Supply chains

Subterms

    Latest story

    50 Shares99 Views

    Seizing solar’s bright future

    by

    Consider the dizzying ascent of solar energy in the United States: In the past decade, solar capacity increased nearly 900 percent, with electricity production eight times greater in 2023 than in 2014. The jump from 2022 to 2023 alone was 51 percent, with a record 32 gigawatts (GW) of solar installations coming online. In the past four years, more solar has been added to the grid than any other form of generation. Installed solar now tops 179 GW, enough to power nearly 33 million homes. The U.S. Department of Energy (DOE) is so bullish on the sun that its decarbonization plans envision solar satisfying 45 percent of the nation’s electricity demands by 2050.But the continued rapid expansion of solar requires advances in technology, notably to improve the efficiency and durability of solar photovoltaic (PV) materials and manufacturing. That’s where Optigon, a three-year-old MIT spinout company, comes in.“Our goal is to build tools for research and industry that can accelerate the energy transition,” says Dane deQuilettes, the company’s co-founder and chief science officer. “The technology we have developed for solar will enable measurements and analysis of materials as they are being made both in lab and on the manufacturing line, dramatically speeding up the optimization of PV.”With roots in MIT’s vibrant solar research community, Optigon is poised for a 2024 rollout of technology it believes will drastically pick up the pace of solar power and other clean energy projects.Beyond siliconSilicon, the material mainstay of most PV, is limited by the laws of physics in the efficiencies it can achieve converting photons from the sun into electrical energy. Silicon-based solar cells can theoretically reach power conversion levels of just 30 percent, and real-world efficiency levels hover in the low 20s. But beyond the physical limitations of silicon, there is another issue at play for many researchers and the solar industry in the United States and elsewhere: China dominates the silicon PV market, from supply chains to manufacturing.Scientists are eagerly pursuing alternative materials, either for enhancing silicon’s solar conversion capacity or for replacing silicon altogether.In the past decade, a family of crystal-structured semiconductors known as perovskites has risen to the fore as a next-generation PV material candidate. Perovskite devices lend themselves to a novel manufacturing process using printing technology that could circumvent the supply chain juggernaut China has built for silicon. Perovskite solar cells can be stacked on each other or layered atop silicon PV, to achieve higher conversion efficiencies. Because perovskite technology is flexible and lightweight, modules can be used on roofs and other structures that cannot support heavier silicon PV, lowering costs and enabling a wider range of building-integrated solar devices.But these new materials require testing, both during R&D and then on assembly lines, where missing or defective optical, electrical, or dimensional properties in the nano-sized crystal structures can negatively impact the end product.“The actual measurement and data analysis processes have been really, really slow, because you have to use a bunch of separate tools that are all very manual,” says Optigon co-founder and chief executive officer Anthony Troupe ’21. “We wanted to come up with tools for automating detection of a material’s properties, for determining whether it could make a good or bad solar cell, and then for optimizing it.”“Our approach packed several non-contact, optical measurements using different types of light sources and detectors into a single system, which together provide a holistic, cross-sectional view of the material,” says Brandon Motes ’21, ME ’22, co-founder and chief technical officer.“This breakthrough in achieving millisecond timescales for data collection and analysis means we can take research-quality tools and actually put them on a full production system, getting extremely detailed information about products being built at massive, gigawatt scale in real-time,” says Troupe.This streamlined system takes measurements “in the snap of the fingers, unlike the traditional tools,” says Joseph Berry, director of the US Manufacturing of Advanced Perovskites Consortium and a senior research scientist at the National Renewable Energy Laboratory. “Optigon’s techniques are high precision and allow high throughput, which means they can be used in a lot of contexts where you want rapid feedback and the ability to develop materials very, very quickly.”According to Berry, Optigon’s technology may give the solar industry not just better materials, but the ability to pump out high-quality PV products at a brisker clip than is currently possible. “If Optigon is successful in deploying their technology, then we can more rapidly develop the materials that we need, manufacturing with the requisite precision again and again,” he says. “This could lead to the next generation of PV modules at a much, much lower cost.”Measuring makes the differenceWith Small Business Innovation Research funding from DOE to commercialize its products and a grant from the Massachusetts Clean Energy Center, Optigon has settled into a space at the climate technology incubator Greentown Labs in Somerville, Massachusetts. Here, the team is preparing for this spring’s launch of its first commercial product, whose genesis lies in MIT’s GridEdge Solar Research Program.Led by Vladimir Bulović, a professor of electrical engineering and the director of MIT.nano, the GridEdge program was established with funding from the Tata Trusts to develop lightweight, flexible, and inexpensive solar cells for distribution to rural communities around the globe. When deQuilettes joined the group in 2017 as a postdoc, he was tasked with directing the program and building the infrastructure to study and make perovskite solar modules.“We were trying to understand once we made the material whether or not it was good,” he recalls. “There were no good commercial metrology [the science of measurements] tools for materials beyond silicon, so we started to build our own.” Recognizing the group’s need for greater expertise on the problem, especially in the areas of electrical, software, and mechanical engineering, deQuilettes put a call out for undergraduate researchers to help build metrology tools for new solar materials.“Forty people inquired, but when I met Brandon and Anthony, something clicked; it was clear we had a complementary skill set,” says deQuilettes. “We started working together, with Anthony coming up with beautiful designs to integrate multiple measurements, and Brandon creating boards to control all of the hardware, including different types of lasers. We started filing multiple patents and that was when we saw it all coming together.”“We knew from the start that metrology could vastly improve not just materials, but production yields,” says Troupe. Adds deQuilettes, “Our goal was getting to the highest performance orders of magnitude faster than it would ordinarily take, so we developed tools that would not just be useful for research labs but for manufacturing lines to give live feedback on quality.”The device Optigon designed for industry is the size of a football, “with sensor packages crammed into a tiny form factor, taking measurements as material flows directly underneath,” says Motes. “We have also thought carefully about ways to make interaction with this tool as seamless and, dare I say, as enjoyable as possible, streaming data to both a dashboard an operator can watch and to a custom database.”Photovoltaics is just the startThe company may have already found its market niche. “A research group paid us to use our in-house prototype because they have such a burning need to get these sorts of measurements,” says Troupe, and according to Motes, “Potential customers ask us if they can buy the system now.” deQuilettes says, “Our hope is that we become the de facto company for doing any sort of characterization metrology in the United States and beyond.”Challenges lie ahead for Optigon: product launches, full-scale manufacturing, technical assistance, and sales. Greentown Labs offers support, as does MIT’s own rich community of solar researchers and entrepreneurs. But the founders are already thinking about next phases.“We are not limiting ourselves to the photovoltaics area,” says deQuilettes. “We’re planning on working in other clean energy materials such as batteries and fuel cells.”That’s because the team wants to make the maximum impact on the climate challenge. “We’ve thought a lot about the potential our tools will have on reducing carbon emissions, and we’ve done a really in-depth analysis looking at how our system can increase production yields of solar panels and other energy technologies, reducing materials and energy wasted in conventional optimization,” deQuilettes says. “If we look across all these sectors, we can expect to offset about 1,000 million metric tons of CO2 [carbon dioxide] per year in the not-too-distant future.”The team has written scale into its business plan. “We want to be the key enabler for bringing these new energy technologies to market,” says Motes. “We envision being deployed on every manufacturing line making these types of materials. It’s our goal to walk around and know that if we see a solar panel deployed, there’s a pretty high likelihood that it will be one we measured at some point.” More

    More stories

    • 88 Shares179 Views

      in Environment

      HPI-MIT design research collaboration creates powerful teams

      by

      The recent ransomware attack on ChangeHealthcare, which severed the network connecting health care providers, pharmacies, and hospitals with health insurance companies, demonstrates just how disruptive supply chain attacks can be. In this case, it hindered the ability of those providing medical services to submit insurance claims and receive payments.This sort of attack and other forms of data theft are becoming increasingly common and often target large, multinational corporations through the small and mid-sized vendors in their corporate supply chains, enabling breaks in these enormous systems of interwoven companies.Cybersecurity researchers at MIT and the Hasso Plattner Institute (HPI) in Potsdam, Germany, are focused on the different organizational security cultures that exist within large corporations and their vendors because it’s that difference that creates vulnerabilities, often due to the lack of emphasis on cybersecurity by the senior leadership in these small to medium-sized enterprises (SMEs).Keri Pearlson, executive director of Cybersecurity at MIT Sloan (CAMS); Jillian Kwong, a research scientist at CAMS; and Christian Doerr, a professor of cybersecurity and enterprise security at HPI, are co-principal investigators (PIs) on the research project, “Culture and the Supply Chain: Transmitting Shared Values, Attitudes and Beliefs across Cybersecurity Supply Chains.”Their project was selected in the 2023 inaugural round of grants from the HPI-MIT Designing for Sustainability program, a multiyear partnership funded by HPI and administered by the MIT Morningside Academy for Design (MAD). The program awards about 10 grants annually of up to $200,000 each to multidisciplinary teams with divergent backgrounds in computer science, artificial intelligence, machine learning, engineering, design, architecture, the natural sciences, humanities, and business and management. The 2024 Call for Applications is open through June 3.Designing for Sustainability grants support scientific research that promotes the United Nations’ Sustainable Development Goals (SDGs) on topics involving sustainable design, innovation, and digital technologies, with teams made up of PIs from both institutions. The PIs on these projects, who have common interests but different strengths, create more powerful teams by working together.Transmitting shared values, attitudes, and beliefs to improve cybersecurity across supply chainsThe MIT and HPI cybersecurity researchers say that most ransomware attacks aren’t reported. Smaller companies hit with ransomware attacks just shut down, because they can’t afford the payment to retrieve their data. This makes it difficult to know just how many attacks and data breaches occur. “As more data and processes move online and into the cloud, it becomes even more important to focus on securing supply chains,” Kwong says. “Investing in cybersecurity allows information to be exchanged freely while keeping data safe. Without it, any progress towards sustainability is stalled.”One of the first large data breaches in the United States to be widely publicized provides a clear example of how an SME cybersecurity can leave a multinational corporation vulnerable to attack. In 2013, hackers entered the Target Corporation’s own network by obtaining the credentials of a small vendor in its supply chain: a Pennsylvania HVAC company. Through that breach, thieves were able to install malware that stole the financial and personal information of 110 million Target customers, which they sold to card shops on the black market.To prevent such attacks, SME vendors in a large corporation’s supply chain are required to agree to follow certain security measures, but the SMEs usually don’t have the expertise or training to make good on these cybersecurity promises, leaving their own systems, and therefore any connected to them, vulnerable to attack.“Right now, organizations are connected economically, but not aligned in terms of organizational culture, values, beliefs, and practices around cybersecurity,” explains Kwong. “Basically, the big companies are realizing the smaller ones are not able to implement all the cybersecurity requirements. We have seen some larger companies address this by reducing requirements or making the process shorter. However, this doesn’t mean companies are more secure; it just lowers the bar for the smaller suppliers to clear it.”Pearlson emphasizes the importance of board members and senior management taking responsibility for cybersecurity in order to change the culture at SMEs, rather than pushing that down to a single department, IT office, or in some cases, one IT employee.The research team is using case studies based on interviews, field studies, focus groups, and direct observation of people in their natural work environments to learn how companies engage with vendors, and the specific ways cybersecurity is implemented, or not, in everyday operations. The goal is to create a shared culture around cybersecurity that can be adopted correctly by all vendors in a supply chain.This approach is in line with the goals of the Charter of Trust Initiative, a partnership of large, multinational corporations formed to establish a better means of implementing cybersecurity in the supply chain network. The HPI-MIT team worked with companies from the Charter of Trust and others last year to understand the impacts of cybersecurity regulation on SME participation in supply chains and develop a conceptual framework to implement changes for stabilizing supply chains.Cybersecurity is a prerequisite needed to achieve any of the United Nations’ SDGs, explains Kwong. Without secure supply chains, access to key resources and institutions can be abruptly cut off. This could include food, clean water and sanitation, renewable energy, financial systems, health care, education, and resilient infrastructure. Securing supply chains helps enable progress on all SDGs, and the HPI-MIT project specifically supports SMEs, which are a pillar of the U.S. and European economies.Personalizing product designs while minimizing material wasteIn a vastly different Designing for Sustainability joint research project that employs AI with engineering, “Personalizing Product Designs While Minimizing Material Waste” will use AI design software to lay out multiple parts of a pattern on a sheet of plywood, acrylic, or other material, so that they can be laser cut to create new products in real time without wasting material.Stefanie Mueller, the TIBCO Career Development Associate Professor in the MIT Department of Electrical Engineering and Computer Science and a member of the Computer Science and Artificial Intelligence Laboratory, and Patrick Baudisch, a professor of computer science and chair of the Human Computer Interaction Lab at HPI, are co-PIs on the project. The two have worked together for years; Baudisch was Mueller’s PhD research advisor at HPI.Baudisch’s lab developed an online design teaching system called Kyub that lets students design 3D objects in pieces that are laser cut from sheets of wood and assembled to become chairs, speaker boxes, radio-controlled aircraft, or even functional musical instruments. For instance, each leg of a chair would consist of four identical vertical pieces attached at the edges to create a hollow-centered column, four of which will provide stability to the chair, even though the material is very lightweight.“By designing and constructing such furniture, students learn not only design, but also structural engineering,” Baudisch says. “Similarly, by designing and constructing musical instruments, they learn about structural engineering, as well as resonance, types of musical tuning, etc.”Mueller was at HPI when Baudisch developed the Kyub software, allowing her to observe “how they were developing and making all the design decisions,” she says. “They built a really neat piece for people to quickly design these types of 3D objects.” However, using Kyub for material-efficient design is not fast; in order to fabricate a model, the software has to break the 3D models down into 2D parts and lay these out on sheets of material. This takes time, and makes it difficult to see the impact of design decisions on material use in real-time.Mueller’s lab at MIT developed software based on a layout algorithm that uses AI to lay out pieces on sheets of material in real time. This allows AI to explore multiple potential layouts while the user is still editing, and thus provide ongoing feedback. “As the user develops their design, Fabricaide decides good placements of parts onto the user’s available materials, provides warnings if the user does not have enough material for a design, and makes suggestions for how the user can resolve insufficient material cases,” according to the project website.The joint MIT-HPI project integrates Mueller’s AI software with Baudisch’s Kyub software and adds machine learning to train the AI to offer better design suggestions that save material while adhering to the user’s design intent.“The project is all about minimizing the waste on these materials sheets,” Mueller says. She already envisions the next step in this AI design process: determining how to integrate the laws of physics into the AI’s knowledge base to ensure the structural integrity and stability of objects it designs.AI-powered startup design for the Anthropocene: Providing guidance for novel enterprisesThrough her work with the teams of MITdesignX and its international programs, Svafa Grönfeldt, faculty director of MITdesignX and professor of the practice in MIT MAD, has helped scores of people in startup companies use the tools and methods of design to ensure that the solution a startup proposes actually fits the problem it seeks to solve. This is often called the problem-solution fit.Grönfeldt and MIT postdoc Norhan Bayomi are now extending this work to incorporate AI into the process, in collaboration with MIT Professor John Fernández and graduate student Tyler Kim. The HPI team includes Professor Gerard de Melo; HPI School of Entrepreneurship Director Frank Pawlitschek; and doctoral student Michael Mansfeld.“The startup ecosystem is characterized by uncertainty and volatility compounded by growing uncertainties in climate and planetary systems,” Grönfeldt says. “Therefore, there is an urgent need for a robust model that can objectively predict startup success and guide design for the Anthropocene.”While startup-success forecasting is gaining popularity, it currently focuses on aiding venture capitalists in selecting companies to fund, rather than guiding the startups in the design of their products, services and business plans.“The coupling of climate and environmental priorities with startup agendas requires deeper analytics for effective enterprise design,” Grönfeldt says. The project aims to explore whether AI-augmented decision-support systems can enhance startup-success forecasting.“We’re trying to develop a machine learning approach that will give a forecasting of probability of success based on a number of parameters, including the type of business model proposed, how the team came together, the team members’ backgrounds and skill sets, the market and industry sector they’re working in and the problem-solution fit,” says Bayomi, who works with Fernández in the MIT Environmental Solutions Initiative. The two are co-founders of the startup Lamarr.AI, which employs robotics and AI to help reduce the carbon dioxide impact of the built environment.The team is studying “how company founders make decisions across four key areas, starting from the opportunity recognition, how they are selecting the team members, how they are selecting the business model, identifying the most automatic strategy, all the way through the product market fit to gain an understanding of the key governing parameters in each of these areas,” explains Bayomi.The team is “also developing a large language model that will guide the selection of the business model by using large datasets from different companies in Germany and the U.S. We train the model based on the specific industry sector, such as a technology solution or a data solution, to find what would be the most suitable business model that would increase the success probability of a company,” she says.The project falls under several of the United Nations’ Sustainable Development Goals, including economic growth, innovation and infrastructure, sustainable cities and communities, and climate action.Furthering the goals of the HPI-MIT Joint Research ProgramThese three diverse projects all advance the mission of the HPI-MIT collaboration. MIT MAD aims to use design to transform learning, catalyze innovation, and empower society by inspiring people from all disciplines to interweave design into problem-solving. HPI uses digital engineering concentrated on the development and research of user-oriented innovations for all areas of life.Interdisciplinary teams with members from both institutions are encouraged to develop and submit proposals for ambitious, sustainable projects that use design strategically to generate measurable, impactful solutions to the world’s problems. More

    • 50 Shares169 Views

      in Environment

      Advancing technology for aquaculture

      by

      According to the National Oceanic and Atmospheric Administration, aquaculture in the United States represents a $1.5 billion industry annually. Like land-based farming, shellfish aquaculture requires healthy seed production in order to maintain a sustainable industry. Aquaculture hatchery production of shellfish larvae — seeds — requires close monitoring to track mortality rates and assess health from the earliest stages of life. 

      Careful observation is necessary to inform production scheduling, determine effects of naturally occurring harmful bacteria, and ensure sustainable seed production. This is an essential step for shellfish hatcheries but is currently a time-consuming manual process prone to human error. 

      With funding from MIT’s Abdul Latif Jameel Water and Food Systems Lab (J-WAFS), MIT Sea Grant is working with Associate Professor Otto Cordero of the MIT Department of Civil and Environmental Engineering, Professor Taskin Padir and Research Scientist Mark Zolotas at the Northeastern University Institute for Experiential Robotics, and others at the Aquaculture Research Corporation (ARC), and the Cape Cod Commercial Fishermen’s Alliance, to advance technology for the aquaculture industry. Located on Cape Cod, ARC is a leading shellfish hatchery, farm, and wholesaler that plays a vital role in providing high-quality shellfish seed to local and regional growers.

      Two MIT students have joined the effort this semester, working with Robert Vincent, MIT Sea Grant’s assistant director of advisory services, through the Undergraduate Research Opportunities Program (UROP). 

      First-year student Unyime Usua and sophomore Santiago Borrego are using microscopy images of shellfish seed from ARC to train machine learning algorithms that will help automate the identification and counting process. The resulting user-friendly image recognition tool aims to aid aquaculturists in differentiating and counting healthy, unhealthy, and dead shellfish larvae, improving accuracy and reducing time and effort.

      Vincent explains that AI is a powerful tool for environmental science that enables researchers, industry, and resource managers to address challenges that have long been pinch points for accurate data collection, analysis, predictions, and streamlining processes. “Funding support from programs like J-WAFS enable us to tackle these problems head-on,” he says. 

      ARC faces challenges with manually quantifying larvae classes, an important step in their seed production process. “When larvae are in their growing stages they are constantly being sized and counted,” explains Cheryl James, ARC larval/juvenile production manager. “This process is critical to encourage optimal growth and strengthen the population.” 

      Developing an automated identification and counting system will help to improve this step in the production process with time and cost benefits. “This is not an easy task,” says Vincent, “but with the guidance of Dr. Zolotas at the Northeastern University Institute for Experiential Robotics and the work of the UROP students, we have made solid progress.” 

      The UROP program benefits both researchers and students. Involving MIT UROP students in developing these types of systems provides insights into AI applications that they might not have considered, providing opportunities to explore, learn, and apply themselves while contributing to solving real challenges.

      Borrego saw this project as an opportunity to apply what he’d learned in class 6.390 (Introduction to Machine Learning) to a real-world issue. “I was starting to form an idea of how computers can see images and extract information from them,” he says. “I wanted to keep exploring that.”

      Usua decided to pursue the project because of the direct industry impacts it could have. “I’m pretty interested in seeing how we can utilize machine learning to make people’s lives easier. We are using AI to help biologists make this counting and identification process easier.” While Usua wasn’t familiar with aquaculture before starting this project, she explains, “Just hearing about the hatcheries that Dr. Vincent was telling us about, it was unfortunate that not a lot of people know what’s going on and the problems that they’re facing.”

      On Cape Cod alone, aquaculture is an $18 million per year industry. But the Massachusetts Division of Marine Fisheries estimates that hatcheries are only able to meet 70–80 percent of seed demand annually, which impacts local growers and economies. Through this project, the partners aim to develop technology that will increase seed production, advance industry capabilities, and help understand and improve the hatchery microbiome.

      Borrego explains the initial challenge of having limited data to work with. “Starting out, we had to go through and label all of the data, but going through that process helped me learn a lot.” In true MIT fashion, he shares his takeaway from the project: “Try to get the best out of what you’re given with the data you have to work with. You’re going to have to adapt and change your strategies depending on what you have.”

      Usua describes her experience going through the research process, communicating in a team, and deciding what approaches to take. “Research is a difficult and long process, but there is a lot to gain from it because it teaches you to look for things on your own and find your own solutions to problems.”

      In addition to increasing seed production and reducing the human labor required in the hatchery process, the collaborators expect this project to contribute to cost savings and technology integration to support one of the most underserved industries in the United States. 

      Borrego and Usua both plan to continue their work for a second semester with MIT Sea Grant. Borrego is interested in learning more about how technology can be used to protect the environment and wildlife. Usua says she hopes to explore more projects related to aquaculture. “It seems like there’s an infinite amount of ways to tackle these issues.” More

    • 100 Shares129 Views

      in Environment

      Harnessing hydrogen’s potential to address long-haul trucking emissions

      by

      The transportation of goods forms the basis of today’s globally distributed supply chains, and long-haul trucking is a central and critical link in this complex system. To meet climate goals around the world, it is necessary to develop decarbonized solutions to replace diesel powertrains, but given trucking’s indispensable and vast role, these solutions must be both economically viable and practical to implement. While hydrogen-based options, as an alternative to diesel, have the potential to become a promising decarbonization strategy, hydrogen has significant limitations when it comes to delivery and refueling.These roadblocks, combined with hydrogen’s compelling decarbonization potential, are what motivated a team of MIT researchers led by William H. Green, the Hoyt Hottel Professor in Chemical Engineering, to explore a cost-effective way to transport and store hydrogen using liquid organic hydrogen carriers (LOHCs). The team is developing a disruptive technology that allows LOHCs to not only deliver the hydrogen to the trucks, but also store the hydrogen onboard.Their findings were recently published in Energy and Fuels, a peer-reviewed journal of the American Chemical Society, in a paper titled “Perspective on Decarbonizing Long-Haul Trucks Using Onboard Dehydrogenation of Liquid Organic Hydrogen Carriers.” The MIT team is led by Green, and includes graduate students Sayandeep Biswas and Kariana Moreno Sader. Their research is supported by the MIT Climate and Sustainability Consortium (MCSC) through its Seed Awards program and MathWorks, and ties into the work within the MCSC’s Tough Transportation Modes focus area.An “onboard” approachCurrently, LOHCs, which work within existing retail fuel distribution infrastructure, are used to deliver hydrogen gas to refueling stations, where it is then compressed and delivered onto trucks equipped with hydrogen fuel cell or combustion engines.“This current approach incurs significant energy loss due to endothermic hydrogen release and compression at the retail station” says Green. “To address this, our work is exploring a more efficient application, with LOHC-powered trucks featuring onboard dehydrogenation.”To implement such a design, the team aims to modify the truck’s powertrain (the system inside a vehicle that produces the energy to propel it forward) to allow onboard hydrogen release from the LOHCs, using waste heat from the engine exhaust to power the “dehydrogenation” process. 

      Proposed process flow diagram for onboard dehydrogenation. Component sizes are not to scale and have been enlarged for illustrative purposes.

      Image courtesy of the Green Group.

      Previous item
      Next item

      The dehydrogenation process happens within a high-temperature reactor, which continually receives hydrogen-rich LOHCs from the fuel storage tank. Hydrogen released from the reactor is fed to the engine, after passing through a separator to remove any lingering LOHC. On its way to the engine, some of the hydrogen gets diverted to a burner to heat the reactor, which helps to augment the reactor heating provided by the engine exhaust gases.Acknowledging and addressing hydrogen’s drawbacksThe team’s paper underscores that current uses of hydrogen, including LOHC systems, to decarbonize the trucking sector have drawbacks. Regardless of technical improvements, these existing options remain prohibitively expensive due to the high cost of retail hydrogen delivery.“We present an alternative option that addresses a lot of the challenges and seems to be a viable way in which hydrogen can be used in this transportation context,” says Biswas, who was recently elected to the MIT Martin Family Society of Fellows for Sustainability for his work in this area. “Hydrogen, when used through LOHCs, has clear benefits for long-hauling, such as scalability and fast refueling time. There is also an enormous potential to improve delivery and refueling to further reduce cost, and our system is working to do that.”“Utilizing hydrogen is an option that is globally accessible, and could be extended to countries like the one where I am from,” says Moreno Sader, who is originally from Colombia. “Since it synergizes with existing infrastructure, large upfront investments are not necessary. The global applicability is huge.”Moreno Sader is a MathWorks Fellow, and, along with the rest of the team, has been using MATLAB tools to develop models and simulations for this work.Different sectors coming togetherDecarbonizing transportation modes, including long-haul trucking, requires expertise and perspectives from different industries — an approach that resonates with the MCSC’s mission.The team’s groundbreaking research into LOHC-powered trucking is among several projects supported by the MCSC within its Tough Transportation Modes focus area, led by postdoc Impact Fellow Danika MacDonell. The MCSC-supported projects were chosen to tackle a complementary set of societally important and industry-relevant challenges to decarbonizing heavy-duty transportation, which span a range of sectors and solution pathways. Other projects focus, for example, on logistics optimization for electrified trucking fleets, or air quality and climate impacts of ammonia-powered shipping.The MCSC works to support and amplify the impact of these projects by engaging the research teams with industry partners from a variety of sectors. In addition, the MCSC pursues a collective multisectoral approach to decarbonizing transportation by facilitating shared learning across the different projects through regular cross-team discussion.The research led by Green celebrates this cross-sector theme by integrating industry-leading computing tools provided by MathWorks with cutting-edge developments in chemical engineering, as well as industry-leading commercial LOHC reactor demonstrations, to build a compelling vision for cost-effective LOHC-powered trucking.The review and research conducted in the Energy and Fuels article lays the groundwork for further investigations into LOHC-powered truck design. The development of such a vehicle — with a power-dense, efficient, and robust onboard hydrogen release system — requires dedicated investigations and further optimization of core components geared specifically toward the trucking application. More

    • 125 Shares169 Views

      in Security

      System tracks movement of food through global humanitarian supply chain

      by

      Although more than enough food is produced to feed everyone in the world, as many as 828 million people face hunger today. Poverty, social inequity, climate change, natural disasters, and political conflicts all contribute to inhibiting access to food. For decades, the U.S. Agency for International Development (USAID) Bureau for Humanitarian Assistance (BHA) has been a leader in global food assistance, supplying millions of metric tons of food to recipients worldwide. Alleviating hunger — and the conflict and instability hunger causes — is critical to U.S. national security.

      But BHA is only one player within a large, complex supply chain in which food gets handed off between more than 100 partner organizations before reaching its final destination. Traditionally, the movement of food through the supply chain has been a black-box operation, with stakeholders largely out of the loop about what happens to the food once it leaves their custody. This lack of direct visibility into operations is due to siloed data repositories, insufficient data sharing among stakeholders, and different data formats that operators must manually sort through and standardize. As a result, accurate, real-time information — such as where food shipments are at any given time, which shipments are affected by delays or food recalls, and when shipments have arrived at their final destination — is lacking. A centralized system capable of tracing food along its entire journey, from manufacture through delivery, would enable a more effective humanitarian response to food-aid needs.

      In 2020, a team from MIT Lincoln Laboratory began engaging with BHA to create an intelligent dashboard for their supply-chain operations. This dashboard brings together the expansive food-aid datasets from BHA’s existing systems into a single platform, with tools for visualizing and analyzing the data. When the team started developing the dashboard, they quickly realized the need for considerably more data than BHA had access to.

      “That’s where traceability comes in, with each handoff partner contributing key pieces of information as food moves through the supply chain,” explains Megan Richardson, a researcher in the laboratory’s Humanitarian Assistance and Disaster Relief Systems Group.

      Richardson and the rest of the team have been working with BHA and their partners to scope, build, and implement such an end-to-end traceability system. This system consists of serialized, unique identifiers (IDs) — akin to fingerprints — that are assigned to individual food items at the time they are produced. These individual IDs remain linked to items as they are aggregated along the supply chain, first domestically and then internationally. For example, individually tagged cans of vegetable oil get packaged into cartons; cartons are placed onto pallets and transported via railway and truck to warehouses; pallets are loaded onto shipping containers at U.S. ports; and pallets are unloaded and cartons are unpackaged overseas.

      With a trace

      Today, visibility at the single-item level doesn’t exist. Most suppliers mark pallets with a lot number (a lot is a batch of items produced in the same run), but this is for internal purposes (i.e., to track issues stemming back to their production supply, like over-enriched ingredients or machinery malfunction), not data sharing. So, organizations know which supplier lot a pallet and carton are associated with, but they can’t track the unique history of an individual carton or item within that pallet. As the lots move further downstream toward their final destination, they are often mixed with lots from other productions, and possibly other commodity types altogether, because of space constraints. On the international side, such mixing and the lack of granularity make it difficult to quickly pull commodities out of the supply chain if food safety concerns arise. Current response times can span several months.

      “Commodities are grouped differently at different stages of the supply chain, so it is logical to track them in those groupings where needed,” Richardson says. “Our item-level granularity serves as a form of Rosetta Stone to enable stakeholders to efficiently communicate throughout these stages. We’re trying to enable a way to track not only the movement of commodities, including through their lot information, but also any problems arising independent of lot, like exposure to high humidity levels in a warehouse. Right now, we have no way to associate commodities with histories that may have resulted in an issue.”

      “You can now track your checked luggage across the world and the fish on your dinner plate,” adds Brice MacLaren, also a researcher in the laboratory’s Humanitarian Assistance and Disaster Relief Systems Group. “So, this technology isn’t new, but it’s new to BHA as they evolve their methodology for commodity tracing. The traceability system needs to be versatile, working across a wide variety of operators who take custody of the commodity along the supply chain and fitting into their existing best practices.”

      As food products make their way through the supply chain, operators at each receiving point would be able to scan these IDs via a Lincoln Laboratory-developed mobile application (app) to indicate a product’s current location and transaction status — for example, that it is en route on a particular shipping container or stored in a certain warehouse. This information would get uploaded to a secure traceability server. By scanning a product, operators would also see its history up until that point.   

      Hitting the mark

      At the laboratory, the team tested the feasibility of their traceability technology, exploring different ways to mark and scan items. In their testing, they considered barcodes and radio-frequency identification (RFID) tags and handheld and fixed scanners. Their analysis revealed 2D barcodes (specifically data matrices) and smartphone-based scanners were the most feasible options in terms of how the technology works and how it fits into existing operations and infrastructure.

      “We needed to come up with a solution that would be practical and sustainable in the field,” MacLaren says. “While scanners can automatically read any RFID tags in close proximity as someone is walking by, they can’t discriminate exactly where the tags are coming from. RFID is expensive, and it’s hard to read commodities in bulk. On the other hand, a phone can scan a barcode on a particular box and tell you that code goes with that box. The challenge then becomes figuring out how to present the codes for people to easily scan without significantly interrupting their usual processes for handling and moving commodities.” 

      As the team learned from partner representatives in Kenya and Djibouti, offloading at the ports is a chaotic, fast operation. At manual warehouses, porters fling bags over their shoulders or stack cartons atop their heads any which way they can and run them to a drop point; at bagging terminals, commodities come down a conveyor belt and land this way or that way. With this variability comes several questions: How many barcodes do you need on an item? Where should they be placed? What size should they be? What will they cost? The laboratory team is considering these questions, keeping in mind that the answers will vary depending on the type of commodity; vegetable oil cartons will have different specifications than, say, 50-kilogram bags of wheat or peas.

      Leaving a mark

      Leveraging results from their testing and insights from international partners, the team has been running a traceability pilot evaluating how their proposed system meshes with real-world domestic and international operations. The current pilot features a domestic component in Houston, Texas, and an international component in Ethiopia, and focuses on tracking individual cartons of vegetable oil and identifying damaged cans. The Ethiopian team with Catholic Relief Services recently received a container filled with pallets of uniquely barcoded cartons of vegetable oil cans (in the next pilot, the cans will be barcoded, too). They are now scanning items and collecting data on product damage by using smartphones with the laboratory-developed mobile traceability app on which they were trained. 

      “The partners in Ethiopia are comparing a couple lid types to determine whether some are more resilient than others,” Richardson says. “With the app — which is designed to scan commodities, collect transaction data, and keep history — the partners can take pictures of damaged cans and see if a trend with the lid type emerges.”

      Next, the team will run a series of pilots with the World Food Program (WFP), the world’s largest humanitarian organization. The first pilot will focus on data connectivity and interoperability, and the team will engage with suppliers to directly print barcodes on individual commodities instead of applying barcode labels to packaging, as they did in the initial feasibility testing. The WFP will provide input on which of their operations are best suited for testing the traceability system, considering factors like the network bandwidth of WFP staff and local partners, the commodity types being distributed, and the country context for scanning. The BHA will likely also prioritize locations for system testing.

      “Our goal is to provide an infrastructure to enable as close to real-time data exchange as possible between all parties, given intermittent power and connectivity in these environments,” MacLaren says.

      In subsequent pilots, the team will try to integrate their approach with existing systems that partners rely on for tracking procurements, inventory, and movement of commodities under their custody so that this information is automatically pushed to the traceability server. The team also hopes to add a capability for real-time alerting of statuses, like the departure and arrival of commodities at a port or the exposure of unclaimed commodities to the elements. Real-time alerts would enable stakeholders to more efficiently respond to food-safety events. Currently, partners are forced to take a conservative approach, pulling out more commodities from the supply chain than are actually suspect, to reduce risk of harm. Both BHA and WHP are interested in testing out a food-safety event during one of the pilots to see how the traceability system works in enabling rapid communication response.

      To implement this technology at scale will require some standardization for marking different commodity types as well as give and take among the partners on best practices for handling commodities. It will also require an understanding of country regulations and partner interactions with subcontractors, government entities, and other stakeholders.

      “Within several years, I think it’s possible for BHA to use our system to mark and trace all their food procured in the United States and sent internationally,” MacLaren says.

      Once collected, the trove of traceability data could be harnessed for other purposes, among them analyzing historical trends, predicting future demand, and assessing the carbon footprint of commodity transport. In the future, a similar traceability system could scale for nonfood items, including medical supplies distributed to disaster victims, resources like generators and water trucks localized in emergency-response scenarios, and vaccines administered during pandemics. Several groups at the laboratory are also interested in such a system to track items such as tools deployed in space or equipment people carry through different operational environments.

      “When we first started this program, colleagues were asking why the laboratory was involved in simple tasks like making a dashboard, marking items with barcodes, and using hand scanners,” MacLaren says. “Our impact here isn’t about the technology; it’s about providing a strategy for coordinated food-aid response and successfully implementing that strategy. Most importantly, it’s about people getting fed.” More

    • 125 Shares149 Views

      in Energy

      MIT welcomes Brian Deese as its next Institute Innovation Fellow

      by

      MIT has appointed former White House National Economic Council (NEC) director Brian Deese as an MIT Innovation Fellow, focusing on the impact of economic policies that strengthen the United States’ industrial capacity and on accelerating climate investment and innovation. Deese will begin his appointment this summer. 

      “From climate change to U.S. industrial strategy, the people of MIT strive to make serious positive change at scale — and in Brian Deese, we have found a brilliant ally, guide, and inspiration,“ says MIT President Sally Kornbluth. “He pairs an easy command of technological questions with a rare grasp of contemporary policy and the politics it takes for such policies to succeed. We are extremely fortunate to have Brian with us for this pivotal year.” 

      Deese is an accomplished public policy innovator. As President Joe Biden’s top economic advisor, he was instrumental in shaping several pieces of legislation — the bipartisan Infrastructure Investment and Jobs Act, the CHIPS and Science Act, and the Inflation Reduction Act  — that together are expected to yield more than $3 trillion over the next decade in public and private investments in physical infrastructure, semiconductors, and clean energy, as well as a major expansion of scientific research. 

      “I was attracted to MIT by its combination of extraordinary capabilities in engineering, science, and economics, and the desire and enthusiasm to translate those capabilities into real-world outcomes,” says Deese. 

      Climate and economic policy expertise

      Deese’s public service career has spanned multiple periods of global economic crisis. He has helped shape policies ranging from clean energy infrastructure investments to addressing supply chain disruptions triggered by the pandemic and the war in Ukraine. 

      As NEC director in the Biden White House, Deese oversaw the development of domestic and international economic policy. Previously, he served as the global head of sustainable investing at BlackRock, Inc., one of the world’s leading asset management firms; before that, he held several key posts in the Obama White House, serving as the president’s top advisor on climate policy; deputy director of the Office of Management and Budget; and deputy director of the NEC. Early in the Obama Administration, Deese played a key role in developing and implementing the rescue of the U.S. auto industry during the Great Recession. Deese earned a bachelor of arts degree from Middlebury College and his JD from Yale Law School.

      Despite recent legislative progress, the world still faces daunting climate and energy challenges, including the need to reduce greenhouse gas emissions, increase energy capacity, and fill infrastructure gaps, Deese notes.

      “Our biggest challenge is our biggest opportunity,” he says. “We need to build at a speed not seen in generations.”  

      Deese is also thinking about how to effectively design and implement industrial strategy approaches that build on recent efforts to restore the U.S. semiconductor industry. What’s needed, he says, is an approach that can foster innovation and build manufacturing capacity — especially in economically disadvantaged areas of the country — while learning lessons from previous successes and failures in this field. 

      “This is a timely and important appointment because Brian has enormous experience at the top levels of government in shaping public policies for climate, technology, manufacturing, and energy, and the consequences for  shared prosperity nationally and globally — all subjects of intense interest to the MIT community,” says MIT Associate Provost Richard Lester. “I fully expect that faculty and student engagement with Brian while he is with us will help advance MIT research, innovation, and impact in these critical areas.”

      Innovation fellowship

      Previous MIT Innovation Fellows, typically in residence for a year or more, have included luminaries from industry and government, including most recently Virginia M. “Ginny” Rometty, former chair, president, and CEO of IBM; Eric Schmidt, former executive chair of Google’s parent company, Alphabet; the late Ash Carter, former U.S. secretary of defense; and former Massachusetts Governor Deval Patrick.

      During his time at MIT, Deese will work on a project detailing and mapping private investment in clean energy and other climate-related activities. He will also interact with students, staff, and faculty from across the Institute. 

      “I hope my role at MIT can largely be about forging partnerships within the Institute and outside of the Institute to significantly reduce the time between innovation and outcomes into the world,” says Deese. More

    • 100 Shares189 Views

      in Energy

      Six ways MIT is taking action on climate

      by

      From reuse and recycling to new carbon markets, events during Earth Month at MIT spanned an astonishing range of ideas and approaches to tackling the climate crisis. The MIT Climate Nucleus offered funding to departments and student organizations to develop programming that would showcase the countless initiatives underway to make a better world.

      Here are six — just six of many — ways the MIT community is making a difference on climate right now.

      1. Exchanging knowledge with policymakers to meet local, regional, and global challenges

      Creating solutions begins with understanding the problem.

      Speaking during the annual Earth Day Colloquium of the MIT Energy Initiative (MITEI) about the practical challenges of implementing wind-power projects, for instance, Massachusetts State Senator Michael J. Barrett offered a sobering assessment.

      The senate chair of the Joint Committee on Telecommunications, Utilities, and Energy, Barrett reported that while the coast of Massachusetts provides a conducive site for offshore wind, economic forces have knocked a major offshore wind installation project off track. The combination of the pandemic and global geopolitical instability has led to such great supply chain disruptions and rising commodity costs that a project considered necessary for the state to meet its near-term climate goals now faces delays, he said.

      Like others at MIT, MITEI researchers keep their work grounded in the real-world constraints and possibilities for decarbonization, engaging with policymakers and industry to understand the on-the-ground challenges to technological and policy-based solutions and highlight the opportunities for greatest impact.

      2. Developing new ways to prevent, mitigate, and adapt to the effects of climate change

      An estimated 20 percent of MIT faculty work on some aspect of the climate crisis, an enormous research effort distributed throughout the departments, labs, centers, and institutes.

      About a dozen such projects were on display at a poster session coordinated by the Abdul Latif Jameel Water and Food Systems Lab (J-WAFS), Environmental Solutions Initiative (ESI), and MITEI.

      Students and postdocs presented innovations including:

      Graduate student Alexa Reese Canaan describes her research on household energy consumption to Massachusetts State Senator Michael J. Barrett, chair of the Joint Committee on Telecommunications, Utilities, and Energy.

      Photo: Caitlin Cunningham

      Previous item
      Next item

      3. Preparing students to meet the challenges of a climate-changed world

      Faculty and staff from more than 30 institutions of higher education convened at the MIT Symposium on Advancing Climate Education to exchange best practices and innovations in teaching and learning. Speakers and participants considered paths to structural change in higher education, the imperative to place equity and justice at the center of new educational approaches, and what it means to “educate the whole student” so that graduates are prepared to live and thrive in a world marked by global environmental and economic disruption.

      Later in April, MIT faculty voted to approve the creation of a new joint degree program in climate system science and engineering.

      4. Offering climate curricula to K-12 teachers

      At a daylong conference on climate education for K-12 schools, the attendees were not just science teachers. Close to 50 teachers of arts, literature, history, math, mental health, English language, world languages, and even carpentry were all hungry for materials and approaches to integrate into their curricula. They were joined by another 50 high school students, ready to test out the workshops and content developed by MIT Climate Action Through Education (CATE), which are already being piloted in at least a dozen schools.

      The CATE initiative is led by Christopher Knittel, the George P. Shultz Professor of Energy Economics at the MIT Sloan School of Management, deputy director for policy at MITEI, and faculty director of the MIT Center for Energy and Environmental Policy Research. The K-12 Climate Action and Education Conference was hosted as a collaboration with the Massachusetts Teachers Association Climate Action Network and Earth Day Boston.

      “We will be honest about the threats posed by climate change, but also give students a sense of agency that they can do something about this,” Knittel told MITEI Energy Futures earlier this spring. “And for the many teachers — especially non-science teachers — starved for knowledge and background material, CATE offers resources to give them confidence to implement our curriculum.”

      High school students and K-12 teachers participated in a workshop on “Exploring a Green City,” part of the Climate Action and Education Conference on April 1.

      Photo: Tony Rinaldo

      Previous item
      Next item

      5. Guiding our communities in making sense of the coming changes

      The arts and humanities, vital in their own right, are also central to the sharing of scientific knowledge and its integration into culture, behavior, and decision-making. A message well-delivered can reach new audiences and prompt reflection and reckoning on ethics and values, identity, and optimism.

      The Climate Machine, part of ESI’s Arts and Climate program, produced an evening art installation on campus featuring dynamic, large-scale projections onto the façade of MIT’s new music building and a musical performance by electronic duo Warung. Passers-by were invited to take a Climate Identity Quiz, with the responses reflected in the visuals. Another exhibit displayed the results of a workshop in which attendees had used an artificial intelligence art tool to imagine the future of their hometowns, while another highlighted native Massachusetts wildlife.

      The Climate Machine is an MIT research project undertaken in collaboration with record label Anjunabeats. The collaborative team imagines interactive experiences centered on sustainability that could be deployed at musical events and festivals to inspire climate action.

      Dillon Ames (left) and Aaron Hopkins, known as the duo Warung, perform a live set during the Climate Machine art installation.

      Photo: Caitlin Cunningham

      Previous item
      Next item

      6. Empowering students to seize this unique policy moment

      ESI’s TILclimate Podcast, which breaks down important climate topics for general listeners, held a live taping at the MIT Museum and offered an explainer on three recent, major pieces of federal legislation: the Inflation Reduction Act of 2022, the Bipartisan Infrastructure Bill of 2021, and the CHIPS and Science Act of 2022.

      The combination of funding and financial incentives for energy- and climate-related projects, along with reinvestment in industrial infrastructure, create “a real moment and an opportunity,” said special guest Elisabeth Reynolds, speaking with host Laur Hesse Fisher. Reynolds was a member of the National Economic Council from 2021 to 2022, serving as special assistant to the president for manufacturing and economic development; after leaving the White House, Reynolds returned to MIT, where she is a lecturer in MIT’s Department of Urban Studies and Planning.

      For students, the opportunities to engage have never been better, Reynolds urged: “There is so much need. … Find a way to contribute, and find a way to help us make this transformation.”

      “What we’re embarking on now, you just can’t overstate the significance of it,” she said.

      For more information on how MIT is advancing climate action across education; research and innovation; policy; economic, social, and environmental justice; public and global engagement; sustainable campus operations; and more, visit Fast Forward: MIT’s Climate Action Plan for the Decade. The actions described in the plan aim to accelerate the global transition to net-zero carbon emissions, and to “educate and empower the next generation.” More

    • 75 Shares119 Views

      in Energy

      Flow batteries for grid-scale energy storage

      by

      In the coming decades, renewable energy sources such as solar and wind will increasingly dominate the conventional power grid. Because those sources only generate electricity when it’s sunny or windy, ensuring a reliable grid — one that can deliver power 24/7 — requires some means of storing electricity when supplies are abundant and delivering it later when they’re not. And because there can be hours and even days with no wind, for example, some energy storage devices must be able to store a large amount of electricity for a long time.

      A promising technology for performing that task is the flow battery, an electrochemical device that can store hundreds of megawatt-hours of energy — enough to keep thousands of homes running for many hours on a single charge. Flow batteries have the potential for long lifetimes and low costs in part due to their unusual design. In the everyday batteries used in phones and electric vehicles, the materials that store the electric charge are solid coatings on the electrodes. “A flow battery takes those solid-state charge-storage materials, dissolves them in electrolyte solutions, and then pumps the solutions through the electrodes,” says Fikile Brushett, an associate professor of chemical engineering at MIT. That design offers many benefits and poses a few challenges.

      Flow batteries: Design and operation

      A flow battery contains two substances that undergo electrochemical reactions in which electrons are transferred from one to the other. When the battery is being charged, the transfer of electrons forces the two substances into a state that’s “less energetically favorable” as it stores extra energy. (Think of a ball being pushed up to the top of a hill.) When the battery is being discharged, the transfer of electrons shifts the substances into a more energetically favorable state as the stored energy is released. (The ball is set free and allowed to roll down the hill.)

      At the core of a flow battery are two large tanks that hold liquid electrolytes, one positive and the other negative. Each electrolyte contains dissolved “active species” — atoms or molecules that will electrochemically react to release or store electrons. During charging, one species is “oxidized” (releases electrons), and the other is “reduced” (gains electrons); during discharging, they swap roles. Pumps are used to circulate the two electrolytes through separate electrodes, each made of a porous material that provides abundant surfaces on which the active species can react. A thin membrane between the adjacent electrodes keeps the two electrolytes from coming into direct contact and possibly reacting, which would release heat and waste energy that could otherwise be used on the grid.

      When the battery is being discharged, active species on the negative side oxidize, releasing electrons that flow through an external circuit to the positive side, causing the species there to be reduced. The flow of those electrons through the external circuit can power the grid. In addition to the movement of the electrons, “supporting” ions — other charged species in the electrolyte — pass through the membrane to help complete the reaction and keep the system electrically neutral.

      Once all the species have reacted and the battery is fully discharged, the system can be recharged. In that process, electricity from wind turbines, solar farms, and other generating sources drives the reverse reactions. The active species on the positive side oxidize to release electrons back through the wires to the negative side, where they rejoin their original active species. The battery is now reset and ready to send out more electricity when it’s needed. Brushett adds, “The battery can be cycled in this way over and over again for years on end.”

      Benefits and challenges

      A major advantage of this system design is that where the energy is stored (the tanks) is separated from where the electrochemical reactions occur (the so-called reactor, which includes the porous electrodes and membrane). As a result, the capacity of the battery — how much energy it can store — and its power — the rate at which it can be charged and discharged — can be adjusted separately. “If I want to have more capacity, I can just make the tanks bigger,” explains Kara Rodby PhD ’22, a former member of Brushett’s lab and now a technical analyst at Volta Energy Technologies. “And if I want to increase its power, I can increase the size of the reactor.” That flexibility makes it possible to design a flow battery to suit a particular application and to modify it if needs change in the future.

      However, the electrolyte in a flow battery can degrade with time and use. While all batteries experience electrolyte degradation, flow batteries in particular suffer from a relatively faster form of degradation called “crossover.” The membrane is designed to allow small supporting ions to pass through and block the larger active species, but in reality, it isn’t perfectly selective. Some of the active species in one tank can sneak through (or “cross over”) and mix with the electrolyte in the other tank. The two active species may then chemically react, effectively discharging the battery. Even if they don’t, some of the active species is no longer in the first tank where it belongs, so the overall capacity of the battery is lower.

      Recovering capacity lost to crossover requires some sort of remediation — for example, replacing the electrolyte in one or both tanks or finding a way to reestablish the “oxidation states” of the active species in the two tanks. (Oxidation state is a number assigned to an atom or compound to tell if it has more or fewer electrons than it has when it’s in its neutral state.) Such remediation is more easily — and therefore more cost-effectively — executed in a flow battery because all the components are more easily accessed than they are in a conventional battery.

      The state of the art: Vanadium

      A critical factor in designing flow batteries is the selected chemistry. The two electrolytes can contain different chemicals, but today the most widely used setup has vanadium in different oxidation states on the two sides. That arrangement addresses the two major challenges with flow batteries.

      First, vanadium doesn’t degrade. “If you put 100 grams of vanadium into your battery and you come back in 100 years, you should be able to recover 100 grams of that vanadium — as long as the battery doesn’t have some sort of a physical leak,” says Brushett.

      And second, if some of the vanadium in one tank flows through the membrane to the other side, there is no permanent cross-contamination of the electrolytes, only a shift in the oxidation states, which is easily remediated by re-balancing the electrolyte volumes and restoring the oxidation state via a minor charge step. Most of today’s commercial systems include a pipe connecting the two vanadium tanks that automatically transfers a certain amount of electrolyte from one tank to the other when the two get out of balance.

      However, as the grid becomes increasingly dominated by renewables, more and more flow batteries will be needed to provide long-duration storage. Demand for vanadium will grow, and that will be a problem. “Vanadium is found around the world but in dilute amounts, and extracting it is difficult,” says Rodby. “So there are limited places — mostly in Russia, China, and South Africa — where it’s produced, and the supply chain isn’t reliable.” As a result, vanadium prices are both high and extremely volatile — an impediment to the broad deployment of the vanadium flow battery.

      Beyond vanadium

      The question then becomes: If not vanadium, then what? Researchers worldwide are trying to answer that question, and many are focusing on promising chemistries using materials that are more abundant and less expensive than vanadium. But it’s not that easy, notes Rodby. While other chemistries may offer lower initial capital costs, they may be more expensive to operate over time. They may require periodic servicing to rejuvenate one or both of their electrolytes. “You may even need to replace them, so you’re essentially incurring that initial (low) capital cost again and again,” says Rodby.

      Indeed, comparing the economics of different options is difficult because “there are so many dependent variables,” says Brushett. “A flow battery is an electrochemical system, which means that there are multiple components working together in order for the device to function. Because of that, if you are trying to improve a system — performance, cost, whatever — it’s very difficult because when you touch one thing, five other things change.”

      So how can we compare these new and emerging chemistries — in a meaningful way — with today’s vanadium systems? And how do we compare them with one another, so we know which ones are more promising and what the potential pitfalls are with each one? “Addressing those questions can help us decide where to focus our research and where to invest our research and development dollars now,” says Brushett.

      Techno-economic modeling as a guide

      A good way to understand and assess the economic viability of new and emerging energy technologies is using techno-economic modeling. With certain models, one can account for the capital cost of a defined system and — based on the system’s projected performance — the operating costs over time, generating a total cost discounted over the system’s lifetime. That result allows a potential purchaser to compare options on a “levelized cost of storage” basis.

      Using that approach, Rodby developed a framework for estimating the levelized cost for flow batteries. The framework includes a dynamic physical model of the battery that tracks its performance over time, including any changes in storage capacity. The calculated operating costs therefore cover all services required over decades of operation, including the remediation steps taken in response to species degradation and crossover.

      Analyzing all possible chemistries would be impossible, so the researchers focused on certain classes. First, they narrowed the options down to those in which the active species are dissolved in water. “Aqueous systems are furthest along and are most likely to be successful commercially,” says Rodby. Next, they limited their analyses to “asymmetric” chemistries; that is, setups that use different materials in the two tanks. (As Brushett explains, vanadium is unusual in that using the same “parent” material in both tanks is rarely feasible.) Finally, they divided the possibilities into two classes: species that have a finite lifetime and species that have an infinite lifetime; that is, ones that degrade over time and ones that don’t.

      Results from their analyses aren’t clear-cut; there isn’t a particular chemistry that leads the pack. But they do provide general guidelines for choosing and pursuing the different options.

      Finite-lifetime materials

      While vanadium is a single element, the finite-lifetime materials are typically organic molecules made up of multiple elements, among them carbon. One advantage of organic molecules is that they can be synthesized in a lab and at an industrial scale, and the structure can be altered to suit a specific function. For example, the molecule can be made more soluble, so more will be present in the electrolyte and the energy density of the system will be greater; or it can be made bigger so it won’t fit through the membrane and cross to the other side. Finally, organic molecules can be made from simple, abundant, low-cost elements, potentially even waste streams from other industries.

      Despite those attractive features, there are two concerns. First, organic molecules would probably need to be made in a chemical plant, and upgrading the low-cost precursors as needed may prove to be more expensive than desired. Second, these molecules are large chemical structures that aren’t always very stable, so they’re prone to degradation. “So along with crossover, you now have a new degradation mechanism that occurs over time,” says Rodby. “Moreover, you may figure out the degradation process and how to reverse it in one type of organic molecule, but the process may be totally different in the next molecule you work on, making the discovery and development of each new chemistry require significant effort.”

      Research is ongoing, but at present, Rodby and Brushett find it challenging to make the case for the finite-lifetime chemistries, mostly based on their capital costs. Citing studies that have estimated the manufacturing costs of these materials, Rodby believes that current options cannot be made at low enough costs to be economically viable. “They’re cheaper than vanadium, but not cheap enough,” says Rodby.

      The results send an important message to researchers designing new chemistries using organic molecules: Be sure to consider operating challenges early on. Rodby and Brushett note that it’s often not until way down the “innovation pipeline” that researchers start to address practical questions concerning the long-term operation of a promising-looking system. The MIT team recommends that understanding the potential decay mechanisms and how they might be cost-effectively reversed or remediated should be an upfront design criterion.

      Infinite-lifetime species

      The infinite-lifetime species include materials that — like vanadium — are not going to decay. The most likely candidates are other metals; for example, iron or manganese. “These are commodity-scale chemicals that will certainly be low cost,” says Rodby.

      Here, the researchers found that there’s a wider “design space” of feasible options that could compete with vanadium. But there are still challenges to be addressed. While these species don’t degrade, they may trigger side reactions when used in a battery. For example, many metals catalyze the formation of hydrogen, which reduces efficiency and adds another form of capacity loss. While there are ways to deal with the hydrogen-evolution problem, a sufficiently low-cost and effective solution for high rates of this side reaction is still needed.

      In addition, crossover is a still a problem requiring remediation steps. The researchers evaluated two methods of dealing with crossover in systems combining two types of infinite-lifetime species.

      The first is the “spectator strategy.” Here, both of the tanks contain both active species. Explains Brushett, “You have the same electrolyte mixture on both sides of the battery, but only one of the species is ever working and the other is a spectator.” As a result, crossover can be remediated in similar ways to those used in the vanadium flow battery. The drawback is that half of the active material in each tank is unavailable for storing charge, so it’s wasted. “You’ve essentially doubled your electrolyte cost on a per-unit energy basis,” says Rodby.

      The second method calls for making a membrane that is perfectly selective: It must let through only the supporting ion needed to maintain the electrical balance between the two sides. However, that approach increases cell resistance, hurting system efficiency. In addition, the membrane would need to be made of a special material — say, a ceramic composite — that would be extremely expensive based on current production methods and scales. Rodby notes that work on such membranes is under way, but the cost and performance metrics are “far off from where they’d need to be to make sense.”

      Time is of the essence

      The researchers stress the urgency of the climate change threat and the need to have grid-scale, long-duration storage systems at the ready. “There are many chemistries now being looked at,” says Rodby, “but we need to hone in on some solutions that will actually be able to compete with vanadium and can be deployed soon and operated over the long term.”

      The techno-economic framework is intended to help guide that process. It can calculate the levelized cost of storage for specific designs for comparison with vanadium systems and with one another. It can identify critical gaps in knowledge related to long-term operation or remediation, thereby identifying technology development or experimental investigations that should be prioritized. And it can help determine whether the trade-off between lower upfront costs and greater operating costs makes sense in these next-generation chemistries.

      The good news, notes Rodby, is that advances achieved in research on one type of flow battery chemistry can often be applied to others. “A lot of the principles learned with vanadium can be translated to other systems,” she says. She believes that the field has advanced not only in understanding but also in the ability to design experiments that address problems common to all flow batteries, thereby helping to prepare the technology for its important role of grid-scale storage in the future.

      This research was supported by the MIT Energy Initiative. Kara Rodby PhD ’22 was supported by an ExxonMobil-MIT Energy Fellowship in 2021-22.

      This article appears in the Winter 2023 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

    • 88 Shares159 Views

      in Environment

      Sustainable supply chains put the customer first

      by

      When we consider the supply chain, we typically think of factories, ships, trucks, and warehouses. Yet, the customer side is equally important, especially in efforts to make our distribution networks more sustainable. Customers are an untapped resource in building sustainability, says Josué C. Velázquez Martínez, a research scientist at MIT Center for Transportation and Logistics. 

      Velázquez Martínez, who is director of MIT’s Sustainable Supply Chain Lab, investigates how customer-facing supply chains can be made more environmentally and socially sustainable. One way is a Green Button project that explores how to optimize e-commerce delivery schedules to reduce carbon emissions and persuade customers to use less carbon-intensive four- or five-day shipping options instead of one or two days. Velázquez Martínez has also launched the MIT Low Income Firms Transformation (LIFT) Lab that is researching ways to improve micro-retailer supply chains in the developing world to provide owners with the necessary tools for survival.  

      “The definition of sustainable supply chain keeps evolving because things that were sustainable 20 to 30 years ago are not as sustainable now,” says Velázquez Martínez. “Today, there are more companies that are capturing information to build strategies for environmental, economic, and social sustainability. They are investing in alternative energy and other solutions to make the supply chain more environmentally friendly and are tracking their suppliers and identifying key vulnerabilities. A big part of this is an attempt to create fairer conditions for people who work in supply chains or are dependent on them.”

      Play video

      The move toward sustainable supply chain is being driven as much by people as by companies, whether they are playing the role of selective consumer or voting citizens. The consumer aspect is often overlooked, says Velázquez Martínez. “Consumers are the ones who move the supply chain. We are looking at how companies can provide transparency to involve customers in their sustainability strategy.” 

      Proposed solutions for sustainability are not always as effective as promised. Some fashion rental schemes fall into this category, says Velázquez Martínez. “There are many new rental companies that are trying to get more use out of clothes to offset the emissions associated with production. We recently researched the environmental impact of monthly subscription models where consumers pay a fee to receive clothes for a month before returning them, as well as peer-to-peer sharing models.” 

      The researchers found that while rental services generally have a lower carbon footprint than retail sales, hidden emissions from logistics played a surprisingly large role. “First, you need to deliver the clothes and pick them up, and there are high return rates,” says Velázquez Martínez. “When you factor in dry cleaning and packaging emissions, the rental models in some cases have a worse carbon footprint than buying new clothes.” Peer-to-peer sharing could be better, he adds, but that depends on how far the consumers travel to meet-up points. 

      Typically, says Velázquez Martínez, garment types that are frequently used are not well suited to rental models. “But for specialty clothes such as wedding dresses or prom dresses, it is better to rent.” 

      Waiting a few days to save the planet 

      Even before the pandemic, online retailing gained a second wind due to low-cost same- and next-day delivery options. While e-commerce may have its drawbacks as a contributor to social isolation and reduced competition, it has proven itself to be far more eco-friendly than brick-and-mortar shopping, not to mention a lot more convenient. Yet rapid deliveries are cutting into online-shopping’s carbon-cutting advantage.

      In 2019, MIT’s Sustainable Supply Chain Lab launched a Green Bottle project to study the rapid delivery phenomenon. The project has been “testing whether consumers would be willing to delay their e-commerce deliveries to reduce the environmental impact of fast shipping,” says Velázquez Martínez. “Many companies such as Walmart and Target have followed Amazon’s 2019 strategy of moving from two-day to same-day delivery. Instead of sending a fully loaded truck to a neighborhood every few days, they now send multiple trucks to that neighborhood every day, and there are more days when trucks are targeting each neighborhood. All this increases carbon emissions and makes it hard for shippers to consolidate. ”  

      Working with Coppel, one of Mexico’s largest retailers, the Green Button project inspired a related Consolidation Ecommerce Project that built a large-scale mathematical model to provide a strategy for consolidation. The model determined what delivery time window each neighborhood demands and then calculated the best day to deliver to each neighborhood to meet the desired window while minimizing carbon emissions. 

      No matter what mixture of delivery times was used, the consolidation model helped retailers schedule deliveries more efficiently. Yet, the biggest cuts in emissions emerged when customers were willing to wait several days.

      Play video

      “When we ran a month-long simulation comparing our model for four-to-five-day delivery with Coppel’s existing model for one- or two-day delivery, we saw savings in fuel consumption of over 50 percent on certain routes” says Velázquez Martínez. “This is huge compared to other strategies for squeezing more efficiency from the last-mile supply chain, such as routing optimization, where savings are close to 5 percent. The optimal solution depends on factors such as the capacity for consolidation, the frequency of delivery, the store capacity, and the impact on inbound operations.” 

      The researchers next set out to determine if customers could be persuaded to wait longer for deliveries. Considering that the price differential is low or nonexistent, this was a considerable challenge. Yet, the same day habit is only a few years old, and some consumers have come to realize they don’t always need rapid deliveries. “Some consumers who order by rapid delivery find they are too busy to open the packages right away,” says Velázquez Martínez.  

      Trees beat kilograms of CO2

      The researchers set out to find if consumers would be willing to sacrifice a bit of convenience if they knew they were helping to reduce climate change. The Green Button project tested different public outreach strategies. For one test group, they reported the carbon impact of delivery times in kilograms of carbon dioxide (CO2). Another group received the information expressed in terms of the energy required to recycle a certain amount of garbage. A third group learned about emissions in terms of the number of trees required to trap the carbon. “Explaining the impact in terms of trees led to almost 90 percent willing to wait another day or two,” says Velázquez Martínez. “This is compared to less than 40 percent for the group that received the data in kilograms of CO2.” 

      Another surprise was that there was no difference in response based on income, gender, or age. “Most studies of green consumers suggest they are predominantly high income, female, highly educated, or younger,” says Velázquez Martínez. “However, our results show that the differences were the same between low and high income, women and men, and younger and older people. We have shown that disclosing emissions transparently and making the consumer a part of the strategy can be a new opportunity for more consumer-driven logistics sustainability.” 

      The researchers are now developing similar models for business-to-business (B2B) e-commerce. “We found that B2B supply chain emissions are often high because many shipping companies require strict delivery windows,” says Velázquez Martínez.  

      The B2B models drill down to examine the Corporate Value Chain (Scope 3) emissions of suppliers. “Although some shipping companies are now asking their suppliers to review emissions, it is a challenge to create a transparent supply chain,” says Velázquez Martínez.  “Technological innovations have made it easier, starting with RFID [radio frequency identification], and then real-time GPS mapping and blockchain. But these technologies need to be more accessible and affordable, and we need more companies willing to use them.” 

      Some companies have been hesitant to dig too deeply into their supply chain, fearing they might uncover a scandal that might risk their reputation, says Velázquez Martínez. Other organizations are forced to look at the issue when nongovernmental organizations research sustainability issues such as social injustice in sweat shops and conflict mineral mines. 

      One challenge to building a transparent supply chain is that “in many companies, the sustainability teams are separate from the rest of the company,” says Velázquez Martínez. “Even if the CEOs receive information on sustainability issues, it often doesn’t filter down because the information does not belong to the planners or managers. We are pushing companies to not only account for sustainability factors in supply chain network design but also examine daily operations that affect sustainability. This is a big topic now: How can we translate sustainability information into something that everybody can understand and use?” 

      LIFT Lab lifts micro-retailers  

      In 2016, Velázquez Martínez launched the MIT GeneSys project to gain insights into micro and small enterprises (MSEs) in developing countries. The project released a GeneSys mobile app, which was used by more than 500 students throughout Latin America to collect data on more than 800 microfirms. In 2022, he launched the LIFT Lab, which focuses more specifically on studying and improving the supply chain for MSEs.  

      Worldwide, some 90 percent of companies have fewer than 10 employees. In Latin America and the Caribbean, companies with fewer than 50 employees represent 99 percent of all companies and 47 percent of employment. 

      Although MSEs represent much of the world’s economy, they are poorly understood, notes Velázquez Martínez. “Those tiny businesses are driving a lot of the economy and serve as important customers for the large companies working in developing countries. They range from small businesses down to people trying to get some money to eat by selling cakes or tacos through their windows.”  

      The MIT LIFT Lab researchers investigated whether MSE supply chain issues could help shed light on why many Latin American countries have been limited to marginal increases in gross domestic product. “Large companies from the developed world that are operating in Latin America, such as Unilever, Walmart, and Coca-Cola, have huge growth there, in some cases higher than they have in the developed world,” says Velázquez Martínez. “Yet, the countries are not developing as fast as we would expect.” 

      The LIFT Lab data showed that while the multinationals are thriving in Latin America, the local MSEs are decreasing in productivity. The study also found the trend has worsened with Covid-19.  

      The LIFT Lab’s first big project, which is sponsored by Mexican beverage and retail company FEMSA, is studying supply chains in Mexico. The study spans 200,000 micro-retailers and 300,000 consumers. In a collaboration with Tecnológico de Monterrey, hundreds of students are helping with a field study.  

      “We are looking at supply chain management and business capabilities and identifying the challenges to adoption of technology and digitalization,” says Velázquez Martínez. “We want to find the best ways for micro-firms to work with suppliers and consumers by identifying the consumers who access this market, as well as the products and services that can best help the micro-firms drive growth.” 

      Based on the earlier research by GeneSys, Velázquez Martínez has developed some hypotheses for potential improvements for micro-retailer supply chain, starting with payment terms. “We found that the micro-firms often get the worst purchasing deals. Owners without credit cards and with limited cash often buy in smaller amounts at much higher prices than retailers like Walmart. The big suppliers are squeezing them.” 

      While large retailers usually get 60 to 120 days to pay, micro-retailers “either pay at the moment of the transaction or in advance,” says Velázquez Martínez. “In a study of 500 micro-retailers in five countries in Latin America, we found the average payment time was minus seven days payment in advance. These terms reduce cash availability and often lead to bankruptcy.” 

      LIFT Lab is working with suppliers to persuade them to offer a minimum payment time of two weeks. “We can show the suppliers that the change in terms will let them move more product and increase sales,” says Velázquez Martínez. “Meanwhile, the micro-retailers gain higher profits and become more stable, even if they may pay a bit more.” 

      LIFT Lab is also looking at ways that micro-retailers can leverage smartphones for digitalization and planning. “Some of these companies are keeping records on napkins,” says Velázquez Martínez. “By using a cellphone, they can charge orders to suppliers and communicate with consumers. We are testing different dashboards for mobile apps to help with planning and financial performance. We are also recommending services the stores can provide, such as paying electricity or water bills. The idea is to build more capabilities and knowledge and increase business competencies for the supply chain that are tailored for micro-retailers.” 

      From a financial perspective, micro-retailers are not always the most efficient way to move products. Yet they also play an important role in building social cohesion within neighborhoods. By offering more services, the corner bodega can bring people together in ways that are impossible with e-commerce and big-box stores.  

      Whether the consumers are micro-firms buying from suppliers or e-commerce customers waiting for packages, “transparency is key to building a sustainable supply chain,” says Velázquez Martínez. “To change consumer habits, consumers need to be better educated on the impacts of their behaviors. With consumer-facing logistics, ‘The last shall be first, and the first last.’” More