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      in Environment

      Using graphene foam to filter toxins from drinking water

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      Some kinds of water pollution, such as algal blooms and plastics that foul rivers, lakes, and marine environments, lie in plain sight. But other contaminants are not so readily apparent, which makes their impact potentially more dangerous. Among these invisible substances is uranium. Leaching into water resources from mining operations, nuclear waste sites, or from natural subterranean deposits, the element can now be found flowing out of taps worldwide.

      In the United States alone, “many areas are affected by uranium contamination, including the High Plains and Central Valley aquifers, which supply drinking water to 6 million people,” says Ahmed Sami Helal, a postdoc in the Department of Nuclear Science and Engineering. This contamination poses a near and present danger. “Even small concentrations are bad for human health,” says Ju Li, the Battelle Energy Alliance Professor of Nuclear Science and Engineering and professor of materials science and engineering.

      Now, a team led by Li has devised a highly efficient method for removing uranium from drinking water. Applying an electric charge to graphene oxide foam, the researchers can capture uranium in solution, which precipitates out as a condensed solid crystal. The foam may be reused up to seven times without losing its electrochemical properties. “Within hours, our process can purify a large quantity of drinking water below the EPA limit for uranium,” says Li.

      A paper describing this work was published in this week Advanced Materials. The two first co-authors are Helal and Chao Wang, a postdoc at MIT during the study, who is now with the School of Materials Science and Engineering at Tongji University, Shanghai. Researchers from Argonne National Laboratory, Taiwan’s National Chiao Tung University, and the University of Tokyo also participated in the research. The Defense Threat Reduction Agency (U.S. Department of Defense) funded later stages of this work.

      Targeting the contaminant

      The project, launched three years ago, began as an effort to find better approaches to environmental cleanup of heavy metals from mining sites. To date, remediation methods for such metals as chromium, cadmium, arsenic, lead, mercury, radium, and uranium have proven limited and expensive. “These techniques are highly sensitive to organics in water, and are poor at separating out the heavy metal contaminants,” explains Helal. “So they involve long operation times, high capital costs, and at the end of extraction, generate more toxic sludge.”

      To the team, uranium seemed a particularly attractive target. Field testing from the U.S. Geological Service and the Environmental Protection Agency (EPA) has revealed unhealthy levels of uranium moving into reservoirs and aquifers from natural rock sources in the northeastern United States, from ponds and pits storing old nuclear weapons and fuel in places like Hanford, Washington, and from mining activities located in many western states. This kind of contamination is prevalent in many other nations as well. An alarming number of these sites show uranium concentrations close to or above the EPA’s recommended ceiling of 30 parts per billion (ppb) — a level linked to kidney damage, cancer risk, and neurobehavioral changes in humans.

      The critical challenge lay in finding a practical remediation process exclusively sensitive to uranium, capable of extracting it from solution without producing toxic residues. And while earlier research showed that electrically charged carbon fiber could filter uranium from water, the results were partial and imprecise.

      Wang managed to crack these problems — based on her investigation of the behavior of graphene foam used for lithium-sulfur batteries. “The physical performance of this foam was unique because of its ability to attract certain chemical species to its surface,” she says. “I thought the ligands in graphene foam would work well with uranium.”

      Simple, efficient, and clean

      The team set to work transforming graphene foam into the equivalent of a uranium magnet. They learned that by sending an electric charge through the foam, splitting water and releasing hydrogen, they could increase the local pH and induce a chemical change that pulled uranium ions out of solution. The researchers found that the uranium would graft itself onto the foam’s surface, where it formed a never-before-seen crystalline uranium hydroxide. On reversal of the electric charge, the mineral, which resembles fish scales, slipped easily off the foam.

      It took hundreds of tries to get the chemical composition and electrolysis just right. “We kept changing the functional chemical groups to get them to work correctly,” says Helal. “And the foam was initially quite fragile, tending to break into pieces, so we needed to make it stronger and more durable,” says Wang.

      This uranium filtration process is simple, efficient, and clean, according to Li: “Each time it’s used, our foam can capture four times its own weight of uranium, and we can achieve an extraction capacity of 4,000 mg per gram, which is a major improvement over other methods,” he says. “We’ve also made a major breakthrough in reusability, because the foam can go through seven cycles without losing its extraction efficiency.” The graphene foam functions as well in seawater, where it reduces uranium concentrations from 3 parts per million to 19.9 ppb, showing that other ions in the brine do not interfere with filtration.

      The team believes its low-cost, effective device could become a new kind of home water filter, fitting on faucets like those of commercial brands. “Some of these filters already have activated carbon, so maybe we could modify these, add low-voltage electricity to filter uranium,” says Li.

      “The uranium extraction this device achieves is very impressive when compared to existing methods,” says Ho Jin Ryu, associate professor of nuclear and quantum engineering at the Korea Advanced Institute of Science and Technology. Ryu, who was not involved in the research, believes that the demonstration of graphene foam reusability is a “significant advance,” and that “the technology of local pH control to enhance uranium deposition will be impactful because the scientific principle can be applied more generally to heavy metal extraction from polluted water.”

      The researchers have already begun investigating broader applications of their method. “There is a science to this, so we can modify our filters to be selective for other heavy metals such as lead, mercury, and cadmium,” says Li. He notes that radium is another significant danger for locales in the United States and elsewhere that lack resources for reliable drinking water infrastructure.

      “In the future, instead of a passive water filter, we could be using a smart filter powered by clean electricity that turns on electrolytic action, which could extract multiple toxic metals, tell you when to regenerate the filter, and give you quality assurance about the water you’re drinking.” More

    • 50 Shares109 Views

      in Energy

      Amy Watterson: Model engineer

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      “I love that we are doing something that no one else is doing.”

      Amy Watterson is excited when she talks about SPARC, the pilot fusion plant being developed by MIT spinoff Commonwealth Fusion Systems (CSF). Since being hired as a mechanical engineer at the Plasma Science and Fusion Center (PSFC) two years ago, Watterson has found her skills stretching to accommodate the multiple needs of the project.

      Fusion, which fuels the sun and stars, has long been sought as a carbon-free energy source for the world. For decades researchers have pursued the “tokamak,” a doughnut-shaped vacuum chamber where hot plasma can be contained by magnetic fields and heated to the point where fusion occurs. Sustaining the fusion reactions long enough to draw energy from them has been a challenge.

      Watterson is intimately aware of this difficulty. Much of her life she has heard the quip, “Fusion is 50 years away and always will be.” The daughter of PSFC research scientist Catherine Fiore, who headed the PSFC’s Office of Environment, Safety and Health, and Reich Watterson, an optical engineer working at the center, she had watched her parents devote years to making fusion a reality. She determined before entering Rensselaer Polytechnic Institute that she could forgo any attempt to follow her parents into a field that might not produce results during her career.

      Working on SPARC has changed her mindset. Taking advantage of a novel high-temperature superconducting tape, SPARC’s magnets will be compact while generating magnetic fields stronger than would be possible from other mid-sized tokamaks, and producing more fusion power. It suggests a high-field device that produces net fusion gain is not 50 years away. SPARC is scheduled to be begin operation in 2025.

      An education in modeling

      Watterson’s current excitement, and focus, is due to an approaching milestone for SPARC: a test of the Toroidal Field Magnet Coil (TFMC), a scaled prototype for the HTS magnets that will surround SPARC’s toroidal vacuum chamber. Its design and manufacture have been shaped by computer models and simulations. As part of a large research team, Waterson has received an education in modeling over the past two years.

      Computer models move scientific experiments forward by allowing researchers to predict what will happen to an experiment — or its materials — if a parameter is changed. Modeling a component of the TFMC, for example, researchers can test how it is affected by varying amounts of current, different temperatures or different materials. With this information they can make choices that will improve the success of the experiment.

      In preparation for the magnet testing, Watterson has modeled aspects of the cryogenic system that will circulate helium gas around the TFMC to keep it cold enough to remain superconducting. Taking into consideration the amount of cooling entering the system, the flow rate of the helium, the resistance created by valves and transfer lines and other parameters, she can model how much helium flow will be necessary to guarantee the magnet stays cold enough. Adjusting a parameter can make the difference between a magnet remaining superconducting and becoming overheated or even damaged.

      Watterson and her teammates have also modeled pressures and stress on the inside of the TFMC. Pumping helium through the coil to cool it down will add 20 atmospheres of pressure, which could create a degree of flex in elements of the magnet that are welded down. Modeling can help determine how much pressure a weld can sustain.

      “How thick does a weld need to be, and where should you put the weld so that it doesn’t break — that’s something you don’t want to leave until you’re finally assembling it,” says Watterson.

      Modeling the behavior of helium is particularly challenging because its properties change significantly as the pressure and temperature change.

      “A few degrees or a little pressure will affect the fluid’s viscosity, density, thermal conductivity, and heat capacity,” says Watterson. “The flow has different pressures and temperatures at different places in the cryogenic loop. You end up with a set of equations that are very dependent on each other, which makes it a challenge to solve.”

      Role model

      Watterson notes that her modeling depends on the contributions of colleagues at the PSFC, and praises the collaborative spirit among researchers and engineers, a community that now feels like family. Her teammates have been her mentors. “I’ve learned so much more on the job in two years than I did in four years at school,” she says.

      She realizes that having her mother as a role model in her own family has always made it easier for her to imagine becoming a scientist or engineer. Tracing her early passion for engineering to a middle school Lego robotics tournament, her eyes widen as she talks about the need for more female engineers, and the importance of encouraging girls to believe they are equal to the challenge.

      “I want to be a role model and tell them ‘I’m a successful engineer, you can be too.’ Something I run into a lot is that little girls will say, ‘I can’t be an engineer, I’m not cut out for that.’ And I say, ‘Well that’s not true. Let me show you. If you can make this Lego robot, then you can be an engineer.’ And it turns out they usually can.”

      Then, as if making an adjustment to one of her computer models, she continues.

      “Actually, they always can.” More

    • 88 Shares119 Views

      in Energy

      Manipulating magnets in the quest for fusion

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      “You get the high field, you get the performance.”

      Senior Research Scientist Brian LaBombard is summarizing what might be considered a guiding philosophy behind designing and engineering fusion devices at MIT’s Plasma Science and Fusion Center (PSFC). Beginning in 1972 with the Alcator A tokamak, through Alcator C (1978) and Alcator C-Mod (1991), the PSFC has used magnets with high fields to confine the hot plasma in compact, high-performance tokamaks. Joining what was then the Plasma Fusion Center as a graduate student in 1978, just as Alcator A was finishing its run, LaBombard is one of the few who has worked with each iteration of the high-field concept. Now he has turned his attention to the PSFC’s latest fusion venture, a fusion energy project called SPARC.

      Designed in collaboration with MIT spinoff Commonwealth Fusion Systems (CFS), SPARC employs novel high temperature superconducting (HTS) magnets at high-field to achieve fusion that will produce net energy gain. Some of these magnets will wrap toroidally around the tokamak’s doughnut-shaped vacuum chamber, confining fusion reactions and preventing damage to the walls of the device.

      The PSFC has spent three years researching, developing, and manufacturing a scaled version of these toroidal field (TF) coils — the toroidal field model coil, or TFMC. Before the TF coils can be built for SPARC, LaBombard and his team need to test the model coil under the conditions that it will experience in this tokamak.

      HTS magnets need to be cooled in order to remain superconducting, and to be protected from the heat generated by current. For testing, the TFMC will be enclosed in a cryostat, cooled to the low temperatures needed for eventual tokamak operation, and charged with current to produce magnetic field. How the magnet responds as the current is provided to the coil will determine if the technology is in hand to construct the 18 TF coils for SPARC.

      A history of achievement

      That LaBombard is part of the PSFC’s next fusion project is not unusual; that he is involved in designing, engineering, and testing the magnets is. Until 2018, when he led the R&D research team for one of the magnet designs being considered for SPARC, LaBombard’s 30-plus years of celebrated research had focused on other areas of the fusion question.

      As a graduate student, he gained early acclaim for the research he reported in his PhD thesis. Working on Alcator C, he made groundbreaking discoveries about the plasma physics in the “boundary” region of the tokamak, between the edge of the fusing core and the wall of the machine. With typical modesty, LaBombard credits some of his success to the fact that the topic was not well-studied, and that Alcator C provided measurements not possible on other machines.

      “People knew about the boundary, but nobody was really studying it in detail. On Alcator C, there were interesting phenomena, such as marfes [multifaceted asymmetric radiation from the edge], being detected for the first time. This pushed me to make boundary layer measurements in great detail that no one had ever seen before. It was all new territory, so I made a big splash.”

      That splash established him as a leading researcher in the field of boundary plasmas. After a two-year turn at the University of California at Los Angeles working on a plasma-wall test facility called PISCES, LaBombard, who grew up in New England, was happy to return to MIT to join the PSFC’s new Alcator C-Mod project.

      Over the next 28 years of C-Mod’s construction phase and operation, LaBombard continued to make groundbreaking contributions to understanding tokamak edge and divertor plasmas, and to design internal components that can survive the harsh conditions and provide plasma control — including C-Mod’s vertical target plate divertor and a unique divertor cryopump system. That experience led him to conceive of the “X-point target divertor” for handling extreme fusion power exhaust and to propose a national Advanced Divertor tokamak eXperiment (ADX) to test such ideas.

      All along, LaBombard’s true passion was in creating revolutionary diagnostics to unfold boundary layer physics and in guiding graduate students to do the same: an Omegatron, to measure impurity concentrations directly in the boundary plasma, resolved by charge-to-mass ratio; fast-scanning Langmuir-Mach probes to measure plasma flows; a Shoelace Antenna to provide insight into plasma fluctuations at the edge; the invention of a Mirror Langmuir Probe for the real-time measurements of plasma turbulence at high bandwidth.

      Switching sides

      His expertise established, he could have continued this focus on the edge of the plasma through collaborations with other laboratories and at the PSFC. Instead, he finds himself on the other side of the vacuum chamber, immersed in magnet design and technology. Challenged with finding an effective HTS magnet design for SPARC, he and his team were able to propose a winning strategy, one that seemed most likely to achieve the compact high field and high performance that PSFC tokamaks have been known for.

      LaBombard is stimulated by his new direction and excited about the upcoming test of the TFMC. His new role takes advantage of his physics background in electricity and magnetism. It also supports his passion for designing and building things, which he honed as high school apprentice to his machinist father and explored professionally building systems for Alcator C-Mod.

      “I view my principal role is to make sure the TF coil works electrically, the way it’s supposed to,” he says. “So it produces the magnetic field without damaging the coil.”

      A successful test would validate the understanding of how the new magnet technology works, and will prepare the team to build magnets for SPARC.

      Among those overseeing the hours of TFMC testing will be graduate students, current and former, reminding LaBombard of his own student days working on Alcator C, and of his years supervising students on Alcator C-Mod.

      “Those students were directly involved with Alcator C-Mod. They would jump in, make things happen — and as a team. This team spirit really enabled everyone to excel.

      “And looking to when SPARC was taking shape, you could see that across the board, from the new folks to the younger folks, they really got engaged by the spirit of Alcator — by recognition of the plasma performance that can be made possible by high magnetic fields.”

      He laughs as he looks to the past and to the future.

      “And they are taking it to SPARC.” More