing methane gas with steam, breaking down the gas into pure hydrogen, which gets used, and carbon dioxide gas that gets released into the air.Other processes exist for making low- or no-emissions hydrogen, such as by using solar or wind-generated electricity to split water into oxygen and hydrogen, but that process can be expensive. That’s why Abate and his team worked on developing a system to produce what they call geological hydrogen. Some places in the world, including some in Africa, have been found to naturally generate hydrogen underground through chemical reactions between water and iron-rich rocks. These pockets of naturally occurring hydrogen can be mined, just like natural methane reservoirs, but the extent and locations of such deposits are still relatively unexplored.Abate realized this process could be created or enhanced by pumping water, laced with copper and nickel catalyst particles to speed up the process, into the ground in places where such iron-rich rocks were already present. “We can use the Earth as a factory to produce clean flows of hydrogen,” he says.He recalls thinking about the problem of the emissions from hydrogen production for ammonia: “The ‘aha!’ moment for me was thinking, how about we link this process of geological hydrogen production with the process of making Haber-Bosch ammonia?”That would solve the biggest problem of the underground hydrogen production process, which is how to capture and store the gas once it’s produced. Hydrogen is a very tiny molecule — the smallest of them all — and hard to contain. But by implementing the entire Haber-Bosch process underground, the only material that would need to be sent to the surface would be the ammonia itself, which is easy to capture, store, and transport.The only extra ingredient needed to complete the process was the addition of a source of nitrogen, such as nitrate or nitrogen gas, into the water-catalyst mixture being injected into the ground. Then, as the hydrogen gets released from water molecules after interacting with the iron-rich rocks, it can immediately bond with the nitrogen atoms also carried in the water, with the deep underground environment providing the high temperatures and pressures required by the Haber-Bosch process. A second well near the injection well then pumps the ammonia out and into tanks on the surface.“We call this geological ammonia,” Abate says, “because we are using subsurface temperature, pressure, chemistry, and geologically existing rocks to produce ammonia directly.”Whereas transporting hydrogen requires expensive equipment to cool and liquefy it, and virtually no pipelines exist for its transport (except near oil refinery sites), transporting ammonia is easier and cheaper. It’s about one-sixth the cost of transporting hydrogen, and there are already more than 5,000 miles of ammonia pipelines and 10,000 terminals in place in the U.S. alone. What’s more, Abate explains, ammonia, unlike hydrogen, already has a substantial commercial market in place, with production volume projected to grow by two to three times by 2050, as it is used not only for fertilizer but also as feedstock for a wide variety of chemical processes.For example, ammonia can be burned directly in gas turbines, engines, and industrial furnaces, providing a carbon-free alternative to fossil fuels. It is being explored for maritime shipping and aviation as an alternative fuel, and as a possible space propellant.Another upside to geological ammonia is that untreated wastewater, including agricultural runoff, which tends to be rich in nitrogen already, could serve as the water source and be treated in the process. “We can tackle the problem of treating wastewater, while also making something of value out of this waste,” Abate says.Gao adds that this process “involves no direct carbon emissions, presenting a potential pathway to reduce global CO2 emissions by up to 1 percent.” To arrive at this point, he says, the team “overcame numerous challenges and learned from many failed attempts. For example, we tested a wide range of conditions and catalysts before identifying the most effective one.”The project was seed-funded under a flagship project of MIT’s Climate Grand Challenges program, the Center for the Electrification and Decarbonization of Industry. Professor Yet-Ming Chiang, co-director of the center, says “I don’t think there’s been any previous example of deliberately using the Earth as a chemical reactor. That’s one of the key novel points of this approach.”  Chiang emphasizes that even though it is a geological process, it happens very fast, not on geological timescales. “The reaction is fundamentally over in a matter of hours,” he says. “The reaction is so fast that this answers one of the key questions: Do you have to wait for geological times? And the answer is absolutely no.”Professor Elsa Olivetti, a mission director of the newly established Climate Project at MIT, says, “The creative thinking by this team is invaluable to MIT’s ability to have impact at scale. Coupling these exciting results with, for example, advanced understanding of the geology surrounding hydrogen accumulations represent the whole-of-Institute efforts the Climate Project aims to support.”“This is a significant breakthrough for the future of sustainable development,” says Geoffrey Ellis, a geologist at the U.S. Geological Survey, who was not associated with this work. He adds, “While there is clearly more work that needs to be done to validate this at the pilot stage and to get this to the commercial scale, the concept that has been demonstrated is truly transformative.  The approach of engineering a system to optimize the natural process of nitrate reduction by Fe2+ is ingenious and will likely lead to further innovations along these lines.”The initial work on the process has been done in the laboratory, so the next step will be to prove the process using a real underground site. “We think that kind of experiment can be done within the next one to two years,” Abate says. This could open doors to using a similar approach for other chemical production processes, he adds.The team has applied for a patent and aims to work towards bringing the process to market.“Moving forward,” Gao says, “our focus will be on optimizing the process conditions and scaling up tests, with the goal of enabling practical applications for geological ammonia in the near future.”The research team also included Ming Lei, Bachu Sravan Kumar, Hugh Smith, Seok Hee Han, and Lokesh Sangabattula, all at MIT. Additional funding was provided by the National Science Foundation and was carried out, in part, through the use of MIT.nano facilities. More