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      in Environment

      Four researchers with MIT ties earn Schmidt Science Fellowships

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      Four researchers with MIT ties — Juncal Arbelaiz, Xiangkun (Elvis) Cao, Sandya Subramanian, and Heather Zlotnick ’17 — have been honored with competitive Schmidt Science Fellowships.

      Created in 2017, the fellows program aims to bring together the world’s brightest minds “to solve society’s toughest challenges.”

      The four MIT-affiliated researchers are among 29 Schmidt Science Fellows from around the world who will receive postdoctoral support for either one or two years with an annual stipend of $100,000, along with individualized mentoring and participation in the program’s Global Meeting Series. The fellows will also have opportunities to engage with thought-leaders from science, business, policy, and society. According to the award announcement, the fellows are expected to pursue research that shifts from the focus of their PhDs, to help expand and enhance their futures as scientific leaders.

      Juncal Arbelaiz is a PhD candidate in applied mathematics at MIT, who is completing her doctorate this summer. Her doctoral research at MIT is advised by Ali Jadbabaie, the JR East Professor of Engineering and head of the Department of Civil and Environmental Engineering; Anette Hosoi, the Neil and Jane Pappalardo Professor of Mechanical Engineering and associate dean of the School of Engineering; and Bassam Bamieh, professor of mechanical engineering and associate director of the Center for Control, Dynamical Systems, and Computation at the University of California at Santa Barbara. Arbelaiz’s research revolves around the design of optimal decentralized intelligence for spatially-distributed dynamical systems.

      “I cannot think of a better way to start my independent scientific career. I feel very excited and grateful for this opportunity,” says Arbelaiz. With her fellowship, she will enlist systems biology to explore how the nervous system encodes and processes sensory information to address future safety-critical artificial intelligence applications. “The Schmidt Science Fellowship will provide me with a unique opportunity to work at the intersection of biological and machine intelligence for two years and will be a steppingstone towards my longer-term objective of becoming a researcher in bio-inspired machine intelligence,” she says.

      Xiangkun (Elvis) Cao is currently a postdoc in the lab of T. Alan Hatton, the Ralph Landau Professor in Chemical Engineering, and an Impact Fellow at the MIT Climate and Sustainability Consortium. Cao received his PhD in mechanical engineering from Cornell University in 2021, during which he focused on microscopic precision in the simultaneous delivery of light and fluids by optofluidics, with advances relevant to health and sustainability applications. As a Schmidt Science Fellow, he plans to be co-advised by Hatton on carbon capture, and Ted Sargent, professor of chemistry at Northwestern University, on carbon utilization. Cao is passionate about integrated carbon capture and utilization (CCU) from molecular to process levels, machine learning to inspire smart CCU, and the nexus of technology, business, and policy for CCU.

      “The Schmidt Science Fellowship provides the perfect opportunity for me to work across disciplines to study integrated carbon capture and utilization from molecular to process levels,” Cao explains. “My vision is that by integrating carbon capture and utilization, we can concurrently make scientific discoveries and unlock economic opportunities while mitigating global climate change. This way, we can turn our carbon liability into an asset.”

      Sandya Subramanian, a 2021 PhD graduate of the Harvard-MIT Program in Health Sciences and Technology (HST) in the area of medical engineering and medical physics, is currently a postdoc at Stanford Data Science. She is focused on the topics of biomedical engineering, statistics, machine learning, neuroscience, and health care. Her research is on developing new technologies and methods to study the interactions between the brain, the autonomic nervous system, and the gut. “I’m extremely honored to receive the Schmidt Science Fellowship and to join the Schmidt community of leaders and scholars,” says Subramanian. “I’ve heard so much about the fellowship and the fact that it can open doors and give people confidence to pursue challenging or unique paths.”

      According to Subramanian, the autonomic nervous system and its interactions with other body systems are poorly understood but thought to be involved in several disorders, such as functional gastrointestinal disorders, Parkinson’s disease, diabetes, migraines, and eating disorders. The goal of her research is to improve our ability to monitor and quantify these physiologic processes. “I’m really interested in understanding how we can use physiological monitoring technologies to inform clinical decision-making, especially around the autonomic nervous system, and I look forward to continuing the work that I’ve recently started at Stanford as Schmidt Science Fellow,” she says. “A huge thank you to all of the mentors, colleagues, friends, and leaders I had the pleasure of meeting and working with at HST and MIT; I couldn’t have done this without everything I learned there.”

      Hannah Zlotnick ’17 attended MIT for her undergraduate studies, majoring in biological engineering with a minor in mechanical engineering. At MIT, Zlotnick was a student-athlete on the women’s varsity soccer team, a UROP student in Alan Grodzinsky’s laboratory, and a member of Pi Beta Phi. For her PhD, Zlotnick attended the University of Pennsylvania, and worked in Robert Mauck’s laboratory within the departments of Bioengineering and Orthopaedic Surgery.

      Zlotnick’s PhD research focused on harnessing remote forces, such as magnetism or gravity, to enhance engineered cartilage and osteochondral repair both in vitro and in large animal models. Zlotnick now plans to pivot to the field of biofabrication to create tissue models of the knee joint to assess potential therapeutics for osteoarthritis. “I am humbled to be a part of the Schmidt Science Fellows community, and excited to venture into the field of biofabrication,” Zlotnick says. “Hopefully this work uncovers new therapies for patients with inflammatory joint diseases.” More

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      in Energy

      Explained: Why perovskites could take solar cells to new heights

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      Perovskites hold promise for creating solar panels that could be easily deposited onto most surfaces, including flexible and textured ones. These materials would also be lightweight, cheap to produce, and as efficient as today’s leading photovoltaic materials, which are mainly silicon. They’re the subject of increasing research and investment, but companies looking to harness their potential do have to address some remaining hurdles before perovskite-based solar cells can be commercially competitive.

      The term perovskite refers not to a specific material, like silicon or cadmium telluride, other leading contenders in the photovoltaic realm, but to a whole family of compounds. The perovskite family of solar materials is named for its structural similarity to a mineral called perovskite, which was discovered in 1839 and named after Russian mineralogist L.A. Perovski.

      The original mineral perovskite, which is calcium titanium oxide (CaTiO3), has a distinctive crystal configuration. It has a three-part structure, whose components have come to be labeled A, B and X, in which lattices of the different components are interlaced. The family of perovskites consists of the many possible combinations of elements or molecules that can occupy each of the three components and form a structure similar to that of the original perovskite itself. (Some researchers even bend the rules a little by naming other crystal structures with similar elements “perovskites,” although this is frowned upon by crystallographers.)

      “You can mix and match atoms and molecules into the structure, with some limits. For instance, if you try to stuff a molecule that’s too big into the structure, you’ll distort it. Eventually you might cause the 3D crystal to separate into a 2D layered structure, or lose ordered structure entirely,” says Tonio Buonassisi, professor of mechanical engineering at MIT and director of the Photovoltaics Research Laboratory. “Perovskites are highly tunable, like a build-your-own-adventure type of crystal structure,” he says.

      That structure of interlaced lattices consists of ions or charged molecules, two of them (A and B) positively charged and the other one (X) negatively charged. The A and B ions are typically of quite different sizes, with the A being larger. 

      Within the overall category of perovskites, there are a number of types, including metal oxide perovskites, which have found applications in catalysis and in energy storage and conversion, such as in fuel cells and metal-air batteries. But a main focus of research activity for more than a decade has been on lead halide perovskites, according to Buonassisi says.

      Within that category, there is still a legion of possibilities, and labs around the world are racing through the tedious work of trying to find the variations that show the best performance in efficiency, cost, and durability — which has so far been the most challenging of the three.

      Many teams have also focused on variations that eliminate the use of lead, to avoid its environmental impact. Buonassisi notes, however, that “consistently over time, the lead-based devices continue to improve in their performance, and none of the other compositions got close in terms of electronic performance.” Work continues on exploring alternatives, but for now none can compete with the lead halide versions.

      One of the great advantages perovskites offer is their great tolerance of defects in the structure, he says. Unlike silicon, which requires extremely high purity to function well in electronic devices, perovskites can function well even with numerous imperfections and impurities.

      Searching for promising new candidate compositions for perovskites is a bit like looking for a needle in a haystack, but recently researchers have come up with a machine-learning system that can greatly streamline this process. This new approach could lead to a much faster development of new alternatives, says Buonassisi, who was a co-author of that research.

      While perovskites continue to show great promise, and several companies are already gearing up to begin some commercial production, durability remains the biggest obstacle they face. While silicon solar panels retain up to 90 percent of their power output after 25 years, perovskites degrade much faster. Great progress has been made — initial samples lasted only a few hours, then weeks or months, but newer formulations have usable lifetimes of up to a few years, suitable for some applications where longevity is not essential.

      From a research perspective, Buonassisi says, one advantage of perovskites is that they are relatively easy to make in the lab — the chemical constituents assemble readily. But that’s also their downside: “The material goes together very easily at room temperature,” he says, “but it also comes apart very easily at room temperature. Easy come, easy go!”

      To deal with that issue, most researchers are focused on using various kinds of protective materials to encapsulate the perovskite, protecting it from exposure to air and moisture. But others are studying the exact mechanisms that lead to that degradation, in hopes of finding formulations or treatments that are more inherently robust. A key finding is that a process called autocatalysis is largely to blame for the breakdown.

      In autocatalysis, as soon as one part of the material starts to degrade, its reaction products act as catalysts to start degrading the neighboring parts of the structure, and a runaway reaction gets underway. A similar problem existed in the early research on some other electronic materials, such as organic light-emitting diodes (OLEDs), and was eventually solved by adding additional purification steps to the raw materials, so a similar solution may be found in the case of perovskites, Buonassisi suggests.

      Buonassisi and his co-researchers recently completed a study showing that once perovskites reach a usable lifetime of at least a decade, thanks to their much lower initial cost that would be sufficient to make them economically viable as a substitute for silicon in large, utility-scale solar farms.

      Overall, progress in the development of perovskites has been impressive and encouraging, he says. With just a few years of work, it has already achieved efficiencies comparable to levels that cadmium telluride (CdTe), “which has been around for much longer, is still struggling to achieve,” he says. “The ease with which these higher performances are reached in this new material are almost stupefying.” Comparing the amount of research time spent to achieve a 1 percent improvement in efficiency, he says, the progress on perovskites has been somewhere between 100 and 1000 times faster than that on CdTe. “That’s one of the reasons it’s so exciting,” he says. More

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      in Energy

      MIT engineers design surfaces that make water boil more efficiently

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      The boiling of water or other fluids is an energy-intensive step at the heart of a wide range of industrial processes, including most electricity generating plants, many chemical production systems, and even cooling systems for electronics.

      Improving the efficiency of systems that heat and evaporate water could significantly reduce their energy use. Now, researchers at MIT have found a way to do just that, with a specially tailored surface treatment for the materials used in these systems.

      The improved efficiency comes from a combination of three different kinds of surface modifications, at different size scales. The new findings are described in the journal Advanced Materials in a paper by recent MIT graduate Youngsup Song PhD ’21, Ford Professor of Engineering Evelyn Wang, and four others at MIT. The researchers note that this initial finding is still at a laboratory scale, and more work is needed to develop a practical, industrial-scale process.

      There are two key parameters that describe the boiling process: the heat transfer coefficient (HTC) and the critical heat flux (CHF). In materials design, there’s generally a tradeoff between the two, so anything that improves one of these parameters tends to make the other worse. But both are important for the efficiency of the system, and now, after years of work, the team has achieved a way of significantly improving both properties at the same time, through their combination of different textures added to a material’s surface.

      “Both parameters are important,” Song says, “but enhancing both parameters together is kind of tricky because they have intrinsic trade off.” The reason for that, he explains, is “because if we have lots of bubbles on the boiling surface, that means boiling is very efficient, but if we have too many bubbles on the surface, they can coalesce together, which can form a vapor film over the boiling surface.” That film introduces resistance to the heat transfer from the hot surface to the water. “If we have vapor in between the surface and water, that prevents the heat transfer efficiency and lowers the CHF value,” he says.

      Song, who is now a postdoc at Lawrence Berkeley National Laboratory, carried out much of the research as part of his doctoral thesis work at MIT. While the various components of the new surface treatment he developed had been previously studied, the researchers say this work is the first to show that these methods could be combined to overcome the tradeoff between the two competing parameters.

      Adding a series of microscale cavities, or dents, to a surface is a way of controlling the way bubbles form on that surface, keeping them effectively pinned to the locations of the dents and preventing them from spreading out into a heat-resisting film. In this work, the researchers created an array of 10-micrometer-wide dents separated by about 2 millimeters to prevent film formation. But that separation also reduces the concentration of bubbles at the surface, which can reduce the boiling efficiency. To compensate for that, the team introduced a much smaller-scale surface treatment, creating tiny bumps and ridges at the nanometer scale, which increases the surface area and promotes the rate of evaporation under the bubbles.

      In these experiments, the cavities were made in the centers of a series of pillars on the material’s surface. These pillars, combined with nanostructures, promote wicking of liquid from the base to their tops, and this enhances the boiling process by providing more surface area exposed to the water. In combination, the three “tiers” of the surface texture — the cavity separation, the posts, and the nanoscale texturing — provide a greatly enhanced efficiency for the boiling process, Song says.

      “Those micro cavities define the position where bubbles come up,” he says. “But by separating those cavities by 2 millimeters, we separate the bubbles and minimize the coalescence of bubbles.” At the same time, the nanostructures promote evaporation under the bubbles, and the capillary action induced by the pillars supplies liquid to the bubble base. That maintains a layer of liquid water between the boiling surface and the bubbles of vapor, which enhances the maximum heat flux.

      Although their work has confirmed that the combination of these kinds of surface treatments can work and achieve the desired effects, this work was done under small-scale laboratory conditions that could not easily be scaled up to practical devices, Wang says. “These kinds of structures we’re making are not meant to be scaled in its current form,” she says, but rather were used to prove that such a system can work. One next step will be to find alternative ways of creating these kinds of surface textures so these methods could more easily be scaled up to practical dimensions.

      “Showing that we can control the surface in this way to get enhancement is a first step,” she says. “Then the next step is to think about more scalable approaches.” For example, though the pillars on the surface in these experiments were created using clean-room methods commonly used to produce semiconductor chips, there are other, less demanding ways of creating such structures, such as electrodeposition. There are also a number of different ways to produce the surface nanostructure textures, some of which may be more easily scalable.

      There may be some significant small-scale applications that could use this process in its present form, such as the thermal management of electronic devices, an area that is becoming more important as semiconductor devices get smaller and managing their heat output becomes ever more important. “There’s definitely a space there where this is really important,” Wang says.

      Even those kinds of applications will take some time to develop because typically thermal management systems for electronics use liquids other than water, known as dielectric liquids. These liquids have different surface tension and other properties than water, so the dimensions of the surface features would have to be adjusted accordingly. Work on these differences is one of the next steps for the ongoing research, Wang says.

      This same multiscale structuring technique could also be applied to different liquids, Song says, by adjusting the dimensions to account for the different properties of the liquids. “Those kinds of details can be changed, and that can be our next step,” he says.

      The team also included Carlos Diaz-Martin, Lenan Zhang, Hyeongyun Cha, and Yajing Zhao, all at MIT. The work was supported by the Advanced Research Projects Agency-Energy (ARPA-E), the Air Force Office of Scientific Research, and the Singapore-MIT Alliance for Research and Technology, and made use of the MIT.nano facilities. More

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      in Energy

      Pursuing progress at the nanoscale

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      Last fall, a team of five senior undergraduate nuclear engineering students met once a week for dinners where they took turns cooking and debated how to tackle a particularly daunting challenge set forth in their program’s capstone course, 22.033 (Nuclear Systems Design Project).

      In past semesters, students had free reign to identify any real-world problem that interested them to solve through team-driven prototyping and design. This past fall worked a little differently. The team continued the trend of tackling daunting problems, but instead got an assignment to explore a particular design challenge on MIT’s campus. Rising to the challenge, the team spent the semester seeking a feasible way to introduce a highly coveted technology at MIT.

      Housed inside a big blue dome is the MIT Nuclear Reactor Laboratory (NRL). The reactor is used to conduct a wide range of science experiments, but in recent years, there have been multiple attempts to implement an instrument at the reactor that could probe the structure of materials, molecules, and devices. With this technology, researchers could model the structure of a wide range of materials and complex liquids made of polymers or containing nanoscale inhomogeneities that differ from the larger mass. On campus, researchers for the first time could conduct experiments to better understand the properties and functions of anything placed in front of a neutron beam emanating from the reactor core.

      The impact of this would be immense. If the reactor could be adapted to conduct this advanced technique, known as small-angle neutron scattering (SANS), it would open up a whole new world of research at MIT.

      “It’s essentially using the nuclear reactor as an incredibly high-performance camera that researchers from all over MIT would be very interested in using, including nuclear science and engineering, chemical engineering, biological engineering, and materials science, who currently use this tool at other institutions,” says Zachary Hartwig, Nuclear Systems Design Project professor and the MIT Robert N. Noyce Career Development Professor.

      SANS instruments have been installed at fewer than 20 facilities worldwide, and MIT researchers have previously considered implementing the capability at the reactor to help MIT expand community-wide access to SANS. Last fall, this mission went from long-time campus dream to potential reality as it became the design challenge that Hartwig’s students confronted. Despite having no experience with SANS, the team embraced the challenge, taking the first steps to figure out how to bring this technology to campus.

      “I really loved the idea that what we were doing could have a very real impact,” says Zoe Fisher, Nuclear Systems Design Project team member and now graduate nuclear engineering student.

      Each fall, Hartwig uses the course to introduce students to real-world challenges with strict constraints on solutions, and last fall’s project came with plenty of thorny design questions for students to tackle. First was the size limitation posed by the space available at MIT’s reactor. In SANS facilities around the world, the average length of the instrument is 30 meters, but at NRL, the space available is approximately 7.5 meters. Second, these instruments can cost up to $30 million, which is far outside NRL’s proposed budget of $3 million. That meant not only did students need to design an instrument that would work in a smaller space, but also one that could be built for a tenth of the typical cost.

      “The challenge was not just implementing one of these instruments,” Hartwig says. “It was whether the students could significantly innovate beyond the ‘traditional’ approach to doing SANS to meet the daunting constraints that we have at the MIT Reactor.”

      Because NRL actually wants to pursue this project, the students had to get creative, and their creative potential was precisely why the idea arose to get them involved, says Jacopo Buongiorno, the director of science and technology at NRL and Tokyo Electric Power Company Professor in Nuclear Engineering. “Involvement in real-world projects that answer questions about feasibility and cost of new technology and capabilities is a key element of a successful undergraduate education at MIT,” Buongiorno says.

      Students say it would have been impossible to tackle the problem without the help of co-instructor Boris Khaykovich, a research scientist at NRL who specializes in neutron instrumentation.

      Over the past two decades, Khaykovich has watched as SANS became the most popular technique for analyzing material structure. As the amount of available SANS beam time at the few facilities that exist became more competitive, access declined. Today only the experiments passing the most stringent review get access. What Khaykovich hopes to bring to MIT is improved access to SANS by designing an instrument that will be suitable for a majority of run-of-the-mill experiments, even if it’s not as powerful as state-of-the-art national SANS facilities. Such an instrument can still serve a wider range of researchers who currently have few opportunities to pursue SANS experiments.

      “In the U.S., we don’t have a simple, small, day-to-day SANS instrument,” Khaykovich says.

      With Khaykovich’s help, nuclear engineering undergraduate student Liam Hines says his team was able to go much further with their assessment than they would’ve starting from scratch, with no background in SANS. This project was unlike anything they’d ever been asked of as MIT students, and for students like Hines, who contributed to NRL research his entire time on campus, it was a project that hit close to home. “We were imagining this thing that might be designed at MIT,” Hines says.

      Fisher and Hines were joined by undergraduate nuclear engineering student team members Francisco Arellano, Jovier Jimenez, and Brendan Vaughan. Together, they devised a design that surprised both Khaykovich and Hartwig, identifying creative solutions that overcame all limitations and significantly reduced cost.

      Their team’s final project featured an adaptation of a conical design that was recently experimentally tested in Japan, but not generally used. The conical design allowed them to maximize precision while working within the other constraints, resulting in an instrument design that exceeded Hartwig’s expectations. The students also showed the feasibility of using an alternative type of glass-based low-cost neutron detector to calibrate the scattering data. By avoiding the need for a traditional detector based on helium-3, which is increasingly scarce and exorbitantly expensive, such a detector would dramatically reduce cost and increase availability. Their final presentation indicated the day-to-day SANS instrument could be built at only 4.5 meters long and with an estimated cost less than $1 million.

      Khaykovich credited the students for their enthusiasm, bouncing ideas off each other and exploring as much terrain as possible by interviewing experts who implemented SANS at other facilities. “They showed quite a perseverance and an ability to go deep into a very unfamiliar territory for them,” Khaykovich says.

      Hines says that Hartwig emphasized the importance of fielding expert opinions to more quickly discover optimal solutions. Fisher says that based on their research, if their design is funded, it would make SANS “more accessible to research for the sake of knowledge,” rather than dominated by industry research.

      Hartwig and Khaykovich agreed the students’ final project results showed a baseline of how MIT could pursue SANS technology cheaply, and when NRL proceeds with its own design process, Hartwig says, “The student’s work might actually change the cost of the feasibility of this at MIT in a way that if we hadn’t run the class, we would never have thought about doing.”

      Buongiorno says as they move forward with the project, NRL staff will consult students’ findings.

      “Indeed, the students developed original technical approaches, which are now being further explored by the NRL staff and may ultimately lead to the deployment of this new important capability on the MIT campus,” Buongiorno says.

      Hartwig says it’s a goal of the Nuclear Systems Design Project course to empower students to learn how to lead teams and embrace challenges, so they can be effective leaders advancing novel solutions in research and industry. “I think it helps teach people to be agile, to be flexible, to have confidence that they can actually go off and learn what they don’t know and solve problems they may think are bigger than themselves,” he says.

      It’s common for past classes of Nuclear Systems Design Project students to continue working on ideas beyond the course, and some students have even launched companies from their project research. What’s less common is for Hartwig’s students to actively serve as engineers pointed to a particular campus problem that’s expected to be resolved in the next few years.

      “In this case, they’re actually working on something real,” Hartwig says. “Their ideas are going to very much influence what we hope will be a facility that gets built at the reactor.”

      For students, it was exciting to inform a major instrument proposal that will soon be submitted to federal funding agencies, and for Hines, it became a chance to make his mark at NRL.

      “This is a lab I’ve been contributing to my entire time at MIT, and then through this project, I finished my time at MIT contributing in a much larger sense,” Hines says. More

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      in Environment

      Better living through multicellular life cycles

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      Cooperation is a core part of life for many organisms, ranging from microbes to complex multicellular life. It emerges when individuals share resources or partition a task in such a way that each derives a greater benefit when acting together than they could on their own. For example, birds and fish flock to evade predators, slime mold swarms to hunt for food and reproduce, and bacteria form biofilms to resist stress.

      Individuals must live in the same “neighborhood” to cooperate. For bacteria, this neighborhood can be as small as tens of microns. But in environments like the ocean, it’s rare for cells with the same genetic makeup to co-occur in the same neighborhood on their own. And this necessity poses a puzzle to scientists: In environments where survival hinges on cooperation, how do bacteria build their neighborhood?

      To study this problem, MIT professor Otto X. Cordero and colleagues took inspiration from nature: They developed a model system around a common coastal seawater bacterium that requires cooperation to eat sugars from brown algae. In the system, single cells were initially suspended in seawater too far away from other cells to cooperate. To share resources and grow, the cells had to find a mechanism of creating a neighborhood. “Surprisingly, each cell was able to divide and create its own neighborhood of clones by forming tightly packed clusters,” says Cordero, associate professor in the Department of Civil and Environmental Engineering.

      A new paper, published today in Current Biology, demonstrates how an algae-eating bacterium solves the engineering challenge of creating local cell density starting from a single-celled state.

      “A key discovery was the importance of phenotypic heterogeneity in supporting this surprising mechanism of clonal cooperation,” says Cordero, lead author of the new paper.

      Using a combination of microscopy, transcriptomics, and labeling experiments to profile a cellular metabolic state, the researchers found that cells phenotypically differentiate into a sticky “shell” population and a motile, carbon-storing “core.” The researchers propose that shell cells create the cellular neighborhood needed to sustain cooperation while core cells accumulate stores of carbon that support further clonal reproduction when the multicellular structure ruptures.

      This work addresses a key piece in the bigger challenge of understanding the bacterial processes that shape our earth, such as the cycling of carbon from dead organic matter back into food webs and the atmosphere. “Bacteria are fundamentally single cells, but often what they accomplish in nature is done through cooperation. We have much to uncover about what bacteria can accomplish together and how that differs from their capacity as individuals,” adds Cordero.

      Co-authors include Julia Schwartzman and Ali Ebrahimi, former postdocs in the Cordero Lab. Other co-authors are Gray Chadwick, a former graduate student at Caltech; Yuya Sato, a senior researcher at Japan’s National Institute of Advanced Industrial Science and Technology; Benjamin Roller, a current postdoc at the University of Vienna; and Victoria Orphan of Caltech.

      Funding was provided by the Simons Foundation. Individual authors received support from the Swiss National Science Foundation, Japan Society for the Promotion of Science, the U.S. National Science Foundation, the Kavli Institute of Theoretical Physics, and the National Institutes of Health. More

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      in Energy

      Donald Sadoway wins European Inventor Award for liquid metal batteries

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      MIT Professor Donald Sadoway has won the 2022 European Inventor Award, in the category for Non-European Patent Office Countries, for his work on liquid metal batteries that could enable the long-term storage of renewable energy.

      Sadoway is the John F. Elliott Professor of Materials Chemistry in MIT’s Department of Materials Science and Engineering, and a longtime supporter and friend of the Materials Research Laboratory.

      “By enabling the large-scale storage of renewable energy, Donald Sadoway’s invention is a huge step towards the deployment of carbon-free electricity generation,” says António Campinos, president of the European Patent Office. “He has spent his career studying electrochemistry and has transformed this expertise into an invention that represents a huge step forward in the transition to green energy.”

      Sadoway was honored at the 2022 European Inventor Award ceremony on June 21. The award is one of Europe’s most prestigious innovation prizes and is presented annually to outstanding inventors from Europe and beyond who have made an exceptional contribution to society, technological progress, and economic growth.

      When accepting the award in Munich, Sadoway told the audience:

      “I am astonished. When I look at all the patented technologies that are represented at this event I see an abundance of excellence, all of them solutions to pressing problems. I wonder if the judges are assessing not only degrees of excellence but degrees of urgency. The liquid metal battery addresses an existential threat to the health of our atmosphere which is related to climate change.

      “By hosting this event the EPO celebrates invention. The thread that connects all the inventors is their efforts to make the world a better place. In my judgment there is no nobler pursuit. So perhaps this is a celebration of nobility.”

      Sadoway’s liquid metal batteries consist of three liquid layers of different densities, which naturally separate in the same way as oil and vinegar do in a salad dressing. The top and bottom layers are made from molten metals, with a middle layer of molten liquid salt.

      To keep the metals liquid, the batteries need to operate at extremely high temperatures, so Sadoway designed a system that is self-heating and insulated, requiring no external heating or cooling. They have a lifespan of more than 20 years, can maintain 99 percent of their capacity over 5,000 charging cycles, and have no combustible materials, meaning there is no fire risk.

      In 2010, with a patent for his invention and support from Bill Gates, Sadoway co-founded Ambri, based in Marlborough, Massachusetts just outside Boston, to develop a commercial product. The company will soon install a unit on a 3,700-acre development for a data center in Nevada. This battery will store energy from a reported 500 megawatts of on-site renewable generation, the same output as a natural gas power plant.

      Born in 1950 into a family of Ukrainian immigrants in Canada, Sadoway studied chemical metallurgy specializing in what he calls “extreme electrochemistry” — chemical reactions in molten salts and liquid metals that have been heated to over 500 degrees Celsius. After earning his BASc, MASc, and PhD, all from the University of Toronto, he joined the faculty at MIT in 1978. More

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      in Energy

      Evan Leppink: Seeking a way to better stabilize the fusion environment

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      “Fusion energy was always one of those kind-of sci-fi technologies that you read about,” says nuclear science and engineering PhD candidate Evan Leppink. He’s recalling the time before fusion became a part of his daily hands-on experience at MIT’s Plasma Science and Fusion Center, where he is studying a unique way to drive current in a tokamak plasma using radiofrequency (RF) waves. 

      Now, an award from the U.S. Department of Energy’s (DOE) Office of Science Graduate Student Research (SCGSR) Program will support his work with a 12-month residency at the DIII-D National Fusion Facility in San Diego, California.

      Like all tokamaks, DIII-D generates hot plasma inside a doughnut-shaped vacuum chamber wrapped with magnets. Because plasma will follow magnetic field lines, tokamaks are able to contain the turbulent plasma fuel as it gets hotter and denser, keeping it away from the edges of the chamber where it could damage the wall materials. A key part of the tokamak concept is that part of the magnetic field is created by electrical currents in the plasma itself, which helps to confine and stabilize the configuration. Researchers often launch high-power RF waves into tokamaks to drive that current.

      Leppink will be contributing to research, led by his MIT advisor Steve Wukitch, that pursues launching RF waves in DIII-D using a unique compact antenna placed on the tokamak center column. Typically, antennas are placed inside the tokamak on the outer edge of the doughnut, farthest from the central hole (or column), primarily because access and installation are easier there. This is known as the “low-field side,” because the magnetic field is lower there than at the central column, the “high-field side.” This MIT-led experiment, for the first time, will mount an antenna on the high-field side. There is some theoretical evidence that placing the wave launcher there could improve power penetration and current drive efficiency. And because the plasma environment is less harsh on this side, the antenna will survive longer, a factor important for any future power-producing tokamak.

      Leppink’s work on DIII-D focuses specifically on measuring the density of plasmas generated in the tokamak, for which he developed a “reflectometer.” This small antenna launches microwaves into the plasma, which reflect back to the antenna to be measured. The time that it takes for these microwaves to traverse the plasma provides information about the plasma density, allowing researchers to build up detailed density profiles, data critical for injecting RF power into the plasma.

      “Research shows that when we try to inject these waves into the plasma to drive the current, they can lose power as they travel through the edge region of the tokamak, and can even have problems entering the core of the plasma, where we would most like to direct them,” says Leppink. “My diagnostic will measure that edge region on the high-field side near the launcher in great detail, which provides us a way to directly verify calculations or compare actual results with simulation results.”

      Although focused on his own research, Leppink has excelled at priming other students for success in their studies and research. In 2021 he received the NSE Outstanding Teaching Assistant and Mentorship Award.

      “The highlights of TA’ing for me were the times when I could watch students go from struggling with a difficult topic to fully understanding it, often with just a nudge in the right direction and then allowing them to follow their own intuition the rest of the way,” he says.

      The right direction for Leppink points toward San Diego and RF current drive experiments on DIII-D. He is grateful for the support from the SCGSR, a program created to prepare graduate students like him for science, technology, engineering, or mathematics careers important to the DOE Office of Science mission. It provides graduate thesis research opportunities through extended residency at DOE national laboratories. He has already made several trips to DIII-D, in part to install his reflectometer, and has been impressed with the size of the operation.

      “It takes a little while to kind of compartmentalize everything and say, ‘OK, well, here’s my part of the machine. This is what I’m doing.’ It can definitely be overwhelming at times. But I’m blessed to be able to work on what has been the workhorse tokamak of the United States for the past few decades.” More

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      in Environment

      Study finds natural sources of air pollution exceed air quality guidelines in many regions

      by

      Alongside climate change, air pollution is one of the biggest environmental threats to human health. Tiny particles known as particulate matter or PM2.5 (named for their diameter of just 2.5 micrometers or less) are a particularly hazardous type of pollutant. These particles are produced from a variety of sources, including wildfires and the burning of fossil fuels, and can enter our bloodstream, travel deep into our lungs, and cause respiratory and cardiovascular damage. Exposure to particulate matter is responsible for millions of premature deaths globally every year.

      In response to the increasing body of evidence on the detrimental effects of PM2.5, the World Health Organization (WHO) recently updated its air quality guidelines, lowering its recommended annual PM2.5 exposure guideline by 50 percent, from 10 micrograms per meter cubed (μm3) to 5 μm3. These updated guidelines signify an aggressive attempt to promote the regulation and reduction of anthropogenic emissions in order to improve global air quality.

      A new study by researchers in the MIT Department of Civil and Environmental Engineering explores if the updated air quality guideline of 5 μm3 is realistically attainable across different regions of the world, particularly if anthropogenic emissions are aggressively reduced. 

      The first question the researchers wanted to investigate was to what degree moving to a no-fossil-fuel future would help different regions meet this new air quality guideline.

      “The answer we found is that eliminating fossil-fuel emissions would improve air quality around the world, but while this would help some regions come into compliance with the WHO guidelines, for many other regions high contributions from natural sources would impede their ability to meet that target,” says senior author Colette Heald, the Germeshausen Professor in the MIT departments of Civil and Environmental Engineering, and Earth, Atmospheric and Planetary Sciences. 

      The study by Heald, Professor Jesse Kroll, and graduate students Sidhant Pai and Therese Carter, published June 6 in the journal Environmental Science and Technology Letters, finds that over 90 percent of the global population is currently exposed to average annual concentrations that are higher than the recommended guideline. The authors go on to demonstrate that over 50 percent of the world’s population would still be exposed to PM2.5 concentrations that exceed the new air quality guidelines, even in the absence of all anthropogenic emissions.

      This is due to the large natural sources of particulate matter — dust, sea salt, and organics from vegetation — that still exist in the atmosphere when anthropogenic emissions are removed from the air. 

      “If you live in parts of India or northern Africa that are exposed to large amounts of fine dust, it can be challenging to reduce PM2.5 exposures below the new guideline,” says Sidhant Pai, co-lead author and graduate student. “This study challenges us to rethink the value of different emissions abatement controls across different regions and suggests the need for a new generation of air quality metrics that can enable targeted decision-making.”

      The researchers conducted a series of model simulations to explore the viability of achieving the updated PM2.5 guidelines worldwide under different emissions reduction scenarios, using 2019 as a representative baseline year. 

      Their model simulations used a suite of different anthropogenic sources that could be turned on and off to study the contribution of a particular source. For instance, the researchers conducted a simulation that turned off all human-based emissions in order to determine the amount of PM2.5 pollution that could be attributed to natural and fire sources. By analyzing the chemical composition of the PM2.5 aerosol in the atmosphere (e.g., dust, sulfate, and black carbon), the researchers were also able to get a more accurate understanding of the most important PM2.5 sources in a particular region. For example, elevated PM2.5 concentrations in the Amazon were shown to predominantly consist of carbon-containing aerosols from sources like deforestation fires. Conversely, nitrogen-containing aerosols were prominent in Northern Europe, with large contributions from vehicles and fertilizer usage. The two regions would thus require very different policies and methods to improve their air quality. 

      “Analyzing particulate pollution across individual chemical species allows for mitigation and adaptation decisions that are specific to the region, as opposed to a one-size-fits-all approach, which can be challenging to execute without an understanding of the underlying importance of different sources,” says Pai. 

      When the WHO air quality guidelines were last updated in 2005, they had a significant impact on environmental policies. Scientists could look at an area that was not in compliance and suggest high-level solutions to improve the region’s air quality. But as the guidelines have tightened, globally-applicable solutions to manage and improve air quality are no longer as evident. 

      “Another benefit of speciating is that some of the particles have different toxicity properties that are correlated to health outcomes,” says Therese Carter, co-lead author and graduate student. “It’s an important area of research that this work can help motivate. Being able to separate out that piece of the puzzle can provide epidemiologists with more insights on the different toxicity levels and the impact of specific particles on human health.”

      The authors view these new findings as an opportunity to expand and iterate on the current guidelines.  

      “Routine and global measurements of the chemical composition of PM2.5 would give policymakers information on what interventions would most effectively improve air quality in any given location,” says Jesse Kroll, a professor in the MIT departments of Civil and Environmental Engineering and Chemical Engineering. “But it would also provide us with new insights into how different chemical species in PM2.5 affect human health.”

      “I hope that as we learn more about the health impacts of these different particles, our work and that of the broader atmospheric chemistry community can help inform strategies to reduce the pollutants that are most harmful to human health,” adds Heald. More