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      Moving perovskite advancements from the lab to the manufacturing floor

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      The following was issued as a joint announcement from MIT.nano and the MIT Research Laboratory for Electronics; CubicPV; Verde Technologies; Princeton University; and the University of California at San Diego.

      Tandem solar cells are made of stacked materials — such as silicon paired with perovskites — that together absorb more of the solar spectrum than single materials, resulting in a dramatic increase in efficiency. Their potential to generate significantly more power than conventional cells could make a meaningful difference in the race to combat climate change and the transition to a clean-energy future.

      However, current methods to create stable and efficient perovskite layers require time-consuming, painstaking rounds of design iteration and testing, inhibiting their development for commercial use. Today, the U.S. Department of Energy Solar Energy Technologies Office (SETO) announced that MIT has been selected to receive an $11.25 million cost-shared award to establish a new research center to address this challenge by using a co-optimization framework guided by machine learning and automation.

      A collaborative effort with lead industry participant CubicPV, solar startup Verde Technologies, and academic partners Princeton University and the University of California San Diego (UC San Diego), the center will bring together teams of researchers to support the creation of perovskite-silicon tandem solar modules that are co-designed for both stability and performance, with goals to significantly accelerate R&D and the transfer of these achievements into commercial environments.

      “Urgent challenges demand rapid action. This center will accelerate the development of tandem solar modules by bringing academia and industry into closer partnership,” says MIT professor of mechanical engineering Tonio Buonassisi, who will direct the center. “We’re grateful to the Department of Energy for supporting this powerful new model and excited to get to work.”

      Adam Lorenz, CTO of solar energy technology company CubicPV, stresses the importance of thinking about scale, alongside quality and efficiency, to accelerate the perovskite effort into the commercial environment. “Instead of chasing record efficiencies with tiny pixel-sized devices and later attempting to stabilize them, we will simultaneously target stability, reproducibility, and efficiency,” he says. “It’s a module-centric approach that creates a direct channel for R&D advancements into industry.”

      The center will be named Accelerated Co-Design of Durable, Reproducible, and Efficient Perovskite Tandems, or ADDEPT. The grant will be administered through the MIT Research Laboratory for Electronics (RLE).

      David Fenning, associate professor of nanoengineering at UC San Diego, has worked with Buonassisi on the idea of merging materials, automation, and computation, specifically in this field of artificial intelligence and solar, since 2014. Now, a central thrust of the ADDEPT project will be to deploy machine learning and robotic screening to optimize processing of perovskite-based solar materials for efficiency and durability.

      “We have already seen early indications of successful technology transfer between our UC San Diego robot PASCAL and industry,” says Fenning. “With this new center, we will bring research labs and the emerging perovskite industry together to improve reproducibility and reduce time to market.”

      “Our generation has an obligation to work collaboratively in the fight against climate change,” says Skylar Bagdon, CEO of Verde Technologies, which received the American-Made Perovskite Startup Prize. “Throughout the course of this center, Verde will do everything in our power to help this brilliant team transition lab-scale breakthroughs into the world where they can have an impact.”

      Several of the academic partners echoed the importance of the joint effort between academia and industry. Barry Rand, professor of electrical and computer engineering at the Andlinger Center for Energy and the Environment at Princeton University, pointed to the intersection of scientific knowledge and market awareness. “Understanding how chemistry affects films and interfaces will empower us to co-design for stability and performance,” he says. “The center will accelerate this use-inspired science, with close guidance from our end customers, the industry partners.”

      A critical resource for the center will be MIT.nano, a 200,000-square-foot research facility set in the heart of the campus. MIT.nano Director Vladimir Bulović, the Fariborz Maseeh (1990) Professor of Emerging Technology, says he envisions MIT.nano as a hub for industry and academic partners, facilitating technology development and transfer through shared lab space, open-access equipment, and streamlined intellectual property frameworks.

      “MIT has a history of groundbreaking innovation using perovskite materials for solar applications,” says Bulović. “We’re thrilled to help build on that history by anchoring ADDEPT at MIT.nano and working to help the nation advance the future of these promising materials.”

      MIT was selected as a part of the SETO Fiscal Year 2022 Photovoltaics (PV) funding program, an effort to reduce costs and supply chain vulnerabilities, further develop durable and recyclable solar technologies, and advance perovskite PV technologies toward commercialization. ADDEPT is one project that will tackle perovskite durability, which will extend module life. The overarching goal of these projects is to lower the levelized cost of electricity generated by PV.

      Research groups involved with the ADDEPT project at MIT include Buonassisi’s Accelerated Materials Laboratory for Sustainability (AMLS), Bulović’s Organic and Nanostructured Electronics (ONE) Lab, and the Bawendi Group led by Lester Wolfe Professor in Chemistry Moungi Bawendi. Also working on the project is Jeremiah Mwaura, research scientist in the ONE Lab. More

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      MIT Energy Conference grapples with geopolitics

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      As Russia’s war in Ukraine rages on, this year’s MIT Energy Conference spotlighted the role of geopolitics in the world’s efforts to lower greenhouse gas emissions and mitigate the worst effects of climate change.

      Each year, the student-run conference, which its organizers say is the largest of its kind, brings together leaders from around the globe to discuss humanity’s most pressing energy and sustainability challenges.

      The event always involves perspectives from the investment, business, research, and startup communities. But this year, as more than 600 attendees gathered on April 11 and 12 for a whirlwind of keynote talks, fireside chats, and panel discussions, common themes also included the influence of Russia’s war, rising tensions between the U.S. and China, and international collaboration.

      As participants grappled with the evolving geopolitical landscape, some speakers encouraged moving past isolationist tendencies.

      “Some people push for self-sufficiency, others emphasize that we should not rely on trading partners that don’t share our values — I think both arguments are misguided,” said Juan Carlos Jobet, Chile’s former ministry of energy and mining. “No country has all that’s needed to create an energy system that’s affordable, clean, and secure. … A third of the world’s energy output is generated in nondemocratic countries. Can we really make our energy systems affordable and secure and curb climate change while excluding those countries from our collective effort? If we enter an area of protectionism and disintegration, we will all be worse off.”

      Another theme was optimism, such as that expressed by Volodymyr Kudrytskyi, CEO of Ukraine’s national power company, who spoke to the conference live from Kyiv. Kudrytskyi outlined Russia’s attacks on Ukraine’s power grids, which included more than 1,000 heavy missiles, making it the largest-ever campaign against a country’s power grid.

      Still, Kudrytskyi said he was confident he’d be able to attend the conference in person next year. As it happened, Kudrytskyi’s presentation marked the day Ukraine resumed its energy exports to other countries.

      “The good news is, after all of that, our system survived and continues operations,” he said.

      Energy security and the green transition

      Richard Duke, the U.S. Department of State’s deputy special envoy for climate, opened the conference with a keynote centered on the U.S.’ role in the global shift toward cleaner energy. Duke was among those advocating for a more integrated and diversified global energy system, noting that no country can address climate change on its own.

      “We need to do all of these things in parallel, in concert with other governments, and through the architecture of the Paris Climate agreement that wraps it together in ambitious net greenhouse gas abatement targets,” Duke said.

      Following his talk, Ditte Juul Jørgensen, the European Commission’s director general for energy, discussed the shift in the EU’s energy policies spurred by the Russian invasion of Ukraine.

      She admitted the EU had grown too dependent on Russian natural gas, but said the invasion forced European states to revise their energy strategy while keeping their long-term objective of net neutrality by 2050.

      “We see energy security and the green transition as interlinked. There is no energy security without the energy transition toward climate neutrality, and there’s no energy transition without energy security,” Jorgensen said.

      Jørgensen also outlined steps the EU has taken to improve its energy security over the last year, including rolling out additional renewable energy projects and replacing Russian fuel with fuel from the U.S., which has now become the continent’s main supplier of energy.

      “The fight against climate change is our shared ambition, it’s our shared responsibility, and I think we’ve shown over these last few years that we can turn that ambition into action and bring results,” she said.

      A challenge and an opportunity

      Optimism also shone through in the way speakers framed the green energy transition as a business opportunity. In keeping with the idea, the conference included a showcase of more than 30 startups focused on clean energy and sustainability.

      “We’re all battling a huge problem that needs a collective effort,” said Malav Sukhadia of Sol Clarity, a conference exhibitor that uses electricity to clean solar panels as a way to replace water cleaning. “This is one of the best energy conferences in the world. We felt if you’re in climate tech, you have to be here.”

      Technological development was a pillar of the conference, and a big topic in those discussions was green hydrogen, a clean fuel source that could replace natural gas in a number of applications and be produced using renewable energy. In one panel discussion on the technology, Sunita Satyapal of the Department of Energy noted the agency has been funding hydrogen development since the 1970s. Other panel members also stressed the maturity of the technology.

      “A lot of the technology needed to advance the ecosystem exists now,” said Laura Parkan, vice president of hydrogen energy at Air Liquide Americas. “The challenge is to get things to a large enough scale so that the costs come down to make it more affordable and really advance the hydrogen ecosystem.”

      Still, panel members acknowledged more technological development is needed to leverage the full potential of hydrogen, such as better mechanisms for storage and transportation.

      Other advanced technologies mentioned in panel discussions included advanced geothermal energy and small modular nuclear reactors that could be built and deployed more quickly than conventional reactors.

      “Exploring these different technologies may actually get us to the net zero — or even a zero carbon future — that we’re hoping for in electricity generation,” said Emma Wong of the OECD Nuclear Energy Agency, noting there are more than 80 advanced reactor designs that have been explored around the world. “There are various challenges and enabling conditions to be addressed, but places like China and Russia are already building these things, so there’s not a technological barrier.”

      “Glass half full”

      Despite the tall tasks that lie ahead, some speakers took a moment to celebrate accomplishments thus far.

      “It’s incredible to think about the progress we’ve made in the last 10 years,” said Neil Brown of the KKR investment firm, whose company is working to build a large offshore wind project. “Solar and wind and electric vehicles have gone from impossibly expensive and hard to imagine penetrating the market to being very close to, if not already at, cost parity. We’ve really come an awful long way.”

      Other speakers mixed their positivity with a confession of envy for the opportunity ahead of the young people in the audience, many of them students from MIT.

      “I have a mix of excitement from the speakers we’ve heard so far and a little bit of envy as well for the open road the young students and professionals here have in front of them,” said Jobert. “Coming back to this place has made me reconnect with the sense of opportunity and responsibility that I felt as a student.”

      Jobert offered lessons learned from his country’s struggles with an energy crisis, populist policies, and severe droughts. His talk finished with questions that struck at the heart of the conference.

      “The evidence is clear: The Earth will change. How much is still to be decided,” Jobert said. “The energy sector has been a central part of the problem. We now must work to become an essential pierce of the solution. Where should we focus our efforts? What can we learn from each other?” More

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      An interdisciplinary approach to fighting climate change through clean energy solutions

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      In early 2021, the U.S. government set an ambitious goal: to decarbonize its power grid, the system that generates and transmits electricity throughout the country, by 2035. It’s an important goal in the fight against climate change, and will require a switch from current, greenhouse-gas producing energy sources (such as coal and natural gas), to predominantly renewable ones (such as wind and solar).

      Getting the power grid to zero carbon will be a challenging undertaking, as Audun Botterud, a principal research scientist at the MIT Laboratory for Information and Decision Systems (LIDS) who has long been interested in the problem, knows well. It will require building lots of renewable energy generators and new infrastructure; designing better technology to capture, store, and carry electricity; creating the right regulatory and economic incentives; and more. Decarbonizing the grid also presents many computational challenges, which is where Botterud’s focus lies. Botterud has modeled different aspects of the grid — the mechanics of energy supply, demand, and storage, and electricity markets — where economic factors can have a huge effect on how quickly renewable solutions get adopted.

      On again, off again

      A major challenge of decarbonization is that the grid must be designed and operated to reliably meet demand. Using renewable energy sources complicates this, as wind and solar power depend on an infamously volatile system: the weather. A sunny day becomes gray and blustery, and wind turbines get a boost but solar farms go idle. This will make the grid’s energy supply variable and hard to predict. Additional resources, including batteries and backup power generators, will need to be incorporated to regulate supply. Extreme weather events, which are becoming more common with climate change, can further strain both supply and demand. Managing a renewables-driven grid will require algorithms that can minimize uncertainty in the face of constant, sometimes random fluctuations to make better predictions of supply and demand, guide how resources are added to the grid, and inform how those resources are committed and dispatched across the entire United States.

      “The problem of managing supply and demand in the grid has to happen every second throughout the year, and given how much we rely on electricity in society, we need to get this right,” Botterud says. “You cannot let the reliability drop as you increase the amount of renewables, especially because I think that will lead to resistance towards adopting renewables.”

      That is why Botterud feels fortunate to be working on the decarbonization problem at LIDS — even though a career here is not something he had originally planned. Botterud’s first experience with MIT came during his time as a graduate student in his home country of Norway, when he spent a year as a visiting student with what is now called the MIT Energy Initiative. He might never have returned, except that while at MIT, Botterud met his future wife, Bilge Yildiz. The pair both ended up working at the Argonne National Laboratory outside of Chicago, with Botterud focusing on challenges related to power systems and electricity markets. Then Yildiz got a faculty position at MIT, where she is a professor of nuclear and materials science and engineering. Botterud moved back to the Cambridge area with her and continued to work for Argonne remotely, but he also kept an eye on local opportunities. Eventually, a position at LIDS became available, and Botterud took it, while maintaining his connections to Argonne.

      “At first glance, it may not be an obvious fit,” Botterud says. “My work is very focused on a specific application, power system challenges, and LIDS tends to be more focused on fundamental methods to use across many different application areas. However, being at LIDS, my lab [the Energy Analytics Group] has access to the most recent advances in these fundamental methods, and we can apply them to power and energy problems. Other people at LIDS are working on energy too, so there is growing momentum to address these important problems.”

      Weather, space, and time

      Much of Botterud’s research involves optimization, using mathematical programming to compare alternatives and find the best solution. Common computational challenges include dealing with large geographical areas that contain regions with different weather, different types and quantities of renewable energy available, and different infrastructure and consumer needs — such as the entire United States. Another challenge is the need for granular time resolution, sometimes even down to the sub-second level, to account for changes in energy supply and demand.

      Often, Botterud’s group will use decomposition to solve such large problems piecemeal and then stitch together solutions. However, it’s also important to consider systems as a whole. For example, in a recent paper, Botterud’s lab looked at the effect of building new transmission lines as part of national decarbonization. They modeled solutions assuming coordination at the state, regional, or national level, and found that the more regions coordinate to build transmission infrastructure and distribute electricity, the less they will need to spend to reach zero carbon.

      In other projects, Botterud uses game theory approaches to study strategic interactions in electricity markets. For example, he has designed agent-based models to analyze electricity markets. These assume each actor will make strategic decisions in their own best interest and then simulate interactions between them. Interested parties can use the models to see what would happen under different conditions and market rules, which may lead companies to make different investment decisions, or governing bodies to issue different regulations and incentives. These choices can shape how quickly the grid gets decarbonized.

      Botterud is also collaborating with researchers in MIT’s chemical engineering department who are working on improving battery storage technologies. Batteries will help manage variable renewable energy supply by capturing surplus energy during periods of high generation to release during periods of insufficient generation. Botterud’s group models the sort of charge cycles that batteries are likely to experience in the power grid, so that chemical engineers in the lab can test their batteries’ abilities in more realistic scenarios. In turn, this also leads to a more realistic representation of batteries in power system optimization models.

      These are only some of the problems that Botterud works on. He enjoys the challenge of tackling a spectrum of different projects, collaborating with everyone from engineers to architects to economists. He also believes that such collaboration leads to better solutions. The problems created by climate change are myriad and complex, and solving them will require researchers to cooperate and explore.

      “In order to have a real impact on interdisciplinary problems like energy and climate,” Botterud says, “you need to get outside of your research sweet spot and broaden your approach.” More

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      Mining for the clean energy transition

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      In a world powered increasingly by clean energy, drilling for oil and gas will gradually give way to digging for metals and minerals. Today, the “critical minerals” used to make electric cars, solar panels, wind turbines, and grid-scale battery storage are facing soaring demand — and some acute bottlenecks as miners race to catch up.

      According to a report from the International Energy Agency, by 2040, the worldwide demand for copper is expected to roughly double; demand for nickel and cobalt will grow at least sixfold; and the world’s hunger for lithium could reach 40 times what we use today.

      “Society is looking to the clean energy transition as a way to solve the environmental and social harms of climate change,” says Scott Odell, a visiting scientist at the MIT Environmental Solutions Initiative (ESI), where he helps run the ESI Mining, Environment, and Society Program, who is also a visiting assistant professor at George Washington University. “Yet mining the materials needed for that transition would also cause social and environmental impacts. So we need to look for ways to reduce our demand for minerals, while also improving current mining practices to minimize social and environmental impacts.”

      ESI recently hosted the inaugural MIT Conference on Mining, Environment, and Society to discuss how the clean energy transition may affect mining and the people and environments in mining areas. The conference convened representatives of mining companies, environmental and human rights groups, policymakers, and social and natural scientists to identify key concerns and possible collaborative solutions.

      “We can’t replace an abusive fossil fuel industry with an abusive mining industry that expands as we move through the energy transition,” said Jim Wormington, a senior researcher at Human Rights Watch, in a panel on the first day of the conference. “There’s a recognition from governments, civil society, and companies that this transition potentially has a really significant human rights and social cost, both in terms of emissions […] but also for communities and workers who are on the front lines of mining.”

      That focus on communities and workers was consistent throughout the three-day conference, as participants outlined the economic and social dimensions of standing up large numbers of new mines. Corporate mines can bring large influxes of government revenue and local investment, but the income is volatile and can leave policymakers and communities stranded when production declines or mineral prices fall. On the other hand, “artisanal” mining operations are an important source of critical minerals, but are hard to regulate and subject to abuses from brokers. And large reserves of minerals are found in conservation areas, regions with fragile ecosystems and experiencing water shortages that can be exacerbated by mining, in particular on Indigenous-controlled lands and other places where mine openings are deeply fraught.

      “One of the real triggers of conflict is a dissatisfaction with the current model of resource extraction,” said Jocelyn Fraser of the University of British Columbia in a panel discussion. “One that’s failed to support the long-term sustainable development of regions that host mining operations, and yet imposes significant local social and environmental impacts.”

      All these challenges point toward solutions in policy and in mining companies’ relationships with the communities where they work. Participants highlighted newer models of mining governance that can create better incentives for the ways mines operate — from full community ownership of mines to recognizing community rights to the benefits of mining to end-of-life planning for mines at the time they open.

      Many of the conference speakers also shared technological innovations that may help reduce mining challenges. Some operations are investing in desalination as alternative water sources in water-scarce regions; low-carbon alternatives are emerging to many of the fossil fuel-powered heavy machines that are mainstays of the industry; and work is being done to reclaim valuable minerals from mine tailings, helping to minimize both waste and the need to open new extraction sites.

      Increasingly, the mining industry itself is recognizing that reforms will allow it to thrive in a rapid clean-energy transition. “Decarbonization is really a profitability imperative,” said Kareemah Mohammed, managing director for sustainability services at the technology consultancy Accenture, on the conference’s second day. “It’s about securing a low-cost and steady supply of either minerals or metals, but it’s also doing so in an optimal way.”

      The three-day conference attracted over 350 attendees, from large mining companies, industry groups, consultancies, multilateral institutions, universities, nongovernmental organizations (NGOs), government, and more. It was held entirely virtually, a choice that helped make the conference not only truly international — participants joined from over 27 countries on six continents — but also accessible to members of nonprofits and professionals in the developing world.

      “Many people are concerned about the environmental and social challenges of supplying the clean energy revolution, and we’d heard repeatedly that there wasn’t a forum for government, industry, academia, NGOs, and communities to all sit at the same table and explore collaborative solutions,” says Christopher Noble, ESI’s director of corporate engagement. “Convening, and researching best practices, are roles that universities can play. The conversations at this conference have generated valuable ideas and consensus to pursue three parallel programs: best-in-class models for community engagement, improving ESG metrics and their use, and civil-society contributions to government/industry relations. We are developing these programs to keep the momentum going.”

      The MIT Conference on Mining, Environment, and Society was funded, in part, by Accenture, as part of the MIT/Accenture Convergence Initiative. Additional funding was provided by the Inter-American Development Bank. More

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      A simple way to significantly increase lifetimes of fuel cells and other devices

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      In research that could jump-start work on a range of technologies including fuel cells, which are key to storing solar and wind energy, MIT researchers have found a relatively simple way to increase the lifetimes of these devices: changing the pH of the system.

      Fuel and electrolysis cells made of materials known as solid metal oxides are of interest for several reasons. For example, in the electrolysis mode, they are very efficient at converting electricity from a renewable source into a storable fuel like hydrogen or methane that can be used in the fuel cell mode to generate electricity when the sun isn’t shining or the wind isn’t blowing. They can also be made without using costly metals like platinum. However, their commercial viability has been hampered, in part, because they degrade over time. Metal atoms seeping from the interconnects used to construct banks of fuel/electrolysis cells slowly poison the devices.

      “What we’ve been able to demonstrate is that we can not only reverse that degradation, but actually enhance the performance above the initial value by controlling the acidity of the air-electrode interface,” says Harry L. Tuller, the R.P. Simmons Professor of Ceramics and Electronic Materials in MIT’s Department of Materials Science and Engineering (DMSE).

      The research, initially funded by the U.S. Department of Energy through the Office of Fossil Energy and Carbon Management’s (FECM) National Energy Technology Laboratory, should help the department meet its goal of significantly cutting the degradation rate of solid oxide fuel cells by 2035 to 2050.

      “Extending the lifetime of solid oxide fuels cells helps deliver the low-cost, high-efficiency hydrogen production and power generation needed for a clean energy future,” says Robert Schrecengost, acting director of FECM’s Division of Hydrogen with Carbon Management. “The department applauds these advancements to mature and ultimately commercialize these technologies so that we can provide clean and reliable energy for the American people.”

      “I’ve been working in this area my whole professional life, and what I’ve seen until now is mostly incremental improvements,” says Tuller, who was recently named a 2022 Materials Research Society Fellow for his career-long work in solid-state chemistry and electrochemistry. “People are normally satisfied with seeing improvements by factors of tens-of-percent. So, actually seeing much larger improvements and, as importantly, identifying the source of the problem and the means to work around it, issues that we’ve been struggling with for all these decades, is remarkable.”

      Says James M. LeBeau, the John Chipman Associate Professor of Materials Science and Engineering at MIT, who was also involved in the research, “This work is important because it could overcome [some] of the limitations that have prevented the widespread use of solid oxide fuel cells. Additionally, the basic concept can be applied to many other materials used for applications in the energy-related field.”

      A report describing the work was reported Aug. 11, in Energy & Environmental Science. Additional authors of the paper are Han Gil Seo, a DMSE postdoc; Anna Staerz, formerly a DMSE postdoc, now at Interuniversity Microelectronics Centre (IMEC) Belgium and soon to join the Colorado School of Mines faculty; Dennis S. Kim, a DMSE postdoc; Dino Klotz, a DMSE visiting scientist, now at Zurich Instruments; Michael Xu, a DMSE graduate student; and Clement Nicollet, formerly a DMSE postdoc, now at the Université de Nantes. Seo and Staerz contributed equally to the work.

      Changing the acidity

      A fuel/electrolysis cell has three principal parts: two electrodes (a cathode and anode) separated by an electrolyte. In the electrolysis mode, electricity from, say, the wind, can be used to generate storable fuel like methane or hydrogen. On the other hand, in the reverse fuel cell reaction, that storable fuel can be used to create electricity when the wind isn’t blowing.

      A working fuel/electrolysis cell is composed of many individual cells that are stacked together and connected by steel metal interconnects that include the element chrome to keep the metal from oxidizing. But “it turns out that at the high temperatures that these cells run, some of that chrome evaporates and migrates to the interface between the cathode and the electrolyte, poisoning the oxygen incorporation reaction,” Tuller says. After a certain point, the efficiency of the cell has dropped to a point where it is not worth operating any longer.

      “So if you can extend the life of the fuel/electrolysis cell by slowing down this process, or ideally reversing it, you could go a long way towards making it practical,” Tuller says.

      The team showed that you can do both by controlling the acidity of the cathode surface. They also explained what is happening.

      To achieve their results, the team coated the fuel/electrolysis cell cathode with lithium oxide, a compound that changes the relative acidity of the surface from being acidic to being more basic. “After adding a small amount of lithium, we were able to recover the initial performance of a poisoned cell,” Tuller says. When the engineers added even more lithium, the performance improved far beyond the initial value. “We saw improvements of three to four orders of magnitude in the key oxygen reduction reaction rate and attribute the change to populating the surface of the electrode with electrons needed to drive the oxygen incorporation reaction.”

      The engineers went on to explain what is happening by observing the material at the nanoscale, or billionths of a meter, with state-of-the-art transmission electron microscopy and electron energy loss spectroscopy at MIT.nano. “We were interested in understanding the distribution of the different chemical additives [chromium and lithium oxide] on the surface,” says LeBeau.

      They found that the lithium oxide effectively dissolves the chromium to form a glassy material that no longer serves to degrade the cathode performance.

      Applications for sensors, catalysts, and more

      Many technologies like fuel cells are based on the ability of the oxide solids to rapidly breathe oxygen in and out of their crystalline structures, Tuller says. The MIT work essentially shows how to recover — and speed up — that ability by changing the surface acidity. As a result, the engineers are optimistic that the work could be applied to other technologies including, for example, sensors, catalysts, and oxygen permeation-based reactors.

      The team is also exploring the effect of acidity on systems poisoned by different elements, like silica.

      Concludes Tuller: “As is often the case in science, you stumble across something and notice an important trend that was not appreciated previously. Then you test that concept further, and you discover that it is really very fundamental.”

      In addition to the DOE, this work was also funded by the National Research Foundation of Korea, the MIT Department of Materials Science and Engineering via Tuller’s appointment as the R.P. Simmons Professor of Ceramics and Electronic Materials, and the U.S. Air Force Office of Scientific Research. More

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      Explained: Why perovskites could take solar cells to new heights

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      Perovskites hold promise for creating solar panels that could be easily deposited onto most surfaces, including flexible and textured ones. These materials would also be lightweight, cheap to produce, and as efficient as today’s leading photovoltaic materials, which are mainly silicon. They’re the subject of increasing research and investment, but companies looking to harness their potential do have to address some remaining hurdles before perovskite-based solar cells can be commercially competitive.

      The term perovskite refers not to a specific material, like silicon or cadmium telluride, other leading contenders in the photovoltaic realm, but to a whole family of compounds. The perovskite family of solar materials is named for its structural similarity to a mineral called perovskite, which was discovered in 1839 and named after Russian mineralogist L.A. Perovski.

      The original mineral perovskite, which is calcium titanium oxide (CaTiO3), has a distinctive crystal configuration. It has a three-part structure, whose components have come to be labeled A, B and X, in which lattices of the different components are interlaced. The family of perovskites consists of the many possible combinations of elements or molecules that can occupy each of the three components and form a structure similar to that of the original perovskite itself. (Some researchers even bend the rules a little by naming other crystal structures with similar elements “perovskites,” although this is frowned upon by crystallographers.)

      “You can mix and match atoms and molecules into the structure, with some limits. For instance, if you try to stuff a molecule that’s too big into the structure, you’ll distort it. Eventually you might cause the 3D crystal to separate into a 2D layered structure, or lose ordered structure entirely,” says Tonio Buonassisi, professor of mechanical engineering at MIT and director of the Photovoltaics Research Laboratory. “Perovskites are highly tunable, like a build-your-own-adventure type of crystal structure,” he says.

      That structure of interlaced lattices consists of ions or charged molecules, two of them (A and B) positively charged and the other one (X) negatively charged. The A and B ions are typically of quite different sizes, with the A being larger. 

      Within the overall category of perovskites, there are a number of types, including metal oxide perovskites, which have found applications in catalysis and in energy storage and conversion, such as in fuel cells and metal-air batteries. But a main focus of research activity for more than a decade has been on lead halide perovskites, according to Buonassisi says.

      Within that category, there is still a legion of possibilities, and labs around the world are racing through the tedious work of trying to find the variations that show the best performance in efficiency, cost, and durability — which has so far been the most challenging of the three.

      Many teams have also focused on variations that eliminate the use of lead, to avoid its environmental impact. Buonassisi notes, however, that “consistently over time, the lead-based devices continue to improve in their performance, and none of the other compositions got close in terms of electronic performance.” Work continues on exploring alternatives, but for now none can compete with the lead halide versions.

      One of the great advantages perovskites offer is their great tolerance of defects in the structure, he says. Unlike silicon, which requires extremely high purity to function well in electronic devices, perovskites can function well even with numerous imperfections and impurities.

      Searching for promising new candidate compositions for perovskites is a bit like looking for a needle in a haystack, but recently researchers have come up with a machine-learning system that can greatly streamline this process. This new approach could lead to a much faster development of new alternatives, says Buonassisi, who was a co-author of that research.

      While perovskites continue to show great promise, and several companies are already gearing up to begin some commercial production, durability remains the biggest obstacle they face. While silicon solar panels retain up to 90 percent of their power output after 25 years, perovskites degrade much faster. Great progress has been made — initial samples lasted only a few hours, then weeks or months, but newer formulations have usable lifetimes of up to a few years, suitable for some applications where longevity is not essential.

      From a research perspective, Buonassisi says, one advantage of perovskites is that they are relatively easy to make in the lab — the chemical constituents assemble readily. But that’s also their downside: “The material goes together very easily at room temperature,” he says, “but it also comes apart very easily at room temperature. Easy come, easy go!”

      To deal with that issue, most researchers are focused on using various kinds of protective materials to encapsulate the perovskite, protecting it from exposure to air and moisture. But others are studying the exact mechanisms that lead to that degradation, in hopes of finding formulations or treatments that are more inherently robust. A key finding is that a process called autocatalysis is largely to blame for the breakdown.

      In autocatalysis, as soon as one part of the material starts to degrade, its reaction products act as catalysts to start degrading the neighboring parts of the structure, and a runaway reaction gets underway. A similar problem existed in the early research on some other electronic materials, such as organic light-emitting diodes (OLEDs), and was eventually solved by adding additional purification steps to the raw materials, so a similar solution may be found in the case of perovskites, Buonassisi suggests.

      Buonassisi and his co-researchers recently completed a study showing that once perovskites reach a usable lifetime of at least a decade, thanks to their much lower initial cost that would be sufficient to make them economically viable as a substitute for silicon in large, utility-scale solar farms.

      Overall, progress in the development of perovskites has been impressive and encouraging, he says. With just a few years of work, it has already achieved efficiencies comparable to levels that cadmium telluride (CdTe), “which has been around for much longer, is still struggling to achieve,” he says. “The ease with which these higher performances are reached in this new material are almost stupefying.” Comparing the amount of research time spent to achieve a 1 percent improvement in efficiency, he says, the progress on perovskites has been somewhere between 100 and 1000 times faster than that on CdTe. “That’s one of the reasons it’s so exciting,” he says. More

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      in Environment

      Helping renewable energy projects succeed in local communities

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      Jungwoo Chun makes surprising discoveries about sustainability initiatives by zooming in on local communities.

      His discoveries lie in understanding how renewable energy infrastructure develops at a local level. With so many stakeholders in a community — citizens, government officials, businesses, and other organizations — the development process gets complicated very quickly. Chun works to unpack stakeholder relationships to help local renewable energy projects move forward.

      While his interests today are in local communities around the U.S., Chun comes from a global background. Growing up, his family moved frequently due to his dad’s work. He lived in Seoul, South Korea until elementary school and then hopped from city to city around Asia, spending time in China, Hong Kong, and Singapore. When it was time for college, he returned to South Korea, majoring in international studies at Korea University and later completing his master’s there in the same field.

      After graduating, Chun wanted to leverage his international expertise to tackle climate change. So, he pursued a second master’s in international environmental policy with William Moomaw at Tufts University.

      During that time, Chun came across an article on climate change by David Victor, a professor in public policy at the University of California at San Diego. Victor argued that while international efforts to fight climate change are necessary, more tangible progress can be made through local efforts catered to each country. That prompted Chun to think a step further: “What can we do in the local community to make a little bit of a difference, which could add up to something big in the long term?”

      With a renewed direction for his goals, Chun arrived at the MIT Department of Urban Studies and Planning, specializing in environmental policy and planning. But he was still missing that final inspirational spark to proactively pursue his goals — until he began working with his primary advisor, Lawrence Susskind, the Ford Professor of Urban and Environmental Planning and director of the Science Impact Collaborative.

      For previous research projects, “I would just do what I was told,” Chun says, but his new advisor “really opened [his] eyes” to being an active member of the community. From the start, Susskind has encouraged Chun to share his research ideas and has shown him how to leverage his research skills for public service. Over the past few years, Chun has also taught several classes with Susskind, learning to approach education thoughtfully for an engaging and equitable classroom. Because of their relationship, Chun now always searches for ways to make a difference through research, teaching, and public service.

      Understanding renewable energy projects at a local level

      For his main dissertation project with Susskind, Chun is studying community-owned solar energy projects, working to understand what makes them successful.

      Often, communities don’t have the required expertise to carry out these projects on their own and instead look to advisory organizations for help. But little research has been done on these organizations and the roles that they play in developing solar energy infrastructure.

      Through over 200 surveys and counting, Chun has discovered that these organizations act as life-long collaborators to communities and are critical in getting community-owned solar projects up and running. At the start of these projects, they walk communities through a mountain of logistics for setting up solar energy infrastructure, including permit applications, budgeting, and contractor employment. After the infrastructure is in place, the organizations stay involved, serving as consultants when needed and sometimes even becoming partners.

      Because of these roles, Chun calls these organizations “intermediaries,” drawing a parallel with roles in in conflict resolution. “But it’s much more than that,” he adds. Intermediaries help local communities “build a movement [for community-owned solar energy projects] … and empower them to be independent and self-sustaining.”

      Chun is also working on another project with Susskind, looking at situations where communities are opposed to renewable energy infrastructure. For this project, Chun is supervising and mentoring a group of five undergraduates. Together, they are trying to pinpoint the reasons behind local opposition to renewable energy projects.

      The idea for this project emerged two years ago, when Chun heard in the news that many solar and wind projects were being delayed or cancelled due to local opposition. But the reasons for this opposition weren’t thoroughly researched.

      “When we started to dig a little deeper, [we found that] communities oppose these projects even though they aren’t opposed to renewable energy,” Chun says. The primary reasons for opposition lie in land use concerns, including financial challenges, health and safety concerns, and ironically, environmental consequences. By better understanding these concerns, Chun hopes to help more renewable energy projects succeed and bring society closer to a sustainable future.

      Bringing research to the classroom and community

      Right now, Chun is looking to bring his research insights on renewable energy infrastructure into the classroom. He’s developing a course on renewable energy that will act as a “clinic” where students will work with communities to understand their concerns for potential renewable energy projects. The students’ findings will then be passed onto project leaders to help them address these concerns.

      This new course is modeled after 11.074/11.274 (Cybersecurity Clinic), which Chun has helped develop over the past few years. In this clinic, students work with local governments in New England to assess potential cybersecurity vulnerabilities in their digital systems. At first, “a lot of city governments were very skeptical, like ‘students doing service for us…?’” Chun says. “But in the end, they were all very satisfied with the outcome” and found the assessments “impactful.”

      Since the Cybersecurity Clinic has kicked off, other universities have approached Chun and his co-instructors about developing their own regional clinics. Now, there are cybersecurity clinics operating around the world. “That’s been a huge success,” Chun says. Going forward, “we’d like to expand the benefit of this clinic [to address] communities opposing renewable energy [projects].” The new course will be a philosophical trifecta for Chun, combining his commitments to research, teaching, and public service.

      Chun plans to wrap up his PhD at the end of this summer and is currently writing his dissertation on community-owned solar energy projects. “I’m done with all the background work — working the soil and throwing the seeds in the right place,” he says, “It’s now time to gather all the crops and present the work.” More

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      in Energy

      Expanding energy access in rural Lesotho

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      Matt Orosz’s mission for the last 20 years can be explained with a single picture: a satellite image of the world at night, with major cities blazing with light and large swaths of land shrouded in darkness.

      The image reminds Orosz SM ’03, SM ’06, PhD ’12 of what he’s trying to change. Orosz is the CEO of OnePower, an MIT spinout building networks of minigrids powered by solar energy to bring electricity to rural regions of Lesotho.

      There are other companies building minigrids in Africa, but OnePower is the only one to have accomplished the feat in Lesotho, and it’s not hard to understand why. Known as the kingdom in the sky, Lesotho is a small, developing country crossed by mountain ranges and rivers, making it difficult to get electricity to rural regions. Recent estimates suggest that less than half of all households have electricity.

      OnePower’s first minigrid is a small system that has been serving around 200 customers for more than a year. The operation is part of an eight-minigrid project that will provide reliable electricity for the first time to more than 30,000 people, 13 health clinics, 25 schools, and over 100 small businesses.

      Construction on those sites is underway, and Orosz is currently working on a power transmission and road crossing over the Senqu river, the largest in southern Africa. During the project, the operators of a health clinic on the off-grid side of the river let Orosz stay there on the condition that he fix their diesel generator. He got the generator working again, but if everything goes according to plan, the clinic won’t need it for much longer.

      “If you don’t have power, then you don’t have lights, you don’t have computers, you don’t have communications,” Orosz says. “That means hospitals can’t refer patients or get expert opinions or run equipment, and schools can’t get internet. When the fundamental institutions for health and education don’t have power, their effectiveness is pretty limited, which affects quality of life for everybody that lives in the area.”

      Finding a spark

      The health clinic Orosz is staying in isn’t far from where he first learned about energy access problems in rural Africa. Between 2000 and 2002, Orosz lived in Lesotho, without electricity, as a member of the Peace Corps. The experience inspired him to help, but without an engineering background, he knew he’d need to gain more skills first.

      “I applied to MIT so that I could gain some knowledge and experience and apply it in this setting,” Orosz says, noting he spent a lot longer at MIT than he initially intended.

      Orosz first joined the research lab of Harry Hemond, the William E Leonhard Professor of Civil and Environmental Engineering, learning about topics like physics and fluid mechanics as part of his first year at MIT. After that, he enrolled in another master’s program in technology and policy. In 2007, he began a PhD at MIT studying solar thermal and photovoltaic hybrid power generation.

      The education wasn’t the only reason Orosz stayed at MIT. Throughout his time on campus, he also took advantage of funding opportunities presented by the IDEAS Social Innovation Challenge and the MIT $100K Entrepreneurship Competition (the $50K at the time). Orosz was also awarded a Fulbright scholarship while at MIT, and was selected for grants from the World Bank and the Environmental Protection Agency.

      Orosz also aligned himself closely with MIT D-Lab. During his second master’s, he led trips to Lesotho with other D-Lab students. Between his master’s and his PhD, Orosz spent a year living in Lesotho exploring energy solutions with three other MIT students, including Amy Mueller ’02, SM ’03, PhD ’12, who is currently chief financial officer of OnePower.

      In 2015, Orosz moved to Lesotho to work on OnePower full-time. The move coincided with OnePower’s successful bid to develop the first utility-scale solar project in Lesotho, a 20-megawatt project that will sell electricity to Lesotho’s central grid in addition to OnePower’s minigrid work. OnePower expects that project, named Neo 1, to start delivering power to Lesotho’s central electric grid next year.

      “It takes quite a lot of time and money to develop utility scale solar projects, but we’ve been told by investors and partners that seven years is not unusual,” Orosz says. “It kind of reminds me of the time it took to get a PhD — surprisingly long, but corroborated by others’ experiences.”

      In conjunction with the grid-scale project, OnePower also piloted the first privately financed, fully licensed minigrid in Lesotho. The company has also set up minigrids to help power six health care centers in the mountains of Lesotho.

      OnePower’s grid-scale project and its minigrids use industry standard, large-format bifacial solar panels, mounted on single axis tracking substructures designed and built in Lesotho by OnePower, but the minigrids send energy to a powerhouse filled with lithium-ion batteries. From there, transmission lines bring the electricity to different villages, where it powers homes, businesses, schools, health clinics, police stations, churches, and more. A smart meter at each customer’s building tracks electricity usage, and customers use a phone app to pay for their electricity.

      OnePower secured funding for the projects from a network of private investors rather than through grants and donations. By paying the investors back, Orosz says OnePower will be showing that funding such projects can be a profitable investment in addition to an impactful one.

      That’s important because grants and donations will only take minigrid operators so far. Orosz says in order to provide reliable electricity to the entire continent of Africa, a huge amount of private investment is needed.

      “The goal is ultimately to prove that you can make this work: that you can generate electricity and sell it to a customer in Africa, and that revenue enables you to pay back the financier that helped you build the infrastructure in the first place,” Orosz says. “Once you close that loop, then it can scale. That’s the holy grail of minigrids.”

      Orosz believes OnePower is differentiated from other minigrid companies in that it develops and owns more of the value chain, like the tracking substructures that allow solar panels to adjust with the sun, which has helped the company continue operations during the pandemic. The technical innovations his team developed at MIT ultimately help OnePower offer lower electricity prices to people in Lesotho.

      Turning the lights on

      OnePower has doubled its employees over the last year as construction on the eight minigrids ramps up. As his team stays busy rolling those projects out, Orosz is already exploring options for the next cluster of minigrids OnePower will build.

      “If we can solve the economics and logistics in Lesotho, then it should be a lot easier to replicate this in other markets,” Orosz says.

      The goal is to bring OnePower’s minigrids to the rural communities that would benefit from them the most. As the satellite image of earth at night shows, that includes many unelectrified community across sub-Saharan Africa.

      “We think Africans in rural areas should have the same quality of power as Africans in urban areas, and that should be the same quality power as everywhere else in the world,” Orosz says. More