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      in Energy

      Finding community in high-energy-density physics

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      Skylar Dannhoff knew one thing: She did not want to be working alone.

      As an undergraduate at Case Western Reserve University, she had committed to a senior project that often felt like solitary lab work, a feeling heightened by the pandemic. Though it was an enriching experience, she was determined to find a graduate school environment that would foster community, one “with lots of people, lots of collaboration; where it’s impossible to work until 3 a.m. without anyone noticing.” A unique group at the Plasma Science and Fusion Center (PSFC) looked promising: the High-Energy-Density Physics (HEDP) division, a lead partner in the National Nuclear Security Administration’s Center for Excellence at MIT.

      “It was a shot in the dark, just more of a whim than anything,” she says of her request to join HEDP on her application to MIT’s Department of Physics. “And then, somehow, they reached out to me. I told them I’m willing to learn about plasma. I didn’t know anything about it.”

      What she did know was that the HEDP group collaborates with other U.S. laboratories on an approach to creating fusion energy known as inertial confinement fusion (ICF). One version of the technique, known as direct-drive ICF, aims multiple laser beams symmetrically onto a spherical capsule filled with nuclear fuel. The other, indirect-drive ICF, instead aims multiple lasers beams into a gold cylindrical cavity called a hohlraum, within which the spherical fuel capsule is positioned. The laser beams are configured to hit the inner hohlraum wall, generating a “bath” of X-rays, which in turn compress the fuel capsule.

      Imploding the capsule generates intense fusion energy within a tiny fraction of a second (an order of tens of picoseconds). In August 2021, the National Ignition Facility (NIF) at Lawrence Livermore National Laboratory (LLNL) used this method to produce an historic fusion yield of 1.3 megajoules, putting researchers within reach of “ignition,” the point where the self-sustained fusion burn spreads into the surrounding fuel, leading to a high fusion-energy gain.  

      Joining the group just a month before this long-sought success, Dannhoff was impressed more with the response of her new teammates and the ICF community than with the scientific milestone. “I got a better appreciation for people who had spent their entire careers working on this project, just chugging along doing their best, ignoring the naysayers. I was excited for the people.”

      Dannhoff is now working toward extending the success of NIF and other ICF experiments, like the OMEGA laser at the University of Rochester’s Laboratory for Laser Energetics. Under the supervision of Senior Research Scientist Chikang Li, she is studying what happens to the flow of plasma within the hohlraum cavity during indirect ICF experiments, particularly for hohlraums with inner-wall aerogel foam linings. Experiments, over the last decade, have shown just how excruciatingly precise the symmetry in ICF targets must be. The more symmetric the X-ray drive, the more effective the implosion, and it is possible that these foam linings will improve the X-ray symmetry and drive efficiency.

      Dannhoff is specifically interested in studying the behavior of silicon and tantalum-based foam liners. She is as concerned with the challenges of the people at General Atomics (GA) and LLNL who are creating these targets as she is with the scientific outcome.

      “I just had a meeting with GA yesterday,” she notes. “And it’s a really tricky process. It’s kind of pushing the boundaries of what is doable at the moment. I got a much better sense of how demanding this project is for them, how much we’re asking of them.”

      What excites Dannhoff is the teamwork she observes, both at MIT and between ICF institutions around the United States. With roughly 10 graduate students and postdocs down the hall, each with an assigned lead role in lab management, she knows she can consult an expert on almost any question. And collaborators across the country are just an email away. “Any information that people can give you, they will give you, and usually very freely,” she notes. “Everyone just wants to see this work.”

      That Dannhoff is a natural team player is also evidenced in her hobbies. A hockey goalie, she prioritizes playing with MIT’s intramural teams, “because goalies are a little hard to come by. I just play with whoever needs a goalie on that night, and it’s a lot of fun.”

      She is also a member of the radio community, a fellowship she first embraced at Case Western — a moment she describes as a turning point in her life. “I literally don’t know who I would be today if I hadn’t figured out radio is something I’m interested in,” she admits. The MIT Radio Society provided the perfect landing pad for her arrival in Cambridge, full of the kinds of supportive, interesting, knowledgeable students she had befriended as an undergraduate. She credits radio with helping her realize that she could make her greatest contributions to science by focusing on engineering.

      Danhoff gets philosophical as she marvels at the invisible waves that surround us.

      “Not just radio waves: every wave,” she asserts. “The voice is the everywhere. Music, signal, space phenomena: it’s always around. And all we have to do is make the right little device and have the right circuit elements put in the right order to unmix and mix the signals and amplify them. And bada-bing, bada-boom, we’re talking with the universe.”

      “Maybe that epitomizes physics to me,” she adds. “We’re trying to listen to the universe, and it’s talking to us. We just have to come up with the right tools and hear what it’s trying to say.” More

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      in Environment

      Studying floods to better predict their dangers

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      “My job is basically flooding Cambridge,” says Katerina “Katya” Boukin, a graduate student in civil and environmental engineering at MIT and the MIT Concrete Sustainability Hub’s resident expert on flood simulations. 

      You can often find her fine-tuning high-resolution flood risk models for the City of Cambridge, Massachusetts, or talking about hurricanes with fellow researcher Ipek Bensu Manav.

      Flooding represents one of the world’s gravest natural hazards. Extreme climate events inducing flooding, like severe storms, winter storms, and tropical cyclones, caused an estimated $128.1 billion of damages in 2021 alone. 

      Climate simulation models suggest that severe storms will become more frequent in the coming years, necessitating a better understanding of which parts of cities are most vulnerable — an understanding that can be improved through modeling.

      A problem with current flood models is that they struggle to account for an oft-misunderstood type of flooding known as pluvial flooding. 

      “You might think of flooding as the overflowing of a body of water, like a river. This is fluvial flooding. This can be somewhat predictable, as you can think of proximity to water as a risk factor,” Boukin explains.

      However, the “flash flooding” that causes many deaths each year can happen even in places nowhere near a body of water. This is an example of pluvial flooding, which is affected by terrain, urban infrastructure, and the dynamic nature of storm loads.

      “If we don’t know how a flood is propagating, we don’t know the risk it poses to the urban environment. And if we don’t understand the risk, we can’t really discuss mitigation strategies,” says Boukin, “That’s why I pursue improving flood propagation models.”

      Boukin is leading development of a new flood prediction method that seeks to address these shortcomings. By better representing the complex morphology of cities, Boukin’s approach may provide a clearer forecast of future urban flooding.

      Katya Boukin developed this model of the City of Cambridge, Massachusetts. The base model was provided through a collaboration between MIT, the City of Cambridge, and Dewberry Engineering.

      Image: Katya Boukin

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      “In contrast to the more typical traditional catchment model, our method has rainwater spread around the urban environment based on the city’s topography, below-the-surface features like sewer pipes, and the characteristics of local soils,” notes Boukin.

      “We can simulate the flooding of regions with local rain forecasts. Our results can show how flooding propagates by the foot and by the second,” she adds.

      While Boukin’s current focus is flood simulation, her unconventional academic career has taken her research in many directions, like examining structural bottlenecks in dense urban rail systems and forecasting ground displacement due to tunneling. 

      “I’ve always been interested in the messy side of problem-solving. I think that difficult problems present a real chance to gain a deeper understanding,” says Boukin.

      Boukin credits her upbringing for giving her this perspective. A native of Israel, Boukin says that civil engineering is the family business. “My parents are civil engineers, my mom’s parents are, too, her grandfather was a professor in civil engineering, and so on. Civil engineering is my bloodline.”

      However, the decision to follow the family tradition did not come so easily. “After I took the Israeli equivalent of the SAT, I was at a decision point: Should I go to engineering school or medical school?” she recalls.

      “I decided to go on a backpacking trip to help make up my mind. It’s sort of an Israeli rite to explore internationally, so I spent six months in South America. I think backpacking is something everyone should do.”

      After this soul searching, Boukin landed on engineering school, where she fell in love with structural engineering. “It was the option that felt most familiar and interesting. I grew up playing with AutoCAD on the family computer, and now I use AutoCAD professionally!” she notes.

      “For my master’s degree, I was looking to study in a department that would help me integrate knowledge from fields like climatology and civil engineering. I found the MIT Department of Civil and Environmental Engineering to be an excellent fit,” she says.

      “I am lucky that MIT has so many people that work together as well as they do. I ended up at the Concrete Sustainability Hub, where I’m working on projects which are the perfect fit between what I wanted to do and what the department wanted to do.” 

      Boukin’s move to Cambridge has given her a new perspective on her family and childhood. 

      “My parents brought me to Israel when I was just 1 year old. In moving here as a second-time immigrant, I have a new perspective on what my parents went through during the move to Israel. I moved when I was 27 years old, the same age as they were. They didn’t have a support network and worked any job they could find,” she explains.

      “I am incredibly grateful to them for the morals they instilled in my sister, who recently graduated medical school, and I. I know I can call my parents if I ever need something, and they will do whatever they can to help.”

      Boukin hopes to honor her parents’ efforts through her research.

      “Not only do I want to help stakeholders understand flood risks, I want to make awareness of flooding more accessible. Each community needs different things to be resilient, and different cultures have different ways of delivering and receiving information,” she says.

      “Everyone should understand that they, in addition to the buildings and infrastructure around them, are part of a complex ecosystem. Any change to a city can affect the rest of it. If designers and residents are aware of this when considering flood mitigation strategies, we can better design cities and understand the consequences of damage.” More

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      in Environment

      MADMEC winner identifies sustainable greenhouse-cooling materials

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      The winners of this year’s MADMEC competition identified a class of materials that could offer a more efficient way to keep greenhouses cool.

      After Covid-19 put the materials science competition on pause for two years, on Tuesday SmartClime, a team made up of three MIT graduate students, took home the first place, $10,000 prize.

      The team showed that a type of material that changes color in response to an electric voltage could reduce energy usage and save money if coated onto the panes of glass in greenhouses.

      “This project came out of our love of gardening,” said SmartClime team member and PhD candidate Isabella Caruso in the winning presentation. “Greenhouses let you grow things year-round, even in New England, but even greenhouse pros need to use heating furnaces in the winter and ventilation in the summer. All of that can be very labor- and energy-intensive.”

      Current options to keep greenhouses cool include traditional air conditioning units, venting and fans, and simple cloth. To develop a better solution, the team looked through scientific papers to find materials with the right climate control properties.

      Two classes of materials that looked promising were thermochromic coatings, which change color based on temperature, and electrochromic solutions, which change color based on electric voltage.

      Creating both the thermochromic and electrochromic solutions required the team to assemble nanoparticles and spin-coat them onto glass substrates. In lab tests, the electrochromic material performed well, turning a deep bluish hue to reduce the heat coming into the greenhouse while also letting in enough light for plants. Specifically, the electrochromic cell kept its test box about 1 to 3 degrees Celsius cooler than the test box coated in regular glass.

      The team estimated that greenhouse owners could make back the added costs of the electrochromic paneling through savings on other climate-control measures. Additional benefits of using the material include reducing heat-related crop losses, increasing crop yields, and reducing water requirements.

      Hosted by MIT’s Department of Materials Science and Engineering (DMSE), the competition was the culmination of team projects that began last spring and included a series of design challenges throughout the summer. Each team received guidance, access to equipment and labs, and up to $1,000 in funding to build and test their prototypes.

      “It’s great to be back and to have everyone here in person,” Mike Tarkanian, a senior lecturer in DMSE and coordinator of MADMEC, said at the event. “I’ve enjoyed getting back to normal, doing the design challenges over the summer and celebrating with everyone here today.”

      The second-place prize was split between YarnZ, which identified a nanofiber yarn that is more sustainable than traditional textile fibers, and WasteAway, which has developed a waste bin monitoring device that can identify the types of items thrown into trash and recycling bins and flag misplaced items.

      YarnZ (which stands for Yarns Are Really NanofiberZ), developed a nanofiber yarn that is more degradable than traditional microfiber yarns without sacrificing on performance.

      A large chunk of the waste and emissions in the clothing industry come from polyester, a slow-degrading polymer that requires an energy-intensive melt spinning process before it’s spun into the fibers of our clothes.

      “The biggest thing I want to impress upon you today is that the textile industry is a major greenhouse gas-producing entity and also produces a huge amount of waste,” YarnZ member and PhD candidate Natalie Mamrol said in the presentation.

      To replace polyester, the team developed a continuous process in which a type of nanofiber film collects in a water bath before being twisted into yarn. In subsequent tests, the nanofiber-based yarn degraded more quicky than traditional microfibers and showed comparable durability. YarnZ believes this early data should encourage others to explore nanofibers as a viable replacement in the clothing industry and to invest in scaling the approach for industrial settings.

      WasteAway’s system includes a camera that sits on top of trash bins and uses artificial intelligence to recognize items that people throw away.

      Of the 300 million tons of waste generated in the U.S. each year, more than half ends up in landfills. A lot of that waste could have been composted or recycled but was misplaced during disposal.

      “When someone throws something into the bin, our sensor detects the motion and captures an image,” explains WasteAway’s Melissa Stok, an undergraduate at MIT. “Those images are then processed by our machine-learning algorithm to find contamination.”

      Each device costs less than $30, and the team says that cost could go down as parts are bought at larger scales. The insights gleaned from the device could help waste management officials identify contaminated trash piles as well as inform education efforts by revealing common mistakes people make.

      Overall, Tarkanian believes the competition was a success not only because of the final results, but because of the experience the students got throughout the MADMEC program, which included several smaller, hands-on competitions involving laser cutters, 3-D printers, soldering irons, and other equipment many students said they had never used before.

      “They end up getting into the lab through these design challenges, which have them compete in various engineering tasks,” Tarkanian says. “It helps them get comfortable designing and prototyping, and they often end up using those tools in their research later.” More

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      in Environment

      3Q: Why Europe is so vulnerable to heat waves

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      This year saw high-temperature records shattered across much of Europe, as crops withered in the fields due to widespread drought. Is this a harbinger of things to come as the Earth’s climate steadily warms up?

      Elfatih Eltahir, MIT professor of civil and environmental engineering and H. M. King Bhumibol Professor of Hydrology and Climate, and former doctoral student Alexandre Tuel PhD ’20 recently published a piece in the Bulletin of the Atomic Scientists describing how their research helps explain this anomalous European weather. The findings are based in part on analyses described in their book “Future Climate of the Mediterranean and Europe,” published earlier this year. MIT News asked the two authors to describe the dynamics behind these extreme weather events.

      Q: Was the European heat wave this summer anticipated based on existing climate models?

      Eltahir: Climate models project increasingly dry summers over Europe. This is especially true for the second half of the 21st century, and for southern Europe. Extreme dryness is often associated with hot conditions and heat waves, since any reduction in evaporation heats the soil and the air above it. In general, models agree in making such projections about European summers. However, understanding the physical mechanisms responsible for these projections is an active area of research.

      The same models that project dry summers over southern Europe also project dry winters over the neighboring Mediterranean Sea. In fact, the Mediterranean Sea stands out as one of the most significantly impacted regions — a literal “hot spot” — for winter droughts triggered by climate change. Again, until recently, the association between the projections of summer dryness over Europe and dry winters over the Mediterranean was not understood.

      In recent MIT doctoral research, carried out in the Department of Civil and Environmental Engineering, a hypothesis was developed to explain why the Mediterranean stands out as a hot spot for winter droughts under climate change. Further, the same theory offers a mechanistic understanding that connects the projections of dry summers over southern Europe and dry winters over the Mediterranean.

      What is exciting about the observed climate over Europe last summer is the fact that the observed drought started and developed with spatial and temporal patterns that are consistent with our proposed theory, and in particular the connection to the dry conditions observed over the Mediterranean during the previous winter.

      Q: What is it about the area around the Mediterranean basin that produces such unusual weather extremes?

      Eltahir: Multiple factors come together to cause extreme heat waves such as the one that Europe has experienced this summer, as well as previously, in 2003, 2015, 2018, 2019, and 2020. Among these, however, mutual influences between atmospheric dynamics and surface conditions, known as land-atmosphere feedbacks, seem to play a very important role.

      In the current climate, southern Europe is located in the transition zone between the dry subtropics (the Sahara Desert in North Africa) and the relatively wet midlatitudes (with a climate similar to that of the Pacific Northwest). High summertime temperatures tend to make the precipitation that falls to the ground evaporate quickly, and as a consequence soil moisture during summer is very dependent on springtime precipitation. A dry spring in Europe (such as the 2022 one) causes dry soils in late spring and early summer. This lack of surface water in turn limits surface evaporation during summer. Two important consequences follow: First, incoming radiative energy from the sun preferentially goes into increasing air temperature rather than evaporating water; and second, the inflow of water into air layers near the surface decreases, which makes the air drier and precipitation less likely. Combined, these two influences increase the likelihood of heat waves and droughts.

      Tuel: Through land-atmosphere feedbacks, dry springs provide a favorable environment for persistent warm and dry summers but are of course not enough to directly cause heat waves. A spark is required to ignite the fuel. In Europe and elsewhere, this spark is provided by large-scale atmospheric dynamics. If an anticyclone sets over an area with very dry soils, surface temperature can quickly shoot up as land-atmosphere feedbacks come into play, developing into a heat wave that can persist for weeks.

      The sensitivity to springtime precipitation makes southern Europe and the Mediterranean particularly prone to persistent summer heat waves. This will play an increasingly important role in the future, as spring precipitation is expected to decline, making scorching summers even more likely in this corner of the world. The decline in spring precipitation, which originates as an anomalously dry winter around the Mediterranean, is very robust across climate projections. Southern Europe and the Mediterranean really stand out from most other land areas, where precipitation will on average increase with global warming.

      In our work, we showed that this Mediterranean winter decline was driven by two independent factors: on the one hand, trends in the large-scale circulation, notably stationary atmospheric waves, and on the other hand, reduced warming of the Mediterranean Sea relative to the surrounding continents — a well-known feature of global warming. Both factors lead to increased surface air pressure and reduced precipitation over the Mediterranean and Southern Europe.

      Q: What can we expect over the coming decades in terms of the frequency and severity of these kinds of droughts, floods, and other extremes in European weather?

      Tuel: Climate models have long shown that the frequency and intensity of heat waves was bound to increase as the global climate warms, and Europe is no exception. The reason is simple: As the global temperature rises, the temperature distribution shifts toward higher values, and heat waves become more intense and more frequent. Southern Europe and the Mediterranean, however, will be hit particularly hard. The reason for this is related to the land-atmosphere feedbacks we just discussed. Winter precipitation over the Mediterranean and spring precipitation over southern Europe will decline significantly, which will lead to a decrease in early summer soil moisture over southern Europe and will push average summer temperatures even higher; the region will become a true climate change hot spot. In that sense, 2022 may really be a taste of the future. The succession of recent heat waves in Europe, however, suggests that things may be going faster than climate model projections imply. Decadal variability or badly understood trends in large-scale atmospheric dynamics may play a role here, though that is still debated. Another possibility is that climate models tend to underestimate the magnitude of land-atmosphere feedbacks and downplay the influence of dry soil moisture anomalies on summertime weather.

      Potential trends in floods are more difficult to assess because floods result from a multiplicity of factors, like extreme precipitation, soil moisture levels, or land cover. Extreme precipitation is generally expected to increase in most regions, but very high uncertainties remain, notably because extreme precipitation is highly dependent on atmospheric dynamics about which models do not always agree. What is almost certain is that with warming, the water content of the atmosphere increases (following a law of thermodynamics known as the Clausius-Clapeyron relationship). Thus, if the dynamics are favorable to precipitation, a lot more of it may fall in a warmer climate. Last year’s floods in Germany, for example, were triggered by unprecedented heavy rainfall which climate change made more likely. More

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      in Energy

      Simulating neutron behavior in nuclear reactors

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      Amelia Trainer applied to MIT because she lost a bet.

      As part of what the fourth-year nuclear science and engineering (NSE) doctoral student labels her “teenage rebellious phase,” Trainer was quite convinced she would just be wasting the application fee were she to submit an application. She wasn’t even “super sure” she wanted to go to college. But a high-school friend was convinced Trainer would get into a “top school” if she only applied. A bet followed: If Trainer lost, she would have to apply to MIT. Trainer lost — and is glad she did.

      Growing up in Daytona Beach, Florida, good grades were Trainer’s thing. Seeing friends participate in interschool math competitions, Trainer decided she would tag along and soon found she loved them. She remembers being adept at reading the room: If teams were especially struggling over a problem, Trainer figured the answer had to be something easy, like zero or one. “The hardest problems would usually have the most goofball answers,” she laughs.

      Simulating neutron behavior

      As a doctoral student, hard problems in math, specifically computational reactor physics, continue to be Trainer’s forte.

      Her research, under the guidance of Professor Benoit Forget in MIT NSE’s Computational Reactor Physics Group (CRPG), focuses on modeling complicated neutron behavior in reactors. Simulation helps forecast the behavior of reactors before millions of dollars sink into development of a potentially uneconomical unit. Using simulations, Trainer can see “where the neutrons are going, how much heat is being produced, and how much power the reactor can generate.” Her research helps form the foundation for the next generation of nuclear power plants.

      To simulate neutron behavior inside of a nuclear reactor, you first need to know how neutrons will interact with the various materials inside the system. These neutrons can have wildly different energies, thereby making them susceptible to different physical phenomena. For the entirety of her graduate studies, Trainer has been primarily interested in the physics regarding slow-moving neutrons and their scattering behavior.

      When a slow neutron scatters off of a material, it can induce or cancel out molecular vibrations between the material’s atoms. The effect that material vibrations can have on neutron energies, and thereby on reactor behavior, has been heavily approximated over the years. Trainer is primarily interested in chipping away at these approximations by creating scattering data for materials that have historically been misrepresented and by exploring new techniques for preparing slow-neutron scattering data.

      Trainer remembers waiting for a simulation to complete in the early days of the Covid-19 pandemic, when she discovered a way to predict neutron behavior with limited input data. Traditionally, “people have to store large tables of what neutrons will do under specific circumstances,” she says. “I’m really happy about it because it’s this really cool method of sampling what your neutron does from very little information,” Trainer says.

      Amelia Trainer — Modeling complicated neutron behavior in nuclear reactors

      As part of her research, Trainer often works closely with two software packages: OpenMC and NJOY. OpenMC is a Monte Carlo neutron transport simulation code that was developed in the CRPG and is used to simulate neutron behavior in reactor systems. NJOY is a nuclear data processing tool, and is used to create, augment, and prepare material data that is fed into tools like OpenMC. By editing both these codes to her specifications, Trainer is able to observe the effect that “upstream” material data has on the “downstream” reactor calculations. Through this, she hopes to identify additional problems: approximations that could lead to a noticeable misrepresentation of the physics.

      A love of geometry and poetry

      Trainer discovered the coolness of science as a child. Her mother, who cares for indoor plants and runs multiple greenhouses, and her father, a blacksmith and farrier, who explored materials science through his craft, were self-taught inspirations.

      Trainer’s father urged his daughter to learn and pursue any topics that she found exciting and encouraged her to read poems from “Calvin and Hobbes” out loud when she struggled with a speech impediment in early childhood. Reading the same passages every day helped her memorize them. “The natural manifestation of that extended into [a love of] poetry,” Trainer says.

      A love of poetry, combined with Trainer’s propensity for fun, led her to compose an ode to pi as part of an MIT-sponsored event for alumni. “I was really only in it for the cupcake,” she laughs. (Participants received an indulgent treat).

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      MIT Matters: A Love Poem to Pi

      Computations and nuclear science

      After being accepted at MIT, Trainer knew she wanted to study in a field that would take her skills at the levels they were at — “my math skills were pretty underdeveloped in the grand scheme of things,” she says. An open-house weekend at MIT, where she met with faculty from the NSE department, and the opportunity to contribute to a discipline working toward clean energy, cemented Trainer’s decision to join NSE.

      As a high schooler, Trainer won a scholarship to Embry-Riddle Aeronautical University to learn computer coding and knew computational physics might be more aligned with her interests. After she joined MIT as an undergraduate student in 2014, she realized that the CRPG, with its focus on coding and modeling, might be a good fit. Fortunately, a graduate student from Forget’s team welcomed Trainer’s enthusiasm for research even as an undergraduate first-year. She has stayed with the lab ever since. 

      Research internships at Los Alamos National Laboratory, the creators of NJOY, have furthered Trainer’s enthusiasm for modeling and computational physics. She met a Los Alamos scientist after he presented a talk at MIT and it snowballed into a collaboration where she could work on parts of the NJOY code. “It became a really cool collaboration which led me into a deep dive into physics and data preparation techniques, which was just so fulfilling,” Trainer says. As for what’s next, Trainer was awarded the Rickover fellowship in nuclear engineering by the the Department of Energy’s Naval Reactors Division and will join the program in Pittsburgh after she graduates.

      For many years, Trainer’s cats, Jacques and Monster, have been a constant companion. “Neutrons, computers, and cats, that’s my personality,” she laughs. Work continues to fuel her passion. To borrow a favorite phrase from Spaceman Spiff, Trainer’s favorite “Calvin” avatar, Trainer’s approach to research has invariably been: “Another day, another mind-boggling adventure.” More

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      in Energy

      New process could enable more efficient plastics recycling

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      The accumulation of plastic waste in the oceans, soil, and even in our bodies is one of the major pollution issues of modern times, with over 5 billion tons disposed of so far. Despite major efforts to recycle plastic products, actually making use of that motley mix of materials has remained a challenging issue.

      A key problem is that plastics come in so many different varieties, and chemical processes for breaking them down into a form that can be reused in some way tend to be very specific to each type of plastic. Sorting the hodgepodge of waste material, from soda bottles to detergent jugs to plastic toys, is impractical at large scale. Today, much of the plastic material gathered through recycling programs ends up in landfills anyway. Surely there’s a better way.

      According to new research from MIT and elsewhere, it appears there may indeed be a much better way. A chemical process using a catalyst based on cobalt has been found to be very effective at breaking down a variety of plastics, such as polyethylene (PET) and polypropylene (PP), the two most widely produced forms of plastic, into a single product, propane. Propane can then be used as a fuel for stoves, heaters, and vehicles, or as a feedstock for the production of a wide variety of products — including new plastics, thus potentially providing at least a partial closed-loop recycling system.

      The finding is described today in the open access journal  JACS Au, in a paper by MIT professor of chemical engineering Yuriy Román-Leshkov, postdoc Guido Zichitella, and seven others at MIT, the SLAC National Accelerator Laboratory, and the National Renewable Energy Laboratory.

      Recycling plastics has been a thorny problem, Román-Leshkov explains, because the long-chain molecules in plastics are held together by carbon bonds, which are “very stable and difficult to break apart.” Existing techniques for breaking these bonds tend to produce a random mix of different molecules, which would then require complex refining methods to separate out into usable specific compounds. “The problem is,” he says, “there’s no way to control where in the carbon chain you break the molecule.”

      But to the surprise of the researchers, a catalyst made of a microporous material called a zeolite that contains cobalt nanoparticles can selectively break down various plastic polymer molecules and turn more than 80 percent of them into propane.

      Although zeolites are riddled with tiny pores less than a nanometer wide (corresponding to the width of the polymer chains), a logical assumption had been that there would be little interaction at all between the zeolite and the polymers. Surprisingly, however, the opposite turned out to be the case: Not only do the polymer chains enter the pores, but the synergistic work between cobalt and the acid sites in the zeolite can break the chain at the same point. That cleavage site turned out to correspond to chopping off exactly one propane molecule without generating unwanted methane, leaving the rest of the longer hydrocarbons ready to undergo the process, again and again.

      “Once you have this one compound, propane, you lessen the burden on downstream separations,” Román-Leshkov says. “That’s the essence of why we think this is quite important. We’re not only breaking the bonds, but we’re generating mainly a single product” that can be used for many different products and processes.

      The materials needed for the process, zeolites and cobalt, “are both quite cheap” and widely available, he says, although today most cobalt comes from troubled areas in the Democratic Republic of Congo. Some new production is being developed in Canada, Cuba, and other places. The other material needed for the process is hydrogen, which today is mostly produced from fossil fuels but can easily be made other ways, including electrolysis of water using carbon-free electricity such as solar or wind power.

      The researchers tested their system on a real example of mixed recycled plastic, producing promising results. But more testing will be needed on a greater variety of mixed waste streams to determine how much fouling takes place from various contaminants in the material — such as inks, glues, and labels attached to the plastic containers, or other nonplastic materials that get mixed in with the waste — and how that affects the long-term stability of the process.

      Together with collaborators at NREL, the MIT team is also continuing to study the economics of the system, and analyzing how it can fit into today’s systems for handling plastic and mixed waste streams. “We don’t have all the answers yet,” Román-Leshkov says, but preliminary analysis looks promising.

      The research team included Amani Ebrahim and Simone Bare at the SLAC National Accelerator Laboratory; Jie Zhu, Anna Brenner, Griffin Drake and Julie Rorrer at MIT; and Greg Beckham at the National Renewable Energy Laboratory. The work was supported by the U.S. Department of Energy (DoE), the Swiss National Science Foundation, and the DoE’s Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office (AMO), and Bioenergy Technologies Office (BETO), as part of the the Bio-Optimized Technologies to keep Thermoplastics out of Landfills and the Environment (BOTTLE) Consortium. More

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      in Security

      Scientists chart how exercise affects the body

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      Exercise is well-known to help people lose weight and avoid gaining it. However, identifying the cellular mechanisms that underlie this process has proven difficult because so many cells and tissues are involved.

      In a new study in mice that expands researchers’ understanding of how exercise and diet affect the body, MIT and Harvard Medical School researchers have mapped out many of the cells, genes, and cellular pathways that are modified by exercise or high-fat diet. The findings could offer potential targets for drugs that could help to enhance or mimic the benefits of exercise, the researchers say.

      “It is extremely important to understand the molecular mechanisms that are drivers of the beneficial effects of exercise and the detrimental effects of a high-fat diet, so that we can understand how we can intervene, and develop drugs that mimic the impact of exercise across multiple tissues,” says Manolis Kellis, a professor of computer science in MIT’s Computer Science and Artificial Intelligence Laboratory (CSAIL) and a member of the Broad Institute of MIT and Harvard.

      The researchers studied mice with high-fat or normal diets, who were either sedentary or given the opportunity to exercise whenever they wanted. Using single-cell RNA sequencing, the researchers cataloged the responses of 53 types of cells found in skeletal muscle and two types of fatty tissue.

      “One of the general points that we found in our study, which is overwhelmingly clear, is how high-fat diets push all of these cells and systems in one way, and exercise seems to be pushing them nearly all in the opposite way,” Kellis says. “It says that exercise can really have a major effect throughout the body.”

      Kellis and Laurie Goodyear, a professor of medicine at Harvard Medical School and senior investigator at the Joslin Diabetes Center, are the senior authors of the study, which appears today in the journal Cell Metabolism. Jiekun Yang, a research scientist in MIT CSAIL; Maria Vamvini, an instructor of medicine at the Joslin Diabetes Center; and Pasquale Nigro, an instructor of medicine at the Joslin Diabetes Center, are the lead authors of the paper.

      The risks of obesity

      Obesity is a growing health problem around the world. In the United States, more than 40 percent of the population is considered obese, and nearly 75 percent is overweight. Being overweight is a risk factor for many diseases, including heart disease, cancer, Alzheimer’s disease, and even infectious diseases such as Covid-19.

      “Obesity, along with aging, is a global factor that contributes to every aspect of human health,” Kellis says.

      Several years ago, his lab performed a study on the FTO gene region, which has been strongly linked to obesity risk. In that 2015 study, the research team found that genes in this region control a pathway that prompts immature fat cells called progenitor adipocytes to either become fat-burning cells or fat-storing cells.

      That finding, which demonstrated a clear genetic component to obesity, motivated Kellis to begin looking at how exercise, a well-known behavioral intervention that can prevent obesity, might act on progenitor adipocytes at the cellular level.

      To explore that question, Kellis and his colleagues decided to perform single-cell RNA sequencing of three types of tissue — skeletal muscle, visceral white adipose tissue (found packed around internal organs, where it stores fat), and subcutaneous white adipose tissue (which is found under the skin and primarily burns fat).

      These tissues came from mice from four different experimental groups. For three weeks, two groups of mice were fed either a normal diet or a high-fat diet. For the next three weeks, each of those two groups were further divided into a sedentary group and an exercise group, which had continuous access to a treadmill.

      By analyzing tissues from those mice, the researchers were able to comprehensively catalog the genes that were activated or suppressed by exercise in 53 different cell types.

      The researchers found that in all three tissue types, mesenchymal stem cells (MSCs) appeared to control many of the diet and exercise-induced effects that they observed. MSCs are stem cells that can differentiate into other cell types, including fat cells and fibroblasts. In adipose tissue, the researchers found that a high-fat diet modulated MSCs’ capacity to differentiate into fat-storing cells, while exercise reversed this effect.

      In addition to promoting fat storage, the researchers found that a high-fat diet also stimulated MSCs to secrete factors that remodel the extracellular matrix (ECM) — a network of proteins and other molecules that surround and support cells and tissues in the body. This ECM remodeling helps provide structure for enlarged fat-storing cells and also creates a more inflammatory environment.

      “As the adipocytes become overloaded with lipids, there’s an extreme amount of stress, and that causes low-grade inflammation, which is systemic and preserved for a long time,” Kellis says. “That is one of the factors that is contributing to many of the adverse effects of obesity.”

      Circadian effects

      The researchers also found that high-fat diets and exercise had opposing effects on cellular pathways that control circadian rhythms — the 24-hour cycles that govern many functions, from sleep to body temperature, hormone release, and digestion. The study revealed that exercise boosts the expression of genes that regulate these rhythms, while a high-fat diet suppresses them.

      “There have been a lot of studies showing that when you eat during the day is extremely important in how you absorb the calories,” Kellis says. “The circadian rhythm connection is a very important one, and shows how obesity and exercise are in fact directly impacting that circadian rhythm in peripheral organs, which could act systemically on distal clocks and regulate stem cell functions and immunity.”

      The researchers then compared their results to a database of human genes that have been linked with metabolic traits. They found that two of the circadian rhythm genes they identified in this study, known as DBP and CDKN1A, have genetic variants that have been associated with a higher risk of obesity in humans.

      “These results help us see the translational values of these targets, and how we could potentially target specific biological processes in specific cell types,” Yang says.

      The researchers are now analyzing samples of small intestine, liver, and brain tissue from the mice in this study, to explore the effects of exercise and high-fat diets on those tissues. They are also conducting work with human volunteers to sample blood and biopsies and study similarities and differences between human and mouse physiology. They hope that their findings will help guide drug developers in designing drugs that might mimic some of the beneficial effects of exercise.

      “The message for everyone should be, eat a healthy diet and exercise if possible,” Kellis says. “For those for whom this is not possible, due to low access to healthy foods, or due to disabilities or other factors that prevent exercise, or simply lack of time to have a healthy diet or a healthy lifestyle, what this study says is that we now have a better handle on the pathways, the specific genes, and the specific molecular and cellular processes that we should be manipulating therapeutically.”

      The research was funded by the National Institutes of Health and the Novo Nordisk Research Center in Seattle. More

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      in Energy

      Processing waste biomass to reduce airborne emissions

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      To prepare fields for planting, farmers the world over often burn corn stalks, rice husks, hay, straw, and other waste left behind from the previous harvest. In many places, the practice creates huge seasonal clouds of smog, contributing to air pollution that kills 7 million people globally a year, according to the World Health Organization.

      Annually, $120 billion worth of crop and forest residues are burned in the open worldwide — a major waste of resources in an energy-starved world, says Kevin Kung SM ’13, PhD ’17. Kung is working to transform this waste biomass into marketable products — and capitalize on a billion-dollar global market — through his MIT spinoff company, Takachar.

      Founded in 2015, Takachar develops small-scale, low-cost, portable equipment to convert waste biomass into solid fuel using a variety of thermochemical treatments, including one known as oxygen-lean torrefaction. The technology emerged from Kung’s PhD project in the lab of Ahmed Ghoniem, the Ronald C. Crane (1972) Professor of Mechanical Engineering at MIT.

      Biomass fuels, including wood, peat, and animal dung, are a major source of carbon emissions — but billions of people rely on such fuels for cooking, heating, and other household needs. “Currently, burning biomass generates 10 percent of the primary energy used worldwide, and the process is used largely in rural, energy-poor communities. We’re not going to change that overnight. There are places with no other sources of energy,” Ghoniem says.

      What Takachar’s technology provides is a way to use biomass more cleanly and efficiently by concentrating the fuel and eliminating contaminants such as moisture and dirt, thus creating a “clean-burning” fuel — one that generates less smoke. “In rural communities where biomass is used extensively as a primary energy source, torrefaction will address air pollution head-on,” Ghoniem says.

      Thermochemical treatment densifies biomass at elevated temperatures, converting plant materials that are typically loose, wet, and bulky into compact charcoal. Centralized processing plants exist, but collection and transportation present major barriers to utilization, Kung says. Takachar’s solution moves processing into the field: To date, Takachar has worked with about 5,500 farmers to process 9,000 metric tons of crops.

      Takachar estimates its technology has the potential to reduce carbon dioxide equivalent emissions by gigatons per year at scale. (“Carbon dioxide equivalent” is a measure used to gauge global warming potential.) In recognition, in 2021 Takachar won the first-ever Earthshot Prize in the clean air category, a £1 million prize funded by Prince William and Princess Kate’s Royal Foundation.

      Roots in Kenya

      As Kung tells the story, Takachar emerged from a class project that took him to Kenya — which explains the company’s name, a combination of takataka, which mean “trash” in Swahili, and char, for the charcoal end product.

      It was 2011, and Kung was at MIT as a biological engineering grad student focused on cancer research. But “MIT gives students big latitude for exploration, and I took courses outside my department,” he says. In spring 2011, he signed up for a class known as 15.966 (Global Health Delivery Lab) in the MIT Sloan School of Management. The class brought Kung to Kenya to work with a nongovernmental organization in Nairobi’s Kibera, the largest urban slum in Africa.

      “We interviewed slum households for their views on health, and that’s when I noticed the charcoal problem,” Kung says. The problem, as Kung describes it, was that charcoal was everywhere in Kibera — piled up outside, traded by the road, and used as the primary fuel, even indoors. Its creation contributed to deforestation, and its smoke presented a serious health hazard.

      Eager to address this challenge, Kung secured fellowship support from the MIT International Development Initiative and the Priscilla King Gray Public Service Center to conduct more research in Kenya. In 2012, he formed Takachar as a team and received seed money from the MIT IDEAS Global Challenge, MIT Legatum Center for Development and Entrepreneurship, and D-Lab to produce charcoal from household organic waste. (This work also led to a fertilizer company, Safi Organics, that Kung founded in 2016 with the help of MIT IDEAS. But that is another story.)

      Meanwhile, Kung had another top priority: finding a topic for his PhD dissertation. Back at MIT, he met Alexander Slocum, the Walter M. May and A. Hazel May Professor of Mechanical Engineering, who on a long walk-and-talk along the Charles River suggested he turn his Kenya work into a thesis. Slocum connected him with Robert Stoner, deputy director for science and technology at the MIT Energy Initiative (MITEI) and founding director of MITEI’s Tata Center for Technology and Design. Stoner in turn introduced Kung to Ghoniem, who became his PhD advisor, while Slocum and Stoner joined his doctoral committee.

      Roots in MIT lab

      Ghoniem’s telling of the Takachar story begins, not surprisingly, in the lab. Back in 2010, he had a master’s student interested in renewable energy, and he suggested the student investigate biomass. That student, Richard Bates ’10, SM ’12, PhD ’16, began exploring the science of converting biomass to more clean-burning charcoal through torrefaction.

      Most torrefaction (also known as low-temperature pyrolysis) systems use external heating sources, but the lab’s goal, Ghoniem explains, was to develop an efficient, self-sustained reactor that would generate fewer emissions. “We needed to understand the chemistry and physics of the process, and develop fundamental scaling models, before going to the lab to build the device,” he says.

      By the time Kung joined the lab in 2013, Ghoniem was working with the Tata Center to identify technology suitable for developing countries and largely based on renewable energy. Kung was able to secure a Tata Fellowship and — building on Bates’ research — develop the small-scale, practical device for biomass thermochemical conversion in the field that launched Takachar.

      This device, which was patented by MIT with inventors Kung, Ghoniem, Stoner, MIT research scientist Santosh Shanbhogue, and Slocum, is self-contained and scalable. It burns a little of the biomass to generate heat; this heat bakes the rest of the biomass, releasing gases; the system then introduces air to enable these gases to combust, which burns off the volatiles and generates more heat, keeping the thermochemical reaction going.

      “The trick is how to introduce the right amount of air at the right location to sustain the process,” Ghoniem explains. “If you put in more air, that will burn the biomass. If you put in less, there won’t be enough heat to produce the charcoal. That will stop the reaction.”

      About 10 percent of the biomass is used as fuel to support the reaction, Kung says, adding that “90 percent is densified into a form that’s easier to handle and utilize.” He notes that the research received financial support from the Abdul Latif Jameel Water and Food Systems Lab and the Deshpande Center for Technological Innovation, both at MIT. Sonal Thengane, another postdoc in Ghoniem’s lab, participated in the effort to scale up the technology at the MIT Bates Lab (no relation to Richard Bates).

      The charcoal produced is more valuable per ton and easier to transport and sell than biomass, reducing transportation costs by two-thirds and giving farmers an additional income opportunity — and an incentive not to burn agricultural waste, Kung says. “There’s more income for farmers, and you get better air quality.”

      Roots in India

      When Kung became a Tata Fellow, he joined a program founded to take on the biggest challenges of the developing world, with a focus on India. According to Stoner, Tata Fellows, including Kung, typically visit India twice a year and spend six to eight weeks meeting stakeholders in industry, the government, and in communities to gain perspective on their areas of study.

      “A unique part of Tata is that you’re considering the ecosystem as a whole,” says Kung, who interviewed hundreds of smallholder farmers, met with truck drivers, and visited existing biomass processing plants during his Tata trips to India. (Along the way, he also connected with Indian engineer Vidyut Mohan, who became Takachar’s co-founder.)

      “It was very important for Kevin to be there walking about, experimenting, and interviewing farmers,” Stoner says. “He learned about the lives of farmers.”

      These experiences helped instill in Kung an appreciation for small farmers that still drives him today as Takachar rolls out its first pilot programs, tinkers with the technology, grows its team (now up to 10), and endeavors to build a revenue stream. So, while Takachar has gotten a lot of attention and accolades — from the IDEAS award to the Earthshot Prize — Kung says what motivates him is the prospect of improving people’s lives.

      The dream, he says, is to empower communities to help both the planet and themselves. “We’re excited about the environmental justice perspective,” he says. “Our work brings production and carbon removal or avoidance to rural communities — providing them with a way to convert waste, make money, and reduce air pollution.”

      This article appears in the Spring 2022 issue of Energy Futures, the magazine of the MIT Energy Initiative. More