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      in Energy

      Using combustion to make better batteries

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      For more than a century, much of the world has run on the combustion of fossil fuels. Now, to avert the threat of climate change, the energy system is changing. Notably, solar and wind systems are replacing fossil fuel combustion for generating electricity and heat, and batteries are replacing the internal combustion engine for powering vehicles. As the energy transition progresses, researchers worldwide are tackling the many challenges that arise.

      Sili Deng has spent her career thinking about combustion. Now an assistant professor in the MIT Department of Mechanical Engineering and the Class of 1954 Career Development Professor, Deng leads a group that, among other things, develops theoretical models to help understand and control combustion systems to make them more efficient and to control the formation of emissions, including particles of soot.

      “So we thought, given our background in combustion, what’s the best way we can contribute to the energy transition?” says Deng. In considering the possibilities, she notes that combustion refers only to the process — not to what’s burning. “While we generally think of fossil fuels when we think of combustion, the term ‘combustion’ encompasses many high-temperature chemical reactions that involve oxygen and typically emit light and large amounts of heat,” she says.

      Given that definition, she saw another role for the expertise she and her team have developed: They could explore the use of combustion to make materials for the energy transition. Under carefully controlled conditions, combusting flames can be used to produce not polluting soot, but rather valuable materials, including some that are critical in the manufacture of lithium-ion batteries.

      Improving the lithium-ion battery by lowering costs

      The demand for lithium-ion batteries is projected to skyrocket in the coming decades. Batteries will be needed to power the growing fleet of electric cars and to store the electricity produced by solar and wind systems so it can be delivered later when those sources aren’t generating. Some experts project that the global demand for lithium-ion batteries may increase tenfold or more in the next decade.

      Given such projections, many researchers are looking for ways to improve the lithium-ion battery technology. Deng and her group aren’t materials scientists, so they don’t focus on making new and better battery chemistries. Instead, their goal is to find a way to lower the high cost of making all of those batteries. And much of the cost of making a lithium-ion battery can be traced to the manufacture of materials used to make one of its two electrodes — the cathode.

      The MIT researchers began their search for cost savings by considering the methods now used to produce cathode materials. The raw materials are typically salts of several metals, including lithium, which provides ions — the electrically charged particles that move when the battery is charged and discharged. The processing technology aims to produce tiny particles, each one made up of a mixture of those ingredients, with the atoms arranged in the specific crystalline structure that will deliver the best performance in the finished battery.

      For the past several decades, companies have manufactured those cathode materials using a two-stage process called coprecipitation. In the first stage, the metal salts — excluding the lithium — are dissolved in water and thoroughly mixed inside a chemical reactor. Chemicals are added to change the acidity (the pH) of the mixture, and particles made up of the combined salts precipitate out of the solution. The particles are then removed, dried, ground up, and put through a sieve.

      A change in pH won’t cause lithium to precipitate, so it is added in the second stage. Solid lithium is ground together with the particles from the first stage until lithium atoms permeate the particles. The resulting material is then heated, or “annealed,” to ensure complete mixing and to achieve the targeted crystalline structure. Finally, the particles go through a “deagglomerator” that separates any particles that have joined together, and the cathode material emerges.

      Coprecipitation produces the needed materials, but the process is time-consuming. The first stage takes about 10 hours, and the second stage requires about 13 hours of annealing at a relatively low temperature (750 degrees Celsius). In addition, to prevent cracking during annealing, the temperature is gradually “ramped” up and down, which takes another 11 hours. The process is thus not only time-consuming but also energy-intensive and costly.

      For the past two years, Deng and her group have been exploring better ways to make the cathode material. “Combustion is very effective at oxidizing things, and the materials for lithium-ion batteries are generally mixtures of metal oxides,” says Deng. That being the case, they thought this could be an opportunity to use a combustion-based process called flame synthesis.

      A new way of making a high-performance cathode material

      The first task for Deng and her team — mechanical engineering postdoc Jianan Zhang, Valerie L. Muldoon ’20, SM ’22, and current graduate students Maanasa Bhat and Chuwei Zhang — was to choose a target material for their study. They decided to focus on a mixture of metal oxides consisting of nickel, cobalt, and manganese plus lithium. Known as “NCM811,” this material is widely used and has been shown to produce cathodes for batteries that deliver high performance; in an electric vehicle, that means a long driving range, rapid discharge and recharge, and a long lifetime. To better define their target, the researchers examined the literature to determine the composition and crystalline structure of NCM811 that has been shown to deliver the best performance as a cathode material.

      They then considered three possible approaches to improving on the coprecipitation process for synthesizing NCM811: They could simplify the system (to cut capital costs), speed up the process, or cut the energy required.

      “Our first thought was, what if we can mix together all of the substances — including the lithium — at the beginning?” says Deng. “Then we would not need to have the two stages” — a clear simplification over coprecipitation.

      Introducing FASP

      One process widely used in the chemical and other industries to fabricate nanoparticles is a type of flame synthesis called flame-assisted spray pyrolysis, or FASP. Deng’s concept for using FASP to make their targeted cathode powders proceeds as follows.

      The precursor materials — the metal salts (including the lithium) — are mixed with water, and the resulting solution is sprayed as fine droplets by an atomizer into a combustion chamber. There, a flame of burning methane heats up the mixture. The water evaporates, leaving the precursor materials to decompose, oxidize, and solidify to form the powder product. The cyclone separates particles of different sizes, and the baghouse filters out those that aren’t useful. The collected particles would then be annealed and deagglomerated.

      To investigate and optimize this concept, the researchers developed a lab-scale FASP setup consisting of a homemade ultrasonic nebulizer, a preheating section, a burner, a filter, and a vacuum pump that withdraws the powders that form. Using that system, they could control the details of the heating process: The preheating section replicates conditions as the material first enters the combustion chamber, and the burner replicates conditions as it passes the flame. That setup allowed the team to explore operating conditions that would give the best results.

      Their experiments showed marked benefits over coprecipitation. The nebulizer breaks up the liquid solution into fine droplets, ensuring atomic-level mixing. The water simply evaporates, so there’s no need to change the pH or to separate the solids from a liquid. As Deng notes, “You just let the gas go, and you’re left with the particles, which is what you want.” With lithium included at the outset, there’s no need for mixing solids with solids, which is neither efficient 
nor effective.

      They could even control the structure, or “morphology,” of the particles that formed. In one series of experiments, they tried exposing the incoming spray to different rates of temperature change over time. They found that the temperature “history” has a direct impact on morphology. With no preheating, the particles burst apart; and with rapid preheating, the particles were hollow. The best outcomes came when they used temperatures ranging from 175-225 C. Experiments with coin-cell batteries (laboratory devices used for testing battery materials) confirmed that by adjusting the preheating temperature, they could achieve a particle morphology that would optimize the performance of their materials.

      Best of all, the particles formed in seconds. Assuming the time needed for conventional annealing and deagglomerating, the new setup could synthesize the finished cathode material in half the total time needed for coprecipitation. Moreover, the first stage of the coprecipitation system is replaced by a far simpler setup — a savings in capital costs.

      “We were very happy,” says Deng. “But then we thought, if we’ve changed the precursor side so the lithium is mixed well with the salts, do we need to have the same process for the second stage? Maybe not!”

      Improving the second stage

      The key time- and energy-consuming step in the second stage is the annealing. In today’s coprecipitation process, the strategy is to anneal at a low temperature for a long time, giving the operator time to manipulate and control the process. But running a furnace for some 20 hours — even at a low temperature — consumes a lot of energy.

      Based on their studies thus far, Deng thought, “What if we slightly increase the temperature but reduce the annealing time by orders of magnitude? Then we could cut energy consumption, and we might still achieve the desired crystal structure.”

      However, experiments at slightly elevated temperatures and short treatment times didn’t bring the results they had hoped for. In transmission electron microscope (TEM) images, the particles that formed had clouds of light-looking nanoscale particles attached to their surfaces. When the researchers performed the same experiments without adding the lithium, those nanoparticles didn’t appear. Based on that and other tests, they concluded that the nanoparticles were pure lithium. So, it seemed like long-duration annealing would be needed to ensure that the lithium made its way inside the particles.

      But they then came up with a different solution to the lithium-distribution problem. They added a small amount — just 1 percent by weight — of an inexpensive compound called urea to their mixture. In TEM images of the particles formed, the “undesirable nanoparticles were largely gone,” says Deng.

      Experiments in the laboratory coin cells showed that the addition of urea significantly altered the response to changes in the annealing temperature. When the urea was absent, raising the annealing temperature led to a dramatic decline in performance of the cathode material that formed. But with the urea present, the performance of the material that formed was unaffected by any temperature change.

      That result meant that — as long as the urea was added with the other precursors — they could push up the temperature, shrink the annealing time, and omit the gradual ramp-up and cool-down process. Further imaging studies confirmed that their approach yields the desired crystal structure and the homogeneous elemental distribution of the cobalt, nickel, manganese, and lithium within the particles. Moreover, in tests of various performance measures, their materials did as well as materials produced by coprecipitation or by other methods using long-time heat treatment. Indeed, the performance was comparable to that of commercial batteries with cathodes made of NCM811.

      So now the long and expensive second stage required in standard coprecipitation could be replaced by just 20 minutes of annealing at about 870 C plus 20 minutes of cooling down at room temperature.

      Theory, continuing work, and planning for scale-up

      While experimental evidence supports their approach, Deng and her group are now working to understand why it works. “Getting the underlying physics right will help us design the process to control the morphology and to scale up the process,” says Deng. And they have a hypothesis for why the lithium nanoparticles in their flame synthesis process end up on the surfaces of the larger particles — and why the presence of urea solves that problem.

      According to their theory, without the added urea, the metal and lithium atoms are initially well-mixed within the droplet. But as heating progresses, the lithium diffuses to the surface and ends up as nanoparticles attached to the solidified particle. As a result, a long annealing process is needed to move the lithium in among the other atoms.

      When the urea is present, it starts out mixed with the lithium and other atoms inside the droplet. As temperatures rise, the urea decomposes, forming bubbles. As heating progresses, the bubbles burst, increasing circulation, which keeps the lithium from diffusing to the surface. The lithium ends up uniformly distributed, so the final heat treatment can be very short.

      The researchers are now designing a system to suspend a droplet of their mixture so they can observe the circulation inside it, with and without the urea present. They’re also developing experiments to examine how droplets vaporize, employing tools and methods they have used in the past to study how hydrocarbons vaporize inside internal combustion engines.

      They also have ideas about how to streamline and scale up their process. In coprecipitation, the first stage takes 10 to 20 hours, so one batch at a time moves on to the second stage to be annealed. In contrast, the novel FASP process generates particles in 20 minutes or less — a rate that’s consistent with continuous processing. In their design for an “integrated synthesis system,” the particles coming out of the baghouse are deposited on a belt that carries them for 10 or 20 minutes through a furnace. A deagglomerator then breaks any attached particles apart, and the cathode powder emerges, ready to be fabricated into a high-performance cathode for a lithium-ion battery. The cathode powders for high-performance lithium-ion batteries would thus be manufactured at unprecedented speed, low cost, and low energy use.

      Deng notes that every component in their integrated system is already used in industry, generally at a large scale and high flow-through rate. “That’s why we see great potential for our technology to be commercialized and scaled up,” she says. “Where our expertise comes into play is in designing the combustion chamber to control the temperature and heating rate so as to produce particles with the desired morphology.” And while a detailed economic analysis has yet to be performed, it seems clear that their technique will be faster, the equipment simpler, and the energy use lower than other methods of manufacturing cathode materials for lithium-ion batteries — potentially a major contribution to the ongoing energy transition.

      This research was supported by the MIT Department of Mechanical Engineering.

      This article appears in the Winter 2023 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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      in Energy

      Preparing students for the new nuclear

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      As nuclear power has gained greater recognition as a zero-emission energy source, the MIT Leaders for Global Operations (LGO) program has taken notice.

      Two years ago, LGO began a collaboration with MIT’s Department of Nuclear Science and Engineering (NSE) as a way to showcase the vital contribution of both business savvy and scientific rigor that LGO’s dual-degree graduates can offer this growing field.

      “We saw that the future of fission and fusion required business acumen and management acumen,” says Professor Anne White, NSE department head. “People who are going to be leaders in our discipline, and leaders in the nuclear enterprise, are going to need all of the technical pieces of the puzzle that our engineering department can provide in terms of education and training. But they’re also going to need a much broader perspective on how the technology connects with society through the lens of business.”

      The resulting response has been positive: “Companies are seeing the value of nuclear technology for their operations,” White says, and this often happens in unexpected ways.

      For example, graduate student Santiago Andrade recently completed a research project at Caterpillar Inc., a preeminent manufacturer of mining and construction equipment. Caterpillar is one of more than 20 major companies that partner with the LGO program, offering six-month internships to each student. On the surface, it seemed like an improbable pairing; what could Andrade, who was pursuing his master’s in nuclear science and engineering, do for a manufacturing company? However, Caterpillar wanted to understand the technical and commercial feasibility of using nuclear energy to power mining sites and data centers when wind and solar weren’t viable.

      “They are leaving no stone unturned in the search of financially smart solutions that can support the transition to a clean energy dependency,” Andrade says. “My project, along with many others’, is part of this effort.”

      “The research done through the LGO program with Santiago is enabling Caterpillar to understand how alternative technologies, like the nuclear microreactor, could participate in these markets in the future,” says Brian George, product manager for large electric power solutions at Caterpillar. “Our ability to connect our customers with the research will provide for a more accurate understanding of the potential opportunity, and helps provide exposure for our customers to emerging technologies.”

      With looming threats of climate change, White says, “We’re going to require more opportunities for nuclear technologies to step in and be part of those solutions. A cohort of LGO graduates will come through this program with technical expertise — a master’s degree in nuclear engineering — and an MBA. There’s going to be a tremendous talent pool out there to help companies and governments.”

      Andrade, who completed an undergraduate degree in chemical engineering and had a strong background in thermodynamics, applied to LGO unsure of which track to choose, but he knew he wanted to confront the world’s energy challenge. When MIT Admissions suggested that he join LGO’s new nuclear track, he was intrigued by how it could further his career.

      “Since the NSE department offers opportunities ranging from energy to health care and from quantum engineering to regulatory policy, the possibilities of career tracks after graduation are countless,” he says.

      He was also inspired by the fact that, as he says, “Nuclear is one of the less-popular solutions in terms of our energy transition journey. One of the things that attracted me is that it’s not one of the most popular, but it’s one of the most useful.”

      In addition to his work at Caterpillar, Andrade connected deeply with professors. He worked closely with professors Jacopo Buongiorno and John Parsons as a research assistant, helping them develop a business model to successfully support the deployment of nuclear microreactors. After graduation, he plans to work in the clean energy sector with an eye to innovations in the nuclear energy technology space.

      His LGO classmate, Lindsey Kennington, a control systems engineer, echoes his sentiments: This is a revolutionary time for nuclear technology.

      “Before MIT, I worked on a lot of nuclear waste or nuclear weapons-related projects. All of them were fission-related. I got disillusioned because of all the bureaucracy and the regulation,” Kennington says. “However, now there are a lot of new nuclear technologies coming straight out of MIT. Commonwealth Fusion Systems, a fusion startup, represents a prime example of MIT’s close relationship to new nuclear tech. Small modular reactors are another emerging technology being developed by MIT. Exposure to these cutting-edge technologies was the main sell factor for me.”

      Kennington conducted an internship with National Grid, where she used her expertise to evaluate how existing nuclear power plants could generate hydrogen. At MIT, she studied nuclear and energy policy, which offered her additional perspective that traditional engineering classes might not have provided. Because nuclear power has long been a hot-button issue, Kennington was able to gain nuanced insight about the pathways and roadblocks to its implementation.

      “I don’t think that other engineering departments emphasize that focus on policy quite as much. [Those classes] have been one of the most enriching parts of being in the nuclear department,” she says.

      Most of all, she says, it’s a pivotal time to be part of a new, blossoming program at the forefront of clean energy, especially as fusion research grows more prevalent.

      “We’re at an inflection point,” she says. “Whether or not we figure out fusion in the next five, 10, or 20 years, people are going to be working on it — and it’s a really exciting time to not only work on the science but to actually help the funding and business side grow.”

      White puts it simply.

      “This is not your parents’ nuclear,” she says. “It’s something totally different. Our discipline is evolving so rapidly that people who have technical expertise in nuclear will have a huge advantage in this next generation.” More

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      in Environment

      Rescuing small plastics from the waste stream

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      As plastic pollution continues to mount, with growing risks to ecosystems and wildlife, manufacturers are beginning to make ambitious commitments to keep new plastics out of the environment. A growing number have signed onto the U.S. Plastics Pact, which pledges to make 100 percent of plastic packaging reusable, recyclable, or compostable, and to see 50 percent of it effectively recycled or composted, by 2025.

      But for companies that make large numbers of small, disposable plastics, these pocket-sized objects are a major barrier to realizing their recycling goals.

      “Think about items like your toothbrush, your travel-size toothpaste tubes, your travel-size shampoo bottles,” says Alexis Hocken, a second-year PhD student in the MIT Department of Chemical Engineering. “They end up actually slipping through the cracks of current recycling infrastructure. So you might put them in your recycling bin at home, they might make it all the way to the sorting facility, but when it comes down to actually sorting them, they never make it into a recycled plastic bale at the very end of the line.”

      Now, a group of five consumer products companies is working with MIT to develop a sorting process that can keep their smallest plastic products inside the recycling chain. The companies — Colgate-Palmolive, Procter & Gamble, the Estée Lauder Companies, L’Oreal, and Haleon — all manufacture a large volume of “small format” plastics, or products less than two inches long in at least two dimensions. In a collaboration with Brad Olsen, the Alexander and I. Michael Kasser (1960) Professor of Chemical Engineering; Desiree Plata, an associate professor of civil and environmental engineering; the MIT Environmental Solutions Initiative; and the nonprofit The Sustainability Consortium, these companies are seeking a prototype sorting technology to bring to recycling facilities for large-scale testing and commercial development.

      Working in Olsen’s lab, Hocken is coming to grips with the complexity of the recycling systems involved. Material recovery facilities, or MRFs, are expected to handle products in any number of shapes, sizes, and materials, and sort them into a pure stream of glass, metal, paper, or plastic. Hocken’s first step in taking on the recycling project was to tour one of these MRFs in Portland, Maine, with Olsen and Plata.

      “We could literally see plastics just falling from the conveyor belts,” she says. “Leaving that tour, I thought, my gosh! There’s so much improvement that can be made. There’s so much impact that we can have on this industry.”

      From designing plastics to managing them

      Hocken always knew she wanted to work in engineering. Growing up in Scottsdale, Arizona, she was able to spend time in the workplace with her father, an electrical engineer who designs biomedical devices. “Seeing him working as an engineer, and how he’s solving these really important problems, definitely sparked my interest,” she says. “When it came time to begin my undergraduate degree, it was a really easy decision to choose engineering after seeing the day-to-day that my dad was doing in his career.”

      At Arizona State University, she settled on chemical engineering as a major and began working with polymers, coming up with combinations of additives for 3D plastics printing that could help fine-tune how the final products behaved. But even working with plastics every day, she rarely thought about the implications of her work for the environment.

      “And then in the spring of my final year at ASU, I took a class about polymers through the lens of sustainability, and that really opened my eyes,” Hocken remembers. The class was taught by Professor Timothy Long, director of the Biodesign Center for Sustainable Macromolecular Materials and Manufacturing and a well-known expert in the field of sustainable plastics. “That first session, where he laid out all of the really scary facts surrounding the plastics crisis, got me very motivated to look more into that field.”

      At MIT the next year, Hocken sought out Olsen as her advisor and made plastics sustainability her focus from the start.

      “Coming to MIT was my first time venturing outside of the state of Arizona for more than a three-month period,” she says. “It’s been really fun. I love living in Cambridge and the Boston area. I love my labmates. Everyone is so supportive, whether it’s to give me advice about some science that I’m trying to figure out, or just give me a pep talk if I’m feeling a little discouraged.”

      A challenge to recycle

      A lot of plastics research today is devoted to creating new materials — including biodegradable ones that are easier for natural ecosystems to absorb, and highly recyclable ones that hold their properties better after being melted down and recast.

      But Hocken also sees a huge need for better ways to handle the plastics we’re already making. “While biodegradable and sustainable polymers represent a very important route, and I think they should certainly be further pursued, we’re still a ways away from that being a reality universally across all plastic packaging,” she says. As long as large volumes of conventional plastic are coming out of factories, we’ll need innovative ways to stop it from piling onto the mountain of plastic pollution. In one of her projects, Hocken is trying to come up with new uses for recycled plastic that take advantage of its lost strength to produce a useful, flexible material similar to rubber.

      The small-format recycling project also falls in this category. The companies supporting the project have challenged the MIT team to work with their products exactly as currently manufactured — especially because their competitors use similar packaging materials that will also need to be covered by any solution the MIT team devises.

      The challenge is a large one. To kick the project off, the participating companies sent the MIT team a wide range of small-format products that need to make it through the sorting process. These include containers for lip balm, deodorant, pills, and shampoo, and disposable tools like toothbrushes and flossing picks. “A constraint, or problem I foresee, is just how variable the shapes are,” says Hocken. “A flossing pick versus a toothbrush are very different shapes.”

      Nor are they all made of the same kind of plastic. Many are made of polyethylene terephthalate (PET, type 1 in the recycling label system) or high-density polyethylene (HDPE, type 2), but nearly all of the seven recycling categories are represented among the sample products. The team’s solution will have to handle them all.

      Another obstacle is that the sorting process at a large MRF is already very complex and requires a heavy investment in equipment. The waste stream typically goes through a “glass breaker screen” that shatters glass and collects the shards; a series of rotating rubber stars to pull out two-dimensional objects, collecting paper and cardboard; a system of magnets and eddy currents to attract or repel different metals; and finally, a series of optical sorters that use infrared spectroscopy to identify the various types of plastics, then blow them down different chutes with jets of air. MRFs won’t be interested in adopting additional sorters unless they’re inexpensive and easy to fit into this elaborate stream.

      “We’re interested in creating something that could be retrofitted into current technology and current infrastructure,” Hocken says.

      Shared solutions

      “Recycling is a really good example of where pre-competitive collaboration is needed,” says Jennifer Park, collective action manager at The Sustainability Consortium (TSC), who has been working with corporate stakeholders on small format recyclability and helped convene the sponsors of this project and organize their contributions. “Companies manufacturing these products recognize that they cannot shift entire systems on their own. Consistency around what is and is not recyclable is the only way to avoid confusion and drive impact at scale.

      “Additionally, it is interesting that consumer packaged goods companies are sponsoring this research at MIT which is focused on MRF-level innovations. They’re investing in innovations that they hope will be adopted by the recycling industry to make progress on their own sustainability goals.”

      Hocken believes that, despite the challenges, it’s well worth pursuing a technology that can keep small-format plastics from slipping through MRFs’ fingers.

      “These are products that would be more recyclable if they were easier to sort,” she says. “The only thing that’s different is the size. So you can recycle both your large shampoo bottle and the small travel-size one at home, but the small one isn’t guaranteed to make it into a plastic bale at the end. If we can come up with a solution that specifically targets those while they’re still on the sorting line, they’re more likely to end up in those plastic bales at the end of the line, which can be sold to plastic reclaimers who can then use that material in new products.”

      “TSC is really excited about this project and our collaboration with MIT,” adds Park. “Our project stakeholders are very dedicated to finding a solution.”

      To learn more about this project, contact Christopher Noble, director of corporate engagement at the MIT Environmental Solutions Initiative. More

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      in Energy

      Manufacturing a cleaner future

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      Manufacturing had a big summer. The CHIPS and Science Act, signed into law in August, represents a massive investment in U.S. domestic manufacturing. The act aims to drastically expand the U.S. semiconductor industry, strengthen supply chains, and invest in R&D for new technological breakthroughs. According to John Hart, professor of mechanical engineering and director of the Laboratory for Manufacturing and Productivity at MIT, the CHIPS Act is just the latest example of significantly increased interest in manufacturing in recent years.

      “You have multiple forces working together: reflections from the pandemic’s impact on supply chains, the geopolitical situation around the world, and the urgency and importance of sustainability,” says Hart. “This has now aligned incentives among government, industry, and the investment community to accelerate innovation in manufacturing and industrial technology.”

      Hand-in-hand with this increased focus on manufacturing is a need to prioritize sustainability.

      Roughly one-quarter of greenhouse gas emissions came from industry and manufacturing in 2020. Factories and plants can also deplete local water reserves and generate vast amounts of waste, some of which can be toxic.

      To address these issues and drive the transition to a low-carbon economy, new products and industrial processes must be developed alongside sustainable manufacturing technologies. Hart sees mechanical engineers as playing a crucial role in this transition.

      “Mechanical engineers can uniquely solve critical problems that require next-generation hardware technologies, and know how to bring their solutions to scale,” says Hart.

      Several fast-growing companies founded by faculty and alumni from MIT’s Department of Mechanical Engineering offer solutions for manufacturing’s environmental problem, paving the path for a more sustainable future.

      Gradiant: Cleantech water solutions

      Manufacturing requires water, and lots of it. A medium-sized semiconductor fabrication plant uses upward of 10 million gallons of water a day. In a world increasingly plagued by droughts, this dependence on water poses a major challenge.

      Gradiant offers a solution to this water problem. Co-founded by Anurag Bajpayee SM ’08, PhD ’12 and Prakash Govindan PhD ’12, the company is a pioneer in sustainable — or “cleantech” — water projects.

      As doctoral students in the Rohsenow Kendall Heat Transfer Laboratory, Bajpayee and Govindan shared a pragmatism and penchant for action. They both worked on desalination research — Bajpayee with Professor Gang Chen and Govindan with Professor John Lienhard.

      Inspired by a childhood spent during a severe drought in Chennai, India, Govindan developed for his PhD a humidification-dehumidification technology that mimicked natural rainfall cycles. It was with this piece of technology, which they named Carrier Gas Extraction (CGE), that the duo founded Gradiant in 2013.

      The key to CGE lies in a proprietary algorithm that accounts for variability in the quality and quantity in wastewater feed. At the heart of the algorithm is a nondimensional number, which Govindan proposes one day be called the “Lienhard Number,” after his doctoral advisor.

      “When the water quality varies in the system, our technology automatically sends a signal to motors within the plant to adjust the flow rates to bring back the nondimensional number to a value of one. Once it’s brought back to a value of one, you’re running in optimal condition,” explains Govindan, who serves as chief operating officer of Gradiant.

      This system can treat and clean the wastewater produced by a manufacturing plant for reuse, ultimately conserving millions of gallons of water each year.

      As the company has grown, the Gradiant team has added new technologies to their arsenal, including Selective Contaminant Extraction, a cost-efficient method that removes only specific contaminants, and a brine-concentration method called Counter-Flow Reverse Osmosis. They now offer a full technology stack of water and wastewater treatment solutions to clients in industries including pharmaceuticals, energy, mining, food and beverage, and the ever-growing semiconductor industry.

      “We are an end-to-end water solutions provider. We have a portfolio of proprietary technologies and will pick and choose from our ‘quiver’ depending on a customer’s needs,” says Bajpayee, who serves as CEO of Gradiant. “Customers look at us as their water partner. We can take care of their water problem end-to-end so they can focus on their core business.”

      Gradiant has seen explosive growth over the past decade. With 450 water and wastewater treatment plants built to date, they treat the equivalent of 5 million households’ worth of water each day. Recent acquisitions saw their total employees rise to above 500.

      The diversity of Gradiant’s solutions is reflected in their clients, who include Pfizer, AB InBev, and Coca-Cola. They also count semiconductor giants like Micron Technology, GlobalFoundries, Intel, and TSMC among their customers.

      “Over the last few years, we have really developed our capabilities and reputation serving semiconductor wastewater and semiconductor ultrapure water,” says Bajpayee.

      Semiconductor manufacturers require ultrapure water for fabrication. Unlike drinking water, which has a total dissolved solids range in the parts per million, water used to manufacture microchips has a range in the parts per billion or quadrillion.

      Currently, the average recycling rate at semiconductor fabrication plants — or fabs — in Singapore is only 43 percent. Using Gradiant’s technologies, these fabs can recycle 98-99 percent of the 10 million gallons of water they require daily. This reused water is pure enough to be put back into the manufacturing process.

      “What we’ve done is eliminated the discharge of this contaminated water and nearly eliminated the dependence of the semiconductor fab on the public water supply,” adds Bajpayee.

      With new regulations being introduced, pressure is increasing for fabs to improve their water use, making sustainability even more important to brand owners and their stakeholders.

      As the domestic semiconductor industry expands in light of the CHIPS and Science Act, Gradiant sees an opportunity to bring their semiconductor water treatment technologies to more factories in the United States.

      Via Separations: Efficient chemical filtration

      Like Bajpayee and Govindan, Shreya Dave ’09, SM ’12, PhD ’16 focused on desalination for her doctoral thesis. Under the guidance of her advisor Jeffrey Grossman, professor of materials science and engineering, Dave built a membrane that could enable more efficient and cheaper desalination.

      A thorough cost and market analysis brought Dave to the conclusion that the desalination membrane she developed would not make it to commercialization.

      “The current technologies are just really good at what they do. They’re low-cost, mass produced, and they worked. There was no room in the market for our technology,” says Dave.

      Shortly after defending her thesis, she read a commentary article in the journal Nature that changed everything. The article outlined a problem. Chemical separations that are central to many manufacturing processes require a huge amount of energy. Industry needed more efficient and cheaper membranes. Dave thought she might have a solution.

      After determining there was an economic opportunity, Dave, Grossman, and Brent Keller PhD ’16 founded Via Separations in 2017. Shortly thereafter, they were chosen as one of the first companies to receive funding from MIT’s venture firm, The Engine.

      Currently, industrial filtration is done by heating chemicals at very high temperatures to separate compounds. Dave likens it to making pasta by boiling all of the water off until it evaporates and all you are left with is the pasta noodles. In manufacturing, this method of chemical separation is extremely energy-intensive and inefficient.

      Via Separations has created the chemical equivalent of a “pasta strainer.” Rather than using heat to separate, their membranes “strain” chemical compounds. This method of chemical filtration uses 90 percent less energy than standard methods.

      While most membranes are made of polymers, Via Separations’ membranes are made with graphene oxide, which can withstand high temperatures and harsh conditions. The membrane is calibrated to the customer’s needs by altering the pore size and tuning the surface chemistry.

      Currently, Dave and her team are focusing on the pulp and paper industry as their beachhead market. They have developed a system that makes the recovery of a substance known as “black liquor” more energy efficient.

      “When tree becomes paper, only one-third of the biomass is used for the paper. Currently the most valuable use for the remaining two-thirds not needed for paper is to take it from a pretty dilute stream to a pretty concentrated stream using evaporators by boiling off the water,” says Dave.

      This black liquor is then burned. Most of the resulting energy is used to power the filtration process.

      “This closed-loop system accounts for an enormous amount of energy consumption in the U.S. We can make that process 84 percent more efficient by putting the ‘pasta strainer’ in front of the boiler,” adds Dave.

      VulcanForms: Additive manufacturing at industrial scale

      The first semester John Hart taught at MIT was a fruitful one. He taught a course on 3D printing, broadly known as additive manufacturing (AM). While it wasn’t his main research focus at the time, he found the topic fascinating. So did many of the students in the class, including Martin Feldmann MEng ’14.

      After graduating with his MEng in advanced manufacturing, Feldmann joined Hart’s research group full time. There, they bonded over their shared interest in AM. They saw an opportunity to innovate with an established metal AM technology, known as laser powder bed fusion, and came up with a concept to realize metal AM at an industrial scale.

      The pair co-founded VulcanForms in 2015.

      “We have developed a machine architecture for metal AM that can build parts with exceptional quality and productivity,” says Hart. “And, we have integrated our machines in a fully digital production system, combining AM, postprocessing, and precision machining.”

      Unlike other companies that sell 3D printers for others to produce parts, VulcanForms makes and sells parts for their customers using their fleet of industrial machines. VulcanForms has grown to nearly 400 employees. Last year, the team opened their first production factory, known as “VulcanOne,” in Devens, Massachusetts.

      The quality and precision with which VulcanForms produces parts is critical for products like medical implants, heat exchangers, and aircraft engines. Their machines can print layers of metal thinner than a human hair.

      “We’re producing components that are difficult, or in some cases impossible to manufacture otherwise,” adds Hart, who sits on the company’s board of directors.

      The technologies developed at VulcanForms may help lead to a more sustainable way to manufacture parts and products, both directly through the additive process and indirectly through more efficient, agile supply chains.

      One way that VulcanForms, and AM in general, promotes sustainability is through material savings.

      Many of the materials VulcanForms uses, such as titanium alloys, require a great deal of energy to produce. When titanium parts are 3D-printed, substantially less of the material is used than in a traditional machining process. This material efficiency is where Hart sees AM making a large impact in terms of energy savings.

      Hart also points out that AM can accelerate innovation in clean energy technologies, ranging from more efficient jet engines to future fusion reactors.

      “Companies seeking to de-risk and scale clean energy technologies require know-how and access to advanced manufacturing capability, and industrial additive manufacturing is transformative in this regard,” Hart adds.

      LiquiGlide: Reducing waste by removing friction

      There is an unlikely culprit when it comes to waste in manufacturing and consumer products: friction. Kripa Varanasi, professor of mechanical engineering, and the team at LiquiGlide are on a mission to create a frictionless future, and substantially reduce waste in the process.

      Founded in 2012 by Varanasi and alum David Smith SM ’11, LiquiGlide designs custom coatings that enable liquids to “glide” on surfaces. Every last drop of a product can be used, whether it’s being squeezed out of a tube of toothpaste or drained from a 500-liter tank at a manufacturing plant. Making containers frictionless substantially minimizes wasted product, and eliminates the need to clean a container before recycling or reusing.

      Since launching, the company has found great success in consumer products. Customer Colgate utilized LiquiGlide’s technologies in the design of the Colgate Elixir toothpaste bottle, which has been honored with several industry awards for design. In a collaboration with world- renowned designer Yves Béhar, LiquiGlide is applying their technology to beauty and personal care product packaging. Meanwhile, the U.S. Food and Drug Administration has granted them a Device Master Filing, opening up opportunities for the technology to be used in medical devices, drug delivery, and biopharmaceuticals.

      In 2016, the company developed a system to make manufacturing containers frictionless. Called CleanTanX, the technology is used to treat the surfaces of tanks, funnels, and hoppers, preventing materials from sticking to the side. The system can reduce material waste by up to 99 percent.

      “This could really change the game. It saves wasted product, reduces wastewater generated from cleaning tanks, and can help make the manufacturing process zero-waste,” says Varanasi, who serves as chair at LiquiGlide.

      LiquiGlide works by creating a coating made of a textured solid and liquid lubricant on the container surface. When applied to a container, the lubricant remains infused within the texture. Capillary forces stabilize and allow the liquid to spread on the surface, creating a continuously lubricated surface that any viscous material can slide right down. The company uses a thermodynamic algorithm to determine the combinations of safe solids and liquids depending on the product, whether it’s toothpaste or paint.

      The company has built a robotic spraying system that can treat large vats and tanks at manufacturing plants on site. In addition to saving companies millions of dollars in wasted product, LiquiGlide drastically reduces the amount of water needed to regularly clean these containers, which normally have product stuck to the sides.

      “Normally when you empty everything out of a tank, you still have residue that needs to be cleaned with a tremendous amount of water. In agrochemicals, for example, there are strict regulations about how to deal with the resulting wastewater, which is toxic. All of that can be eliminated with LiquiGlide,” says Varanasi.

      While the closure of many manufacturing facilities early in the pandemic slowed down the rollout of CleanTanX pilots at plants, things have picked up in recent months. As manufacturing ramps up both globally and domestically, Varanasi sees a growing need for LiquiGlide’s technologies, especially for liquids like semiconductor slurry.

      Companies like Gradiant, Via Separations, VulcanForms, and LiquiGlide demonstrate that an expansion in manufacturing industries does not need to come at a steep environmental cost. It is possible for manufacturing to be scaled up in a sustainable way.

      “Manufacturing has always been the backbone of what we do as mechanical engineers. At MIT in particular, there is always a drive to make manufacturing sustainable,” says Evelyn Wang, Ford Professor of Engineering and former head of the Department of Mechanical Engineering. “It’s amazing to see how startups that have an origin in our department are looking at every aspect of the manufacturing process and figuring out how to improve it for the health of our planet.”

      As legislation like the CHIPS and Science Act fuels growth in manufacturing, there will be an increased need for startups and companies that develop solutions to mitigate the environmental impact, bringing us closer to a more sustainable future. More

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      in Energy

      Mining for the clean energy transition

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      In a world powered increasingly by clean energy, drilling for oil and gas will gradually give way to digging for metals and minerals. Today, the “critical minerals” used to make electric cars, solar panels, wind turbines, and grid-scale battery storage are facing soaring demand — and some acute bottlenecks as miners race to catch up.

      According to a report from the International Energy Agency, by 2040, the worldwide demand for copper is expected to roughly double; demand for nickel and cobalt will grow at least sixfold; and the world’s hunger for lithium could reach 40 times what we use today.

      “Society is looking to the clean energy transition as a way to solve the environmental and social harms of climate change,” says Scott Odell, a visiting scientist at the MIT Environmental Solutions Initiative (ESI), where he helps run the ESI Mining, Environment, and Society Program, who is also a visiting assistant professor at George Washington University. “Yet mining the materials needed for that transition would also cause social and environmental impacts. So we need to look for ways to reduce our demand for minerals, while also improving current mining practices to minimize social and environmental impacts.”

      ESI recently hosted the inaugural MIT Conference on Mining, Environment, and Society to discuss how the clean energy transition may affect mining and the people and environments in mining areas. The conference convened representatives of mining companies, environmental and human rights groups, policymakers, and social and natural scientists to identify key concerns and possible collaborative solutions.

      “We can’t replace an abusive fossil fuel industry with an abusive mining industry that expands as we move through the energy transition,” said Jim Wormington, a senior researcher at Human Rights Watch, in a panel on the first day of the conference. “There’s a recognition from governments, civil society, and companies that this transition potentially has a really significant human rights and social cost, both in terms of emissions […] but also for communities and workers who are on the front lines of mining.”

      That focus on communities and workers was consistent throughout the three-day conference, as participants outlined the economic and social dimensions of standing up large numbers of new mines. Corporate mines can bring large influxes of government revenue and local investment, but the income is volatile and can leave policymakers and communities stranded when production declines or mineral prices fall. On the other hand, “artisanal” mining operations are an important source of critical minerals, but are hard to regulate and subject to abuses from brokers. And large reserves of minerals are found in conservation areas, regions with fragile ecosystems and experiencing water shortages that can be exacerbated by mining, in particular on Indigenous-controlled lands and other places where mine openings are deeply fraught.

      “One of the real triggers of conflict is a dissatisfaction with the current model of resource extraction,” said Jocelyn Fraser of the University of British Columbia in a panel discussion. “One that’s failed to support the long-term sustainable development of regions that host mining operations, and yet imposes significant local social and environmental impacts.”

      All these challenges point toward solutions in policy and in mining companies’ relationships with the communities where they work. Participants highlighted newer models of mining governance that can create better incentives for the ways mines operate — from full community ownership of mines to recognizing community rights to the benefits of mining to end-of-life planning for mines at the time they open.

      Many of the conference speakers also shared technological innovations that may help reduce mining challenges. Some operations are investing in desalination as alternative water sources in water-scarce regions; low-carbon alternatives are emerging to many of the fossil fuel-powered heavy machines that are mainstays of the industry; and work is being done to reclaim valuable minerals from mine tailings, helping to minimize both waste and the need to open new extraction sites.

      Increasingly, the mining industry itself is recognizing that reforms will allow it to thrive in a rapid clean-energy transition. “Decarbonization is really a profitability imperative,” said Kareemah Mohammed, managing director for sustainability services at the technology consultancy Accenture, on the conference’s second day. “It’s about securing a low-cost and steady supply of either minerals or metals, but it’s also doing so in an optimal way.”

      The three-day conference attracted over 350 attendees, from large mining companies, industry groups, consultancies, multilateral institutions, universities, nongovernmental organizations (NGOs), government, and more. It was held entirely virtually, a choice that helped make the conference not only truly international — participants joined from over 27 countries on six continents — but also accessible to members of nonprofits and professionals in the developing world.

      “Many people are concerned about the environmental and social challenges of supplying the clean energy revolution, and we’d heard repeatedly that there wasn’t a forum for government, industry, academia, NGOs, and communities to all sit at the same table and explore collaborative solutions,” says Christopher Noble, ESI’s director of corporate engagement. “Convening, and researching best practices, are roles that universities can play. The conversations at this conference have generated valuable ideas and consensus to pursue three parallel programs: best-in-class models for community engagement, improving ESG metrics and their use, and civil-society contributions to government/industry relations. We are developing these programs to keep the momentum going.”

      The MIT Conference on Mining, Environment, and Society was funded, in part, by Accenture, as part of the MIT/Accenture Convergence Initiative. Additional funding was provided by the Inter-American Development Bank. More

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      in Environment

      Silk offers an alternative to some microplastics

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      Microplastics, tiny particles of plastic that are now found worldwide in the air, water, and soil, are increasingly recognized as a serious pollution threat, and have been found in the bloodstream of animals and people around the world.

      Some of these microplastics are intentionally added to a variety of products, including agricultural chemicals, paints, cosmetics, and detergents — amounting to an estimated 50,000 tons a year in the European Union alone, according to the European Chemicals Agency. The EU has already declared that these added, nonbiodegradable microplastics must be eliminated by 2025, so the search is on for suitable replacements, which do not currently exist.

      Now, a team of scientists at MIT and elsewhere has developed a system based on silk that could provide an inexpensive and easily manufactured substitute. The new process is described in a paper in the journal Small, written by MIT postdoc Muchun Liu, MIT professor of civil and environmental engineering Benedetto Marelli, and five others at the chemical company BASF in Germany and the U.S.

      The microplastics widely used in industrial products generally protect some specific active ingredient (or ingredients) from being degraded by exposure to air or moisture, until the time they are needed. They provide a slow release of the active ingredient for a targeted period of time and minimize adverse effects to its surroundings. For example, vitamins are often delivered in the form of microcapsules packed into a pill or capsule, and pesticides and herbicides are similarly enveloped. But the materials used today for such microencapsulation are plastics that persist in the environment for a long time. Until now, there has been no practical, economical substitute available that would biodegrade naturally.

      Much of the burden of environmental microplastics comes from other sources, such as the degradation over time of larger plastic objects such as bottles and packaging, and from the wear of car tires. Each of these sources may require its own kind of solutions for reducing its spread, Marelli says. The European Chemical Agency has estimated that the intentionally added microplastics represent approximately 10-15 percent of the total amount in the environment, but this source may be relatively easy to address using this nature-based biodegradable replacement, he says.

      “We cannot solve the whole microplastics problem with one solution that fits them all,” he says. “Ten percent of a big number is still a big number. … We’ll solve climate change and pollution of the world one percent at a time.”

      Unlike the high-quality silk threads used for fine fabrics, the silk protein used in the new alternative material is widely available and less expensive, Liu says. While silkworm cocoons must be painstakingly unwound to produce the fine threads needed for fabric, for this use, non-textile-quality cocoons can be used, and the silk fibers can simply be dissolved using a scalable water-based process. The processing is so simple and tunable that the resulting material can be adapted to work on existing manufacturing equipment, potentially providing a simple “drop in” solution using existing factories.

      Silk is recognized as safe for food or medical use, as it is nontoxic and degrades naturally in the body. In lab tests, the researchers demonstrated that the silk-based coating material could be used in existing, standard spray-based manufacturing equipment to make a standard water-soluble microencapsulated herbicide product, which was then tested in a greenhouse on a corn crop. The test showed it worked even better than an existing commercial product, inflicting less damage to the plants, Liu says.

      While other groups have proposed degradable encapsulation materials that may work at a small laboratory scale, Marelli says, “there is a strong need to achieve encapsulation of high-content actives to open the door to commercial use. The only way to have an impact is where we can not only replace a synthetic polymer with a biodegradable counterpart, but also achieve performance that is the same, if not better.”

      The secret to making the material compatible with existing equipment, Liu explains, is in the tunability of the silk material. By precisely adjusting the polymer chain arrangements of silk materials and addition of a surfactant, it is possible to fine-tune the properties of the resulting coatings once they dry out and harden. The material can be hydrophobic (water-repelling) even though it is made and processed in a water solution, or it can be hydrophilic (water-attracting), or anywhere in between, and for a given application it can be made to match the characteristics of the material it is being used to replace.

      In order to arrive at a practical solution, Liu had to develop a way of freezing the forming droplets of encapsulated materials as they were forming, to study the formation process in detail. She did this using a special spray-freezing system, and was able to observe exactly how the encapsulation works in order to control it better. Some of the encapsulated “payload” materials, whether they be pesticides or nutrients or enzymes, are water-soluble and some are not, and they interact in different ways with the coating material.

      “To encapsulate different materials, we have to study how the polymer chains interact and whether they are compatible with different active materials in suspension,” she says. The payload material and the coating material are mixed together in a solution and then sprayed. As droplets form, the payload tends to be embedded in a shell of the coating material, whether that’s the original synthetic plastic or the new silk material.

      The new method can make use of low-grade silk that is unusable for fabrics, and large quantities of which are currently discarded because they have no significant uses, Liu says. It can also use used, discarded silk fabric, diverting that material from being disposed of in landfills.

      Currently, 90 percent of the world’s silk production takes place in China, Marelli says, but that’s largely because China has perfected the production of the high-quality silk threads needed for fabrics. But because this process uses bulk silk and has no need for that level of quality, production could easily be ramped up in other parts of the world to meet local demand if this process becomes widely used, he says.

      “This elegant and clever study describes a sustainable and biodegradable silk-based replacement for microplastic encapsulants, which are a pressing environmental challenge,” says Alon Gorodetsky, an associate professor of chemical and biomolecular engineering at the University of California at Irvine, who was not associated with this research. “The modularity of the described materials and the scalability of the manufacturing processes are key advantages that portend well for translation to real-world applications.”

      This process “represents a potentially highly significant advance in active ingredient delivery for a range of industries, particularly agriculture,” says Jason White, director of the Connecticut Agricultural Experiment Station, who also was not associated with this work. “Given the current and future challenges related to food insecurity, agricultural production, and a changing climate, novel strategies such as this are greatly needed.”

      The research team also included Pierre-Eric Millard, Ophelie Zeyons, Henning Urch, Douglas Findley and Rupert Konradi from the BASF corporation, in Germany and in the U.S. The work was supported by BASF through the Northeast Research Alliance (NORA). More

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      in Energy

      New program bolsters innovation in next-generation artificial intelligence hardware

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      The MIT AI Hardware Program is a new academia and industry collaboration aimed at defining and developing translational technologies in hardware and software for the AI and quantum age. A collaboration between the MIT School of Engineering and MIT Schwarzman College of Computing, involving the Microsystems Technologies Laboratories and programs and units in the college, the cross-disciplinary effort aims to innovate technologies that will deliver enhanced energy efficiency systems for cloud and edge computing.

      “A sharp focus on AI hardware manufacturing, research, and design is critical to meet the demands of the world’s evolving devices, architectures, and systems,” says Anantha Chandrakasan, dean of the MIT School of Engineering and Vannevar Bush Professor of Electrical Engineering and Computer Science. “Knowledge-sharing between industry and academia is imperative to the future of high-performance computing.”

      Based on use-inspired research involving materials, devices, circuits, algorithms, and software, the MIT AI Hardware Program convenes researchers from MIT and industry to facilitate the transition of fundamental knowledge to real-world technological solutions. The program spans materials and devices, as well as architecture and algorithms enabling energy-efficient and sustainable high-performance computing.

      “As AI systems become more sophisticated, new solutions are sorely needed to enable more advanced applications and deliver greater performance,” says Daniel Huttenlocher, dean of the MIT Schwarzman College of Computing and Henry Ellis Warren Professor of Electrical Engineering and Computer Science. “Our aim is to devise real-world technological solutions and lead the development of technologies for AI in hardware and software.”

      The inaugural members of the program are companies from a wide range of industries including chip-making, semiconductor manufacturing equipment, AI and computing services, and information systems R&D organizations. The companies represent a diverse ecosystem, both nationally and internationally, and will work with MIT faculty and students to help shape a vibrant future for our planet through cutting-edge AI hardware research.

      The five inaugural members of the MIT AI Hardware Program are:  

      Amazon, a global technology company whose hardware inventions include the Kindle, Amazon Echo, Fire TV, and Astro; 
      Analog Devices, a global leader in the design and manufacturing of analog, mixed signal, and DSP integrated circuits; 
      ASML, an innovation leader in the semiconductor industry, providing chipmakers with hardware, software, and services to mass produce patterns on silicon through lithography; 
      NTT Research, a subsidiary of NTT that conducts fundamental research to upgrade reality in game-changing ways that improve lives and brighten our global future; and 
      TSMC, the world’s leading dedicated semiconductor foundry.

      The MIT AI Hardware Program will create a roadmap of transformative AI hardware technologies. Leveraging MIT.nano, the most advanced university nanofabrication facility anywhere, the program will foster a unique environment for AI hardware research.  

      “We are all in awe at the seemingly superhuman capabilities of today’s AI systems. But this comes at a rapidly increasing and unsustainable energy cost,” says Jesús del Alamo, the Donner Professor in MIT’s Department of Electrical Engineering and Computer Science. “Continued progress in AI will require new and vastly more energy-efficient systems. This, in turn, will demand innovations across the entire abstraction stack, from materials and devices to systems and software. The program is in a unique position to contribute to this quest.”

      The program will prioritize the following topics:

      analog neural networks;
      new roadmap CMOS designs;
      heterogeneous integration for AI systems;
      onolithic-3D AI systems;
      analog nonvolatile memory devices;
      software-hardware co-design;
      intelligence at the edge;
      intelligent sensors;
      energy-efficient AI;
      intelligent internet of things (IIoT);
      neuromorphic computing;
      AI edge security;
      quantum AI;
      wireless technologies;
      hybrid-cloud computing; and
      high-performance computation.

      “We live in an era where paradigm-shifting discoveries in hardware, systems communications, and computing have become mandatory to find sustainable solutions — solutions that we are proud to give to the world and generations to come,” says Aude Oliva, senior research scientist in the MIT Computer Science and Artificial Intelligence Laboratory (CSAIL) and director of strategic industry engagement in the MIT Schwarzman College of Computing.

      The new program is co-led by Jesús del Alamo and Aude Oliva, and Anantha Chandrakasan serves as chair. More

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      in Energy

      The reasons behind lithium-ion batteries’ rapid cost decline

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      Lithium-ion batteries, those marvels of lightweight power that have made possible today’s age of handheld electronics and electric vehicles, have plunged in cost since their introduction three decades ago at a rate similar to the drop in solar panel prices, as documented by a study published last March. But what brought about such an astonishing cost decline, of about 97 percent?

      Some of the researchers behind that earlier study have now analyzed what accounted for the extraordinary savings. They found that by far the biggest factor was work on research and development, particularly in chemistry and materials science. This outweighed the gains achieved through economies of scale, though that turned out to be the second-largest category of reductions.

      The new findings are being published today in the journal Energy and Environmental Science, in a paper by MIT postdoc Micah Ziegler, recent graduate student Juhyun Song PhD ’19, and Jessika Trancik, a professor in MIT’s Institute for Data, Systems and Society.

      The findings could be useful for policymakers and planners to help guide spending priorities in order to continue the pathway toward ever-lower costs for this and other crucial energy storage technologies, according to Trancik. Their work suggests that there is still considerable room for further improvement in electrochemical battery technologies, she says.

      The analysis required digging through a variety of sources, since much of the relevant information consists of closely held proprietary business data. “The data collection effort was extensive,” Ziegler says. “We looked at academic articles, industry and government reports, press releases, and specification sheets. We even looked at some legal filings that came out. We had to piece together data from many different sources to get a sense of what was happening.” He says they collected “about 15,000 qualitative and quantitative data points, across 1,000 individual records from approximately 280 references.”

      Data from the earliest times are hardest to access and can have the greatest uncertainties, Trancik says, but by comparing different data sources from the same period they have attempted to account for these uncertainties.

      Overall, she says, “we estimate that the majority of the cost decline, more than 50 percent, came from research-and-development-related activities.” That included both private sector and government-funded research and development, and “the vast majority” of that cost decline within that R&D category came from chemistry and materials research.

      That was an interesting finding, she says, because “there were so many variables that people were working on through very different kinds of efforts,” including the design of the battery cells themselves, their manufacturing systems, supply chains, and so on. “The cost improvement emerged from a diverse set of efforts and many people, and not from the work of only a few individuals.”

      The findings about the importance of investment in R&D were especially significant, Ziegler says, because much of this investment happened after lithium-ion battery technology was commercialized, a stage at which some analysts thought the research contribution would become less significant. Over roughly a 20-year period starting five years after the batteries’ introduction in the early 1990s, he says, “most of the cost reduction still came from R&D. The R&D contribution didn’t end when commercialization began. In fact, it was still the biggest contributor to cost reduction.”

      The study took advantage of an analytical approach that Trancik and her team initially developed to analyze the similarly precipitous drop in costs of silicon solar panels over the last few decades. They also applied the approach to understand the rising costs of nuclear energy. “This is really getting at the fundamental mechanisms of technological change,” she says. “And we can also develop these models looking forward in time, which allows us to uncover the levers that people could use to improve the technology in the future.”

      One advantage of the methodology Trancik and her colleagues have developed, she says, is that it helps to sort out the relative importance of different factors when many variables are changing all at once, which typically happens as a technology improves. “It’s not simply adding up the cost effects of these variables,” she says, “because many of these variables affect many different cost components. There’s this kind of intricate web of dependencies.” But the team’s methodology makes it possible to “look at how that overall cost change can be attributed to those variables, by essentially mapping out that network of dependencies,” she says.

      This can help provide guidance on public spending, private investments, and other incentives. “What are all the things that different decision makers could do?” she asks. “What decisions do they have agency over so that they could improve the technology, which is important in the case of low-carbon technologies, where we’re looking for solutions to climate change and we have limited time and limited resources? The new approach allows us to potentially be a bit more intentional about where we make those investments of time and money.”

      “This paper collects data available in a systematic way to determine changes in the cost components of lithium-ion batteries between 1990-1995 and 2010-2015,” says Laura Diaz Anadon, a professor of climate change policy at Cambridge University, who was not connected to this research. “This period was an important one in the history of the technology, and understanding the evolution of cost components lays the groundwork for future work on mechanisms and could help inform research efforts in other types of batteries.”

      The research was supported by the Alfred P. Sloan Foundation, the Environmental Defense Fund, and the MIT Technology and Policy Program. More