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      in Energy

      Building communities, founding a startup with people in mind

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      MIT postdoc Francesco Benedetti admits he wasn’t always a star student. But the people he met along his educational journey inspired him to strive, which led him to conduct research at MIT, launch a startup, and even lead the team that won the 2021 MIT $100K Entrepreneurship Competition. Now he is determined to make sure his company, Osmoses, succeeds in boosting the energy efficiency of traditional and renewable natural gas processing, hydrogen production, and carbon capture — thus helping to address climate change.

      “I can’t be grateful enough to MIT for bringing together a community of people who want to change the world,” Benedetti says. “Now we have a technology that can solve one of the big problems of our society.”

      Benedetti and his team have developed an innovative way to separate molecules using a membrane fine enough to extract impurities such as carbon dioxide or hydrogen sulfide from raw natural gas to obtain higher-quality fuel, fulfilling a crucial need in the energy industry. “Natural gas now provides about 40 percent of the energy used to power homes and industry in the United States,” Benedetti says. Using his team’s technology to upgrade natural gas more efficiently could reduce emissions of greenhouse gases while saving enough energy to power the equivalent of 7 million additional U.S. homes for a year, he adds.

      The MIT community

      Benedetti first came to MIT in 2017 as a visiting student from the University of Bologna in Italy, where he was working on membranes for gas separation for his PhD in chemical engineering. Having completed a master’s thesis on water desalination at the University of Texas (UT) at Austin, he connected with UT alumnus Zachary P. Smith, the Robert N. Noyce Career Development Professor of Chemical Engineering at MIT, and the two discovered they shared a vision. “We found ourselves very much aligned on the need for new technology in industry to lower the energy consumption of separating components,” Benedetti says.

      Although Benedetti had always been interested in making a positive impact on the world, particularly the environment, he says it was his university studies that first sparked his interest in more efficient separation technologies. “When you study chemical engineering, you understand hundreds of ways the field can have a positive impact in the world. But we learn very early that 15 percent of the world’s energy is wasted because of inefficient chemical separation — because we still rely on centuries-old technology,” he says. Most separation processes still use heat or toxic solvents to separate components, he explains.

      Still, Benedetti says, his main drive comes from the joy of working with terrific mentors and colleagues. “It’s the people I’ve met that really inspired me to tackle the biggest challenges and find that intrinsic motivation,” he says.

      To help build his community at MIT and provide support for international students, Benedetti co-founded the MIT Visiting Student Association (VISTA) in September 2017. By February 2018, the organization had hundreds of members and official Institute recognition. In May 2018, the group won two Institute awards, including the Golden Beaver Award for enhancing the campus environment. “VISTA gave me a sense of belonging; I loved it,” Benedetti says.

      Membrane technology

      Benedetti also published two papers on membrane research during his stint as a visiting student at MIT, so he was delighted to return in 2019 for postdoctoral work through the MIT Energy Initiative, where he was a 2019-20 ExxonMobil-MIT Energy Fellow. “I came back because the research was extremely exciting, but also because I got extremely passionate about the energy I found on campus and with the people,” he says.

      Returning to MIT enabled Benedetti to continue his work with Smith and Holden Lai, both of whom helped co-found Osmoses. Lai, a recent Stanford PhD in chemistry who was also a visiting student at MIT in 2018, is now the chief technology officer at Osmoses. Co-founder Katherine Mizrahi Rodriguez ’17, an MIT PhD candidate, joined the team more recently.

      Together, the Osmoses team has developed polymer membranes with microporosities capable of filtering gases by separating out molecules that differ by as little as a fraction of an angstrom — a unit of length equal to one hundred-millionth of a centimeter. “We can get up to five times higher selectivity than commercially available technology for methane upgrading, and this has been observed operating the membranes in industrially relevant environments,” Benedetti says.

      Today, methane upgrading — removing carbon dioxide (CO2) from raw natural gas to obtain a higher-grade fuel — is often accomplished using amine absorption, a process that uses toxic solvents to capture CO2 and burns methane to fuel the regeneration of those solvents for reuse. Using Osmoses’ filters would eliminate the need for such solvents while reducing CO2 emissions by up to 16 million metric tons per year in the United States alone, Benedetti says.

      The technology has a wide range of applications — in oxygen and nitrogen generation, hydrogen purification, and carbon capture, for example — but Osmoses plans to start with the $5 billion market for natural gas upgrading because the need to bring innovation and sustainability to that space is urgent, says Benedetti, who received guidance in bringing technology to market from MIT’s Deshpande Center for Technological Innovation. The Osmoses team has also received support from the MIT Sandbox Innovation Fund Program.

      The next step for the startup is to build an industrial-scale prototype, and Benedetti says the company got a huge boost toward that goal in May when it won the MIT $100K Entrepreneurship Competition, a student-run contest that has launched more than 160 companies since it began in 1990. Ninety teams began the competition by pitching their startup ideas; 20 received mentorship and development funding; then eight finalists presented business plans to compete for the $100,000 prize. “Because of this, we’re getting a lot of interest from venture capital firms, investors, companies, corporate funds, et cetera, that want to partner with us or to use our product,” he says. In June, the Osmoses team received a two-year Activate Fellowship, which will support moving its research to market; in October, it won the Northeast Regional and Carbon Sequestration Prizes at the Cleantech Open Accelerator; and in November, the team closed a $3 million pre-seed round of financing.

      FAIL!

      Naturally, Benedetti hopes Osmoses is on the path to success, but he wants everyone to know that there is no shame in failures that come from best efforts. He admits it took him three years longer than usual to finish his undergraduate and master’s degrees, and he says, “I have experienced the pressure you feel when society judges you like a book by its cover and how much a lack of inspired leaders and a supportive environment can kill creativity and the will to try.”

      That’s why in 2018 he, along with other MIT students and VISTA members, started FAIL!–Inspiring Resilience, an organization that provides a platform for sharing unfiltered stories and the lessons leaders have gleaned from failure. “We wanted to help de-stigmatize failure, appreciate vulnerabilities, and inspire humble leadership, eventually creating better communities,” Benedetti says. “If we can make failures, big and small, less intimidating and all-consuming, individuals with great potential will be more willing to take risks, think outside the box, and try things that may push new boundaries. In this way, more breakthrough discoveries are likely to follow, without compromising anyone’s mental health.”

      Benedetti says he will strive to create a supportive culture at Osmoses, because people are central to success. “What drives me every day is the people. I would have no story without the people around me,” he says. “The moment you lose touch with people, you lose the opportunity to create something special.”

      This article appears in the Autumn 2021 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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      in Energy

      Tuning in to invisible waves on the JET tokamak

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      Research scientist Alex Tinguely is readjusting to Cambridge and Boston.

      As a postdoc with the Plasma Science and Fusion Center (PSFC), the MIT graduate spent the last two years in Oxford, England, a city he recalls can be traversed entirely “in the time it takes to walk from MIT to Harvard.” With its ancient stone walls, cathedrals, cobblestone streets, and winding paths, that small city was his home base for a big project: JET, a tokamak that is currently the largest operating magnetic fusion energy experiment in the world.

      Located at the Culham Center for Fusion Energy (CCFE), part of the U.K. Atomic Energy Authority, this key research center of the European Fusion Program has recently announced historic success. Using a 50-50 deuterium-tritium fuel mixture for the first time since 1997, JET established a fusion power record of 10 megawatts output over five seconds. It produced 59 megajoules of fusion energy, more than doubling the 22 megajoule record it set in 1997. As a member of the JET Team, Tinguely has overseen the measurement and instrumentation systems (diagnostics) contributed by the MIT group.

      A lucky chance

      The postdoctoral opportunity arose just as Tinguely was graduating with a PhD in physics from MIT. Managed by Professor Miklos Porkolab as the principal investigator for over 20 years, this postdoctoral program has prepared multiple young researchers for careers in fusion facilities around the world. The collaborative research provided Tinguely the chance to work on a fusion device that would be adding tritium to the usual deuterium fuel.

      Fusion, the process that fuels the sun and other stars, could provide a long-term source of carbon-free power on Earth, if it can be harnessed. For decades researchers have tried to create an artificial star in a doughnut-shaped bottle, or “tokamak,” using magnetic fields to keep the turbulent plasma fuel confined and away from the walls of its container long enough for fusion to occur.

      In his graduate student days at MIT, Tinguely worked on the PSFC’s Alcator C-Mod tokamak, now decommissioned, which, like most magnetic fusion devices, used deuterium to create the plasmas for experiments. JET, since beginning operation in 1983, has done the same, later joining a small number of facilities that added tritium, a radioactive isotope of hydrogen. While this addition increases the amount of fusion, it also creates much more radiation and activation.

      Tinguely considers himself fortunate to have been placed at JET.

      “There aren’t that many operating tokamaks in the U.S. right now,” says Tinguely, “not to mention one that would be running deuterium-tritium (DT), which hasn’t been run for over 20 years, and which would be making some really important measurements. I got a very lucky spot where I was an MIT postdoc, but I lived in Oxford, working on a very international project.”

      Strumming magnetic field lines

      The measurements that interest Tinguely are of low-frequency electromagnetic waves in tokamak plasmas. Tinguely uses an antenna diagnostic developed by MIT, EPFL Swiss Plasma Center, and CCFE to probe the so-called Alfvén eigenmodes when they are stable, before the energetic alpha particles produced by DT fusion plasmas can drive them toward instability.

      What makes MIT’s “Alfvén Eigenmode Active Diagnostic” essential is that without it researchers cannot see, or measure, stable eigenmodes. Unstable modes show up clearly as magnetic fluctuations in the data, but stable waves are invisible without prompting from the antenna. These measurements help researchers understand the physics of Alfvén waves and their potential for degrading fusion performance, providing insights that will be increasingly important for future DT fusion devices.

      Tinguely likens the diagnostic to fingers on guitar strings.

      “The magnetic field lines in the tokamak are like guitar strings. If you have nothing to give energy to the strings — or give energy to the waves of the magnetic field lines — they just sit there, they don’t do anything. The energetic plasma particles can essentially ‘play the guitar strings,’ strum the magnetic field lines of the plasma, and that’s when you can see the waves in your plasma. But if the energetic particle drive of the waves is not strong enough you won’t see them, so you need to come along and ‘pluck the strings’ with our antenna. And that’s how you learn some information about the waves.”

      Much of Tinguely’s experience on JET took place during the Covid-19 pandemic, when off-site operation and analysis were the norm. However, because the MIT diagnostic needed to be physically turned on and off, someone from Tinguely’s team needed to be on site twice a day, a routine that became even less convenient when tritium was introduced.

      “When you have deuterium and tritium, you produce a lot of neutrons. So, some of the buildings became off-limits during operation, which meant they had to be turned on really early in the morning, like 6:30 a.m., and then turned off very late at night, around 10:30 p.m.”

      Looking to the future

      Now a research scientist at the PSFC, Tinguely continues to work at JET remotely. He sometimes wishes he could again ride that train from Oxford to Culham — which he fondly remembers for its clean, comfortable efficiency — to see work colleagues and to visit local friends. The life he created for himself in England included practice and performance with the 125-year-old Oxford Bach Choir, as well as weekly dinner service at The Gatehouse, a facility that offers free support for the local homeless and low-income communities.

      “Being back is exciting too,” he says. “It’s fun to see how things have changed, how people and projects have grown, what new opportunities have arrived.”

      He refers specifically to a project that is beginning to take up more of his time: SPARC, the tokamak the PSFC supports in collaboration with Commonwealth Fusion Systems. Designed to use deuterium-tritium to make net fusion gains, SPARC will be able to use the latest research on JET to advantage. Tinguely is already exploring how his expertise with Alfvén eigenmodes can support the experiment.

      “I actually had an opportunity to do my PhD — or DPhil as they would call it — at Oxford University, but I went to MIT for grad school instead,” Tinguely reveals. “So, this is almost like closure, in a sense. I got to have my Oxford experience in the end, just in a different way, and have the MIT experience too.”

      He adds, “And I see myself being here at MIT for some time.” More

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      in Energy

      Nurturing human communities and natural ecosystems

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      When she was in 7th grade, Heidi Li and the five other members of the Oyster Gardening Club cultivated hundreds of oysters to help repopulate the Chesapeake Bay. On the day they released the oysters into the bay, the event attracted TV journalists and local officials, including the governor. The attention opened the young Li’s eyes to the ways that a seemingly small effort in her local community could have a real-world impact.

      “I got to see firsthand how we can make change at a grassroots level and how that impacts where we are,” she says.

      Growing up in Howard County, Maryland, Li was constantly surrounded by nature. Her family made frequent trips to the Chesapeake Bay, as it reminded them of her parent’s home in Shandong, China. Li worked to bridge the cultural gap between parents, who grew up in China, and their children, who grew up in the U.S., and attended Chinese school every Sunday for 12 years. These experiences instilled in her a community-oriented mindset, which Li brought with her to MIT, where she now majors in materials science and engineering.

      During her first year, Li pursued a microbiology research project through the Undergraduate Research Opportunities Program (UROP) in the Department of Civil and Environmental Engineering. She studied microbes in aquatic environments, analyzing how the cleanliness of water impacted immunity and behavioral changes of the marine bacteria.

      The experience led her to consider the ways environmental policy affected sustainability efforts. She began applying the problem to energy, asking herself questions such as, “How can you take this specific economic principle and apply it to energy? What has energy policy looked like in the past and how can we tailor that to apply to our current energy system?”

      To explore the intersection of policy and energy, Li participated in the Roosevelt Project, through the Center of Energy and Environmental Policy Research, during the summer after her junior year. The project used case studies targeting specific communities in vulnerable areas to propose methods for a more sustainable future. Li focused on Pittsburgh, Pennsylvania, evaluating the efficiency of an energy transition from natural gas and fossil fuels to carbon-capture, which would mean redistributing the carbon dioxide produced by the coal industry. After traveling to Pittsburgh and interviewing stakeholders in the area, Li watched as local community leaders created physical places for citizens to share their ideas and opinions on the energy transition

      “I watched community leaders create a safe space for people from the surrounding town to share their ideas for entrepreneurship. I saw how important community is and how to create change at a grassroots level,” she says.

      In the summer of 2021, Li pursued an internship through the energy consulting firm Wood Mackenzie, where she looked at technologies that could potentially help with the energy transition from fossil fuels to renewable energy. Her job was to make sure the technology could be implemented efficiently and cost-effectively, optimizing the resources available to the surrounding area. The project allowed Li to engage with industry-based efforts to chart and analyze the technological advancements for various decarbonization scenarios. She hopes to continue looking at both the local, community-based, and external, industry-based, inputs on how economic policy would affect stakeholders.

      On campus, Li is the current president of the Sustainable Energy Alliance (SEA), where she aims to make students more conscious about climate change and their impact on the environment. During summer of her sophomore year, Li chaired a sustainability hackathon for over 200 high school students, where she designed and led the “Protecting Climate Refugees” and “Tackling Environmental Injustice” challenges to inspire students to think about humanitarian efforts for protecting frontline communities.

      “The whole goal of this is to empower students to think about solutions for themselves. Empowering students is really important to show them they can make change and inspire hope in themselves and the people around them,” she says.

      Li also hosted and produced “Open SEAcrets,” a podcast designed to engage MIT students with topics surrounding energy sustainability and provide them with the opportunity to share their opinions on the subject. She sees the podcast as a platform to raise awareness about energy, climate change, and environmental policy, while also inspiring a sense of community with listeners.

      When she is not in the classroom or the lab, Li relaxes by playing volleyball. She joined the Volleyball Club during her first year at MIT, though she has been playing since she was 12. The sport allows her to not only relieve stress, but also have conversations with both undergrads and graduate students, who bring different their backgrounds, interests, and experiences to conversations. The sport has also taught Li about teamwork, trust, and the importance of community in ways that her other experience doesn’t.

      Looking ahead, Li is currently working on a UROP project, called Climate Action Through Education (CATE), that designs climate change curriculum for K-12 grades and aims to show how climate change and energy are integral to peoples’ daily lives. Seeing the energy transition as an interdisciplinary problem, she wants to educate students about the problems of climate change and sustainability using perspectives from math, science, history, and psychology to name a few areas.

      But above all, Li wants to empower younger generations to develop solution-minded approaches to environmentalism. She hopes to give local communities a voice in policy implementation, with the end goal of a more sustainable future for all.

      “Finding a community you really thrive in will allow you to push yourself and be the best version of yourself you can be. I want to take this mindset and create spaces for people and establish and instill this sense of community,” she says. More

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      in Environment

      Students dive into research with the MIT Climate and Sustainability Consortium

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      Throughout the fall 2021 semester, the MIT Climate and Sustainability Consortium (MCSC) supported several research projects with a climate-and-sustainability topic related to the consortium, through the MIT Undergraduate Research Opportunities Program (UROP). These students, who represent a range of disciplines, had the opportunity to work with MCSC Impact Fellows on topics related directly to the ongoing work and collaborations with MCSC member companies and the broader MIT community, from carbon capture to value-chain resilience to biodegradables. Many of these students are continuing their work this spring semester.

      Hannah Spilman, who is studying chemical engineering, worked with postdoc Glen Junor, an MCSC Impact Fellow, to investigate carbon capture, utilization, and storage (CCUS), with the goal of facilitating CCUS on a gigaton scale, a much larger capacity than what currently exists. “Scientists agree CCUS will be an important tool in combating climate change, but the largest CCUS facility only captures CO2 on a megaton scale, and very few facilities are actually operating,” explains Spilman. 

      Throughout her UROP, she worked on analyzing the currently deployed technology in the CCUS field, using National Carbon Capture Center post-combustion project reports to synthesize the results and outline those technologies. Examining projects like the RTI-NAS experiment, which showcased innovation with carbon capture technology, was especially helpful. “We must first understand where we are, and as we continue to conduct analyses, we will be able to understand the field’s current state and path forward,” she concludes.

      Fellow chemical engineering students Claire Kim and Alfonso Restrepo are working with postdoc and MCSC Impact Fellow Xiangkun (Elvis) Cao, also on investigating CCUS technology. Kim’s focus is on life cycle assessment (LCA), while Restrepo’s focus is on techno-economic assessment (TEA). They have been working together to use the two tools to evaluate multiple CCUS technologies. While LCA and TEA are not new tools themselves, their application in CCUS has not been comprehensively defined and described. “CCUS can play an important role in the flexible, low-carbon energy systems,” says Kim, which was part of the motivation behind her project choice.

      Through TEA, Restrepo has been investigating how various startups and larger companies are incorporating CCUS technology in their processes. “In order to reduce CO2 emissions before it’s too late to act, there is a strong need for resources that effectively evaluate CCUS technology, to understand the effectiveness and viability of emerging technology for future implementation,” he explains. For their next steps, Kim and Restrepo will apply LCA and TEA to the analysis of a specific capture (for example, direct ocean capture) or conversion (for example, CO2-to-fuel conversion) process​ in CCUS.

      Cameron Dougal, a first-year student, and James Santoro, studying management, both worked with postdoc and MCSC Impact Fellow Paloma Gonzalez-Rojas on biodegradable materials. Dougal explored biodegradable packaging film in urban systems. “I have had a longstanding interest in sustainability, with a newer interest in urban planning and design, which motivated me to work on this project,” Dougal says. “Bio-based plastics are a promising step for the future.”

      Dougal spent time conducting internet and print research, as well as speaking with faculty on their relevant work. From these efforts, Dougal has identified important historical context for the current recycling landscape — as well as key case studies and cities around the world to explore further. In addition to conducting more research, Dougal plans to create a summary and statistic sheet.

      Santoro dove into the production angle, working on evaluating the economic viability of the startups that are creating biodegradable materials. “Non-renewable plastics (created with fossil fuels) continue to pollute and irreparably damage our environment,” he says. “As we look for innovative solutions, a key question to answer is how can we determine a more effective way to evaluate the economic viability and probability of success for new startups and technologies creating biodegradable plastics?” The project aims to develop an effective framework to begin to answer this.

      At this point, Santoro has been understanding the overall ecosystem, understanding how these biodegradable materials are developed, and analyzing the economics side of things. He plans to have conversations with company founders, investors, and experts, and identify major challenges for biodegradable technology startups in creating high performance products with attractive unit economics. There is also still a lot to research about new technologies and trends in the industry, the profitability of different products, as well as specific individual companies doing this type of work.

      Tess Buchanan, who is studying materials science and engineering, is working with Katharina Fransen and Sarah Av-Ron, MIT graduate students in the Department of Chemical Engineering, and principal investigator Professor Bradley Olsen, to also explore biodegradables by looking into their development from biomass “This is critical work, given the current plastics sustainability crisis, and the potential of bio-based polymers,” Buchanan says.

      The objective of the project is to explore new sustainable polymers through a biodegradation assay using clear zone growth analysis to yield degradation rates. For next steps, Buchanan is diving into synthesis expansion and using machine learning to understand the relationship between biodegradation and polymer chemistry.

      Kezia Hector, studying chemical engineering, and Tamsin Nottage, a first-year student, working with postdoc and MCSC Impact Fellow Sydney Sroka, explored advancing and establishing sustainable solutions for value chain resilience. Hector’s focus was understanding how wildfires can affect supply chains, specifically identifying sources of economic loss. She reviewed academic literature and news articles, and looked at the Amazon, California, Siberia, and Washington, finding that wildfires cause millions of dollars in damage every year and impact supply chains by cutting off or slowing down freight activity. She will continue to identify ways to make supply chains more resilient and sustainable.

      Nottage focused on the economic impact of typhoons, closely studying Typhoon Mangkhut, a powerful and catastrophic tropical cyclone that caused extensive damages of $593 million in Guam, the Philippines, and South China in September 2018. “As a Bahamian, I’ve witnessed the ferocity of hurricanes and challenges of rebuilding after them,” says Nottage. “I used this project to identify the tropical cyclones that caused the most extensive damage for further investigation.”She compiled the causes of damage and their costs to inform targets of supply chain resiliency reform (shipping, building materials, power supply, etc.). As a next step, Nottage will focus on modeling extreme events like Mangkunt to develop frameworks that companies can learn from and utilize to build more sustainable supply chains in the future.

      Ellie Vaserman, a first-year student working with postdoc and MCSC Impact Fellow Poushali Maji, also explored a topic related to value chains: unlocking circularity across the entire value chain through quality improvement, inclusive policy, and behavior to improve materials recovery. Specifically, her objectives have been to learn more about methods of chemolysis and the viability of their products, to compare methods of chemical recycling of polyethylene terephthalate (PET) using quantitative metrics, and to design qualitative visuals to make the steps in PET chemical recycling processes more understandable.

      To do so, she conducted a literature review to identify main methods of chemolysis that are utilized in the field (and collect data about these methods) and created graphics for some of the more common processes. Moving forward, she hopes to compare the processes using other metrics and research the energy intensity of the monomer purification processes.

      The work of these students, as well as many others, continued over MIT’s Independent Activities Period in January. More

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      in Environment

      Understanding air pollution from space

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      Climate change and air pollution are interlocking crises that threaten human health. Reducing emissions of some air pollutants can help achieve climate goals, and some climate mitigation efforts can in turn improve air quality.

      One part of MIT Professor Arlene Fiore’s research program is to investigate the fundamental science in understanding air pollutants — how long they persist and move through our environment to affect air quality.

      “We need to understand the conditions under which pollutants, such as ozone, form. How much ozone is formed locally and how much is transported long distances?” says Fiore, who notes that Asian air pollution can be transported across the Pacific Ocean to North America. “We need to think about processes spanning local to global dimensions.”

      Fiore, the Peter H. Stone and Paola Malanotte Stone Professor in Earth, Atmospheric and Planetary Sciences, analyzes data from on-the-ground readings and from satellites, along with models, to better understand the chemistry and behavior of air pollutants — which ultimately can inform mitigation strategies and policy setting.

      A global concern

      At the United Nations’ most recent climate change conference, COP26, air quality management was a topic discussed over two days of presentations.

      “Breathing is vital. It’s life. But for the vast majority of people on this planet right now, the air that they breathe is not giving life, but cutting it short,” said Sarah Vogel, senior vice president for health at the Environmental Defense Fund, at the COP26 session.

      “We need to confront this twin challenge now through both a climate and clean air lens, of targeting those pollutants that warm both the air and harm our health.”

      Earlier this year, the World Health Organization (WHO) updated its global air quality guidelines it had issued 15 years earlier for six key pollutants including ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), and carbon monoxide (CO). The new guidelines are more stringent based on what the WHO stated is the “quality and quantity of evidence” of how these pollutants affect human health. WHO estimates that roughly 7 million premature deaths are attributable to the joint effects of air pollution.

      “We’ve had all these health-motivated reductions of aerosol and ozone precursor emissions. What are the implications for the climate system, both locally but also around the globe? How does air quality respond to climate change? We study these two-way interactions between air pollution and the climate system,” says Fiore.

      But fundamental science is still required to understand how gases, such as ozone and nitrogen dioxide, linger and move throughout the troposphere — the lowermost layer of our atmosphere, containing the air we breathe.

      “We care about ozone in the air we’re breathing where we live at the Earth’s surface,” says Fiore. “Ozone reacts with biological tissue, and can be damaging to plants and human lungs. Even if you’re a healthy adult, if you’re out running hard during an ozone smog event, you might feel an extra weight on your lungs.”

      Telltale signs from space

      Ozone is not emitted directly, but instead forms through chemical reactions catalyzed by radiation from the sun interacting with nitrogen oxides — pollutants released in large part from burning fossil fuels—and volatile organic compounds. However, current satellite instruments cannot sense ground-level ozone.

      “We can’t retrieve surface- or even near-surface ozone from space,” says Fiore of the satellite data, “although the anticipated launch of a new instrument looks promising for new advances in retrieving lower-tropospheric ozone”. Instead, scientists can look at signatures from other gas emissions to get a sense of ozone formation. “Nitrogen dioxide and formaldehyde are a heavy focus of our research because they serve as proxies for two of the key ingredients that go on to form ozone in the atmosphere.”

      To understand ozone formation via these precursor pollutants, scientists have gathered data for more than two decades using spectrometer instruments aboard satellites that measure sunlight in ultraviolet and visible wavelengths that interact with these pollutants in the Earth’s atmosphere — known as solar backscatter radiation.

      Satellites, such as NASA’s Aura, carry instruments like the Ozone Monitoring Instrument (OMI). OMI, along with European-launched satellites such as the Global Ozone Monitoring Experiment (GOME) and the Scanning Imaging Absorption spectroMeter for Atmospheric CartograpHY (SCIAMACHY), and the newest generation TROPOspheric Monitoring instrument (TROPOMI), all orbit the Earth, collecting data during daylight hours when sunlight is interacting with the atmosphere over a particular location.

      In a recent paper from Fiore’s group, former graduate student Xiaomeng Jin (now a postdoc at the University of California at Berkeley), demonstrated that she could bring together and “beat down the noise in the data,” as Fiore says, to identify trends in ozone formation chemistry over several U.S. metropolitan areas that “are consistent with our on-the-ground understanding from in situ ozone measurements.”

      “This finding implies that we can use these records to learn about changes in surface ozone chemistry in places where we lack on-the-ground monitoring,” says Fiore. Extracting these signals by stringing together satellite data — OMI, GOME, and SCIAMACHY — to produce a two-decade record required reconciling the instruments’ differing orbit days, times, and fields of view on the ground, or spatial resolutions. 

      Currently, spectrometer instruments aboard satellites are retrieving data once per day. However, newer instruments, such as the Geostationary Environment Monitoring Spectrometer launched in February 2020 by the National Institute of Environmental Research in the Ministry of Environment of South Korea, will monitor a particular region continuously, providing much more data in real time.

      Over North America, the Tropospheric Emissions: Monitoring of Pollution Search (TEMPO) collaboration between NASA and the Smithsonian Astrophysical Observatory, led by Kelly Chance of Harvard University, will provide not only a stationary view of the atmospheric chemistry over the continent, but also a finer-resolution view — with the instrument recording pollution data from only a few square miles per pixel (with an anticipated launch in 2022).

      “What we’re very excited about is the opportunity to have continuous coverage where we get hourly measurements that allow us to follow pollution from morning rush hour through the course of the day and see how plumes of pollution are evolving in real time,” says Fiore.

      Data for the people

      Providing Earth-observing data to people in addition to scientists — namely environmental managers, city planners, and other government officials — is the goal for the NASA Health and Air Quality Applied Sciences Team (HAQAST).

      Since 2016, Fiore has been part of HAQAST, including collaborative “tiger teams” — projects that bring together scientists, nongovernment entities, and government officials — to bring data to bear on real issues.

      For example, in 2017, Fiore led a tiger team that provided guidance to state air management agencies on how satellite data can be incorporated into state implementation plans (SIPs). “Submission of a SIP is required for any state with a region in non-attainment of U.S. National Ambient Air Quality Standards to demonstrate their approach to achieving compliance with the standard,” says Fiore. “What we found is that small tweaks in, for example, the metrics we use to convey the science findings, can go a long way to making the science more usable, especially when there are detailed policy frameworks in place that must be followed.”

      Now, in 2021, Fiore is part of two tiger teams announced by HAQAST in late September. One team is looking at data to address environmental justice issues, by providing data to assess communities disproportionately affected by environmental health risks. Such information can be used to estimate the benefits of governmental investments in environmental improvements for disproportionately burdened communities. The other team is looking at urban emissions of nitrogen oxides to try to better quantify and communicate uncertainties in the estimates of anthropogenic sources of pollution.

      “For our HAQAST work, we’re looking at not just the estimate of the exposure to air pollutants, or in other words their concentrations,” says Fiore, “but how confident are we in our exposure estimates, which in turn affect our understanding of the public health burden due to exposure. We have stakeholder partners at the New York Department of Health who will pair exposure datasets with health data to help prioritize decisions around public health.

      “I enjoy working with stakeholders who have questions that require science to answer and can make a difference in their decisions.” Fiore says. More

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      in Energy

      Helping to make nuclear fusion a reality

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      Up until she served in the Peace Corps in Malawi, Rachel Bielajew was open to a career reboot. Having studied nuclear engineering as an undergraduate at the University of Michigan at Ann Arbor, graduate school had been on her mind. But seeing the drastic impacts of climate change play out in real-time in Malawi — the lives of the country’s subsistence farmers swing wildly, depending on the rains — convinced Bielajew of the importance of nuclear engineering. Bielajew was struck that her high school students in the small town of Chisenga had a shaky understanding of math, but universally understood global warming. “The concept of the changing world due to human impact was evident, and they could see it,” Bielajew says.

      Bielajew was looking to work on solutions that could positively impact global problems and feed her love of physics. Nuclear engineering, especially the study of fusion as a carbon-free energy source, checked off both boxes. Bielajew is now a fourth-year doctoral candidate in the Department of Nuclear Science and Engineering (NSE). She researches magnetic confinement fusion in the Plasma Science and Fusion Center (PSFC) with Professor Anne White.

      Researching fusion’s big challenge

      You need to confine plasma effectively in order to generate the extremely high temperatures (100 million degrees Celsius) fusion needs, without melting the walls of the tokamak, the device that hosts these reactions. Magnets can do the job, but “plasmas are weird, they behave strangely and are challenging to understand,” Bielajew says. Small instabilities in plasma can coalesce into fluctuating turbulence that can drive heat and particles out of the machine.

      In high-confinement mode, the edges of the plasma have less tolerance for such unruly behavior. “The turbulence gets damped out and sheared apart at the edge,” Bielajew says. This might seem like a good thing, but high-confinement plasmas have their own challenges. They are so tightly bound that they create edge-localized modes (ELMs), bursts of damaging particles and energy, that can be extremely damaging to the machine.

      The questions Bielajew is looking to answer: How do we get high confinement without ELMs? How do turbulence and transport play a role in plasmas? “We do not fully understand turbulence, even though we have studied it for a long time,” Bielajew says, “It is a big and important problem to solve for fusion to be a reality. I like that challenge,” Bielajew adds.

      A love of science

      Confronting such challenges head-on has been part of Bielajew’s toolkit since she was a child growing up in Ann Arbor, Michigan. Her father, Alex Bielajew, is a professor of nuclear engineering at the University of Michigan, and Bielajew’s mother also pursued graduate studies.

      Bielajew’s parents encouraged her to follow her own path and she found it led to her father’s chosen profession: nuclear engineering. Once she decided to pursue research in fusion, MIT stood out as a school she could set her sights on. “I knew that MIT had an extensive program in fusion and a lot of faculty in the field,” Bielajew says. The mechanics of the application were challenging: Chisenga had limited internet access, so Bielajew had to ride on the back of a pickup truck to meet a friend in a city a few hours away and use his phone as a hotspot to send the documents.

      A similar tenacity has surfaced in Bielajew’s approach to research during the Covid-19 pandemic. Working off a blueprint, Bielajew built the Correlation Cyclotron Emission Diagnostic, which measures turbulent electron temperature fluctuations. Through a collaboration, Bielajew conducts her plasma research at the ASDEX Upgrade tokamak in Germany. Traditionally, Bielajew would ship the diagnostic to Germany, follow and install it, and conduct the research in person. The pandemic threw a wrench in the plans, so Bielajew shipped the diagnostic and relied on team members to install it. She Zooms into the control room and trusts others to run the plasma experiments.

      DEI advocate

      Bielajew is very hands-on with another endeavor: improving diversity, equity, and inclusion (DEI) in her own backyard. Having grown up with parental encouragement and in an environment that never doubted her place as a woman in engineering, Bielajew realizes not everyone has the same opportunities. “I wish that the world was in a place where all I had to do was care about my research, but it’s not,” Bielajew says. While science can solve many problems, more fundamental ones about equity need humans to act in specific ways, she points out. “I want to see more women represented, more people of color. Everyone needs a voice in building a better world,” Bielajew says.

      To get there, Bielajew co-launched NSE’s Graduate Application Assistance Program, which connects underrepresented student applicants with NSE mentors. She has been the DEI officer with NSE’s student group, ANS, and is very involved in the department’s DEI committee.

      As for future research, Bielajew hopes to concentrate on the experiments that make her question existing paradigms about plasmas under high confinement. Bielajew has registered more head-scratching “hmm” moments than “a-ha” ones. Measurements from her experiments drive the need for more intensive study.

      Bielajew’s dogs, Dobby and Winky, keep her company through it all. They came home with her from Malawi. More

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      in Environment

      Expanding the conversation about sustainability

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      Stacy Godfreey-Igwe sat in her dorm room at MIT, staring frantically at her phone. An unprecedented snowstorm had hit her hometown of Richardson, Texas, and she was having difficulty contacting her family. She felt worried and frustrated, aware that nearby neighborhoods hadn’t lost power during the storm but that her family home had suffered significant damage. She finally got a hold of her parents, who had taken refuge in a nearby office building, but the experience left her shaken and more determined than ever to devote herself to addressing climate injustice.

      Godfreey-Igwe, the daughter of Nigerian immigrants, has long been concerned about how marginalized communities can shoulder a disproportionately heavy environmental burden. At MIT, she chose a double major in mechanical engineering with a concentration in global and sustainable development, and in African and African diaspora studies, a major she helped establish and became the first student to declare. Initially seeing the two fields as separate, she now embraces their intersectionality in her work in and out of the classroom.

      Through an Undergraduate Research Opportunity Program (UROP) project with Amah Edoh, the Homer A. Burnell Assistant Professor of Anthropology and African Studies at MIT, Godfreey-Igwe has learned more about her Igbo cultural heritage and hopes to understand what the future of climate change poses for the culture’s sustainability. Godfreey-Igwe herself is the “Ada” – or eldest child – in her family, a role that carries a responsibility for keeping her family’s culture alive. That sense of responsibility, to her community and to future generations, has stayed with her at MIT.

      For Independent Activities Period during her first year at the Institute, Godfreey-Igwe traveled to Kazakhstan through MIT’s Global Teaching Labs. As a student teacher, she taught Kazakh high school chemistry students about polymers and the impact plastic materials can have on the Earth’s climate. She was also an MIT International Science and Technology Initiatives (MISTI) Identity X Ambassador during her time there, blogging about her experiences as a Black woman in the country. She saw the role as an opportunity to shed light on the challenges of navigating her identity abroad, with hopes of fostering community through her posts.

      The following summer, Godfreey-Igwe interned for the Saathi Biodegradable Sanitary Napkins Startup in Ahmedabad, India. During her time there, she researched and wrote articles focused on educating the public about the benefits eco-friendly sanitary pads posed to public health and the environment. She also interviewed a director for the city’s Center for Environmental Education, about the importance of uplifting and supporting marginalized communities hit hardest by climate change. The conversation was eye-opening for Godfreey-Igwe; she saw not only how complex the process of mitigating climate change was, but also how diverse the solutions needed to be.

      She has also pursued her interest in plastics and sustainability through summer research projects. In of the summer of 2020, Godfreey-Igwe worked under a lab in Stanford University’s civil and environmental engineering department to create and design models maximizing the efficiency of bacterial processes leading to the creation of bioplastics. The project’s goal was to find a sustainable form of plastic breakdown for future applications in the environment.  She presented her research at the Harvard National Collegiate Research Conference and received a presentation award during the MIT Mechanical Engineering Research Exhibition. This past summer, she was awarded a grant through the NSF Center for Sustainable Polymers at the University of Minnesota to work on a research project seeking to understand microplastic generation.

      Ultimately, Godfreey-Igwe recognizes that to propose thoughtful solutions to climate issues, the people hit hardest must be a part of the conversation. For her, a key way to bring more people into conversations about sustainability and inclusion is through mentorship. This role is especially meaningful to Godfreey-Igwe because she knows firsthand how important for members of underrepresented groups to feel supported at a place like MIT. “The experience of coming to an institution like MIT, as someone who is low-income or of color, can be isolating. Especially if you feel like there are people who can’t relate to your background,” she says.

      Godfreey-Igwe is a member of Active Community Engagement FPOP (ACE), a social action group on campus that engages with local communities through public service work. Initially joining as a participant, Godfreey-Igwe became a counselor and then coordinator; she facilitates social action workshops and introduces students to service opportunities both at MIT and around Boston. She says her time in ACE has helped build her confidence in her abilities as a leader, mentor, and cultivator of inclusionary spaces. She is also a member of iHouse (International Development House), where she served for three years as the housing and service co-chair.

      Godfreey-Igwe also tutors one-on-one for Tutoring Plus in Cambridge, where since her first year she has provided mentorship and STEM tutoring to a low-income, high school student of color. Last spring, she was awarded the Tutoring Plus of Cambridge Unwavering Service Award for her service and commitment to the program.

      Looking ahead, Godfreey-Igwe hopes to use the skills learned from her mentorship and leadership roles to establish greater structures for collaboration on climate mitigation technologies, ideas, and practices. Focusing on mentoring young scientists of color, she wants to build up underprivileged groups and institutions for sustainable climate change research, ensuring everyone has a voice in the ongoing conversation.

      “In all this work, I’m hoping to make sure that globally marginalized communities are more visible in climate-related spaces, both in terms of who is doing the engineering and who the engineering works for,” she says. More

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      in Environment

      3 Questions: Tolga Durak on building a safety culture at MIT

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      Environment, Health, and Safety Managing Director Tolga Durak heads a team working to build a strong safety culture at the Institute and to implement systems that lead to successful lab and makerspace operations. EHS is also pursuing new opportunities in the areas of safe and sustainable labs and applied makerspace research. 

      Durak holds a BS in mechanical engineering, a MS in industrial and systems engineering, and a PhD in building construction/environmental design and planning. He has over 20 years of experience in engineering and EHS in higher education, having served in such roles as authority having jurisdiction, responsible official, fire marshal, risk manager, radiation safety officer, laser safety officer, safety engineer, project manager, and emergency manager for government agencies, as well as universities with extensive health-care and research facilities.

      Q: What “words of wisdom” regarding lab/shop health and safety would you like to share with the research community? 

      A: EHS staff always strive to help maintain the safety and well-being of the MIT community. When it comes to lab/shop safety or any areas with hazards, first and foremost, we encourage wearing the appropriate personal protective equipment (PPE) when handling potentially hazardous materials. While PPE needs depend on the hazards and the space, common PPE includes safety glasses, lab coats, gloves, clothes that cover your skin, and closed-toe shoes. Shorts and open-toe shoes have no place in the lab/shop setting when hazardous materials are stored or used. Accidents will and do happen. The severity of injuries due to accidental exposures can be minimized when researchers are wearing PPE. Remember, there is only one you!   

      Overall, be aware of your surroundings, be knowledgeable about the hazards of the materials and equipment you are using, and be prepared for the unexpected. Ask yourself, “What’s the worst thing that can happen during this experiment or procedure?” Prepare by doing a thorough risk assessment, ask others who may be knowledgeable for their ideas and help, and standardize procedures where possible. Be prepared to respond appropriately when an emergency arises. 

      Safety in our classrooms, labs, and makerspaces is paramount and requires a collaborative effort. 

      Q: What are the established programs within EHS that students and researchers should be aware of, and what opportunities and challenges do you face trying to advance a healthy safety culture at MIT? 

      A: The EHS program staff in Biosafety, Industrial Hygiene, Environmental Management, Occupational and Construction Safety, and Radiation Protection are ready to assist with risk assessments, chemical safety, physical hazards, hazard-specific training, materials management, and hazardous waste disposal and reuse/recycling. Locally, each department, laboratory, and center has an EHS coordinator, as well as an assigned EHS team, to assist in the implementation of required EHS programs. Each lab/shop also has a designated EHS representative — someone who has local knowledge of your lab/shop and can help you with safety requirements specific to your work area.  

      One of the biggest challenges we face is that due to the decentralized nature of the Institute, no one size fits all when it comes to implementing successful safety practices. We also view this as an opportunity to enhance our safety culture. A strong safety culture is reflected at MIT when all lab and makerspace members are willing to look out for each other, challenge the status quo when necessary, and do the right thing even when no one is looking. In labs/shops with a strong safety culture, faculty and researchers discuss safety topics at group meetings, group members remind each other to wear the appropriate PPE (lab coats, safety glasses, etc.), more experienced team members mentor the newcomers, and riskier operations are reviewed and assessed to make them as safe as possible.  

      Q: Can you describe the new Safe and Sustainable Laboratories (S2L) efforts and the makerspace operational research programs envisioned for the future? 

      A: The MIT EHS Office has a plan for renewing its dedication to sustainability and climate action. We are dedicated to doing our part to promote a research environment that assures the highest level of health and safety but also strives to reduce energy, water, and waste through educating and supporting faculty, students, and researchers. With the goal of integrating sustainability across the lab sector of campus and bridging that with the Institute’s climate action goals, EHS has partnered with the MIT Office of Sustainability, Department of Facilities, vice president for finance, and vice president for campus services and stewardship to relaunch the “green” labs sustainability efforts under a new Safe and Sustainable Labs program.

      Part of that plan is to implement a Sustainable Labs Certification program. The process is designed to be as easy as possible for the lab groups. We are starting with simple actions like promoting the use of equipment timers in certain locations to conserve energy, fume hood/ventilation management, preventative maintenance for ultra-low-temperature freezers, increasing recycling, and helping labs update their central chemical inventory system, which can help forecast MIT’s potential waste streams. 

      EHS has also partnered with Project Manus to build a test-bed lab to study potential health and environmental exposures present in makerspaces as a result of specialized equipment and processes with our new Applied Makerspace Research Initiative.   More