Plasma Science and Fusion Center

Subterms

    More stories

    • 88 Shares169 Views

      in Energy

      More durable metals for fusion power reactors

      by

      For many decades, nuclear fusion power has been viewed as the ultimate energy source. A fusion power plant could generate carbon-free energy at a scale needed to address climate change. And it could be fueled by deuterium recovered from an essentially endless source — seawater.Decades of work and billions of dollars in research funding have yielded many advances, but challenges remain. To Ju Li, the TEPCO Professor in Nuclear Science and Engineering and a professor of materials science and engineering at MIT, there are still two big challenges. The first is to build a fusion power plant that generates more energy than is put into it; in other words, it produces a net output of power. Researchers worldwide are making progress toward meeting that goal.The second challenge that Li cites sounds straightforward: “How do we get the heat out?” But understanding the problem and finding a solution are both far from obvious.Research in the MIT Energy Initiative (MITEI) includes development and testing of advanced materials that may help address those challenges, as well as many other challenges of the energy transition. MITEI has multiple corporate members that have been supporting MIT’s efforts to advance technologies required to harness fusion energy.The problem: An abundance of helium, a destructive forceKey to a fusion reactor is a superheated plasma — an ionized gas — that’s reacting inside a vacuum vessel. As light atoms in the plasma combine to form heavier ones, they release fast neutrons with high kinetic energy that shoot through the surrounding vacuum vessel into a coolant. During this process, those fast neutrons gradually lose their energy by causing radiation damage and generating heat. The heat that’s transferred to the coolant is eventually used to raise steam that drives an electricity-generating turbine.The problem is finding a material for the vacuum vessel that remains strong enough to keep the reacting plasma and the coolant apart, while allowing the fast neutrons to pass through to the coolant. If one considers only the damage due to neutrons knocking atoms out of position in the metal structure, the vacuum vessel should last a full decade. However, depending on what materials are used in the fabrication of the vacuum vessel, some projections indicate that the vacuum vessel will last only six to 12 months. Why is that? Today’s nuclear fission reactors also generate neutrons, and those reactors last far longer than a year.The difference is that fusion neutrons possess much higher kinetic energy than fission neutrons do, and as they penetrate the vacuum vessel walls, some of them interact with the nuclei of atoms in the structural material, giving off particles that rapidly turn into helium atoms. The result is hundreds of times more helium atoms than are present in a fission reactor. Those helium atoms look for somewhere to land — a place with low “embedding energy,” a measure that indicates how much energy it takes for a helium atom to be absorbed. As Li explains, “The helium atoms like to go to places with low helium embedding energy.” And in the metals used in fusion vacuum vessels, there are places with relatively low helium embedding energy — namely, naturally occurring openings called grain boundaries.Metals are made up of individual grains inside which atoms are lined up in an orderly fashion. Where the grains come together there are gaps where the atoms don’t line up as well. That open space has relatively low helium embedding energy, so the helium atoms congregate there. Worse still, helium atoms have a repellent interaction with other atoms, so the helium atoms basically push open the grain boundary. Over time, the opening grows into a continuous crack, and the vacuum vessel breaks.That congregation of helium atoms explains why the structure fails much sooner than expected based just on the number of helium atoms that are present. Li offers an analogy to illustrate. “Babylon is a city of a million people. But the claim is that 100 bad persons can destroy the whole city — if all those bad persons work at the city hall.” The solution? Give those bad persons other, more attractive places to go, ideally in their own villages.To Li, the problem and possible solution are the same in a fusion reactor. If many helium atoms go to the grain boundary at once, they can destroy the metal wall. The solution? Add a small amount of a material that has a helium embedding energy even lower than that of the grain boundary. And over the past two years, Li and his team have demonstrated — both theoretically and experimentally — that their diversionary tactic works. By adding nanoscale particles of a carefully selected second material to the metal wall, they’ve found they can keep the helium atoms that form from congregating in the structurally vulnerable grain boundaries in the metal.Looking for helium-absorbing compoundsTo test their idea, So Yeon Kim ScD ’23 of the Department of Materials Science and Engineering and Haowei Xu PhD ’23 of the Department of Nuclear Science and Engineering acquired a sample composed of two materials, or “phases,” one with a lower helium embedding energy than the other. They and their collaborators then implanted helium ions into the sample at a temperature similar to that in a fusion reactor and watched as bubbles of helium formed. Transmission electron microscope images confirmed that the helium bubbles occurred predominantly in the phase with the lower helium embedding energy. As Li notes, “All the damage is in that phase — evidence that it protected the phase with the higher embedding energy.”Having confirmed their approach, the researchers were ready to search for helium-absorbing compounds that would work well with iron, which is often the principal metal in vacuum vessel walls. “But calculating helium embedding energy for all sorts of different materials would be computationally demanding and expensive,” says Kim. “We wanted to find a metric that is easy to compute and a reliable indicator of helium embedding energy.”They found such a metric: the “atomic-scale free volume,” which is basically the maximum size of the internal vacant space available for helium atoms to potentially settle. “This is just the radius of the largest sphere that can fit into a given crystal structure,” explains Kim. “It is a simple calculation.” Examination of a series of possible helium-absorbing ceramic materials confirmed that atomic free volume correlates well with helium embedding energy. Moreover, many of the ceramics they investigated have higher free volume, thus lower embedding energy, than the grain boundaries do.However, in order to identify options for the nuclear fusion application, the screening needed to include some other factors. For example, in addition to the atomic free volume, a good second phase must be mechanically robust (able to sustain a load); it must not get very radioactive with neutron exposure; and it must be compatible — but not too cozy — with the surrounding metal, so it disperses well but does not dissolve into the metal. “We want to disperse the ceramic phase uniformly in the bulk metal to ensure that all grain boundary regions are close to the dispersed ceramic phase so it can provide protection to those regions,” says Li. “The two phases need to coexist, so the ceramic won’t either clump together or totally dissolve in the iron.”Using their analytical tools, Kim and Xu examined about 50,000 compounds and identified 750 potential candidates. Of those, a good option for inclusion in a vacuum vessel wall made mainly of iron was iron silicate.Experimental testingThe researchers were ready to examine samples in the lab. To make the composite material for proof-of-concept demonstrations, Kim and collaborators dispersed nanoscale particles of iron silicate into iron and implanted helium into that composite material. She took X-ray diffraction (XRD) images before and after implanting the helium and also computed the XRD patterns. The ratio between the implanted helium and the dispersed iron silicate was carefully controlled to allow a direct comparison between the experimental and computed XRD patterns. The measured XRD intensity changed with the helium implantation exactly as the calculations had predicted. “That agreement confirms that atomic helium is being stored within the bulk lattice of the iron silicate,” says Kim.To follow up, Kim directly counted the number of helium bubbles in the composite. In iron samples without the iron silicate added, grain boundaries were flanked by many helium bubbles. In contrast, in the iron samples with the iron silicate ceramic phase added, helium bubbles were spread throughout the material, with many fewer occurring along the grain boundaries. Thus, the iron silicate had provided sites with low helium-embedding energy that lured the helium atoms away from the grain boundaries, protecting those vulnerable openings and preventing cracks from opening up and causing the vacuum vessel to fail catastrophically.The researchers conclude that adding just 1 percent (by volume) of iron silicate to the iron walls of the vacuum vessel will cut the number of helium bubbles in half and also reduce their diameter by 20 percent — “and having a lot of small bubbles is OK if they’re not in the grain boundaries,” explains Li.Next stepsThus far, Li and his team have gone from computational studies of the problem and a possible solution to experimental demonstrations that confirm their approach. And they’re well on their way to commercial fabrication of components. “We’ve made powders that are compatible with existing commercial 3D printers and are preloaded with helium-absorbing ceramics,” says Li. The helium-absorbing nanoparticles are well dispersed and should provide sufficient helium uptake to protect the vulnerable grain boundaries in the structural metals of the vessel walls. While Li confirms that there’s more scientific and engineering work to be done, he, along with Alexander O’Brien PhD ’23 of the Department of Nuclear Science and Engineering and Kang Pyo So, a former postdoc in the same department, have already developed a startup company that’s ready to 3D print structural materials that can meet all the challenges faced by the vacuum vessel inside a fusion reactor.This research was supported by Eni S.p.A. through the MIT Energy Initiative. Additional support was provided by a Kwajeong Scholarship; the U.S. Department of Energy (DOE) Laboratory Directed Research and Development program at Idaho National Laboratory; U.S. DOE Lawrence Livermore National Laboratory; and Creative Materials Discovery Program through the National Research Foundation of Korea. More

    • 50 Shares149 Views

      in Energy

      Going Dutch on climate

      by

      When MIT senior Rudiba Laiba saw that stores in the Netherlands eschewed plastic bags to save the planet, her first thought was, “that doesn’t happen in Bangladesh.”Laiba is one of eight MIT students who traveled to the Netherlands in June as part of an MIT Energy Initiative (MITEI)-sponsored trip to experience first-hand the country’s approach to the energy transition. The Netherlands aims to be carbon neutral by 2050, making it one of the top 10 countries leading the charge on climate change, according to U.S. News and World Report.MITEI sponsored the week-long trip to allow undergraduate and graduate students to collaboratively explore clean energy efforts with researchers, corporate leaders, and nongovernmental organizations. The students heard about projects ranging from creating hydrogen pipelines in the North Sea to climate-proofing a fuel-guzzling, asphalt-dense neighborhood.Felipe Abreu from Kissimmee, Florida, a rising second-year student studying materials science and engineering, is working this summer on ways to melt and reuse metal scraps discarded in manufacturing processes. “When MITEI put out this notice about visiting the Netherlands, I wanted to see if there were more advanced approaches to renewable energy that I’d never been exposed to,” Abreu says.Laiba notes that her native Bangladesh has not yet achieved the Netherlands’ nearly universal buy-in to tackling climate change, even though this South Asian country, like the Netherlands, is particularly vulnerable to rising sea levels due to topography and high population density.Laiba, who spent part of her childhood in New York City and lived in Bangladesh from ages 8 to 18, calls Bangladesh “on the front lines of climate change.“Even if I didn’t want to care about climate change, I had to, because I would see the effects of it,” she says.Key playersThe MIT students conducted hands-on exercises on how to switch from traditional energy sources to zero-carbon technologies. “We talked a lot about infrastructure, particularly how to repurpose natural gas infrastructure for hydrogen,” says Antje Danielson, director of education at MITEI, who led the trip with Em Schule, MITEI research and programming assistant. “The students were challenged to grapple with real-world decision-making.”The northern section of the Netherlands is known as the “hydrogen valley” of Europe. At the University of Groningen and Hanze University School of Applied Sciences, also in Groningen, the students heard about how the region profiles itself as a world capital for the energy transition through its push toward a hydrogen-based economy and its state-of-the-art global climate models.Erick Liang, a rising junior from Boston’s Roslindale neighborhood pursuing a dual major in nuclear science and engineering and physics, was intrigued by a massive wind farm in the port city of Eemshaven, one of the group’s first stops in the north of the country. “It was impressive as an engineering challenge, because they must have figured out ways to cheaply and effectively manufacture all these wind turbines,” he says.They visited German energy company RWE, which is generating 15 percent of Eemshaven’s electricity from biomass, replacing coal.Laiba, who is majoring in molecular biology and electrical engineering and computer science with a minor in business management, was intrigued by a presentation on biofuels. “It piqued my interest to see if they would use biomass on a large scale” because of the challenges and unpredictability associated with it as a fuel source.In Paddepoel, the students toured the first of several neighborhoods that once lacked greenery and used fossil fuel-based heating systems and now aim to generate more energy than they consume.“The students got to see what the size of the district heating pipes would be, and how they go through people’s gardens into the houses. We talked about the physical impact on the neighborhood of installing these pipes, as well as the potential social and political implications connected to a really difficult transition like this,” Danielson says.Going greenGreen hydrogen promises to be a key player in the energy transition, and Netherlands officials say they have committed to the new infrastructure and business models needed to move ahead with hydrogen as a fuel source.The students explored how green hydrogen differs from fossil fuel-generated hydrogen. They saw how Dutch companies grappled with siting hydrogen production facilities and handling hydrogen as a gas, which, unlike natural gas, does not yet have a detectable artificial odor. The students heard from energy network operator Gasunie about the science and engineering behind repurposing existing natural gas pipelines for a hydrogen network in the North Sea, and were challenged to solve the puzzle of combining hydrogen production with offshore wind energy. In the port of Rotterdam, they saw how the startup Battolyser Systems — which is working with Delft University of Technology on an electrolysis device that splits water into hydrogen and oxygen and doubles as a battery — is transitioning from lab bench to market.Laiba was impressed by how much capital was going into high-risk ventures and startups, “not only because they’re trying to make something revolutionary, but also because society needs to accept and use” their products.Abreu says that at Battolyser Systems, “I saw people my age on the forefront of green hydrogen, trying to make a difference.”The students visited the Global Center on Adaptation’s carbon-neutral floating offices and learned how this international organization supports climate adaptation actions around the world and the practice of mitigation.Also in Rotterdam, international marine contractor Van Oord took students to view a ship that installs wind turbines and explained how their new technology reduces the sound shockwave impact of the installations on marine life.At the Port of Rotterdam, the students heard about the challenges faced by Europe’s largest port in terms of global shipping and choosing the fuels of the future. The speaker tasked the MIT students with coming up with a plan to transition the privately owned, owner-inhabited barges that ply the region’s inland waterways to a zero-carbon system.“The Port Authority uses this exercise to illustrate the enormous complexity faced by companies in the energy transition,” Danielson says. “The fact that our students performed really well on the spot shows that we are doing something right at MIT.”Defining a path forwardLiang, Abreu, and Laiba were struck by how the Netherlands has come together as a country over climate change. “In the U.S., a lot of people disagree with the concept of climate change as a whole,” Liang says. “But in the Netherlands, everyone is on the same page that this is an issue that we should be working toward. They’re capable of seeing a path forward and trying to take action whenever possible.”Liang, a member of the MIT Solar Electric Vehicle Team, is doing undergraduate research sponsored by MITEI this summer, working to accelerate fusion manufacturing and development at the MIT Plasma Science and Fusion Center. He’s improving 3D printing processes to manufacture components that can accommodate the high temperatures and small space within a tokamak reactor, which uses magnetic fields to confine plasma and produce controlled thermonuclear fusion.“I personally would like to try finding a new solution” to achieving carbon neutrality, he says. That solution, to Liang, is fusion energy, with some entities hoping to demonstrate net energy gain through fusion in the next five years.Laiba is a researcher with the MIT Office of Sustainability, looking at ways to quantify and reduce the level of MIT’s Scope 3 greenhouse gas emissions. Scope 3 emissions are tied to the purchase of goods that use fossil fuels in their manufacture. She says, ​“Whatever I decide to do in the future will involve making a more sustainable future. And to me, renewable energy is the driving force behind that.”In the Netherlands, she says, “what we learned through the entire trip was that renewable energy powers the country to a large amount. Things I could see tangibly was Starbucks having paper cups even for our iced drinks, which I think would flop very hard in the U.S. I don’t think society’s ready for that yet.”Abreu says, “In America, sustainability has always been in the back seat while other things take the forefront. So going to a country where everybody you talk to has a stake (in sustainability) and actually cares, and they’re all pushing together for this common goal, it was inspiring. It gave me hope.” More

    • 138 Shares119 Views

      in Energy

      Nuno Loureiro named director of MIT’s Plasma Science and Fusion Center

      by

      Nuno Loureiro, professor of nuclear science and engineering and of physics, has been appointed the new director of the MIT Plasma Science and Fusion Center, effective May 1.Loureiro is taking the helm of one of MIT’s largest labs: more than 250 full-time researchers, staff members, and students work and study in seven buildings with 250,000 square feet of lab space. A theoretical physicist and fusion scientist, Loureiro joined MIT as a faculty member in 2016, and was appointed deputy director of the Plasma Science and Fusion Center (PSFC) in 2022. Loureiro succeeds Dennis Whyte, who stepped down at the end of 2023 to return to teaching and research.Stepping into his new role as director, Loureiro says, “The PSFC has an impressive tradition of discovery and leadership in plasma and fusion science and engineering. Becoming director of the PSFC is an incredible opportunity to shape the future of these fields. We have a world-class team, and it’s an honor to be chosen as its leader.”Loureiro’s own research ranges widely. He is recognized for advancing the understanding of multiple aspects of plasma behavior, particularly turbulence and the physics underpinning solar flares and other astronomical phenomena. In the fusion domain, his work enables the design of fusion devices that can more efficiently control and harness the energy of fusing plasmas, bringing the dream of clean, near-limitless fusion power that much closer. Plasma physics is foundational to advancing fusion science, a fact Loureiro has embraced and that is relevant as he considers the direction of the PSFC’s multidisciplinary research. “But plasma physics is only one aspect of our focus. Building a scientific agenda that continues and expands on the PSFC’s history of innovation in all aspects of fusion science and engineering is vital, and a key facet of that work is facilitating our researchers’ efforts to produce the breakthroughs that are necessary for the realization of fusion energy.”As the climate crisis accelerates, fusion power continues to grow in appeal: It produces no carbon emissions, its fuel is plentiful, and dangerous “meltdowns” are impossible. The sooner that fusion power is commercially available, the greater impact it can have on reducing greenhouse gas emissions and meeting global climate goals. While technical challenges remain, “the PSFC is well poised to meet them, and continue to show leadership. We are a mission-driven lab, and our students and staff are incredibly motivated,” Loureiro comments.“As MIT continues to lead the way toward the delivery of clean fusion power onto the grid, I have no doubt that Nuno is the right person to step into this key position at this critical time,” says Maria T. Zuber, MIT’s presidential advisor for science and technology policy. “I look forward to the steady advance of plasma physics and fusion science at MIT under Nuno’s leadership.”Over the last decade, there have been massive leaps forward in the field of fusion energy, driven in part by innovations like high-temperature superconducting magnets developed at the PSFC. Further progress is guaranteed: Loureiro believes that “The next few years are certain to be an exciting time for us, and for fusion as a whole. It’s the dawn of a new era with burning plasma experiments” — a reference to the collaboration between the PSFC and Commonwealth Fusion Systems, a startup company spun out of the PSFC, to build SPARC, a fusion device that is slated to turn on in 2026 and produce a burning plasma that yields more energy than it consumes. “It’s going to be a watershed moment,” says Loureiro.He continues, “In addition, we have strong connections to inertial confinement fusion experiments, including those at Lawrence Livermore National Lab, and we’re looking forward to expanding our research into stellarators, which are another kind of magnetic fusion device.” Over recent years, the PSFC has significantly increased its collaboration with industrial partners such Eni, IBM, and others. Loureiro sees great value in this: “These collaborations are mutually beneficial: they allow us to grow our research portfolio while advancing companies’ R&D efforts. It’s very dynamic and exciting.”Loureiro’s directorship begins as the PSFC is launching key tech development projects like LIBRA, a “blanket” of molten salt that can be wrapped around fusion vessels and perform double duty as a neutron energy absorber and a breeder for tritium (the fuel for fusion). Researchers at the PSFC have also developed a way to rapidly test the durability of materials being considered for use in a fusion power plant environment, and are now creating an experiment that will utilize a powerful particle accelerator called a gyrotron to irradiate candidate materials.Interest in fusion is at an all-time high; the demand for researchers and engineers, particularly in the nascent commercial fusion industry, is reflected by the record number of graduate students that are studying at the PSFC — more than 90 across seven affiliated MIT departments. The PSFC’s classrooms are full, and Loureiro notes a palpable sense of excitement. “Students are our greatest strength,” says Loureiro. “They come here to do world-class research but also to grow as individuals, and I want to give them a great place to do that. Supporting those experiences, making sure they can be as successful as possible is one of my top priorities.” Loureiro plans to continue teaching and advising students after his appointment begins.MIT President Sally Kornbluth’s recently announced Climate Project is a clarion call for Loureiro: “It’s not hyperbole to say MIT is where you go to find solutions to humanity’s biggest problems,” he says. “Fusion is a hard problem, but it can be solved with resolve and ingenuity — characteristics that define MIT. Fusion energy will change the course of human history. It’s both humbling and exciting to be leading a research center that will play a key role in enabling that change.”  More

    • 175 Shares159 Views

      in Energy

      Future nuclear power reactors could rely on molten salts — but what about corrosion?

      by

      Most discussions of how to avert climate change focus on solar and wind generation as key to the transition to a future carbon-free power system. But Michael Short, the Class of ’42 Associate Professor of Nuclear Science and Engineering at MIT and associate director of the MIT Plasma Science and Fusion Center (PSFC), is impatient with such talk. “We can say we should have only wind and solar someday. But we don’t have the luxury of ‘someday’ anymore, so we can’t ignore other helpful ways to combat climate change,” he says. “To me, it’s an ‘all-hands-on-deck’ thing. Solar and wind are clearly a big part of the solution. But I think that nuclear power also has a critical role to play.”

      For decades, researchers have been working on designs for both fission and fusion nuclear reactors using molten salts as fuels or coolants. While those designs promise significant safety and performance advantages, there’s a catch: Molten salt and the impurities within it often corrode metals, ultimately causing them to crack, weaken, and fail. Inside a reactor, key metal components will be exposed not only to molten salt but also simultaneously to radiation, which generally has a detrimental effect on materials, making them more brittle and prone to failure. Will irradiation make metal components inside a molten salt-cooled nuclear reactor corrode even more quickly?

      Short and Weiyue Zhou PhD ’21, a postdoc in the PSFC, have been investigating that question for eight years. Their recent experimental findings show that certain alloys will corrode more slowly when they’re irradiated — and identifying them among all the available commercial alloys can be straightforward.

      The first challenge — building a test facility

      When Short and Zhou began investigating the effect of radiation on corrosion, practically no reliable facilities existed to look at the two effects at once. The standard approach was to examine such mechanisms in sequence: first corrode, then irradiate, then examine the impact on the material. That approach greatly simplifies the task for the researchers, but with a major trade-off. “In a reactor, everything is going to be happening at the same time,” says Short. “If you separate the two processes, you’re not simulating a reactor; you’re doing some other experiment that’s not as relevant.”

      So, Short and Zhou took on the challenge of designing and building an experimental setup that could do both at once. Short credits a team at the University of Michigan for paving the way by designing a device that could accomplish that feat in water, rather than molten salts. Even so, Zhou notes, it took them three years to come up with a device that would work with molten salts. Both researchers recall failure after failure, but the persistent Zhou ultimately tried a totally new design, and it worked. Short adds that it also took them three years to precisely replicate the salt mixture used by industry — another factor critical to getting a meaningful result. The hardest part was achieving and ensuring that the purity was correct by removing critical impurities such as moisture, oxygen, and certain other metals.

      As they were developing and testing their setup, Short and Zhou obtained initial results showing that proton irradiation did not always accelerate corrosion but sometimes actually decelerated it. They and others had hypothesized that possibility, but even so, they were surprised. “We thought we must be doing something wrong,” recalls Short. “Maybe we mixed up the samples or something.” But they subsequently made similar observations for a variety of conditions, increasing their confidence that their initial observations were not outliers.

      The successful setup

      Central to their approach is the use of accelerated protons to mimic the impact of the neutrons inside a nuclear reactor. Generating neutrons would be both impractical and prohibitively expensive, and the neutrons would make everything highly radioactive, posing health risks and requiring very long times for an irradiated sample to cool down enough to be examined. Using protons would enable Short and Zhou to examine radiation-altered corrosion both rapidly and safely.

      Key to their experimental setup is a test chamber that they attach to a proton accelerator. To prepare the test chamber for an experiment, they place inside it a thin disc of the metal alloy being tested on top of a a pellet of salt. During the test, the entire foil disc is exposed to a bath of molten salt. At the same time, a beam of protons bombards the sample from the side opposite the salt pellet, but the proton beam is restricted to a circle in the middle of the foil sample. “No one can argue with our results then,” says Short. “In a single experiment, the whole sample is subjected to corrosion, and only a circle in the center of the sample is simultaneously irradiated by protons. We can see the curvature of the proton beam outline in our results, so we know which region is which.”

      The results with that arrangement were unchanged from the initial results. They confirmed the researchers’ preliminary findings, supporting their controversial hypothesis that rather than accelerating corrosion, radiation would actually decelerate corrosion in some materials under some conditions. Fortunately, they just happen to be the same conditions that will be experienced by metals in molten salt-cooled reactors.

      Why is that outcome controversial? A closeup look at the corrosion process will explain. When salt corrodes metal, the salt finds atomic-level openings in the solid, seeps in, and dissolves salt-soluble atoms, pulling them out and leaving a gap in the material — a spot where the material is now weak. “Radiation adds energy to atoms, causing them to be ballistically knocked out of their positions and move very fast,” explains Short. So, it makes sense that irradiating a material would cause atoms to move into the salt more quickly, increasing the rate of corrosion. Yet in some of their tests, the researchers found the opposite to be true.

      Experiments with “model” alloys

      The researchers’ first experiments in their novel setup involved “model” alloys consisting of nickel and chromium, a simple combination that would give them a first look at the corrosion process in action. In addition, they added europium fluoride to the salt, a compound known to speed up corrosion. In our everyday world, we often think of corrosion as taking years or decades, but in the more extreme conditions of a molten salt reactor it can noticeably occur in just hours. The researchers used the europium fluoride to speed up corrosion even more without changing the corrosion process. This allowed for more rapid determination of which materials, under which conditions, experienced more or less corrosion with simultaneous proton irradiation.

      The use of protons to emulate neutron damage to materials meant that the experimental setup had to be carefully designed and the operating conditions carefully selected and controlled. Protons are hydrogen atoms with an electrical charge, and under some conditions the hydrogen could chemically react with atoms in the sample foil, altering the corrosion response, or with ions in the salt, making the salt more corrosive. Therefore, the proton beam had to penetrate the foil sample but then stop in the salt as soon as possible. Under these conditions, the researchers found they could deliver a relatively uniform dose of radiation inside the foil layer while also minimizing chemical reactions in both the foil and the salt.

      Tests showed that a proton beam accelerated to 3 million electron-volts combined with a foil sample between 25 and 30 microns thick would work well for their nickel-chromium alloys. The temperature and duration of the exposure could be adjusted based on the corrosion susceptibility of the specific materials being tested.

      Optical images of samples examined after tests with the model alloys showed a clear boundary between the area that was exposed only to the molten salt and the area that was also exposed to the proton beam. Electron microscope images focusing on that boundary showed that the area that had been exposed only to the molten salt included dark patches where the molten salt had penetrated all the way through the foil, while the area that had also been exposed to the proton beam showed almost no such dark patches.

      To confirm that the dark patches were due to corrosion, the researchers cut through the foil sample to create cross sections. In them, they could see tunnels that the salt had dug into the sample. “For regions not under radiation, we see that the salt tunnels link the one side of the sample to the other side,” says Zhou. “For regions under radiation, we see that the salt tunnels stop more or less halfway and rarely reach the other side. So we verified that they didn’t penetrate the whole way.”

      The results “exceeded our wildest expectations,” says Short. “In every test we ran, the application of radiation slowed corrosion by a factor of two to three times.”

      More experiments, more insights

      In subsequent tests, the researchers more closely replicated commercially available molten salt by omitting the additive (europium fluoride) that they had used to speed up corrosion, and they tweaked the temperature for even more realistic conditions. “In carefully monitored tests, we found that by raising the temperature by 100 degrees Celsius, we could get corrosion to happen about 1,000 times faster than it would in a reactor,” says Short.

      Images from experiments with the nickel-chromium alloy plus the molten salt without the corrosive additive yielded further insights. Electron microscope images of the side of the foil sample facing the molten salt showed that in sections only exposed to the molten salt, the corrosion is clearly focused on the weakest part of the structure — the boundaries between the grains in the metal. In sections that were exposed to both the molten salt and the proton beam, the corrosion isn’t limited to the grain boundaries but is more spread out over the surface. Experimental results showed that these cracks are shallower and less likely to cause a key component to break.

      Short explains the observations. Metals are made up of individual grains inside which atoms are lined up in an orderly fashion. Where the grains come together there are areas — called grain boundaries — where the atoms don’t line up as well. In the corrosion-only images, dark lines track the grain boundaries. Molten salt has seeped into the grain boundaries and pulled out salt-soluble atoms. In the corrosion-plus-irradiation images, the damage is more general. It’s not only the grain boundaries that get attacked but also regions within the grains.

      So, when the material is irradiated, the molten salt also removes material from within the grains. Over time, more material comes out of the grains themselves than from the spaces between them. The removal isn’t focused on the grain boundaries; it’s spread out over the whole surface. As a result, any cracks that form are shallower and more spread out, and the material is less likely to fail.

      Testing commercial alloys

      The experiments described thus far involved model alloys — simple combinations of elements that are good for studying science but would never be used in a reactor. In the next series of experiments, the researchers focused on three commercially available alloys that are composed of nickel, chromium, iron, molybdenum, and other elements in various combinations.

      Results from the experiments with the commercial alloys showed a consistent pattern — one that confirmed an idea that the researchers had going in: the higher the concentration of salt-soluble elements in the alloy, the worse the radiation-induced corrosion damage. Radiation will increase the rate at which salt-soluble atoms such as chromium leave the grain boundaries, hastening the corrosion process. However, if there are more not-soluble elements such as nickel present, those atoms will go into the salt more slowly. Over time, they’ll accumulate at the grain boundary and form a protective coating that blocks the grain boundary — a “self-healing mechanism that decelerates the rate of corrosion,” say the researchers.

      Thus, if an alloy consists mostly of atoms that don’t dissolve in molten salt, irradiation will cause them to form a protective coating that slows the corrosion process. But if an alloy consists mostly of atoms that dissolve in molten salt, irradiation will make them dissolve faster, speeding up corrosion. As Short summarizes, “In terms of corrosion, irradiation makes a good alloy better and a bad alloy worse.”

      Real-world relevance plus practical guidelines

      Short and Zhou find their results encouraging. In a nuclear reactor made of “good” alloys, the slowdown in corrosion will probably be even more pronounced than what they observed in their proton-based experiments because the neutrons that inflict the damage won’t chemically react with the salt to make it more corrosive. As a result, reactor designers could push the envelope more in their operating conditions, allowing them to get more power out of the same nuclear plant without compromising on safety.

      However, the researchers stress that there’s much work to be done. Many more projects are needed to explore and understand the exact corrosion mechanism in specific alloys under different irradiation conditions. In addition, their findings need to be replicated by groups at other institutions using their own facilities. “What needs to happen now is for other labs to build their own facilities and start verifying whether they get the same results as we did,” says Short. To that end, Short and Zhou have made the details of their experimental setup and all of their data freely available online. “We’ve also been actively communicating with researchers at other institutions who have contacted us,” adds Zhou. “When they’re planning to visit, we offer to show them demonstration experiments while they’re here.”

      But already their findings provide practical guidance for other researchers and equipment designers. For example, the standard way to quantify corrosion damage is by “mass loss,” a measure of how much weight the material has lost. But Short and Zhou consider mass loss a flawed measure of corrosion in molten salts. “If you’re a nuclear plant operator, you usually care whether your structural components are going to break,” says Short. “Our experiments show that radiation can change how deep the cracks are, when all other things are held constant. The deeper the cracks, the more likely a structural component is to break, leading to a reactor failure.”

      In addition, the researchers offer a simple rule for identifying good metal alloys for structural components in molten salt reactors. Manufacturers provide extensive lists of available alloys with different compositions, microstructures, and additives. Faced with a list of options for critical structures, the designer of a new nuclear fission or fusion reactor can simply examine the composition of each alloy being offered. The one with the highest content of corrosion-resistant elements such as nickel will be the best choice. Inside a nuclear reactor, that alloy should respond to a bombardment of radiation not by corroding more rapidly but by forming a protective layer that helps block the corrosion process. “That may seem like a trivial result, but the exact threshold where radiation decelerates corrosion depends on the salt chemistry, the density of neutrons in the reactor, their energies, and a few other factors,” says Short. “Therefore, the complete guidelines are a bit more complicated. But they’re presented in a straightforward way that users can understand and utilize to make a good choice for the molten salt–based reactor they’re designing.”

      This research was funded, in part, by Eni S.p.A. through the MIT Plasma Science and Fusion Center’s Laboratory for Innovative Fusion Technologies. Earlier work was funded, in part, by the Transatomic Power Corporation and by the U.S. Department of Energy Nuclear Energy University Program. Equipment development and testing was supported by the Transatomic Power Corporation.

      This article appears in the Winter 2024 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

    • 113 Shares119 Views

      in Energy

      Tests show high-temperature superconducting magnets are ready for fusion

      by

      In the predawn hours of Sept. 5, 2021, engineers achieved a major milestone in the labs of MIT’s Plasma Science and Fusion Center (PSFC), when a new type of magnet, made from high-temperature superconducting material, achieved a world-record magnetic field strength of 20 tesla for a large-scale magnet. That’s the intensity needed to build a fusion power plant that is expected to produce a net output of power and potentially usher in an era of virtually limitless power production.

      The test was immediately declared a success, having met all the criteria established for the design of the new fusion device, dubbed SPARC, for which the magnets are the key enabling technology. Champagne corks popped as the weary team of experimenters, who had labored long and hard to make the achievement possible, celebrated their accomplishment.

      But that was far from the end of the process. Over the ensuing months, the team tore apart and inspected the components of the magnet, pored over and analyzed the data from hundreds of instruments that recorded details of the tests, and performed two additional test runs on the same magnet, ultimately pushing it to its breaking point in order to learn the details of any possible failure modes.

      All of this work has now culminated in a detailed report by researchers at PSFC and MIT spinout company Commonwealth Fusion Systems (CFS), published in a collection of six peer-reviewed papers in a special edition of the March issue of IEEE Transactions on Applied Superconductivity. Together, the papers describe the design and fabrication of the magnet and the diagnostic equipment needed to evaluate its performance, as well as the lessons learned from the process. Overall, the team found, the predictions and computer modeling were spot-on, verifying that the magnet’s unique design elements could serve as the foundation for a fusion power plant.

      Enabling practical fusion power

      The successful test of the magnet, says Hitachi America Professor of Engineering Dennis Whyte, who recently stepped down as director of the PSFC, was “the most important thing, in my opinion, in the last 30 years of fusion research.”

      Before the Sept. 5 demonstration, the best-available superconducting magnets were powerful enough to potentially achieve fusion energy — but only at sizes and costs that could never be practical or economically viable. Then, when the tests showed the practicality of such a strong magnet at a greatly reduced size, “overnight, it basically changed the cost per watt of a fusion reactor by a factor of almost 40 in one day,” Whyte says.

      “Now fusion has a chance,” Whyte adds. Tokamaks, the most widely used design for experimental fusion devices, “have a chance, in my opinion, of being economical because you’ve got a quantum change in your ability, with the known confinement physics rules, about being able to greatly reduce the size and the cost of objects that would make fusion possible.”

      The comprehensive data and analysis from the PSFC’s magnet test, as detailed in the six new papers, has demonstrated that plans for a new generation of fusion devices — the one designed by MIT and CFS, as well as similar designs by other commercial fusion companies — are built on a solid foundation in science.

      The superconducting breakthrough

      Fusion, the process of combining light atoms to form heavier ones, powers the sun and stars, but harnessing that process on Earth has proved to be a daunting challenge, with decades of hard work and many billions of dollars spent on experimental devices. The long-sought, but never yet achieved, goal is to build a fusion power plant that produces more energy than it consumes. Such a power plant could produce electricity without emitting greenhouse gases during operation, and generating very little radioactive waste. Fusion’s fuel, a form of hydrogen that can be derived from seawater, is virtually limitless.

      But to make it work requires compressing the fuel at extraordinarily high temperatures and pressures, and since no known material could withstand such temperatures, the fuel must be held in place by extremely powerful magnetic fields. Producing such strong fields requires superconducting magnets, but all previous fusion magnets have been made with a superconducting material that requires frigid temperatures of about 4 degrees above absolute zero (4 kelvins, or -270 degrees Celsius). In the last few years, a newer material nicknamed REBCO, for rare-earth barium copper oxide, was added to fusion magnets, and allows them to operate at 20 kelvins, a temperature that despite being only 16 kelvins warmer, brings significant advantages in terms of material properties and practical engineering.

      Taking advantage of this new higher-temperature superconducting material was not just a matter of substituting it in existing magnet designs. Instead, “it was a rework from the ground up of almost all the principles that you use to build superconducting magnets,” Whyte says. The new REBCO material is “extraordinarily different than the previous generation of superconductors. You’re not just going to adapt and replace, you’re actually going to innovate from the ground up.” The new papers in Transactions on Applied Superconductivity describe the details of that redesign process, now that patent protection is in place.

      A key innovation: no insulation

      One of the dramatic innovations, which had many others in the field skeptical of its chances of success, was the elimination of insulation around the thin, flat ribbons of superconducting tape that formed the magnet. Like virtually all electrical wires, conventional superconducting magnets are fully protected by insulating material to prevent short-circuits between the wires. But in the new magnet, the tape was left completely bare; the engineers relied on REBCO’s much greater conductivity to keep the current flowing through the material.

      “When we started this project, in let’s say 2018, the technology of using high-temperature superconductors to build large-scale high-field magnets was in its infancy,” says Zach Hartwig, the Robert N. Noyce Career Development Professor in the Department of Nuclear Science and Engineering. Hartwig has a co-appointment at the PSFC and is the head of its engineering group, which led the magnet development project. “The state of the art was small benchtop experiments, not really representative of what it takes to build a full-size thing. Our magnet development project started at benchtop scale and ended up at full scale in a short amount of time,” he adds, noting that the team built a 20,000-pound magnet that produced a steady, even magnetic field of just over 20 tesla — far beyond any such field ever produced at large scale.

      “The standard way to build these magnets is you would wind the conductor and you have insulation between the windings, and you need insulation to deal with the high voltages that are generated during off-normal events such as a shutdown.” Eliminating the layers of insulation, he says, “has the advantage of being a low-voltage system. It greatly simplifies the fabrication processes and schedule.” It also leaves more room for other elements, such as more cooling or more structure for strength.

      The magnet assembly is a slightly smaller-scale version of the ones that will form the donut-shaped chamber of the SPARC fusion device now being built by CFS in Devens, Massachusetts. It consists of 16 plates, called pancakes, each bearing a spiral winding of the superconducting tape on one side and cooling channels for helium gas on the other.

      But the no-insulation design was considered risky, and a lot was riding on the test program. “This was the first magnet at any sufficient scale that really probed what is involved in designing and building and testing a magnet with this so-called no-insulation no-twist technology,” Hartwig says. “It was very much a surprise to the community when we announced that it was a no-insulation coil.”

      Pushing to the limit … and beyond

      The initial test, described in previous papers, proved that the design and manufacturing process not only worked but was highly stable — something that some researchers had doubted. The next two test runs, also performed in late 2021, then pushed the device to the limit by deliberately creating unstable conditions, including a complete shutoff of incoming power that can lead to a catastrophic overheating. Known as quenching, this is considered a worst-case scenario for the operation of such magnets, with the potential to destroy the equipment.

      Part of the mission of the test program, Hartwig says, was “to actually go off and intentionally quench a full-scale magnet, so that we can get the critical data at the right scale and the right conditions to advance the science, to validate the design codes, and then to take the magnet apart and see what went wrong, why did it go wrong, and how do we take the next iteration toward fixing that. … It was a very successful test.”

      That final test, which ended with the melting of one corner of one of the 16 pancakes, produced a wealth of new information, Hartwig says. For one thing, they had been using several different computational models to design and predict the performance of various aspects of the magnet’s performance, and for the most part, the models agreed in their overall predictions and were well-validated by the series of tests and real-world measurements. But in predicting the effect of the quench, the model predictions diverged, so it was necessary to get the experimental data to evaluate the models’ validity.

      “The highest-fidelity models that we had predicted almost exactly how the magnet would warm up, to what degree it would warm up as it started to quench, and where would the resulting damage to the magnet would be,” he says. As described in detail in one of the new reports, “That test actually told us exactly the physics that was going on, and it told us which models were useful going forward and which to leave by the wayside because they’re not right.”

      Whyte says, “Basically we did the worst thing possible to a coil, on purpose, after we had tested all other aspects of the coil performance. And we found that most of the coil survived with no damage,” while one isolated area sustained some melting. “It’s like a few percent of the volume of the coil that got damaged.” And that led to revisions in the design that are expected to prevent such damage in the actual fusion device magnets, even under the most extreme conditions.

      Hartwig emphasizes that a major reason the team was able to accomplish such a radical new record-setting magnet design, and get it right the very first time and on a breakneck schedule, was thanks to the deep level of knowledge, expertise, and equipment accumulated over decades of operation of the Alcator C-Mod tokamak, the Francis Bitter Magnet Laboratory, and other work carried out at PSFC. “This goes to the heart of the institutional capabilities of a place like this,” he says. “We had the capability, the infrastructure, and the space and the people to do these things under one roof.”

      The collaboration with CFS was also key, he says, with MIT and CFS combining the most powerful aspects of an academic institution and private company to do things together that neither could have done on their own. “For example, one of the major contributions from CFS was leveraging the power of a private company to establish and scale up a supply chain at an unprecedented level and timeline for the most critical material in the project: 300 kilometers (186 miles) of high-temperature superconductor, which was procured with rigorous quality control in under a year, and integrated on schedule into the magnet.”

      The integration of the two teams, those from MIT and those from CFS, also was crucial to the success, he says. “We thought of ourselves as one team, and that made it possible to do what we did.” More

    • 138 Shares129 Views

      in Energy

      New study shows how universities are critical to emerging fusion industry

      by

      A new study suggests that universities have an essential role to fulfill in the continued growth and success of any modern high-tech industry, and especially the nascent fusion industry; however, the importance of that role is not reflected in the number of fusion-oriented faculty and educational channels currently available. Academia’s responsiveness to the birth of other modern scientific fields, such as aeronautics and nuclear fission, provides a template for the steps universities can take to enable a robust fusion industry.

      Authored by Dennis Whyte, the Hitachi America Professor of Engineering and director of the Plasma Science and Fusion Center at MIT; Carlos Paz-Soldan, associate professor of applied physics and applied mathematics at Columbia University; and Brian D. Wirth, the Governor’s Chair Professor of Computational Nuclear Engineering at the University of Tennessee, the paper was recently published in the journal Physics of Plasmas as part of a special collection titled “Private Fusion Research: Opportunities and Challenges in Plasma Science.”

      With contributions from authors in academia, government, and private industry, the collection outlines a framework for public-private partnerships that will be essential for the success of the fusion industry.

      Now being seen as a potential source of unlimited green energy, fusion is the same process that powers the sun — hydrogen atoms combine to form helium, releasing vast amounts of clean energy in the form of light and heat.

      The excitement surrounding fusion’s arrival has resulted in the proliferation of dozens of for-profit companies positioning themselves at the forefront of the commercial fusion energy industry. In the near future, those companies will require a significant network of fusion-fluent workers to take on varied tasks requiring a range of skills.

      While the authors acknowledge the role of private industry, especially as an increasingly dominant source of research funding, they also show that academia is and will continue to be critical to industry’s development, and it cannot be decoupled from private industry’s growth. Despite the evidence of this burgeoning interest, the size and scale of the field’s academic network at U.S.-based universities is sparse.

      According to Whyte, “Diversifying the [fusion] field by adding more tracks for master’s students and undergraduates who can transition into industry more quickly is an important step.”

      An analysis found that while there are 57 universities in the United States active in plasma and fusion research, the average number of tenured or tenure-track plasma/fusion faculty at each institution is only two. By comparison, a sampling of US News and World Report’s top 10 programs for nuclear fission and aeronautics/astronautics found an average of nearly 20 faculty devoted to fission and 32 to aero/astro.

      “University programs in fusion and their sponsors need to up their game and hire additional faculty if they want to provide the necessary workforce to support a growing U.S. fusion industry,” adds Paz-Soldan.

      The growth and proliferation of those fields and others, such as computing and biotechnology, were historically in lockstep with the creation of academic programs that helped drive the fields’ progress and widespread acceptance. Creating a similar path for fusion is essential to ensuring its sustainable growth, and as Wirth notes, “that this growth should be pursued in a way that is interdisciplinary across numerous engineering and science disciplines.”

      At MIT, an example of that path is seen at the Plasma Science and Fusion Center.

      The center has deep historical ties to government research programs, and the largest fusion company in the world, Commonwealth Fusion Systems (CFS), was spun out of the PSFC by Whyte’s former students and an MIT postdoc. Whyte also serves as the primary investigator in collaborative research with CFS on SPARC, a proof-of-concept fusion platform for advancing tokamak science that is scheduled for completion in 2025.

      “Public and private roles in the fusion community are rapidly evolving in response to the growth of privately funded commercial product development,” says Michael Segal, head of open innovation at CFS. “The fusion industry will increasingly rely on its university partners to train students, work across diverse disciplines, and execute small and midsize programs at speed.”

      According to the authors, another key reason academia will remain essential to the continued growth and development of fusion is because it is unconflicted. Whyte comments, “Our mandate is sharing information and education, which means we have no competitive conflict and innovation can flow freely.” Furthermore, fusion science is inherently multidisciplinary: “[It] requires physicists, computer scientists, engineers, chemists, etc. and it’s easy to tap into all those disciplines in an academic environment where they’re all naturally rubbing elbows and collaborating.”

      Creating a new energy industry, however, will also require a workforce skilled in disciplines other than STEM, say the authors. As fusion companies continue to grow, they will need expertise in finance, safety, licensing, and market analysis. Any successful fusion enterprise will also have major geopolitical, societal, and economic impacts, all of which must be managed.

      Ultimately, there are several steps the authors identify to help build the connections between academia and industry that will be important going forward: The first is for universities to acknowledge the rapidly changing fusion landscape and begin to adapt. “Universities need to embrace the growth of the private sector in fusion, recognize the opportunities it provides, and seek out mutually beneficial partnerships,” says Paz-Soldan.

      The second step is to reconcile the mission of educational institutions — unconflicted open access — with condensed timelines and proprietary outputs that come with private partnerships. At the same time, the authors note that private fusion companies should embrace the transparency of academia by publishing and sharing the findings they can through peer-reviewed journals, which will be a necessary part of building the industry’s credibility.

      The last step, the authors say, is for universities to become more flexible and creative in their technology licensing strategies to ensure ideas and innovations find their way from the lab into industry.

      “As an industry, we’re in a unique position because everything is brand new,” Whyte says. “But we’re enough students of history that we can see what’s needed to succeed; quantifying the status of the private and academic landscape is an important strategic touchstone. By drawing attention to the current trajectory, hopefully we’ll be in a better position to work with our colleagues in the public and private sector and make better-informed choices about how to proceed.” More

    • 163 Shares159 Views

      in Energy

      Team engineers nanoparticles using ion irradiation to advance clean energy and fuel conversion

      by

      MIT researchers and colleagues have demonstrated a way to precisely control the size, composition, and other properties of nanoparticles key to the reactions involved in a variety of clean energy and environmental technologies. They did so by leveraging ion irradiation, a technique in which beams of charged particles bombard a material.

      They went on to show that nanoparticles created this way have superior performance over their conventionally made counterparts.

      “The materials we have worked on could advance several technologies, from fuel cells to generate CO2-free electricity to the production of clean hydrogen feedstocks for the chemical industry [through electrolysis cells],” says Bilge Yildiz, leader of the work and a professor in MIT’s departments of Nuclear Science and Engineering and Materials Science and Engineering.

      Critical catalyst

      Fuel and electrolysis cells both involve electrochemical reactions through three principal parts: two electrodes (a cathode and anode) separated by an electrolyte. The difference between the two cells is that the reactions involved run in reverse.

      The electrodes are coated with catalysts, or materials that make the reactions involved go faster. But a critical catalyst made of metal-oxide materials has been limited by challenges including low durability. “The metal catalyst particles coarsen at high temperatures, and you lose surface area and activity as a result,” says Yildiz, who is also affiliated with the Materials Research Laboratory and is an author of an open-access paper on the work published in the journal Energy & Environmental Science.

      Enter metal exsolution, which involves precipitating metal nanoparticles out of a host oxide onto the surface of the electrode. The particles embed themselves into the electrode, “and that anchoring makes them more stable,” says Yildiz. As a result, exsolution has “led to remarkable progress in clean energy conversion and energy-efficient computing devices,” the researchers write in their paper.

      However, controlling the precise properties of the resulting nanoparticles has been difficult. “We know that exsolution can give us stable and active nanoparticles, but the challenging part is really to control it. The novelty of this work is that we’ve found a tool — ion irradiation — that can give us that control,” says Jiayue Wang PhD ’22, first author of the paper. Wang, who conducted the work while earning his PhD in the MIT Department of Nuclear Science and Engineering, is now a postdoc at Stanford University.

      Sossina Haile ’86, PhD ’92, the Walter P. Murphy Professor of Materials Science and Engineering at Northwestern University, who was not involved in the current work, says:

      “Metallic nanoparticles serve as catalysts in a whole host of reactions, including the important reaction of splitting water to generate hydrogen for energy storage. In this work, Yildiz and colleagues have created an ingenious method for controlling the way that nanoparticles form.”

      Haile continues, “the community has shown that exsolution results in structurally stable nanoparticles, but the process is not easy to control, so one doesn’t necessarily get the optimal number and size of particles. Using ion irradiation, this group was able to precisely control the features of the nanoparticles, resulting in excellent catalytic activity for water splitting.”

      What they did

      The researchers found that aiming a beam of ions at the electrode while simultaneously exsolving metal nanoparticles onto the electrode’s surface allowed them to control several properties of the resulting nanoparticles.

      “Through ion-matter interactions, we have successfully engineered the size, composition, density, and location of the exsolved nanoparticles,” the team writes in Energy & Environmental Science.

      For example, they could make the particles much smaller — down to 2 billionths of a meter in diameter — than those made using conventional thermal exsolution methods alone. Further, they were able to change the composition of the nanoparticles by irradiating with specific elements. They demonstrated this with a beam of nickel ions that implanted nickel into the exsolved metal nanoparticle. As a result, they demonstrated a direct and convenient way to engineer the composition of exsolved nanoparticles.

      “We want to have multi-element nanoparticles, or alloys, because they usually have higher catalytic activity,” Yildiz says. “With our approach, the exsolution target does not have to be dependent on the substrate oxide itself.” Irradiation opens the door to many more compositions. “We can pretty much choose any oxide and any ion that we can irradiate with and exsolve that,” says Yildiz.

      The team also found that ion irradiation forms defects in the electrode itself. And these defects provide additional nucleation sites, or places for the exsolved nanoparticles to grow from, increasing the density of the resulting nanoparticles.

      Irradiation could also allow extreme spatial control over the nanoparticles. “Because you can focus the ion beam, you can imagine that you could ‘write’ with it to form specific nanostructures,” says Wang. “We did a preliminary demonstration [of that], but we believe it has potential to realize well-controlled micro- and nano-structures.”

      The team also showed that the nanoparticles they created with ion irradiation had superior catalytic activity over those created by conventional thermal exsolution alone.

      Additional MIT authors of the paper are Kevin B. Woller, a principal research scientist at the Plasma Science and Fusion Center (PSFC), home to the equipment used for ion irradiation; Abinash Kumar PhD ’22, who received his PhD from the Department of Materials Science and Engineering (DMSE) and is now at Oak Ridge National Laboratory; and James M. LeBeau, an associate professor in DMSE. Other authors are Zhan Zhang and Hua Zhou of Argonne National Laboratory, and Iradwikanari Waluyo and Adrian Hunt of Brookhaven National Laboratory.

      This work was funded by the OxEon Corp. and MIT’s PSFC. The research also used resources supported by the U.S. Department of Energy Office of Science, MIT’s Materials Research Laboratory, and MIT.nano. The work was performed, in part, at Harvard University through a network funded by the National Science Foundation. More

    • 163 Shares169 Views

      in Energy

      Dennis Whyte steps down as director of the Plasma Science and Fusion Center

      by

      Dennis Whyte, who spearheaded the development of the world’s most powerful fusion electromagnet and grew the MIT Plasma Science and Fusion Center’s research volume by more than 50 percent, has announced he will be stepping down as the center’s director at the end of the year in order to devote his full attention to teaching, engaging in cutting-edge fusion research, and pursuing entrepreneurial activities at the PSFC.

      “The reason I came to MIT as a faculty member in ’06 was because of the PSFC and the very special place it held and still holds in fusion,” says Whyte, the Hitachi America Professor of Engineering in the Department of Nuclear Science and Engineering. When he was appointed director of the PSFC in 2015, Whyte saw it as an opportunity to realize even more of the PSFC’s potential: “After 10 years I think we’ve seen that dream come to life. Research and entrepreneurship are stronger than ever.”

      Whyte’s passion has always been for fusion — the process by which light elements combine to form heavier ones, releasing massive amounts of energy. One hundred years ago fusion was solely the provenance of astronomers’ speculation; through the efforts of generations of scientists and engineers, fusion now holds the potential to offer humanity an entirely new source of clean, abundant energy — and Whyte has been at the forefront of that effort.

      “Fusion’s challenges require interdisciplinary work, so it’s always fresh, and you get these unexpected intersections that can have wild outcomes. As an inherently curious person, fusion is perfect for me.”

      Whyte’s enthusiasm is legendary, especially when it comes to teaching. The effects of that enthusiasm are easy to see: At the start of his tenure, only a handful of students chose to pursue plasma physics and fusion science. Since then, the number of students has ballooned, and this year nearly 100 students from six departments are working with 15 faculty members.

      Of the growth, Whyte says, “It’s not just that we have more students; it’s that they’re working on more diverse topics, and their passion to make fusion a reality is the best part of the PSFC. Seeing full seminars and classes is fundamentally why I’m here.”

      Even as he managed the directorship and pursued his own scholarly work, Whyte remained active in the classroom and continued advising students. Zach Hartwig, a former student who is now a PSFC researcher and MIT faculty member himself, recalled his first meeting with Whyte as an incoming PhD student: “I had to choose between several projects and advisors and meeting Dennis made my decision easy. He catapulted out of his chair and started sketching his vision for a new fusion diagnostic that many people thought was crazy. His passion and eagerness to tackle only the most difficult problems in the field was immediately tangible.”

      For the past 13 years Whyte has offered a fusion technology design class that has generated several key breakthroughs, including liquid immersion blankets essential for converting fusion energy to heat, inside launch radio frequency systems used to stabilize fusing plasmas, and high-temperature superconducting electromagnets that have opened the door to the possibility of fusion devices that are not only smaller, but also more powerful and efficient.

      In fact, the potential of these electromagnets was significant enough that Whyte, an MIT postdoc, and three of Whyte’s former students (Hartwig among them) spun out a private fusion company to fully realize the magnets’ capabilities. Commonwealth Fusion Systems (CFS) both launched and signed a cooperative research agreement with the PSFC in 2018, and the founders’ vision parlayed into significant external investment, allowing a coalition of CFS and PSFC researchers to refine and develop the electromagnets first conceived in Whyte’s class.

      Three years later, after a historic day of testing, the magnet produced a field strength of 20 tesla, making it the most powerful fusion superconducting electromagnet in the world. According to Whyte, “The success of the TFMC magnet is an encapsulation of everything PSFC. It would’ve been impossible for a single investigator, or a lone spin-out, but we brought together all these disciplines in a team that could execute innovatively and incredibly quickly. We shortened the timescale not just for this project, but for fusion as a whole.”

      CFS remains an important collaborator, accounting for approximately 20 percent of the PSFC’s current research portfolio. While Whyte has no financial stake in the company, he remains a principal investigator on CFS’s SPARC project, a proof-of-concept fusion device predicted to produce more energy than it consumes, ready in 2025. SPARC is the lead-up to ARC, CFS’s commercially scalable fusion power plant planned to arrive in the early 2030s.

      The collaboration between CFS and MIT followed a blueprint that had been piloted more than a decade prior, when the Italian energy company Eni S.p.A signed on as a founding member of the MIT Energy Initiative to develop low-carbon technologies. After many years of successfully working in tandem with MITEI to advance renewable energy research, in 2018 Eni made a significant investment in a young CFS to assist in realizing commercial fusion power, which in turn indirectly funded PSFC research; Eni also collaborated directly with the PSFC to create the Laboratory for Innovative Fusion Technologies, which remains active.

      Whyte believes that “thoughtful and meaningful collaboration with the energy industry can make a difference with research and climate change. Industry engagement is very relevant — it changed both of us. Now Eni has fusion in their portfolio.” The arrangement is a demonstration of how public-private collaborations can accelerate the progress of fusion science, and ultimately the arrival of fusion power.

      Whyte’s move to diversify collaborators, leverage the PSFC’s strength as a multidisciplinary hub, and expand research volume was essential to the center’s survival and growth. Early in his tenure, a shift in funding priorities necessitated the shutdown of Alcator C-Mod, the fusion research device in operation at the PSFC for 23 years — though not before C-Mod set the world record for plasma pressure on its last day of operation. Through this transition, Whyte and the members of his leadership team were able to keep the PSFC whole.

      One alumnus was a particular source of inspiration to Whyte during that time: “Reinier [Beeuwkes] said to me, ‘what you’re doing doesn’t just matter to students and MIT, it matters to the world.’ That was so meaningful, and his words really sustained me when I was feeling major doubt.” In 2022 Beeuwkes won the MIT Alumni Better World Service Award for his support of fusion and the PSFC. Since 2018, sponsored research at the PSFC has more than doubled, as have the number of personnel.

      Whyte’s determination to build and maintain a strong community is a prevailing feature of his leadership. Matt Fulton, who started at the PSFC in 1987 and is now director of operations, says of Whyte, “You want a leader like Dennis on your worst days. We were staring down disaster and he had a plan to hold the PSFC together, and somehow it worked. The research was important, but the people have always been more important to him. We’re so lucky to have him.”

      The Office of the Vice President for Research is launching a search for the PSFC’s next leader. Should the search extend beyond the end of the year, an interim director will be appointed.  

      “As MIT works to magnify its impact in the areas of climate and sustainability, Dennis has built the PSFC into an extraordinary resource for the Institute to draw upon,” says Maria T. Zuber, MIT’s vice president for research. “His leadership has positioned MIT on the leading edge of fusion research and the emerging commercial fusion industry, and while the nature of his contributions will change, … the value he brings to the MIT community will remain clear. As Dennis steps down as director, the PSFC is ascendant.”  More