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      in Environment

      A mineral produced by plate tectonics has a global cooling effect, study finds

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      MIT geologists have found that a clay mineral on the seafloor, called smectite, has a surprisingly powerful ability to sequester carbon over millions of years.

      Under a microscope, a single grain of the clay resembles the folds of an accordion. These folds are known to be effective traps for organic carbon.

      Now, the MIT team has shown that the carbon-trapping clays are a product of plate tectonics: When oceanic crust crushes against a continental plate, it can bring rocks to the surface that, over time, can weather into minerals including smectite. Eventually, the clay sediment settles back in the ocean, where the minerals trap bits of dead organisms in their microscopic folds. This keeps the organic carbon from being consumed by microbes and expelled back into the atmosphere as carbon dioxide.

      Over millions of years, smectite can have a global effect, helping to cool the entire planet. Through a series of analyses, the researchers showed that smectite was likely produced after several major tectonic events over the last 500 million years. During each tectonic event, the clays trapped enough carbon to cool the Earth and induce the subsequent ice age.

      The findings are the first to show that plate tectonics can trigger ice ages through the production of carbon-trapping smectite.

      These clays can be found in certain tectonically active regions today, and the scientists believe that smectite continues to sequester carbon, providing a natural, albeit slow-acting, buffer against humans’ climate-warming activities.

      “The influence of these unassuming clay minerals has wide-ranging implications for the habitability of planets,” says Joshua Murray, a graduate student in MIT’s Department of Earth, Atmospheric, and Planetary Sciences. “There may even be a modern application for these clays in offsetting some of the carbon that humanity has placed into the atmosphere.”

      Murray and Oliver Jagoutz, professor of geology at MIT, have published their findings today in Nature Geoscience.

      A clear and present clay

      The new study follows up on the team’s previous work, which showed that each of the Earth’s major ice ages was likely triggered by a tectonic event in the tropics. The researchers found that each of these tectonic events exposed ocean rocks called ophiolites to the atmosphere. They put forth the idea that, when a tectonic collision occurs in a tropical region, ophiolites can undergo certain weathering effects, such as exposure to wind, rain, and chemical interactions, that transform the rocks into various minerals, including clays.

      “Those clay minerals, depending on the kinds you create, influence the climate in different ways,” Murray explains.

      At the time, it was unclear which minerals could come out of this weathering effect, and whether and how these minerals could directly contribute to cooling the planet. So, while it appeared there was a link between plate tectonics and ice ages, the exact mechanism by which one could trigger the other was still in question.

      With the new study, the team looked to see whether their proposed tectonic tropical weathering process would produce carbon-trapping minerals, and in quantities that would be sufficient to trigger a global ice age.

      The team first looked through the geologic literature and compiled data on the ways in which major magmatic minerals weather over time, and on the types of clay minerals this weathering can produce. They then worked these measurements into a weathering simulation of different rock types that are known to be exposed in tectonic collisions.

      “Then we look at what happens to these rock types when they break down due to weathering and the influence of a tropical environment, and what minerals form as a result,” Jagoutz says.

      Next, they plugged each weathered, “end-product” mineral into a simulation of the Earth’s carbon cycle to see what effect a given mineral might have, either in interacting with organic carbon, such as bits of dead organisms, or with inorganic, in the form of carbon dioxide in the atmosphere.

      From these analyses, one mineral had a clear presence and effect: smectite. Not only was the clay a naturally weathered product of tropical tectonics, it was also highly effective at trapping organic carbon. In theory, smectite seemed like a solid connection between tectonics and ice ages.

      But were enough of the clays actually present to trigger the previous four ice ages? Ideally, researchers should confirm this by finding smectite in ancient rock layers dating back to each global cooling period.

      “Unfortunately, as clays are buried by other sediments, they get cooked a bit, so we can’t measure them directly,” Murray says. “But we can look for their fingerprints.”

      A slow build

      The team reasoned that, as smectites are a product of ophiolites, these ocean rocks also bear characteristic elements such as nickel and chromium, which would be preserved in ancient sediments. If smectites were present in the past, nickel and chromium should be as well.

      To test this idea, the team looked through a database containing thousands of oceanic sedimentary rocks that were deposited over the last 500 million years. Over this time period, the Earth experienced four separate ice ages. Looking at rocks around each of these periods, the researchers observed large spikes of nickel and chromium, and inferred from this that smectite must also have been present.

      By their estimates, the clay mineral could have increased the preservation of organic carbon by less than one-tenth of a percent. In absolute terms, this is a miniscule amount. But over millions of years, they calculated that the clay’s accumulated, sequestered carbon was enough to trigger each of the four major ice ages.

      “We found that you really don’t need much of this material to have a huge effect on the climate,” Jagoutz says.

      “These clays also have probably contributed some of the Earth’s cooling in the last 3 to 5 million years, before humans got involved,” Murray adds. “In the absence of humans, these clays are probably making a difference to the climate. It’s just such a slow process.”

      “Jagoutz and Murray’s work is a nice demonstration of how important it is to consider all biotic and physical components of the global carbon cycle,” says Lee Kump, a professor of geosciences at Penn State University, who was not involved with the study. “Feedbacks among all these components control atmospheric greenhouse gas concentrations on all time scales, from the annual rise and fall of atmospheric carbon dioxide levels to the swings from icehouse to greenhouse over millions of years.”

      Could smectites be harnessed intentionally to further bring down the world’s carbon emissions? Murray sees some potential, for instance to shore up carbon reservoirs such as regions of permafrost. Warming temperatures are predicted to melt permafrost and expose long-buried organic carbon. If smectites could be applied to these regions, the clays could prevent this exposed carbon from escaping into and further warming the atmosphere.

      “If you want to understand how nature works, you have to understand it on the mineral and grain scale,” Jagoutz says. “And this is also the way forward for us to find solutions for this climatic catastrophe. If you study these natural processes, there’s a good chance you will stumble on something that will be actually useful.”

      This research was funded, in part, by the National Science Foundation. More

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      in Energy

      New study shows how universities are critical to emerging fusion industry

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      A new study suggests that universities have an essential role to fulfill in the continued growth and success of any modern high-tech industry, and especially the nascent fusion industry; however, the importance of that role is not reflected in the number of fusion-oriented faculty and educational channels currently available. Academia’s responsiveness to the birth of other modern scientific fields, such as aeronautics and nuclear fission, provides a template for the steps universities can take to enable a robust fusion industry.

      Authored by Dennis Whyte, the Hitachi America Professor of Engineering and director of the Plasma Science and Fusion Center at MIT; Carlos Paz-Soldan, associate professor of applied physics and applied mathematics at Columbia University; and Brian D. Wirth, the Governor’s Chair Professor of Computational Nuclear Engineering at the University of Tennessee, the paper was recently published in the journal Physics of Plasmas as part of a special collection titled “Private Fusion Research: Opportunities and Challenges in Plasma Science.”

      With contributions from authors in academia, government, and private industry, the collection outlines a framework for public-private partnerships that will be essential for the success of the fusion industry.

      Now being seen as a potential source of unlimited green energy, fusion is the same process that powers the sun — hydrogen atoms combine to form helium, releasing vast amounts of clean energy in the form of light and heat.

      The excitement surrounding fusion’s arrival has resulted in the proliferation of dozens of for-profit companies positioning themselves at the forefront of the commercial fusion energy industry. In the near future, those companies will require a significant network of fusion-fluent workers to take on varied tasks requiring a range of skills.

      While the authors acknowledge the role of private industry, especially as an increasingly dominant source of research funding, they also show that academia is and will continue to be critical to industry’s development, and it cannot be decoupled from private industry’s growth. Despite the evidence of this burgeoning interest, the size and scale of the field’s academic network at U.S.-based universities is sparse.

      According to Whyte, “Diversifying the [fusion] field by adding more tracks for master’s students and undergraduates who can transition into industry more quickly is an important step.”

      An analysis found that while there are 57 universities in the United States active in plasma and fusion research, the average number of tenured or tenure-track plasma/fusion faculty at each institution is only two. By comparison, a sampling of US News and World Report’s top 10 programs for nuclear fission and aeronautics/astronautics found an average of nearly 20 faculty devoted to fission and 32 to aero/astro.

      “University programs in fusion and their sponsors need to up their game and hire additional faculty if they want to provide the necessary workforce to support a growing U.S. fusion industry,” adds Paz-Soldan.

      The growth and proliferation of those fields and others, such as computing and biotechnology, were historically in lockstep with the creation of academic programs that helped drive the fields’ progress and widespread acceptance. Creating a similar path for fusion is essential to ensuring its sustainable growth, and as Wirth notes, “that this growth should be pursued in a way that is interdisciplinary across numerous engineering and science disciplines.”

      At MIT, an example of that path is seen at the Plasma Science and Fusion Center.

      The center has deep historical ties to government research programs, and the largest fusion company in the world, Commonwealth Fusion Systems (CFS), was spun out of the PSFC by Whyte’s former students and an MIT postdoc. Whyte also serves as the primary investigator in collaborative research with CFS on SPARC, a proof-of-concept fusion platform for advancing tokamak science that is scheduled for completion in 2025.

      “Public and private roles in the fusion community are rapidly evolving in response to the growth of privately funded commercial product development,” says Michael Segal, head of open innovation at CFS. “The fusion industry will increasingly rely on its university partners to train students, work across diverse disciplines, and execute small and midsize programs at speed.”

      According to the authors, another key reason academia will remain essential to the continued growth and development of fusion is because it is unconflicted. Whyte comments, “Our mandate is sharing information and education, which means we have no competitive conflict and innovation can flow freely.” Furthermore, fusion science is inherently multidisciplinary: “[It] requires physicists, computer scientists, engineers, chemists, etc. and it’s easy to tap into all those disciplines in an academic environment where they’re all naturally rubbing elbows and collaborating.”

      Creating a new energy industry, however, will also require a workforce skilled in disciplines other than STEM, say the authors. As fusion companies continue to grow, they will need expertise in finance, safety, licensing, and market analysis. Any successful fusion enterprise will also have major geopolitical, societal, and economic impacts, all of which must be managed.

      Ultimately, there are several steps the authors identify to help build the connections between academia and industry that will be important going forward: The first is for universities to acknowledge the rapidly changing fusion landscape and begin to adapt. “Universities need to embrace the growth of the private sector in fusion, recognize the opportunities it provides, and seek out mutually beneficial partnerships,” says Paz-Soldan.

      The second step is to reconcile the mission of educational institutions — unconflicted open access — with condensed timelines and proprietary outputs that come with private partnerships. At the same time, the authors note that private fusion companies should embrace the transparency of academia by publishing and sharing the findings they can through peer-reviewed journals, which will be a necessary part of building the industry’s credibility.

      The last step, the authors say, is for universities to become more flexible and creative in their technology licensing strategies to ensure ideas and innovations find their way from the lab into industry.

      “As an industry, we’re in a unique position because everything is brand new,” Whyte says. “But we’re enough students of history that we can see what’s needed to succeed; quantifying the status of the private and academic landscape is an important strategic touchstone. By drawing attention to the current trajectory, hopefully we’ll be in a better position to work with our colleagues in the public and private sector and make better-informed choices about how to proceed.” More

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      in Energy

      Team engineers nanoparticles using ion irradiation to advance clean energy and fuel conversion

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      MIT researchers and colleagues have demonstrated a way to precisely control the size, composition, and other properties of nanoparticles key to the reactions involved in a variety of clean energy and environmental technologies. They did so by leveraging ion irradiation, a technique in which beams of charged particles bombard a material.

      They went on to show that nanoparticles created this way have superior performance over their conventionally made counterparts.

      “The materials we have worked on could advance several technologies, from fuel cells to generate CO2-free electricity to the production of clean hydrogen feedstocks for the chemical industry [through electrolysis cells],” says Bilge Yildiz, leader of the work and a professor in MIT’s departments of Nuclear Science and Engineering and Materials Science and Engineering.

      Critical catalyst

      Fuel and electrolysis cells both involve electrochemical reactions through three principal parts: two electrodes (a cathode and anode) separated by an electrolyte. The difference between the two cells is that the reactions involved run in reverse.

      The electrodes are coated with catalysts, or materials that make the reactions involved go faster. But a critical catalyst made of metal-oxide materials has been limited by challenges including low durability. “The metal catalyst particles coarsen at high temperatures, and you lose surface area and activity as a result,” says Yildiz, who is also affiliated with the Materials Research Laboratory and is an author of an open-access paper on the work published in the journal Energy & Environmental Science.

      Enter metal exsolution, which involves precipitating metal nanoparticles out of a host oxide onto the surface of the electrode. The particles embed themselves into the electrode, “and that anchoring makes them more stable,” says Yildiz. As a result, exsolution has “led to remarkable progress in clean energy conversion and energy-efficient computing devices,” the researchers write in their paper.

      However, controlling the precise properties of the resulting nanoparticles has been difficult. “We know that exsolution can give us stable and active nanoparticles, but the challenging part is really to control it. The novelty of this work is that we’ve found a tool — ion irradiation — that can give us that control,” says Jiayue Wang PhD ’22, first author of the paper. Wang, who conducted the work while earning his PhD in the MIT Department of Nuclear Science and Engineering, is now a postdoc at Stanford University.

      Sossina Haile ’86, PhD ’92, the Walter P. Murphy Professor of Materials Science and Engineering at Northwestern University, who was not involved in the current work, says:

      “Metallic nanoparticles serve as catalysts in a whole host of reactions, including the important reaction of splitting water to generate hydrogen for energy storage. In this work, Yildiz and colleagues have created an ingenious method for controlling the way that nanoparticles form.”

      Haile continues, “the community has shown that exsolution results in structurally stable nanoparticles, but the process is not easy to control, so one doesn’t necessarily get the optimal number and size of particles. Using ion irradiation, this group was able to precisely control the features of the nanoparticles, resulting in excellent catalytic activity for water splitting.”

      What they did

      The researchers found that aiming a beam of ions at the electrode while simultaneously exsolving metal nanoparticles onto the electrode’s surface allowed them to control several properties of the resulting nanoparticles.

      “Through ion-matter interactions, we have successfully engineered the size, composition, density, and location of the exsolved nanoparticles,” the team writes in Energy & Environmental Science.

      For example, they could make the particles much smaller — down to 2 billionths of a meter in diameter — than those made using conventional thermal exsolution methods alone. Further, they were able to change the composition of the nanoparticles by irradiating with specific elements. They demonstrated this with a beam of nickel ions that implanted nickel into the exsolved metal nanoparticle. As a result, they demonstrated a direct and convenient way to engineer the composition of exsolved nanoparticles.

      “We want to have multi-element nanoparticles, or alloys, because they usually have higher catalytic activity,” Yildiz says. “With our approach, the exsolution target does not have to be dependent on the substrate oxide itself.” Irradiation opens the door to many more compositions. “We can pretty much choose any oxide and any ion that we can irradiate with and exsolve that,” says Yildiz.

      The team also found that ion irradiation forms defects in the electrode itself. And these defects provide additional nucleation sites, or places for the exsolved nanoparticles to grow from, increasing the density of the resulting nanoparticles.

      Irradiation could also allow extreme spatial control over the nanoparticles. “Because you can focus the ion beam, you can imagine that you could ‘write’ with it to form specific nanostructures,” says Wang. “We did a preliminary demonstration [of that], but we believe it has potential to realize well-controlled micro- and nano-structures.”

      The team also showed that the nanoparticles they created with ion irradiation had superior catalytic activity over those created by conventional thermal exsolution alone.

      Additional MIT authors of the paper are Kevin B. Woller, a principal research scientist at the Plasma Science and Fusion Center (PSFC), home to the equipment used for ion irradiation; Abinash Kumar PhD ’22, who received his PhD from the Department of Materials Science and Engineering (DMSE) and is now at Oak Ridge National Laboratory; and James M. LeBeau, an associate professor in DMSE. Other authors are Zhan Zhang and Hua Zhou of Argonne National Laboratory, and Iradwikanari Waluyo and Adrian Hunt of Brookhaven National Laboratory.

      This work was funded by the OxEon Corp. and MIT’s PSFC. The research also used resources supported by the U.S. Department of Energy Office of Science, MIT’s Materials Research Laboratory, and MIT.nano. The work was performed, in part, at Harvard University through a network funded by the National Science Foundation. More

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      in Environment

      Merging science and systems thinking to make materials more sustainable

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      For Professor Elsa Olivetti, tackling a problem as large and complex as climate change requires not only lab research but also understanding the systems of production that power the global economy.

      Her career path reflects a quest to investigate materials at scales ranging from the microscopic to the mass-manufactured.

      “I’ve always known what questions I wanted to ask, and then set out to build the tools to help me ask those questions,” says Olivetti, the Jerry McAfee Professor in Engineering.

      Olivetti, who earned tenure in 2022 and was recently appointed associate dean of engineering, has sought to equip students with similar skills, whether in the classroom, in her lab group, or through the interdisciplinary programs she leads at MIT. Those efforts have earned her accolades including the Bose Award for Excellence in Teaching, a MacVicar Faculty Fellowship in 2021, and the McDonald Award for Excellence in Mentoring and Advising in 2023.

      “I think to make real progress in sustainability, materials scientists need to think in interdisciplinary, systems-level ways, but at a deep technical level,” Olivetti says. “Supporting my students so that’s something that a lot more people can do is very rewarding for me.”

      Her mission to make materials more sustainable also makes Olivetti grateful [EAO1] she’s at MIT, which has a long tradition of both interdisciplinary collaboration and technical know-how.

      “MIT’s core competencies are well-positioned for bold achievements in climate and sustainability — the deep expertise on the economics side, the frontier knowledge in science, the computational creativity,” Olivetti says. “It’s a really exciting time and place where the key ingredients for progress are simmering in transformative ways.”

      Answering the call

      The moment that set Olivetti on her life’s journey began when she was 8, with a knock at her door. Her parents were in the other room, so Olivetti opened the door and met an organizer for Greenpeace, a nonprofit that works to raise awareness of environmental issues.

      “I had a chat with that guy and got hooked on environmental concerns,” Olivetti says. “I still remember that conversation.”

      The interaction changed the way Olivetti thought about her place in the world, and her new perspective manifested itself in some unique ways. Her elementary school science fair projects became elaborate pursuits of environmental solutions involving burying various items in the backyard to test for biodegradability. There was also an awkward attempt at natural pesticide development, which lead to a worm hatching in her bedroom.

      As an undergraduate at the University of Virginia, Olivetti gravitated toward classes in environmentalism and materials science.

      “There was a link between materials science and a broader, systems way of framing design for environment, and that just clicked for me in terms of the way I wanted to think about environmental problems — from the atom to the system,” Olivetti recalls.

      That interest led Olivetti to MIT for a PhD in 2001, where she studied the feasibility of new materials for lithium-ion batteries.

      “I really wanted to be thinking of things at a systems level, but I wanted to ground that in lab-based research,” Olivetti says. “I wanted an experiential experience in grad school, and that’s why I chose MIT’s program.”

      Whether it was her undergraduate studies, her PhD, or her ensuing postdoc work at MIT, Olivetti sought to learn new skills to continue bridging the gap between materials science and environmental systems thinking.

      “I think of it as, ‘Here’s how I can build up the ways I ask questions,’” Olivetti explains. “How do we design these materials while thinking about their implications as early as possible?”

      Since joining MIT’s faculty in 2014, Olivetti has developed computational models to measure the cost and environmental impact of new materials, explored ways to adopt more sustainable and circular supply chains, and evaluated potential materials limitations as lithium-ion battery production is scaled. That work helps companies increase their use of greener, recyclable materials and more sustainably dispose of waste.

      Olivetti believes the wide scope of her research gives the students in her lab a more holistic understanding of the life cycle of materials.

      “When the group started, each student was working on a different aspect of the problem — like on the natural language processing pipeline, or on recycling technology assessment, or beneficial use of waste — and now each student can link each of those pieces in their research,” Olivetti explains.

      Beyond her research, Olivetti also co-directs the MIT Climate and Sustainability Consortium, which has established a set of eight areas of sustainability that it organizes coalitions around. Each coalition involves technical leaders at companies and researchers at MIT that work together to accelerate the impact of MIT’s research by helping companies adopt innovative and more sustainable technologies.

      “Climate change mitigation and resilience is such a complex problem, and at MIT we have practice in working together across disciplines on many challenges,” Olivetti says. “It’s been exciting to lean on that culture and unlock ways to move forward more effectively.”

      Bridging divides

      Today, Olivetti tries to maximize the impact of her and her students’ research in materials industrial ecology by maintaining close ties to applications. In her research, this means working directly with aluminum companies to design alloys that could incorporate more scrap material or with nongovernmental organizations to incorporate agricultural residues in building products. In the classroom, that means bringing in people from companies to explain how they think about concepts like heat exchange or fluid flow in their products.

      “I enjoy trying to ground what students are learning in the classroom with what’s happening in the world,” Olivetti explains.

      Exposing students to industry is also a great way to help them think about their own careers. In her research lab, she’s started using the last 30 minutes of meetings to host talks from people working in national labs, startups, and larger companies to show students what they can do after their PhDs. The talks are similar to the Industry Seminar series Olivetti started that pairs undergraduate students with people working in areas like 3D printing, environmental consulting, and manufacturing.

      “It’s about helping students learn what they’re excited about,” Olivetti says.

      Whether in the classroom, lab, or at events held by organizations like MCSC, Olivetti believes collaboration is humanity’s most potent tool to combat climate change.

      “I just really enjoy building links between people,” Olivetti says. “Learning about people and meeting them where they are is a way that one can create effective links. It’s about creating the right playgrounds for people to think and learn.” More

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      in Security

      Microbes could help reduce the need for chemical fertilizers

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      Production of chemical fertilizers accounts for about 1.5 percent of the world’s greenhouse gas emissions. MIT chemists hope to help reduce that carbon footprint by replacing some chemical fertilizer with a more sustainable source — bacteria.

      Bacteria that can convert nitrogen gas to ammonia could not only provide nutrients that plants need, but also help regenerate soil and protect plants from pests. However, these bacteria are sensitive to heat and humidity, so it’s difficult to scale up their manufacture and ship them to farms.

      To overcome that obstacle, MIT chemical engineers have devised a metal-organic coating that protects bacterial cells from damage without impeding their growth or function. In a new study, they found that these coated bacteria improved the germination rate of a variety of seeds, including vegetables such as corn and bok choy.

      This coating could make it much easier for farmers to deploy microbes as fertilizers, says Ariel Furst, the Paul M. Cook Career Development Assistant Professor of Chemical Engineering at MIT and the senior author of the study.

      “We can protect them from the drying process, which would allow us to distribute them much more easily and with less cost because they’re a dried powder instead of in liquid,” she says. “They can also withstand heat up to 132 degrees Fahrenheit, which means that you wouldn’t have to use cold storage for these microbes.”

      Benjamin Burke ’23 and postdoc Gang Fan are the lead authors of the open-access paper, which appears in the Journal of the American Chemical Society Au. MIT undergraduate Pris Wasuwanich and Evan Moore ’23 are also authors of the study.

      Protecting microbes

      Chemical fertilizers are manufactured using an energy-intensive process known as Haber-Bosch, which uses extremely high pressures to combine nitrogen from the air with hydrogen to make ammonia.

      In addition to the significant carbon footprint of this process, another drawback to chemical fertilizers is that long-term use eventually depletes the nutrients in the soil. To help restore soil, some farmers have turned to “regenerative agriculture,” which uses a variety of strategies, including crop rotation and composting, to keep soil healthy. Nitrogen-fixing bacteria, which convert nitrogen gas to ammonia, can aid in this approach.

      Some farmers have already begun deploying these “microbial fertilizers,” growing them in large onsite fermenters before applying them to the soil. However, this is cost-prohibitive for many farmers.

      Shipping these bacteria to rural areas is not currently a viable option, because they are susceptible to heat damage. The microbes are also too delicate to survive the freeze-drying process that would make them easier to transport.

      To protect the microbes from both heat and freeze-drying, Furst decided to apply a coating called a metal-phenol network (MPN), which she has previously developed to encapsulate microbes for other uses, such as protecting therapeutic bacteria delivered to the digestive tract.

      The coatings contain two components — a metal and an organic compound called a polyphenol — that can self-assemble into a protective shell. The metals used for the coatings, including iron, manganese, aluminum, and zinc, are considered safe as food additives. Polyphenols, which are often found in plants, include molecules such as tannins and other antioxidants. The FDA classifies many of these polyphenols as GRAS (generally regarded as safe).

      “We are using these natural food-grade compounds that are known to have benefits on their own, and then they form these little suits of armor that protect the microbes,” Furst says.

      For this study, the researchers created 12 different MPNs and used them to encapsulate Pseudomonas chlororaphis, a nitrogen-fixing bacterium that also protects plants against harmful fungi and other pests. They found that all of the coatings protected the bacteria from temperatures up to 50 degrees Celsius (122 degrees Fahrenheit), and also from relative humidity up to 48 percent. The coatings also kept the microbes alive during the freeze-drying process.

      A boost for seeds

      Using microbes coated with the most effective MPN — a combination of manganese and a polyphenol called epigallocatechin gallate (EGCG) — the researchers tested their ability to help seeds germinate in a lab dish. They heated the coated microbes to 50 C before placing them in the dish, and compared them to fresh uncoated microbes and freeze-dried uncoated microbes.

      The researchers found that the coated microbes improved the seeds’ germination rate by 150 percent, compared to seeds treated with fresh, uncoated microbes. This result was consistent across several different types of seeds, including dill, corn, radishes, and bok choy.

      Furst has started a company called Seia Bio to commercialize the coated bacteria for large-scale use in regenerative agriculture. She hopes that the low cost of the manufacturing process will help make microbial fertilizers accessible to small-scale farmers who don’t have the fermenters needed to grow such microbes.

      “When we think about developing technology, we need to intentionally design it to be inexpensive and accessible, and that’s what this technology is. It would help democratize regenerative agriculture,” she says.

      The research was funded by the Army Research Office, a National Institutes of Health New Innovator Award, a National Institute for Environmental Health Sciences Core Center Grant, the CIFAR Azrieli Global Scholars Program, the MIT J-WAFS Program, the MIT Climate and Sustainability Consortium, and the MIT Deshpande Center. More

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      in Environment

      In a surprising finding, light can make water evaporate without heat

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      Evaporation is happening all around us all the time, from the sweat cooling our bodies to the dew burning off in the morning sun. But science’s understanding of this ubiquitous process may have been missing a piece all this time.

      In recent years, some researchers have been puzzled upon finding that water in their experiments, which was held in a sponge-like material known as a hydrogel, was evaporating at a higher rate than could be explained by the amount of heat, or thermal energy, that the water was receiving. And the excess has been significant — a doubling, or even a tripling or more, of the theoretical maximum rate.

      After carrying out a series of new experiments and simulations, and reexamining some of the results from various groups that claimed to have exceeded the thermal limit, a team of researchers at MIT has reached a startling conclusion: Under certain conditions, at the interface where water meets air, light can directly bring about evaporation without the need for heat, and it actually does so even more efficiently than heat. In these experiments, the water was held in a hydrogel material, but the researchers suggest that the phenomenon may occur under other conditions as well.

      The findings are published this week in a paper in PNAS, by MIT postdoc Yaodong Tu, professor of mechanical engineering Gang Chen, and four others.

      The phenomenon might play a role in the formation and evolution of fog and clouds, and thus would be important to incorporate into climate models to improve their accuracy, the researchers say. And it might play an important part in many industrial processes such as solar-powered desalination of water, perhaps enabling alternatives to the step of converting sunlight to heat first.

      The new findings come as a surprise because water itself does not absorb light to any significant degree. That’s why you can see clearly through many feet of clean water to the surface below. So, when the team initially began exploring the process of solar evaporation for desalination, they first put particles of a black, light-absorbing material in a container of water to help convert the sunlight to heat.

      Then, the team came across the work of another group that had achieved an evaporation rate double the thermal limit — which is the highest possible amount of evaporation that can take place for a given input of heat, based on basic physical principles such as the conservation of energy. It was in these experiments that the water was bound up in a hydrogel. Although they were initially skeptical, Chen and Tu starting their own experiments with hydrogels, including a piece of the material from the other group. “We tested it under our solar simulator, and it worked,” confirming the unusually high evaporation rate, Chen says. “So, we believed them now.” Chen and Tu then began making and testing their own hydrogels.

      They began to suspect that the excess evaporation was being caused by the light itself —that photons of light were actually knocking bundles of water molecules loose from the water’s surface. This effect would only take place right at the boundary layer between water and air, at the surface of the hydrogel material — and perhaps also on the sea surface or the surfaces of droplets in clouds or fog.

      In the lab, they monitored the surface of a hydrogel, a JELL-O-like matrix consisting mostly of water bound by a sponge-like lattice of thin membranes. They measured its responses to simulated sunlight with precisely controlled wavelengths.

      The researchers subjected the water surface to different colors of light in sequence and measured the evaporation rate. They did this by placing a container of water-laden hydrogel on a scale and directly measuring the amount of mass lost to evaporation, as well as monitoring the temperature above the hydrogel surface. The lights were shielded to prevent them from introducing extra heat. The researchers found that the effect varied with color and peaked at a particular wavelength of green light. Such a color dependence has no relation to heat, and so supports the idea that it is the light itself that is causing at least some of the evaporation.

      The puffs of white condensation on glass is water being evaporated from a hydrogel using green light, without heat.Image: Courtesy of the researchers

      The researchers tried to duplicate the observed evaporation rate with the same setup but using electricity to heat the material, and no light. Even though the thermal input was the same as in the other test, the amount of water that evaporated never exceeded the thermal limit. However, it did so when the simulated sunlight was on, confirming that light was the cause of the extra evaporation.

      Though water itself does not absorb much light, and neither does the hydrogel material itself, when the two combine they become strong absorbers, Chen says. That allows the material to harness the energy of the solar photons efficiently and exceed the thermal limit, without the need for any dark dyes for absorption.

      Having discovered this effect, which they have dubbed the photomolecular effect, the researchers are now working on how to apply it to real-world needs. They have a grant from the Abdul Latif Jameel Water and Food Systems Lab to study the use of this phenomenon to improve the efficiency of solar-powered desalination systems, and a Bose Grant to explore the phenomenon’s effects on climate change modeling.

      Tu explains that in standard desalination processes, “it normally has two steps: First we evaporate the water into vapor, and then we need to condense the vapor to liquify it into fresh water.” With this discovery, he says, potentially “we can achieve high efficiency on the evaporation side.” The process also could turn out to have applications in processes that require drying a material.

      Chen says that in principle, he thinks it may be possible to increase the limit of water produced by solar desalination, which is currently 1.5 kilograms per square meter, by as much as three- or fourfold using this light-based approach. “This could potentially really lead to cheap desalination,” he says.

      Tu adds that this phenomenon could potentially also be leveraged in evaporative cooling processes, using the phase change to provide a highly efficient solar cooling system.

      Meanwhile, the researchers are also working closely with other groups who are attempting to replicate the findings, hoping to overcome skepticism that has faced the unexpected findings and the hypothesis being advanced to explain them.

      The research team also included Jiawei Zhou, Shaoting Lin, Mohammed Alshrah, and Xuanhe Zhao, all in MIT’s Department of Mechanical Engineering. More

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      in Energy

      Engineers develop an efficient process to make fuel from carbon dioxide

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      The search is on worldwide to find ways to extract carbon dioxide from the air or from power plant exhaust and then make it into something useful. One of the more promising ideas is to make it into a stable fuel that can replace fossil fuels in some applications. But most such conversion processes have had problems with low carbon efficiency, or they produce fuels that can be hard to handle, toxic, or flammable.

      Now, researchers at MIT and Harvard University have developed an efficient process that can convert carbon dioxide into formate, a liquid or solid material that can be used like hydrogen or methanol to power a fuel cell and generate electricity. Potassium or sodium formate, already produced at industrial scales and commonly used as a de-icer for roads and sidewalks, is nontoxic, nonflammable, easy to store and transport, and can remain stable in ordinary steel tanks to be used months, or even years, after its production.

      The new process, developed by MIT doctoral students Zhen Zhang, Zhichu Ren, and Alexander H. Quinn; Harvard University doctoral student Dawei Xi; and MIT Professor Ju Li, is described this week in an open-access paper in Cell Reports Physical Science. The whole process — including capture and electrochemical conversion of the gas to a solid formate powder, which is then used in a fuel cell to produce electricity — was demonstrated at a small, laboratory scale. However, the researchers expect it to be scalable so that it could provide emissions-free heat and power to individual homes and even be used in industrial or grid-scale applications.

      Other approaches to converting carbon dioxide into fuel, Li explains, usually involve a two-stage process: First the gas is chemically captured and turned into a solid form as calcium carbonate, then later that material is heated to drive off the carbon dioxide and convert it to a fuel feedstock such as carbon monoxide. That second step has very low efficiency, typically converting less than 20 percent of the gaseous carbon dioxide into the desired product, Li says.

      By contrast, the new process achieves a conversion of well over 90 percent and eliminates the need for the inefficient heating step by first converting the carbon dioxide into an intermediate form, liquid metal bicarbonate. That liquid is then electrochemically converted into liquid potassium or sodium formate in an electrolyzer that uses low-carbon electricity, e.g. nuclear, wind, or solar power. The highly concentrated liquid potassium or sodium formate solution produced can then be dried, for example by solar evaporation, to produce a solid powder that is highly stable and can be stored in ordinary steel tanks for up to years or even decades, Li says.

      Several steps of optimization developed by the team made all the difference in changing an inefficient chemical-conversion process into a practical solution, says Li, who holds joint appointments in the departments of Nuclear Science and Engineering and of Materials Science and Engineering.

      The process of carbon capture and conversion involves first an alkaline solution-based capture that concentrates carbon dioxide, either from concentrated streams such as from power plant emissions or from very low-concentration sources, even open air, into the form of a liquid metal-bicarbonate solution. Then, through the use of a cation-exchange membrane electrolyzer, this bicarbonate is electrochemically converted into solid formate crystals with a carbon efficiency of greater than 96 percent, as confirmed in the team’s lab-scale experiments.

      These crystals have an indefinite shelf life, remaining so stable that they could be stored for years, or even decades, with little or no loss. By comparison, even the best available practical hydrogen storage tanks allow the gas to leak out at a rate of about 1 percent per day, precluding any uses that would require year-long storage, Li says. Methanol, another widely explored alternative for converting carbon dioxide into a fuel usable in fuel cells, is a toxic substance that cannot easily be adapted to use in situations where leakage could pose a health hazard. Formate, on the other hand, is widely used and considered benign, according to national safety standards.

      Several improvements account for the greatly improved efficiency of this process. First, a careful design of the membrane materials and their configuration overcomes a problem that previous attempts at such a system have encountered, where a buildup of certain chemical byproducts changes the pH, causing the system to steadily lose efficiency over time. “Traditionally, it is difficult to achieve long-term, stable, continuous conversion of the feedstocks,” Zhang says. “The key to our system is to achieve a pH balance for steady-state conversion.”

      To achieve that, the researchers carried out thermodynamic modeling to design the new process so that it is chemically balanced and the pH remains at a steady state with no shift in acidity over time. It can therefore continue operating efficiently over long periods. In their tests, the system ran for over 200 hours with no significant decrease in output. The whole process can be done at ambient temperatures and relatively low pressures (about five times atmospheric pressure).

      Another issue was that unwanted side reactions produced other chemical products that were not useful, but the team figured out a way to prevent these side reactions by the introduction of an extra “buffer” layer of bicarbonate-enriched fiberglass wool that blocked these reactions.

      The team also built a fuel cell specifically optimized for the use of this formate fuel to produce electricity. The stored formate particles are simply dissolved in water and pumped into the fuel cell as needed. Although the solid fuel is much heavier than pure hydrogen, when the weight and volume of the high-pressure gas tanks needed to store hydrogen is considered, the end result is an electricity output near parity for a given storage volume, Li says.

      The formate fuel can potentially be adapted for anything from home-sized units to large scale industrial uses or grid-scale storage systems, the researchers say. Initial household applications might involve an electrolyzer unit about the size of a refrigerator to capture and convert the carbon dioxide into formate, which could be stored in an underground or rooftop tank. Then, when needed, the powdered solid would be mixed with water and fed into a fuel cell to provide power and heat. “This is for community or household demonstrations,” Zhang says, “but we believe that also in the future it may be good for factories or the grid.”

      “The formate economy is an intriguing concept because metal formate salts are very benign and stable, and a compelling energy carrier,” says Ted Sargent, a professor of chemistry and of electrical and computer engineering at Northwestern University, who was not associated with this work. “The authors have demonstrated enhanced efficiency in liquid-to-liquid conversion from bicarbonate feedstock to formate, and have demonstrated these fuels can be used later to produce electricity,” he says.

      The work was supported by the U.S. Department of Energy Office of Science. More

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      in Energy

      MIT design would harness 40 percent of the sun’s heat to produce clean hydrogen fuel

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      MIT engineers aim to produce totally green, carbon-free hydrogen fuel with a new, train-like system of reactors that is driven solely by the sun.

      In a study appearing today in Solar Energy Journal, the engineers lay out the conceptual design for a system that can efficiently produce “solar thermochemical hydrogen.” The system harnesses the sun’s heat to directly split water and generate hydrogen — a clean fuel that can power long-distance trucks, ships, and planes, while in the process emitting no greenhouse gas emissions.

      Today, hydrogen is largely produced through processes that involve natural gas and other fossil fuels, making the otherwise green fuel more of a “grey” energy source when considered from the start of its production to its end use. In contrast, solar thermochemical hydrogen, or STCH, offers a totally emissions-free alternative, as it relies entirely on renewable solar energy to drive hydrogen production. But so far, existing STCH designs have limited efficiency: Only about 7 percent of incoming sunlight is used to make hydrogen. The results so far have been low-yield and high-cost.

      In a big step toward realizing solar-made fuels, the MIT team estimates its new design could harness up to 40 percent of the sun’s heat to generate that much more hydrogen. The increase in efficiency could drive down the system’s overall cost, making STCH a potentially scalable, affordable option to help decarbonize the transportation industry.

      “We’re thinking of hydrogen as the fuel of the future, and there’s a need to generate it cheaply and at scale,” says the study’s lead author, Ahmed Ghoniem, the Ronald C. Crane Professor of Mechanical Engineering at MIT. “We’re trying to achieve the Department of Energy’s goal, which is to make green hydrogen by 2030, at $1 per kilogram. To improve the economics, we have to improve the efficiency and make sure most of the solar energy we collect is used in the production of hydrogen.”

      Ghoniem’s study co-authors are Aniket Patankar, first author and MIT postdoc; Harry Tuller, MIT professor of materials science and engineering; Xiao-Yu Wu of the University of Waterloo; and Wonjae Choi at Ewha Womans University in South Korea.

      Solar stations

      Similar to other proposed designs, the MIT system would be paired with an existing source of solar heat, such as a concentrated solar plant (CSP) — a circular array of hundreds of mirrors that collect and reflect sunlight to a central receiving tower. An STCH system then absorbs the receiver’s heat and directs it to split water and produce hydrogen. This process is very different from electrolysis, which uses electricity instead of heat to split water.

      At the heart of a conceptual STCH system is a two-step thermochemical reaction. In the first step, water in the form of steam is exposed to a metal. This causes the metal to grab oxygen from steam, leaving hydrogen behind. This metal “oxidation” is similar to the rusting of iron in the presence of water, but it occurs much faster. Once hydrogen is separated, the oxidized (or rusted) metal is reheated in a vacuum, which acts to reverse the rusting process and regenerate the metal. With the oxygen removed, the metal can be cooled and exposed to steam again to produce more hydrogen. This process can be repeated hundreds of times.

      The MIT system is designed to optimize this process. The system as a whole resembles a train of box-shaped reactors running on a circular track. In practice, this track would be set around a solar thermal source, such as a CSP tower. Each reactor in the train would house the metal that undergoes the redox, or reversible rusting, process.

      Each reactor would first pass through a hot station, where it would be exposed to the sun’s heat at temperatures of up to 1,500 degrees Celsius. This extreme heat would effectively pull oxygen out of a reactor’s metal. That metal would then be in a “reduced” state — ready to grab oxygen from steam. For this to happen, the reactor would move to a cooler station at temperatures around 1,000 C, where it would be exposed to steam to produce hydrogen.

      Rust and rails

      Other similar STCH concepts have run up against a common obstacle: what to do with the heat released by the reduced reactor as it is cooled. Without recovering and reusing this heat, the system’s efficiency is too low to be practical.

      A second challenge has to do with creating an energy-efficient vacuum where metal can de-rust. Some prototypes generate a vacuum using mechanical pumps, though the pumps are too energy-intensive and costly for large-scale hydrogen production.

      To address these challenges, the MIT design incorporates several energy-saving workarounds. To recover most of the heat that would otherwise escape from the system, reactors on opposite sides of the circular track are allowed to exchange heat through thermal radiation; hot reactors get cooled while cool reactors get heated. This keeps the heat within the system. The researchers also added a second set of reactors that would circle around the first train, moving in the opposite direction. This outer train of reactors would operate at generally cooler temperatures and would be used to evacuate oxygen from the hotter inner train, without the need for energy-consuming mechanical pumps.

      These outer reactors would carry a second type of metal that can also easily oxidize. As they circle around, the outer reactors would absorb oxygen from the inner reactors, effectively de-rusting the original metal, without having to use energy-intensive vacuum pumps. Both reactor trains would  run continuously and would enerate separate streams of pure hydrogen and oxygen.

      The researchers carried out detailed simulations of the conceptual design, and found that it would significantly boost the efficiency of solar thermochemical hydrogen production, from 7 percent, as previous designs have demonstrated, to 40 percent.

      “We have to think of every bit of energy in the system, and how to use it, to minimize the cost,” Ghoniem says. “And with this design, we found that everything can be powered by heat coming from the sun. It is able to use 40 percent of the sun’s heat to produce hydrogen.”

      “If this can be realized, it could drastically change our energy future — namely, enabling hydrogen production, 24/7,” says Christopher Muhich, an assistant professor of chemical engineering at Arizona State University, who was not involved in the research. “The ability to make hydrogen is the linchpin to producing liquid fuels from sunlight.”

      In the next year, the team will be building a prototype of the system that they plan to test in concentrated solar power facilities at laboratories of the Department of Energy, which is currently funding the project.

      “When fully implemented, this system would be housed in a little building in the middle of a solar field,” Patankar explains. “Inside the building, there could be one or more trains each having about 50 reactors. And we think this could be a modular system, where you can add reactors to a conveyor belt, to scale up hydrogen production.”

      This work was supported by the Centers for Mechanical Engineering Research and Education at MIT and SUSTech. More