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      in Environment

      MIT announces 2024 Bose Grants

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      MIT Provost Cynthia Barnhart announced four Professor Amar G. Bose Research Grants to support bold research projects across diverse areas of study, including a way to generate clean hydrogen from deep in the Earth, build an environmentally friendly house of basalt, design maternity clothing that monitors fetal health, and recruit sharks as ocean oxygen monitors.

      This year’s recipients are Iwnetim Abate, assistant professor of materials science and engineering; Andrew Babbin, the Cecil and Ida Green Associate Professor in Earth, Atmospheric and Planetary Sciences; Yoel Fink, professor of materials science and engineering and of electrical engineering and computer science; and Skylar Tibbits, associate professor of design research in the Department of Architecture.

      The program was named for the visionary founder of the Bose Corporation and MIT alumnus Amar G. Bose ’51, SM ’52, ScD ’56. After gaining admission to MIT, Bose became a top math student and a Fulbright Scholarship recipient. He spent 46 years as a professor at MIT, led innovations in sound design, and founded the Bose Corp. in 1964. MIT launched the Bose grant program 11 years ago to provide funding over a three-year period to MIT faculty who propose original, cross-disciplinary, and often risky research projects that would likely not be funded by conventional sources.

      “The promise of the Bose Fellowship is to help bold, daring ideas become realities, an approach that honors Amar Bose’s legacy,” says Barnhart. “Thanks to support from this program, these talented faculty members have the freedom to explore their bold and innovative ideas.”

      Deep and clean hydrogen futures

      A green energy future will depend on harnessing hydrogen as a clean energy source, sequestering polluting carbon dioxide, and mining the minerals essential to building clean energy technologies such as advanced batteries. Iwnetim Abate thinks he has a solution for all three challenges: an innovative hydrogen reactor.

      He plans to build a reactor that will create natural hydrogen from ultramafic mineral rocks in the crust. “The Earth is literally a giant hydrogen factory waiting to be tapped,” Abate explains. “A back-of-the-envelope calculation for the first seven kilometers of the Earth’s crust estimates that there is enough ultramafic rock to produce hydrogen for 250,000 years.”

      The reactor envisioned by Abate injects water to create a reaction that releases hydrogen, while also supporting the injection of climate-altering carbon dioxide into the rock, providing a global carbon capacity of 100 trillion tons. At the same time, the reactor process could provide essential elements such as lithium, nickel, and cobalt — some of the most important raw materials used in advanced batteries and electronics.

      “Ultimately, our goal is to design and develop a scalable reactor for simultaneously tapping into the trifecta from the Earth’s subsurface,” Abate says.

      Sharks as oceanographers

      If we want to understand more about how oxygen levels in the world’s seas are disturbed by human activities and climate change, we should turn to a sensing platform “that has been honed by 400 million years of evolution to perfectly sample the ocean: sharks,” says Andrew Babbin.

      As the planet warms, oceans are projected to contain less dissolved oxygen, with impacts on the productivity of global fisheries, natural carbon sequestration, and the flux of climate-altering greenhouse gasses from the ocean to the air. While scientists know dissolved oxygen is important, it has proved difficult to track over seasons, decades, and underexplored regions both shallow and deep.

      Babbin’s goal is to develop a low-cost sensor for dissolved oxygen that can be integrated with preexisting electronic shark tags used by marine biologists. “This fleet of sharks … will finally enable us to measure the extent of the low-oxygen zones of the ocean, how they change seasonally and with El Niño/La Niña oscillation, and how they expand or contract into the future.”

      The partnership with sharks will also spotlight the importance of these often-maligned animals for global marine and fisheries health, Babbin says. “We hope in pursuing this work marrying microscopic and macroscopic life we will inspire future oceanographers and conservationists, and lead to a better appreciation for the chemistry that underlies global habitability.”

      Maternity wear that monitors fetal health

      There are 2 million stillbirths around the world each year, and in the United States alone, 21,000 families suffer this terrible loss. In many cases, mothers and their doctors had no warning of any abnormalities or changes in fetal health leading up to these deaths. Yoel Fink and colleagues are looking for a better way to monitor fetal health and provide proactive treatment.

      Fink is building on years of research on acoustic fabrics to design an affordable shirt for mothers that would monitor and communicate important details of fetal health. His team’s original research drew inspiration from the function of the eardrum, designing a fiber that could be woven into other fabrics to create a kind of fabric microphone.

      “Given the sensitivity of the acoustic fabrics in sensing these nanometer-scale vibrations, could a mother’s clothing transcend its conventional role and become a health monitor, picking up on the acoustic signals and subsequent vibrations that arise from her unborn baby’s heartbeat and motion?” Fink says. “Could a simple and affordable worn fabric allow an expecting mom to sleep better, knowing that her fetus is being listened to continuously?”

      The proposed maternity shirt could measure fetal heart and breathing rate, and might be able to give an indication of the fetal body position, he says. In the final stages of development, he and his colleagues hope to develop machine learning approaches that would identify abnormal fetal heart rate and motion and deliver real-time alerts.

      A basalt house in Iceland

      In the land of volcanoes, Skylar Tibbits wants to build a case-study home almost entirely from the basalt rock that makes up the Icelandic landscape.

      Architects are increasingly interested in building using one natural material — creating a monomaterial structure — that can be easily recycled. At the moment, the building industry represents 40 percent of carbon emissions worldwide, and consists of many materials and structures, from metal to plastics to concrete, that can’t be easily disassembled or reused.

      The proposed basalt house in Iceland, a project co-led by J. Jih, associate professor of the practice in the Department of Architecture, is “an architecture that would be fully composed of the surrounding earth, that melts back into that surrounding earth at the end of its lifespan, and that can be recycled infinitely,” Tibbits explains.

      Basalt, the most common rock form in the Earth’s crust, can be spun into fibers for insulation and rebar. Basalt fiber performs as well as glass and carbon fibers at a lower cost in some applications, although it is not widely used in architecture. In cast form, it can make corrosion- and heat-resistant plumbing, cladding and flooring.

      “A monomaterial architecture is both a simple and radical proposal that unfortunately falls outside of traditional funding avenues,” says Tibbits. “The Bose grant is the perfect and perhaps the only option for our research, which we see as a uniquely achievable moonshot with transformative potential for the entire built environment.” More

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      in Environment

      New major crosses disciplines to address climate change

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      Lauren Aguilar knew she wanted to study energy systems at MIT, but before Course 1-12 (Climate System Science and Engineering) became a new undergraduate major, she didn’t see an obvious path to study the systems aspects of energy, policy, and climate associated with the energy transition.

      Aguilar was drawn to the new major that was jointly launched by the departments of Civil and Environmental Engineering (CEE) and Earth, Atmospheric and Planetary Sciences (EAPS) in 2023. She could take engineering systems classes and gain knowledge in climate.

      “Having climate knowledge enriches my understanding of how to build reliable and resilient energy systems for climate change mitigation. Understanding upon what scale we can forecast and predict climate change is crucial to build the appropriate level of energy infrastructure,” says Aguilar.

      The interdisciplinary structure of the 1-12 major has students engaging with and learning from professors in different disciplines across the Institute. The blended major was designed to provide a foundational understanding of the Earth system and engineering principles — as well as an understanding of human and institutional behavior as it relates to the climate challenge. Students learn the fundamental sciences through subjects like an atmospheric chemistry class focused on the global carbon cycle or a physics class on low-carbon energy systems. The major also covers topics in data science and machine learning as they relate to forecasting climate risks and building resilience, in addition to policy, economics, and environmental justice studies.

      Junior Ananda Figueiredo was one of the first students to declare the 1-12 major. Her decision to change majors stemmed from a motivation to improve people’s lives, especially when it comes to equality. “I like to look at things from a systems perspective, and climate change is such a complicated issue connected to many different pieces of our society,” says Figueiredo.

      A multifaceted field of study

      The 1-12 major prepares students with the necessary foundational expertise across disciplines to confront climate change. Andrew Babbin, an academic advisor in the new degree program and the Cecil and Ida Green Career Development Associate Professor in EAPS, says the new major harnesses rigorous training encompassing science, engineering, and policy to design and execute a way forward for society.

      Within its first year, Course 1-12 has attracted students with a diverse set of interests, ranging from machine learning for sustainability to nature-based solutions for carbon management to developing the next renewable energy technology and integrating it into the power system.

      Academic advisor Michael Howland, the Esther and Harold E. Edgerton Assistant Professor of Civil and Environmental Engineering, says the best part of this degree is the students, and the enthusiasm and optimism they bring to the climate challenge.

      “We have students seeking to impact policy and students double-majoring in computer science. For this generation, climate change is a challenge for today, not for the future. Their actions inside and outside the classroom speak to the urgency of the challenge and the promise that we can solve it,” Howland says.

      The degree program also leaves plenty of space for students to develop and follow their interests. Sophomore Katherine Kempff began this spring semester as a 1-12 major interested in sustainability and renewable energy. Kempff was worried she wouldn’t be able to finish 1-12 once she made the switch to a different set of classes, but Howland assured her there would be no problems, based on the structure of 1-12.

      “I really like how flexible 1-12 is. There’s a lot of classes that satisfy the requirements, and you are not pigeonholed. I feel like I’m going to be able to do what I’m interested in, rather than just following a set path of a major,” says Kempff.

      Kempff is leveraging her skills she developed this semester and exploring different career interests. She is interviewing for sustainability and energy-sector internships in Boston and MIT this summer, and is particularly interested in assisting MIT in meeting its new sustainability goals.

      Engineering a sustainable future

      The new major dovetail’s MIT’s commitment to address climate change with its steps in prioritizing and enhancing climate education. As the Institute continues making strides to accelerate solutions, students can play a leading role in changing the future.   

      “Climate awareness is critical to all MIT students, most of whom will face the consequences of the projection models for the end of the century,” says Babbin. “One-12 will be a focal point of the climate education mission to train the brightest and most creative students to engineer a better world and understand the complex science necessary to design and verify any solutions they invent.”

      Justin Cole, who transferred to MIT in January from the University of Colorado, served in the U.S. Air Force for nine years. Over the course of his service, he had a front row seat to the changing climate. From helping with the wildfire cleanup in Black Forest, Colorado — after the state’s most destructive fire at the time — to witnessing two category 5 typhoons in Japan in 2018, Cole’s experiences of these natural disasters impressed upon him that climate security was a prerequisite to international security. 

      Cole was recently accepted into the MIT Energy and Climate Club Launchpad initiative where he will work to solve real-world climate and energy problems with professionals in industry.

      “All of the dots are connecting so far in my classes, and all the hopes that I have for studying the climate crisis and the solutions to it at MIT are coming true,” says Cole.

      With a career path that is increasingly growing, there is a rising demand for scientists and engineers who have both deep knowledge of environmental and climate systems and expertise in methods for climate change mitigation.

      “Climate science must be coupled with climate solutions. As we experience worsening climate change, the environmental system will increasingly behave in new ways that we haven’t seen in the past,” says Howland. “Solutions to climate change must go beyond good engineering of small-scale components. We need to ensure that our system-scale solutions are maximally effective in reducing climate change, but are also resilient to climate change. And there is no time to waste,” he says. More

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      in Environment

      Atmospheric observations in China show rise in emissions of a potent greenhouse gas

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      To achieve the aspirational goal of the Paris Agreement on climate change — limiting the increase in global average surface temperature to 1.5 degrees Celsius above preindustrial levels — will require its 196 signatories to dramatically reduce their greenhouse gas (GHG) emissions. Those greenhouse gases differ widely in their global warming potential (GWP), or ability to absorb radiative energy and thereby warm the Earth’s surface. For example, measured over a 100-year period, the GWP of methane is about 28 times that of carbon dioxide (CO2), and the GWP of sulfur hexafluoride (SF6) is 24,300 times that of CO2, according to the Intergovernmental Panel on Climate Change (IPCC) Sixth Assessment Report. 

      Used primarily in high-voltage electrical switchgear in electric power grids, SF6 is one of the most potent greenhouse gases on Earth. In the 21st century, atmospheric concentrations of SF6 have risen sharply along with global electric power demand, threatening the world’s efforts to stabilize the climate. This heightened demand for electric power is particularly pronounced in China, which has dominated the expansion of the global power industry in the past decade. Quantifying China’s contribution to global SF6 emissions — and pinpointing its sources in the country — could lead that nation to implement new measures to reduce them, and thereby reduce, if not eliminate, an impediment to the Paris Agreement’s aspirational goal. 

      To that end, a new study by researchers at the MIT Joint Program on the Science and Policy of Global Change, Fudan University, Peking University, University of Bristol, and Meteorological Observation Center of China Meteorological Administration determined total SF6 emissions in China over 2011-21 from atmospheric observations collected from nine stations within a Chinese network, including one station from the Advanced Global Atmospheric Gases Experiment (AGAGE) network. For comparison, global total emissions were determined from five globally distributed, relatively unpolluted “background” AGAGE stations, involving additional researchers from the Scripps Institution of Oceanography and CSIRO, Australia’s National Science Agency.

      The researchers found that SF6 emissions in China almost doubled from 2.6 gigagrams (Gg) per year in 2011, when they accounted for 34 percent of global SF6 emissions, to 5.1 Gg per year in 2021, when they accounted for 57 percent of global total SF6 emissions. This increase from China over the 10-year period — some of it emerging from the country’s less-populated western regions — was larger than the global total SF6 emissions rise, highlighting the importance of lowering SF6 emissions from China in the future.

      The open-access study, which appears in the journal Nature Communications, explores prospects for future SF6 emissions reduction in China.

      “Adopting maintenance practices that minimize SF6 leakage rates or using SF6-free equipment or SF6 substitutes in the electric power grid will benefit greenhouse-gas mitigation in China,” says Minde An, a postdoc at the MIT Center for Global Change Science (CGCS) and the study’s lead author. “We see our findings as a first step in quantifying the problem and identifying how it can be addressed.”

      Emissions of SF6 are expected to last more than 1,000 years in the atmosphere, raising the stakes for policymakers in China and around the world.

      “Any increase in SF6 emissions this century will effectively alter our planet’s radiative budget — the balance between incoming energy from the sun and outgoing energy from the Earth — far beyond the multi-decadal time frame of current climate policies,” says MIT Joint Program and CGCS Director Ronald Prinn, a coauthor of the study. “So it’s imperative that China and all other nations take immediate action to reduce, and ultimately eliminate, their SF6 emissions.”

      The study was supported by the National Key Research and Development Program of China and Shanghai B&R Joint Laboratory Project, the U.S. National Aeronautics and Space Administration, and other funding agencies.   More

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      in Environment

      A new sensor detects harmful “forever chemicals” in drinking water

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      MIT chemists have designed a sensor that detects tiny quantities of perfluoroalkyl and polyfluoroalkyl substances (PFAS) — chemicals found in food packaging, nonstick cookware, and many other consumer products.

      These compounds, also known as “forever chemicals” because they do not break down naturally, have been linked to a variety of harmful health effects, including cancer, reproductive problems, and disruption of the immune and endocrine systems.

      Using the new sensor technology, the researchers showed that they could detect PFAS levels as low as 200 parts per trillion in a water sample. The device they designed could offer a way for consumers to test their drinking water, and it could also be useful in industries that rely heavily on PFAS chemicals, including the manufacture of semiconductors and firefighting equipment.

      “There’s a real need for these sensing technologies. We’re stuck with these chemicals for a long time, so we need to be able to detect them and get rid of them,” says Timothy Swager, the John D. MacArthur Professor of Chemistry at MIT and the senior author of the study, which appears this week in the Proceedings of the National Academy of Sciences.

      Other authors of the paper are former MIT postdoc and lead author Sohyun Park and MIT graduate student Collette Gordon.

      Detecting PFAS

      Coatings containing PFAS chemicals are used in thousands of consumer products. In addition to nonstick coatings for cookware, they are also commonly used in water-repellent clothing, stain-resistant fabrics, grease-resistant pizza boxes, cosmetics, and firefighting foams.

      These fluorinated chemicals, which have been in widespread use since the 1950s, can be released into water, air, and soil, from factories, sewage treatment plants, and landfills. They have been found in drinking water sources in all 50 states.

      In 2023, the Environmental Protection Agency created an “advisory health limit” for two of the most hazardous PFAS chemicals, known as perfluorooctanoic acid (PFOA) and perfluorooctyl sulfonate (PFOS). These advisories call for a limit of 0.004 parts per trillion for PFOA and 0.02 parts per trillion for PFOS in drinking water.

      Currently, the only way that a consumer could determine if their drinking water contains PFAS is to send a water sample to a laboratory that performs mass spectrometry testing. However, this process takes several weeks and costs hundreds of dollars.

      To create a cheaper and faster way to test for PFAS, the MIT team designed a sensor based on lateral flow technology — the same approach used for rapid Covid-19 tests and pregnancy tests. Instead of a test strip coated with antibodies, the new sensor is embedded with a special polymer known as polyaniline, which can switch between semiconducting and conducting states when protons are added to the material.

      The researchers deposited these polymers onto a strip of nitrocellulose paper and coated them with a surfactant that can pull fluorocarbons such as PFAS out of a drop of water placed on the strip. When this happens, protons from the PFAS are drawn into the polyaniline and turn it into a conductor, reducing the electrical resistance of the material. This change in resistance, which can be measured precisely using electrodes and sent to an external device such as a smartphone, gives a quantitative measurement of how much PFAS is present.

      This approach works only with PFAS that are acidic, which includes two of the most harmful PFAS — PFOA and perfluorobutanoic acid (PFBA).

      A user-friendly system

      The current version of the sensor can detect concentrations as low as 200 parts per trillion for PFBA, and 400 parts per trillion for PFOA. This is not quite low enough to meet the current EPA guidelines, but the sensor uses only a fraction of a milliliter of water. The researchers are now working on a larger-scale device that would be able to filter about a liter of water through a membrane made of polyaniline, and they believe this approach should increase the sensitivity by more than a hundredfold, with the goal of meeting the very low EPA advisory levels.

      “We do envision a user-friendly, household system,” Swager says. “You can imagine putting in a liter of water, letting it go through the membrane, and you have a device that measures the change in resistance of the membrane.”

      Such a device could offer a less expensive, rapid alternative to current PFAS detection methods. If PFAS are detected in drinking water, there are commercially available filters that can be used on household drinking water to reduce those levels. The new testing approach could also be useful for factories that manufacture products with PFAS chemicals, so they could test whether the water used in their manufacturing process is safe to release into the environment.

      The research was funded by an MIT School of Science Fellowship to Gordon, a Bose Research Grant, and a Fulbright Fellowship to Park. More

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      in Environment

      Gosha Geogdzhayev and Sadhana Lolla named 2024 Gates Cambridge Scholars

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      This article was updated on April 23 to reflect the promotion of Gosha Geogdzhayev from alternate to winner of the Gates Cambridge Scholarship.

      MIT seniors Gosha Geogdzhayev and Sadhana Lolla have won the prestigious Gates Cambridge Scholarship, which offers students an opportunity to pursue graduate study in the field of their choice at Cambridge University in the U.K.

      Established in 2000, Gates Cambridge offers full-cost post-graduate scholarships to outstanding applicants from countries outside of the U.K. The mission of Gates Cambridge is to build a global network of future leaders committed to improving the lives of others.

      Gosha Geogdzhayev

      Originally from New York City, Geogdzhayev is a senior majoring in physics with minors in mathematics and computer science. At Cambridge, Geogdzhayev intends to pursue an MPhil in quantitative climate and environmental science. He is interested in applying these subjects to climate science and intends to spend his career developing novel statistical methods for climate prediction.

      At MIT, Geogdzhayev researches climate emulators with Professor Raffaele Ferrari’s group in the Department of Earth, Atmospheric and Planetary Sciences and is part of the “Bringing Computation to the Climate Challenge” Grand Challenges project. He is currently working on an operator-based emulator for the projection of climate extremes. Previously, Geogdzhayev studied the statistics of changing chaotic systems, work that has recently been published as a first-author paper.

      As a recipient of the National Oceanic and Atmospheric Agency (NOAA) Hollings Scholarship, Geogdzhayev has worked on bias correction methods for climate data at the NOAA Geophysical Fluid Dynamics Laboratory. He is the recipient of several other awards in the field of earth and atmospheric sciences, notably the American Meteorological Society Ward and Eileen Seguin Scholarship.

      Outside of research, Geogdzhayev enjoys writing poetry and is actively involved with his living community, Burton 1, for which he has previously served as floor chair.

      Sadhana Lolla

      Lolla, a senior from Clarksburg, Maryland, is majoring in computer science and minoring in mathematics and literature. At Cambridge, she will pursue an MPhil in technology policy.

      In the future, Lolla aims to lead conversations on deploying and developing technology for marginalized communities, such as the rural Indian village that her family calls home, while also conducting research in embodied intelligence.

      At MIT, Lolla conducts research on safe and trustworthy robotics and deep learning at the Distributed Robotics Laboratory with Professor Daniela Rus. Her research has spanned debiasing strategies for autonomous vehicles and accelerating robotic design processes. At Microsoft Research and Themis AI, she works on creating uncertainty-aware frameworks for deep learning, which has impacts across computational biology, language modeling, and robotics. She has presented her work at the Neural Information Processing Systems (NeurIPS) conference and the International Conference on Machine Learning (ICML). 

      Outside of research, Lolla leads initiatives to make computer science education more accessible globally. She is an instructor for class 6.s191 (MIT Introduction to Deep Learning), one of the largest AI courses in the world, which reaches millions of students annually. She serves as the curriculum lead for Momentum AI, the only U.S. program that teaches AI to underserved students for free, and she has taught hundreds of students in Northern Scotland as part of the MIT Global Teaching Labs program.

      Lolla was also the director for xFair, MIT’s largest student-run career fair, and is an executive board member for Next Sing, where she works to make a cappella more accessible for students across musical backgrounds. In her free time, she enjoys singing, solving crossword puzzles, and baking. More

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      in Energy

      With just a little electricity, MIT researchers boost common catalytic reactions

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      A simple technique that uses small amounts of energy could boost the efficiency of some key chemical processing reactions, by up to a factor of 100,000, MIT researchers report. These reactions are at the heart of petrochemical processing, pharmaceutical manufacturing, and many other industrial chemical processes.

      The surprising findings are reported today in the journal Science, in a paper by MIT graduate student Karl Westendorff, professors Yogesh Surendranath and Yuriy Roman-Leshkov, and two others.

      “The results are really striking,” says Surendranath, a professor of chemistry and chemical engineering. Rate increases of that magnitude have been seen before but in a different class of catalytic reactions known as redox half-reactions, which involve the gain or loss of an electron. The dramatically increased rates reported in the new study “have never been observed for reactions that don’t involve oxidation or reduction,” he says.

      The non-redox chemical reactions studied by the MIT team are catalyzed by acids. “If you’re a first-year chemistry student, probably the first type of catalyst you learn about is an acid catalyst,” Surendranath says. There are many hundreds of such acid-catalyzed reactions, “and they’re super important in everything from processing petrochemical feedstocks to making commodity chemicals to doing transformations in pharmaceutical products. The list goes on and on.”

      “These reactions are key to making many products we use daily,” adds Roman-Leshkov, a professor of chemical engineering and chemistry.

      But the people who study redox half-reactions, also known as electrochemical reactions, are part of an entirely different research community than those studying non-redox chemical reactions, known as thermochemical reactions. As a result, even though the technique used in the new study, which involves applying a small external voltage, was well-known in the electrochemical research community, it had not been systematically applied to acid-catalyzed thermochemical reactions.

      People working on thermochemical catalysis, Surendranath says, “usually don’t consider” the role of the electrochemical potential at the catalyst surface, “and they often don’t have good ways of measuring it. And what this study tells us is that relatively small changes, on the order of a few hundred millivolts, can have huge impacts — orders of magnitude changes in the rates of catalyzed reactions at those surfaces.”

      “This overlooked parameter of surface potential is something we should pay a lot of attention to because it can have a really, really outsized effect,” he says. “It changes the paradigm of how we think about catalysis.”

      Chemists traditionally think about surface catalysis based on the chemical binding energy of molecules to active sites on the surface, which influences the amount of energy needed for the reaction, he says. But the new findings show that the electrostatic environment is “equally important in defining the rate of the reaction.”

      The team has already filed a provisional patent application on parts of the process and is working on ways to apply the findings to specific chemical processes. Westendorff says their findings suggest that “we should design and develop different types of reactors to take advantage of this sort of strategy. And we’re working right now on scaling up these systems.”

      While their experiments so far were done with a two-dimensional planar electrode, most industrial reactions are run in three-dimensional vessels filled with powders. Catalysts are distributed through those powders, providing a lot more surface area for the reactions to take place. “We’re looking at how catalysis is currently done in industry and how we can design systems that take advantage of the already existing infrastructure,” Westendorff says.

      Surendranath adds that these new findings “raise tantalizing possibilities: Is this a more general phenomenon? Does electrochemical potential play a key role in other reaction classes as well? In our mind, this reshapes how we think about designing catalysts and promoting their reactivity.”

      Roman-Leshkov adds that “traditionally people who work in thermochemical catalysis would not associate these reactions with electrochemical processes at all. However, introducing this perspective to the community will redefine how we can integrate electrochemical characteristics into thermochemical catalysis. It will have a big impact on the community in general.”

      While there has typically been little interaction between electrochemical and thermochemical catalysis researchers, Surendranath says, “this study shows the community that there’s really a blurring of the line between the two, and that there is a huge opportunity in cross-fertilization between these two communities.”

      Westerndorff adds that to make it work, “you have to design a system that’s pretty unconventional to either community to isolate this effect.” And that helps explain why such a dramatic effect had never been seen before. He notes that even their paper’s editor asked them why this effect hadn’t been reported before. The answer has to do with “how disparate those two ideologies were before this,” he says. “It’s not just that people don’t really talk to each other. There are deep methodological differences between how the two communities conduct experiments. And this work is really, we think, a great step toward bridging the two.”

      In practice, the findings could lead to far more efficient production of a wide variety of chemical materials, the team says. “You get orders of magnitude changes in rate with very little energy input,” Surendranath says. “That’s what’s amazing about it.”

      The findings, he says, “build a more holistic picture of how catalytic reactions at interfaces work, irrespective of whether you’re going to bin them into the category of electrochemical reactions or thermochemical reactions.” He adds that “it’s rare that you find something that could really revise our foundational understanding of surface catalytic reactions in general. We’re very excited.”

      “This research is of the highest quality,” says Costas Vayenas, a professor of engineering at the university of Patras, in Greece, who was not associated with the study. The work “is very promising for practical applications, particularly since it extends previous related work in redox catalytic systems,” he says.

      The team included MIT postdoc Max Hulsey PhD ’22 and graduate student Thejas Wesley PhD ’23, and was supported by the Air Force Office of Scientific Research and the U.S. Department of Energy Basic Energy Sciences. More

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      in Environment

      Study: Global deforestation leads to more mercury pollution

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      About 10 percent of human-made mercury emissions into the atmosphere each year are the result of global deforestation, according to a new MIT study.

      The world’s vegetation, from the Amazon rainforest to the savannahs of sub-Saharan Africa, acts as a sink that removes the toxic pollutant from the air. However, if the current rate of deforestation remains unchanged or accelerates, the researchers estimate that net mercury emissions will keep increasing.

      “We’ve been overlooking a significant source of mercury, especially in tropical regions,” says Ari Feinberg, a former postdoc in the Institute for Data, Systems, and Society (IDSS) and lead author of the study.

      The researchers’ model shows that the Amazon rainforest plays a particularly important role as a mercury sink, contributing about 30 percent of the global land sink. Curbing Amazon deforestation could thus have a substantial impact on reducing mercury pollution.

      The team also estimates that global reforestation efforts could increase annual mercury uptake by about 5 percent. While this is significant, the researchers emphasize that reforestation alone should not be a substitute for worldwide pollution control efforts.

      “Countries have put a lot of effort into reducing mercury emissions, especially northern industrialized countries, and for very good reason. But 10 percent of the global anthropogenic source is substantial, and there is a potential for that to be even greater in the future. [Addressing these deforestation-related emissions] needs to be part of the solution,” says senior author Noelle Selin, a professor in IDSS and MIT’s Department of Earth, Atmospheric and Planetary Sciences.

      Feinberg and Selin are joined on the paper by co-authors Martin Jiskra, a former Swiss National Science Foundation Ambizione Fellow at the University of Basel; Pasquale Borrelli, a professor at Roma Tre University in Italy; and Jagannath Biswakarma, a postdoc at the Swiss Federal Institute of Aquatic Science and Technology. The paper appears today in Environmental Science and Technology.

      Modeling mercury

      Over the past few decades, scientists have generally focused on studying deforestation as a source of global carbon dioxide emissions. Mercury, a trace element, hasn’t received the same attention, partly because the terrestrial biosphere’s role in the global mercury cycle has only recently been better quantified.

      Plant leaves take up mercury from the atmosphere, in a similar way as they take up carbon dioxide. But unlike carbon dioxide, mercury doesn’t play an essential biological function for plants. Mercury largely stays within a leaf until it falls to the forest floor, where the mercury is absorbed by the soil.

      Mercury becomes a serious concern for humans if it ends up in water bodies, where it can become methylated by microorganisms. Methylmercury, a potent neurotoxin, can be taken up by fish and bioaccumulated through the food chain. This can lead to risky levels of methylmercury in the fish humans eat.

      “In soils, mercury is much more tightly bound than it would be if it were deposited in the ocean. The forests are doing a sort of ecosystem service, in that they are sequestering mercury for longer timescales,” says Feinberg, who is now a postdoc in the Blas Cabrera Institute of Physical Chemistry in Spain.

      In this way, forests reduce the amount of toxic methylmercury in oceans.

      Many studies of mercury focus on industrial sources, like burning fossil fuels, small-scale gold mining, and metal smelting. A global treaty, the 2013 Minamata Convention, calls on nations to reduce human-made emissions. However, it doesn’t directly consider impacts of deforestation.

      The researchers launched their study to fill in that missing piece.

      In past work, they had built a model to probe the role vegetation plays in mercury uptake. Using a series of land use change scenarios, they adjusted the model to quantify the role of deforestation.

      Evaluating emissions

      This chemical transport model tracks mercury from its emissions sources to where it is chemically transformed in the atmosphere and then ultimately to where it is deposited, mainly through rainfall or uptake into forest ecosystems.

      They divided the Earth into eight regions and performed simulations to calculate deforestation emissions factors for each, considering elements like type and density of vegetation, mercury content in soils, and historical land use.

      However, good data for some regions were hard to come by.

      They lacked measurements from tropical Africa or Southeast Asia — two areas that experience heavy deforestation. To get around this gap, they used simpler, offline models to simulate hundreds of scenarios, which helped them improve their estimations of potential uncertainties.

      They also developed a new formulation for mercury emissions from soil. This formulation captures the fact that deforestation reduces leaf area, which increases the amount of sunlight that hits the ground and accelerates the outgassing of mercury from soils.

      The model divides the world into grid squares, each of which is a few hundred square kilometers. By changing land surface and vegetation parameters in certain squares to represent deforestation and reforestation scenarios, the researchers can capture impacts on the mercury cycle.

      Overall, they found that about 200 tons of mercury are emitted to the atmosphere as the result of deforestation, or about 10 percent of total human-made emissions. But in tropical and sub-tropical countries, deforestation emissions represent a higher percentage of total emissions. For example, in Brazil deforestation emissions are 40 percent of total human-made emissions.

      In addition, people often light fires to prepare tropical forested areas for agricultural activities, which causes more emissions by releasing mercury stored by vegetation.

      “If deforestation was a country, it would be the second highest emitting country, after China, which emits around 500 tons of mercury a year,” Feinberg adds.

      And since the Minamata Convention is now addressing primary mercury emissions, scientists can expect deforestation to become a larger fraction of human-made emissions in the future.

      “Policies to protect forests or cut them down have unintended effects beyond their target. It is important to consider the fact that these are systems, and they involve human activities, and we need to understand them better in order to actually solve the problems that we know are out there,” Selin says.

      By providing this first estimate, the team hopes to inspire more research in this area.

      In the future, they want to incorporate more dynamic Earth system models into their analysis, which would enable them to interactively track mercury uptake and better model the timescale of vegetation regrowth.

      “This paper represents an important advance in our understanding of global mercury cycling by quantifying a pathway that has long been suggested but not yet quantified. Much of our research to date has focused on primary anthropogenic emissions — those directly resulting from human activity via coal combustion or mercury-gold amalgam burning in artisanal and small-scale gold mining,” says Jackie Gerson, an assistant professor in the Department of Earth and Environmental Sciences at Michigan State University, who was not involved with this research. “This research shows that deforestation can also result in substantial mercury emissions and needs to be considered both in terms of global mercury models and land management policies. It therefore has the potential to advance our field scientifically as well as to promote policies that reduce mercury emissions via deforestation.

      This work was funded, in part, by the U.S. National Science Foundation, the Swiss National Science Foundation, and Swiss Federal Institute of Aquatic Science and Technology. More

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      3 Questions: The Climate Project at MIT

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      MIT is preparing a major campus-wide effort to develop technological, behavioral, and policy solutions to some of the toughest problems now impeding an effective global climate response. The Climate Project at MIT, as the new enterprise is known, includes new arrangements for promoting cross-Institute collaborations and new mechanisms for engaging with outside partners to speed the development and implementation of climate solutions.

      MIT News spoke with Richard K. Lester, MIT’s vice provost for international activities, who has helped oversee the development of the project.

      Q: What is the Climate Project at MIT?

      A: In her inaugural address last May, President Kornbluth called on the MIT community to join her in a “bold, tenacious response” to climate change. The Climate Project at MIT is a response to that call. It aims to mobilize every part of MIT to develop, deliver, and scale up practical climate solutions, as quickly as possible.

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      At MIT, well over 300 of our faculty are already working with their students and research staff members on different aspects of the climate problem. Almost all of our academic departments and more than a score of our interdepartmental labs and centers are involved in some way. What they are doing is remarkable, and this decentralized structure reflects the best traditions of MIT as a “bottom up,” entrepreneurial institution. But, as President Kornbluth said, we must do much more. We must be bolder in our research choices and more creative in how we organize ourselves to work with each other and with our partners. The purpose of the Climate Project is to support our community’s efforts to do bigger things faster in the climate domain. We will have succeeded if our work changes the trajectory of global climate outcomes for the better.

      I want to be clear that the clay is still wet here. The Climate Project will continue to take shape as more members of the MIT community bring their excellence, their energy, and their ambition to bear on the climate challenge. But I believe we have a vision and a framework for accelerating and amplifying MIT’s real-world climate impact, and I know that President Kornbluth is eager to share this progress report with the MIT community now to convey the breadth and ambition of what we’re planning.

      Q: How will the project be organized?

      A: The Climate Project will have three core components: the Climate Missions; their offshoots, the Climate Frontier Projects; and Climate HQ. A new vice president for climate will lead the enterprise.

      Initially there will be six missions, which you can read about in the plan. Each will address a different domain of climate impact where new solutions are required and where a critical mass of research excellence exists at MIT. One such mission, of course, is to decarbonize energy and industry, an area where we estimate that about 150 of our faculty are already working.

      The mission leaders will build multidisciplinary problem-solving communities reaching across the Institute and beyond. Each of these will be charged with roadmapping and assessing progress toward its mission, identifying critical gaps and bottlenecks, and launching applied research projects to accelerate progress where the MIT community and our partners are well-positioned to achieve impactful results. These projects — the climate frontier projects — will benefit from active, professional project management, with clear metrics and milestones. We are in a critical decade for responding to climate change, so it’s important that these research projects move quickly, with an eye on producing real-world results.

      The new Climate HQ will drive the overall vision for the Climate Project and support the work of the missions. We’ve talked about a core focus on impact-driven research, but much is still unknown about the Earth’s physical and biogeochemical systems, and there is also much to be learned about the behavior of the social and political systems that led us to the very difficult situation the world now faces. Climate HQ will support fundamental research in the scientific and humanistic disciplines related to climate, and will promote engagement between these disciplines and the missions. We must also advance climate-related education, led by departments and programs, as well as policy work, public outreach, and more, including an MIT-wide student-centric Climate Corps to elevate climate-related, community-focused service in MIT’s culture.

      Q: Why are partners a key part of this project?

      A: It is important to build strong partners right from the very start for our innovations, inventions, and discoveries to have any prospect of achieving scale. And in many cases, with climate change, it’s all about scale.

      One of the aims of this initiative is to strengthen MIT’s climate “scaffolding” — the people and processes connecting what we do on campus to the practical world of climate impact and response. We can build on MIT’s highly developed infrastructure for translation, innovation, and entrepreneurship, even as we promote other important pathways to scale involving communities, municipalities, and other not-for-profit organizations. Working with all these different organizations will help us build a broad infrastructure to help us get traction in the world. On a related note, the Sloan School of Management will be sharing details in the coming days of an exciting new effort to enhance MIT’s contributions in the climate policy arena.

      MIT is committing $75 million, including $25 million from Sloan, at the outset of the project. But we anticipate developing new partnerships, including philanthropic partnerships, to increase that scope dramatically. More