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      in Environment

      Study: Rocks from Mars’ Jezero Crater, which likely predate life on Earth, contain signs of water

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      In a new study appearing today in the journal AGU Advances, scientists at MIT and NASA report that seven rock samples collected along the “fan front” of Mars’ Jezero Crater contain minerals that are typically formed in water. The findings suggest that the rocks were originally deposited by water, or may have formed in the presence of water.The seven samples were collected by NASA’s Perseverance rover in 2022 during its exploration of the crater’s western slope, where some rocks were hypothesized to have formed in what is now a dried-up ancient lake. Members of the Perseverance science team, including MIT scientists, have studied the rover’s images and chemical analyses of the samples, and confirmed that the rocks indeed contain signs of water, and that the crater was likely once a watery, habitable environment.Whether the crater was actually inhabited is yet unknown. The team found that the presence of organic matter — the starting material for life — cannot be confirmed, at least based on the rover’s measurements. But judging from the rocks’ mineral content, scientists believe the samples are their best chance of finding signs of ancient Martian life once the rocks are returned to Earth for more detailed analysis.“These rocks confirm the presence, at least temporarily, of habitable environments on Mars,” says the study’s lead author, Tanja Bosak, professor of geobiology in MIT’s Department of Earth, Atmospheric and Planetary Sciences (EAPS). “What we’ve found is that indeed there was a lot of water activity. For how long, we don’t know, but certainly for long enough to create these big sedimentary deposits.”What’s more, some of the collected samples may have originally been deposited in the ancient lake more than 3.5 billion years ago — before even the first signs of life on Earth.“These are the oldest rocks that may have been deposited by water, that we’ve ever laid hands or rover arms on,” says co-author Benjamin Weiss, the Robert R. Shrock Professor of Earth and Planetary Sciences at MIT. “That’s exciting, because it means these are the most promising rocks that may have preserved fossils, and signatures of life.”The study’s MIT co-authors include postdoc Eva Scheller, and research scientist Elias Mansbach, along with members of the Perseverance science team.At the front

      NASA’s Perseverance rover collected rock samples from two locations seen in this image of Mars’ Jezero Crater: “Wildcat Ridge” (lower left) and “Skinner Ridge” (upper right).

      Credit: NASA/JPL-Caltech/ASU/MSSS

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      The new rock samples were collected in 2022 as part of the rover’s Fan Front Campaign — an exploratory phase during which Perseverance traversed Jezero Crater’s western slope, where a fan-like region contains sedimentary, layered rocks. Scientists suspect that this “fan front” is an ancient delta that was created by sediment that flowed with a river and settled into a now bone-dry lakebed. If life existed on Mars, scientists believe that it could be preserved in the layers of sediment along the fan front.In the end, Perseverance collected seven samples from various locations along the fan front. The rover obtained each sample by drilling into the Martian bedrock and extracting a pencil-sized core, which it then sealed in a tube to one day be retrieved and returned to Earth for detailed analysis.

      Composed of multiple images from NASA’s Perseverance Mars rover, this mosaic shows a rocky outcrop called “Wildcat Ridge,” where the rover extracted two rock cores and abraded a circular patch to investigate the rock’s composition.

      Credit: NASA/JPL-Caltech/ASU/MSSS

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      Prior to extracting the cores, the rover took images of the surrounding sediments at each of the seven locations. The science team then processed the imaging data to estimate a sediment’s average grain size and mineral composition. This analysis showed that all seven collected samples likely contain signs of water, suggesting that they were initially deposited by water.Specifically, Bosak and her colleagues found evidence of certain minerals in the sediments that are known to precipitate out of water.“We found lots of minerals like carbonates, which are what make reefs on Earth,” Bosak says. “And it’s really an ideal material that can preserve fossils of microbial life.”Interestingly, the researchers also identified sulfates in some samples that were collected at the base of the fan front. Sulfates are minerals that form in very salty water — another sign that water was present in the crater at one time — though very salty water, Bosak notes, “is not necessarily the best thing for life.” If the entire crater was once filled with very salty water, then it would be difficult for any form of life to thrive. But if only the bottom of the lake were briny, that could be an advantage, at least for preserving any signs of life that may have lived further up, in less salty layers, that eventually died and drifted down to the bottom.“However salty it was, if there were any organics present, it’s like pickling something in salt,” Bosak says. “If there was life that fell into the salty layer, it would be very well-preserved.”Fuzzy fingerprintsBut the team emphasizes that organic matter has not been confidently detected by the rover’s instruments. Organic matter can be signs of life, but can also be produced by certain geological processes that have nothing to do with living matter. Perseverance’s predecessor, the Curiosity rover, had detected organic matter throughout Mars’ Gale Crater, which scientists suspect may have come from asteroids that made impact with Mars in the past.And in a previous campaign, Perseverance detected what appeared to be organic molecules at multiple locations along Jezero Crater’s floor. These observations were taken by the rover’s Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC) instrument, which uses ultraviolet light to scan the Martian surface. If organics are present, they can glow, similar to material under a blacklight. The wavelengths at which the material glows act as a sort of fingerprint for the kind of organic molecules that are present.In Perseverance’s previous exploration of the crater floor, SHERLOC appeared to pick up signs of organic molecules throughout the region, and later, at some locations along the fan front. But a careful analysis, led by MIT’s Eva Scheller, has found that while the particular wavelengths observed could be signs of organic matter, they could just as well be signatures of substances that have nothing to do with organic matter.“It turns out that cerium metals incorporated in minerals actually produce very similar signals as the organic matter,” Scheller says. “When investigated, the potential organic signals were strongly correlated with phosphate minerals, which always contain some cerium.”Scheller’s work shows that the rover’s measurements cannot be interpreted definitively as organic matter.“This is not bad news,” Bosak says. “It just tells us there is not very abundant organic matter. It’s still possible that it’s there. It’s just below the rover’s detection limit.”When the collected samples are finally sent back to Earth, Bosak says laboratory instruments will have more than enough sensitivity to detect any organic matter that might lie within.“On Earth, once we have microscopes with nanometer-scale resolution, and various types of instruments that we cannot staff on one rover, then we can actually attempt to look for life,” she says.This work was supported, in part, by NASA. More

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      MIT School of Science launches Center for Sustainability Science and Strategy

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      The MIT School of Science is launching a center to advance knowledge and computational capabilities in the field of sustainability science, and support decision-makers in government, industry, and civil society to achieve sustainable development goals. Aligned with the Climate Project at MIT, researchers at the MIT Center for Sustainability Science and Strategy will develop and apply expertise from across the Institute to improve understanding of sustainability challenges, and thereby provide actionable knowledge and insight to inform strategies for improving human well-being for current and future generations.Noelle Selin, professor at MIT’s Institute for Data, Systems and Society and the Department of Earth, Atmospheric and Planetary Sciences, will serve as the center’s inaugural faculty director. C. Adam Schlosser and Sergey Paltsev, senior research scientists at MIT, will serve as deputy directors, with Anne Slinn as executive director.Incorporating and succeeding both the Center for Global Change Science and Joint Program on the Science and Policy of Global Change while adding new capabilities, the center aims to produce leading-edge research to help guide societal transitions toward a more sustainable future. Drawing on the long history of MIT’s efforts to address global change and its integrated environmental and human dimensions, the center is well-positioned to lead burgeoning global efforts to advance the field of sustainability science, which seeks to understand nature-society systems in their full complexity. This understanding is designed to be relevant and actionable for decision-makers in government, industry, and civil society in their efforts to develop viable pathways to improve quality of life for multiple stakeholders.“As critical challenges such as climate, health, energy, and food security increasingly affect people’s lives around the world, decision-makers need a better understanding of the earth in its full complexity — and that includes people, technologies, and institutions as well as environmental processes,” says Selin. “Better knowledge of these systems and how they interact can lead to more effective strategies that avoid unintended consequences and ensure an improved quality of life for all.”    Advancing knowledge, computational capability, and decision supportTo produce more precise and comprehensive knowledge of sustainability challenges and guide decision-makers to formulate more effective strategies, the center has set the following goals:Advance fundamental understanding of the complex interconnected physical and socio-economic systems that affect human well-being. As new policies and technologies are developed amid climate and other global changes, they interact with environmental processes and institutions in ways that can alter the earth’s critical life-support systems. Fundamental mechanisms that determine many of these systems’ behaviors, including those related to interacting climate, water, food, and socio-economic systems, remain largely unknown and poorly quantified. Better understanding can help society mitigate the risks of abrupt changes and “tipping points” in these systems.Develop, establish and disseminate new computational tools toward better understanding earth systems, including both environmental and human dimensions. The center’s work will integrate modeling and data analysis across disciplines in an era of increasing volumes of observational data. MIT multi-system models and data products will provide robust information to inform decision-making and shape the next generation of sustainability science and strategy.Produce actionable science that supports equity and justice within and across generations. The center’s research will be designed to inform action associated with measurable outcomes aligned with supporting human well-being across generations. This requires engaging a broad range of stakeholders, including not only nations and companies, but also nongovernmental organizations and communities that take action to promote sustainable development — with special attention to those who have historically borne the brunt of environmental injustice.“The center’s work will advance fundamental understanding in sustainability science, leverage leading-edge computing and data, and promote engagement and impact,” says Selin. “Our researchers will help lead scientists and strategists across the globe who share MIT’s commitment to mobilizing knowledge to inform action toward a more sustainable world.”Building a better world at MITBuilding on existing MIT capabilities in sustainability, science, and strategy, the center aims to: focus research, education, and outreach under a theme that reflects a comprehensive state of the field and international research directions, fostering a dynamic community of students, researchers, and faculty;raise the visibility of sustainability science at MIT, emphasizing links between science and action, in the context of existing Institute goals and other efforts on climate and sustainability, and in a way that reflects the vital contributions of a range of natural and social science disciplines to understanding human-environment systems; andre-emphasize MIT’s long-standing expertise in integrated systems modeling while leveraging the Institute’s concurrent leading-edge strengths in data and computing, establishing leadership that harnesses recent innovations, including those in machine learning and artificial intelligence, toward addressing the science challenges of global change and sustainability.“The Center for Sustainability Science and Strategy will provide the necessary synergy for our MIT researchers to develop, deploy, and scale up serious solutions to climate change and other critical sustainability challenges,” says Nergis Mavalvala, the Curtis and Kathleen Marble Professor of Astrophysics and dean of the MIT School of Science. “With Professor Selin at its helm, the center will also ensure that these solutions are created in concert with the people who are directly affected now and in the future.”The center builds on more than three decades of achievements by the Center for Global Change Science and the Joint Program on the Science and Policy of Global Change, both of which were directed or co-directed by professor of atmospheric science Ronald Prinn. 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      in Environment

      Scientists find a human “fingerprint” in the upper troposphere’s increasing ozone

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      Ozone can be an agent of good or harm, depending on where you find it in the atmosphere. Way up in the stratosphere, the colorless gas shields the Earth from the sun’s harsh ultraviolet rays. But closer to the ground, ozone is a harmful air pollutant that can trigger chronic health problems including chest pain, difficulty breathing, and impaired lung function.And somewhere in between, in the upper troposphere — the layer of the atmosphere just below the stratosphere, where most aircraft cruise — ozone contributes to warming the planet as a potent greenhouse gas.There are signs that ozone is continuing to rise in the upper troposphere despite efforts to reduce its sources at the surface in many nations. Now, MIT scientists confirm that much of ozone’s increase in the upper troposphere is likely due to humans.In a paper appearing today in the journal Environmental Science and Technology, the team reports that they detected a clear signal of human influence on upper tropospheric ozone trends in a 17-year satellite record starting in 2005.“We confirm that there’s a clear and increasing trend in upper tropospheric ozone in the northern midlatitudes due to human beings rather than climate noise,” says study lead author Xinyuan Yu, a graduate student in MIT’s Department of Earth, Atmospheric and Planetary Sciences (EAPS).“Now we can do more detective work and try to understand what specific human activities are leading to this ozone trend,” adds co-author Arlene Fiore, the Peter H. Stone and Paola Malanotte Stone Professor in Earth, Atmospheric and Planetary Sciences.The study’s MIT authors include Sebastian Eastham and Qindan Zhu, along with Benjamin Santer at the University of California at Los Angeles, Gustavo Correa of Columbia University, Jean-François Lamarque at the National Center for Atmospheric Research, and Jerald Zimeke at NASA Goddard Space Flight Center.Ozone’s tangled webUnderstanding ozone’s causes and influences is a challenging exercise. Ozone is not emitted directly, but instead is a product of “precursors” — starting ingredients, such as nitrogen oxides and volatile organic compounds (VOCs), that react in the presence of sunlight to form ozone. These precursors are generated from vehicle exhaust, power plants, chemical solvents, industrial processes, aircraft emissions, and other human-induced activities.Whether and how long ozone lingers in the atmosphere depends on a tangle of variables, including the type and extent of human activities in a given area, as well as natural climate variability. For instance, a strong El Niño year could nudge the atmosphere’s circulation in a way that affects ozone’s concentrations, regardless of how much ozone humans are contributing to the atmosphere that year.Disentangling the human- versus climate-driven causes of ozone trend, particularly in the upper troposphere, is especially tricky. Complicating matters is the fact that in the lower troposphere — the lowest layer of the atmosphere, closest to ground level — ozone has stopped rising, and has even fallen in some regions at northern midlatitudes in the last few decades. This decrease in lower tropospheric ozone is mainly a result of efforts in North America and Europe to reduce industrial sources of air pollution.“Near the surface, ozone has been observed to decrease in some regions, and its variations are more closely linked to human emissions,” Yu notes. “In the upper troposphere, the ozone trends are less well-monitored but seem to decouple with those near the surface, and ozone is more easily influenced by climate variability. So, we don’t know whether and how much of that increase in observed ozone in the upper troposphere is attributed to humans.”A human signal amid climate noiseYu and Fiore wondered whether a human “fingerprint” in ozone levels, caused directly by human activities, could be strong enough to be detectable in satellite observations in the upper troposphere. To see such a signal, the researchers would first have to know what to look for.For this, they looked to simulations of the Earth’s climate and atmospheric chemistry. Following approaches developed in climate science, they reasoned that if they could simulate a number of possible climate variations in recent decades, all with identical human-derived sources of ozone precursor emissions, but each starting with a slightly different climate condition, then any differences among these scenarios should be due to climate noise. By inference, any common signal that emerged when averaging over the simulated scenarios should be due to human-driven causes. Such a signal, then, would be a “fingerprint” revealing human-caused ozone, which the team could look for in actual satellite observations.With this strategy in mind, the team ran simulations using a state-of-the-art chemistry climate model. They ran multiple climate scenarios, each starting from the year 1950 and running through 2014.From their simulations, the team saw a clear and common signal across scenarios, which they identified as a human fingerprint. They then looked to tropospheric ozone products derived from multiple instruments aboard NASA’s Aura satellite.“Quite honestly, I thought the satellite data were just going to be too noisy,” Fiore admits. “I didn’t expect that the pattern would be robust enough.”But the satellite observations they used gave them a good enough shot. The team looked through the upper tropospheric ozone data derived from the satellite products, from the years 2005 to 2021, and found that, indeed, they could see the signal of human-caused ozone that their simulations predicted. The signal is especially pronounced over Asia, where industrial activity has risen significantly in recent decades and where abundant sunlight and frequent weather events loft pollution, including ozone and its precursors, to the upper troposphere.Yu and Fiore are now looking to identify the specific human activities that are leading to ozone’s increase in the upper troposphere.“Where is this increasing trend coming from? Is it the near-surface emissions from combusting fossil fuels in vehicle engines and power plants? Is it the aircraft that are flying in the upper troposphere? Is it the influence of wildland fires? Or some combination of all of the above?” Fiore says. “Being able to separate human-caused impacts from natural climate variations can help to inform strategies to address climate change and air pollution.”This research was funded, in part, by NASA. More

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      in Environment

      Researchers return to Arctic to test integrated sensor nodes

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      Shimmering ice extends in all directions as far as the eye can see. Air temperatures plunge to minus 40 degrees Fahrenheit and colder with wind chills. Ocean currents drag large swaths of ice floating at sea. Polar bears, narwhals, and other iconic Arctic species roam wild.For a week this past spring, MIT Lincoln Laboratory researchers Ben Evans and Dave Whelihan called this place — drifting some 200 nautical miles offshore from Prudhoe Bay, Alaska, on the frozen Beaufort Sea in the Arctic Circle — home. Two ice runways for small aircraft provided their only way in and out of this remote wilderness; heated tents provided their only shelter from the bitter cold.

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      Video: MIT Lincoln Laboratory

      Here, in the northernmost region on Earth, Evans and Whelihan joined other groups conducting fieldwork in the Arctic as part of Operation Ice Camp (OIC) 2024, an operational exercise run by the U.S. Navy’s Arctic Submarine Laboratory (ASL). Riding on snowmobiles and helicopters, the duo deployed a small set of integrated sensor nodes that measure everything from atmospheric conditions to ice properties to the structure of water deep below the surface.Ultimately, they envision deploying an unattended network of these low-cost sensor nodes across the Arctic to increase scientific understanding of the trending loss in sea ice extent and thickness. Warming much faster than the rest of the world, the Arctic is a ground zero for climate change, with cascading impacts across the planet that include rising sea levels and extreme weather. Openings in the sea ice cover, or leads, are concerning not only for climate change but also for global geopolitical competition over transit routes and natural resources. A synoptic view of the physical processes happening above, at, and below sea ice is key to determining why the ice is diminishing. In turn, this knowledge can help predict when and where fractures will occur, to inform planning and decision-making.Winter “camp”Every two years, OIC, previously called Ice Exercise (ICEX), provides a way for the international community to access the Arctic for operational readiness exercises and scientific research, with the focus switching back and forth; this year’s focus was scientific research. Coordination, planning, and execution of the month-long operation is led by ASL, a division of the U.S. Navy’s Undersea Warfighting Development Center responsible for ensuring the submarine force can effectively operate in the Arctic Ocean.Making this inhospitable and unforgiving environment safe for participants takes considerable effort. The critical first step is determining where to set up camp. In the weeks before the first participants arrived for OIC 2024, ASL — with assistance from the U.S. National Ice Center, University of Alaska Fairbanks Geophysical Institute, and UIC Science — flew over large sheets of floating ice (ice floes) identified via satellite imagery, landed on some they thought might be viable sites, and drilled through the ice to check its thickness. The ice floe must not only be large enough to accommodate construction of a camp and two runways but also feature both multiyear ice and first-year ice. Multiyear ice is thick and strong but rough, making it ideal for camp setup, while the smooth but thinner first-year ice is better suited for building runways. Once the appropriate ice floe was selected, ASL began to haul in equipment and food, build infrastructure like lodging and a command center, and fly in a small group before fully operationalizing the site. They also identified locations near the camp for two Navy submarines to surface through the ice.The more than 200 participants represented U.S. and allied forces and scientists from research organizations and universities. Distinguished visitors from government offices also attended OIC to see the unique Arctic environment and unfolding challenges firsthand.“Our ASL hosts do incredible work to build this camp from scratch and keep us alive,” Evans says.Evans and Whelihan, part of the laboratory’s Advanced Undersea Systems and Technology Group, first trekked to the Arctic in March 2022 for ICEX 2022. (The laboratory in general has been participating since 2016 in these events, the first iteration of which occurred in 1946.) There, they deployed a suite of commercial off-the-shelf sensors for detecting acoustic (sound) and seismic (vibration) events created by ice fractures or collisions, and for measuring salinity, temperature, and pressure in the water below the ice. They also deployed a prototype fiber-based temperature sensor array developed by the laboratory and research partners for precisely measuring temperature across the entire water column at one location, and a University of New Hampshire (UNH)−supplied echosounder to investigate the different layers present in the water column. In this maiden voyage, their goals were to assess how these sensors fared in the harsh Arctic conditions and to collect a dataset from which characteristic signatures of ice-fracturing events could begin to be identified. These events would be correlated with weather and water conditions to eventually offer a predictive capability.“We saw real phenomenology in our data,” Whelihan says. “But, we’re not ice experts. What we’re good at here at the laboratory is making and deploying sensors. That’s our place in the world of climate science: to be a data provider. In fact, we hope to open source all of our data this year so that ice scientists can access and analyze them and then we can make enhanced sensors and collect more data.”Interim iceIn the two years since that expedition, they and their colleagues have been modifying their sensor designs and deployment strategies. As Evans and Whelihan learned at ICEX 2022, to be resilient in the Arctic, a sensor must not only be kept warm and dry during deployment but also be deployed in a way to prevent breaking. Moreover, sufficient power and data links are needed to collect and access sensor data.“We can make cold-weather electronics, no problem,” Whelihan says. “The two drivers are operating the sensors in an energy-starved environment — the colder it is, the worse batteries perform — and keeping them from getting destroyed when ice floes crash together as leads in the ice open up.”Their work in the interim to OIC 2024 involved integrating the individual sensors into hardened sensor nodes and practicing deploying these nodes in easier-to-access locations. To facilitate incorporating additional sensors into a node, Whelihan spearheaded the development of an open-source, easily extensible hardware and software architecture.In March 2023, the Lincoln Laboratory team deployed three sensor nodes for a week on Huron Bay off Lake Superior through Michigan Tech’s Great Lakes Research Center (GLRC). Engineers from GLRC helped the team safely set up an operations base on the ice. They demonstrated that the sensor integration worked, and the sensor nodes proved capable of surviving for at least a week in relatively harsh conditions. The researchers recorded seismic activity on all three nodes, corresponding to some ice breaking further up the bay.“Proving our sensor node in an Arctic surrogate environment provided a stepping stone for testing in the real Arctic,” Evans says.Evans then received an invitation from Ignatius Rigor, the coordinator of the International Arctic Buoy Program (IABP), to join him on an upcoming trip to Utqiaġvik (formerly Barrow), Alaska, and deploy one of their seismic sensor nodes on the ice there (with support from UIC Science). The IABP maintains a network of Arctic buoys equipped with meteorological and oceanic sensors. Data collected by these buoys are shared with the operational and research communities to support real-time operations (e.g., forecasting sea ice conditions for coastal Alaskans) and climate research. However, these buoys are typically limited in the frequency at which they collect data, so phenomenology on shorter time scales important to climate change may be missed. Moreover, these buoys are difficult and expensive to deploy because they are designed to survive in the harshest environments for years at a time.  The laboratory-developed sensor nodes could offer an inexpensive, easier-to-deploy option for collecting more data over shorter periods of time. In April 2023, Evans placed a sensor node in Utqiaġvik on landfast sea ice, which is stationary ice anchored to the seabed just off the coast. During the sensor node’s week-long deployment, a big piece of drift ice (ice not attached to the seabed or other fixed object) broke off and crashed into the landfast ice. The event was recorded by a radar maintained by the University of Alaska Fairbanks that monitors sea ice movement in near real time to warn of any instability. Though this phenomenology is not exactly the same as that expected for Arctic sea ice, the researchers were encouraged to see seismic activity recorded by their sensor node.In December 2023, Evans and Whelihan headed to New Hampshire, where they conducted echosounder testing in UNH’s engineering test tank and on the Piscataqua River. Together with their UNH partners, they sought to determine whether a low-cost, hobby-grade echosounder could detect the same phenomenology of interest as the high-fidelity UNH echosounder, which would be far too costly to deploy in sensor nodes across the Arctic. In the test tank and on the river, the low-cost echosounder proved capable of detecting masses of water moving in the water column, but with considerably less structural detail than afforded by the higher-cost option. Seeing such dynamics is important to inferring where water comes from and understanding how it affects sea ice breakup — for example, how warm water moving in from the Pacific Ocean is coming into contact with and melting the ice. So, the laboratory researchers and UNH partners have been building a medium-fidelity, medium-cost echosounder.In January 2024, Evans and Whelihan — along with Jehan Diaz, a fellow staff member in their research group — returned to GLRC. With logistical support from their GLRC hosts, they snowmobiled across the ice on Portage Lake, where they practiced several activities to prepare for OIC 2024: augering (drilling) six-inch holes in the ice, albeit in thinner ice than that in the Arctic; placing their long, pipe-like sensor nodes through these holes; operating cold-hardened drones to interact with the nodes; and retrieving the nodes. They also practiced sensor calibration by hitting the ice with an iron bar some distance away from the nodes and correlating this distance with the resulting measured acoustic and seismic intensity.“Our time at GLRC helped us mitigate a lot of risks and prepare to deploy these complex systems in the Arctic,” Whelihan says.Arctic againTo get to OIC, Evans and Whelihan first flew to Prudhoe Bay and reacclimated to the frigid temperatures. They spent the next two days at the Deadhorse Aviation Center hangar inspecting their equipment for transit-induced damage, which included squashed cables and connectors that required rejiggering.“That’s part of the adventure story,” Evans says. “Getting stuff to Prudhoe Bay is not your standard shipping; it’s ice-road trucking.”From there, they boarded a small aircraft to the ice camp.“Even though this trip marked our second time coming here, it was still disorienting,” Evans continues. “You land in the middle of nowhere on a small aircraft after a couple-hour flight. You get out bundled in all of your Arctic gear in this remote, pristine environment.”After unloading and rechecking their equipment for any damage, calibrating their sensors, and attending safety briefings, they were ready to begin their experiments.An icy situationInside the project tent, Evans and Whelihan deployed the UNH-supplied echosounder and a suite of ground-truth sensors on an automated winch to profile water conductivity, temperature, and depth (CTD). Echosounder data needed to be validated with associated CTD data to determine the source of the water in the water column. Ocean properties change as a function of depth, and these changes are important to capture, in part because masses of water coming in from the Atlantic and Pacific oceans arrive at different depths. Though masses of warm water have always existed, climate change–related mechanisms are now bringing them into contact with the ice.  “As ice breaks up, wind can directly interact with the ocean because it’s lacking that barrier of ice cover,” Evans explains. “Kinetic energy from the wind causes mixing in the ocean; all the warm water that used to stay at depth instead gets brought up and interacts with the ice.”They also deployed four of their sensor nodes several miles outside of camp. To access this deployment site, they rode on a sled pulled via a snowmobile driven by Ann Hill, an ASL field party leader trained in Arctic survival and wildlife encounters. The temperature that day was -55 F. At such a dangerously cold temperature, frostnip and frostbite are all too common. To avoid removal of gloves or other protective clothing, the researchers enabled the nodes with WiFi capability (the nodes also have a satellite communications link to transmit low-bandwidth data). Large amounts of data are automatically downloaded over WiFi to an arm-wearable haptic (touch-based) system when a user walks up to a node.“It was so cold that the holes we were drilling in the ice to reach the water column were freezing solid,” Evans explains. “We realized it was going to be quite an ordeal to get our sensor nodes out of the ice.”So, after drilling a big hole in the ice, they deployed only one central node with all the sensor components: a commercial echosounder, an underwater microphone, a seismometer, and a weather station. They deployed the other three nodes, each with a seismometer and weather station, atop the ice.“One of our design considerations was flexibility,” Whelihan says. “Each node can integrate as few or as many sensors as desired.”The small sensor array was only collecting data for about a day when Evans and Whelihan, who were at the time on a helicopter, saw that their initial field site had become completely cut off from camp by a 150-meter-wide ice lead. They quickly returned to camp to load the tools needed to pull the nodes, which were no longer accessible by snowmobile. Two recently arrived staff members from the Ted Stevens Center for Arctic Security Studies offered to help them retrieve their nodes. The helicopter landed on the ice floe near a crack, and the pilot told them they had half an hour to complete their recovery mission. By the time they had retrieved all four sensors, the crack had increased from thumb to fist size.“When we got home, we analyzed the collected sensor data and saw a spike in seismic activity corresponding to what could be the major ice-fracturing event that necessitated our node recovery mission,” Whelihan says.  The researchers also conducted experiments with their Arctic-hardened drones to evaluate their utility for retrieving sensor node data and to develop concepts of operations for future capabilities.“The idea is to have some autonomous vehicle land next to the node, download data, and come back, like a data mule, rather than having to expend energy getting data off the system, say via high-speed satellite communications,” Whelihan says. “We also started testing whether the drone is capable on its own of finding sensors that are constantly moving and getting close enough to them. Even flying in 25-mile-per-hour winds, and at very low temperatures, the drone worked well.”Aside from carrying out their experiments, the researchers had the opportunity to interact with other participants. Their “roommates” were ice scientists from Norway and Finland. They met other ice and water scientists conducting chemistry experiments on the salt content of ice taken from different depths in the ice sheet (when ocean water freezes, salt tends to get pushed out of the ice). One of their collaborators — Nicholas Schmerr, an ice seismologist from the University of Maryland — placed high-quality geophones (for measuring vibrations in the ice) alongside their nodes deployed on the camp field site. They also met with junior enlisted submariners, who temporarily came to camp to open up spots on the submarine for distinguished visitors.“Part of what we’ve been doing over the last three years is building connections within the Arctic community,” Evans says. “Every time I start to get a handle on the phenomenology that exists out here, I learn something new. For example, I didn’t know that sometimes a layer of ice forms a little bit deeper than the primary ice sheet, and you can actually see fish swimming in between the layers.”“One day, we were out with our field party leader, who saw fog while she was looking at the horizon and said the ice was breaking up,” Whelihan adds. “I said, ‘Wait, what?’ As she explained, when an ice lead forms, fog comes out of the ocean. Sure enough, within 30 minutes, we had quarter-mile visibility, whereas beforehand it was unlimited.”Back to solid groundBefore leaving, Whelihan and Evans retrieved and packed up all the remaining sensor nodes, adopting the “leave no trace” philosophy of preserving natural places.“Only a limited number of people get access to this special environment,” Whelihan says. “We hope to grow our footprint at these events in future years, giving opportunities to other laboratory staff members to attend.”In the meantime, they will analyze the collected sensor data and refine their sensor node design. One design consideration is how to replenish the sensors’ battery power. A potential path forward is to leverage the temperature difference between water and air, and harvest energy from the water currents moving under ice floes. Wind energy may provide another viable solution. Solar power would only work for part of the year because the Arctic Circle undergoes periods of complete darkness.The team is also seeking external sponsorship to continue their work engineering sensing systems that advance the scientific community’s understanding of changes to Arctic ice; this work is currently funded through Lincoln Laboratory’s internally administered R&D portfolio on climate change. And, in learning more about this changing environment and its critical importance to strategic interests, they are considering other sensing problems that they could tackle using their Arctic engineering expertise.“The Arctic is becoming a more visible and important region because of how it’s changing,” Evans concludes. “Going forward as a country, we must be able to operate there.” More

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      in Energy

      Proton-conducting materials could enable new green energy technologies

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      As the name suggests, most electronic devices today work through the movement of electrons. But materials that can efficiently conduct protons — the nucleus of the hydrogen atom — could be key to a number of important technologies for combating global climate change.Most proton-conducting inorganic materials available now require undesirably high temperatures to achieve sufficiently high conductivity. However, lower-temperature alternatives could enable a variety of technologies, such as more efficient and durable fuel cells to produce clean electricity from hydrogen, electrolyzers to make clean fuels such as hydrogen for transportation, solid-state proton batteries, and even new kinds of computing devices based on iono-electronic effects.In order to advance the development of proton conductors, MIT engineers have identified certain traits of materials that give rise to fast proton conduction. Using those traits quantitatively, the team identified a half-dozen new candidates that show promise as fast proton conductors. Simulations suggest these candidates will perform far better than existing materials, although they still need to be conformed experimentally. In addition to uncovering potential new materials, the research also provides a deeper understanding at the atomic level of how such materials work.The new findings are described in the journal Energy and Environmental Sciences, in a paper by MIT professors Bilge Yildiz and Ju Li, postdocs Pjotrs Zguns and Konstantin Klyukin, and their collaborator Sossina Haile and her students from Northwestern University. Yildiz is the Breene M. Kerr Professor in the departments of Nuclear Science and Engineering, and Materials Science and Engineering.“Proton conductors are needed in clean energy conversion applications such as fuel cells, where we use hydrogen to produce carbon dioxide-free electricity,” Yildiz explains. “We want to do this process efficiently, and therefore we need materials that can transport protons very fast through such devices.”Present methods of producing hydrogen, for example steam methane reforming, emit a great deal of carbon dioxide. “One way to eliminate that is to electrochemically produce hydrogen from water vapor, and that needs very good proton conductors,” Yildiz says. Production of other important industrial chemicals and potential fuels, such as ammonia, can also be carried out through efficient electrochemical systems that require good proton conductors.But most inorganic materials that conduct protons can only operate at temperatures of 200 to 600 degrees Celsius (roughly 450 to 1,100 Fahrenheit), or even higher. Such temperatures require energy to maintain and can cause degradation of materials. “Going to higher temperatures is not desirable because that makes the whole system more challenging, and the material durability becomes an issue,” Yildiz says. “There is no good inorganic proton conductor at room temperature.” Today, the only known room-temperature proton conductor is a polymeric material that is not practical for applications in computing devices because it can’t easily be scaled down to the nanometer regime, she says.To tackle the problem, the team first needed to develop a basic and quantitative understanding of exactly how proton conduction works, taking a class of inorganic proton conductors, called solid acids. “One has to first understand what governs proton conduction in these inorganic compounds,” she says. While looking at the materials’ atomic configurations, the researchers identified a pair of characteristics that directly relates to the materials’ proton-carrying potential.As Yildiz explains, proton conduction first involves a proton “hopping from a donor oxygen atom to an acceptor oxygen. And then the environment has to reorganize and take the accepted proton away, so that it can hop to another neighboring acceptor, enabling long-range proton diffusion.” This process happens in many inorganic solids, she says. Figuring out how that last part works — how the atomic lattice gets reorganized to take the accepted proton away from the original donor atom — was a key part of this research, she says.The researchers used computer simulations to study a class of materials called solid acids that become good proton conductors above 200 degrees Celsius. This class of materials has a substructure called the polyanion group sublattice, and these groups have to rotate and take the proton away from its original site so it can then transfer to other sites. The researchers were able to identify the phonons that contribute to the flexibility of this sublattice, which is essential for proton conduction. Then they used this information to comb through vast databases of theoretically and experimentally possible compounds, in search of better proton conducting materials.As a result, they found solid acid compounds that are promising proton conductors and that have been developed and produced for a variety of different applications but never before studied as proton conductors; these compounds turned out to have just the right characteristics of lattice flexibility. The team then carried out computer simulations of how the specific materials they identified in their initial screening would perform under relevant temperatures, to confirm their suitability as proton conductors for fuel cells or other uses. Sure enough, they found six promising materials, with predicted proton conduction speeds faster than the best existing solid acid proton conductors.“There are uncertainties in these simulations,” Yildiz cautions. “I don’t want to say exactly how much higher the conductivity will be, but these look very promising. Hopefully this motivates the experimental field to try to synthesize them in different forms and make use of these compounds as proton conductors.”Translating these theoretical findings into practical devices could take some years, she says. The likely first applications would be for electrochemical cells to produce fuels and chemical feedstocks such as hydrogen and ammonia, she says.The work was supported by the U.S. Department of Energy, the Wallenberg Foundation, and the U.S. National Science Foundation. More

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      in Environment

      China-based emissions of three potent climate-warming greenhouse gases spiked in past decade

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      When it comes to heating up the planet, not all greenhouse gases are created equal. They vary widely in their global warming potential (GWP), a measure of how much infrared thermal radiation a greenhouse gas would absorb over a given time frame once it enters the atmosphere. For example, measured over a 100-year period, the GWP of methane is about 28 times that of carbon dioxide (CO2), and the GWPs of a class of greenhouse gases known as perfluorocarbons (PFCs) are thousands of times that of CO2. The lifespans in the atmosphere of different greenhouse gases also vary widely. Methane persists in the atmosphere for around 10 years; CO2 for over 100 years, and PFCs for up to tens of thousands of years.Given the high GWPs and lifespans of PFCs, their emissions could pose a major roadblock to achieving the aspirational goal of the Paris Agreement on climate change — to limit the increase in global average surface temperature to 1.5 degrees Celsius above preindustrial levels. Now, two new studies based on atmospheric observations inside China and high-resolution atmospheric models show a rapid rise in Chinese emissions over the last decade (2011 to 2020 or 2021) of three PFCs: tetrafluoromethane (PFC-14) and hexafluoroethane (PFC-116) (results in PNAS), and perfluorocyclobutane (PFC-318) (results in Environmental Science & Technology).Both studies find that Chinese emissions have played a dominant role in driving up global emission levels for all three PFCs.The PNAS study identifies substantial PFC-14 and PFC-116 emission sources in the less-populated western regions of China from 2011 to 2021, likely due to the large amount of aluminum industry in these regions. The semiconductor industry also contributes to some of the emissions detected in the more economically developed eastern regions. These emissions are byproducts from aluminum smelting, or occur during the use of the two PFCs in the production of semiconductors and flat panel displays. During the observation period, emissions of both gases in China rose by 78 percent, accounting for most of the increase in global emissions of these gases.The ES&T study finds that during 2011-20, a 70 percent increase in Chinese PFC-318 emissions (contributing more than half of the global emissions increase of this gas) — originated primarily in eastern China. The regions with high emissions of PFC-318 in China overlap with geographical areas densely populated with factories that produce polytetrafluoroethylene (PTFE, commonly used for nonstick cookware coatings), implying that PTFE factories are major sources of PFC-318 emissions in China. In these factories, PFC-318 is formed as a byproduct.“Using atmospheric observations from multiple monitoring sites, we not only determined the magnitudes of PFC emissions, but also pinpointed the possible locations of their sources,” says Minde An, a postdoc at the MIT Center for Global Change Science (CGCS), and corresponding author of both studies. “Identifying the actual source industries contributing to these PFC emissions, and understanding the reasons for these largely byproduct emissions, can provide guidance for developing region- or industry-specific mitigation strategies.”“These three PFCs are largely produced as unwanted byproducts during the manufacture of otherwise widely used industrial products,” says MIT professor of atmospheric sciences Ronald Prinn, director of both the MIT Joint Program on the Science and Policy of Global Change and CGCS, and a co-author of both studies. “Phasing out emissions of PFCs as early as possible is highly beneficial for achieving global climate mitigation targets and is likely achievable by recycling programs and targeted technological improvements in these industries.”Findings in both studies were obtained, in part, from atmospheric observations collected from nine stations within a Chinese network, including one station from the Advanced Global Atmospheric Gases Experiment (AGAGE) network. For comparison, global total emissions were determined from five globally distributed, relatively unpolluted “background” AGAGE stations, as reported in the latest United Nations Environment Program and World Meteorological Organization Ozone Assessment report. More

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      in Energy

      AI method radically speeds predictions of materials’ thermal properties

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      It is estimated that about 70 percent of the energy generated worldwide ends up as waste heat.If scientists could better predict how heat moves through semiconductors and insulators, they could design more efficient power generation systems. However, the thermal properties of materials can be exceedingly difficult to model.The trouble comes from phonons, which are subatomic particles that carry heat. Some of a material’s thermal properties depend on a measurement called the phonon dispersion relation, which can be incredibly hard to obtain, let alone utilize in the design of a system.A team of researchers from MIT and elsewhere tackled this challenge by rethinking the problem from the ground up. The result of their work is a new machine-learning framework that can predict phonon dispersion relations up to 1,000 times faster than other AI-based techniques, with comparable or even better accuracy. Compared to more traditional, non-AI-based approaches, it could be 1 million times faster.This method could help engineers design energy generation systems that produce more power, more efficiently. It could also be used to develop more efficient microelectronics, since managing heat remains a major bottleneck to speeding up electronics.“Phonons are the culprit for the thermal loss, yet obtaining their properties is notoriously challenging, either computationally or experimentally,” says Mingda Li, associate professor of nuclear science and engineering and senior author of a paper on this technique.Li is joined on the paper by co-lead authors Ryotaro Okabe, a chemistry graduate student; and Abhijatmedhi Chotrattanapituk, an electrical engineering and computer science graduate student; Tommi Jaakkola, the Thomas Siebel Professor of Electrical Engineering and Computer Science at MIT; as well as others at MIT, Argonne National Laboratory, Harvard University, the University of South Carolina, Emory University, the University of California at Santa Barbara, and Oak Ridge National Laboratory. The research appears in Nature Computational Science.Predicting phononsHeat-carrying phonons are tricky to predict because they have an extremely wide frequency range, and the particles interact and travel at different speeds.A material’s phonon dispersion relation is the relationship between energy and momentum of phonons in its crystal structure. For years, researchers have tried to predict phonon dispersion relations using machine learning, but there are so many high-precision calculations involved that models get bogged down.“If you have 100 CPUs and a few weeks, you could probably calculate the phonon dispersion relation for one material. The whole community really wants a more efficient way to do this,” says Okabe.The machine-learning models scientists often use for these calculations are known as graph neural networks (GNN). A GNN converts a material’s atomic structure into a crystal graph comprising multiple nodes, which represent atoms, connected by edges, which represent the interatomic bonding between atoms.While GNNs work well for calculating many quantities, like magnetization or electrical polarization, they are not flexible enough to efficiently predict an extremely high-dimensional quantity like the phonon dispersion relation. Because phonons can travel around atoms on X, Y, and Z axes, their momentum space is hard to model with a fixed graph structure.To gain the flexibility they needed, Li and his collaborators devised virtual nodes.They create what they call a virtual node graph neural network (VGNN) by adding a series of flexible virtual nodes to the fixed crystal structure to represent phonons. The virtual nodes enable the output of the neural network to vary in size, so it is not restricted by the fixed crystal structure.Virtual nodes are connected to the graph in such a way that they can only receive messages from real nodes. While virtual nodes will be updated as the model updates real nodes during computation, they do not affect the accuracy of the model.“The way we do this is very efficient in coding. You just generate a few more nodes in your GNN. The physical location doesn’t matter, and the real nodes don’t even know the virtual nodes are there,” says Chotrattanapituk.Cutting out complexitySince it has virtual nodes to represent phonons, the VGNN can skip many complex calculations when estimating phonon dispersion relations, which makes the method more efficient than a standard GNN. The researchers proposed three different versions of VGNNs with increasing complexity. Each can be used to predict phonons directly from a material’s atomic coordinates.Because their approach has the flexibility to rapidly model high-dimensional properties, they can use it to estimate phonon dispersion relations in alloy systems. These complex combinations of metals and nonmetals are especially challenging for traditional approaches to model.The researchers also found that VGNNs offered slightly greater accuracy when predicting a material’s heat capacity. In some instances, prediction errors were two orders of magnitude lower with their technique.A VGNN could be used to calculate phonon dispersion relations for a few thousand materials in just a few seconds with a personal computer, Li says.This efficiency could enable scientists to search a larger space when seeking materials with certain thermal properties, such as superior thermal storage, energy conversion, or superconductivity.Moreover, the virtual node technique is not exclusive to phonons, and could also be used to predict challenging optical and magnetic properties.In the future, the researchers want to refine the technique so virtual nodes have greater sensitivity to capture small changes that can affect phonon structure.“Researchers got too comfortable using graph nodes to represent atoms, but we can rethink that. Graph nodes can be anything. And virtual nodes are a very generic approach you could use to predict a lot of high-dimensional quantities,” Li says.“The authors’ innovative approach significantly augments the graph neural network description of solids by incorporating key physics-informed elements through virtual nodes, for instance, informing wave-vector dependent band-structures and dynamical matrices,” says Olivier Delaire, associate professor in the Thomas Lord Department of Mechanical Engineering and Materials Science at Duke University, who was not involved with this work. “I find that the level of acceleration in predicting complex phonon properties is amazing, several orders of magnitude faster than a state-of-the-art universal machine-learning interatomic potential. Impressively, the advanced neural net captures fine features and obeys physical rules. There is great potential to expand the model to describe other important material properties: Electronic, optical, and magnetic spectra and band structures come to mind.”This work is supported by the U.S. Department of Energy, National Science Foundation, a Mathworks Fellowship, a Sow-Hsin Chen Fellowship, the Harvard Quantum Initiative, and the Oak Ridge National Laboratory. More

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      in Environment

      Study finds health risks in switching ships from diesel to ammonia fuel

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      As container ships the size of city blocks cross the oceans to deliver cargo, their huge diesel engines emit large quantities of air pollutants that drive climate change and have human health impacts. It has been estimated that maritime shipping accounts for almost 3 percent of global carbon dioxide emissions and the industry’s negative impacts on air quality cause about 100,000 premature deaths each year.Decarbonizing shipping to reduce these detrimental effects is a goal of the International Maritime Organization, a U.N. agency that regulates maritime transport. One potential solution is switching the global fleet from fossil fuels to sustainable fuels such as ammonia, which could be nearly carbon-free when considering its production and use.But in a new study, an interdisciplinary team of researchers from MIT and elsewhere caution that burning ammonia for maritime fuel could worsen air quality further and lead to devastating public health impacts, unless it is adopted alongside strengthened emissions regulations.Ammonia combustion generates nitrous oxide (N2O), a greenhouse gas that is about 300 times more potent than carbon dioxide. It also emits nitrogen in the form of nitrogen oxides (NO and NO2, referred to as NOx), and unburnt ammonia may slip out, which eventually forms fine particulate matter in the atmosphere. These tiny particles can be inhaled deep into the lungs, causing health problems like heart attacks, strokes, and asthma.The new study indicates that, under current legislation, switching the global fleet to ammonia fuel could cause up to about 600,000 additional premature deaths each year. However, with stronger regulations and cleaner engine technology, the switch could lead to about 66,000 fewer premature deaths than currently caused by maritime shipping emissions, with far less impact on global warming.“Not all climate solutions are created equal. There is almost always some price to pay. We have to take a more holistic approach and consider all the costs and benefits of different climate solutions, rather than just their potential to decarbonize,” says Anthony Wong, a postdoc in the MIT Center for Global Change Science and lead author of the study.His co-authors include Noelle Selin, an MIT professor in the Institute for Data, Systems, and Society and the Department of Earth, Atmospheric and Planetary Sciences (EAPS); Sebastian Eastham, a former principal research scientist who is now a senior lecturer at Imperial College London; Christine Mounaïm-Rouselle, a professor at the University of Orléans in France; Yiqi Zhang, a researcher at the Hong Kong University of Science and Technology; and Florian Allroggen, a research scientist in the MIT Department of Aeronautics and Astronautics. The research appears this week in Environmental Research Letters.Greener, cleaner ammoniaTraditionally, ammonia is made by stripping hydrogen from natural gas and then combining it with nitrogen at extremely high temperatures. This process is often associated with a large carbon footprint. The maritime shipping industry is betting on the development of “green ammonia,” which is produced by using renewable energy to make hydrogen via electrolysis and to generate heat.“In theory, if you are burning green ammonia in a ship engine, the carbon emissions are almost zero,” Wong says.But even the greenest ammonia generates nitrous oxide (N2O), nitrogen oxides (NOx) when combusted, and some of the ammonia may slip out, unburnt. This nitrous oxide would escape into the atmosphere, where the greenhouse gas would remain for more than 100 years. At the same time, the nitrogen emitted as NOx and ammonia would fall to Earth, damaging fragile ecosystems. As these emissions are digested by bacteria, additional N2O  is produced.NOx and ammonia also mix with gases in the air to form fine particulate matter. A primary contributor to air pollution, fine particulate matter kills an estimated 4 million people each year.“Saying that ammonia is a ‘clean’ fuel is a bit of an overstretch. Just because it is carbon-free doesn’t necessarily mean it is clean and good for public health,” Wong says.A multifaceted modelThe researchers wanted to paint the whole picture, capturing the environmental and public health impacts of switching the global fleet to ammonia fuel. To do so, they designed scenarios to measure how pollutant impacts change under certain technology and policy assumptions.From a technological point of view, they considered two ship engines. The first burns pure ammonia, which generates higher levels of unburnt ammonia but emits fewer nitrogen oxides. The second engine technology involves mixing ammonia with hydrogen to improve combustion and optimize the performance of a catalytic converter, which controls both nitrogen oxides and unburnt ammonia pollution.They also considered three policy scenarios: current regulations, which only limit NOx emissions in some parts of the world; a scenario that adds ammonia emission limits over North America and Western Europe; and a scenario that adds global limits on ammonia and NOx emissions.The researchers used a ship track model to calculate how pollutant emissions change under each scenario and then fed the results into an air quality model. The air quality model calculates the impact of ship emissions on particulate matter and ozone pollution. Finally, they estimated the effects on global public health.One of the biggest challenges came from a lack of real-world data, since no ammonia-powered ships are yet sailing the seas. Instead, the researchers relied on experimental ammonia combustion data from collaborators to build their model.“We had to come up with some clever ways to make that data useful and informative to both the technology and regulatory situations,” he says.A range of outcomesIn the end, they found that with no new regulations and ship engines that burn pure ammonia, switching the entire fleet would cause 681,000 additional premature deaths each year.“While a scenario with no new regulations is not very realistic, it serves as a good warning of how dangerous ammonia emissions could be. And unlike NOx, ammonia emissions from shipping are currently unregulated,” Wong says.However, even without new regulations, using cleaner engine technology would cut the number of premature deaths down to about 80,000, which is about 20,000 fewer than are currently attributed to maritime shipping emissions. With stronger global regulations and cleaner engine technology, the number of people killed by air pollution from shipping could be reduced by about 66,000.“The results of this study show the importance of developing policies alongside new technologies,” Selin says. “There is a potential for ammonia in shipping to be beneficial for both climate and air quality, but that requires that regulations be designed to address the entire range of potential impacts, including both climate and air quality.”Ammonia’s air quality impacts would not be felt uniformly across the globe, and addressing them fully would require coordinated strategies across very different contexts. Most premature deaths would occur in East Asia, since air quality regulations are less stringent in this region. Higher levels of existing air pollution cause the formation of more particulate matter from ammonia emissions. In addition, shipping volume over East Asia is far greater than elsewhere on Earth, compounding these negative effects.In the future, the researchers want to continue refining their analysis. They hope to use these findings as a starting point to urge the marine industry to share engine data they can use to better evaluate air quality and climate impacts. They also hope to inform policymakers about the importance and urgency of updating shipping emission regulations.This research was funded by the MIT Climate and Sustainability Consortium. More