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    Concrete “battery” developed at MIT now packs 10 times the power

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    Concrete already builds our world, and now it’s one step closer to powering it, too. Made by combining cement, water, ultra-fine carbon black (with nanoscale particles), and electrolytes, electron-conducting carbon concrete (ec3, pronounced “e-c-cubed”) creates a conductive “nanonetwork” inside concrete that could enable everyday structures like walls, sidewalks, and bridges to store and release electrical energy. In other words, the concrete around us could one day double as giant “batteries.”As MIT researchers report in a new PNAS paper, optimized electrolytes and manufacturing processes have increased the energy storage capacity of the latest ec3 supercapacitors by an order of magnitude. In 2023, storing enough energy to meet the daily needs of the average home would have required about 45 cubic meters of ec3, roughly the amount of concrete used in a typical basement. Now, with the improved electrolyte, that same task can be achieved with about 5 cubic meters, the volume of a typical basement wall.“A key to the sustainability of concrete is the development of ‘multifunctional concrete,’ which integrates functionalities like this energy storage, self-healing, and carbon sequestration. Concrete is already the world’s most-used construction material, so why not take advantage of that scale to create other benefits?” asks Admir Masic, lead author of the new study, MIT Electron-Conducting Carbon-Cement-Based Materials Hub (EC³ Hub) co-director, and associate professor of civil and environmental engineering (CEE) at MIT.The improved energy density was made possible by a deeper understanding of how the nanocarbon black network inside ec3 functions and interacts with electrolytes. Using focused ion beams for the sequential removal of thin layers of the ec3 material, followed by high-resolution imaging of each slice with a scanning electron microscope (a technique called FIB-SEM tomography), the team across the EC³ Hub and MIT Concrete Sustainability Hub was able to reconstruct the conductive nanonetwork at the highest resolution yet. This approach allowed the team to discover that the network is essentially a fractal-like “web” that surrounds ec3 pores, which is what allows the electrolyte to infiltrate and for current to flow through the system. “Understanding how these materials ‘assemble’ themselves at the nanoscale is key to achieving these new functionalities,” adds Masic.Equipped with their new understanding of the nanonetwork, the team experimented with different electrolytes and their concentrations to see how they impacted energy storage density. As Damian Stefaniuk, first author and EC³ Hub research scientist, highlights, “we found that there is a wide range of electrolytes that could be viable candidates for ec3. This even includes seawater, which could make this a good material for use in coastal and marine applications, perhaps as support structures for offshore wind farms.”At the same time, the team streamlined the way they added electrolytes to the mix. Rather than curing ec3 electrodes and then soaking them in electrolyte, they added the electrolyte directly into the mixing water. Since electrolyte penetration was no longer a limitation, the team could cast thicker electrodes that stored more energy.The team achieved the greatest performance when they switched to organic electrolytes, especially those that combined quaternary ammonium salts — found in everyday products like disinfectants — with acetonitrile, a clear, conductive liquid often used in industry. A cubic meter of this version of ec3 — about the size of a refrigerator — can store over 2 kilowatt-hours of energy. That’s about enough to power an actual refrigerator for a day.While batteries maintain a higher energy density, ec3 can in principle be incorporated directly into a wide range of architectural elements — from slabs and walls to domes and vaults — and last as long as the structure itself.“The Ancient Romans made great advances in concrete construction. Massive structures like the Pantheon stand to this day without reinforcement. If we keep up their spirit of combining material science with architectural vision, we could be at the brink of a new architectural revolution with multifunctional concretes like ec3,” proposes Masic.Taking inspiration from Roman architecture, the team built a miniature ec3 arch to show how structural form and energy storage can work together. Operating at 9 volts, the arch supported its own weight and additional load while powering an LED light.However, something unique happened when the load on the arch increased: the light flickered. This is likely due to the way stress impacts electrical contacts or the distribution of charges. “There may be a kind of self-monitoring capacity here. If we think of an ec3 arch at architectural scale, its output may fluctuate when it’s impacted by a stressor like high winds. We may be able to use this as a signal of when and to what extent a structure is stressed, or monitor its overall health in real time,” envisions Masic.The latest developments in ec³ technology bring it a step closer to real-world scalability. It’s already been used to heat sidewalk slabs in Sapporo, Japan, due to its thermally conductive properties, representing a potential alternative to salting. “With these higher energy densities and demonstrated value across a broader application space, we now have a powerful and flexible tool that can help us address a wide range of persistent energy challenges,” explains Stefaniuk. “One of our biggest motivations was to help enable the renewable energy transition. Solar power, for example, has come a long way in terms of efficiency. However, it can only generate power when there’s enough sunlight. So, the question becomes: How do you meet your energy needs at night, or on cloudy days?”Franz-Josef Ulm, EC³ Hub co-director and CEE professor, continues the thread: “The answer is that you need a way to store and release energy. This has usually meant a battery, which often relies on scarce or harmful materials. We believe that ec3 is a viable substitute, letting our buildings and infrastructure meet our energy storage needs.” The team is working toward applications like parking spaces and roads that could charge electric vehicles, as well as homes that can operate fully off the grid.“What excites us most is that we’ve taken a material as ancient as concrete and shown that it can do something entirely new,” says James Weaver, a co-author on the paper who is an associate professor of design technology and materials science and engineering at Cornell University, as well as a former EC³ Hub researcher. “By combining modern nanoscience with an ancient building block of civilization, we’re opening a door to infrastructure that doesn’t just support our lives, it powers them.” More

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      AI system learns from many types of scientific information and runs experiments to discover new materials

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      Machine-learning models can speed up the discovery of new materials by making predictions and suggesting experiments. But most models today only consider a few specific types of data or variables. Compare that with human scientists, who work in a collaborative environment and consider experimental results, the broader scientific literature, imaging and structural analysis, personal experience or intuition, and input from colleagues and peer reviewers.Now, MIT researchers have developed a method for optimizing materials recipes and planning experiments that incorporates information from diverse sources like insights from the literature, chemical compositions, microstructural images, and more. The approach is part of a new platform, named Copilot for Real-world Experimental Scientists (CRESt), that also uses robotic equipment for high-throughput materials testing, the results of which are fed back into large multimodal models to further optimize materials recipes.Human researchers can converse with the system in natural language, with no coding required, and the system makes its own observations and hypotheses along the way. Cameras and visual language models also allow the system to monitor experiments, detect issues, and suggest corrections.“In the field of AI for science, the key is designing new experiments,” says Ju Li, School of Engineering Carl Richard Soderberg Professor of Power Engineering. “We use multimodal feedback — for example information from previous literature on how palladium behaved in fuel cells at this temperature, and human feedback — to complement experimental data and design new experiments. We also use robots to synthesize and characterize the material’s structure and to test performance.”The system is described in a paper published in Nature. The researchers used CRESt to explore more than 900 chemistries and conduct 3,500 electrochemical tests, leading to the discovery of a catalyst material that delivered record power density in a fuel cell that runs on formate salt to produce electricity.Joining Li on the paper as first authors are PhD student Zhen Zhang, Zhichu Ren PhD ’24, PhD student Chia-Wei Hsu, and postdoc Weibin Chen. Their coauthors are MIT Assistant Professor Iwnetim Abate; Associate Professor Pulkit Agrawal; JR East Professor of Engineering Yang Shao-Horn; MIT.nano researcher Aubrey Penn; Zhang-Wei Hong PhD ’25, Hongbin Xu PhD ’25; Daniel Zheng PhD ’25; MIT graduate students Shuhan Miao and Hugh Smith; MIT postdocs Yimeng Huang, Weiyin Chen, Yungsheng Tian, Yifan Gao, and Yaoshen Niu; former MIT postdoc Sipei Li; and collaborators including Chi-Feng Lee, Yu-Cheng Shao, Hsiao-Tsu Wang, and Ying-Rui Lu.

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      A smarter systemMaterials science experiments can be time-consuming and expensive. They require researchers to carefully design workflows, make new material, and run a series of tests and analysis to understand what happened. Those results are then used to decide how to improve the material.To improve the process, some researchers have turned to a machine-learning strategy known as active learning to make efficient use of previous experimental data points and explore or exploit those data. When paired with a statistical technique known as Bayesian optimization (BO), active learning has helped researchers identify new materials for things like batteries and advanced semiconductors.“Bayesian optimization is like Netflix recommending the next movie to watch based on your viewing history, except instead it recommends the next experiment to do,” Li explains. “But basic Bayesian optimization is too simplistic. It uses a boxed-in design space, so if I say I’m going to use platinum, palladium, and iron, it only changes the ratio of those elements in this small space. But real materials have a lot more dependencies, and BO often gets lost.”Most active learning approaches also rely on single data streams that don’t capture everything that goes on in an experiment. To equip computational systems with more human-like knowledge, while still taking advantage of the speed and control of automated systems, Li and his collaborators built CRESt.CRESt’s robotic equipment includes a liquid-handling robot, a carbothermal shock system to rapidly synthesize materials, an automated electrochemical workstation for testing, characterization equipment including automated electron microscopy and optical microscopy, and auxiliary devices such as pumps and gas valves, which can also be remotely controlled.  Many processing parameters can also be tuned.With the user interface, researchers can chat with CRESt and tell it to use active learning to find promising materials recipes for different projects. CRESt can include up to 20 precursor molecules and substrates into its recipe. To guide material designs, CRESt’s models search through scientific papers for descriptions of elements or precursor molecules that might be useful. When human researchers tell CRESt to pursue new recipes, it kicks off a robotic symphony of sample preparation, characterization, and testing. The researcher can also ask CRESt to perform image analysis from scanning electron microscopy imaging, X-ray diffraction, and other sources.Information from those processes is used to train the active learning models, which use both literature knowledge and current experimental results to suggest further experiments and accelerate materials discovery.“For each recipe we use previous literature text or databases, and it creates these huge representations of every recipe based on the previous knowledge base before even doing the experiment,” says Li. “We perform principal component analysis in this knowledge embedding space to get a reduced search space that captures most of the performance variability. Then we use Bayesian optimization in this reduced space to design the new experiment. After the new experiment, we feed newly acquired multimodal experimental data and human feedback into a large language model to augment the knowledgebase and redefine the reduced search space, which gives us a big boost in active learning efficiency.”Materials science experiments can also face reproducibility challenges. To address the problem, CRESt monitors its experiments with cameras, looking for potential problems and suggesting solutions via text and voice to human researchers.The researchers used CRESt to develop an electrode material for an advanced type of high-density fuel cell known as a direct formate fuel cell. After exploring more than 900 chemistries over three months, CRESt discovered a catalyst material made from eight elements that achieved a 9.3-fold improvement in power density per dollar over pure palladium, an expensive precious metal. In further tests, CRESTs material was used to deliver a record power density to a working direct formate fuel cell even though the cell contained just one-fourth of the precious metals of previous devices.The results show the potential for CRESt to find solutions to real-world energy problems that have plagued the materials science and engineering community for decades.“A significant challenge for fuel-cell catalysts is the use of precious metal,” says Zhang. “For fuel cells, researchers have used various precious metals like palladium and platinum. We used a multielement catalyst that also incorporates many other cheap elements to create the optimal coordination environment for catalytic activity and resistance to poisoning species such as carbon monoxide and adsorbed hydrogen atom. People have been searching low-cost options for many years. This system greatly accelerated our search for these catalysts.”A helpful assistantEarly on, poor reproducibility emerged as a major problem that limited the researchers’ ability to perform their new active learning technique on experimental datasets. Material properties can be influenced by the way the precursors are mixed and processed, and any number of problems can subtly alter experimental conditions, requiring careful inspection to correct.To partially automate the process, the researchers coupled computer vision and vision language models with domain knowledge from the scientific literature, which allowed the system to hypothesize sources of irreproducibility and propose solutions. For example, the models can notice when there’s a millimeter-sized deviation in a sample’s shape or when a pipette moves something out of place. The researchers incorporated some of the model’s suggestions, leading to improved consistency, suggesting the models already make good experimental assistants.The researchers noted that humans still performed most of the debugging in their experiments.“CREST is an assistant, not a replacement, for human researchers,” Li says. “Human researchers are still indispensable. In fact, we use natural language so the system can explain what it is doing and present observations and hypotheses. But this is a step toward more flexible, self-driving labs.” More

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      Creeping crystals: Scientists observe “salt creep” at the single-crystal scale

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      Salt creeping, a phenomenon that occurs in both natural and industrial processes, describes the collection and migration of salt crystals from evaporating solutions onto surfaces. Once they start collecting, the crystals climb, spreading away from the solution. This creeping behavior, according to researchers, can cause damage or be harnessed for good, depending on the context. New research published June 30 in the journal Langmuir is the first to show salt creeping at a single-crystal scale and beneath a liquid’s meniscus.“The work not only explains how salt creeping begins, but why it begins and when it does,” says Joseph Phelim Mooney, a postdoc in the MIT Device Research Laboratory and one of the authors of the new study. “We hope this level of insight helps others, whether they’re tackling water scarcity, preserving ancient murals, or designing longer-lasting infrastructure.”The work is the first to directly visualize how salt crystals grow and interact with surfaces underneath a liquid meniscus, something that’s been theorized for decades but never actually imaged or confirmed at this level, and it offers fundamental insights that could impact a wide range of fields — from mineral extraction and desalination to anti-fouling coatings, membrane design for separation science, and even art conservation, where salt damage is a major threat to heritage materials.In civil engineering applications, for example, the research can help explain why and when salt crystals start growing across surfaces like concrete, stone, or building materials. “These crystals can exert pressure and cause cracking or flaking, reducing the long-term durability of structures,” says Mooney. “By pinpointing the moment when salt begins to creep, engineers can better design protective coatings or drainage systems to prevent this form of degradation.”For a field like art conservation, where salt can be devastating to murals, frescoes, and ancient artifacts, often forming beneath the surface before visible damage appears, the work can help identify the exact conditions that cause salt to start moving and spreading, allowing conservators to act earlier and more precisely to protect heritage objects.The work began during Mooney’s Marie Curie Fellowship at MIT. “I was focused on improving desalination systems and quickly ran into [salt buildup as] a major roadblock,” he says. “[Salt] was everywhere, coating surfaces, clogging flow paths, and undermining the efficiency of our designs. I realized we didn’t fully understand how or why salt starts creeping across surfaces in the first place.”That experience led Mooney to team up with colleagues to dig into the fundamentals of salt crystallization at the air–liquid–solid interface. “We wanted to zoom in, to really see the moment salt begins to move, so we turned to in situ X-ray microscopy,” he says. “What we found gave us a whole new way to think about surface fouling, material degradation, and controlled crystallization.”The new research may, in fact, allow better control of a crystallization processes required to remove salt from water in zero-liquid discharge systems. It can also be used to explain how and when scaling happens on equipment surfaces, and may support emerging climate technologies that depend on smart control of evaporation and crystallization.The work also supports mineral and salt extraction applications, where salt creeping can be both a bottleneck and an opportunity. In these applications, Mooney says, “by understanding the precise physics of salt formation at surfaces, operators can optimize crystal growth, improving recovery rates and reducing material losses.”Mooney’s co-authors on the paper include fellow MIT Device Lab researchers Omer Refet Caylan, Bachir El Fil (now an associate professor at Georgia Tech), and Lenan Zhang (now an associate professor at Cornell University); Jeff Punch and Vanessa Egan of the University of Limerick; and Jintong Gao of Cornell.The research was conducted using in situ X-ray microscopy. Mooney says the team’s big realization moment occurred when they were able to observe a single salt crystal pinning itself to the surface, which kicked off a cascading chain reaction of growth.“People had speculated about this, but we captured it on X-ray for the first time. It felt like watching the microscopic moment where everything tips, the ignition points of a self-propagating process,” says Mooney. “Even more surprising was what followed: The salt crystal didn’t just grow passively to fill the available space. It pierced through the liquid-air interface and reshaped the meniscus itself, setting up the perfect conditions for the next crystal. That subtle, recursive mechanism had never been visually documented before — and seeing it play out in real time completely changed how we thought about salt crystallization.”The paper, “In Situ X-ray Microscopy Unraveling the Onset of Salt Creeping at a Single-Crystal Level,” is available now in the journal Langmuir. Research was conducted in MIT.nano.  More

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      Universal nanosensor unlocks the secrets to plant growth

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      Researchers from the Disruptive and Sustainable Technologies for Agricultural Precision (DiSTAP) interdisciplinary research group within the Singapore-MIT Alliance for Research and Technology have developed the world’s first near-infrared fluorescent nanosensor capable of real-time, nondestructive, and species-agnostic detection of indole-3-acetic acid (IAA) — the primary bioactive auxin hormone that controls the way plants develop, grow, and respond to stress.Auxins, particularly IAA, play a central role in regulating key plant processes such as cell division, elongation, root and shoot development, and response to environmental cues like light, heat, and drought. External factors like light affect how auxin moves within the plant, temperature influences how much is produced, and a lack of water can disrupt hormone balance. When plants cannot effectively regulate auxins, they may not grow well, adapt to changing conditions, or produce as much food. Existing IAA detection methods, such as liquid chromatography, require taking plant samples from the plant — which harms or removes part of it. Conventional methods also measure the effects of IAA rather than detecting it directly, and cannot be used universally across different plant types. In addition, since IAA are small molecules that cannot be easily tracked in real time, biosensors that contain fluorescent proteins need to be inserted into the plant’s genome to measure auxin, making it emit a fluorescent signal for live imaging.SMART’s newly developed nanosensor enables direct, real-time tracking of auxin levels in living plants with high precision. The sensor uses near infrared imaging to monitor IAA fluctuations non-invasively across tissues like leaves, roots, and cotyledons, and it is capable of bypassing chlorophyll interference to ensure highly reliable readings even in densely pigmented tissues. The technology does not require genetic modification and can be integrated with existing agricultural systems — offering a scalable precision tool to advance both crop optimization and fundamental plant physiology research. By providing real-time, precise measurements of auxin, the sensor empowers farmers with earlier and more accurate insights into plant health. With these insights and comprehensive data, farmers can make smarter, data-driven decisions on irrigation, nutrient delivery, and pruning, tailored to the plant’s actual needs — ultimately improving crop growth, boosting stress resilience, and increasing yields.“We need new technologies to address the problems of food insecurity and climate change worldwide. Auxin is a central growth signal within living plants, and this work gives us a way to tap it to give new information to farmers and researchers,” says Michael Strano, co-lead principal investigator at DiSTAP, Carbon P. Dubbs Professor of Chemical Engineering at MIT, and co-corresponding author of the paper. “The applications are many, including early detection of plant stress, allowing for timely interventions to safeguard crops. For urban and indoor farms, where light, water, and nutrients are already tightly controlled, this sensor can be a valuable tool in fine-tuning growth conditions with even greater precision to optimize yield and sustainability.”The research team documented the nanosensor’s development in a paper titled, “A Near-Infrared Fluorescent Nanosensor for Direct and Real-Time Measurement of Indole-3-Acetic Acid in Plants,” published in the journal ACS Nano. The sensor comprises single-walled carbon nanotubes wrapped in a specially designed polymer, which enables it to detect IAA through changes in near infrared fluorescence intensity. Successfully tested across multiple species, including Arabidopsis, Nicotiana benthamiana, choy sum, and spinach, the nanosensor can map IAA responses under various environmental conditions such as shade, low light, and heat stress. “This sensor builds on DiSTAP’s ongoing work in nanotechnology and the CoPhMoRe technique, which has already been used to develop other sensors that can detect important plant compounds such as gibberellins and hydrogen peroxide. By adapting this approach for IAA, we’re adding to our inventory of novel, precise, and nondestructive tools for monitoring plant health. Eventually, these sensors can be multiplexed, or combined, to monitor a spectrum of plant growth markers for more complete insights into plant physiology,” says Duc Thinh Khong, research scientist at DiSTAP and co-first author of the paper.“This small but mighty nanosensor tackles a long-standing challenge in agriculture: the need for a universal, real-time, and noninvasive tool to monitor plant health across various species. Our collaborative achievement not only empowers researchers and farmers to optimize growth conditions and improve crop yield and resilience, but also advances our scientific understanding of hormone pathways and plant-environment interactions,” says In-Cheol Jang, senior principal investigator at TLL, principal investigator at DiSTAP, and co-corresponding author of the paper.Looking ahead, the research team is looking to combine multiple sensing platforms to simultaneously detect IAA and its related metabolites to create a comprehensive hormone signaling profile, offering deeper insights into plant stress responses and enhancing precision agriculture. They are also working on using microneedles for highly localized, tissue-specific sensing, and collaborating with industrial urban farming partners to translate the technology into practical, field-ready solutions. The research was carried out by SMART, and supported by the National Research Foundation of Singapore under its Campus for Research Excellence And Technological Enterprise program. More

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      SLB joins the MIT.nano Consortium

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      SLB, a global company creating technology to address the world’s energy challenges, has joined the MIT.nano Consortium.The MIT.nano Consortium is a platform for academia-industry collaboration, fostering research and innovation in nanoscale science and engineering.“The addition of SLB to the MIT.nano Consortium represents a powerful synergy between academic innovation and leading industry,” says Vladimir Bulović, the founding faculty director of MIT.nano and the Fariborz Masseh (1990) Professor of Emerging Technologies at MIT. “SLB’s expertise in developing energy technologies and its commitment to decarbonization aligns with MIT‘s mission to address the many challenges of climate change. Their addition to the consortium, and collaborations that will follow, will empower the MIT.nano community to advance critical research in this domain.”For 100 years, SLB has developed strategies and systems to unlock access to energy beneath the Earth’s surface. The company’s founder, Conrad Schlumberger, conceived the idea of using electrical measurements to map subsurface rock bodies back in 1912. Since then, SLB has continued to open new fronts in energy exploration—innovating in oil and gas, scaling new technologies, and designing digital solutions. Applying decades of innovation in science and engineering, SLB has committed to accelerating the decarbonization of the energy sector and supporting the global transition to low-carbon energy systems.With more than 900 facilities in over 120 countries, SLB adds to the global industry perspective of the MIT.nano Consortium and the broader MIT research community.“Taking a nanoscale approach to the scientific and technological challenges we face in the decarbonization domains is an endeavor that SLB is excited to embark on with MIT.nano,” says Smaine Zeroug, SLB research director and ambassador to MIT. “We are confident our engagement with MIT.nano and the extensive research network they offer access to will ultimately lead to field-viable solutions.”SLB has a longstanding relationship with MIT. The company, formerly named Schlumberger, donated specialized software to the MIT Seismic Visualization Laboratory in 1999 to enable MIT researchers and students to use three-dimensional seismic data in their studies of the Earth’s upper crust. SLB is also a current member of the MIT CSAIL Alliances.As a member of the MIT.nano consortium, SLB will gain unparalleled access to MIT.nano’s dynamic user community, providing opportunities to share expertise and guide advances in nanoscale technology.MIT.nano continues to welcome new companies as sustaining members. For details, and to see a list of current members, visit the MIT.nano Consortium page. More

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      The MIT-Portugal Program enters Phase 4

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      Since its founding 19 years ago as a pioneering collaboration with Portuguese universities, research institutions and corporations, the MIT-Portugal Program (MPP) has achieved a slew of successes — from enabling 47 entrepreneurial spinoffs and funding over 220 joint projects between MIT and Portuguese researchers to training a generation of exceptional researchers on both sides of the Atlantic.In March, with nearly two decades of collaboration under their belts, MIT and the Portuguese Science and Technology Foundation (FCT) signed an agreement that officially launches the program’s next chapter. Running through 2030, MPP’s Phase 4 will support continued exploration of innovative ideas and solutions in fields ranging from artificial intelligence and nanotechnology to climate change — both on the MIT campus and with partners throughout Portugal.  “One of the advantages of having a program that has gone on so long is that we are pretty well familiar with each other at this point. Over the years, we’ve learned each other’s systems, strengths and weaknesses and we’ve been able to create a synergy that would not have existed if we worked together for a short period of time,” says Douglas Hart, MIT mechanical engineering professor and MPP co-director.Hart and John Hansman, the T. Wilson Professor of Aeronautics and Astronautics at MIT and MPP co-director, are eager to take the program’s existing research projects further, while adding new areas of focus identified by MIT and FCT. Known as the Fundação para a Ciência e Tecnologia in Portugal, FCT is the national public agency supporting research in science, technology and innovation under Portugal’s Ministry of Education, Science and Innovation.“Over the past two decades, the partnership with MIT has built a foundation of trust that has fostered collaboration among researchers and the development of projects with significant scientific impact and contributions to the Portuguese economy,” Fernando Alexandre, Portugal’s minister for education, science, and innovation, says. “In this new phase of the partnership, running from 2025 to 2030, we expect even greater ambition and impact — raising Portuguese science and its capacity to transform the economy and improve our society to even higher levels, while helping to address the challenges we face in areas such as climate change and the oceans, digitalization, and space.”“International collaborations like the MIT-Portugal Program are absolutely vital to MIT’s mission of research, education and service. I’m thrilled to see the program move into its next phase,” says MIT President Sally Kornbluth. “MPP offers our faculty and students opportunities to work in unique research environments where they not only make new findings and learn new methods but also contribute to solving urgent local and global problems. MPP’s work in the realm of ocean science and climate is a prime example of how international partnerships like this can help solve important human problems.”Sharing MIT’s commitment to academic independence and excellence, Kornbluth adds, “the institutions and researchers we partner with through MPP enhance MIT’s ability to achieve its mission, enabling us to pursue the exacting standards of intellectual and creative distinction that make MIT a cradle of innovation and world leader in scientific discovery.”The epitome of an effective international collaboration, MPP has stayed true to its mission and continued to deliver results here in the U.S. and in Portugal for nearly two decades — prevailing amid myriad shifts in the political, social, and economic landscape. The multifaceted program encompasses an annual research conference and educational summits such as an Innovation Workshop at MIT each June and a Marine Robotics Summer School in the Azores in July, as well as student and faculty exchanges that facilitate collaborative research. During the third phase of the program alone, 59 MIT students and 53 faculty and researchers visited Portugal, and MIT hosted 131 students and 49 faculty and researchers from Portuguese universities and other institutions.In each roughly five-year phase, MPP researchers focus on a handful of core research areas. For Phase 3, MPP advanced cutting-edge research in four strategic areas: climate science and climate change; Earth systems: oceans to near space; digital transformation in manufacturing; and sustainable cities. Within these broad areas, MIT and FCT researchers worked together on numerous small-scale projects and several large “flagship” ones, including development of Portugal’s CubeSat satellite, a collaboration between MPP and several Portuguese universities and companies that marked the country’s second satellite launch and the first in 30 years.While work in the Phase 3 fields will continue during Phase 4, researchers will also turn their attention to four more areas: chips/nanotechnology, energy (a previous focus in Phase 2), artificial intelligence, and space.“We are opening up the aperture for additional collaboration areas,” Hansman says.In addition to focusing on distinct subject areas, each phase has emphasized the various parts of MPP’s mission to differing degrees. While Phase 3 accentuated collaborative research more than educational exchanges and entrepreneurship, those two aspects will be given more weight under the Phase 4 agreement, Hart said.“We have approval in Phase 4 to bring a number of Portuguese students over, and our principal investigators will benefit from close collaborations with Portuguese researchers,” he says.The longevity of MPP and the recent launch of Phase 4 are evidence of the program’s value. The program has played a role in the educational, technological and economic progress Portugal has achieved over the past two decades, as well.  “The Portugal of today is remarkably stronger than the Portugal of 20 years ago, and many of the places where they are stronger have been impacted by the program,” says Hansman, pointing to sustainable cities and “green” energy, in particular. “We can’t take direct credit, but we’ve been part of Portugal’s journey forward.”Since MPP began, Hart adds, “Portugal has become much more entrepreneurial. Many, many, many more start-up companies are coming out of Portuguese universities than there used to be.”  A recent analysis of MPP and FCT’s other U.S. collaborations highlighted a number of positive outcomes. The report noted that collaborations with MIT and other US universities have enhanced Portuguese research capacities and promoted organizational upgrades in the national R&D ecosystem, while providing Portuguese universities and companies with opportunities to engage in complex projects that would have been difficult to undertake on their own.Regarding MIT in particular, the report found that MPP’s long-term collaboration has spawned the establishment of sustained doctoral programs and pointed to a marked shift within Portugal’s educational ecosystem toward globally aligned standards. MPP, it reported, has facilitated the education of 198 Portuguese PhDs.Portugal’s universities, students and companies are not alone in benefitting from the research, networks, and economic activity MPP has spawned. MPP also delivers unique value to MIT, as well as to the broader US science and research community. Among the program’s consistent themes over the years, for example, is “joint interest in the Atlantic,” Hansman says.This summer, Faial Island in the Azores will host MPP’s fifth annual Marine Robotics Summer School, a two-week course open to 12 Portuguese Master’s and first year PhD students and 12 MIT upper-level undergraduates and graduate students. The course, which includes lectures by MIT and Portuguese faculty and other researchers, workshops, labs and hands-on experiences, “is always my favorite,” said Hart.“I get to work with some of the best researchers in the world there, and some of the top students coming out of Woods Hole Oceanographic Institution, MIT, and Portugal,” he says, adding that some of his previous Marine Robotics Summer School students have come to study at MIT and then gone on to become professors in ocean science.“So, it’s been exciting to see the growth of students coming out of that program, certainly a positive impact,” Hart says.MPP provides one-of-a-kind opportunities for ocean research due to the unique marine facilities available in Portugal, including not only open ocean off the Azores but also Lisbon’s deep-water port and a Portuguese Naval facility just south of Lisbon that is available for collaborative research by international scientists. Like MIT, Portuguese universities are also strongly invested in climate change research — a field of study keenly related to ocean systems.“The international collaboration has allowed us to test and further develop our research prototypes in different aquaculture environments both in the US and in Portugal, while building on the unique expertise of our Portuguese faculty collaborator Dr. Ricardo Calado from the University of Aveiro and our industry collaborators,” says Stefanie Mueller, the TIBCO Career Development Associate Professor in MIT’s departments of Electrical Engineering and Computer Science and Mechanical Engineering and leader of the Human-Computer Interaction Group at the MIT Computer Science and Artificial Intelligence Lab.Mueller points to the work of MIT mechanical engineering PhD student Charlene Xia, a Marine Robotics Summer School participant, whose research is aimed at developing an economical system to monitor the microbiome of seaweed farms and halt the spread of harmful bacteria associated with ocean warming. In addition to participating in the summer school as a student, Xia returned to the Azores for two subsequent years as a teaching assistant.“The MIT-Portugal Program has been a key enabler of our research on monitoring the aquatic microbiome for potential disease outbreaks,” Mueller says.As MPP enters its next phase, Hart and Hansman are optimistic about the program’s continuing success on both sides of the Atlantic and envision broadening its impact going forward.“I think, at this point, the research is going really well, and we’ve got a lot of connections. I think one of our goals is to expand not the science of the program necessarily, but the groups involved,” Hart says, noting that MPP could have a bigger presence in technical fields such as AI and micro-nano manufacturing, as well as in social sciences and humanities.“We’d like to involve many more people and new people here at MIT, as well as in Portugal,” he says, “so that we can reach a larger slice of the population.”  More

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      in Environment

      Cleaning up critical minerals and materials production, using microwave plasma

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      The push to bring manufacturing back to the U.S. is running up against an unfortunate truth: The processes for making many critical materials today create toxic byproducts and other environmental hazards. That’s true for commonly used industrial metals like nickel and titanium, as well as specialty minerals, materials, and coatings that go into batteries, advanced electronics, and defense applications.Now 6K, founded by former MIT research scientist Kamal Hadidi, is using a new production process to bring critical materials production back to America without the toxic byproducts.The company is actively scaling its microwave plasma technology, which it calls UniMelt, to transform the way critical minerals are processed, creating new domestic supply chains in the process. UniMelt uses beams of tightly controlled thermal plasma to melt or vaporize precursor materials into particles with precise sizes and crystalline phases.The technology converts metals, such as titanium, nickel, and refractory alloys, into particles optimized for additive manufacturing for a range of industrial applications. It is also being used to create battery materials for electric vehicles, grid infrastructure, and data centers.“The markets and critical materials we are focused on are important for not just economic reasons but also U.S. national security, because the bulk of these materials are manufactured today in nonfriendly countries,” 6K CEO Saurabh Ullal says. “Now, the [U.S. government] and our growing customer base can leverage this technology invented at MIT to make the U.S. less dependent on these nonfriendly countries, ensuring supply chain independence now and in the future.”Named after the 6,000-degree temperature of its plasma, 6K is currently selling its high-performance metal powders to parts manufacturers as well as defense, automotive, medical, and oil and gas companies for use in applications from engine components and medical implants to rockets. To scale its battery materials business, 6K is also building a 100,000-square-foot production facility in Jackson, Tennessee, which will begin construction later this year.A weekend projectBetween 1994 and 2007, Hadidi worked at the Plasma Science and Fusion Center (PFSC), where he developed plasma technologies for a range of applications, including hydrogen production, fuel reforming, and detecting environmental toxins. His first company was founded in 2000 out of the PFSC to detect mercury in coal-fired power plants’ smokestacks.“I loved working at MIT,” Hadidi says. “It’s an amazing place that really challenges you. Just being there is so stimulating because everyone’s trying to come up with new solutions and connect dots between different fields.”Hadidi also began using high-frequency microwave plasmas to create nanomaterials for use in optical applications. He wasn’t a materials expert, so he collaborated with Professor Eric Jordan, a materials synthesis expert from the University of Connecticut, and the researchers started working on nights and weekends in the PSFC to develop the idea further, eventually patenting the technology.Hadidi officially founded the company as Amastan in 2007, exploring the use of his microwave plasma technology, later named UniMelt for “uniform melt state process,” to make a host of different materials as part of a government grant he and Jordan received.The researchers soon realized the microwave plasma technology had several advantages over traditional production techniques for certain materials. For one, it could eliminate several high-energy steps of conventional processes, reducing production times from days to hours in some cases. For batteries and certain critical minerals, the process also works with recycled feedstocks. Amastan was renamed 6K in 2019.Early on, Hadidi produced metal powders used in additive manufacturing through a process called spheroidization, which results in dense, spherical powders that flow well and make high-performance 3D-printed parts.Following another grant, Hadidi explored methods for producing a type of battery cathode made from lithium, nickel, manganese, and cobalt (NMC). The standard process for making NMCs involved chemical synthesis, precipitation, heat treatment, and a lot of water. 6K is able to reduce many of those steps, speeding up production and lowering costs while also being more sustainable.“Our technology completely eliminates toxic waste and recycles all of the byproducts back through the process to utilize everything, including water,” Ullal says.Scaling domestic productionToday, 6K’s additive manufacturing arm operates out of a factory in Pennsylvania. The company’s critical minerals processing, refining, and recycling systems can produce about 400 tons of material per year and can be used to make more than a dozen types of metal powders. The company also has 33,000-square-foot battery center in North Andover, Massachusetts, where it produces battery cathode materials for its energy storage and mobility customers.The Tennessee facility will be used to produce battery cathode materials and represents a massive step up in throughput. The company says it will be able to produce 13,000 tons of material annually when construction is complete next year.“I’m happy if what I started brings something positive to society, and I’m extremely thankful to all the people that helped me,” says Hadidi, who left the company in 2019. “I’m an entrepreneur at heart. I like to make things. But that doesn’t mean I always succeed. It’s personally very satisfying to see this make an impact.”The 6K team says its technology can also create a variety of specialty ceramics, advanced coatings, and nanoengineered materials. They say it may also be used to eliminate PFAS, or “forever chemicals,” though that work is at an early stage.The company recently received a grant to demonstrate a process for recycling critical materials from military depots to produce aerospace and defense products, creating a new value stream for these materials that would otherwise deteriorate or go to landfill. That work is consistent with the company’s motto, “We take nothing from the ground and put nothing into the ground.”The company’s additive division recently received a $23.4 Defense Production Act grant “that will enable us to double processing capacity in the next three years,” Ullal says. “The next step is to scale battery materials production to the tens of thousands of tons per year. At this point, it’s a scale-up of known processes, and we just need to execute. The idea of creating a circular economy is near and dear to us because that’s how we’ve built this company and that’s how we generate value: addressing our U.S. national security concerns and protecting the planet as well.” More

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      in Energy

      Nanoscale transistors could enable more efficient electronics

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      Silicon transistors, which are used to amplify and switch signals, are a critical component in most electronic devices, from smartphones to automobiles. But silicon semiconductor technology is held back by a fundamental physical limit that prevents transistors from operating below a certain voltage.This limit, known as “Boltzmann tyranny,” hinders the energy efficiency of computers and other electronics, especially with the rapid development of artificial intelligence technologies that demand faster computation.In an effort to overcome this fundamental limit of silicon, MIT researchers fabricated a different type of three-dimensional transistor using a unique set of ultrathin semiconductor materials.Their devices, featuring vertical nanowires only a few nanometers wide, can deliver performance comparable to state-of-the-art silicon transistors while operating efficiently at much lower voltages than conventional devices.“This is a technology with the potential to replace silicon, so you could use it with all the functions that silicon currently has, but with much better energy efficiency,” says Yanjie Shao, an MIT postdoc and lead author of a paper on the new transistors.The transistors leverage quantum mechanical properties to simultaneously achieve low-voltage operation and high performance within an area of just a few square nanometers. Their extremely small size would enable more of these 3D transistors to be packed onto a computer chip, resulting in fast, powerful electronics that are also more energy-efficient.“With conventional physics, there is only so far you can go. The work of Yanjie shows that we can do better than that, but we have to use different physics. There are many challenges yet to be overcome for this approach to be commercial in the future, but conceptually, it really is a breakthrough,” says senior author Jesús del Alamo, the Donner Professor of Engineering in the MIT Department of Electrical Engineering and Computer Science (EECS).They are joined on the paper by Ju Li, the Tokyo Electric Power Company Professor in Nuclear Engineering and professor of materials science and engineering at MIT; EECS graduate student Hao Tang; MIT postdoc Baoming Wang; and professors Marco Pala and David Esseni of the University of Udine in Italy. The research appears today in Nature Electronics.Surpassing siliconIn electronic devices, silicon transistors often operate as switches. Applying a voltage to the transistor causes electrons to move over an energy barrier from one side to the other, switching the transistor from “off” to “on.” By switching, transistors represent binary digits to perform computation.A transistor’s switching slope reflects the sharpness of the “off” to “on” transition. The steeper the slope, the less voltage is needed to turn on the transistor and the greater its energy efficiency.But because of how electrons move across an energy barrier, Boltzmann tyranny requires a certain minimum voltage to switch the transistor at room temperature.To overcome the physical limit of silicon, the MIT researchers used a different set of semiconductor materials — gallium antimonide and indium arsenide — and designed their devices to leverage a unique phenomenon in quantum mechanics called quantum tunneling.Quantum tunneling is the ability of electrons to penetrate barriers. The researchers fabricated tunneling transistors, which leverage this property to encourage electrons to push through the energy barrier rather than going over it.“Now, you can turn the device on and off very easily,” Shao says.But while tunneling transistors can enable sharp switching slopes, they typically operate with low current, which hampers the performance of an electronic device. Higher current is necessary to create powerful transistor switches for demanding applications.Fine-grained fabricationUsing tools at MIT.nano, MIT’s state-of-the-art facility for nanoscale research, the engineers were able to carefully control the 3D geometry of their transistors, creating vertical nanowire heterostructures with a diameter of only 6 nanometers. They believe these are the smallest 3D transistors reported to date.Such precise engineering enabled them to achieve a sharp switching slope and high current simultaneously. This is possible because of a phenomenon called quantum confinement.Quantum confinement occurs when an electron is confined to a space that is so small that it can’t move around. When this happens, the effective mass of the electron and the properties of the material change, enabling stronger tunneling of the electron through a barrier.Because the transistors are so small, the researchers can engineer a very strong quantum confinement effect while also fabricating an extremely thin barrier.“We have a lot of flexibility to design these material heterostructures so we can achieve a very thin tunneling barrier, which enables us to get very high current,” Shao says.Precisely fabricating devices that were small enough to accomplish this was a major challenge.“We are really into single-nanometer dimensions with this work. Very few groups in the world can make good transistors in that range. Yanjie is extraordinarily capable to craft such well-functioning transistors that are so extremely small,” says del Alamo.When the researchers tested their devices, the sharpness of the switching slope was below the fundamental limit that can be achieved with conventional silicon transistors. Their devices also performed about 20 times better than similar tunneling transistors.“This is the first time we have been able to achieve such sharp switching steepness with this design,” Shao adds.The researchers are now striving to enhance their fabrication methods to make transistors more uniform across an entire chip. With such small devices, even a 1-nanometer variance can change the behavior of the electrons and affect device operation. They are also exploring vertical fin-shaped structures, in addition to vertical nanowire transistors, which could potentially improve the uniformity of devices on a chip.“This work definitively steps in the right direction, significantly improving the broken-gap tunnel field effect transistor (TFET) performance. It demonstrates steep-slope together with a record drive-current. It highlights the importance of small dimensions, extreme confinement, and low-defectivity materials and interfaces in the fabricated broken-gap TFET. These features have been realized through a well-mastered and nanometer-size-controlled process,” says Aryan Afzalian, a principal member of the technical staff at the nanoelectronics research organization imec, who was not involved with this work.This research is funded, in part, by Intel Corporation. More

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      in Energy

      Affordable high-tech windows for comfort and energy savings

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      Imagine if the windows of your home didn’t transmit heat. They’d keep the heat indoors in winter and outdoors on a hot summer’s day. Your heating and cooling bills would go down; your energy consumption and carbon emissions would drop; and you’d still be comfortable all year ’round.AeroShield, a startup spun out of MIT, is poised to start manufacturing such windows. Building operations make up 36 percent of global carbon dioxide emissions, and today’s windows are a major contributor to energy inefficiency in buildings. To improve building efficiency, AeroShield has developed a window technology that promises to reduce heat loss by up to 65 percent, significantly reducing energy use and carbon emissions in buildings, and the company just announced the opening of a new facility to manufacture its breakthrough energy-efficient windows.“Our mission is to decarbonize the built environment,” says Elise Strobach SM ’17, PhD ’20, co-founder and CEO of AeroShield. “The availability of affordable, thermally insulating windows will help us achieve that goal while also reducing homeowner’s heating and cooling bills.” According to the U.S. Department of Energy, for most homeowners, 30 percent of that bill results from window inefficiencies.Technology development at MITResearch on AeroShield’s window technology began a decade ago in the MIT lab of Evelyn Wang, Ford Professor of Engineering, now on leave to serve as director of the Advanced Research Projects Agency-Energy (ARPA-E). In late 2014, the MIT team received funding from ARPA-E, and other sponsors followed, including the MIT Energy Initiative through the MIT Tata Center for Technology and Design in 2016.The work focused on aerogels, remarkable materials that are ultra-porous, lighter than a marshmallow, strong enough to support a brick, and an unparalleled barrier to heat flow. Aerogels were invented in the 1930s and used by NASA and others as thermal insulation. The team at MIT saw the potential for incorporating aerogel sheets into windows to keep heat from escaping or entering buildings. But there was one problem: Nobody had been able to make aerogels transparent.An aerogel is made of transparent, loosely connected nanoscale silica particles and is 95 percent air. But an aerogel sheet isn’t transparent because light traveling through it gets scattered by the silica particles.After five years of theoretical and experimental work, the MIT team determined that the key to transparency was having the silica particles both small and uniform in size. This allows light to pass directly through, so the aerogel becomes transparent. Indeed, as long as the particle size is small and uniform, increasing the thickness of an aerogel sheet to achieve greater thermal insulation won’t make it less clear.Teams in the MIT lab looked at various applications for their super-insulating, transparent aerogels. Some focused on improving solar thermal collectors by making the systems more efficient and less expensive. But to Strobach, increasing the thermal efficiency of windows looked especially promising and potentially significant as a means of reducing climate change.The researchers determined that aerogel sheets could be inserted into the gap in double-pane windows, making them more than twice as insulating. The windows could then be manufactured on existing production lines with minor changes, and the resulting windows would be affordable and as wide-ranging in style as the window options available today. Best of all, once purchased and installed, the windows would reduce electricity bills, energy use, and carbon emissions.The impact on energy use in buildings could be considerable. “If we only consider winter, windows in the United States lose enough energy to power over 50 million homes,” says Strobach. “That wasted energy generates about 350 million tons of carbon dioxide — more than is emitted by 76 million cars.” Super-insulating windows could help home and building owners reduce carbon dioxide emissions by gigatons while saving billions in heating and cooling costs.The AeroShield storyIn 2019, Strobach and her MIT colleagues — Aaron Baskerville-Bridges MBA ’20, SM ’20 and Kyle Wilke PhD ’19 — co-founded AeroShield to further develop and commercialize their aerogel-based technology for windows and other applications. And in the subsequent five years, their hard work has attracted attention, recently leading to two major accomplishments.In spring 2024, the company announced the opening of its new pilot manufacturing facility in Waltham, Massachusetts, where the team will be producing, testing, and certifying their first full-size windows and patio doors for initial product launch. The 12,000 square foot facility will significantly expand the company’s capabilities, with cutting-edge aerogel R&D labs, manufacturing equipment, assembly lines, and testing equipment. Says Strobach, “Our pilot facility will supply window and door manufacturers as we launch our first products and will also serve as our R&D headquarters as we develop the next generation of energy-efficient products using transparent aerogels.”Also in spring 2024, AeroShield received a $14.5 million award from ARPA-E’s “Seeding Critical Advances for Leading Energy technologies with Untapped Potential” (SCALEUP) program, which provides new funding to previous ARPA-E awardees that have “demonstrated a viable path to market.” That funding will enable the company to expand its production capacity to tens of thousands, or even hundreds of thousands, of units per year.Strobach also cites two less-obvious benefits of the SCALEUP award.First, the funding is enabling the company to move more quickly on the scale-up phase of their technology development. “We know from our fundamental studies and lab experiments that we can make large-area aerogel sheets that could go in an entry or patio door,” says Elise. “The SCALEUP award allows us to go straight for that vision. We don’t have to do all the incremental sizes of aerogels to prove that we can make a big one. The award provides capital for us to buy the big equipment to make the big aerogel.”Second, the SCALEUP award confirms the viability of the company to other potential investors and collaborators. Indeed, AeroShield recently announced $5 million of additional funding from existing investors Massachusetts Clean Energy Center and MassVentures, as well as new investor MassMutual Ventures. Strobach notes that the company now has investor, engineering, and customer partners.She stresses the importance of partners in achieving AeroShield’s mission. “We know that what we’ve got from a fundamental perspective can change the industry,” she says. “Now we want to go out and do it. With the right partners and at the right pace, we may actually be able to increase the energy efficiency of our buildings early enough to help make a real dent in climate change.” More