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      In nanotube science, is boron nitride the new carbon?

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      Engineers at MIT and the University of Tokyo have produced centimeter-scale structures, large enough for the eye to see, that are packed with hundreds of billions of hollow aligned fibers, or nanotubes, made from hexagonal boron nitride.

      Hexagonal boron nitride, or hBN, is a single-atom-thin material that has been coined “white graphene” for its transparent appearance and its similarity to carbon-based graphene in molecular structure and strength. It can also withstand higher temperatures than graphene, and is electrically insulating, rather than conductive. When hBN is rolled into nanometer-scale tubes, or nanotubes, its exceptional properties are significantly enhanced.

      The team’s results, published today in the journal ACS Nano, provide a route toward fabricating aligned boron nitride nanotubes (A-BNNTs) in bulk. The researchers plan to harness the technique to fabricate bulk-scale arrays of these nanotubes, which can then be combined with other materials to make stronger, more heat-resistant composites, for instance to shield space structures and hypersonic aircraft.

      As hBN is transparent and electrically insulating, the team also envisions incorporating the BNNTs into transparent windows and using them to electrically insulate sensors within electronic devices. The team is also investigating ways to weave the nanofibers into membranes for water filtration and for “blue energy” — a concept for renewable energy in which electricity is produced from the ionic filtering of salt water into fresh water.

      Brian Wardle, professor of aeronautics and astronautics at MIT, likens the team’s results to scientists’ decades-long, ongoing pursuit of manufacturing bulk-scale carbon nanotubes.

      “In 1991, a single carbon nanotube was identified as an interesting thing, but it’s been 30 years getting to bulk aligned carbon nanotubes, and the world’s not even fully there yet,” Wardle says. “With the work we’re doing, we’ve just short-circuited about 20 years in getting to bulk-scale versions of aligned boron nitride nanotubes.”

      Wardle is the senior author of the new study, which includes lead author and MIT research scientist Luiz Acauan, former MIT postdoc Haozhe Wang, and collaborators at the University of Tokyo.

      A vision, aligned

      Like graphene, hexagonal boron nitride has a molecular structure resembling chicken wire. In graphene, this chicken wire configuration is made entirely of carbon atoms, arranged in a repeating pattern of hexagons. For hBN, the hexagons are composed of alternating atoms of boron and nitrogen. In recent years, researchers have found that two-dimensional sheets of hBN exhibit exceptional properties of strength, stiffness, and resilience at high temperatures. When sheets of hBN are rolled into nanotube form, these properties are further enhanced, particularly when the nanotubes are aligned, like tiny trees in a densely packed forest.

      But finding ways to synthesize stable, high quality BNNTs has proven challenging. A handful of efforts to do so have produced low-quality, nonaligned fibers.

      “If you can align them, you have much better chance of harnessing BNNTs properties at the bulk scale to make actual physical devices, composites, and membranes,” Wardle says.

      In 2020, Rong Xiang and colleagues at the University of Tokyo found they could produce high-quality boron nitride nanotubes by first using a conventional approach of chemical vapor deposition to grow a forest of short, few micron-long carbon nanotubes. They then coated the carbon-based forest with “precursors” of boron and nitrogen gas, which when baked in an oven at high temperatures crystallized onto the carbon nanotubes to form high-quality nanotubes of hexagonal boron nitride with carbon nanotubes inside.

      Burning scaffolds

      In the new study, Wardle and Acauan have extend and scale Xiang’s approach, essentially removing the underlying carbon nanotubes and leaving the long boron nitride nanotubes to stand on their own. The team drew on the expertise of Wardle’s group, which has focused for years on fabricating high-quality aligned arrays of carbon nanotubes. With their current work, the researchers looked for ways to tweak the temperatures and pressures of the chemical vapor deposition process in order to remove the carbon nanotubes while leaving the boron nitride nanotubes intact.

      “The first few times we did it, it was completely ugly garbage,” Wardle recalls. “The tubes curled up into a ball, and they didn’t work.”

      Eventually, the team hit on a combination of temperatures, pressures, and precursors that did the trick. With this combination of processes, the researchers first reproduced the steps that Xiang took to synthesize the boron-nitride-coated carbon nanotubes. As hBN is resistant to higher temperatures than graphene, the team then cranked up the heat to burn away the underlying black carbon nanotube scaffold, while leaving the transparent, freestanding boron nitride nanotubes intact.
      By using carbon nanotubes as a scaffold, MIT engineers grow forests of “white graphene” that emerge (in MIT pattern) after burning away the black carbon scaffold. Courtesy of the researchersIn microscopic images, the team observed clear crystalline structures — evidence that the boron nitride nanotubes have a high quality. The structures were also dense: Within a square centimeter, the researchers were able to synthesize a forest of more than 100 billion aligned boron nitride nanotubes, that measured about a millimeter in height — large enough to be visible by eye. By nanotube engineering standards, these dimensions are considered to be “bulk” in scale.

      “We are now able to make these nanoscale fibers at bulk scale, which has never been shown before,” Acauan says.

      To demonstrate the flexibility of their technique, the team synthesized larger carbon-based structures, including a weave of carbon fibers, a mat of “fuzzy” carbon nanotubes, and sheets of randomly oriented carbon nanotubes known as “buckypaper.” They coated each carbon-based sample with boron and nitrogen precursors, then went through their process to burn away the underlying carbon. In each demonstration, they were left with a boron-nitride replica of the original black carbon scaffold.

      They also were able to “knock down” the forests of BNNTs, producing horizontally aligned fiber films that are a preferred configuration for incorporating into composite materials.

      “We are now working toward fibers to reinforce ceramic matrix composites, for hypersonic and space applications where there are very high temperatures, and for windows for devices that need to be optically transparent,” Wardle says. “You could make transparent materials that are reinforced with these very strong nanotubes.”

      This research was supported, in part, by Airbus, ANSYS, Boeing, Embraer, Lockheed Martin, Saab AB, and Teijin Carbon America through MIT’s Nano-Engineered Composite aerospace STructures (NECST) Consortium. More

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      Simplifying the production of lithium-ion batteries

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      When it comes to battery innovations, much attention gets paid to potential new chemistries and materials. Often overlooked is the importance of production processes for bringing down costs.

      Now the MIT spinout 24M Technologies has simplified lithium-ion battery production with a new design that requires fewer materials and fewer steps to manufacture each cell. The company says the design, which it calls “SemiSolid” for its use of gooey electrodes, reduces production costs by up to 40 percent. The approach also improves the batteries’ energy density, safety, and recyclability.

      Judging by industry interest, 24M is onto something. Since coming out of stealth mode in 2015, 24M has licensed its technology to multinational companies including Volkswagen, Fujifilm, Lucas TVS, Axxiva, and Freyr. Those last three companies are planning to build gigafactories (factories with gigawatt-scale annual production capacity) based on 24M’s technology in India, China, Norway, and the United States.

      “The SemiSolid platform has been proven at the scale of hundreds of megawatts being produced for residential energy-storage systems. Now we want to prove it at the gigawatt scale,” says 24M CEO Naoki Ota, whose team includes 24M co-founder, chief scientist, and MIT Professor Yet-Ming Chiang.

      Establishing large-scale production lines is only the first phase of 24M’s plan. Another key draw of its battery design is that it can work with different combinations of lithium-ion chemistries. That means 24M’s partners can incorporate better-performing materials down the line without substantially changing manufacturing processes.

      The kind of quick, large-scale production of next-generation batteries that 24M hopes to enable could have a dramatic impact on battery adoption across society — from the cost and performance of electric cars to the ability of renewable energy to replace fossil fuels.

      “This is a platform technology,” Ota says. “We’re not just a low-cost and high-reliability operator. That’s what we are today, but we can also be competitive with next-generation chemistry. We can use any chemistry in the market without customers changing their supply chains. Other startups are trying to address that issue tomorrow, not today. Our tech can address the issue today and tomorrow.”

      A simplified design

      Chiang, who is MIT’s Kyocera Professor of Materials Science and Engineering, got his first glimpse into large-scale battery production after co-founding another battery company, A123 Systems, in 2001. As that company was preparing to go public in the late 2000s, Chiang began wondering if he could design a battery that would be easier to manufacture.

      “I got this window into what battery manufacturing looked like, and what struck me was that even though we pulled it off, it was an incredibly complicated manufacturing process,” Chiang says. “It derived from magnetic tape manufacturing that was adapted to batteries in the late 1980s.”

      In his lab at MIT, where he’s been a professor since 1985, Chiang started from scratch with a new kind of device he called a “semi-solid flow battery” that pumps liquids carrying particle-based electrodes to and from tanks to store a charge.

      In 2010, Chiang partnered with W. Craig Carter, who is MIT’s POSCO Professor of Materials Science and Engineering, and the two professors supervised a student, Mihai Duduta ’11, who explored flow batteries for his undergraduate thesis. Within a month, Duduta had developed a prototype in Chiang’s lab, and 24M was born. (Duduta was the company’s first hire.)

      But even as 24M worked with MIT’s Technology Licensing Office (TLO) to commercialize research done in Chiang’s lab, people in the company including Duduta began rethinking the flow battery concept. An internal cost analysis by Carter, who consulted for 24M for several years, ultimately lead the researchers to change directions.

      That left the company with loads of the gooey slurry that made up the electrodes in their flow batteries. A few weeks after Carter’s cost analysis, Duduta, then a senior research scientist at 24M, decided to start using the slurry to assemble batteries by hand, mixing the gooey electrodes directly into the electrolyte. The idea caught on.

      The main components of batteries are the positive and negatively charged electrodes and the electrolyte material that allows ions to flow between them. Traditional lithium-ion batteries use solid electrodes separated from the electrolyte by layers of inert plastics and metals, which hold the electrodes in place.

      Stripping away the inert materials of traditional batteries and embracing the gooey electrode mix gives 24M’s design a number of advantages.

      For one, it eliminates the energy-intensive process of drying and solidifying the electrodes in traditional lithium-ion production. The company says it also reduces the need for more than 80 percent of the inactive materials in traditional batteries, including expensive ones like copper and aluminum. The design also requires no binder and features extra thick electrodes, improving the energy density of the batteries.

      “When you start a company, the smart thing to do is to revisit all of your assumptions  and ask what is the best way to accomplish your objectives, which in our case was simply-manufactured, low-cost batteries,” Chiang says. “We decided our real value was in making a lithium-ion suspension that was electrochemically active from the beginning, with electrolyte in it, and you just use the electrolyte as the processing solvent.”

      In 2017, 24M participated in the MIT Industrial Liaison Program’s STEX25 Startup Accelerator, in which Chiang and collaborators made critical industry connections that would help it secure early partnerships. 24M has also collaborated with MIT researchers on projects funded by the Department of Energy.

      Enabling the battery revolution

      Most of 24M’s partners are eyeing the rapidly growing electric vehicle (EV) market for their batteries, and the founders believe their technology will accelerate EV adoption. (Battery costs make up 30 to 40 percent of the price of EVs, according to the Institute for Energy Research).

      “Lithium-ion batteries have made huge improvements over the years, but even Elon Musk says we need some breakthrough technology,” Ota says, referring to the CEO of EV firm Tesla. “To make EVs more common, we need a production cost breakthrough; we can’t just rely on cost reduction through scaling because we already make a lot of batteries today.”

      24M is also working to prove out new battery chemistries that its partners could quickly incorporate into their gigafactories. In January of this year, 24M received a grant from the Department of Energy’s ARPA-E program to develop and scale a high-energy-density battery that uses a lithium metal anode and semi-solid cathode for use in electric aviation.

      That project is one of many around the world designed to validate new lithium-ion battery chemistries that could enable a long-sought battery revolution. As 24M continues to foster the creation of large scale, global production lines, the team believes it is well-positioned to turn lab innovations into ubiquitous, world-changing products.

      “This technology is a platform, and our vision is to be like Google’s Android [operating system], where other people can build things on our platform,” Ota says. “We want to do that but with hardware. That’s why we’re licensing the technology. Our partners can use the same production lines to get the benefits of new chemistries and approaches. This platform gives everyone more options.” More

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      Doubling down on sustainability innovation in Kendall Square

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      From its new headquarters in Cambridge’s Kendall Square, The Engine is investing in a number of “tough tech” startups seeking to transform the world’s energy systems. A few blocks away, the startup Inari is using gene editing to improve seeds’ resilience to climate change. On the MIT campus nearby, researchers are working on groundbreaking innovations to meet the urgent challenges our planet faces.

      Kendall Square is known as the biotech capital of the world, but as the latest annual meeting of the Kendal Square Association (KSA) made clear, it’s also a thriving hub of sustainability-related innovation.

      The Oct. 20 event, which began at MIT’s Welcome Center before moving to the MIT Museum for a panel discussion, brought together professionals from across Cambridge’s prolific innovation ecosystem — not just entrepreneurs working at startups, but also students, restaurant and retail shop owners, and people from local nonprofits.

      Titled “[Re] Imagining a Sustainable Future,” the meeting highlighted advances in climate change technologies that are afoot in Kendall Square, to help inspire and connect the community as it works toward common sustainability goals.

      “Our focus is on building a better future together — and together is the most important word there,” KSA Executive Director Beth O’Neill Maloney said in her opening remarks. “This is an incredibly innovative ecosystem and community that’s making changes that affect us here in Kendall Square and far, far beyond.”

      The pace of change

      The main event of the evening was a panel discussion moderated by Lee McGuire, the chief communications officer of the Broad Institute of MIT and Harvard. The panel featured Stuart Brown, chief financial officer at Inari; Emily Knight, chief operating officer at The Engine; and Joe Higgins, vice president for campus services and stewardship at MIT.

      “Sustainability is obviously one of the most important — if not the most important — challenge facing us as a society today,” said McGuire, opening the discussion. “Kendall Square is known for its work in biotech, life sciences, AI, and climate, and the more we dug into it the more we realized how interconnected all of those things are. The talent in Kendall Square wants to work on problems relevant for humanity, and the tools and skills you need for that can be very similar depending on the problem you’re working on.”

      Higgins, who oversees the creation of programs to reduce MIT’s environmental impact and improve the resilience of campus operations, focused on the enormity of the problem humanity is facing. He showed the audience a map of the U.S. power grid, with power plants and transmission lines illuminated in a complex web across the country, to underscore the scale of electrification that will be needed to mitigate the worst effects of climate change.

      “The U.S. power grid is the largest machine ever made by mankind,” Higgins said. “It’s been developed over 100 years; it has 7,000 generating plants that feed into it every day; it has 7 million miles of cable and wires; there are transformers and substations; and it lives in every single one of your walls. But people don’t think about it that much.”

      Many cities, states, and organizations like MIT have made commitments to shift to 100 percent clean energy in coming decades. Higgins wanted the audience to try to grasp what that’s going to take.

      “Hundreds of millions of devices and equipment across the planet are going to have to be swapped from fossil fuel to electric-based,” Higgins said. “Our cars, appliances, processes in industry, like making steel and concrete, are going to need to come from this grid. It’ll need to undergo a major modernization and transformation. The good news is it’s already changing.”

      Multiple panelists pointed to developments like the passing of the Inflation Reduction Act to show there was progress being made in reaching urgent sustainability goals.

      “There is a tide change coming, and it’s not only being driven by private capital,” Knight said. “There’s a huge opportunity here, and it’s a really important part of this [Kendall Square] ecosystem.”

      Chief among the topics of discussion was technology development. Even as leaders implement today’s technologies to decarbonize, people in Kendall Square keep a close eye on the new tech being developed and commercialized nearby.

      “I was trying to think about where we are with gene editing,” Brown said. “CRISPR’s been around for 10 years. Compare that to video games. Pong was the first video game when it came out in 1972. Today you have Chess.com using artificial intelligence to power chess games. On gene editing and a lot of these other technologies, we’re much closer to Pong than we are to where it’s going to be. We just can’t imagine today the technology changes we’re going to see over the next five to 10 years.”

      In that regard, Knight discussed some of the promising portfolio companies of The Engine, which invests in early stage, technologically innovative companies. In particular, she highlighted two companies seeking to transform the world’s energy systems with entirely new, 100 percent clean energy sources. MIT spinout Commonwealth Fusion Systems is working on nuclear fusion reactors that could provide abundant, safe, and constant streams of clean energy to our grids, while fellow MIT spinout Quaise Energy is seeking to harvest a new kind of deep geothermal energy using millimeter wave drilling technology.

      “All of our portfolio companies have a focus on sustainability in one way or another,” Knight said. “People who are working on these very hard technologies will change the world.”

      Knight says the kind of collaboration championed by the KSA is important for startups The Engine invests in.

      “We know these companies need a lot of people around them, whether from government, academia, advisors, corporate partners, anyone who can help them on their path, because for a lot of them this is a new path and a new market,” Knight said.

      Reasons for hope

      The KSA is made up of over 150 organizations across Kendall Square. From major employers like Sanofi, Pfizer, MIT, and the Broad Institute to local nonprofit organizations, startups, and independent shops and restaurants, the KSA represents the entire Kendall ecosystem.

      O’Neill Maloney celebrated a visible example of sustainability in Kendall Square early on by the Charles River Conservancy, which has built a floating wetland designed to naturally remove harmful algae blooms from Charles River.

      Other examples of sustainability work in the neighborhood can be found at MIT. Under its “Fast Forward” climate action plan, the Institute has set a goal of eliminating direct emissions from its campus by 2050, including a near-term milestone of achieving net-zero emissions by 2026. Since 2014, when MIT launched a five-year plan for action on climate change, net campus emissions have already been cut by 20 percent by making its campus buildings more energy efficient, transitioning to electric vehicles, and enabling large-scale renewable energy projects, among other strategies.

      In the face of a daunting global challenge, such milestones are reason for optimism.

      “If anybody’s going to be able to do this [shift to 100 percent clean energy] and show how it can be done at an urban, city scale, it’s probably MIT and the city of Cambridge,” McGuire said. “We have a lot of good ingredients to figure this out.”

      Throughout the night, many speakers, attendees, and panelists echoed that sentiment. They said they see plenty of reasons for hope.

      “I’m absolutely optimistic,” Higgins said. “I’m seeing utility companies working with businesses working with regulators — people are coming together on this topic. And one of these new technologies being commercialized is going to change things before 2030, whether its fusion, deep geothermal, small modular nuclear reactors, the technology is just moving so quickly.” More

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      Finding community in high-energy-density physics

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      Skylar Dannhoff knew one thing: She did not want to be working alone.

      As an undergraduate at Case Western Reserve University, she had committed to a senior project that often felt like solitary lab work, a feeling heightened by the pandemic. Though it was an enriching experience, she was determined to find a graduate school environment that would foster community, one “with lots of people, lots of collaboration; where it’s impossible to work until 3 a.m. without anyone noticing.” A unique group at the Plasma Science and Fusion Center (PSFC) looked promising: the High-Energy-Density Physics (HEDP) division, a lead partner in the National Nuclear Security Administration’s Center for Excellence at MIT.

      “It was a shot in the dark, just more of a whim than anything,” she says of her request to join HEDP on her application to MIT’s Department of Physics. “And then, somehow, they reached out to me. I told them I’m willing to learn about plasma. I didn’t know anything about it.”

      What she did know was that the HEDP group collaborates with other U.S. laboratories on an approach to creating fusion energy known as inertial confinement fusion (ICF). One version of the technique, known as direct-drive ICF, aims multiple laser beams symmetrically onto a spherical capsule filled with nuclear fuel. The other, indirect-drive ICF, instead aims multiple lasers beams into a gold cylindrical cavity called a hohlraum, within which the spherical fuel capsule is positioned. The laser beams are configured to hit the inner hohlraum wall, generating a “bath” of X-rays, which in turn compress the fuel capsule.

      Imploding the capsule generates intense fusion energy within a tiny fraction of a second (an order of tens of picoseconds). In August 2021, the National Ignition Facility (NIF) at Lawrence Livermore National Laboratory (LLNL) used this method to produce an historic fusion yield of 1.3 megajoules, putting researchers within reach of “ignition,” the point where the self-sustained fusion burn spreads into the surrounding fuel, leading to a high fusion-energy gain.  

      Joining the group just a month before this long-sought success, Dannhoff was impressed more with the response of her new teammates and the ICF community than with the scientific milestone. “I got a better appreciation for people who had spent their entire careers working on this project, just chugging along doing their best, ignoring the naysayers. I was excited for the people.”

      Dannhoff is now working toward extending the success of NIF and other ICF experiments, like the OMEGA laser at the University of Rochester’s Laboratory for Laser Energetics. Under the supervision of Senior Research Scientist Chikang Li, she is studying what happens to the flow of plasma within the hohlraum cavity during indirect ICF experiments, particularly for hohlraums with inner-wall aerogel foam linings. Experiments, over the last decade, have shown just how excruciatingly precise the symmetry in ICF targets must be. The more symmetric the X-ray drive, the more effective the implosion, and it is possible that these foam linings will improve the X-ray symmetry and drive efficiency.

      Dannhoff is specifically interested in studying the behavior of silicon and tantalum-based foam liners. She is as concerned with the challenges of the people at General Atomics (GA) and LLNL who are creating these targets as she is with the scientific outcome.

      “I just had a meeting with GA yesterday,” she notes. “And it’s a really tricky process. It’s kind of pushing the boundaries of what is doable at the moment. I got a much better sense of how demanding this project is for them, how much we’re asking of them.”

      What excites Dannhoff is the teamwork she observes, both at MIT and between ICF institutions around the United States. With roughly 10 graduate students and postdocs down the hall, each with an assigned lead role in lab management, she knows she can consult an expert on almost any question. And collaborators across the country are just an email away. “Any information that people can give you, they will give you, and usually very freely,” she notes. “Everyone just wants to see this work.”

      That Dannhoff is a natural team player is also evidenced in her hobbies. A hockey goalie, she prioritizes playing with MIT’s intramural teams, “because goalies are a little hard to come by. I just play with whoever needs a goalie on that night, and it’s a lot of fun.”

      She is also a member of the radio community, a fellowship she first embraced at Case Western — a moment she describes as a turning point in her life. “I literally don’t know who I would be today if I hadn’t figured out radio is something I’m interested in,” she admits. The MIT Radio Society provided the perfect landing pad for her arrival in Cambridge, full of the kinds of supportive, interesting, knowledgeable students she had befriended as an undergraduate. She credits radio with helping her realize that she could make her greatest contributions to science by focusing on engineering.

      Danhoff gets philosophical as she marvels at the invisible waves that surround us.

      “Not just radio waves: every wave,” she asserts. “The voice is the everywhere. Music, signal, space phenomena: it’s always around. And all we have to do is make the right little device and have the right circuit elements put in the right order to unmix and mix the signals and amplify them. And bada-bing, bada-boom, we’re talking with the universe.”

      “Maybe that epitomizes physics to me,” she adds. “We’re trying to listen to the universe, and it’s talking to us. We just have to come up with the right tools and hear what it’s trying to say.” More

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      3 Questions: Blue hydrogen and the world’s energy systems

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      In the past several years, hydrogen energy has increasingly become a more central aspect of the clean energy transition. Hydrogen can produce clean, on-demand energy that could complement variable renewable energy sources such as wind and solar power. That being said, pathways for deploying hydrogen at scale have yet to be fully explored. In particular, the optimal form of hydrogen production remains in question.

      MIT Energy Initiative Research Scientist Emre Gençer and researchers from a wide range of global academic and research institutions recently published “On the climate impacts of blue hydrogen production,” a comprehensive life-cycle assessment analysis of blue hydrogen, a term referring to natural gas-based hydrogen production with carbon capture and storage. Here, Gençer describes blue hydrogen and the role that hydrogen will play more broadly in decarbonizing the world’s energy systems.

      Q: What are the differences between gray, green, and blue hydrogen?

      A: Though hydrogen does not generate any emissions directly when it is used, hydrogen production can have a huge environmental impact. Colors of hydrogen are increasingly used to distinguish different production methods and as a proxy to represent the associated environmental impact. Today, close to 95 percent of hydrogen production comes from fossil resources. As a result, the carbon dioxide (CO2) emissions from hydrogen production are quite high. Gray, black, and brown hydrogen refer to fossil-based production. Gray is the most common form of production and comes from natural gas, or methane, using steam methane reformation but without capturing CO2.

      There are two ways to move toward cleaner hydrogen production. One is applying carbon capture and storage to the fossil fuel-based hydrogen production processes. Natural gas-based hydrogen production with carbon capture and storage is referred to as blue hydrogen. If substantial amounts of CO2 from natural gas reforming are captured and permanently stored, such hydrogen could be a low-carbon energy carrier. The second way to produce cleaner hydrogen is by using electricity to produce hydrogen via electrolysis. In this case, the source of the electricity determines the environmental impact of the hydrogen, with the lowest impact being achieved when electricity is generated from renewable sources, such as wind and solar. This is known as green hydrogen.

      Q: What insights have you gleaned with a life cycle assessment (LCA) of blue hydrogen and other low-carbon energy systems?

      A: Mitigating climate change requires significant decarbonization of the global economy. Accurate estimation of cumulative greenhouse gas (GHG) emissions and its reduction pathways is critical irrespective of the source of emissions. An LCA approach allows the quantification of the environmental life cycle of a commercial product, process, or service impact with all the stages (cradle-to-grave). The LCA-based comparison of alternative energy pathways, fuel options, etc., provides an apples-to-apples comparison of low-carbon energy choices. In the context of low-carbon hydrogen, it is essential to understand the GHG impact of supply chain options. Depending on the production method, contribution of life-cycle stages to the total emissions might vary. For example, with natural gas–based hydrogen production, emissions associated with production and transport of natural gas might be a significant contributor based on its leakage and flaring rates. If these rates are not precisely accounted for, the environmental impact of blue hydrogen can be underestimated. However, the same rationale is also true for electricity-based hydrogen production. If the electricity is not supplied from low-
carbon sources such as wind, solar, or nuclear, the carbon intensity of hydrogen can be significantly underestimated. In the case of nuclear, there are also other environmental impact considerations.

      An LCA approach — if performed with consistent system boundaries — can provide an accurate environmental impact comparison. It should also be noted that these estimations can only be as good as the assumptions and correlations used unless they are supported by measurements. 

      Q: What conditions are needed to make blue hydrogen production most effective, and how can it complement other decarbonization pathways?

      A: Hydrogen is considered one of the key vectors for the decarbonization of hard-to-abate sectors such as heavy-duty transportation. Currently, more than 95 percent of global hydrogen production is fossil-fuel based. In the next decade, massive amounts of hydrogen must be produced to meet this anticipated demand. It is very hard, if not impossible, to meet this demand without leveraging existing production assets. The immediate and relatively cost-effective option is to retrofit existing plants with carbon capture and storage (blue hydrogen).

      The environmental impact of blue hydrogen may vary over large ranges but depends on only a few key parameters: the methane emission rate of the natural gas supply chain, the CO2 removal rate at the hydrogen production plant, and the global warming metric applied. State-of-the-art reforming with high CO2 capture rates, combined with natural gas supply featuring low methane emissions, substantially reduces GHG emissions compared to conventional natural gas reforming. Under these conditions, blue hydrogen is compatible with low-carbon economies and exhibits climate change impacts at the upper end of the range of those caused by hydrogen production from renewable-based electricity. However, neither current blue nor green hydrogen production pathways render fully “net-zero” hydrogen without additional CO2 removal.

      This article appears in the Spring 2022 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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      Simulating neutron behavior in nuclear reactors

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      Amelia Trainer applied to MIT because she lost a bet.

      As part of what the fourth-year nuclear science and engineering (NSE) doctoral student labels her “teenage rebellious phase,” Trainer was quite convinced she would just be wasting the application fee were she to submit an application. She wasn’t even “super sure” she wanted to go to college. But a high-school friend was convinced Trainer would get into a “top school” if she only applied. A bet followed: If Trainer lost, she would have to apply to MIT. Trainer lost — and is glad she did.

      Growing up in Daytona Beach, Florida, good grades were Trainer’s thing. Seeing friends participate in interschool math competitions, Trainer decided she would tag along and soon found she loved them. She remembers being adept at reading the room: If teams were especially struggling over a problem, Trainer figured the answer had to be something easy, like zero or one. “The hardest problems would usually have the most goofball answers,” she laughs.

      Simulating neutron behavior

      As a doctoral student, hard problems in math, specifically computational reactor physics, continue to be Trainer’s forte.

      Her research, under the guidance of Professor Benoit Forget in MIT NSE’s Computational Reactor Physics Group (CRPG), focuses on modeling complicated neutron behavior in reactors. Simulation helps forecast the behavior of reactors before millions of dollars sink into development of a potentially uneconomical unit. Using simulations, Trainer can see “where the neutrons are going, how much heat is being produced, and how much power the reactor can generate.” Her research helps form the foundation for the next generation of nuclear power plants.

      To simulate neutron behavior inside of a nuclear reactor, you first need to know how neutrons will interact with the various materials inside the system. These neutrons can have wildly different energies, thereby making them susceptible to different physical phenomena. For the entirety of her graduate studies, Trainer has been primarily interested in the physics regarding slow-moving neutrons and their scattering behavior.

      When a slow neutron scatters off of a material, it can induce or cancel out molecular vibrations between the material’s atoms. The effect that material vibrations can have on neutron energies, and thereby on reactor behavior, has been heavily approximated over the years. Trainer is primarily interested in chipping away at these approximations by creating scattering data for materials that have historically been misrepresented and by exploring new techniques for preparing slow-neutron scattering data.

      Trainer remembers waiting for a simulation to complete in the early days of the Covid-19 pandemic, when she discovered a way to predict neutron behavior with limited input data. Traditionally, “people have to store large tables of what neutrons will do under specific circumstances,” she says. “I’m really happy about it because it’s this really cool method of sampling what your neutron does from very little information,” Trainer says.

      Amelia Trainer — Modeling complicated neutron behavior in nuclear reactors

      As part of her research, Trainer often works closely with two software packages: OpenMC and NJOY. OpenMC is a Monte Carlo neutron transport simulation code that was developed in the CRPG and is used to simulate neutron behavior in reactor systems. NJOY is a nuclear data processing tool, and is used to create, augment, and prepare material data that is fed into tools like OpenMC. By editing both these codes to her specifications, Trainer is able to observe the effect that “upstream” material data has on the “downstream” reactor calculations. Through this, she hopes to identify additional problems: approximations that could lead to a noticeable misrepresentation of the physics.

      A love of geometry and poetry

      Trainer discovered the coolness of science as a child. Her mother, who cares for indoor plants and runs multiple greenhouses, and her father, a blacksmith and farrier, who explored materials science through his craft, were self-taught inspirations.

      Trainer’s father urged his daughter to learn and pursue any topics that she found exciting and encouraged her to read poems from “Calvin and Hobbes” out loud when she struggled with a speech impediment in early childhood. Reading the same passages every day helped her memorize them. “The natural manifestation of that extended into [a love of] poetry,” Trainer says.

      A love of poetry, combined with Trainer’s propensity for fun, led her to compose an ode to pi as part of an MIT-sponsored event for alumni. “I was really only in it for the cupcake,” she laughs. (Participants received an indulgent treat).

      Play video

      MIT Matters: A Love Poem to Pi

      Computations and nuclear science

      After being accepted at MIT, Trainer knew she wanted to study in a field that would take her skills at the levels they were at — “my math skills were pretty underdeveloped in the grand scheme of things,” she says. An open-house weekend at MIT, where she met with faculty from the NSE department, and the opportunity to contribute to a discipline working toward clean energy, cemented Trainer’s decision to join NSE.

      As a high schooler, Trainer won a scholarship to Embry-Riddle Aeronautical University to learn computer coding and knew computational physics might be more aligned with her interests. After she joined MIT as an undergraduate student in 2014, she realized that the CRPG, with its focus on coding and modeling, might be a good fit. Fortunately, a graduate student from Forget’s team welcomed Trainer’s enthusiasm for research even as an undergraduate first-year. She has stayed with the lab ever since. 

      Research internships at Los Alamos National Laboratory, the creators of NJOY, have furthered Trainer’s enthusiasm for modeling and computational physics. She met a Los Alamos scientist after he presented a talk at MIT and it snowballed into a collaboration where she could work on parts of the NJOY code. “It became a really cool collaboration which led me into a deep dive into physics and data preparation techniques, which was just so fulfilling,” Trainer says. As for what’s next, Trainer was awarded the Rickover fellowship in nuclear engineering by the the Department of Energy’s Naval Reactors Division and will join the program in Pittsburgh after she graduates.

      For many years, Trainer’s cats, Jacques and Monster, have been a constant companion. “Neutrons, computers, and cats, that’s my personality,” she laughs. Work continues to fuel her passion. To borrow a favorite phrase from Spaceman Spiff, Trainer’s favorite “Calvin” avatar, Trainer’s approach to research has invariably been: “Another day, another mind-boggling adventure.” More

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      New process could enable more efficient plastics recycling

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      The accumulation of plastic waste in the oceans, soil, and even in our bodies is one of the major pollution issues of modern times, with over 5 billion tons disposed of so far. Despite major efforts to recycle plastic products, actually making use of that motley mix of materials has remained a challenging issue.

      A key problem is that plastics come in so many different varieties, and chemical processes for breaking them down into a form that can be reused in some way tend to be very specific to each type of plastic. Sorting the hodgepodge of waste material, from soda bottles to detergent jugs to plastic toys, is impractical at large scale. Today, much of the plastic material gathered through recycling programs ends up in landfills anyway. Surely there’s a better way.

      According to new research from MIT and elsewhere, it appears there may indeed be a much better way. A chemical process using a catalyst based on cobalt has been found to be very effective at breaking down a variety of plastics, such as polyethylene (PET) and polypropylene (PP), the two most widely produced forms of plastic, into a single product, propane. Propane can then be used as a fuel for stoves, heaters, and vehicles, or as a feedstock for the production of a wide variety of products — including new plastics, thus potentially providing at least a partial closed-loop recycling system.

      The finding is described today in the open access journal  JACS Au, in a paper by MIT professor of chemical engineering Yuriy Román-Leshkov, postdoc Guido Zichitella, and seven others at MIT, the SLAC National Accelerator Laboratory, and the National Renewable Energy Laboratory.

      Recycling plastics has been a thorny problem, Román-Leshkov explains, because the long-chain molecules in plastics are held together by carbon bonds, which are “very stable and difficult to break apart.” Existing techniques for breaking these bonds tend to produce a random mix of different molecules, which would then require complex refining methods to separate out into usable specific compounds. “The problem is,” he says, “there’s no way to control where in the carbon chain you break the molecule.”

      But to the surprise of the researchers, a catalyst made of a microporous material called a zeolite that contains cobalt nanoparticles can selectively break down various plastic polymer molecules and turn more than 80 percent of them into propane.

      Although zeolites are riddled with tiny pores less than a nanometer wide (corresponding to the width of the polymer chains), a logical assumption had been that there would be little interaction at all between the zeolite and the polymers. Surprisingly, however, the opposite turned out to be the case: Not only do the polymer chains enter the pores, but the synergistic work between cobalt and the acid sites in the zeolite can break the chain at the same point. That cleavage site turned out to correspond to chopping off exactly one propane molecule without generating unwanted methane, leaving the rest of the longer hydrocarbons ready to undergo the process, again and again.

      “Once you have this one compound, propane, you lessen the burden on downstream separations,” Román-Leshkov says. “That’s the essence of why we think this is quite important. We’re not only breaking the bonds, but we’re generating mainly a single product” that can be used for many different products and processes.

      The materials needed for the process, zeolites and cobalt, “are both quite cheap” and widely available, he says, although today most cobalt comes from troubled areas in the Democratic Republic of Congo. Some new production is being developed in Canada, Cuba, and other places. The other material needed for the process is hydrogen, which today is mostly produced from fossil fuels but can easily be made other ways, including electrolysis of water using carbon-free electricity such as solar or wind power.

      The researchers tested their system on a real example of mixed recycled plastic, producing promising results. But more testing will be needed on a greater variety of mixed waste streams to determine how much fouling takes place from various contaminants in the material — such as inks, glues, and labels attached to the plastic containers, or other nonplastic materials that get mixed in with the waste — and how that affects the long-term stability of the process.

      Together with collaborators at NREL, the MIT team is also continuing to study the economics of the system, and analyzing how it can fit into today’s systems for handling plastic and mixed waste streams. “We don’t have all the answers yet,” Román-Leshkov says, but preliminary analysis looks promising.

      The research team included Amani Ebrahim and Simone Bare at the SLAC National Accelerator Laboratory; Jie Zhu, Anna Brenner, Griffin Drake and Julie Rorrer at MIT; and Greg Beckham at the National Renewable Energy Laboratory. The work was supported by the U.S. Department of Energy (DoE), the Swiss National Science Foundation, and the DoE’s Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office (AMO), and Bioenergy Technologies Office (BETO), as part of the the Bio-Optimized Technologies to keep Thermoplastics out of Landfills and the Environment (BOTTLE) Consortium. More

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      Professor Emeritus Richard “Dick” Eckaus, who specialized in development economics, dies at 96

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      Richard “Dick” Eckaus, Ford Foundation International Professor of Economics, emeritus, in the Department of Economics, died on Sept. 11 in Boston. He was 96 years old.

      Eckaus was born in Kansas City, Missouri on April 30, 1926, the youngest of three children to parents who had emigrated from Lithuania. His father, Julius Eckaus, was a tailor, and his mother, Bessie (Finkelstein) Eckaus helped run the business. The family struggled to make ends meet financially but academic success offered Eckaus a way forward.

      He graduated from Westport High School, joined the United States Navy, and was awarded a college scholarship via the V-12 Navy College Training Program during World War II to study electrical engineering at Iowa State University. After graduating in 1944, Eckaus served on a base in New York State until he was discharged in 1946 as lieutenant junior grade.

      He attended Washington University in St. Louis, Missouri, on the GI Bill, graduating in 1948 with a master’s degree in economics, before relocating to Boston and serving as instructor of economics at Babson Institute, and then assistant and associate professor of economics at Brandeis University from 1951 to 1962. He concurrently earned a PhD in economics from MIT in 1954.

      The following year, the American Economic Review published “The Factor Proportions Problem in Economic Development,” a paper written by Eckaus that remained part of the macroeconomics canon for decades. He returned to MIT in 1962 and went on to teach development economics to generations of MIT students, serving as head of the department from 1986 to 1990 and continuing to work there for the remainder of his career.

      The development economist Paul Rosenstein-Rodan (1902-85), Eckaus’ mentor at MIT, took him to live and work first in Italy in 1954 and then in India in 1961. These stints helping governments abroad solidified Eckaus’ commitment to not only excelling in the field, but also creating opportunities for colleagues and students to contribute as well — occasionally in conjunction with the World Bank.

      Longtime colleague Abhijit Banerjee, a Nobel laureate, Ford Foundation International Professor of Economics, and director of the Abdul Latif Jameel Poverty Action Lab at MIT, recalls reading a reprint of Eckaus’ 1955 paper as an undergraduate in India. When he subsequently arrived at MIT as a doctoral candidate, he remembers “trying to tread lightly and not to take up too much space,” around the senior economist. “In fact, he made me feel so welcome,” Banerjee says. “He was both an outstanding scholar and someone who had the modesty and generosity to make younger scholars feel valued and heard.”

      The field of development economics provided Eckaus with a broad, powerful platform to work with governments in developing countries — including India, Egypt, Bhutan, Mexico, and Portugal — to set up economic systems. His development planning models helped governments to forecast where their economies were headed and how public policies could be implemented to shift or accelerate the direction.

      The Government of Portugal awarded Eckaus the Great-Cross of the Order of Prince Henry the Navigator after he brought teams from MIT to assist the country in its peaceful transition to democracy following the 1974 Carnation Revolution. Initiated at the request of the Portuguese Central Bank, these graduate students became some of the most prominent economists of their generation in America. They include Paul Krugman, Andrew Abel, Jeremy I. Bulow, and Kenneth Rogoff.

      His colleague for five decades, Paul Joskow, the Elizabeth and James Killian Professor of Economics at MIT, says that’s no surprise. “He was a real rock of the economics department. He deeply cared about the graduate students and younger faculty. He was a very supportive person.”

      Eckaus was also deeply interested in economic aspects of energy and environment, and in 1991 was instrumental in the formation of the MIT Joint Program on the Science and Policy of Global Change, a program that integrates the natural and social sciences in analysis of global climate threat. As Joint Program co-founder Henry Jacoby observes, “Dick provided crucial ideas as to how that kind of interdisciplinary work might be done at MIT. He was already 65 at the time, and continued for three decades to be active in guiding the research and analysis.”

      Although Eckaus retired officially in 1996, he continued to attend weekly faculty lunches, conduct research, mentor colleagues, and write papers related to climate change and the energy crisis. He leaves behind a trove of more than 100 published papers and eight authored and co-authored books.

      “He was continuously retooling himself and creating new interests. I was impressed by his agility of mind and his willingness to shift to new areas,” says his oldest living friend and peer, Jagdish Bhagwati, Columbia University professor of economics, law, and international relations, emeritus, and director of the Raj Center on Indian Economic Policies. “In their early career, economists usually write short theoretical articles that make large points, and Dick did that with two seminal articles in the leading professional journals of the time, the Quarterly Journal of Economics and the American Economic Review. Then, he shifted his focus to building large computable models. He also diversified by working in an advisory capacity in countries as diverse as Portugal and India. He was a ‘complete’ economist who straddled all styles of economics with distinction.” 

      Eckaus is survived by his beloved wife of 32 years Patricia Leahy Meaney of Brookline, Massachusetts. The two traveled the world, hiked the Alps, and collected pre-Columbian and contemporary art. He is lovingly remembered by his daughter Susan Miller; his step-son James Meaney (Bruna); step-daughter Caitlin Meaney Burrows (Lee); and four grandchildren, Chloe Burrows, Finley Burrows, Brandon Meaney, and Maria Sophia Meaney.

      In lieu of flowers, please consider a donation in Eckaus’ name to MIT Economics (77 Massachusetts Ave., Building E52-300, Cambridge, MA 02139). A memorial in his honor will be held later this year. More