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      A lasting — and valuable — legacy

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      Betar Gallant, MIT associate professor and Class of 1922 Career Development Chair in Mechanical Engineering, grew up in a curious, independently minded family. Her mother had multiple jobs over the years, including in urban planning and in the geospatial field. Her father, although formally trained in English, read textbooks of all kinds from cover to cover, taught himself numerous technical fields including engineering, and worked successfully in them. When Gallant was very young, she and her father did science experiments in the basement.

      It wasn’t until she was in her teenage years, though, that she says she got drawn into science. Her father, who had fallen ill five years before, died when Gallant was 16, and while grieving, “when I was missing him the most,” she started to look at what had captivated her father.

      “I started to take a deeper interest in the things he had spent his life working on as a way to feel closer to him in his absence,” Gallant says. “I spent a few long months one summer looking through some of the things he had worked on, and found myself reading physics textbooks. That was enough, and I was hooked.”

      The love for independently finding and understanding solutions, that she had apparently inherited from her parents, eventually took her to the professional love of her life: electrochemistry.

      As an undergraduate at MIT, Gallant did an Undergraduate Research Opportunities Program project with Professor Yang Shao-Horn’s research group that went from her sophomore year through her senior thesis. This was Gallant’s first official exposure to electrochemistry.

      “When I met Yang, she showed me very quickly how challenging and enriching electrochemistry can be, and there was real conviction and excitement in how she and her group members talked about research,” Gallant says. “It was totally eye-opening, and I’m fortunate that she was a (relatively rare) electrochemist in a mechanical engineering department, or else I likely would not have been able to go down that road.”

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      Gallant earned three degrees at MIT (’08, SM ’10, and PhD ’13). Before joining the MIT faculty in 2016, she was a Kavli Nanoscience Institute Prize Postdoctoral Fellow at Caltech in the Division of Chemistry and Chemical Engineering.

      Her passion for electrochemistry is enormous. “Electrons are just dazzling — they power so much of our everyday world, and are the key to a renewable future,” she says, explaining that despite electrons’ amazing potential, isolated electrons cannot be stored and produced on demand, because “nature doesn’t allow excessive amounts of charge imbalances to accumulate.”

      Electrons can, however, be stored on molecules, in bonds and in metal ions or nonmetal centers that are able to lose and gain electrons — as long as positive charge transfers occur to accommodate the electrons.

      “Here’s where chemistry rears its head,” Gallant says. “What types of molecules or materials can behave in this way? How do we store as much charge as possible while making the weight and volume as low as possible?”

      Gallant points out that early battery developers using lithium and ions built a technology that “has arguably shaped our modern world more than any other.

      “If you look at some early papers, the concepts of how a lithium-ion battery or a lithium metal anode worked were sketched out by hand — they had been deduced to be true, before the field even had the tools to prove all the mechanisms were actually occurring — yet even now, those ideas are still turning out to be right!”

      Gallant says, “that’s because if you truly understand the basic principles of electrochemistry, you can start to intuit how systems will behave. Once you can do that, you can really begin to engineer better materials and devices.”

      Truly her father’s daughter, Gallant’s emphasis is on independently finding solutions.

      “Ultimately, it’s a race to have the best mental models,” she says. “A great lab and lots of funding and personnel to run it are very nice, but the most valuable tools in the toolbox are solid mental models and a way of thinking about electrochemistry, which is actually very personalized depending on the researcher.”

      She says one project with immediate impact that’s coming out of her Gallant Energy and Carbon Conversion Lab relates to primary (non-rechargeable) battery work that she and her team are working to commercialize. It involves injecting new electrochemically active electrolytes into leading high-energy batteries as they’re being assembled. Replacing a conventional electrolyte with the new chemistry decreases the normally inactive weight of the battery and boosts the energy substantially, Gallant says. One important application of such batteries would be for medical devices such as pacemakers.

      “If you can extend lifetime, you’re talking about longer times between invasive replacement surgeries, which really affects patient quality of life,” she says.

      Gallant’s team is also leading efforts to enable higher-energy rechargeable lithium-ion batteries for electric vehicles. Key to a step-change in energy, and therefore driving range, is to use a lithium metal anode in place of graphite. Lithium metal is highly reactive, however, with all battery electrolytes, and its interface needs to be stabilized in ways that still elude researchers. Gallant’s team is developing design guidelines for such interfaces, and for next-generation electrolytes to form and sustain these interfaces. Gallant says that applying the technology to that purpose and commercializing it would be “a bit longer-term, but I believe this change to lithium anodes will happen, and it’s just a matter of when.”

      About six years ago, when Gallant founded her lab, she and her team started introducing carbon dioxide into batteries as a way to experiment with electrochemical conversion of the greenhouse gas. She says they realized that batteries do not present the best practical technology to mitigate CO2, but their experimentation did open up new paths to carbon capture and conversion. “That work allowed us to think creatively, and we started to realize that there is tremendous potential to manipulate CO2 reactions by carefully designing the electrochemical environment.” That led her team to the idea of conducting electrochemical transformations on CO2 from a captured state bound to a capture sorbent, replacing the energy-intense regeneration step of today’s capture processes and streamlining the process.  

      “Now we’re seeing other researchers working on that, too, and taking this idea in exciting directions — it’s a very challenging and very rich topic,” she says.

      Gallant has won awards including an MIT Bose Fellowship, the Army Research Office Young Investigator Award, the Scialog Fellowship in Energy Storage and in Negative Emissions Science, a CAREER award from the National Science Foundation, the Ruth and Joel Spira Award for Distinguished Teaching at MIT, the Electrochemical Society (ECS) Battery Division Early Career award, and an ECS-Toyota Young Investigator Award.

      These days, Gallant does some of her best thinking while brainstorming with her research group members and with her husband, who is also an academic. She says being a professor at MIT means she has “a queue of things to think about,” but she sometimes gets awarded with a revelation.

      “My brain gets overloaded because I can’t think through everything instantaneously; ideas have to get in line! So there’s a lot going on in the background at all times,” she say. “I don’t know how it works, but sometimes I’ll be going for a walk or doing something else, and an idea breaks through. Those are the fun ones.” More

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      A simple way to significantly increase lifetimes of fuel cells and other devices

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      In research that could jump-start work on a range of technologies including fuel cells, which are key to storing solar and wind energy, MIT researchers have found a relatively simple way to increase the lifetimes of these devices: changing the pH of the system.

      Fuel and electrolysis cells made of materials known as solid metal oxides are of interest for several reasons. For example, in the electrolysis mode, they are very efficient at converting electricity from a renewable source into a storable fuel like hydrogen or methane that can be used in the fuel cell mode to generate electricity when the sun isn’t shining or the wind isn’t blowing. They can also be made without using costly metals like platinum. However, their commercial viability has been hampered, in part, because they degrade over time. Metal atoms seeping from the interconnects used to construct banks of fuel/electrolysis cells slowly poison the devices.

      “What we’ve been able to demonstrate is that we can not only reverse that degradation, but actually enhance the performance above the initial value by controlling the acidity of the air-electrode interface,” says Harry L. Tuller, the R.P. Simmons Professor of Ceramics and Electronic Materials in MIT’s Department of Materials Science and Engineering (DMSE).

      The research, initially funded by the U.S. Department of Energy through the Office of Fossil Energy and Carbon Management’s (FECM) National Energy Technology Laboratory, should help the department meet its goal of significantly cutting the degradation rate of solid oxide fuel cells by 2035 to 2050.

      “Extending the lifetime of solid oxide fuels cells helps deliver the low-cost, high-efficiency hydrogen production and power generation needed for a clean energy future,” says Robert Schrecengost, acting director of FECM’s Division of Hydrogen with Carbon Management. “The department applauds these advancements to mature and ultimately commercialize these technologies so that we can provide clean and reliable energy for the American people.”

      “I’ve been working in this area my whole professional life, and what I’ve seen until now is mostly incremental improvements,” says Tuller, who was recently named a 2022 Materials Research Society Fellow for his career-long work in solid-state chemistry and electrochemistry. “People are normally satisfied with seeing improvements by factors of tens-of-percent. So, actually seeing much larger improvements and, as importantly, identifying the source of the problem and the means to work around it, issues that we’ve been struggling with for all these decades, is remarkable.”

      Says James M. LeBeau, the John Chipman Associate Professor of Materials Science and Engineering at MIT, who was also involved in the research, “This work is important because it could overcome [some] of the limitations that have prevented the widespread use of solid oxide fuel cells. Additionally, the basic concept can be applied to many other materials used for applications in the energy-related field.”

      A report describing the work was reported Aug. 11, in Energy & Environmental Science. Additional authors of the paper are Han Gil Seo, a DMSE postdoc; Anna Staerz, formerly a DMSE postdoc, now at Interuniversity Microelectronics Centre (IMEC) Belgium and soon to join the Colorado School of Mines faculty; Dennis S. Kim, a DMSE postdoc; Dino Klotz, a DMSE visiting scientist, now at Zurich Instruments; Michael Xu, a DMSE graduate student; and Clement Nicollet, formerly a DMSE postdoc, now at the Université de Nantes. Seo and Staerz contributed equally to the work.

      Changing the acidity

      A fuel/electrolysis cell has three principal parts: two electrodes (a cathode and anode) separated by an electrolyte. In the electrolysis mode, electricity from, say, the wind, can be used to generate storable fuel like methane or hydrogen. On the other hand, in the reverse fuel cell reaction, that storable fuel can be used to create electricity when the wind isn’t blowing.

      A working fuel/electrolysis cell is composed of many individual cells that are stacked together and connected by steel metal interconnects that include the element chrome to keep the metal from oxidizing. But “it turns out that at the high temperatures that these cells run, some of that chrome evaporates and migrates to the interface between the cathode and the electrolyte, poisoning the oxygen incorporation reaction,” Tuller says. After a certain point, the efficiency of the cell has dropped to a point where it is not worth operating any longer.

      “So if you can extend the life of the fuel/electrolysis cell by slowing down this process, or ideally reversing it, you could go a long way towards making it practical,” Tuller says.

      The team showed that you can do both by controlling the acidity of the cathode surface. They also explained what is happening.

      To achieve their results, the team coated the fuel/electrolysis cell cathode with lithium oxide, a compound that changes the relative acidity of the surface from being acidic to being more basic. “After adding a small amount of lithium, we were able to recover the initial performance of a poisoned cell,” Tuller says. When the engineers added even more lithium, the performance improved far beyond the initial value. “We saw improvements of three to four orders of magnitude in the key oxygen reduction reaction rate and attribute the change to populating the surface of the electrode with electrons needed to drive the oxygen incorporation reaction.”

      The engineers went on to explain what is happening by observing the material at the nanoscale, or billionths of a meter, with state-of-the-art transmission electron microscopy and electron energy loss spectroscopy at MIT.nano. “We were interested in understanding the distribution of the different chemical additives [chromium and lithium oxide] on the surface,” says LeBeau.

      They found that the lithium oxide effectively dissolves the chromium to form a glassy material that no longer serves to degrade the cathode performance.

      Applications for sensors, catalysts, and more

      Many technologies like fuel cells are based on the ability of the oxide solids to rapidly breathe oxygen in and out of their crystalline structures, Tuller says. The MIT work essentially shows how to recover — and speed up — that ability by changing the surface acidity. As a result, the engineers are optimistic that the work could be applied to other technologies including, for example, sensors, catalysts, and oxygen permeation-based reactors.

      The team is also exploring the effect of acidity on systems poisoned by different elements, like silica.

      Concludes Tuller: “As is often the case in science, you stumble across something and notice an important trend that was not appreciated previously. Then you test that concept further, and you discover that it is really very fundamental.”

      In addition to the DOE, this work was also funded by the National Research Foundation of Korea, the MIT Department of Materials Science and Engineering via Tuller’s appointment as the R.P. Simmons Professor of Ceramics and Electronic Materials, and the U.S. Air Force Office of Scientific Research. More

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      in Energy

      A new concept for low-cost batteries

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      As the world builds out ever larger installations of wind and solar power systems, the need is growing fast for economical, large-scale backup systems to provide power when the sun is down and the air is calm. Today’s lithium-ion batteries are still too expensive for most such applications, and other options such as pumped hydro require specific topography that’s not always available.

      Now, researchers at MIT and elsewhere have developed a new kind of battery, made entirely from abundant and inexpensive materials, that could help to fill that gap.

      The new battery architecture, which uses aluminum and sulfur as its two electrode materials, with a molten salt electrolyte in between, is described today in the journal Nature, in a paper by MIT Professor Donald Sadoway, along with 15 others at MIT and in China, Canada, Kentucky, and Tennessee.

      “I wanted to invent something that was better, much better, than lithium-ion batteries for small-scale stationary storage, and ultimately for automotive [uses],” explains Sadoway, who is the John F. Elliott Professor Emeritus of Materials Chemistry.

      In addition to being expensive, lithium-ion batteries contain a flammable electrolyte, making them less than ideal for transportation. So, Sadoway started studying the periodic table, looking for cheap, Earth-abundant metals that might be able to substitute for lithium. The commercially dominant metal, iron, doesn’t have the right electrochemical properties for an efficient battery, he says. But the second-most-abundant metal in the marketplace — and actually the most abundant metal on Earth — is aluminum. “So, I said, well, let’s just make that a bookend. It’s gonna be aluminum,” he says.

      Then came deciding what to pair the aluminum with for the other electrode, and what kind of electrolyte to put in between to carry ions back and forth during charging and discharging. The cheapest of all the non-metals is sulfur, so that became the second electrode material. As for the electrolyte, “we were not going to use the volatile, flammable organic liquids” that have sometimes led to dangerous fires in cars and other applications of lithium-ion batteries, Sadoway says. They tried some polymers but ended up looking at a variety of molten salts that have relatively low melting points — close to the boiling point of water, as opposed to nearly 1,000 degrees Fahrenheit for many salts. “Once you get down to near body temperature, it becomes practical” to make batteries that don’t require special insulation and anticorrosion measures, he says.

      The three ingredients they ended up with are cheap and readily available — aluminum, no different from the foil at the supermarket; sulfur, which is often a waste product from processes such as petroleum refining; and widely available salts. “The ingredients are cheap, and the thing is safe — it cannot burn,” Sadoway says.

      In their experiments, the team showed that the battery cells could endure hundreds of cycles at exceptionally high charging rates, with a projected cost per cell of about one-sixth that of comparable lithium-ion cells. They showed that the charging rate was highly dependent on the working temperature, with 110 degrees Celsius (230 degrees Fahrenheit) showing 25 times faster rates than 25 C (77 F).

      Surprisingly, the molten salt the team chose as an electrolyte simply because of its low melting point turned out to have a fortuitous advantage. One of the biggest problems in battery reliability is the formation of dendrites, which are narrow spikes of metal that build up on one electrode and eventually grow across to contact the other electrode, causing a short-circuit and hampering efficiency. But this particular salt, it happens, is very good at preventing that malfunction.

      The chloro-aluminate salt they chose “essentially retired these runaway dendrites, while also allowing for very rapid charging,” Sadoway says. “We did experiments at very high charging rates, charging in less than a minute, and we never lost cells due to dendrite shorting.”

      “It’s funny,” he says, because the whole focus was on finding a salt with the lowest melting point, but the catenated chloro-aluminates they ended up with turned out to be resistant to the shorting problem. “If we had started off with trying to prevent dendritic shorting, I’m not sure I would’ve known how to pursue that,” Sadoway says. “I guess it was serendipity for us.”

      What’s more, the battery requires no external heat source to maintain its operating temperature. The heat is naturally produced electrochemically by the charging and discharging of the battery. “As you charge, you generate heat, and that keeps the salt from freezing. And then, when you discharge, it also generates heat,” Sadoway says. In a typical installation used for load-leveling at a solar generation facility, for example, “you’d store electricity when the sun is shining, and then you’d draw electricity after dark, and you’d do this every day. And that charge-idle-discharge-idle is enough to generate enough heat to keep the thing at temperature.”

      This new battery formulation, he says, would be ideal for installations of about the size needed to power a single home or small to medium business, producing on the order of a few tens of kilowatt-hours of storage capacity.

      For larger installations, up to utility scale of tens to hundreds of megawatt hours, other technologies might be more effective, including the liquid metal batteries Sadoway and his students developed several years ago and which formed the basis for a spinoff company called Ambri, which hopes to deliver its first products within the next year. For that invention, Sadoway was recently awarded this year’s European Inventor Award.

      The smaller scale of the aluminum-sulfur batteries would also make them practical for uses such as electric vehicle charging stations, Sadoway says. He points out that when electric vehicles become common enough on the roads that several cars want to charge up at once, as happens today with gasoline fuel pumps, “if you try to do that with batteries and you want rapid charging, the amperages are just so high that we don’t have that amount of amperage in the line that feeds the facility.” So having a battery system such as this to store power and then release it quickly when needed could eliminate the need for installing expensive new power lines to serve these chargers.

      The new technology is already the basis for a new spinoff company called Avanti, which has licensed the patents to the system, co-founded by Sadoway and Luis Ortiz ’96 ScD ’00, who was also a co-founder of Ambri. “The first order of business for the company is to demonstrate that it works at scale,” Sadoway says, and then subject it to a series of stress tests, including running through hundreds of charging cycles.

      Would a battery based on sulfur run the risk of producing the foul odors associated with some forms of sulfur? Not a chance, Sadoway says. “The rotten-egg smell is in the gas, hydrogen sulfide. This is elemental sulfur, and it’s going to be enclosed inside the cells.” If you were to try to open up a lithium-ion cell in your kitchen, he says (and please don’t try this at home!), “the moisture in the air would react and you’d start generating all sorts of foul gases as well. These are legitimate questions, but the battery is sealed, it’s not an open vessel. So I wouldn’t be concerned about that.”

      The research team included members from Peking University, Yunnan University and the Wuhan University of Technology, in China; the University of Louisville, in Kentucky; the University of Waterloo, in Canada; Oak Ridge National Laboratory, in Tennessee; and MIT. The work was supported by the MIT Energy Initiative, the MIT Deshpande Center for Technological Innovation, and ENN Group. More

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      in Energy

      Building better batteries, faster

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      To help combat climate change, many car manufacturers are racing to add more electric vehicles in their lineups. But to convince prospective buyers, manufacturers need to improve how far these cars can go on a single charge. One of their main challenges? Figuring out how to make extremely powerful but lightweight batteries.

      Typically, however, it takes decades for scientists to thoroughly test new battery materials, says Pablo Leon, an MIT graduate student in materials science. To accelerate this process, Leon is developing a machine-learning tool for scientists to automate one of the most time-consuming, yet key, steps in evaluating battery materials.

      With his tool in hand, Leon plans to help search for new materials to enable the development of powerful and lightweight batteries. Such batteries would not only improve the range of EVs, but they could also unlock potential in other high-power systems, such as solar energy systems that continuously deliver power, even at night.

      From a young age, Leon knew he wanted to pursue a PhD, hoping to one day become a professor of engineering, like his father. Growing up in College Station, Texas, home to Texas A&M University, where his father worked, many of Leon’s friends also had parents who were professors or affiliated with the university. Meanwhile, his mom worked outside the university, as a family counselor in a neighboring city.

      In college, Leon followed in his father’s and older brother’s footsteps to become a mechanical engineer, earning his bachelor’s degree at Texas A&M. There, he learned how to model the behaviors of mechanical systems, such as a metal spring’s stiffness. But he wanted to delve deeper, down to the level of atoms, to understand exactly where these behaviors come from.

      So, when Leon applied to graduate school at MIT, he switched fields to materials science, hoping to satisfy his curiosity. But the transition to a different field was “a really hard process,” Leon says, as he rushed to catch up to his peers.

      To help with the transition, Leon sought out a congenial research advisor and found one in Rafael Gómez-Bombarelli, an assistant professor in the Department of Materials Science and Engineering (DMSE). “Because he’s from Spain and my parents are Peruvian, there’s a cultural ease with the way we talk,” Leon says. According to Gómez-Bombarelli, sometimes the two of them even discuss research in Spanish — a “rare treat.” That connection has empowered Leon to freely brainstorm ideas or talk through concerns with his advisor, enabling him to make significant progress in his research.

      Leveraging machine learning to research battery materials

      Scientists investigating new battery materials generally use computer simulations to understand how different combinations of materials perform. These simulations act as virtual microscopes for batteries, zooming in to see how materials interact at an atomic level. With these details, scientists can understand why certain combinations do better, guiding their search for high-performing materials.

      But building accurate computer simulations is extremely time-intensive, taking years and sometimes even decades. “You need to know how every atom interacts with every other atom in your system,” Leon says. To create a computer model of these interactions, scientists first make a rough guess at a model using complex quantum mechanics calculations. They then compare the model with results from real-life experiments, manually tweaking different parts of the model, including the distances between atoms and the strength of chemical bonds, until the simulation matches real life.

      With well-studied battery materials, the simulation process is somewhat easier. Scientists can buy simulation software that includes pre-made models, Leon says, but these models often have errors and still require additional tweaking.

      To build accurate computer models more quickly, Leon is developing a machine-learning-based tool that can efficiently guide the trial-and-error process. “The hope with our machine learning framework is to not have to rely on proprietary models or do any hand-tuning,” he says. Leon has verified that for well-studied materials, his tool is as accurate as the manual method for building models.

      With this system, scientists will have a single, standardized approach for building accurate models in lieu of the patchwork of approaches currently in place, Leon says.

      Leon’s tool comes at an opportune time, when many scientists are investigating a new paradigm of batteries: solid-state batteries. Compared to traditional batteries, which contain liquid electrolytes, solid-state batteries are safer, lighter, and easier to manufacture. But creating versions of these batteries that are powerful enough for EVs or renewable energy storage is challenging.

      This is largely because in battery chemistry, ions dislike flowing through solids and instead prefer liquids, in which atoms are spaced further apart. Still, scientists believe that with the right combination of materials, solid-state batteries can provide enough electricity for high-power systems, such as EVs. 

      Leon plans to use his machine-learning tool to help look for good solid-state battery materials more quickly. After he finds some powerful candidates in simulations, he’ll work with other scientists to test out the new materials in real-world experiments.

      Helping students navigate graduate school

      To get to where he is today, doing exciting and impactful research, Leon credits his community of family and mentors. Because of his upbringing, Leon knew early on which steps he would need to take to get into graduate school and work toward becoming a professor. And he appreciates the privilege of his position, even more so as a Peruvian American, given that many Latino students are less likely to have access to the same resources. “I understand the academic pipeline in a way that I think a lot of minority groups in academia don’t,” he says.

      Now, Leon is helping prospective graduate students from underrepresented backgrounds navigate the pipeline through the DMSE Application Assistance Program. Each fall, he mentors applicants for the DMSE PhD program at MIT, providing feedback on their applications and resumes. The assistance program is student-run and separate from the admissions process.

      Knowing firsthand how invaluable mentorship is from his relationship with his advisor, Leon is also heavily involved in mentoring junior PhD students in his department. This past year, he served as the academic chair on his department’s graduate student organization, the Graduate Materials Council. With MIT still experiencing disruptions from Covid-19, Leon noticed a problem with student cohesiveness. “I realized that traditional [informal] modes of communication across [incoming class] years had been cut off,” he says, making it harder for junior students to get advice from their senior peers. “They didn’t have any community to fall back on.”

      To help fix this problem, Leon served as a go-to mentor for many junior students. He helped second-year PhD students prepare for their doctoral qualification exam, an often-stressful rite of passage. He also hosted seminars for first-year students to teach them how to make the most of their classes and help them acclimate to the department’s fast-paced classes. For fun, Leon organized an axe-throwing event to further facilitate student cameraderie.

      Leon’s efforts were met with success. Now, “newer students are building back the community,” he says, “so I feel like I can take a step back” from being academic chair. He will instead continue mentoring junior students through other programs within the department. He also plans to extend his community-building efforts among faculty and students, facilitating opportunities for students to find good mentors and work on impactful research. With these efforts, Leon hopes to help others along the academic pipeline that he’s become familiar with, journeying together over their PhDs. More

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      Donald Sadoway wins European Inventor Award for liquid metal batteries

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      MIT Professor Donald Sadoway has won the 2022 European Inventor Award, in the category for Non-European Patent Office Countries, for his work on liquid metal batteries that could enable the long-term storage of renewable energy.

      Sadoway is the John F. Elliott Professor of Materials Chemistry in MIT’s Department of Materials Science and Engineering, and a longtime supporter and friend of the Materials Research Laboratory.

      “By enabling the large-scale storage of renewable energy, Donald Sadoway’s invention is a huge step towards the deployment of carbon-free electricity generation,” says António Campinos, president of the European Patent Office. “He has spent his career studying electrochemistry and has transformed this expertise into an invention that represents a huge step forward in the transition to green energy.”

      Sadoway was honored at the 2022 European Inventor Award ceremony on June 21. The award is one of Europe’s most prestigious innovation prizes and is presented annually to outstanding inventors from Europe and beyond who have made an exceptional contribution to society, technological progress, and economic growth.

      When accepting the award in Munich, Sadoway told the audience:

      “I am astonished. When I look at all the patented technologies that are represented at this event I see an abundance of excellence, all of them solutions to pressing problems. I wonder if the judges are assessing not only degrees of excellence but degrees of urgency. The liquid metal battery addresses an existential threat to the health of our atmosphere which is related to climate change.

      “By hosting this event the EPO celebrates invention. The thread that connects all the inventors is their efforts to make the world a better place. In my judgment there is no nobler pursuit. So perhaps this is a celebration of nobility.”

      Sadoway’s liquid metal batteries consist of three liquid layers of different densities, which naturally separate in the same way as oil and vinegar do in a salad dressing. The top and bottom layers are made from molten metals, with a middle layer of molten liquid salt.

      To keep the metals liquid, the batteries need to operate at extremely high temperatures, so Sadoway designed a system that is self-heating and insulated, requiring no external heating or cooling. They have a lifespan of more than 20 years, can maintain 99 percent of their capacity over 5,000 charging cycles, and have no combustible materials, meaning there is no fire risk.

      In 2010, with a patent for his invention and support from Bill Gates, Sadoway co-founded Ambri, based in Marlborough, Massachusetts just outside Boston, to develop a commercial product. The company will soon install a unit on a 3,700-acre development for a data center in Nevada. This battery will store energy from a reported 500 megawatts of on-site renewable generation, the same output as a natural gas power plant.

      Born in 1950 into a family of Ukrainian immigrants in Canada, Sadoway studied chemical metallurgy specializing in what he calls “extreme electrochemistry” — chemical reactions in molten salts and liquid metals that have been heated to over 500 degrees Celsius. After earning his BASc, MASc, and PhD, all from the University of Toronto, he joined the faculty at MIT in 1978. More

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      Energy storage important to creating affordable, reliable, deeply decarbonized electricity systems

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      In deeply decarbonized energy systems utilizing high penetrations of variable renewable energy (VRE), energy storage is needed to keep the lights on and the electricity flowing when the sun isn’t shining and the wind isn’t blowing — when generation from these VRE resources is low or demand is high. The MIT Energy Initiative’s Future of Energy Storage study makes clear the need for energy storage and explores pathways using VRE resources and storage to reach decarbonized electricity systems efficiently by 2050.

      “The Future of Energy Storage,” a new multidisciplinary report from the MIT Energy Initiative (MITEI), urges government investment in sophisticated analytical tools for planning, operation, and regulation of electricity systems in order to deploy and use storage efficiently. Because storage technologies will have the ability to substitute for or complement essentially all other elements of a power system, including generation, transmission, and demand response, these tools will be critical to electricity system designers, operators, and regulators in the future. The study also recommends additional support for complementary staffing and upskilling programs at regulatory agencies at the state and federal levels. 

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      Why is energy storage so important?

      The MITEI report shows that energy storage makes deep decarbonization of reliable electric power systems affordable. “Fossil fuel power plant operators have traditionally responded to demand for electricity — in any given moment — by adjusting the supply of electricity flowing into the grid,” says MITEI Director Robert Armstrong, the Chevron Professor of Chemical Engineering and chair of the Future of Energy Storage study. “But VRE resources such as wind and solar depend on daily and seasonal variations as well as weather fluctuations; they aren’t always available to be dispatched to follow electricity demand. Our study finds that energy storage can help VRE-dominated electricity systems balance electricity supply and demand while maintaining reliability in a cost-effective manner — that in turn can support the electrification of many end-use activities beyond the electricity sector.”

      The three-year study is designed to help government, industry, and academia chart a path to developing and deploying electrical energy storage technologies as a way of encouraging electrification and decarbonization throughout the economy, while avoiding excessive or inequitable burdens.

      Focusing on three distinct regions of the United States, the study shows the need for a varied approach to energy storage and electricity system design in different parts of the country. Using modeling tools to look out to 2050, the study team also focuses beyond the United States, to emerging market and developing economy (EMDE) countries, particularly as represented by India. The findings highlight the powerful role storage can play in EMDE nations. These countries are expected to see massive growth in electricity demand over the next 30 years, due to rapid overall economic expansion and to increasing adoption of electricity-consuming technologies such as air conditioning. In particular, the study calls attention to the pivotal role battery storage can play in decarbonizing grids in EMDE countries that lack access to low-cost gas and currently rely on coal generation.

      The authors find that investment in VRE combined with storage is favored over new coal generation over the medium and long term in India, although existing coal plants may linger unless forced out by policy measures such as carbon pricing. 

      “Developing countries are a crucial part of the global decarbonization challenge,” says Robert Stoner, the deputy director for science and technology at MITEI and one of the report authors. “Our study shows how they can take advantage of the declining costs of renewables and storage in the coming decades to become climate leaders without sacrificing economic development and modernization.”

      The study examines four kinds of storage technologies: electrochemical, thermal, chemical, and mechanical. Some of these technologies, such as lithium-ion batteries, pumped storage hydro, and some thermal storage options, are proven and available for commercial deployment. The report recommends that the government focus R&D efforts on other storage technologies, which will require further development to be available by 2050 or sooner — among them, projects to advance alternative electrochemical storage technologies that rely on earth-abundant materials. It also suggests government incentives and mechanisms that reward success but don’t interfere with project management. The report calls for the federal government to change some of the rules governing technology demonstration projects to enable more projects on storage. Policies that require cost-sharing in exchange for intellectual property rights, the report argues, discourage the dissemination of knowledge. The report advocates for federal requirements for demonstration projects that share information with other U.S. entities.

      The report says many existing power plants that are being shut down can be converted to useful energy storage facilities by replacing their fossil fuel boilers with thermal storage and new steam generators. This retrofit can be done using commercially available technologies and may be attractive to plant owners and communities — using assets that would otherwise be abandoned as electricity systems decarbonize.  

      The study also looks at hydrogen and concludes that its use for storage will likely depend on the extent to which hydrogen is used in the overall economy. That broad use of hydrogen, the report says, will be driven by future costs of hydrogen production, transportation, and storage — and by the pace of innovation in hydrogen end-use applications. 

      The MITEI study predicts the distribution of hourly wholesale prices or the hourly marginal value of energy will change in deeply decarbonized power systems — with many more hours of very low prices and more hours of high prices compared to today’s wholesale markets. So the report recommends systems adopt retail pricing and retail load management options that reward all consumers for shifting electricity use away from times when high wholesale prices indicate scarcity, to times when low wholesale prices signal abundance. 

      The Future of Energy Storage study is the ninth in MITEI’s “Future of” series, exploring complex and vital issues involving energy and the environment. Previous studies have focused on nuclear power, solar energy, natural gas, geothermal energy, and coal (with capture and sequestration of carbon dioxide emissions), as well as on systems such as the U.S. electric power grid. The Alfred P. Sloan Foundation and the Heising-Simons Foundation provided core funding for MITEI’s Future of Energy Storage study. MITEI members Equinor and Shell provided additional support.  More

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      A new heat engine with no moving parts is as efficient as a steam turbine

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      Engineers at MIT and the National Renewable Energy Laboratory (NREL) have designed a heat engine with no moving parts. Their new demonstrations show that it converts heat to electricity with over 40 percent efficiency — a performance better than that of traditional steam turbines.

      The heat engine is a thermophotovoltaic (TPV) cell, similar to a solar panel’s photovoltaic cells, that passively captures high-energy photons from a white-hot heat source and converts them into electricity. The team’s design can generate electricity from a heat source of between 1,900 to 2,400 degrees Celsius, or up to about 4,300 degrees Fahrenheit.

      The researchers plan to incorporate the TPV cell into a grid-scale thermal battery. The system would absorb excess energy from renewable sources such as the sun and store that energy in heavily insulated banks of hot graphite. When the energy is needed, such as on overcast days, TPV cells would convert the heat into electricity, and dispatch the energy to a power grid.

      With the new TPV cell, the team has now successfully demonstrated the main parts of the system in separate, small-scale experiments. They are working to integrate the parts to demonstrate a fully operational system. From there, they hope to scale up the system to replace fossil-fuel-driven power plants and enable a fully decarbonized power grid, supplied entirely by renewable energy.

      “Thermophotovoltaic cells were the last key step toward demonstrating that thermal batteries are a viable concept,” says Asegun Henry, the Robert N. Noyce Career Development Professor in MIT’s Department of Mechanical Engineering. “This is an absolutely critical step on the path to proliferate renewable energy and get to a fully decarbonized grid.”

      Henry and his collaborators have published their results today in the journal Nature. Co-authors at MIT include Alina LaPotin, Kevin Schulte, Kyle Buznitsky, Colin Kelsall, Andrew Rohskopf, and Evelyn Wang, the Ford Professor of Engineering and head of the Department of Mechanical Engineering, along with collaborators at NREL in Golden, Colorado.

      Jumping the gap

      More than 90 percent of the world’s electricity comes from sources of heat such as coal, natural gas, nuclear energy, and concentrated solar energy. For a century, steam turbines have been the industrial standard for converting such heat sources into electricity.

      On average, steam turbines reliably convert about 35 percent of a heat source into electricity, with about 60 percent representing the highest efficiency of any heat engine to date. But the machinery depends on moving parts that are temperature- limited. Heat sources higher than 2,000 degrees Celsius, such as Henry’s proposed thermal battery system, would be too hot for turbines.

      In recent years, scientists have looked into solid-state alternatives — heat engines with no moving parts, that could potentially work efficiently at higher temperatures.

      “One of the advantages of solid-state energy converters are that they can operate at higher temperatures with lower maintenance costs because they have no moving parts,” Henry says. “They just sit there and reliably generate electricity.”

      Thermophotovoltaic cells offered one exploratory route toward solid-state heat engines. Much like solar cells, TPV cells could be made from semiconducting materials with a particular bandgap — the gap between a material’s valence band and its conduction band. If a photon with a high enough energy is absorbed by the material, it can kick an electron across the bandgap, where the electron can then conduct, and thereby generate electricity — doing so without moving rotors or blades.

      To date, most TPV cells have only reached efficiencies of around 20 percent, with the record at 32 percent, as they have been made of relatively low-bandgap materials that convert lower-temperature, low-energy photons, and therefore convert energy less efficiently.

      Catching light

      In their new TPV design, Henry and his colleagues looked to capture higher-energy photons from a higher-temperature heat source, thereby converting energy more efficiently. The team’s new cell does so with higher-bandgap materials and multiple junctions, or material layers, compared with existing TPV designs.

      The cell is fabricated from three main regions: a high-bandgap alloy, which sits over a slightly lower-bandgap alloy, underneath which is a mirror-like layer of gold. The first layer captures a heat source’s highest-energy photons and converts them into electricity, while lower-energy photons that pass through the first layer are captured by the second and converted to add to the generated voltage. Any photons that pass through this second layer are then reflected by the mirror, back to the heat source, rather than being absorbed as wasted heat.

      The team tested the cell’s efficiency by placing it over a heat flux sensor — a device that directly measures the heat absorbed from the cell. They exposed the cell to a high-temperature lamp and concentrated the light onto the cell. They then varied the bulb’s intensity, or temperature, and observed how the cell’s power efficiency — the amount of power it produced, compared with the heat it absorbed — changed with temperature. Over a range of 1,900 to 2,400 degrees Celsius, the new TPV cell maintained an efficiency of around 40 percent.

      “We can get a high efficiency over a broad range of temperatures relevant for thermal batteries,” Henry says.

      The cell in the experiments is about a square centimeter. For a grid-scale thermal battery system, Henry envisions the TPV cells would have to scale up to about 10,000 square feet (about a quarter of a football field), and would operate in climate-controlled warehouses to draw power from huge banks of stored solar energy. He points out that an infrastructure exists for making large-scale photovoltaic cells, which could also be adapted to manufacture TPVs.

      “There’s definitely a huge net positive here in terms of sustainability,” Henry says. “The technology is safe, environmentally benign in its life cycle, and can have a tremendous impact on abating carbon dioxide emissions from electricity production.”

      This research was supported, in part, by the U.S. Department of Energy. More

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      in Energy

      New England renewables + Canadian hydropower

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      The urgent need to cut carbon emissions has prompted a growing number of U.S. states to commit to achieving 100 percent clean electricity by 2040 or 2050. But figuring out how to meet those commitments and still have a reliable and affordable power system is a challenge. Wind and solar installations will form the backbone of a carbon-free power system, but what technologies can meet electricity demand when those intermittent renewable sources are not adequate?

      In general, the options being discussed include nuclear power, natural gas with carbon capture and storage (CCS), and energy storage technologies such as new and improved batteries and chemical storage in the form of hydrogen. But in the northeastern United States, there is one more possibility being proposed: electricity imported from hydropower plants in the neighboring Canadian province of Quebec.

      The proposition makes sense. Those plants can produce as much electricity as about 40 large nuclear power plants, and some power generated in Quebec already comes to the Northeast. So, there could be abundant additional supply to fill any shortfall when New England’s intermittent renewables underproduce. However, U.S. wind and solar investors view Canadian hydropower as a competitor and argue that reliance on foreign supply discourages further U.S. investment.

      Two years ago, three researchers affiliated with the MIT Center for Energy and Environmental Policy Research (CEEPR) — Emil Dimanchev SM ’18, now a PhD candidate at the Norwegian University of Science and Technology; Joshua Hodge, CEEPR’s executive director; and John Parsons, a senior lecturer in the MIT Sloan School of Management — began wondering whether viewing Canadian hydro as another source of electricity might be too narrow. “Hydropower is a more-than-hundred-year-old technology, and plants are already built up north,” says Dimanchev. “We might not need to build something new. We might just need to use those plants differently or to a greater extent.”

      So the researchers decided to examine the potential role and economic value of Quebec’s hydropower resource in a future low-carbon system in New England. Their goal was to help inform policymakers, utility decision-makers, and others about how best to incorporate Canadian hydropower into their plans and to determine how much time and money New England should spend to integrate more hydropower into its system. What they found out was surprising, even to them.

      The analytical methods

      To explore possible roles for Canadian hydropower to play in New England’s power system, the MIT researchers first needed to predict how the regional power system might look in 2050 — both the resources in place and how they would be operated, given any policy constraints. To perform that analysis, they used GenX, a modeling tool originally developed by Jesse Jenkins SM ’14, PhD ’18 and Nestor Sepulveda SM ’16, PhD ’20 while they were researchers at the MIT Energy Initiative (MITEI).

      The GenX model is designed to support decision-making related to power system investment and real-time operation and to examine the impacts of possible policy initiatives on those decisions. Given information on current and future technologies — different kinds of power plants, energy storage technologies, and so on — GenX calculates the combination of equipment and operating conditions that can meet a defined future demand at the lowest cost. The GenX modeling tool can also incorporate specified policy constraints, such as limits on carbon emissions.

      For their study, Dimanchev, Hodge, and Parsons set parameters in the GenX model using data and assumptions derived from a variety of sources to build a representation of the interconnected power systems in New England, New York, and Quebec. (They included New York to account for that state’s existing demand on the Canadian hydro resources.) For data on the available hydropower, they turned to Hydro-Québec, the public utility that owns and operates most of the hydropower plants in Quebec.

      It’s standard in such analyses to include real-world engineering constraints on equipment, such as how quickly certain power plants can be ramped up and down. With help from Hydro-Québec, the researchers also put hour-to-hour operating constraints on the hydropower resource.

      Most of Hydro-Québec’s plants are “reservoir hydropower” systems. In them, when power isn’t needed, the flow on a river is restrained by a dam downstream of a reservoir, and the reservoir fills up. When power is needed, the dam is opened, and the water in the reservoir runs through downstream pipes, turning turbines and generating electricity. Proper management of such a system requires adhering to certain operating constraints. For example, to prevent flooding, reservoirs must not be allowed to overfill — especially prior to spring snowmelt. And generation can’t be increased too quickly because a sudden flood of water could erode the river edges or disrupt fishing or water quality.

      Based on projections from the National Renewable Energy Laboratory and elsewhere, the researchers specified electricity demand for every hour of the year 2050, and the model calculated the cost-optimal mix of technologies and system operating regime that would satisfy that hourly demand, including the dispatch of the Hydro-Québec hydropower system. In addition, the model determined how electricity would be traded among New England, New York, and Quebec.

      Effects of decarbonization limits on technology mix and electricity trading

      To examine the impact of the emissions-reduction mandates in the New England states, the researchers ran the model assuming reductions in carbon emissions between 80 percent and 100 percent relative to 1990 levels. The results of those runs show that, as emissions limits get more stringent, New England uses more wind and solar and extends the lifetime of its existing nuclear plants. To balance the intermittency of the renewables, the region uses natural gas plants, demand-side management, battery storage (modeled as lithium-ion batteries), and trading with Quebec’s hydropower-based system. Meanwhile, the optimal mix in Quebec is mostly composed of existing hydro generation. Some solar is added, but new reservoirs are built only if renewable costs are assumed to be very high.

      The most significant — and perhaps surprising — outcome is that in all the scenarios, the hydropower-based system of Quebec is not only an exporter but also an importer of electricity, with the direction of flow on the Quebec-New England transmission lines changing over time.

      Historically, energy has always flowed from Quebec to New England. The model results for 2018 show electricity flowing from north to south, with the quantity capped by the current transmission capacity limit of 2,225 megawatts (MW).

      An analysis for 2050, assuming that New England decarbonizes 90 percent and the capacity of the transmission lines remains the same, finds electricity flows going both ways. Flows from north to south still dominate. But for nearly 3,500 of the 8,760 hours of the year, electricity flows in the opposite direction — from New England to Quebec. And for more than 2,200 of those hours, the flow going north is at the maximum the transmission lines can carry.

      The direction of flow is motivated by economics. When renewable generation is abundant in New England, prices are low, and it’s cheaper for Quebec to import electricity from New England and conserve water in its reservoirs. Conversely, when New England’s renewables are scarce and prices are high, New England imports hydro-generated electricity from Quebec.

      So rather than delivering electricity, Canadian hydro provides a means of storing the electricity generated by the intermittent renewables in New England.

      “We see this in our modeling because when we tell the model to meet electricity demand using these resources, the model decides that it is cost-optimal to use the reservoirs to store energy rather than anything else,” says Dimanchev. “We should be sending the energy back and forth, so the reservoirs in Quebec are in essence a battery that we use to store some of the electricity produced by our intermittent renewables and discharge it when we need it.”

      Given that outcome, the researchers decided to explore the impact of expanding the transmission capacity between New England and Quebec. Building transmission lines is always contentious, but what would be the impact if it could be done?

      Their model results shows that when transmission capacity is increased from 2,225 MW to 6,225 MW, flows in both directions are greater, and in both cases the flow is at the new maximum for more than 1,000 hours.

      Results of the analysis thus confirm that the economic response to expanded transmission capacity is more two-way trading. To continue the battery analogy, more transmission capacity to and from Quebec effectively increases the rate at which the battery can be charged and discharged.

      Effects of two-way trading on the energy mix

      What impact would the advent of two-way trading have on the mix of energy-generating sources in New England and Quebec in 2050?

      Assuming current transmission capacity, in New England, the change from one-way to two-way trading increases both wind and solar power generation and to a lesser extent nuclear; it also decreases the use of natural gas with CCS. The hydro reservoirs in Canada can provide long-duration storage — over weeks, months, and even seasons — so there is less need for natural gas with CCS to cover any gaps in supply. The level of imports is slightly lower, but now there are also exports. Meanwhile, in Quebec, two-way trading reduces solar power generation, and the use of wind disappears. Exports are roughly the same, but now there are imports as well. Thus, two-way trading reallocates renewables from Quebec to New England, where it’s more economical to install and operate solar and wind systems.

      Another analysis examined the impact on the energy mix of assuming two-way trading plus expanded transmission capacity. For New England, greater transmission capacity allows wind, solar, and nuclear to expand further; natural gas with CCS all but disappears; and both imports and exports increase significantly. In Quebec, solar decreases still further, and both exports and imports of electricity increase.

      Those results assume that the New England power system decarbonizes by 99 percent in 2050 relative to 1990 levels. But at 90 percent and even 80 percent decarbonization levels, the model concludes that natural gas capacity decreases with the addition of new transmission relative to the current transmission scenario. Existing plants are retired, and new plants are not built as they are no longer economically justified. Since natural gas plants are the only source of carbon emissions in the 2050 energy system, the researchers conclude that the greater access to hydro reservoirs made possible by expanded transmission would accelerate the decarbonization of the electricity system.

      Effects of transmission changes on costs

      The researchers also explored how two-way trading with expanded transmission capacity would affect costs in New England and Quebec, assuming 99 percent decarbonization in New England. New England’s savings on fixed costs (investments in new equipment) are largely due to a decreased need to invest in more natural gas with CCS, and its savings on variable costs (operating costs) are due to a reduced need to run those plants. Quebec’s savings on fixed costs come from a reduced need to invest in solar generation. The increase in cost — borne by New England — reflects the construction and operation of the increased transmission capacity. The net benefit for the region is substantial.

      Thus, the analysis shows that everyone wins as transmission capacity increases — and the benefit grows as the decarbonization target tightens. At 99 percent decarbonization, the overall New England-Quebec region pays about $21 per megawatt-hour (MWh) of electricity with today’s transmission capacity but only $18/MWh with expanded transmission. Assuming 100 percent reduction in carbon emissions, the region pays $29/MWh with current transmission capacity and only $22/MWh with expanded transmission.

      Addressing misconceptions

      These results shed light on several misconceptions that policymakers, supporters of renewable energy, and others tend to have.

      The first misconception is that the New England renewables and Canadian hydropower are competitors. The modeling results instead show that they’re complementary. When the power systems in New England and Quebec work together as an integrated system, the Canadian reservoirs are used part of the time to store the renewable electricity. And with more access to hydropower storage in Quebec, there’s generally more renewable investment in New England.

      The second misconception arises when policymakers refer to Canadian hydro as a “baseload resource,” which implies a dependable source of electricity — particularly one that supplies power all the time. “Our study shows that by viewing Canadian hydropower as a baseload source of electricity — or indeed a source of electricity at all — you’re not taking full advantage of what that resource can provide,” says Dimanchev. “What we show is that Quebec’s reservoir hydro can provide storage, specifically for wind and solar. It’s a solution to the intermittency problem that we foresee in carbon-free power systems for 2050.”

      While the MIT analysis focuses on New England and Quebec, the researchers believe that their results may have wider implications. As power systems in many regions expand production of renewables, the value of storage grows. Some hydropower systems have storage capacity that has not yet been fully utilized and could be a good complement to renewable generation. Taking advantage of that capacity can lower the cost of deep decarbonization and help move some regions toward a decarbonized supply of electricity.

      This research was funded by the MIT Center for Energy and Environmental Policy Research, which is supported in part by a consortium of industry and government associates.

      This article appears in the Autumn 2021 issue of Energy Futures, the magazine of the MIT Energy Initiative. More