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      in Security

      Food for thought, thought for food

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      According to the Food and Agriculture Organization of the United Nations, approximately 3.1 billion people worldwide were unable to afford a healthy diet in 2020. Meanwhile, in 2021 close to 2.3 billion people were moderately or severely food insecure. Given the strong link between malnutrition and income disparity, the numbers paint a grim picture representing one of the grand challenges of our time.

      “I’m probably an idealist,” says MIT Research Scientist Christopher Mejía Argueta, “but I really believe that if we change our diets and think about ways to help others, we can make a difference — that’s my motivation.”

      Mejía Argueta is the founder and director of the MIT Food and Retail Operations Lab (FaROL). He has more than a decade of experience in supply chain management, optimization, and effective data-driven decision-making on pressing issues like the evolution of end consumers for retail and e-tail supply chains, food waste, and equitable access to nutrition.  

      Supply chain network designs typically focus on minimizing costs without considering the implications (e.g., cost) of changes in consumer behavior. Mejía Argueta and his colleagues at the FaROL, however, are working to understand and design optimal supply chains to create high-performance operations based on consumer choice. “Understanding the significant factors of consumer choice and analyzing their evolution over time becomes critical to designing forward-looking retail operations with data-driven and customer-centric supply chains, inventory management, and distribution systems,” explains Mejía Argueta. 

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      One of his recent projects examined the challenges of small retailers worldwide. These mom-and-pop outlets, or nanostores, account for 50 percent of the global market share and are the primary source of consumer packaged goods for people in urban areas. Worldwide there are nearly 50 million nanostores, each serving between 100-200 households in a community. In India alone, there are 14 million nanostores known as kiranas. And while these retailers are more prevalent in emerging markets, they play an important role in developed markets, particularly in under-resourced communities, and are frequently located in “food deserts,” where they are the only source of essential goods for the community.  

      These small retailers thrive thanks, partly, to their ability to offer the right combination of affordability and convenience while fostering trust with local customers, who often lack access to a supermarket or a grocery store. They often exist in fragmented, densely populated areas where infrastructure and public transportation services are poor and consumers have limited purchasing power. But nanostore shopkeepers and owners are intimately familiar with their customers and their consumption patterns, which means they can connect those consumption patterns or information to the larger supply chain. According to Mejía Argueta, when it comes to the future of retail, nanostores will be the cornerstones of growth in emerging economies. 

      But it’s a complicated scenario. Mom-and-pop shops don’t have the capacity to offer a broad range of products to their customers, and often, they lack access to nutritious food options. Logistically speaking, it is expensive to supply them, and the cost-to-serve (i.e., the logistics cost) is between 10 to 30 percent more expensive than other retailers. According to Mejía Argueta, this has a significant ripple effect, impacting education, productivity, and, eventually, the economic performance of an entire nation.  

      “The high fragmentation of nanostores causes substantial distribution inefficiencies, especially in congested megacities,” he says. “At my lab, we study how to make nanostores more efficient and effective by considering various commercial and logistics strategies while considering inherent technical challenges. We need to serve these small retailers better to help them survive and thrive, to provide a greater impact for underserved communities and the entire economic ecosystem.”

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      Mejía Argueta and his team recently collaborated with Tufts University and the City of Somerville, Massachusetts, to conduct research on food access models in underserved communities. The Somerville Project explored various interventions to supply fresh produce in food desert neighborhoods.

      “A lack of nutrition does not simply mean a lack of food,” Mejía Argueta says. “It can also be caused by an overabundance of unhealthy foods in a given market, which is particularly troublesome for U.S. cities where people in underserved communities don’t have access to healthy food options. We believe that one way to combat the problem of food deserts is to supply these areas with healthy food options affordably and create awareness programs.”  

      The collaborative project saw Mejía Argueta and his colleagues assessing the impact of several intervention schemes designed to empower the end consumer. For example, they implemented a low-cost grocery delivery model similar to Instacart as well as a ride sharing system to transport people from their homes to grocery stores and back. They also collaborated with a nonprofit organization, Partnership for a Healthier America, and began working with retailers to deliver “veggie boxes” in underserved communities. Models like these provide low-income people access to food while providing dignity of choice, Mejía Argueta explains.  

      When it comes to supply chain management research, sustainability and societal impact often fall by the wayside, but Mejía Argueta’s bottom-up approach shirks tradition. “We’re trying to build a community, employing a socially driven perspective because if you work with the community, you gain their trust. If you want to make something sustainable in the long term, people need to trust in these solutions and engage with the ecosystem as a whole.”  

      And to achieve real-world impact, collaboration is key. Mejía Argueta says that government has an important role to play, developing policy to connect the models he and his colleagues develop in academia to societal challenges. Meanwhile, he believes startups and entrepreneurs can function as bridge-builders to link the flows of information, the flows of goods and cash, and even knowledge and security in an ecosystem that suffers from fragmentation and siloed thinking among stakeholders.

      Finally, Mejía Argueta reflects on the role of corporations and his belief that the MIT Industrial Liaison Program is essential to getting his research to the frontline of business challenges. “The Industrial Liaison Program does a fantastic job of connecting our research to real-world scenarios,” he says. “It creates opportunities for us to have meaningful interactions with corporates for real-world impact. I believe strongly in the MIT motto ‘mens et manus,’ and ILP helps drive our research into practice.” More

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      in Energy

      On batteries, teaching, and world peace

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      Over his long career as an electrochemist and professor, Donald Sadoway has earned an impressive variety of honors, from being named one of Time magazine’s 100 most influential people in 2012 to appearing on “The Colbert Report,” where he talked about “renewable energy and world peace,” according to Comedy Central.

      What does he personally consider to be his top achievements?

      “That’s easy,” he says immediately. “For teaching, it’s 3.091,” the MIT course on solid-state chemistry he led for some 18 years. An MIT core requirement, 3.091 is also one of the largest classes at the Institute. In 2003 it was the largest, with 630 students. Sadoway, who retires this year after 45 years in the Department of Materials Science and Engineering, estimates that over the years he’s taught the course to some 10,000 undergraduates.

      A passion for teaching

      Along the way he turned the class into an MIT favorite, complete with music, art, and literature. “I brought in all that enrichment because I knew that 95 percent of the students in that room weren’t going to major in anything chemical and this might be the last class they’d take in the subject. But it’s a requirement. So they’re 18 years old, they’re very smart, and many of them are very bored. You have to find a hook [to reach them]. And I did.”

      In 1995, Sadoway was named a Margaret MacVicar Faculty Fellow, an honor that recognizes outstanding classroom teaching at the Institute. Among the communications in support of his nomination:

      “His contributions are enormous and the class is in rapt attention from beginning to end. His lectures are highly articulate yet animated and he has uncommon grace and style. I was awed by his ability to introduce playful and creative elements into a core lecture…”

      Bill Gates would agree. In the early 2000s Sadoway’s lectures were shared with the world through OpenCourseWare, the web-based publication of MIT course materials. Gates was so inspired by the lectures that he asked to meet with Sadoway to learn more about his research. (Sadoway initially ignored Gates’ email because he thought his account had been hacked by MIT pranksters.)

      Research breakthroughs

      Teaching is not Sadoway’s only passion. He’s also proud of his accomplishments in electrochemistry. The discipline that involves electron transfer reactions is key to everything from batteries to the primary extraction of metals like aluminum and magnesium. “It’s quite wide-ranging,” says the John F. Elliott Professor Emeritus of Materials Chemistry.

      Sadoway’s contributions include two battery breakthroughs. First came the liquid metal battery, which could enable the large-scale storage of renewable energy. “That represents a huge step forward in the transition to green energy,” said António Campinos, president of the European Patent Office, earlier this year when Sadoway won the 2022 European Inventor Award for the invention in the category for Non-European Patent Office Countries.

      On “The Colbert Report,” Sadoway alluded to that work when he told Stephen Colbert that electrochemistry is the key to world peace. Why? Because it could lead to a battery capable of storing energy from the sun when the sun doesn’t shine and otherwise make renewables an important part of the clean energy mix. And that in turn could “plummet the price of petroleum and depose dictators all over the world without one shot being fired,” he recently recalled.

      The liquid metal battery is the focus of Ambri, one of six companies based on Sadoway’s inventions. Bill Gates was the first funder of the company, which formed in 2010 and aims to install its first battery soon. That battery will store energy from a reported 500 megawatts of on-site renewable generation, the same output as a natural gas power plant.

      Then, in August of this year, Sadoway and colleagues published a paper in Nature about “one of the first new battery chemistries in 30 years,” Sadoway says. “I wanted to invent something that was better, much better,” than the expensive lithium-ion batteries used in, for example, today’s electric cars.

      That battery is the focus of Avanti, one of three Sadoway companies formed just last year. The other two are Pure Lithium, to commercialize his inventions related to that element, and Sadoway Labs. The latter, a nonprofit, is essentially “a space to try radical innovations. We’re gonna start working on wild ideas.”

      Another focus of Sadoway’s research: green steel. Steelmaking produces huge amounts of greenhouse gases. Enter Boston Metal, another Sadoway company. This one is developing a new approach to producing steel based on research begun some 25 years ago. Unlike the current technology for producing steel, the Boston Metal approach — molten oxide electrolysis — does not use the element at the root of steel’s problems: carbon. The principal byproduct of the new system? Oxygen.

      In 2012, Sadoway gave a TED talk to 2,000 people on the liquid metal battery. He believes that that talk, which has now been seen by almost 2.5 million people, led to the wider publicity of his work — and science overall — on “The Colbert Report” and elsewhere. “The moral here is that if you step out of your comfort zone, you might be surprised at what can happen,” he concludes.

      Colleagues’ reflections

      “I met Don in 2006 when I was working for the iron and steel industry in Europe on ways to reduce greenhouse gas emissions from the production of those materials,” says Antoine Allanore, professor of metallurgy, Department of Materials Science and Engineering. “He was the same Don Sadoway that you see in recordings of his lectures: very elegant, very charismatic, and passionate about the technical solutions and underlying science of the process we were all investigating; electrolysis. A few years later, when I decided to pursue an academic career, I contacted Don and became a postdoctoral associate in his lab. That ultimately led to my becoming an MIT professor. People don’t believe me, but before I came to MIT the only thing I knew about the Institute was that Noam Chomsky was there … and Don Sadoway. And I felt, that’s a great place to be. And I stayed because I saw the exceptional things that can be accomplished at MIT and Don is the perfect example of that.”

      “I had the joy of meeting Don when I first arrived on the MIT campus in 1994,” recalls Felice Frankel, research scientist in the MIT departments of Chemical Engineering and Mechanical Engineering. “I didn’t have to talk him into the idea that researchers needed to take their images and graphics more seriously.  He got it — that it wasn’t just about pretty pictures. He was an important part of our five-year National Science Foundation project — Picturing to Learn — to bring that concept into the classroom. How lucky that was for me!”

      “Don has been a friend and mentor since we met in 1995 when I was an MIT senior,” says Luis Ortiz, co-founder and chief executive officer, Avanti Battery Co. “One story that is emblematic of Don’s insistence on excellence is from when he and I met with Bill Gates about the challenges in addressing climate change and how batteries could be the linchpin in solving them. I suggested that we create our presentation in PowerPoint [Microsoft software]. Don balked. He insisted that we present using Keynote on his MacBook Air, because ‘it looks so much better.’ I was incredulous that he wanted to walk into that venue exclusively using Apple products. Of course, he won the argument, but not without my admonition that there had better not be even a blip of an issue. In the meeting room, Microsoft’s former chief technology officer asked Don if he needed anything to hook up to the screen, ‘we have all those dongles.’ Don declined, but gave me that knowing look and whispered, ‘You see, they know, too.’ I ate my crow and we had a great long conversation without any issues.”

      “I remember when I first started working with Don on the liquid metal battery project at MIT, after I had chosen it as the topic for my master’s of engineering thesis,” adds David Bradwell, co-founder and chief technology officer, Ambri. “I was a wide-eyed graduate student, sitting in his office, amongst his art deco decorations, unique furniture, and historical and stylistic infographics, and from our first meeting, I could see Don’s passion for coming up with new and creative, yet practical scientific ideas, and for working on hard problems, in service of society. Don’s approaches always appear to be unconventional — wanting to stand out in a crowd, take the path less trodden, both based on his ideas, and his sense of style. It’s been an amazing journey working with him over the past decade-and-a-half, and I remain excited to see what other new, unconventional ideas, he can bring to this world.” More

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      in Security

      Pesticide innovation takes top prize at Collegiate Inventors Competition

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      On Oct. 12, MIT mechanical engineering alumnus Vishnu Jayaprakash SM ’19, PhD ’22 was named the first-place winner in the graduate category of the Collegiate Inventors Competition. The annual competition, which is organized by the National Inventors Hall of Fame, celebrates college and university student inventors. Jayaprakash won for his pesticide innovation AgZen-Cloak, which he developed while he was a student in the lab of Kripa Varanasi, a professor of mechanical engineering.

      Currently, only 2 percent of pesticide spray is retained by crops. Many crops are naturally water-repellent, causing pesticide-laden water to bounce off of them. Farmers are forced to over-spray significantly to ensure proper spray coverage on their crops. Not only does this waste expensive pesticides, but it also comes at an environmental cost.

      Runoff from pesticide treatment pollutes soil and nearby streams. Droplets can travel in the air, leading to illness and death in nearby populations. It is estimated that each year, pesticide pollution causes between 20,000 and 200,000 deaths, and up to 385 million acute illnesses like cancer, birth defects, and neurological conditions.   

      With his invention AgZen-Cloak, Jayaprakash has found a way to keep droplets of water containing pesticide from bouncing off crops by “cloaking” the droplets in a small amount of plant-derived oil. As a result, farmers could use just one-fifth the amount of spray, minimizing water waste and cost for farmers and eliminating airborne pollution and toxic runoff. It also improves pesticide retention, which can lead to higher crop yield.

      “By cloaking each droplet with a minute quantity of a plant-based oil, we promote water retention on even the most water-repellent plant surfaces,” says Jayaprakash. “AgZen-Cloak presents a universal, inexpensive, and environmentally sustainable way to prevent pesticide overuse and waste.”

      Farming is in Jayaprakash’s DNA. His family operates a 10-acre farm near Chennai, India, where they grow rice and mangoes. Upon joining the Varanasi Research Group as a graduate student, Jayaprakash was instantly drawn to Varanasi’s work on pesticides in agriculture.

      “Growing up, I would spray crops on my family farm wearing a backpack sprayer. So, I’ve always wanted to work on research that made farmer’s lives easier,” says Jayaprakash, who serves as CEO of the startup AgZen.

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      2022 World Food Day First Prize Winner – AgZen Cloak: Reducing Pesticide Pollution and Waste

      Helping droplets stick

      Varanasi and his lab at MIT work on what is known as interfacial phenomena — or the study of what happens when different phases come into contact and interact with one another. Understanding how a liquid interacts with a solid or how a liquid reacts to a certain gas has endless applications, which explains the diversity of the research Varanasi has conducted over the years. He and his team have developed solutions for everything from consumer product packaging to power plant emissions.

      In 2009, Varanasi gave a talk at the U.S. Department of Agriculture (USDA). There, he learned from the USDA just how big of a problem runoff from pesticide spray was for farmers around the world.
      A green cabbage leaf is treated with pesticide-laden water using conventional spraying. Image courtesy of AgZen.A green cabbage leaf is treated with pesticide-laden water using AgZen’s technology. By cloaking droplets in a tiny amount of plant-derived oil, the droplets stick to the leaf, minimizing over-spraying, waste, and pollution. Image courtesy of AgZen.He enlisted the help of then-graduate student Maher Damak SM ’15, PhD ’18 to apply their work in interfacial phenomena to pesticide sprays. Over the next several years, the Varanasi Research Group developed a technology that utilized electrically charged polymers to keep droplets from bouncing off hydrophobic surfaces. When droplets containing positively and negatively charged additives meet, their surface chemistry allows them to stick to a plant’s surface.

      Using polyelectrolytes, the researchers could reduce the amount of spray needed to cover a crop by tenfold in the lab. This motivated the Varanasi Research Group to pursue three years of field trials with various commercial growers around the world, where they were able to demonstrate significant savings for farmers.

      “We got fantastic feedback on our technology from farmers. We are really excited to change the paradigm for agriculture. Not only is it good for the environment, but we’ve heard from farmers that they love it. If we can put money back into farms, it helps society as a whole,” adds Varanasi.

      In response to the positive feedback, Varanasi and Jayaprakash co-founded startup AgZen in 2020. 

      When field testing their polyelectrolyte technology, Varanasi and Jayaprakash came up with the idea to explore the use of a fully plant-based material to help farmers achieve the same savings. 

      Cloaking droplets and engineering nozzles

      Jayaprakash found that by cloaking a small amount of plant-derived oil around a water droplet, droplets stick to plant surfaces that would typically repel water. After conducting many studies in the lab, he found that the oil only needs to make up 0.1 percent of a droplet’s total volume to stick to crops and provide total, uniform coverage.

      While his cloaking solution worked in the lab, Jayaprakash knew that to have a tangible impact in the real world he needed to find an easy, low-cost way for farmers to coat pesticide spray droplets in oil.

      Jayaprakash focused on spray nozzles. He developed a proprietary nozzle that coats each droplet with a small amount of oil as they are being formed. The nozzles can easily be added to any hose or farming equipment.

      “What we’ve done is figured out a smart way to cloak these droplets by using a very small quantity of oil on the outside of each drop. Because of that, we get this drastic improvement in performance that can really be a game-changer for farmers,” says Jayaprakash.

      In addition to improving pesticide retention in crops, the AgZen-Cloak solves a second problem. Since large droplets are prone to break apart and bounce off crops, historically, farmers have sprayed pesticide in tiny, mist-like droplets. These fine droplets are often carried by the wind, increasing pesticide pollution in nearby areas. 

      When AgZen-Cloak is used, the pesticide-laden droplets can be larger and still stick to crops. These larger droplets aren’t carried by the wind, decreasing the risk of pollution and minimizing the health impacts on local populations.  

      “We’re actually solving two problems with one solution. With the cloaking technology, we can spray much larger droplets that aren’t prone to wind drift and they can stick to the plant,” Jayaprakash adds.

      Bringing AgZen-Cloaks to farmers around the world

      This spring, Varanasi encouraged Jayaprakash to submit AgZen-Cloak to the Collegiate Inventors Competition. Out of hundreds of applications, Jayaprakash was one of 25 student inventors to be chosen as a finalist.

      On Oct. 12, Jayaprakash presented his technology to a panel of judges composed of National Inventors Hall of Fame inductees and U.S. Patent and Trademark Office officials. Meeting with such an illustrious group of inventors and officials left an impression on Jayaprakash.

      “These are people who have invented things that have changed the world. So, to get their feedback on what we’re doing was incredibly valuable,” he says. Jayaprakash received a $10,000 prize for being named the first-place graduate winner.

      As full-time CEO of AgZen, Jayaprakash is shifting focus to field testing and commercialization. He and the AgZen team have already conducted field testing across the world at locations including a Prosecco vineyard outside of Venice, a ranch in California, and Ward’s Berry Farm in Sharon, Massachusetts. The University of Massachusetts at Amherst’s vegetable extension program, led by their program director Susan Scheufele, recently concluded a field test that validated AgZen’s on-field performance.

      Two days after his win at the Collegiate Inventors Competition, Jayaprakash was named the first prize winner of the MIT Abdul Latif Jamel Water and Food Systems Lab World Food Day student video competition. Hours later, he flew across the country to attend an agricultural tech conference in California, eager to meet with farmers and discuss plans for rolling out AgZen’s innovations to farms everywhere. More

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      in Energy

      Simplifying the production of lithium-ion batteries

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      When it comes to battery innovations, much attention gets paid to potential new chemistries and materials. Often overlooked is the importance of production processes for bringing down costs.

      Now the MIT spinout 24M Technologies has simplified lithium-ion battery production with a new design that requires fewer materials and fewer steps to manufacture each cell. The company says the design, which it calls “SemiSolid” for its use of gooey electrodes, reduces production costs by up to 40 percent. The approach also improves the batteries’ energy density, safety, and recyclability.

      Judging by industry interest, 24M is onto something. Since coming out of stealth mode in 2015, 24M has licensed its technology to multinational companies including Volkswagen, Fujifilm, Lucas TVS, Axxiva, and Freyr. Those last three companies are planning to build gigafactories (factories with gigawatt-scale annual production capacity) based on 24M’s technology in India, China, Norway, and the United States.

      “The SemiSolid platform has been proven at the scale of hundreds of megawatts being produced for residential energy-storage systems. Now we want to prove it at the gigawatt scale,” says 24M CEO Naoki Ota, whose team includes 24M co-founder, chief scientist, and MIT Professor Yet-Ming Chiang.

      Establishing large-scale production lines is only the first phase of 24M’s plan. Another key draw of its battery design is that it can work with different combinations of lithium-ion chemistries. That means 24M’s partners can incorporate better-performing materials down the line without substantially changing manufacturing processes.

      The kind of quick, large-scale production of next-generation batteries that 24M hopes to enable could have a dramatic impact on battery adoption across society — from the cost and performance of electric cars to the ability of renewable energy to replace fossil fuels.

      “This is a platform technology,” Ota says. “We’re not just a low-cost and high-reliability operator. That’s what we are today, but we can also be competitive with next-generation chemistry. We can use any chemistry in the market without customers changing their supply chains. Other startups are trying to address that issue tomorrow, not today. Our tech can address the issue today and tomorrow.”

      A simplified design

      Chiang, who is MIT’s Kyocera Professor of Materials Science and Engineering, got his first glimpse into large-scale battery production after co-founding another battery company, A123 Systems, in 2001. As that company was preparing to go public in the late 2000s, Chiang began wondering if he could design a battery that would be easier to manufacture.

      “I got this window into what battery manufacturing looked like, and what struck me was that even though we pulled it off, it was an incredibly complicated manufacturing process,” Chiang says. “It derived from magnetic tape manufacturing that was adapted to batteries in the late 1980s.”

      In his lab at MIT, where he’s been a professor since 1985, Chiang started from scratch with a new kind of device he called a “semi-solid flow battery” that pumps liquids carrying particle-based electrodes to and from tanks to store a charge.

      In 2010, Chiang partnered with W. Craig Carter, who is MIT’s POSCO Professor of Materials Science and Engineering, and the two professors supervised a student, Mihai Duduta ’11, who explored flow batteries for his undergraduate thesis. Within a month, Duduta had developed a prototype in Chiang’s lab, and 24M was born. (Duduta was the company’s first hire.)

      But even as 24M worked with MIT’s Technology Licensing Office (TLO) to commercialize research done in Chiang’s lab, people in the company including Duduta began rethinking the flow battery concept. An internal cost analysis by Carter, who consulted for 24M for several years, ultimately lead the researchers to change directions.

      That left the company with loads of the gooey slurry that made up the electrodes in their flow batteries. A few weeks after Carter’s cost analysis, Duduta, then a senior research scientist at 24M, decided to start using the slurry to assemble batteries by hand, mixing the gooey electrodes directly into the electrolyte. The idea caught on.

      The main components of batteries are the positive and negatively charged electrodes and the electrolyte material that allows ions to flow between them. Traditional lithium-ion batteries use solid electrodes separated from the electrolyte by layers of inert plastics and metals, which hold the electrodes in place.

      Stripping away the inert materials of traditional batteries and embracing the gooey electrode mix gives 24M’s design a number of advantages.

      For one, it eliminates the energy-intensive process of drying and solidifying the electrodes in traditional lithium-ion production. The company says it also reduces the need for more than 80 percent of the inactive materials in traditional batteries, including expensive ones like copper and aluminum. The design also requires no binder and features extra thick electrodes, improving the energy density of the batteries.

      “When you start a company, the smart thing to do is to revisit all of your assumptions  and ask what is the best way to accomplish your objectives, which in our case was simply-manufactured, low-cost batteries,” Chiang says. “We decided our real value was in making a lithium-ion suspension that was electrochemically active from the beginning, with electrolyte in it, and you just use the electrolyte as the processing solvent.”

      In 2017, 24M participated in the MIT Industrial Liaison Program’s STEX25 Startup Accelerator, in which Chiang and collaborators made critical industry connections that would help it secure early partnerships. 24M has also collaborated with MIT researchers on projects funded by the Department of Energy.

      Enabling the battery revolution

      Most of 24M’s partners are eyeing the rapidly growing electric vehicle (EV) market for their batteries, and the founders believe their technology will accelerate EV adoption. (Battery costs make up 30 to 40 percent of the price of EVs, according to the Institute for Energy Research).

      “Lithium-ion batteries have made huge improvements over the years, but even Elon Musk says we need some breakthrough technology,” Ota says, referring to the CEO of EV firm Tesla. “To make EVs more common, we need a production cost breakthrough; we can’t just rely on cost reduction through scaling because we already make a lot of batteries today.”

      24M is also working to prove out new battery chemistries that its partners could quickly incorporate into their gigafactories. In January of this year, 24M received a grant from the Department of Energy’s ARPA-E program to develop and scale a high-energy-density battery that uses a lithium metal anode and semi-solid cathode for use in electric aviation.

      That project is one of many around the world designed to validate new lithium-ion battery chemistries that could enable a long-sought battery revolution. As 24M continues to foster the creation of large scale, global production lines, the team believes it is well-positioned to turn lab innovations into ubiquitous, world-changing products.

      “This technology is a platform, and our vision is to be like Google’s Android [operating system], where other people can build things on our platform,” Ota says. “We want to do that but with hardware. That’s why we’re licensing the technology. Our partners can use the same production lines to get the benefits of new chemistries and approaches. This platform gives everyone more options.” More

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      in Energy

      Doubling down on sustainability innovation in Kendall Square

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      From its new headquarters in Cambridge’s Kendall Square, The Engine is investing in a number of “tough tech” startups seeking to transform the world’s energy systems. A few blocks away, the startup Inari is using gene editing to improve seeds’ resilience to climate change. On the MIT campus nearby, researchers are working on groundbreaking innovations to meet the urgent challenges our planet faces.

      Kendall Square is known as the biotech capital of the world, but as the latest annual meeting of the Kendal Square Association (KSA) made clear, it’s also a thriving hub of sustainability-related innovation.

      The Oct. 20 event, which began at MIT’s Welcome Center before moving to the MIT Museum for a panel discussion, brought together professionals from across Cambridge’s prolific innovation ecosystem — not just entrepreneurs working at startups, but also students, restaurant and retail shop owners, and people from local nonprofits.

      Titled “[Re] Imagining a Sustainable Future,” the meeting highlighted advances in climate change technologies that are afoot in Kendall Square, to help inspire and connect the community as it works toward common sustainability goals.

      “Our focus is on building a better future together — and together is the most important word there,” KSA Executive Director Beth O’Neill Maloney said in her opening remarks. “This is an incredibly innovative ecosystem and community that’s making changes that affect us here in Kendall Square and far, far beyond.”

      The pace of change

      The main event of the evening was a panel discussion moderated by Lee McGuire, the chief communications officer of the Broad Institute of MIT and Harvard. The panel featured Stuart Brown, chief financial officer at Inari; Emily Knight, chief operating officer at The Engine; and Joe Higgins, vice president for campus services and stewardship at MIT.

      “Sustainability is obviously one of the most important — if not the most important — challenge facing us as a society today,” said McGuire, opening the discussion. “Kendall Square is known for its work in biotech, life sciences, AI, and climate, and the more we dug into it the more we realized how interconnected all of those things are. The talent in Kendall Square wants to work on problems relevant for humanity, and the tools and skills you need for that can be very similar depending on the problem you’re working on.”

      Higgins, who oversees the creation of programs to reduce MIT’s environmental impact and improve the resilience of campus operations, focused on the enormity of the problem humanity is facing. He showed the audience a map of the U.S. power grid, with power plants and transmission lines illuminated in a complex web across the country, to underscore the scale of electrification that will be needed to mitigate the worst effects of climate change.

      “The U.S. power grid is the largest machine ever made by mankind,” Higgins said. “It’s been developed over 100 years; it has 7,000 generating plants that feed into it every day; it has 7 million miles of cable and wires; there are transformers and substations; and it lives in every single one of your walls. But people don’t think about it that much.”

      Many cities, states, and organizations like MIT have made commitments to shift to 100 percent clean energy in coming decades. Higgins wanted the audience to try to grasp what that’s going to take.

      “Hundreds of millions of devices and equipment across the planet are going to have to be swapped from fossil fuel to electric-based,” Higgins said. “Our cars, appliances, processes in industry, like making steel and concrete, are going to need to come from this grid. It’ll need to undergo a major modernization and transformation. The good news is it’s already changing.”

      Multiple panelists pointed to developments like the passing of the Inflation Reduction Act to show there was progress being made in reaching urgent sustainability goals.

      “There is a tide change coming, and it’s not only being driven by private capital,” Knight said. “There’s a huge opportunity here, and it’s a really important part of this [Kendall Square] ecosystem.”

      Chief among the topics of discussion was technology development. Even as leaders implement today’s technologies to decarbonize, people in Kendall Square keep a close eye on the new tech being developed and commercialized nearby.

      “I was trying to think about where we are with gene editing,” Brown said. “CRISPR’s been around for 10 years. Compare that to video games. Pong was the first video game when it came out in 1972. Today you have Chess.com using artificial intelligence to power chess games. On gene editing and a lot of these other technologies, we’re much closer to Pong than we are to where it’s going to be. We just can’t imagine today the technology changes we’re going to see over the next five to 10 years.”

      In that regard, Knight discussed some of the promising portfolio companies of The Engine, which invests in early stage, technologically innovative companies. In particular, she highlighted two companies seeking to transform the world’s energy systems with entirely new, 100 percent clean energy sources. MIT spinout Commonwealth Fusion Systems is working on nuclear fusion reactors that could provide abundant, safe, and constant streams of clean energy to our grids, while fellow MIT spinout Quaise Energy is seeking to harvest a new kind of deep geothermal energy using millimeter wave drilling technology.

      “All of our portfolio companies have a focus on sustainability in one way or another,” Knight said. “People who are working on these very hard technologies will change the world.”

      Knight says the kind of collaboration championed by the KSA is important for startups The Engine invests in.

      “We know these companies need a lot of people around them, whether from government, academia, advisors, corporate partners, anyone who can help them on their path, because for a lot of them this is a new path and a new market,” Knight said.

      Reasons for hope

      The KSA is made up of over 150 organizations across Kendall Square. From major employers like Sanofi, Pfizer, MIT, and the Broad Institute to local nonprofit organizations, startups, and independent shops and restaurants, the KSA represents the entire Kendall ecosystem.

      O’Neill Maloney celebrated a visible example of sustainability in Kendall Square early on by the Charles River Conservancy, which has built a floating wetland designed to naturally remove harmful algae blooms from Charles River.

      Other examples of sustainability work in the neighborhood can be found at MIT. Under its “Fast Forward” climate action plan, the Institute has set a goal of eliminating direct emissions from its campus by 2050, including a near-term milestone of achieving net-zero emissions by 2026. Since 2014, when MIT launched a five-year plan for action on climate change, net campus emissions have already been cut by 20 percent by making its campus buildings more energy efficient, transitioning to electric vehicles, and enabling large-scale renewable energy projects, among other strategies.

      In the face of a daunting global challenge, such milestones are reason for optimism.

      “If anybody’s going to be able to do this [shift to 100 percent clean energy] and show how it can be done at an urban, city scale, it’s probably MIT and the city of Cambridge,” McGuire said. “We have a lot of good ingredients to figure this out.”

      Throughout the night, many speakers, attendees, and panelists echoed that sentiment. They said they see plenty of reasons for hope.

      “I’m absolutely optimistic,” Higgins said. “I’m seeing utility companies working with businesses working with regulators — people are coming together on this topic. And one of these new technologies being commercialized is going to change things before 2030, whether its fusion, deep geothermal, small modular nuclear reactors, the technology is just moving so quickly.” More

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      in Environment

      MADMEC winner identifies sustainable greenhouse-cooling materials

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      The winners of this year’s MADMEC competition identified a class of materials that could offer a more efficient way to keep greenhouses cool.

      After Covid-19 put the materials science competition on pause for two years, on Tuesday SmartClime, a team made up of three MIT graduate students, took home the first place, $10,000 prize.

      The team showed that a type of material that changes color in response to an electric voltage could reduce energy usage and save money if coated onto the panes of glass in greenhouses.

      “This project came out of our love of gardening,” said SmartClime team member and PhD candidate Isabella Caruso in the winning presentation. “Greenhouses let you grow things year-round, even in New England, but even greenhouse pros need to use heating furnaces in the winter and ventilation in the summer. All of that can be very labor- and energy-intensive.”

      Current options to keep greenhouses cool include traditional air conditioning units, venting and fans, and simple cloth. To develop a better solution, the team looked through scientific papers to find materials with the right climate control properties.

      Two classes of materials that looked promising were thermochromic coatings, which change color based on temperature, and electrochromic solutions, which change color based on electric voltage.

      Creating both the thermochromic and electrochromic solutions required the team to assemble nanoparticles and spin-coat them onto glass substrates. In lab tests, the electrochromic material performed well, turning a deep bluish hue to reduce the heat coming into the greenhouse while also letting in enough light for plants. Specifically, the electrochromic cell kept its test box about 1 to 3 degrees Celsius cooler than the test box coated in regular glass.

      The team estimated that greenhouse owners could make back the added costs of the electrochromic paneling through savings on other climate-control measures. Additional benefits of using the material include reducing heat-related crop losses, increasing crop yields, and reducing water requirements.

      Hosted by MIT’s Department of Materials Science and Engineering (DMSE), the competition was the culmination of team projects that began last spring and included a series of design challenges throughout the summer. Each team received guidance, access to equipment and labs, and up to $1,000 in funding to build and test their prototypes.

      “It’s great to be back and to have everyone here in person,” Mike Tarkanian, a senior lecturer in DMSE and coordinator of MADMEC, said at the event. “I’ve enjoyed getting back to normal, doing the design challenges over the summer and celebrating with everyone here today.”

      The second-place prize was split between YarnZ, which identified a nanofiber yarn that is more sustainable than traditional textile fibers, and WasteAway, which has developed a waste bin monitoring device that can identify the types of items thrown into trash and recycling bins and flag misplaced items.

      YarnZ (which stands for Yarns Are Really NanofiberZ), developed a nanofiber yarn that is more degradable than traditional microfiber yarns without sacrificing on performance.

      A large chunk of the waste and emissions in the clothing industry come from polyester, a slow-degrading polymer that requires an energy-intensive melt spinning process before it’s spun into the fibers of our clothes.

      “The biggest thing I want to impress upon you today is that the textile industry is a major greenhouse gas-producing entity and also produces a huge amount of waste,” YarnZ member and PhD candidate Natalie Mamrol said in the presentation.

      To replace polyester, the team developed a continuous process in which a type of nanofiber film collects in a water bath before being twisted into yarn. In subsequent tests, the nanofiber-based yarn degraded more quicky than traditional microfibers and showed comparable durability. YarnZ believes this early data should encourage others to explore nanofibers as a viable replacement in the clothing industry and to invest in scaling the approach for industrial settings.

      WasteAway’s system includes a camera that sits on top of trash bins and uses artificial intelligence to recognize items that people throw away.

      Of the 300 million tons of waste generated in the U.S. each year, more than half ends up in landfills. A lot of that waste could have been composted or recycled but was misplaced during disposal.

      “When someone throws something into the bin, our sensor detects the motion and captures an image,” explains WasteAway’s Melissa Stok, an undergraduate at MIT. “Those images are then processed by our machine-learning algorithm to find contamination.”

      Each device costs less than $30, and the team says that cost could go down as parts are bought at larger scales. The insights gleaned from the device could help waste management officials identify contaminated trash piles as well as inform education efforts by revealing common mistakes people make.

      Overall, Tarkanian believes the competition was a success not only because of the final results, but because of the experience the students got throughout the MADMEC program, which included several smaller, hands-on competitions involving laser cutters, 3-D printers, soldering irons, and other equipment many students said they had never used before.

      “They end up getting into the lab through these design challenges, which have them compete in various engineering tasks,” Tarkanian says. “It helps them get comfortable designing and prototyping, and they often end up using those tools in their research later.” More

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      in Energy

      Processing waste biomass to reduce airborne emissions

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      To prepare fields for planting, farmers the world over often burn corn stalks, rice husks, hay, straw, and other waste left behind from the previous harvest. In many places, the practice creates huge seasonal clouds of smog, contributing to air pollution that kills 7 million people globally a year, according to the World Health Organization.

      Annually, $120 billion worth of crop and forest residues are burned in the open worldwide — a major waste of resources in an energy-starved world, says Kevin Kung SM ’13, PhD ’17. Kung is working to transform this waste biomass into marketable products — and capitalize on a billion-dollar global market — through his MIT spinoff company, Takachar.

      Founded in 2015, Takachar develops small-scale, low-cost, portable equipment to convert waste biomass into solid fuel using a variety of thermochemical treatments, including one known as oxygen-lean torrefaction. The technology emerged from Kung’s PhD project in the lab of Ahmed Ghoniem, the Ronald C. Crane (1972) Professor of Mechanical Engineering at MIT.

      Biomass fuels, including wood, peat, and animal dung, are a major source of carbon emissions — but billions of people rely on such fuels for cooking, heating, and other household needs. “Currently, burning biomass generates 10 percent of the primary energy used worldwide, and the process is used largely in rural, energy-poor communities. We’re not going to change that overnight. There are places with no other sources of energy,” Ghoniem says.

      What Takachar’s technology provides is a way to use biomass more cleanly and efficiently by concentrating the fuel and eliminating contaminants such as moisture and dirt, thus creating a “clean-burning” fuel — one that generates less smoke. “In rural communities where biomass is used extensively as a primary energy source, torrefaction will address air pollution head-on,” Ghoniem says.

      Thermochemical treatment densifies biomass at elevated temperatures, converting plant materials that are typically loose, wet, and bulky into compact charcoal. Centralized processing plants exist, but collection and transportation present major barriers to utilization, Kung says. Takachar’s solution moves processing into the field: To date, Takachar has worked with about 5,500 farmers to process 9,000 metric tons of crops.

      Takachar estimates its technology has the potential to reduce carbon dioxide equivalent emissions by gigatons per year at scale. (“Carbon dioxide equivalent” is a measure used to gauge global warming potential.) In recognition, in 2021 Takachar won the first-ever Earthshot Prize in the clean air category, a £1 million prize funded by Prince William and Princess Kate’s Royal Foundation.

      Roots in Kenya

      As Kung tells the story, Takachar emerged from a class project that took him to Kenya — which explains the company’s name, a combination of takataka, which mean “trash” in Swahili, and char, for the charcoal end product.

      It was 2011, and Kung was at MIT as a biological engineering grad student focused on cancer research. But “MIT gives students big latitude for exploration, and I took courses outside my department,” he says. In spring 2011, he signed up for a class known as 15.966 (Global Health Delivery Lab) in the MIT Sloan School of Management. The class brought Kung to Kenya to work with a nongovernmental organization in Nairobi’s Kibera, the largest urban slum in Africa.

      “We interviewed slum households for their views on health, and that’s when I noticed the charcoal problem,” Kung says. The problem, as Kung describes it, was that charcoal was everywhere in Kibera — piled up outside, traded by the road, and used as the primary fuel, even indoors. Its creation contributed to deforestation, and its smoke presented a serious health hazard.

      Eager to address this challenge, Kung secured fellowship support from the MIT International Development Initiative and the Priscilla King Gray Public Service Center to conduct more research in Kenya. In 2012, he formed Takachar as a team and received seed money from the MIT IDEAS Global Challenge, MIT Legatum Center for Development and Entrepreneurship, and D-Lab to produce charcoal from household organic waste. (This work also led to a fertilizer company, Safi Organics, that Kung founded in 2016 with the help of MIT IDEAS. But that is another story.)

      Meanwhile, Kung had another top priority: finding a topic for his PhD dissertation. Back at MIT, he met Alexander Slocum, the Walter M. May and A. Hazel May Professor of Mechanical Engineering, who on a long walk-and-talk along the Charles River suggested he turn his Kenya work into a thesis. Slocum connected him with Robert Stoner, deputy director for science and technology at the MIT Energy Initiative (MITEI) and founding director of MITEI’s Tata Center for Technology and Design. Stoner in turn introduced Kung to Ghoniem, who became his PhD advisor, while Slocum and Stoner joined his doctoral committee.

      Roots in MIT lab

      Ghoniem’s telling of the Takachar story begins, not surprisingly, in the lab. Back in 2010, he had a master’s student interested in renewable energy, and he suggested the student investigate biomass. That student, Richard Bates ’10, SM ’12, PhD ’16, began exploring the science of converting biomass to more clean-burning charcoal through torrefaction.

      Most torrefaction (also known as low-temperature pyrolysis) systems use external heating sources, but the lab’s goal, Ghoniem explains, was to develop an efficient, self-sustained reactor that would generate fewer emissions. “We needed to understand the chemistry and physics of the process, and develop fundamental scaling models, before going to the lab to build the device,” he says.

      By the time Kung joined the lab in 2013, Ghoniem was working with the Tata Center to identify technology suitable for developing countries and largely based on renewable energy. Kung was able to secure a Tata Fellowship and — building on Bates’ research — develop the small-scale, practical device for biomass thermochemical conversion in the field that launched Takachar.

      This device, which was patented by MIT with inventors Kung, Ghoniem, Stoner, MIT research scientist Santosh Shanbhogue, and Slocum, is self-contained and scalable. It burns a little of the biomass to generate heat; this heat bakes the rest of the biomass, releasing gases; the system then introduces air to enable these gases to combust, which burns off the volatiles and generates more heat, keeping the thermochemical reaction going.

      “The trick is how to introduce the right amount of air at the right location to sustain the process,” Ghoniem explains. “If you put in more air, that will burn the biomass. If you put in less, there won’t be enough heat to produce the charcoal. That will stop the reaction.”

      About 10 percent of the biomass is used as fuel to support the reaction, Kung says, adding that “90 percent is densified into a form that’s easier to handle and utilize.” He notes that the research received financial support from the Abdul Latif Jameel Water and Food Systems Lab and the Deshpande Center for Technological Innovation, both at MIT. Sonal Thengane, another postdoc in Ghoniem’s lab, participated in the effort to scale up the technology at the MIT Bates Lab (no relation to Richard Bates).

      The charcoal produced is more valuable per ton and easier to transport and sell than biomass, reducing transportation costs by two-thirds and giving farmers an additional income opportunity — and an incentive not to burn agricultural waste, Kung says. “There’s more income for farmers, and you get better air quality.”

      Roots in India

      When Kung became a Tata Fellow, he joined a program founded to take on the biggest challenges of the developing world, with a focus on India. According to Stoner, Tata Fellows, including Kung, typically visit India twice a year and spend six to eight weeks meeting stakeholders in industry, the government, and in communities to gain perspective on their areas of study.

      “A unique part of Tata is that you’re considering the ecosystem as a whole,” says Kung, who interviewed hundreds of smallholder farmers, met with truck drivers, and visited existing biomass processing plants during his Tata trips to India. (Along the way, he also connected with Indian engineer Vidyut Mohan, who became Takachar’s co-founder.)

      “It was very important for Kevin to be there walking about, experimenting, and interviewing farmers,” Stoner says. “He learned about the lives of farmers.”

      These experiences helped instill in Kung an appreciation for small farmers that still drives him today as Takachar rolls out its first pilot programs, tinkers with the technology, grows its team (now up to 10), and endeavors to build a revenue stream. So, while Takachar has gotten a lot of attention and accolades — from the IDEAS award to the Earthshot Prize — Kung says what motivates him is the prospect of improving people’s lives.

      The dream, he says, is to empower communities to help both the planet and themselves. “We’re excited about the environmental justice perspective,” he says. “Our work brings production and carbon removal or avoidance to rural communities — providing them with a way to convert waste, make money, and reduce air pollution.”

      This article appears in the Spring 2022 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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      in Energy

      Cracking the carbon removal challenge

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      By most measures, MIT chemical engineering spinoff Verdox has been enjoying an exceptional year. The carbon capture and removal startup, launched in 2019, announced $80 million in funding in February from a group of investors that included Bill Gates’ Breakthrough Energy Ventures. Then, in April — after recognition as one of the year’s top energy pioneers by Bloomberg New Energy Finance — the company and partner Carbfix won a $1 million XPRIZE Carbon Removal milestone award. This was the first round in the Musk Foundation’s four-year, $100 million-competition, the largest prize offered in history.

      “While our core technology has been validated by the significant improvement of performance metrics, this external recognition further verifies our vision,” says Sahag Voskian SM ’15, PhD ’19, co-founder and chief technology officer at Verdox. “It shows that the path we’ve chosen is the right one.”

      The search for viable carbon capture technologies has intensified in recent years, as scientific models show with increasing certainty that any hope of avoiding catastrophic climate change means limiting CO2 concentrations below 450 parts per million by 2100. Alternative energies will only get humankind so far, and a vast removal of CO2 will be an important tool in the race to remove the gas from the atmosphere.

      Voskian began developing the company’s cost-effective and scalable technology for carbon capture in the lab of T. Alan Hatton, the Ralph Landau Professor of Chemical Engineering at MIT. “It feels exciting to see ideas move from the lab to potential commercial production,” says Hatton, a co-founder of the company and scientific advisor, adding that Verdox has speedily overcome the initial technical hiccups encountered by many early phase companies. “This recognition enhances the credibility of what we’re doing, and really validates our approach.”

      At the heart of this approach is technology Voskian describes as “elegant and efficient.” Most attempts to grab carbon from an exhaust flow or from air itself require a great deal of energy. Voskian and Hatton came up with a design whose electrochemistry makes carbon capture appear nearly effortless. Their invention is a kind of battery: conductive electrodes coated with a compound called polyanthraquinone, which has a natural chemical attraction to carbon dioxide under certain conditions, and no affinity for CO2 when these conditions are relaxed. When activated by a low-level electrical current, the battery charges, reacting with passing molecules of CO2 and pulling them onto its surface. Once the battery becomes saturated, the CO2 can be released with a flip of voltage as a pure gas stream.

      “We showed that our technology works in a wide range of CO2 concentrations, from the 20 percent or higher found in cement and steel industry exhaust streams, down to the very diffuse 0.04 percent in air itself,” says Hatton. Climate change science suggests that removing CO2 directly from air “is an important component of the whole mitigation strategy,” he adds.

      “This was an academic breakthrough,” says Brian Baynes PhD ’04, CEO and co-founder of Verdox. Baynes, a chemical engineering alumnus and a former associate of Hatton’s, has many startups to his name, and a history as a venture capitalist and mentor to young entrepreneurs. When he first encountered Hatton and Voskian’s research in 2018, he was “impressed that their technology showed it could reduce energy consumption for certain kinds of carbon capture by 70 percent compared to other technologies,” he says. “I was encouraged and impressed by this low-energy footprint, and recommended that they start a company.”

      Neither Hatton nor Voskian had commercialized a product before, so they asked Baynes to help them get going. “I normally decline these requests, because the costs are generally greater than the upside,” Baynes says. “But this innovation had the potential to move the needle on climate change, and I saw it as a rare opportunity.”

      The Verdox team has no illusions about the challenge ahead. “The scale of the problem is enormous,” says Voskian. “Our technology must be in a position to capture mega- and gigatons of CO2 from air and emission sources.” Indeed, the International Panel on Climate Change estimates the world must remove 10 gigatons of CO2 per year by 2050 in order to keep global temperature rise under 2 degrees Celsius.

      To scale up successfully and at a pace that could meet the world’s climate challenge, Verdox must become “a business that works in a technoeconomic sense,” as Baynes puts it. This means, for instance, ensuring its carbon capture system offers clear and competitive cost benefits when deployed. Not a problem, says Voskian: “Our technology, because it uses electric energy, can be easily integrated into the grid, working with solar and wind on a plug-and-play basis.” The Verdox team believes their carbon footprint will beat that of competitors by orders of magnitude.

      The company is pushing past a series of technical obstacles as it ramps up: enabling the carbon capture battery to run hundreds of thousands of cycles before its performance wanes, and enhancing the polyanthraquinone chemistry so that the device is even more selective for CO2.

      After hurtling past critical milestones, Verdox is now working with its first announced commercial client: Norwegian aluminum company Hydro, which aims to eliminate CO2 from the exhaust of its smelters as it transitions to zero-carbon production.

      Verdox is also developing systems that can efficiently pull CO2 out of ambient air. “We’re designing units that would look like rows and rows of big fans that bring the air into boxes containing our batteries,” he says. Such approaches might prove especially useful in locations such as airfields, where there are higher-than-normal concentrations of CO2 emissions present.

      All this captured carbon needs to go somewhere. With XPRIZE partner Carbfix, which has a decade-old, proven method for mineralizing captured CO2 and depositing it in deep underground caverns, Verdox will have a final resting place for CO2 that cannot immediately be reused for industrial applications such as new fuels or construction materials.

      With its clients and partners, the team appears well-positioned for the next round of the carbon removal XPRIZE competition, which will award up to $50 million to the group that best demonstrates a working solution at a scale of at least 1,000 tons removed per year, and can present a viable blueprint for scaling to gigatons of removal per year.

      Can Verdox meaningfully reduce the planet’s growing CO2 burden? Voskian is sure of it. “Going at our current momentum, and seeing the world embrace carbon capture, this is the right path forward,” he says. “With our partners, deploying manufacturing facilities on a global scale, we will make a dent in the problem in our lifetime.” More