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      in Energy

      A green hydrogen innovation for clean energy

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      Renewable energy today — mainly derived from the sun or wind — depends on batteries for storage. While costs have dropped in recent years, the pursuit of more efficient means of storing renewable power continues.

      “All of these technologies, unfortunately, have a long way to go,” said Sossina Haile SB ’86, PhD ’92, the Walter P. Murphy Professor of Materials Science and Engineering at Northwestern University, at recent talk at MIT. She was the speaker of the fall 2023 Wulff Lecture, an event hosted by the Department of Materials Science and Engineering (DMSE) to ignite enthusiasm for the discipline.

      To add to the renewable energy mix — and help quicken the pace to a sustainable future — Haile is working on an approach based on hydrogen in fuel cells, particularly for eco-friendly fuel in cars. Fuel cells, like batteries, produce electricity from chemical reactions but don’t lose their charge so long as fuel is supplied.

      To generate power, the hydrogen must be pure — not attached to another molecule. Most methods of producing hydrogen today require burning fossil fuel, which generates planet-heating carbon emissions. Haile proposes a “green” process using renewable electricity to extract the hydrogen from steam.

      When hydrogen is used in a fuel cell, “you have water as the product, and that’s the beautiful zero emissions,” Haile said, referring to the renewable energy production cycle that is set in motion.

      Ammonia fuels hydrogen’s potential

      Hydrogen is not yet widely used as a fuel because it’s difficult to transport. For one, it has low energy density, meaning a large volume of hydrogen gas is needed to store a large amount of energy. And storing it is challenging because hydrogen’s tiny molecules can infiltrate metal tanks or pipes, causing cracks and gas leakage.

      Haile’s solution for transporting hydrogen is using ammonia to “carry” it. Ammonia is three parts hydrogen and one part nitrogen, so the hydrogen needs to be separated from the nitrogen before it can be used in the kind of fuel cells that can power cars.

      Ammonia has some advantages, including using existing pipelines and a high transmission capacity, Haile said — so more power can be transmitted at any given time.

      To extract the hydrogen from ammonia, Haile has built devices that look a lot like fuel cells, with cesium dihydrogen phosphate as an electrolyte. The “superprotonic” material displays high proton conductivity — it allows protons, or positively charged particles, to move through it. This is important for hydrogen, which has just a proton and an electron. By letting only protons through the electrolyte, the device strips hydrogen from the ammonia, leaving behind the nitrogen.

      The material has other benefits, too, Haile said: “It’s inexpensive, nontoxic, earth-abundant — all these good things that you want to have when you think about a sustainable energy technology.”

      Play video

      2023 Fall Wulff LectureVideo: Department of Materials Science and Engineering

      Sparking interest — and hope

      Haile’s talk piqued interest in the audience, which nearly filled the 6-120 auditorium at MIT, which seats about 150 people.

      Materials science and engineering major Nikhita Law heard hope in Haile’s talk for a more sustainable future.

      “A major problem in making our energy system sustainable is finding ways to store energy from renewables,” Law says. Even if hydrogen-powered cars are not as wide-scale as lithium-battery-powered electric cars, “a permanent energy storage station where we convert electricity into hydrogen and convert it back seems like it makes more sense than mining more lithium.”

      Another DMSE student, senior Daniel Tong, learned about the challenges involved in transporting hydrogen at another seminar and was curious to learn more. “This was something I hadn’t thought of: Can you carry hydrogen more effectively in a different form? That’s really cool.”

      He adds that talks like the Wulff Lecture are helpful in keeping people up to date in a wide-ranging, interdisciplinary field such as materials science and engineering, which spans chemistry, physics, engineering, and other disciplines. “This is a really good way to get exposed to different parts of materials science. There are so many more facets than you know of.”

      In her talk, Haile encouraged audience members to get involved in sustainability research.

      “There’s lots of room for further insight and materials discovery,” she said.

      Haile concluded by underscoring the challenges faced by developing countries in dealing with climate change impacts, particularly those near the equator where there isn’t adequate infrastructure to deal with big swings in precipitation and temperature. For the people who aren’t driven to solve problems that affect people on the other side of the world, Haile offered some extra motivation.

      “I’m sure many of you enjoy coffee. This is going to put the coffee crops in jeopardy as well,” she said. More

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      in Environment

      Merging science and systems thinking to make materials more sustainable

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      For Professor Elsa Olivetti, tackling a problem as large and complex as climate change requires not only lab research but also understanding the systems of production that power the global economy.

      Her career path reflects a quest to investigate materials at scales ranging from the microscopic to the mass-manufactured.

      “I’ve always known what questions I wanted to ask, and then set out to build the tools to help me ask those questions,” says Olivetti, the Jerry McAfee Professor in Engineering.

      Olivetti, who earned tenure in 2022 and was recently appointed associate dean of engineering, has sought to equip students with similar skills, whether in the classroom, in her lab group, or through the interdisciplinary programs she leads at MIT. Those efforts have earned her accolades including the Bose Award for Excellence in Teaching, a MacVicar Faculty Fellowship in 2021, and the McDonald Award for Excellence in Mentoring and Advising in 2023.

      “I think to make real progress in sustainability, materials scientists need to think in interdisciplinary, systems-level ways, but at a deep technical level,” Olivetti says. “Supporting my students so that’s something that a lot more people can do is very rewarding for me.”

      Her mission to make materials more sustainable also makes Olivetti grateful [EAO1] she’s at MIT, which has a long tradition of both interdisciplinary collaboration and technical know-how.

      “MIT’s core competencies are well-positioned for bold achievements in climate and sustainability — the deep expertise on the economics side, the frontier knowledge in science, the computational creativity,” Olivetti says. “It’s a really exciting time and place where the key ingredients for progress are simmering in transformative ways.”

      Answering the call

      The moment that set Olivetti on her life’s journey began when she was 8, with a knock at her door. Her parents were in the other room, so Olivetti opened the door and met an organizer for Greenpeace, a nonprofit that works to raise awareness of environmental issues.

      “I had a chat with that guy and got hooked on environmental concerns,” Olivetti says. “I still remember that conversation.”

      The interaction changed the way Olivetti thought about her place in the world, and her new perspective manifested itself in some unique ways. Her elementary school science fair projects became elaborate pursuits of environmental solutions involving burying various items in the backyard to test for biodegradability. There was also an awkward attempt at natural pesticide development, which lead to a worm hatching in her bedroom.

      As an undergraduate at the University of Virginia, Olivetti gravitated toward classes in environmentalism and materials science.

      “There was a link between materials science and a broader, systems way of framing design for environment, and that just clicked for me in terms of the way I wanted to think about environmental problems — from the atom to the system,” Olivetti recalls.

      That interest led Olivetti to MIT for a PhD in 2001, where she studied the feasibility of new materials for lithium-ion batteries.

      “I really wanted to be thinking of things at a systems level, but I wanted to ground that in lab-based research,” Olivetti says. “I wanted an experiential experience in grad school, and that’s why I chose MIT’s program.”

      Whether it was her undergraduate studies, her PhD, or her ensuing postdoc work at MIT, Olivetti sought to learn new skills to continue bridging the gap between materials science and environmental systems thinking.

      “I think of it as, ‘Here’s how I can build up the ways I ask questions,’” Olivetti explains. “How do we design these materials while thinking about their implications as early as possible?”

      Since joining MIT’s faculty in 2014, Olivetti has developed computational models to measure the cost and environmental impact of new materials, explored ways to adopt more sustainable and circular supply chains, and evaluated potential materials limitations as lithium-ion battery production is scaled. That work helps companies increase their use of greener, recyclable materials and more sustainably dispose of waste.

      Olivetti believes the wide scope of her research gives the students in her lab a more holistic understanding of the life cycle of materials.

      “When the group started, each student was working on a different aspect of the problem — like on the natural language processing pipeline, or on recycling technology assessment, or beneficial use of waste — and now each student can link each of those pieces in their research,” Olivetti explains.

      Beyond her research, Olivetti also co-directs the MIT Climate and Sustainability Consortium, which has established a set of eight areas of sustainability that it organizes coalitions around. Each coalition involves technical leaders at companies and researchers at MIT that work together to accelerate the impact of MIT’s research by helping companies adopt innovative and more sustainable technologies.

      “Climate change mitigation and resilience is such a complex problem, and at MIT we have practice in working together across disciplines on many challenges,” Olivetti says. “It’s been exciting to lean on that culture and unlock ways to move forward more effectively.”

      Bridging divides

      Today, Olivetti tries to maximize the impact of her and her students’ research in materials industrial ecology by maintaining close ties to applications. In her research, this means working directly with aluminum companies to design alloys that could incorporate more scrap material or with nongovernmental organizations to incorporate agricultural residues in building products. In the classroom, that means bringing in people from companies to explain how they think about concepts like heat exchange or fluid flow in their products.

      “I enjoy trying to ground what students are learning in the classroom with what’s happening in the world,” Olivetti explains.

      Exposing students to industry is also a great way to help them think about their own careers. In her research lab, she’s started using the last 30 minutes of meetings to host talks from people working in national labs, startups, and larger companies to show students what they can do after their PhDs. The talks are similar to the Industry Seminar series Olivetti started that pairs undergraduate students with people working in areas like 3D printing, environmental consulting, and manufacturing.

      “It’s about helping students learn what they’re excited about,” Olivetti says.

      Whether in the classroom, lab, or at events held by organizations like MCSC, Olivetti believes collaboration is humanity’s most potent tool to combat climate change.

      “I just really enjoy building links between people,” Olivetti says. “Learning about people and meeting them where they are is a way that one can create effective links. It’s about creating the right playgrounds for people to think and learn.” More

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      in Energy

      Engineers develop an efficient process to make fuel from carbon dioxide

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      The search is on worldwide to find ways to extract carbon dioxide from the air or from power plant exhaust and then make it into something useful. One of the more promising ideas is to make it into a stable fuel that can replace fossil fuels in some applications. But most such conversion processes have had problems with low carbon efficiency, or they produce fuels that can be hard to handle, toxic, or flammable.

      Now, researchers at MIT and Harvard University have developed an efficient process that can convert carbon dioxide into formate, a liquid or solid material that can be used like hydrogen or methanol to power a fuel cell and generate electricity. Potassium or sodium formate, already produced at industrial scales and commonly used as a de-icer for roads and sidewalks, is nontoxic, nonflammable, easy to store and transport, and can remain stable in ordinary steel tanks to be used months, or even years, after its production.

      The new process, developed by MIT doctoral students Zhen Zhang, Zhichu Ren, and Alexander H. Quinn; Harvard University doctoral student Dawei Xi; and MIT Professor Ju Li, is described this week in an open-access paper in Cell Reports Physical Science. The whole process — including capture and electrochemical conversion of the gas to a solid formate powder, which is then used in a fuel cell to produce electricity — was demonstrated at a small, laboratory scale. However, the researchers expect it to be scalable so that it could provide emissions-free heat and power to individual homes and even be used in industrial or grid-scale applications.

      Other approaches to converting carbon dioxide into fuel, Li explains, usually involve a two-stage process: First the gas is chemically captured and turned into a solid form as calcium carbonate, then later that material is heated to drive off the carbon dioxide and convert it to a fuel feedstock such as carbon monoxide. That second step has very low efficiency, typically converting less than 20 percent of the gaseous carbon dioxide into the desired product, Li says.

      By contrast, the new process achieves a conversion of well over 90 percent and eliminates the need for the inefficient heating step by first converting the carbon dioxide into an intermediate form, liquid metal bicarbonate. That liquid is then electrochemically converted into liquid potassium or sodium formate in an electrolyzer that uses low-carbon electricity, e.g. nuclear, wind, or solar power. The highly concentrated liquid potassium or sodium formate solution produced can then be dried, for example by solar evaporation, to produce a solid powder that is highly stable and can be stored in ordinary steel tanks for up to years or even decades, Li says.

      Several steps of optimization developed by the team made all the difference in changing an inefficient chemical-conversion process into a practical solution, says Li, who holds joint appointments in the departments of Nuclear Science and Engineering and of Materials Science and Engineering.

      The process of carbon capture and conversion involves first an alkaline solution-based capture that concentrates carbon dioxide, either from concentrated streams such as from power plant emissions or from very low-concentration sources, even open air, into the form of a liquid metal-bicarbonate solution. Then, through the use of a cation-exchange membrane electrolyzer, this bicarbonate is electrochemically converted into solid formate crystals with a carbon efficiency of greater than 96 percent, as confirmed in the team’s lab-scale experiments.

      These crystals have an indefinite shelf life, remaining so stable that they could be stored for years, or even decades, with little or no loss. By comparison, even the best available practical hydrogen storage tanks allow the gas to leak out at a rate of about 1 percent per day, precluding any uses that would require year-long storage, Li says. Methanol, another widely explored alternative for converting carbon dioxide into a fuel usable in fuel cells, is a toxic substance that cannot easily be adapted to use in situations where leakage could pose a health hazard. Formate, on the other hand, is widely used and considered benign, according to national safety standards.

      Several improvements account for the greatly improved efficiency of this process. First, a careful design of the membrane materials and their configuration overcomes a problem that previous attempts at such a system have encountered, where a buildup of certain chemical byproducts changes the pH, causing the system to steadily lose efficiency over time. “Traditionally, it is difficult to achieve long-term, stable, continuous conversion of the feedstocks,” Zhang says. “The key to our system is to achieve a pH balance for steady-state conversion.”

      To achieve that, the researchers carried out thermodynamic modeling to design the new process so that it is chemically balanced and the pH remains at a steady state with no shift in acidity over time. It can therefore continue operating efficiently over long periods. In their tests, the system ran for over 200 hours with no significant decrease in output. The whole process can be done at ambient temperatures and relatively low pressures (about five times atmospheric pressure).

      Another issue was that unwanted side reactions produced other chemical products that were not useful, but the team figured out a way to prevent these side reactions by the introduction of an extra “buffer” layer of bicarbonate-enriched fiberglass wool that blocked these reactions.

      The team also built a fuel cell specifically optimized for the use of this formate fuel to produce electricity. The stored formate particles are simply dissolved in water and pumped into the fuel cell as needed. Although the solid fuel is much heavier than pure hydrogen, when the weight and volume of the high-pressure gas tanks needed to store hydrogen is considered, the end result is an electricity output near parity for a given storage volume, Li says.

      The formate fuel can potentially be adapted for anything from home-sized units to large scale industrial uses or grid-scale storage systems, the researchers say. Initial household applications might involve an electrolyzer unit about the size of a refrigerator to capture and convert the carbon dioxide into formate, which could be stored in an underground or rooftop tank. Then, when needed, the powdered solid would be mixed with water and fed into a fuel cell to provide power and heat. “This is for community or household demonstrations,” Zhang says, “but we believe that also in the future it may be good for factories or the grid.”

      “The formate economy is an intriguing concept because metal formate salts are very benign and stable, and a compelling energy carrier,” says Ted Sargent, a professor of chemistry and of electrical and computer engineering at Northwestern University, who was not associated with this work. “The authors have demonstrated enhanced efficiency in liquid-to-liquid conversion from bicarbonate feedstock to formate, and have demonstrated these fuels can be used later to produce electricity,” he says.

      The work was supported by the U.S. Department of Energy Office of Science. More

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      in Environment

      Elsa Olivetti appointed associate dean of engineering

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      Elsa Olivetti, the Jerry McAfee (1940) Professor in Engineering in the Department of Materials Science and Engineering, has been appointed as associate dean of engineering, effective Sept. 1.

      As associate dean, Olivetti will oversee a number of strategically important programs and initiatives across MIT’s School of Engineering. She will help lead and shape school-wide efforts related to climate and sustainability. In close collaboration with Nandi Bynoe, the assistant dean for diversity, equity, and inclusion; the school’s DEI faculty lead; and various program faculty leads, Olivetti will oversee the school’s DEI activities and programs. She will also assist with the faculty promotion process and will support both faculty and students across the school with regards fellowships, awards, and honors.

      “Professor Olivetti has demonstrated tremendous leadership abilities, particularly as co-director of the MIT Climate and Sustainability Consortium. Her contributions as a researcher, educator, and leader at MIT have been substantial,” says Anantha Chandrakasan, dean of the School of Engineering and the Vannevar Bush Professor of Electrical Engineering and Computer Science. “I am thrilled to welcome her to the School of Engineering leadership team and look forward to closely with her in this new role.”

      Olivetti first joined MIT as a graduate student after receiving her bachelor’s degree in engineering science from the University of Virginia. As a PhD student in the Department of Materials Science and Engineering (DMSE), her research focused on electrochemistry in inorganic materials for use in lithium-ion batteries. Through postdoctoral research and a staff scientist position with the MIT Materials System Laboratory beginning in 2009, Olivetti developed methods for streamlined carbon footprinting of electronics, a method that is still used widely by the electronics industry.

      In 2014, Olivetti joined the DMSE faculty, where her team works in sustainable and scalable design, processing, and manufacturing of materials use across industries. The Olivetti Group develops experimental and analytical methods for efficient use of industrial waste and recycled materials in concrete, metals, and plastic guiding decisions on a plant floor to policy makers.

      Olivetti’s team has also developed methods to automatically learn from texts within materials ranging from inorganic materials synthesis, zeolites, solid state batteries, and cement. Her work uses an interdisciplinary approach combining industrial ecology with materials science and engineering to inform and then mitigate the environmental and economic impact of materials.

      Olivetti has lead climate and sustainability efforts across the Institute. She serves as the co-director of the MIT Climate and Sustainability Consortium (MCSC). Launched in 2021, the MCSC fosters collaboration between academia and industry in an effort to accelerate real-world solutions for the climate crisis at scale. Under Olivetti’s leadership alongside co-director Jeffrey Grossman, the Morton and Claire Goulder and Family Professor in Environmental Systems, and executive director Jeremy Gregory, the consortium has grown to 18 member companies and has provided 20 research projects with seed funding. It has also launched programs such as the MCSC Climate and Sustainability Scholars Program for undergraduate students and the MCSC Impact Fellows Program for postdocs.

      In addition to her leadership at the MCSC, Olivetti is a member of the MIT Climate Nucleus, a faculty committee responsible for the implementation of “Fast Forward: MIT’s Climate Action Plan for the Decade.”

      A dedicated educator, Olivetti has made significant contributions to MIT’s material science and engineering education. She was instrumental in the development of a refined DMSE undergraduate curriculum. She also launched a new class 3.081 (Industrial Ecology of Materials) and served as a founding thread lead for MIT New Engineering Education Transformation’s Advanced Materials Machines program. Olivetti launched “Course 3 Industry Seminars,” which provide undergraduate students an opportunity to learn from industry leaders in fields like manufacturing and environmental consulting.

      Throughout her career, Olivetti has received numerous awards and honors for both her commitment to students and her research contributions. She is the recipient of the 2017 Earll M. Murman Award for Excellence in Undergraduate Advising, a 2020 Paul Gray Award for Public Service, the 2021 Bose Teaching Award, 2021 MacVicar Faculty Fellowship, and the 2023 Capers (1976) and Marion McDonald Award for Excellence in Mentoring and Advising. She also received an Early Career Faculty Fellowship from the Minerals, Metals and Materials Society as well as a National Science Foundation Early Career Development Award.

      Olivetti joins Dean Chandrakasan and Deputy Dean Maria Yang, the Gail E. Kendall (1978) Professor, on the School of Engineering faculty leadership team. More

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      in Energy

      MIT engineers create an energy-storing supercapacitor from ancient materials

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      Two of humanity’s most ubiquitous historical materials, cement and carbon black (which resembles very fine charcoal), may form the basis for a novel, low-cost energy storage system, according to a new study. The technology could facilitate the use of renewable energy sources such as solar, wind, and tidal power by allowing energy networks to remain stable despite fluctuations in renewable energy supply.

      The two materials, the researchers found, can be combined with water to make a supercapacitor — an alternative to batteries — that could provide storage of electrical energy. As an example, the MIT researchers who developed the system say that their supercapacitor could eventually be incorporated into the concrete foundation of a house, where it could store a full day’s worth of energy while adding little (or no) to the cost of the foundation and still providing the needed structural strength. The researchers also envision a concrete roadway that could provide contactless recharging for electric cars as they travel over that road.

      The simple but innovative technology is described this week in the journal PNAS, in a paper by MIT professors Franz-Josef Ulm, Admir Masic, and Yang-Shao Horn, and four others at MIT and at the Wyss Institute for Biologically Inspired Engineering.

      Capacitors are in principle very simple devices, consisting of two electrically conductive plates immersed in an electrolyte and separated by a membrane. When a voltage is applied across the capacitor, positively charged ions from the electrolyte accumulate on the negatively charged plate, while the positively charged plate accumulates negatively charged ions. Since the membrane in between the plates blocks charged ions from migrating across, this separation of charges creates an electric field between the plates, and the capacitor becomes charged. The two plates can maintain this pair of charges for a long time and then deliver them very quickly when needed. Supercapacitors are simply capacitors that can store exceptionally large charges.

      The amount of power a capacitor can store depends on the total surface area of its conductive plates. The key to the new supercapacitors developed by this team comes from a method of producing a cement-based material with an extremely high internal surface area due to a dense, interconnected network of conductive material within its bulk volume. The researchers achieved this by introducing carbon black — which is highly conductive — into a concrete mixture along with cement powder and water, and letting it cure. The water naturally forms a branching network of openings within the structure as it reacts with cement, and the carbon migrates into these spaces to make wire-like structures within the hardened cement. These structures have a fractal-like structure, with larger branches sprouting smaller branches, and those sprouting even smaller branchlets, and so on, ending up with an extremely large surface area within the confines of a relatively small volume. The material is then soaked in a standard electrolyte material, such as potassium chloride, a kind of salt, which provides the charged particles that accumulate on the carbon structures. Two electrodes made of this material, separated by a thin space or an insulating layer, form a very powerful supercapacitor, the researchers found.

      The two plates of the capacitor function just like the two poles of a rechargeable battery of equivalent voltage: When connected to a source of electricity, as with a battery, energy gets stored in the plates, and then when connected to a load, the electrical current flows back out to provide power.

      “The material is fascinating,” Masic says, “because you have the most-used manmade material in the world, cement, that is combined with carbon black, that is a well-known historical material — the Dead Sea Scrolls were written with it. You have these at least two-millennia-old materials that when you combine them in a specific manner you come up with a conductive nanocomposite, and that’s when things get really interesting.”

      As the mixture sets and cures, he says, “The water is systematically consumed through cement hydration reactions, and this hydration fundamentally affects nanoparticles of carbon because they are hydrophobic (water repelling).” As the mixture evolves, “the carbon black is self-assembling into a connected conductive wire,” he says. The process is easily reproducible, with materials that are inexpensive and readily available anywhere in the world. And the amount of carbon needed is very small — as little as 3 percent by volume of the mix — to achieve a percolated carbon network, Masic says.

      Supercapacitors made of this material have great potential to aid in the world’s transition to renewable energy, Ulm says. The principal sources of emissions-free energy, wind, solar, and tidal power, all produce their output at variable times that often do not correspond to the peaks in electricity usage, so ways of storing that power are essential. “There is a huge need for big energy storage,” he says, and existing batteries are too expensive and mostly rely on materials such as lithium, whose supply is limited, so cheaper alternatives are badly needed. “That’s where our technology is extremely promising, because cement is ubiquitous,” Ulm says.

      The team calculated that a block of nanocarbon-black-doped concrete that is 45 cubic meters (or yards) in size — equivalent to a cube about 3.5 meters across — would have enough capacity to store about 10 kilowatt-hours of energy, which is considered the average daily electricity usage for a household. Since the concrete would retain its strength, a house with a foundation made of this material could store a day’s worth of energy produced by solar panels or windmills and allow it to be used whenever it’s needed. And, supercapacitors can be charged and discharged much more rapidly than batteries.

      After a series of tests used to determine the most effective ratios of cement, carbon black, and water, the team demonstrated the process by making small supercapacitors, about the size of some button-cell batteries, about 1 centimeter across and 1 millimeter thick, that could each be charged to 1 volt, comparable to a 1-volt battery. They then connected three of these to demonstrate their ability to light up a 3-volt light-emitting diode (LED). Having proved the principle, they now plan to build a series of larger versions, starting with ones about the size of a typical 12-volt car battery, then working up to a 45-cubic-meter version to demonstrate its ability to store a house-worth of power.

      There is a tradeoff between the storage capacity of the material and its structural strength, they found. By adding more carbon black, the resulting supercapacitor can store more energy, but the concrete is slightly weaker, and this could be useful for applications where the concrete is not playing a structural role or where the full strength-potential of concrete is not required. For applications such as a foundation, or structural elements of the base of a wind turbine, the “sweet spot” is around 10 percent carbon black in the mix, they found.

      Another potential application for carbon-cement supercapacitors is for building concrete roadways that could store energy produced by solar panels alongside the road and then deliver that energy to electric vehicles traveling along the road using the same kind of technology used for wirelessly rechargeable phones. A related type of car-recharging system is already being developed by companies in Germany and the Netherlands, but using standard batteries for storage.

      Initial uses of the technology might be for isolated homes or buildings or shelters far from grid power, which could be powered by solar panels attached to the cement supercapacitors, the researchers say.

      Ulm says that the system is very scalable, as the energy-storage capacity is a direct function of the volume of the electrodes. “You can go from 1-millimeter-thick electrodes to 1-meter-thick electrodes, and by doing so basically you can scale the energy storage capacity from lighting an LED for a few seconds, to powering a whole house,” he says.

      Depending on the properties desired for a given application, the system could be tuned by adjusting the mixture. For a vehicle-charging road, very fast charging and discharging rates would be needed, while for powering a home “you have the whole day to charge it up,” so slower-charging material could be used, Ulm says.

      “So, it’s really a multifunctional material,” he adds. Besides its ability to store energy in the form of supercapacitors, the same kind of concrete mixture can be used as a heating system, by simply applying electricity to the carbon-laced concrete.

      Ulm sees this as “a new way of looking toward the future of concrete as part of the energy transition.”

      The research team also included postdocs Nicolas Chanut and Damian Stefaniuk at MIT’s Department of Civil and Environmental Engineering, James Weaver at the Wyss Institute, and Yunguang Zhu in MIT’s Department of Mechanical Engineering. The work was supported by the MIT Concrete Sustainability Hub, with sponsorship by the Concrete Advancement Foundation. More

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      in Energy

      3 Questions: What’s it like winning the MIT $100K Entrepreneurship Competition?

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      Solar power plays a major role in nearly every roadmap for global decarbonization. But solar panels are large, heavy, and expensive, which limits their deployment. But what if solar panels looked more like a yoga mat?

      Such a technology could be transported in a roll, carried to the top of a building, and rolled out across the roof in a matter of minutes, slashing installation costs and dramatically expanding the places where rooftop solar makes sense.

      That was the vision laid out by the MIT spinout Active Surfaces as part of the winning pitch at this year’s MIT $100K Entrepreneurship Competition, which took place May 15. The company is leveraging materials science and manufacturing innovations from labs across MIT to make ultra-thin, lightweight, and durable solar a reality.

      The $100K is one of MIT’s most visible entrepreneurship competitions, and past winners say the prize money is only part of the benefit that winning brings to a burgeoning new company. MIT News sat down with Active Surface founders Shiv Bhakta, a graduate student in MIT’s Leaders for Global Operations dual-degree program within the MIT Sloan School of Management and Department of Civil and Environmental Engineering, and Richard Swartwout SM ’18 PhD ’21, an electrical engineering and computer science graduate and former Research Laboratory of Electronics postdoc and MIT.nano innovation fellow, to learn what the last couple of months have been like since they won.

      Q: What is Active Surfaces’ solution, and what is its potential?

      Bhakta: We’re commercializing an ultrathin film, flexible solar technology. Solar is one of the most broadly distributed resources in the world, but access is limited today. It’s heavy — it weighs 50 to 60 pounds a panel — it requires large teams to move around, and the form factor can only be deployed in specific environments.

      Our approach is to develop a solar technology for the built environment. In a nutshell, we can create flexible solar panels that are as thin as paper, just as efficient as traditional panels, and at unprecedented cost floors, all while being applied to any surface. Same area, same power. That’s our motto.

      When I came to MIT, my north star was to dive deeper in my climate journey and help make the world a better, greener place. Now, as we build Active Surfaces, I’m excited to see that dream taking shape. The prospect of transforming any surface into an energy source, thereby expanding solar accessibility globally, holds the promise of significantly reducing CO2 emissions at a gigaton scale. That’s what gets me out of bed in the morning.

      Swartwout: Solar and a lot of other renewables tend to be pretty land-inefficient. Solar 1.0 is using low hanging fruit: cheap land next to easy interconnects and new buildings designed to handle the weight of current panels. But as we ramp up solar, those things will run out. We need to utilize spaces and assets better. That’s what I think solar 2.0 will be: urban PV deployments, solar that’s closer to demand, and integrated into the built environment. These next-generation use cases aren’t just a racking system in the middle of nowhere.

      We’re going after commercial roofs, which would cover most [building] energy demand. Something like 80-90 percent of building electricity demands in the space can be met by rooftop solar.

      The goal is to do the manufacturing in-house. We use roll-to-roll manufacturing, so we can buy tons of equipment off the shelf, but most roll-to-roll manufacturing is made for things like labeling and tape, and not a semiconductor, so our plan is to be the core of semiconductor roll-to-roll manufacturing. There’s never been roll-to-roll semiconductor manufacturing before.

      Q: What have the last few months been like since you won the $100K competition?

      Bhakta: After winning the $100K, we’ve gotten a lot of inbound contact from MIT alumni. I think that’s my favorite part about the MIT community — people stay connected. They’ve been congratulating us, asking to chat, looking to partner, deploy, and invest.

      We’ve also gotten contacted by previous $100K competition winners and other startups that have spun out of MIT that are a year or two or three ahead of us in terms of development. There are a lot of startup scaling challenges that other startup founders are best equipped to answer, and it’s been huge to get guidance from them.

      We’ve also gotten into top accelerators like Cleantech Open, Venture For Climatetech, and ACCEL at Greentown Labs. We also onboarded two rockstar MIT Sloan interns for the summer. Now we’re getting to the product-development phase, building relationships with potential pilot partners, and scaling up the area of our technology.      

      Swartwout: Winning the $100K competition was a great point of validation for the company, because the judges themselves are well known in the venture capital community as well as people who have been in the startup ecosystem for a long time, so that has really propelled us forward. Ideally, we’ll be getting more MIT alumni to join us to fulfill this mission.

      Q: What are your plans for the next year or so?

      Swartwout: We’re planning on leveraging open-access facilities like those at MIT.nano and the University of Massachusetts Amherst. We’re pretty focused now on scaling size. Out of the lab, [the technology] is a 4-inch by 4-inch solar module, and the goal is to get up to something that’s relevant for the industry to offset electricity for building owners and generate electricity for the grid at a reasonable cost.

      Bhakta: In the next year, through those open-access facilities, the goal is to go from 100-millimeter width to 300-millimeter width and a very long length using a roll-to-roll manufacturing process. That means getting through the engineering challenges of scaling technology and fine tuning the performance.

      When we’re ready to deliver a pilotable product, it’s my job to have customers lined up ready to demonstrate this works on their buildings, sign longer term contracts to get early revenue, and have the support we need to demonstrate this at scale. That’s the goal. More

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      Powering the future in Mongolia

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      Nestled within the Tuul River valley and embraced by the southern Khentii Mountain Range, Ulaanbaatar (UB), Mongolia’s largest city, presents itself as an arena where nature’s forces wage an unrelenting battle against human resilience. The capital city is an icy crucible, with bone-chilling winters that plummet temperatures to an astonishing -40 degrees Fahrenheit (-40 degrees Celsius). Mongolia, often hailed with the celestial moniker of “The Land of the Eternal Blue Sky,” paradoxically succumbs to a veil of pollution and energy struggles during the winter months, obscuring the true shade of the cherished vista.

      To understand the root of these issues, MIT students from classes 22.S094 (Climate and Sustainability Systems: Decarbonizing Ulaanbaatar at Scale) and 21A.S01 (Anthro-Engineering: Decarbonization at the Million-Person Scale) visited Mongolia to conduct on-site surveys, diving into the diverse tapestry of local life as they gleaned insight from various stakeholder groups. Setting foot on Mongolian soil on a crisp day in January, they wasted no time in shaking off the weariness of their arduous 17-hour flight, promptly embarking on a waiting bus. As they traversed the vast expanse of the countryside, their eyes were captivated by snow-laden terrain.

      That is, until a disconcerting sight unfolded — thick smog, akin to ethereal pillars, permeated the cityscape ahead. These imposing plumes emanated from the colossal smokestacks of Ulaanbaatar’s coal-fired power plants, steadfastly churning electricity and heat to fuel Mongolia’s central and district energy systems. Over 93 percent of the nation’s energy comes from coal-fired power plants, where the most considerable load is caused by household consumption. Nevertheless, with nearly half of Ulaanbaatar’s population disconnected from the central heating networks, one of Mongolia’s most significant sources of pollution comes from coal-burning stoves in the residential settlements known as the ger districts. Over the past three decades, since the democratic revolution in 1990, Mongolians have grappled with escalating concerns surrounding energy provision, accessibility, and sustainability.

      Engineers who think like anthropologists

      “We find ourselves compelled to venture on-site, engaging in direct conversations with the locals, and immersing ourselves in the fabric of daily life to uncover what we don’t know,” emphasized Michael Short, professor in MIT’s Department of Nuclear Science and Engineering and faculty lead of MIT’s NEET Climate and Sustainability Systems thread, shortly before heading to Mongolia.

      The Ulaanbaatar Project sprang from a multiyear collaboration between MIT and the National University of Mongolia (NUM). Shedding light on the matter, Professor Munkhbat Byambajav of the Department of Chemical and Biological Engineering at NUM underscored the paramount importance of mitigating environmental pollution at an economic scale to alleviate the heavy burden borne by the people.

      Class 22.S094 is offered through MIT’s New Engineering Education Transformation (NEET) program, which allows students with multidisciplinary interests to collaborate across departments within four different subject areas, or threads. In this capstone project, students consider ways to decarbonize a city like Ulaanbaatar, transitioning from burning coal briquettes to a more sustainable, energy-efficient solution, given several parameters and constraints set by the local context.

      One of the ideas students have recently explored is a thermal battery made with molten salt that can store enough energy to heat a ger for up to 12 hours with added insulation for cooling curve regulation. The Mongolian ger, meaning home, is a dome-like portable dwelling covered in felt and canvas, held together by ropes traditionally crafted of animal hair or wool. Over several semesters, students have been testing a version of their proposed idea on campus, working with a prototype that weighs around 35 pounds.

      Nathan Melenbrink, the lead instructor of NEET’s Climate and Sustainability Systems (CSS) thread, believes that the complexity of the Ulaanbaatar capstone project allows students to reject the one-way solution approach and instead consider challenges with a nonprescriptive mindset. The uniqueness of the CSS thread is that students are asked to build on the previous findings from the past cohort and iterate on their designs each year. This workflow has allowed the project to mature and advance in ways that may not be feasible within a semester schedule. When asked how the recent trip impacted the ongoing research back on campus, Melenbrink states, “In light of the recent trip to Mongolia, students are beginning to see the impact of cultural immersion and social awareness leveraging the technical scope and rigor of their work.”

      Course 21A.S01, taught by Professor Manduhai Buyandelger of the MIT Anthropology Section, proved instrumental in deepening students’ understanding of the intricate dynamics at play. She asks, “The prototype works in the lab, but does it work in real life once you factor in the challenges in the larger structures of delivery, production, and implementation in Mongolia?”

      This recognition of the social dimensions of engineering permeated the early stages of the UB project, engaging all participants, including students from MIT and NUM, professionals residing in Mongolia, and local nongovernmental organizations, fostering what Buyandelger aptly describes as “a collaboration on multiple scales: trans-disciplinary and transcontinental.” Lauren Bonilla, co-lecturer for the anthropology course, was crucial in devising the first onsite trip to Mongolia. Drawing upon her extensive ethnographic research in Mongolia that spans decades, Bonilla remarks, “To me, engineering is a highly social discipline.” She further stresses how anthro-engineering elevates the social dimensions of engineering by critically questioning the framing of problems and solutions, stating, “It draws on anthropological insights and methods, like ethnography, to bring a human face to the users of a technology and adds complexity and nuance to the social constraints that limit designs.”

      Making of khorkhog

      Amidst the frigid atmosphere, a traditional Mongolian ger stands in front of the Nuclear Science Laboratory at the National University of Mongolia, emitting warm steam from its roof. The faculty and students of NUM organize a welcoming event inside the ger, inviting everyone to partake in a khorkhog cookout. Earlier that week, a remark from the Mongolian energy representative stood out during one of the presentations: “We need powerful heat. Solar is not enough, and electricity is not enough. Mongolians need fire,” he had emphasized.

      Indeed, the culinary delight known as khorkhog demands the relentless embrace of scorching flames. The process involves a large metal jug, stones, fire, and lamb. With skillful precision, the volunteer chef places the fire-heated stones and large pieces of lamb into the cooking container, triggering a cascade of steam that fills the ger, accompanied by the sounds of sizzling and hissing. Everyone waits patiently as the cook carefully inspects the dish, keenly listening for signs of readiness. And when the time comes, a feast is shared among all, complemented by steam-cooked potatoes, freshly sliced onions, and vegetables. In this moment, the presence of fire symbolizes a profound connection with the heart of Mongolian culture, evoking a deep resonance among the gathered crowd as they partake in this cherished staple meal.

      The distance between two points

      Familiar faces form a grid on the computer screen as the standing meeting between the students in Massachusetts and Ulaanbaatar begins. Sharing the morning (evening in Mongolia) for updates has been a critical effort by both sides to stay engaged and make decisions together. NEET CSS students in Cambridge proceeded to share their latest findings.

      Lucy Nester, a nuclear science and engineering major, has been diligently working on developing a high-efficiency electrical heating solution for individual consumers. Her primary focus is leveraging the discounted electricity rates available in the ger districts and utilize existing infrastructure. Recognizing the importance of maximum flexibility in heating the brick, Nester emphasizes the “no one-size-fits-all” solution. She shares the results of her test trials, which involve both inductive and resistive heating methods, outlining the advantages and disadvantages of each approach. Despite her limited experience in electrical engineering and circuit building, Nester has impressively overcome the steep learning curve. She enthusiastically describes her UB trip as “one of the most remarkable experiences I’ve had during my time at MIT.”

      Darshdeep Grewal, a dedicated materials science and engineering major with a strong passion for data science and computation, has been diligently conducting research on convection heating using COMSOL Multiphysics. In his investigation, Grewal explores the correlation between air temperature and heating, investigates the impact of convecting air arrangement on the heating process, and examines the conditions that may contribute to overheating. Leveraging his expertise in computational workflows, Grewal presents an impressive collection of heatmap simulations derived from the extensive data accumulated by his team throughout the project. Recognizing the immense value of these simulations in modeling complex scenarios, he highlights the importance of running experiments concurrently with simulations to ensure accurate calibration of results, stating, “It’s important to stay rooted in reality.”

      Arina Khotimsky, another materials science and engineering major, has actively engaged in NEET’s Climate and Sustainability Systems thread since her sophomore year. Balancing the demands of her final semester at MIT and the upcoming review of 22.S094, Khotimsky reveals how she has seamlessly integrated her project involvement into her energy studies minor. Reflecting on her journey, she remarks, “Working on the Ulaanbaatar project has taught me the significance of taking local context into account while suggesting solutions as an engineer.” Khotimsky has been tirelessly iterating and refining the insulation box prototype, which holds the thermal battery and controls the rate at which the battery releases heat. In addition, the on-site observations have unveiled another design challenge — ensuring the insulation box functions as a secure and dependable means of transportation. 

      To “engineer” means to contrive through one’s deliberate use of skills. What confronted the UB Project team on site was not the limitations of skill or technology, but the real-world constraints often amiss in the early equation: the people and their everyday lives. With over 6,195 miles of distance between the two groups, it takes more than just dedication to make a collaboration blossom. That may be the desire for a positive impact. Moreover, it may be the goal of cultivating a healthier relationship with energy that spans a million-person scale. No matter where you are, there is no one solution to the complex story of energy. This progressive realization brings the two teams together every two weeks in virtual space, bridging the distance between the two points.  More

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      in Energy

      Arina Khotimsky ’23 awarded 2023 Michel David-Weill Scholarship

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      Arina Khotimsky ’23 was selected for the 2023 Michel David-Weill scholarship, awarded each year to one student from the United States in a master’s program at Sciences Po in France who exemplifies the core values embodied by its namesake: excellence, leadership, multiculturalism, and high achievement. This fall Khotimsky will enter the master’s program in international energy, which is part of Sciences Po’s Paris School of International Affairs. The program aims to provide a holistic understanding of energy issues, across disciplines and across all energy sources.

      Khotimsky graduated this year from MIT with a major in materials science and engineering, and minors in energy studies and in French.

      Asked what drew her to her major, Khotimsky talked about her love of the outdoors. Seeing effects of climate change on the world around made her made her want to explore solutions. “I settled on material science and engineering because there’s so many different applications: whether it be solar power, developing different battery materials and chemistries, or some other technology. Getting that technical background at MIT can help me understand how we can implement solutions around the world, with diverse cultures in mind.”

      One of Khotimsky’s material sciences professors, Polina Anikeeva, observes that “Arina possesses the spirit of creativity, optimism, and unparalleled work ethic — all necessary ingredients to solve energy and climate challenges of our century.”

      Khotimsky is well aware of the big stakes in discussions around energy policy. She explains, “We have to cooperate internationally to make a dent in carbon emissions. The United States is historically the biggest CO2 emitter and has a large role to play to transition to a more sustainable future.”

      Her interest in studying climate change solutions on a world scale also converged with her interest in studying other languages and cultures. Her main language studies at MIT have been in French, although she also speaks Russian and beginner Chinese.

      Due to her achievement in MIT French classes, Khotimsky was one of nine students selected for a two-week cultural immersion program in Paris last June, led by MIT Professor Bruno Perreau. Perreau also had her in class last fall, and spoke about the energy and commitment she brought to class, describing her as “one of my very best students since I started to teach 22 years ago.” Khotimsky is excited to be living in France for her master’s program and putting her French skills to work.

      Khotimsky’s impressive undergraduate career has also included being co-president of the MIT Energy and Climate Club, and participating in the MIT delegation to 2022 Conference of the Parties summit (COP27) of the United Nations in Egypt last November. She also participated in the NEET Decarbonizing Ulaanbaatar project, traveling to Mongolia in Independent Activities Period 2023 with a group of students and instructors to work on clean heating technologies for traditional ger homes.

      In addition to her academic work and other extracurricular activities, Khotimsky was also a member of the MIT women’s rowing team. She walked onto the team as a first-year student, making it into the Varsity 8 boat for her senior season. Holly Metcalf, MIT women’s varsity openweight rowing coach, explains, “Being on the rowing team has in many ways become a metaphor for what Arina has come to study … She realized that rowing is about so much more than physics — it is about who one must become as an individual to contribute to the sum of mental and physical strength of the entire team.” Khotimsky was recognized on May 22 by the Patriot League, who named her the 2023 Patriot League Women’s Rowing Scholar-Athlete of the Year.

      Looking ahead, Khotimsky envisions her future involving international energy negotiations or policy. “The master’s degree I’m pursuing in international relations will help me develop skills to communicate with stakeholders from around the world and figure out how to implement solutions globally.” More