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      in Energy

      3 Questions: What should scientists and the public know about nuclear waste?

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      Many researchers see an expansion of nuclear power, which produces no greenhouse gas emissions from its power generation, as an essential component of strategies to combat global climate change. Yet there is still strong resistance to such expansion, and much of that is based on the issue of how to safely dispose of the resulting radioactive waste material. MIT recently convened a workshop to help nuclear engineers, policymakers, and academics learn about approaches to communicating accurate information about the management of nuclear waste to students and the public, in hopes of allaying fears and encouraging support for the development of new, safer nuclear power plants around the world.

      Organized by Haruko Wainwright, an MIT assistant professor of nuclear science and engineering and of civil and environmental engineering, the workshop included professors, researchers, industry representatives, and government officials, and was designed to emphasize the multidisciplinary nature of the issue. MIT News asked Wainwright to describe the workshop and its conclusions, which she reported on in a paper just published in the Journal of Environmental Radioactivity.

      Q: What was the main objective of the this workshop?

      A: There is a growing concern that, in spite of much excitement about new nuclear reactor deployment and nuclear energy for tackling climate change, relatively less attention is being paid to the thorny question of long-term management of the spent fuel (waste) from these reactors. The government and industry have embraced consent-based siting approaches — that is, finding sites to store and dispose nuclear waste through broad community participation with equity and environmental justice considered. However, many of us in academia feel that those in the industry are missing key facts to communicate to the public.

      Understanding and managing nuclear waste requires a multidisciplinary expertise in nuclear, civil, and chemical engineering as well as environmental and earth sciences. For example, the amount of waste per se, which is always very small for nuclear systems, is not the only factor determining the environmental impacts because some radionuclides in the waste are vastly more mobile than others, and thus can spread farther and more quickly. Nuclear engineers, environmental scientists, and others need to work together to predict the environmental impacts of radionuclides in the waste generated by the new reactors, and to develop waste isolation strategies for an extended time.

      We organized this workshop to ensure this collaborative approach is mastered from the start. A second objective was to develop a blueprint for educating next-generation engineers and scientists about nuclear waste and shaping a more broadly educated group of nuclear and general engineers.

      Q: What kinds of innovative teaching practices were discussed and recommended, and are there examples of these practices in action?

       A: Some participants teach project-based or simulation-based courses of real-world situations. For example, students are divided into several groups representing various stakeholders — such as the public, policymakers, scientists, and governments — and discuss the potential siting of a nuclear waste repository in a community. Such a course helps the students to consider the perspectives of different groups, understand a plurality of points of view, and learn how to communicate their ideas and concerns effectively. Other courses may ask students to synthesize key technical facts and numbers, and to develop a Congressional testimony statement or an opinion article for newspapers. 

      Q: What are some of the biggest misconceptions people have about nuclear waste, and how do you think these misconceptions can be addressed?

      A: The workshop participants agreed that the broader and life-cycle perspectives are important. Within the nuclear energy life cycle, for example, people focus disproportionally on high-level radioactive waste or spent fuel, which has been highly regulated and well managed. Nuclear systems also produce secondary waste, including low-level waste and uranium mining waste, which gets less attention.

      The participants also believe that the nuclear industry has been exemplary in leading the environmental and waste isolation science and technologies. Nuclear waste disposal strategies were developed in the 1950s, much earlier than other hazardous waste which began to receive serious regulation only in the 1970s. In addition, current nuclear waste disposal practices consider the compliance periods of isolation for thousands of years, while other hazardous waste disposal is not required to consider beyond 30 years, although some waste has an essentially infinite longevity, for example, mercury or lead. Finally, there is relatively unregulated waste — such as CO2 from fossil energy, agricultural effluents and other sources — that is released freely into the biosphere and is already impacting our environment. Yet, many people remain more concerned about the relatively well-regulated nuclear waste than about all these unregulated sources.

      Interestingly, many engineers — even nuclear engineers — do not know these facts. We believe that we need to teach students not just cutting-edge technologies, but also broader perspectives, including the history of industries and regulations, as well as environmental science.

      At the same time, we need to move the nuclear community to think more holistically about waste and its environmental impacts from the early stages of design of nuclear systems. We should design new reactors from the “waste up.”  We believe that the nuclear industry should continue to lead waste-management technologies and strategies, and also encourage other industries to adopt lifecycle approaches about their own waste to improve the overall sustainability. More

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      in Environment

      Improving US air quality, equitably

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      Decarbonization of national economies will be key to achieving global net-zero emissions by 2050, a major stepping stone to the Paris Agreement’s long-term goal of keeping global warming well below 2 degrees Celsius (and ideally 1.5 C), and thereby averting the worst consequences of climate change. Toward that end, the United States has pledged to reduce its greenhouse gas emissions by 50-52 percent from 2005 levels by 2030, backed by its implementation of the 2022 Inflation Reduction Act. This strategy is consistent with a 50-percent reduction in carbon dioxide (CO2) by the end of the decade.

      If U.S. federal carbon policy is successful, the nation’s overall air quality will also improve. Cutting CO2 emissions reduces atmospheric concentrations of air pollutants that lead to the formation of fine particulate matter (PM2.5), which causes more than 200,000 premature deaths in the United States each year. But an average nationwide improvement in air quality will not be felt equally; air pollution exposure disproportionately harms people of color and lower-income populations.

      How effective are current federal decarbonization policies in reducing U.S. racial and economic disparities in PM2.5 exposure, and what changes will be needed to improve their performance? To answer that question, researchers at MIT and Stanford University recently evaluated a range of policies which, like current U.S. federal carbon policies, reduce economy-wide CO2 emissions by 40-60 percent from 2005 levels by 2030. Their findings appear in an open-access article in the journal Nature Communications.

      First, they show that a carbon-pricing policy, while effective in reducing PM2.5 exposure for all racial/ethnic groups, does not significantly mitigate relative disparities in exposure. On average, the white population undergoes far less exposure than Black, Hispanic, and Asian populations. This policy does little to reduce exposure disparities because the CO2 emissions reductions that it achieves primarily occur in the coal-fired electricity sector. Other sectors, such as industry and heavy-duty diesel transportation, contribute far more PM2.5-related emissions.

      The researchers then examine thousands of different reduction options through an optimization approach to identify whether any possible combination of carbon dioxide reductions in the range of 40-60 percent can mitigate disparities. They find that that no policy scenario aligned with current U.S. carbon dioxide emissions targets is likely to significantly reduce current PM2.5 exposure disparities.

      “Policies that address only about 50 percent of CO2 emissions leave many polluting sources in place, and those that prioritize reductions for minorities tend to benefit the entire population,” says Noelle Selin, supervising author of the study and a professor at MIT’s Institute for Data, Systems and Society and Department of Earth, Atmospheric and Planetary Sciences. “This means that a large range of policies that reduce CO2 can improve air quality overall, but can’t address long-standing inequities in air pollution exposure.”

      So if climate policy alone cannot adequately achieve equitable air quality results, what viable options remain? The researchers suggest that more ambitious carbon policies could narrow racial and economic PM2.5 exposure disparities in the long term, but not within the next decade. To make a near-term difference, they recommend interventions designed to reduce PM2.5 emissions resulting from non-CO2 sources, ideally at the economic sector or community level.

      “Achieving improved PM2.5 exposure for populations that are disproportionately exposed across the United States will require thinking that goes beyond current CO2 policy strategies, most likely involving large-scale structural changes,” says Selin. “This could involve changes in local and regional transportation and housing planning, together with accelerated efforts towards decarbonization.” More

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      in Environment

      How to tackle the global deforestation crisis

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      Imagine if France, Germany, and Spain were completely blanketed in forests — and then all those trees were quickly chopped down. That’s nearly the amount of deforestation that occurred globally between 2001 and 2020, with profound consequences.

      Deforestation is a major contributor to climate change, producing between 6 and 17 percent of global greenhouse gas emissions, according to a 2009 study. Meanwhile, because trees also absorb carbon dioxide, removing it from the atmosphere, they help keep the Earth cooler. And climate change aside, forests protect biodiversity.

      “Climate change and biodiversity make this a global problem, not a local problem,” says MIT economist Ben Olken. “Deciding to cut down trees or not has huge implications for the world.”

      But deforestation is often financially profitable, so it continues at a rapid rate. Researchers can now measure this trend closely: In the last quarter-century, satellite-based technology has led to a paradigm change in charting deforestation. New deforestation datasets, based on the Landsat satellites, for instance, track forest change since 2000 with resolution at 30 meters, while many other products now offer frequent imaging at close resolution.

      “Part of this revolution in measurement is accuracy, and the other part is coverage,” says Clare Balboni, an assistant professor of economics at the London School of Economics (LSE). “On-site observation is very expensive and logistically challenging, and you’re talking about case studies. These satellite-based data sets just open up opportunities to see deforestation at scale, systematically, across the globe.”

      Balboni and Olken have now helped write a new paper providing a road map for thinking about this crisis. The open-access article, “The Economics of Tropical Deforestation,” appears this month in the Annual Review of Economics. The co-authors are Balboni, a former MIT faculty member; Aaron Berman, a PhD candidate in MIT’s Department of Economics; Robin Burgess, an LSE professor; and Olken, MIT’s Jane Berkowitz Carlton and Dennis William Carlton Professor of Microeconomics. Balboni and Olken have also conducted primary research in this area, along with Burgess.

      So, how can the world tackle deforestation? It starts with understanding the problem.

      Replacing forests with farms

      Several decades ago, some thinkers, including the famous MIT economist Paul Samuelson in the 1970s, built models to study forests as a renewable resource; Samuelson calculated the “maximum sustained yield” at which a forest could be cleared while being regrown. These frameworks were designed to think about tree farms or the U.S. national forest system, where a fraction of trees would be cut each year, and then new trees would be grown over time to take their place.

      But deforestation today, particularly in tropical areas, often looks very different, and forest regeneration is not common.

      Indeed, as Balboni and Olken emphasize, deforestation is now rampant partly because the profits from chopping down trees come not just from timber, but from replacing forests with agriculture. In Brazil, deforestation has increased along with agricultural prices; in Indonesia, clearing trees accelerated as the global price of palm oil went up, leading companies to replace forests with palm tree orchards.

      All this tree-clearing creates a familiar situation: The globally shared costs of climate change from deforestation are “externalities,” as economists say, imposed on everyone else by the people removing forest land. It is akin to a company that pollutes into a river, affecting the water quality of residents.

      “Economics has changed the way it thinks about this over the last 50 years, and two things are central,” Olken says. “The relevance of global externalities is very important, and the conceptualization of alternate land uses is very important.” This also means traditional forest-management guidance about regrowth is not enough. With the economic dynamics in mind, which policies might work, and why?

      The search for solutions

      As Balboni and Olken note, economists often recommend “Pigouvian” taxes (named after the British economist Arthur Pigou) in these cases, levied against people imposing externalities on others. And yet, it can be hard to identify who is doing the deforesting.

      Instead of taxing people for clearing forests, governments can pay people to keep forests intact. The UN uses Payments for Environmental Services (PES) as part of its REDD+ (Reducing Emissions from Deforestation and forest Degradation) program. However, it is similarly tough to identify the optimal landowners to subsidize, and these payments may not match the quick cash-in of deforestation. A 2017 study in Uganda showed PES reduced deforestation somewhat; a 2022 study in Indonesia found no reduction; another 2022 study, in Brazil, showed again that some forest protection resulted.

      “There’s mixed evidence from many of these [studies],” Balboni says. These policies, she notes, must reach people who would otherwise clear forests, and a key question is, “How can we assess their success compared to what would have happened anyway?”

      Some places have tried cash transfer programs for larger populations. In Indonesia, a 2020 study found such subsidies reduced deforestation near villages by 30 percent. But in Mexico, a similar program meant more people could afford milk and meat, again creating demand for more agriculture and thus leading to more forest-clearing.

      At this point, it might seem that laws simply banning deforestation in key areas would work best — indeed, about 16 percent of the world’s land overall is protected in some way. Yet the dynamics of protection are tricky. Even with protected areas in place, there is still “leakage” of deforestation into other regions. 

      Still more approaches exist, including “nonstate agreements,” such as the Amazon Soy Moratorium in Brazil, in which grain traders pledged not to buy soy from deforested lands, and reduced deforestation without “leakage.”

      Also, intriguingly, a 2008 policy change in the Brazilian Amazon made agricultural credit harder to obtain by requiring recipients to comply with environmental and land registration rules. The result? Deforestation dropped by up to 60 percent over nearly a decade. 

      Politics and pulp

      Overall, Balboni and Olken observe, beyond “externalities,” two major challenges exist. One, it is often unclear who holds property rights in forests. In these circumstances, deforestation seems to increase. Two, deforestation is subject to political battles.

      For instance, as economist Bard Harstad of Stanford University has observed, environmental lobbying is asymmetric. Balboni and Olken write: “The conservationist lobby must pay the government in perpetuity … while the deforestation-oriented lobby need pay only once to deforest in the present.” And political instability leads to more deforestation because “the current administration places lower value on future conservation payments.”

      Even so, national political measures can work. In the Amazon from 2001 to 2005, Brazilian deforestation rates were three to four times higher than on similar land across the border, but that imbalance vanished once the country passed conservation measures in 2006. However, deforestation ramped up again after a 2014 change in government. Looking at particular monitoring approaches, a study of Brazil’s satellite-based Real-Time System for Detection of Deforestation (DETER), launched in 2004, suggests that a 50 percent annual increase in its use in municipalities created a 25 percent reduction in deforestation from 2006 to 2016.

      How precisely politics matters may depend on the context. In a 2021 paper, Balboni and Olken (with three colleagues) found that deforestation actually decreased around elections in Indonesia. Conversely, in Brazil, one study found that deforestation rates were 8 to 10 percent higher where mayors were running for re-election between 2002 and 2012, suggesting incumbents had deforestation industry support.

      “The research there is aiming to understand what the political economy drivers are,” Olken says, “with the idea that if you understand those things, reform in those countries is more likely.”

      Looking ahead, Balboni and Olken also suggest that new research estimating the value of intact forest land intact could influence public debates. And while many scholars have studied deforestation in Brazil and Indonesia, fewer have examined the Democratic Republic of Congo, another deforestation leader, and sub-Saharan Africa.

      Deforestation is an ongoing crisis. But thanks to satellites and many recent studies, experts know vastly more about the problem than they did a decade or two ago, and with an economics toolkit, can evaluate the incentives and dynamics at play.

      “To the extent that there’s ambuiguity across different contexts with different findings, part of the point of our review piece is to draw out common themes — the important considerations in determining which policy levers can [work] in different circumstances,” Balboni says. “That’s a fast-evolving area. We don’t have all the answers, but part of the process is bringing together growing evidence about [everything] that affects how successful those choices can be.” More

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      in Energy

      Jackson Jewett wants to design buildings that use less concrete

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      After three years leading biking tours through U.S. National Parks, Jackson Jewett decided it was time for a change.

      “It was a lot of fun, but I realized I missed buildings,” says Jewett. “I really wanted to be a part of that industry, learn more about it, and reconnect with my roots in the built environment.”

      Jewett grew up in California in what he describes as a “very creative household.”

      “I remember making very elaborate Halloween costumes with my parents, making fun dioramas for school projects, and building forts in the backyard, that kind of thing,” Jewett explains.

      Both of his parents have backgrounds in design; his mother studied art in college and his father is a practicing architect. From a young age, Jewett was interested in following in his father’s footsteps. But when he arrived at the University of California at Berkeley in the midst of the 2009 housing crash, it didn’t seem like the right time. Jewett graduated with a degree in cognitive science and a minor in history of architecture. And even as he led tours through Yellowstone, the Grand Canyon, and other parks, buildings were in the back of his mind.

      It wasn’t just the built environment that Jewett was missing. He also longed for the rigor and structure of an academic environment.

      Jewett arrived at MIT in 2017, initially only planning on completing the master’s program in civil and environmental engineering. It was then that he first met Josephine Carstensen, a newly hired lecturer in the department. Jewett was interested in Carstensen’s work on “topology optimization,” which uses algorithms to design structures that can achieve their performance requirements while using only a limited amount of material. He was particularly interested in applying this approach to concrete design, and he collaborated with Carstensen to help demonstrate its viability.

      After earning his master’s, Jewett spent a year and a half as a structural engineer in New York City. But when Carstensen was hired as a professor, she reached out to Jewett about joining her lab as a PhD student. He was ready for another change.

      Now in the third year of his PhD program, Jewett’s dissertation work builds upon his master’s thesis to further refine algorithms that can design building-scale concrete structures that use less material, which would help lower carbon emissions from the construction industry. It is estimated that the concrete industry alone is responsible for 8 percent of global carbon emissions, so any efforts to reduce that number could help in the fight against climate change.

      Implementing new ideas

      Topology optimization is a small field, with the bulk of the prior work being computational without any experimental verification. The work Jewett completed for his master’s thesis was just the start of a long learning process.

      “I do feel like I’m just getting to the part where I can start implementing my own ideas without as much support as I’ve needed in the past,” says Jewett. “In the last couple of months, I’ve been working on a reinforced concrete optimization algorithm that I hope will be the cornerstone of my thesis.”

      The process of fine-tuning a generative algorithm is slow going, particularly when tackling a multifaceted problem.

      “It can take days or usually weeks to take a step toward making it work as an entire integrated system,” says Jewett. “The days when that breakthrough happens and I can see the algorithm converging on a solution that makes sense — those are really exciting moments.”

      By harnessing computational power, Jewett is searching for materially efficient components that can be used to make up structures such as bridges or buildings. These are other constraints to consider as well, particularly ensuring that the cost of manufacturing isn’t too high. Having worked in the industry before starting the PhD program, Jewett has an eye toward doing work that can be feasibly implemented.

      Inspiring others

      When Jewett first visited MIT campus, he was drawn in by the collaborative environment of the institute and the students’ drive to learn. Now, he’s a part of that process as a teaching assistant and a supervisor in the Undergraduate Research Opportunities Program.  

      Working as a teaching assistant isn’t a requirement for Jewett’s program, but it’s been one of his favorite parts of his time at MIT.

      “The MIT undergrads are so gifted and just constantly impress me,” says Jewett. “Being able to teach, especially in the context of what MIT values is a lot of fun. And I learn, too. My coding practices have gotten so much better since working with undergrads here.”

      Jewett’s experiences have inspired him to pursue a career in academia after the completion of his program, which he expects to complete in the spring of 2025. But he’s making sure to take care of himself along the way. He still finds time to plan cycling trips with his friends and has gotten into running ever since moving to Boston. So far, he’s completed two marathons.

      “It’s so inspiring to be in a place where so many good ideas are just bouncing back and forth all over campus,” says Jewett. “And on most days, I remember that and it inspires me. But it’s also the case that academics is hard, PhD programs are hard, and MIT — there’s pressure being here, and sometimes that pressure can feel like it’s working against you.”

      Jewett is grateful for the mental health resources that MIT provides students. While he says it can be imperfect, it’s been a crucial part of his journey.

      “My PhD thesis will be done in 2025, but the work won’t be done. The time horizon of when these things need to be implemented is relatively short if we want to make an impact before global temperatures have already risen too high. My PhD research will be developing a framework for how that could be done with concrete construction, but I’d like to keep thinking about other materials and construction methods even after this project is finished.” More

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      in Environment

      Harnessing hydrogen’s potential to address long-haul trucking emissions

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      The transportation of goods forms the basis of today’s globally distributed supply chains, and long-haul trucking is a central and critical link in this complex system. To meet climate goals around the world, it is necessary to develop decarbonized solutions to replace diesel powertrains, but given trucking’s indispensable and vast role, these solutions must be both economically viable and practical to implement. While hydrogen-based options, as an alternative to diesel, have the potential to become a promising decarbonization strategy, hydrogen has significant limitations when it comes to delivery and refueling.These roadblocks, combined with hydrogen’s compelling decarbonization potential, are what motivated a team of MIT researchers led by William H. Green, the Hoyt Hottel Professor in Chemical Engineering, to explore a cost-effective way to transport and store hydrogen using liquid organic hydrogen carriers (LOHCs). The team is developing a disruptive technology that allows LOHCs to not only deliver the hydrogen to the trucks, but also store the hydrogen onboard.Their findings were recently published in Energy and Fuels, a peer-reviewed journal of the American Chemical Society, in a paper titled “Perspective on Decarbonizing Long-Haul Trucks Using Onboard Dehydrogenation of Liquid Organic Hydrogen Carriers.” The MIT team is led by Green, and includes graduate students Sayandeep Biswas and Kariana Moreno Sader. Their research is supported by the MIT Climate and Sustainability Consortium (MCSC) through its Seed Awards program and MathWorks, and ties into the work within the MCSC’s Tough Transportation Modes focus area.An “onboard” approachCurrently, LOHCs, which work within existing retail fuel distribution infrastructure, are used to deliver hydrogen gas to refueling stations, where it is then compressed and delivered onto trucks equipped with hydrogen fuel cell or combustion engines.“This current approach incurs significant energy loss due to endothermic hydrogen release and compression at the retail station” says Green. “To address this, our work is exploring a more efficient application, with LOHC-powered trucks featuring onboard dehydrogenation.”To implement such a design, the team aims to modify the truck’s powertrain (the system inside a vehicle that produces the energy to propel it forward) to allow onboard hydrogen release from the LOHCs, using waste heat from the engine exhaust to power the “dehydrogenation” process. 

      Proposed process flow diagram for onboard dehydrogenation. Component sizes are not to scale and have been enlarged for illustrative purposes.

      Image courtesy of the Green Group.

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      The dehydrogenation process happens within a high-temperature reactor, which continually receives hydrogen-rich LOHCs from the fuel storage tank. Hydrogen released from the reactor is fed to the engine, after passing through a separator to remove any lingering LOHC. On its way to the engine, some of the hydrogen gets diverted to a burner to heat the reactor, which helps to augment the reactor heating provided by the engine exhaust gases.Acknowledging and addressing hydrogen’s drawbacksThe team’s paper underscores that current uses of hydrogen, including LOHC systems, to decarbonize the trucking sector have drawbacks. Regardless of technical improvements, these existing options remain prohibitively expensive due to the high cost of retail hydrogen delivery.“We present an alternative option that addresses a lot of the challenges and seems to be a viable way in which hydrogen can be used in this transportation context,” says Biswas, who was recently elected to the MIT Martin Family Society of Fellows for Sustainability for his work in this area. “Hydrogen, when used through LOHCs, has clear benefits for long-hauling, such as scalability and fast refueling time. There is also an enormous potential to improve delivery and refueling to further reduce cost, and our system is working to do that.”“Utilizing hydrogen is an option that is globally accessible, and could be extended to countries like the one where I am from,” says Moreno Sader, who is originally from Colombia. “Since it synergizes with existing infrastructure, large upfront investments are not necessary. The global applicability is huge.”Moreno Sader is a MathWorks Fellow, and, along with the rest of the team, has been using MATLAB tools to develop models and simulations for this work.Different sectors coming togetherDecarbonizing transportation modes, including long-haul trucking, requires expertise and perspectives from different industries — an approach that resonates with the MCSC’s mission.The team’s groundbreaking research into LOHC-powered trucking is among several projects supported by the MCSC within its Tough Transportation Modes focus area, led by postdoc Impact Fellow Danika MacDonell. The MCSC-supported projects were chosen to tackle a complementary set of societally important and industry-relevant challenges to decarbonizing heavy-duty transportation, which span a range of sectors and solution pathways. Other projects focus, for example, on logistics optimization for electrified trucking fleets, or air quality and climate impacts of ammonia-powered shipping.The MCSC works to support and amplify the impact of these projects by engaging the research teams with industry partners from a variety of sectors. In addition, the MCSC pursues a collective multisectoral approach to decarbonizing transportation by facilitating shared learning across the different projects through regular cross-team discussion.The research led by Green celebrates this cross-sector theme by integrating industry-leading computing tools provided by MathWorks with cutting-edge developments in chemical engineering, as well as industry-leading commercial LOHC reactor demonstrations, to build a compelling vision for cost-effective LOHC-powered trucking.The review and research conducted in the Energy and Fuels article lays the groundwork for further investigations into LOHC-powered truck design. The development of such a vehicle — with a power-dense, efficient, and robust onboard hydrogen release system — requires dedicated investigations and further optimization of core components geared specifically toward the trucking application. More

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      in Environment

      Technologies for water conservation and treatment move closer to commercialization

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      The Abdul Latif Jameel Water and Food Systems Lab (J-WAFS) provides Solutions Grants to help MIT researchers launch startup companies or products to commercialize breakthrough technologies in water and food systems. The Solutions Grant Program began in 2015 and is supported by Community Jameel. In addition to one-year, renewable grants of up to $150,000, the program also matches grantees with industry mentors and facilitates introductions to potential investors. Since its inception, the J-WAFS Solutions Program has awarded over $3 million in funding to the MIT community. Numerous startups and products, including a portable desalination device and a company commercializing a novel food safety sensor, have spun out of this support.

      The 2023 J-WAFS Solutions Grantees are Professor C. Cem Tasan of the Department of Materials Science and Engineering and Professor Andrew Whittle of the Department of Civil and Environmental Engineering. Tasan’s project involves reducing water use in steel manufacturing and Whittle’s project tackles harmful algal blooms in water. Project work commences this September.

      “This year’s Solutions Grants are being award to professors Tasan and Whittle to help commercialize technologies they have been developing at MIT,” says J-WAFS executive director Renee J. Robins. “With J-WAFS’ support, we hope to see the teams move their technologies from the lab to the market, so they can have a beneficial impact on water use and water quality challenges,” Robins adds.

      Reducing water consumption by solid-state steelmaking

      Water is a major requirement for steel production. The steel industry ranks fourth in industrial freshwater consumption worldwide, since large amounts of water are needed mainly for cooling purposes in the process. Unfortunately, a strong correlation has also been shown to exist between freshwater use in steelmaking and water contamination. As the global demand for steel increases and freshwater availability decreases due to climate change, improved methods for more sustainable steel production are needed.

      A strategy to reduce the water footprint of steelmaking is to explore steel recycling processes that avoid liquid metal processing. With this motivation, Cem Tasan, the Thomas B. King Associate Professor of Metallurgy in the Department of Materials Science and Engineering, and postdoc Onur Guvenc PhD created a new process called Scrap Metal Consolidation (SMC). SMC is based on a well-established metal forming process known as roll bonding. Conventionally, roll bonding requires intensive prior surface treatment of the raw material, specific atmospheric conditions, and high deformation levels. Tasan and Guvenc’s research revealed that SMC can overcome these restrictions by enabling the solid-state bonding of scrap into a sheet metal form, even when the surface quality, atmospheric conditions, and deformation levels are suboptimal. Through lab-scale proof-of-principle investigations, they have already identified SMC process conditions and validated the mechanical formability of resulting steel sheets, focusing on mild steel, the most common sheet metal scrap.

      The J-WAFS Solutions Grant will help the team to build customer product prototypes, design the processing unit, and develop a scale-up strategy and business model. By simultaneously decreasing water usage, energy demand, contamination risk, and carbon dioxide burden, SMC has the potential to decrease the energy need for steel recycling by up to 86 percent, as well as reduce the linked carbon dioxide emissions and safeguard the freshwater resources that would otherwise be directed to industrial consumption. 

      Detecting harmful algal blooms in water before it’s too late

      Harmful algal blooms (HABs) are a growing problem in both freshwater and saltwater environments worldwide, causing an estimated $13 billion in annual damage to drinking water, water for recreational use, commercial fishing areas, and desalination activities. HABs pose a threat to both human health and aquaculture, thereby threatening the food supply. Toxins in HABs are produced by some cyanobacteria, or blue-green algae, whose communities change in composition in response to eutrophication from agricultural runoff, sewer overflows, or other events. Mitigation of risks from HABs are most effective when there is advance warning of these changes in algal communities. 

      Most in situ measurements of algae are based on fluorescence spectroscopy that is conducted with LED-induced fluorescence (LEDIF) devices, or probes that induce fluorescence of specific algal pigments using LED light sources. While LEDIFs provide reasonable estimates of concentrations of individual pigments, they lack resolution to discriminate algal classes within complex mixtures found in natural water bodies. In prior research, Andrew Whittle, the Edmund K. Turner Professor of Civil and Environmental Engineering, worked with colleagues to design REMORA, a low-cost, field-deployable prototype spectrofluorometer for measuring induced fluorescence. This research was part of a collaboration between MIT and the AMS Institute. Whittle and the team successfully trained a machine learning model to discriminate and quantify cell concentrations for mixtures of different algal groups in water samples through an extensive laboratory calibration program using various algae cultures. The group demonstrated these capabilities in a series of field measurements at locations in Boston and Amsterdam. 

      Whittle will work with Fábio Duarte of the Department of Urban Studies and Planning, the Senseable City Lab, and MIT’s Center for Real Estate to refine the design of REMORA. They will develop software for autonomous operation of the sensor that can be deployed remotely on mobile vessels or platforms to enable high-resolution spatiotemporal monitoring for harmful algae. Sensor commercialization will hopefully be able to exploit the unique capabilities of REMORA for long-term monitoring applications by water utilities, environmental regulatory agencies, and water-intensive industries.  More

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      in Energy

      Study suggests energy-efficient route to capturing and converting CO2

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      In the race to draw down greenhouse gas emissions around the world, scientists at MIT are looking to carbon-capture technologies to decarbonize the most stubborn industrial emitters.

      Steel, cement, and chemical manufacturing are especially difficult industries to decarbonize, as carbon and fossil fuels are inherent ingredients in their production. Technologies that can capture carbon emissions and convert them into forms that feed back into the production process could help to reduce the overall emissions from these “hard-to-abate” sectors.

      But thus far, experimental technologies that capture and convert carbon dioxide do so as two separate processes, that themselves require a huge amount of energy to run. The MIT team is looking to combine the two processes into one integrated and far more energy-efficient system that could potentially run on renewable energy to both capture and convert carbon dioxide from concentrated, industrial sources.

      In a study appearing today in ACS Catalysis, the researchers reveal the hidden functioning of how carbon dioxide can be both captured and converted through a single electrochemical process. The process involves using an electrode to attract carbon dioxide released from a sorbent, and to convert it into a reduced, reusable form.

      Others have reported similar demonstrations, but the mechanisms driving the electrochemical reaction have remained unclear. The MIT team carried out extensive experiments to determine that driver, and found that, in the end, it came down to the partial pressure of carbon dioxide. In other words, the more pure carbon dioxide that makes contact with the electrode, the more efficiently the electrode can capture and convert the molecule.

      Knowledge of this main driver, or “active species,” can help scientists tune and optimize similar electrochemical systems to efficiently capture and convert carbon dioxide in an integrated process.

      The study’s results imply that, while these electrochemical systems would probably not work for very dilute environments (for instance, to capture and convert carbon emissions directly from the air), they would be well-suited to the highly concentrated emissions generated by industrial processes, particularly those that have no obvious renewable alternative.

      “We can and should switch to renewables for electricity production. But deeply decarbonizing industries like cement or steel production is challenging and will take a longer time,” says study author Betar Gallant, the Class of 1922 Career Development Associate Professor at MIT. “Even if we get rid of all our power plants, we need some solutions to deal with the emissions from other industries in the shorter term, before we can fully decarbonize them. That’s where we see a sweet spot, where something like this system could fit.”

      The study’s MIT co-authors are lead author and postdoc Graham Leverick and graduate student Elizabeth Bernhardt, along with Aisyah Illyani Ismail, Jun Hui Law, Arif Arifutzzaman, and Mohamed Kheireddine Aroua of Sunway University in Malaysia.

      Breaking bonds

      Carbon-capture technologies are designed to capture emissions, or “flue gas,” from the smokestacks of power plants and manufacturing facilities. This is done primarily using large retrofits to funnel emissions into chambers filled with a “capture” solution — a mix of amines, or ammonia-based compounds, that chemically bind with carbon dioxide, producing a stable form that can be separated out from the rest of the flue gas.

      High temperatures are then applied, typically in the form of fossil-fuel-generated steam, to release the captured carbon dioxide from its amine bond. In its pure form, the gas can then be pumped into storage tanks or underground, mineralized, or further converted into chemicals or fuels.

      “Carbon capture is a mature technology, in that the chemistry has been known for about 100 years, but it requires really large installations, and is quite expensive and energy-intensive to run,” Gallant notes. “What we want are technologies that are more modular and flexible and can be adapted to more diverse sources of carbon dioxide. Electrochemical systems can help to address that.”

      Her group at MIT is developing an electrochemical system that both recovers the captured carbon dioxide and converts it into a reduced, usable product. Such an integrated system, rather than a decoupled one, she says, could be entirely powered with renewable electricity rather than fossil-fuel-derived steam.

      Their concept centers on an electrode that would fit into existing chambers of carbon-capture solutions. When a voltage is applied to the electrode, electrons flow onto the reactive form of carbon dioxide and convert it to a product using protons supplied from water. This makes the sorbent available to bind more carbon dioxide, rather than using steam to do the same.

      Gallant previously demonstrated this electrochemical process could work to capture and convert carbon dioxide into a solid carbonate form.

      “We showed that this electrochemical process was feasible in very early concepts,” she says. “Since then, there have been other studies focused on using this process to attempt to produce useful chemicals and fuels. But there’s been inconsistent explanations of how these reactions work, under the hood.”

      Solo CO2

      In the new study, the MIT team took a magnifying glass under the hood to tease out the specific reactions driving the electrochemical process. In the lab, they generated amine solutions that resemble the industrial capture solutions used to extract carbon dioxide from flue gas. They methodically altered various properties of each solution, such as the pH, concentration, and type of amine, then ran each solution past an electrode made from silver — a metal that is widely used in electrolysis studies and known to efficiently convert carbon dioxide to carbon monoxide. They then measured the concentration of carbon monoxide that was converted at the end of the reaction, and compared this number against that of every other solution they tested, to see which parameter had the most influence on how much carbon monoxide was produced.

      In the end, they found that what mattered most was not the type of amine used to initially capture carbon dioxide, as many have suspected. Instead, it was the concentration of solo, free-floating carbon dioxide molecules, which avoided bonding with amines but were nevertheless present in the solution. This “solo-CO2” determined the concentration of carbon monoxide that was ultimately produced.

      “We found that it’s easier to react this ‘solo’ CO2, as compared to CO2 that has been captured by the amine,” Leverick offers. “This tells future researchers that this process could be feasible for industrial streams, where high concentrations of carbon dioxide could efficiently be captured and converted into useful chemicals and fuels.”

      “This is not a removal technology, and it’s important to state that,” Gallant stresses. “The value that it does bring is that it allows us to recycle carbon dioxide some number of times while sustaining existing industrial processes, for fewer associated emissions. Ultimately, my dream is that electrochemical systems can be used to facilitate mineralization, and permanent storage of CO2 — a true removal technology. That’s a longer-term vision. And a lot of the science we’re starting to understand is a first step toward designing those processes.”

      This research is supported by Sunway University in Malaysia. More

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      in Environment

      New clean air and water labs to bring together researchers, policymakers to find climate solutions

      by

      MIT’s Abdul Latif Jameel Poverty Action Lab (J-PAL) is launching the Clean Air and Water Labs, with support from Community Jameel, to generate evidence-based solutions aimed at increasing access to clean air and water.

      Led by J-PAL’s Africa, Middle East and North Africa (MENA), and South Asia regional offices, the labs will partner with government agencies to bring together researchers and policymakers in areas where impactful clean air and water solutions are most urgently needed.

      Together, the labs aim to improve clean air and water access by informing the scaling of evidence-based policies and decisions of city, state, and national governments that serve nearly 260 million people combined.

      The Clean Air and Water Labs expand the work of J-PAL’s King Climate Action Initiative, building on the foundational support of King Philanthropies, which significantly expanded J-PAL’s work at the nexus of climate change and poverty alleviation worldwide. 

      Air pollution, water scarcity and the need for evidence 

      Africa, MENA, and South Asia are on the front lines of global air and water crises. 

      “There is no time to waste investing in solutions that do not achieve their desired effects,” says Iqbal Dhaliwal, global executive director of J-PAL. “By co-generating rigorous real-world evidence with researchers, policymakers can have the information they need to dedicate resources to scaling up solutions that have been shown to be effective.”

      In India, about 75 percent of households did not have drinking water on premises in 2018. In MENA, nearly 90 percent of children live in areas facing high or extreme water stress. Across Africa, almost 400 million people lack access to safe drinking water. 

      Simultaneously, air pollution is one of the greatest threats to human health globally. In India, extraordinary levels of air pollution are shortening the average life expectancy by five years. In Africa, rising indoor and ambient air pollution contributed to 1.1 million premature deaths in 2019. 

      There is increasing urgency to find high-impact and cost-effective solutions to the worsening threats to human health and resources caused by climate change. However, data and evidence on potential solutions are limited.

      Fostering collaboration to generate policy-relevant evidence 

      The Clean Air and Water Labs will foster deep collaboration between government stakeholders, J-PAL regional offices, and researchers in the J-PAL network. 

      Through the labs, J-PAL will work with policymakers to:

      co-diagnose the most pressing air and water challenges and opportunities for policy innovation;
      expand policymakers’ access to and use of high-quality air and water data;
      co-design potential solutions informed by existing evidence;
      co-generate evidence on promising solutions through rigorous evaluation, leveraging existing and new data sources; and
      support scaling of air and water policies and programs that are found to be effective through evaluation. 
      A research and scaling fund for each lab will prioritize resources for co-generated pilot studies, randomized evaluations, and scaling projects. 

      The labs will also collaborate with C40 Cities, a global network of mayors of the world’s leading cities that are united in action to confront the climate crisis, to share policy-relevant evidence and identify opportunities for potential new connections and research opportunities within India and across Africa.

      This model aims to strengthen the use of evidence in decision-making to ensure solutions are highly effective and to guide research to answer policymakers’ most urgent questions. J-PAL Africa, MENA, and South Asia’s strong on-the-ground presence will further bridge research and policy work by anchoring activities within local contexts. 

      “Communities across the world continue to face challenges in accessing clean air and water, a threat to human safety that has only been exacerbated by the climate crisis, along with rising temperatures and other hazards,” says George Richards, director of Community Jameel. “Through our collaboration with J-PAL and C40 in creating climate policy labs embedded in city, state, and national governments in Africa and South Asia, we are committed to innovative and science-based approaches that can help hundreds of millions of people enjoy healthier lives.”

      J-PAL Africa, MENA, and South Asia will formally launch Clean Air and Water Labs with government partners over the coming months. J-PAL is housed in the MIT Department of Economics, within the School of Humanities, Arts, and Social Sciences. More