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      in Energy

      How to pull carbon dioxide out of seawater

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      As carbon dioxide continues to build up in the Earth’s atmosphere, research teams around the world have spent years seeking ways to remove the gas efficiently from the air. Meanwhile, the world’s number one “sink” for carbon dioxide from the atmosphere is the ocean, which soaks up some 30 to 40 percent of all of the gas produced by human activities.

      Recently, the possibility of removing carbon dioxide directly from ocean water has emerged as another promising possibility for mitigating CO2 emissions, one that could potentially someday even lead to overall net negative emissions. But, like air capture systems, the idea has not yet led to any widespread use, though there are a few companies attempting to enter this area.

      Now, a team of researchers at MIT says they may have found the key to a truly efficient and inexpensive removal mechanism. The findings were reported this week in the journal Energy and Environmental Science, in a paper by MIT professors T. Alan Hatton and Kripa Varanasi, postdoc Seoni Kim, and graduate students Michael Nitzsche, Simon Rufer, and Jack Lake.

      The existing methods for removing carbon dioxide from seawater apply a voltage across a stack of membranes to acidify a feed stream by water splitting. This converts bicarbonates in the water to molecules of CO2, which can then be removed under vacuum. Hatton, who is the Ralph Landau Professor of Chemical Engineering, notes that the membranes are expensive, and chemicals are required to drive the overall electrode reactions at either end of the stack, adding further to the expense and complexity of the processes. “We wanted to avoid the need for introducing chemicals to the anode and cathode half cells and to avoid the use of membranes if at all possible” he says.

      The team came up with a reversible process consisting of membrane-free electrochemical cells. Reactive electrodes are used to release protons to the seawater fed to the cells, driving the release of the dissolved carbon dioxide from the water. The process is cyclic: It first acidifies the water to convert dissolved inorganic bicarbonates to molecular carbon dioxide, which is collected as a gas under vacuum. Then, the water is fed to a second set of cells with a reversed voltage, to recover the protons and turn the acidic water back to alkaline before releasing it back to the sea. Periodically, the roles of the two cells are reversed once one set of electrodes is depleted of protons (during acidification) and the other has been regenerated during alkalization.

      This removal of carbon dioxide and reinjection of alkaline water could slowly start to reverse, at least locally, the acidification of the oceans that has been caused by carbon dioxide buildup, which in turn has threatened coral reefs and shellfish, says Varanasi, a professor of mechanical engineering. The reinjection of alkaline water could be done through dispersed outlets or far offshore to avoid a local spike of alkalinity that could disrupt ecosystems, they say.

      “We’re not going to be able to treat the entire planet’s emissions,” Varanasi says. But the reinjection might be done in some cases in places such as fish farms, which tend to acidify the water, so this could be a way of helping to counter that effect.

      Once the carbon dioxide is removed from the water, it still needs to be disposed of, as with other carbon removal processes. For example, it can be buried in deep geologic formations under the sea floor, or it can be chemically converted into a compound like ethanol, which can be used as a transportation fuel, or into other specialty chemicals. “You can certainly consider using the captured CO2 as a feedstock for chemicals or materials production, but you’re not going to be able to use all of it as a feedstock,” says Hatton. “You’ll run out of markets for all the products you produce, so no matter what, a significant amount of the captured CO2 will need to be buried underground.”

      Initially at least, the idea would be to couple such systems with existing or planned infrastructure that already processes seawater, such as desalination plants. “This system is scalable so that we could integrate it potentially into existing processes that are already processing ocean water or in contact with ocean water,” Varanasi says. There, the carbon dioxide removal could be a simple add-on to existing processes, which already return vast amounts of water to the sea, and it would not require consumables like chemical additives or membranes.

      “With desalination plants, you’re already pumping all the water, so why not co-locate there?” Varanasi says. “A bunch of capital costs associated with the way you move the water, and the permitting, all that could already be taken care of.”

      The system could also be implemented by ships that would process water as they travel, in order to help mitigate the significant contribution of ship traffic to overall emissions. There are already international mandates to lower shipping’s emissions, and “this could help shipping companies offset some of their emissions, and turn ships into ocean scrubbers,” Varanasi says.

      The system could also be implemented at locations such as offshore drilling platforms, or at aquaculture farms. Eventually, it could lead to a deployment of free-standing carbon removal plants distributed globally.

      The process could be more efficient than air-capture systems, Hatton says, because the concentration of carbon dioxide in seawater is more than 100 times greater than it is in air. In direct air-capture systems it is first necessary to capture and concentrate the gas before recovering it. “The oceans are large carbon sinks, however, so the capture step has already kind of been done for you,” he says. “There’s no capture step, only release.” That means the volumes of material that need to be handled are much smaller, potentially simplifying the whole process and reducing the footprint requirements.

      The research is continuing, with one goal being to find an alternative to the present step that requires a vacuum to remove the separated carbon dioxide from the water. Another need is to identify operating strategies to prevent precipitation of minerals that can foul the electrodes in the alkalinization cell, an inherent issue that reduces the overall efficiency in all reported approaches. Hatton notes that significant progress has been made on these issues, but that it is still too early to report on them. The team expects that the system could be ready for a practical demonstration project within about two years.

      “The carbon dioxide problem is the defining problem of our life, of our existence,” Varanasi says. “So clearly, we need all the help we can get.”

      The work was supported by ARPA-E. More

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      in Environment

      Featured video: Investigating our blue ocean planet

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      A five-year doctoral degree program, the MIT – Woods Hole Oceanographic Institution (WHOI) Joint Program in Oceanography/Applied Ocean Science and Engineering combines the strengths of MIT and WHOI to create one of the largest oceanographic facilities in the world. Graduate study in oceanography encompasses virtually all the basic sciences as they apply to the marine environment: physics, chemistry, geochemistry, geology, geophysics, and biology.

      “As a species and as a society we really want to understand the planet that we live on and our place in it,” says Professor Michael Follows, who serves as director of the MIT-WHOI Joint Program.

      “The reason I joined the program was because we cannot afford to wait to be able to address the climate crisis,” explains graduate student Paris Smalls. “The freedom to be able to execute on and have your interests come to life has been incredibly rewarding.”

      “If you have a research problem, you can think of the top five people in that particular niche of a topic and they’re either down the hallway or have some association with WHOI,” adds graduate student Samantha Clevenger. “It’s a really incredible place in terms of connections and just having access to really anything you need.”

      Video by: Melanie Gonick/MIT | 5 min, 12 sec More

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      in Energy

      Responsive design meets responsibility for the planet’s future

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      MIT senior Sylas Horowitz kneeled at the edge of a marsh, tinkering with a blue-and-black robot about the size and shape of a shoe box and studded with lights and mini propellers.

      The robot was a remotely operated vehicle (ROV) — an underwater drone slated to collect water samples from beneath a sheet of Arctic ice. But its pump wasn’t working, and its intake line was clogged with sand and seaweed.

      “Of course, something must always go wrong,” Horowitz, a mechanical engineering major with minors in energy studies and environment and sustainability, later blogged about the Falmouth, Massachusetts, field test. By making some adjustments, Horowitz was able to get the drone functioning on site.

      Through a 2020 collaboration between MIT’s Department of Mechanical Engineering and the Woods Hole Oceanographic Institute (WHOI), Horowitz had been assembling and retrofitting the high-performance ROV to measure the greenhouse gases emitted by thawing permafrost.

      The Arctic’s permafrost holds an estimated 1,700 billion metric tons of methane and carbon dioxide — roughly 50 times the amount of carbon tied to fossil fuel emissions in 2019, according to climate research from NASA’s Jet Propulsion Laboratory. WHOI scientists wanted to understand the role the Arctic plays as a greenhouse gas source or sink.

      Horowitz’s ROV would be deployed from a small boat in sub-freezing temperatures to measure carbon dioxide and methane in the water. Meanwhile, a flying drone would sample the air.

      An MIT Student Sustainability Coalition leader and one of the first members of the MIT Environmental Solutions Initiative’s Rapid Response Group, Horowitz has focused on challenges related to clean energy, climate justice, and sustainable development.

      In addition to the ROV, Horowitz has tackled engineering projects through D-Lab, where community partners from around the world work with MIT students on practical approaches to alleviating global poverty. Horowitz worked on fashioning waste bins out of heat-fused recycled plastic for underserved communities in Liberia. Their thesis project, also initiated through D-Lab, is designing and building user-friendly, space- and fuel-efficient firewood cook stoves to improve the lives of women in Santa Catarina Palopó in northern Guatemala.

      Through the Tata-MIT GridEdge Solar Research program, they helped develop flexible, lightweight solar panels to mount on the roofs of street vendors’ e-rickshaws in Bihar, India.

      The thread that runs through Horowitz’s projects is user-centered design that creates a more equitable society. “In the transition to sustainable energy, we want our technology to adapt to the society that we live in,” they say. “Something I’ve learned from the D-Lab projects and also from the ROV project is that when you’re an engineer, you need to understand the societal and political implications of your work, because all of that should get factored into the design.”

      Horowitz describes their personal mission as creating systems and technology that “serve the well-being and longevity of communities and the ecosystems we exist within.

      “I want to relate mechanical engineering to sustainability and environmental justice,” they say. “Engineers need to think about how technology fits into the greater societal context of people in the environment. We want our technology to adapt to the society we live in and for people to be able, based on their needs, to interface with the technology.”

      Imagination and inspiration

      In Dix Hills, New York, a Long Island suburb, Horowitz’s dad is in banking and their mom is a speech therapist. The family hiked together, but Horowitz doesn’t tie their love for the natural world to any one experience. “I like to play in the dirt,” they say. “I’ve always had a connection to nature. It was a kind of childlike wonder.”

      Seeing footage of the massive 2010 oil spill in the Gulf of Mexico caused by an explosion on the Deepwater Horizon oil rig — which occurred when Horowitz was around 10 — was a jarring introduction to how human activity can impact the health of the planet.

      Their first interest was art — painting and drawing portraits, album covers, and more recently, digital images such as a figure watering a houseplant at a window while lightning flashes outside; a neon pink jellyfish in a deep blue sea; and, for an MIT-wide Covid quarantine project, two figures watching the sun set over a Green Line subway platform.

      Art dovetailed into a fascination with architecture, then shifted to engineering. In high school, Horowitz and a friend were co-captains of an all-girls robotics team. “It was just really wonderful, having this community and being able to build stuff,” they say. Horowitz and another friend on the team learned they were accepted to MIT on Pi Day 2018.

      Art, architecture, engineering — “it’s all kind of the same,” Horowitz says. “I like the creative aspect of design, being able to create things out of imagination.”

      Sustaining political awareness

      At MIT, Horowitz connected with a like-minded community of makers. They also launched themself into taking action against environmental injustice.

      In 2022, through the Student Sustainability Coalition (SSC), they encouraged MIT students to get involved in advocating for the Cambridge Green New Deal, legislation aimed at reducing emissions from new large commercial buildings such as those owned by MIT and creating a green jobs training program.

      In February 2022, Horowitz took part in a sit-in in Building 3 as part of MIT Divest, a student-led initiative urging the MIT administration to divest its endowment of fossil fuel companies.

      “I want to see MIT students more locally involved in politics around sustainability, not just the technology side,” Horowitz says. “I think there’s a lot of power from students coming together. They could be really influential.”

      User-oriented design

      The Arctic underwater ROV Horowitz worked on had to be waterproof and withstand water temperatures as low as 5 degrees Fahrenheit. It was tethered to a computer by a 150-meter-long cable that had to spool and unspool without tangling. The pump and tubing that collected water samples had to work without kinking.

      “It was cool, throughout the project, to think, ‘OK, what kind of needs will these scientists have when they’re out in these really harsh conditions in the Arctic? How can I make a machine that will make their field work easier?’

      “I really like being able to design things directly with the users, working within their design constraints,” they say.

      Inevitably, snafus occurred, but in photos and videos taken the day of the Falmouth field tests, Horowitz is smiling. “Here’s a fun unexpected (or maybe quite expected) occurrence!” they reported later. “The plastic mount for the shaft collar [used in the motor’s power transmission] ripped itself apart!” Undaunted, Horowitz jury-rigged a replacement out of sheet metal.

      Horowitz replaced broken wires in the winch-like device that spooled the cable. They added a filter at the intake to prevent sand and plants from clogging the pump.

      With a few more tweaks, the ROV was ready to descend into frigid waters. Last summer, it was successfully deployed on a field run in the Canadian high Arctic. A few months later, Horowitz was slated to attend OCEANS 2022 Hampton Roads, their first professional conference, to present a poster on their contribution to the WHOI permafrost research.

      Ultimately, Horowitz hopes to pursue a career in renewable energy, sustainable design, or sustainable agriculture, or perhaps graduate studies in data science or econometrics to quantify environmental justice issues such as the disproportionate exposure to pollution among certain populations and the effect of systemic changes designed to tackle these issues.

      After completing their degree this month, Horowitz will spend six months with MIT International Science and Technology Initiatives (MISTI), which fosters partnerships with industry leaders and host organizations around the world.

      Horowitz is thinking of working with a renewable energy company in Denmark, one of the countries they toured during a summer 2019 field trip led by the MIT Energy Initiative’s Director of Education Antje Danielson. They were particularly struck by Samsø, the world’s first carbon-neutral island, run entirely on renewable energy. “It inspired me to see what’s out there when I was a sophomore,” Horowitz says. They’re ready to see where inspiration takes them next.

      This article appears in the Winter 2023 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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      in Environment

      Rescuing small plastics from the waste stream

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      As plastic pollution continues to mount, with growing risks to ecosystems and wildlife, manufacturers are beginning to make ambitious commitments to keep new plastics out of the environment. A growing number have signed onto the U.S. Plastics Pact, which pledges to make 100 percent of plastic packaging reusable, recyclable, or compostable, and to see 50 percent of it effectively recycled or composted, by 2025.

      But for companies that make large numbers of small, disposable plastics, these pocket-sized objects are a major barrier to realizing their recycling goals.

      “Think about items like your toothbrush, your travel-size toothpaste tubes, your travel-size shampoo bottles,” says Alexis Hocken, a second-year PhD student in the MIT Department of Chemical Engineering. “They end up actually slipping through the cracks of current recycling infrastructure. So you might put them in your recycling bin at home, they might make it all the way to the sorting facility, but when it comes down to actually sorting them, they never make it into a recycled plastic bale at the very end of the line.”

      Now, a group of five consumer products companies is working with MIT to develop a sorting process that can keep their smallest plastic products inside the recycling chain. The companies — Colgate-Palmolive, Procter & Gamble, the Estée Lauder Companies, L’Oreal, and Haleon — all manufacture a large volume of “small format” plastics, or products less than two inches long in at least two dimensions. In a collaboration with Brad Olsen, the Alexander and I. Michael Kasser (1960) Professor of Chemical Engineering; Desiree Plata, an associate professor of civil and environmental engineering; the MIT Environmental Solutions Initiative; and the nonprofit The Sustainability Consortium, these companies are seeking a prototype sorting technology to bring to recycling facilities for large-scale testing and commercial development.

      Working in Olsen’s lab, Hocken is coming to grips with the complexity of the recycling systems involved. Material recovery facilities, or MRFs, are expected to handle products in any number of shapes, sizes, and materials, and sort them into a pure stream of glass, metal, paper, or plastic. Hocken’s first step in taking on the recycling project was to tour one of these MRFs in Portland, Maine, with Olsen and Plata.

      “We could literally see plastics just falling from the conveyor belts,” she says. “Leaving that tour, I thought, my gosh! There’s so much improvement that can be made. There’s so much impact that we can have on this industry.”

      From designing plastics to managing them

      Hocken always knew she wanted to work in engineering. Growing up in Scottsdale, Arizona, she was able to spend time in the workplace with her father, an electrical engineer who designs biomedical devices. “Seeing him working as an engineer, and how he’s solving these really important problems, definitely sparked my interest,” she says. “When it came time to begin my undergraduate degree, it was a really easy decision to choose engineering after seeing the day-to-day that my dad was doing in his career.”

      At Arizona State University, she settled on chemical engineering as a major and began working with polymers, coming up with combinations of additives for 3D plastics printing that could help fine-tune how the final products behaved. But even working with plastics every day, she rarely thought about the implications of her work for the environment.

      “And then in the spring of my final year at ASU, I took a class about polymers through the lens of sustainability, and that really opened my eyes,” Hocken remembers. The class was taught by Professor Timothy Long, director of the Biodesign Center for Sustainable Macromolecular Materials and Manufacturing and a well-known expert in the field of sustainable plastics. “That first session, where he laid out all of the really scary facts surrounding the plastics crisis, got me very motivated to look more into that field.”

      At MIT the next year, Hocken sought out Olsen as her advisor and made plastics sustainability her focus from the start.

      “Coming to MIT was my first time venturing outside of the state of Arizona for more than a three-month period,” she says. “It’s been really fun. I love living in Cambridge and the Boston area. I love my labmates. Everyone is so supportive, whether it’s to give me advice about some science that I’m trying to figure out, or just give me a pep talk if I’m feeling a little discouraged.”

      A challenge to recycle

      A lot of plastics research today is devoted to creating new materials — including biodegradable ones that are easier for natural ecosystems to absorb, and highly recyclable ones that hold their properties better after being melted down and recast.

      But Hocken also sees a huge need for better ways to handle the plastics we’re already making. “While biodegradable and sustainable polymers represent a very important route, and I think they should certainly be further pursued, we’re still a ways away from that being a reality universally across all plastic packaging,” she says. As long as large volumes of conventional plastic are coming out of factories, we’ll need innovative ways to stop it from piling onto the mountain of plastic pollution. In one of her projects, Hocken is trying to come up with new uses for recycled plastic that take advantage of its lost strength to produce a useful, flexible material similar to rubber.

      The small-format recycling project also falls in this category. The companies supporting the project have challenged the MIT team to work with their products exactly as currently manufactured — especially because their competitors use similar packaging materials that will also need to be covered by any solution the MIT team devises.

      The challenge is a large one. To kick the project off, the participating companies sent the MIT team a wide range of small-format products that need to make it through the sorting process. These include containers for lip balm, deodorant, pills, and shampoo, and disposable tools like toothbrushes and flossing picks. “A constraint, or problem I foresee, is just how variable the shapes are,” says Hocken. “A flossing pick versus a toothbrush are very different shapes.”

      Nor are they all made of the same kind of plastic. Many are made of polyethylene terephthalate (PET, type 1 in the recycling label system) or high-density polyethylene (HDPE, type 2), but nearly all of the seven recycling categories are represented among the sample products. The team’s solution will have to handle them all.

      Another obstacle is that the sorting process at a large MRF is already very complex and requires a heavy investment in equipment. The waste stream typically goes through a “glass breaker screen” that shatters glass and collects the shards; a series of rotating rubber stars to pull out two-dimensional objects, collecting paper and cardboard; a system of magnets and eddy currents to attract or repel different metals; and finally, a series of optical sorters that use infrared spectroscopy to identify the various types of plastics, then blow them down different chutes with jets of air. MRFs won’t be interested in adopting additional sorters unless they’re inexpensive and easy to fit into this elaborate stream.

      “We’re interested in creating something that could be retrofitted into current technology and current infrastructure,” Hocken says.

      Shared solutions

      “Recycling is a really good example of where pre-competitive collaboration is needed,” says Jennifer Park, collective action manager at The Sustainability Consortium (TSC), who has been working with corporate stakeholders on small format recyclability and helped convene the sponsors of this project and organize their contributions. “Companies manufacturing these products recognize that they cannot shift entire systems on their own. Consistency around what is and is not recyclable is the only way to avoid confusion and drive impact at scale.

      “Additionally, it is interesting that consumer packaged goods companies are sponsoring this research at MIT which is focused on MRF-level innovations. They’re investing in innovations that they hope will be adopted by the recycling industry to make progress on their own sustainability goals.”

      Hocken believes that, despite the challenges, it’s well worth pursuing a technology that can keep small-format plastics from slipping through MRFs’ fingers.

      “These are products that would be more recyclable if they were easier to sort,” she says. “The only thing that’s different is the size. So you can recycle both your large shampoo bottle and the small travel-size one at home, but the small one isn’t guaranteed to make it into a plastic bale at the end. If we can come up with a solution that specifically targets those while they’re still on the sorting line, they’re more likely to end up in those plastic bales at the end of the line, which can be sold to plastic reclaimers who can then use that material in new products.”

      “TSC is really excited about this project and our collaboration with MIT,” adds Park. “Our project stakeholders are very dedicated to finding a solution.”

      To learn more about this project, contact Christopher Noble, director of corporate engagement at the MIT Environmental Solutions Initiative. More

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      in Environment

      MIT Solve announces 2023 global challenges and Indigenous Communities Fellowship

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      MIT Solve, an MIT initiative with a mission to drive innovation to solve world challenges, announced today the 2023 Global Challenges and the Indigenous Communities Fellowship. 

      Solve invites anyone from anywhere in the world to submit a solution to this year’s challenges by 12 p.m. EST on May 9. The 40 innovators — including eight new Indigenous Communities Fellows — will form the 2023 Solver Class, and pitch their solutions during Solve Challenge Finals on Sept. 17-18 in New York City. These selected teams will share over $1 million in available funding, take part in a nine-month support program, and join the Solve community made of cross-sector social impact leaders, to scale their solutions.

      Solve’s 2023 Global Challenges are: 

      For its second year, Solve will select a cohort of entrepreneurs among the 2023 Solver Class to join the Black and Brown Innovators in the U.S. Program. The program offers culturally-responsive support and partnership opportunities, and selected teams will participate in Solve’s annual U.S. Equity Summit. 

      In addition to the Global Challenges, Solve is also opening applications for the 2023 Indigenous Communities Fellowship. The fellowship, which looks for Native innovators in the United States and its territories, has now expanded eligibility to Canada. 

      “Every year we are inspired by people’s ingenuity and their determination to solve the most pressing issues of our time,” says Hala Hanna, acting executive director of MIT Solve. “We are excited to shine a spotlight on the most promising ones and grateful for our supporters who will help scale their impact.”

      Interested applicants can learn more and apply online at solve.mit.edu/challenges. 

      To date, the funding available for selected Solver teams and fellows includes:

      MIT Solve Funding — $400,000 with a $10,000 grant to each Solver team and fellow selected
      The GM Prize (supported by General Motors) — up to $150,000 across up to six solutions from the Learning for Civic Action Challenge, the Climate Adaptation & Low-Carbon Housing Challenge, and the 2023 Indigenous Communities Fellowship
      The AI for Humanity Prize (supported by The Patrick J. McGovern Foundation) — up to $150,000 to solutions that leverage data science, artificial intelligence, and/or machine learning to benefit humanity, selected from any of the 2023 Global Challenges
      The GSR Foundation Prize (supported by GSR Foundation) — up to $200,000 to innovative technology solutions from any of the 2023 Global Challenges, with a focus on solutions that use blockchain to improve financial inclusion
      Living Forests Prize (supported by Good Energies Foundation) — up to $100,000 across up to four solutions that help restore ecosystems or increase the use of sustainable forest products, selected from the Climate Adaptation & Low-Carbon Housing Challenge
      Those interested in sponsoring a prize should contact sue.kim@solve.mit.edu.

      Additionally, Solve Innovation Future will offer investment capital to Solver teams selected as a part of the 2023 class. To date, Solve Innovation Future has deployed over $1.3 million to more than 13 for-profit Solver team companies that are driving impact toward UN Sustainable Development Goals, and has catalyzed nearly seven times its investment in additional investment capital toward the Solver teams.

      The Solve community will convene on MIT’s campus for its flagship event Solve at MIT May 4-6 to celebrate the 2022 Solver Class. You may request an invitation here. Press interested in attending the event should contact maya.bingaman@solve.mit.edu. 

      Solve is a marketplace for social impact innovation. Through open innovation challenges, Solve finds incredible tech-based social entrepreneurs all around the world. Solve then brings together MIT’s innovation ecosystem and a community of members to fund and support these entrepreneurs to drive lasting, transformational impact. Solve has catalyzed over $60 million in commitments for Solver teams and entrepreneurs to date. More

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      in Energy

      To decarbonize the chemical industry, electrify it

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      The chemical industry is the world’s largest industrial energy consumer and the third-largest source of industrial emissions, according to the International Energy Agency. In 2019, the industrial sector as a whole was responsible for 24 percent of global greenhouse gas emissions. And yet, as the world races to find pathways to decarbonization, the chemical industry has been largely untouched.

      “When it comes to climate action and dealing with the emissions that come from the chemical sector, the slow pace of progress is partly technical and partly driven by the hesitation on behalf of policymakers to overly impact the economic competitiveness of the sector,” says Dharik Mallapragada, a principal research scientist at the MIT Energy Initiative.

      With so many of the items we interact with in our daily lives — from soap to baking soda to fertilizer — deriving from products of the chemical industry, the sector has become a major source of economic activity and employment for many nations, including the United States and China. But as the global demand for chemical products continues to grow, so do the industry’s emissions.

      New sustainable chemical production methods need to be developed and deployed and current emission-intensive chemical production technologies need to be reconsidered, urge the authors of a new paper published in Joule. Researchers from DC-MUSE, a multi-institution research initiative, argue that electrification powered by low-carbon sources should be viewed more broadly as a viable decarbonization pathway for the chemical industry. In this paper, they shine a light on different potential methods to do just that.

      “Generally, the perception is that electrification can play a role in this sector — in a very narrow sense — in that it can replace fossil fuel combustion by providing the heat that the combustion is providing,” says Mallapragada, a member of DC-MUSE. “What we argue is that electrification could be much more than that.”

      The researchers outline four technological pathways — ranging from more mature, near-term options to less technologically mature options in need of research investment — and present the opportunities and challenges associated with each.

      The first two pathways directly replace fossil fuel-produced heat (which facilitates the reactions inherent in chemical production) with electricity or electrochemically generated hydrogen. The researchers suggest that both options could be deployed now and potentially be used to retrofit existing facilities. Electrolytic hydrogen is also highlighted as an opportunity to replace fossil fuel-produced hydrogen (a process that emits carbon dioxide) as a critical chemical feedstock. In 2020, fossil-based hydrogen supplied nearly all hydrogen demand (90 megatons) in the chemical and refining industries — hydrogen’s largest consumers.

      The researchers note that increasing the role of electricity in decarbonizing the chemical industry will directly affect the decarbonization of the power grid. They stress that to successfully implement these technologies, their operation must coordinate with the power grid in a mutually beneficial manner to avoid overburdening it. “If we’re going to be serious about decarbonizing the sector and relying on electricity for that, we have to be creative in how we use it,” says Mallapragada. “Otherwise we run the risk of having addressed one problem, while creating a massive problem for the grid in the process.”

      Electrified processes have the potential to be much more flexible than conventional fossil fuel-driven processes. This can reduce the cost of chemical production by allowing producers to shift electricity consumption to times when the cost of electricity is low. “Process flexibility is particularly impactful during stressed power grid conditions and can help better accommodate renewable generation resources, which are intermittent and are often poorly correlated with daily power grid cycles,” says Yury Dvorkin, an associate research professor at the Johns Hopkins Ralph O’Connor Sustainable Energy Institute. “It’s beneficial for potential adopters because it can help them avoid consuming electricity during high-price periods.”

      Dvorkin adds that some intermediate energy carriers, such as hydrogen, can potentially be used as highly efficient energy storage for day-to-day operations and as long-term energy storage. This would help support the power grid during extreme events when traditional and renewable generators may be unavailable. “The application of long-duration storage is of particular interest as this is a key enabler of a low-emissions society, yet not widespread beyond pumped hydro units,” he says. “However, as we envision electrified chemical manufacturing, it is important to ensure that the supplied electricity is sourced from low-emission generators to prevent emissions leakages from the chemical to power sector.” 

      The next two pathways introduced — utilizing electrochemistry and plasma — are less technologically mature but have the potential to replace energy- and carbon-intensive thermochemical processes currently used in the industry. By adopting electrochemical processes or plasma-driven reactions instead, chemical transformations can occur at lower temperatures and pressures, potentially enhancing efficiency. “These reaction pathways also have the potential to enable more flexible, grid-responsive plants and the deployment of modular manufacturing plants that leverage distributed chemical feedstocks such as biomass waste — further enhancing sustainability in chemical manufacturing,” says Miguel Modestino, the director of the Sustainable Engineering Initiative at the New York University Tandon School of Engineering.

      A large barrier to deep decarbonization of chemical manufacturing relates to its complex, multi-product nature. But, according to the researchers, each of these electricity-driven pathways supports chemical industry decarbonization for various feedstock choices and end-of-life disposal decisions. Each should be evaluated in comprehensive techno-economic and environmental life cycle assessments to weigh trade-offs and establish suitable cost and performance metrics.

      Regardless of the pathway chosen, the researchers stress the need for active research and development and deployment of these technologies. They also emphasize the importance of workforce training and development running in parallel to technology development. As André Taylor, the director of DC-MUSE, explains, “There is a healthy skepticism in the industry regarding electrification and adoption of these technologies, as it involves processing chemicals in a new way.” The workforce at different levels of the industry hasn’t necessarily been exposed to ideas related to the grid, electrochemistry, or plasma. The researchers say that workforce training at all levels will help build greater confidence in these different solutions and support customer-driven industry adoption.

      “There’s no silver bullet, which is kind of the standard line with all climate change solutions,” says Mallapragada. “Each option has pros and cons, as well as unique advantages. But being aware of the portfolio of options in which you can use electricity allows us to have a better chance of success and of reducing emissions — and doing so in a way that supports grid decarbonization.”

      This work was supported, in part, by the Alfred P. Sloan Foundation. More

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      in Environment

      Preparing to be prepared

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      The Kobe earthquake of 1995 devastated one of Japan’s major cities, leaving over 6,000 people dead while destroying or making unusable hundreds of thousands of structures. It toppled elevated freeway segments, wrecked mass transit systems, and damaged the city’s port capacity.

      “It was a shock to a highly engineered, urban city to have undergone that much destruction,” says Miho Mazereeuw, an associate professor at MIT who specializes in disaster resilience.

      Even in a country like Japan, with advanced engineering, and policies in place to update safety codes, natural forces can overwhelm the built environment.

      “There’s nothing that’s ever guaranteed safe,” says Mazereeuw, an associate professor of architecture and urbanism in MIT’s Department of Architecture and director of the Urban Risk Lab. “We [think that] through technology and engineering we can solve things and fight nature. Whereas it’s really that we’re living with nature. We’re part of this natural ecosystem.”

      That’s why Mazereeuw’s work on disaster resilience focuses on plans, people, and policies, well as technology and design to prepare for the future. In the Urban Risk Lab, which Mazereeuw founded, several projects are based on the design of physical objects, spaces, and software platforms, but many others involve community-level efforts, so that local governments have workable procedures in case of emergency.

      “What we can do for ourselves and each other is have plans in place so that if something does happen, the level of chaos and fear can be reduced and we can all be there to help each other through,” Mazereeuw says. When it comes to disaster preparedness, she adds, “Definitely a lot of it is on the built environment side of things, but a lot of it is also social, making sure that in our communities, we know who would need help, and we have those kinds of relationships beforehand.”

      The Kobe earthquake was a highly influential event for Mazereeuw. She has researched the response to it and has a book coming out about natural disasters, policies, and design in Japan. Beyond that, the Kobe event helped reinforce her sense that when it comes to disaster preparedness, progress can be made many ways. For her research, teaching, and innovative work at the Urban Risk Lab, Mazereeuw was granted tenure at MIT last year.

      Two cultures grappling with nature

      Mazereeuw has one Dutch parent and one Japanese parent, and both cultures helped produce her interest in managing natural forces. On her Dutch side, many family friends were involved with local government and water management — practically an existential issue in a country that sits largely below sea level.

      Mazereeuw’s parents, however, were living in Japan in 1995. And while they happened to be away while the Kobe earthquake hit, her Japanese links helped spur her interest in studying the event and its aftermath.

      “I think that was a wake-up call for me, too, about how we need to plan and design cities to reduce the impact of chaos at the time of disasters,” Mazereeuw says.

      Mazereeuw earned her undergraduate degree from Wesleyan University, majoring in earth and environmental sciences and in studio art. After working in an architectural office in Tokyo, she decided to attend graduate school, receiving her dual masters from Harvard University’s Graduate School of Design, with a thesis about Kobe and disaster readiness. She then worked in architecture offices, including the Office of Metropolitan Architecture in Rotterdam, but returned to academia to work on climate change and disaster resilience.   

      Mazereeuw’s book, “Design Before Disaster,” explores this subject in depth, from urban planning to coastal-safety strategies to community-based design frameworks, and is forthcoming from the University of Virginia Press.

      Since joining the MIT faculty, Mazereeuw has also devoted significant time to the launch and growth of the Urban Risk Lab, an interdisciplinary group working on an array of disaster-preparedness efforts. One such project has seen lab members work with local officials from many places — including Massachusetts, California, Georgia, and Puerto Rico — to add to their own disaster-preparedness planning.

      A plan developed by local officials with community input, Mazereeuw suggests, will likely function better than one produced by, say, consultants from outside a community, as she has seen happen many times: “A report on a dusty shelf isn’t actionable,” she says. “This way it’s a decision-making process by the people involved.”

      In a project based on physical design, the Urban Risk Lab has also been working with the U.S. Federal Emergency Management Agency on an effort to produce temporary postdisaster housing for the OCONUS region (Alaska, Hawaii, and other U.S. overseas territories). The lab’s design, called SEED (Shelter for Emergency Expansion Design), features a house that is compact enough to be shipped anywhere and unfolds on-site, while being sturdy enough to withstand follow-up events such as hurricanes, and durable enough to be incorporated into longer-term housing designs.

      “We felt it had to be really, really good quality, so it would be a resource, rather than something temporary that disintegrates after five years,” Mazereeuw says. “It’s built to be a small safety shelter but also could be part of a permanent house.”

      A grand challenge, and a plethora of projects

      Mazereeuw is also a co-lead of one of the five multiyear projects selected in 2022 to move forward as part of MIT’s Climate Grand Challenges competition. Along with Kerry Emanuel and Paul O’Gorman, of MIT’s Department of Earth, Atmospheric and Planetary Sciences, Mazereeuw will help direct a project advancing climate modeling by quantifying the risk of extreme weather events for specific locations. The idea is to help vulnerable urban centers and other communities prepare for such events.

      The Urban Risk Lab has many other kinds of projects in its portfolio, following Mazereeuw’s own interest in conceptualizing disaster preparedness broadly. In collaboration with officials in Japan, and with support from Google, lab members worked on interactive, real-time flood-mapping software, in which residents can help officials know where local flooding has reached emergency levels. The researchers also created an AI module to prioritize the information.

      “Residents really have the most localized information, which you can’t get from a satellite,” Mazereeuw says. “They’re also the ones who learn about it first, so they have a lot of information that emergency managers can use for their response. The program is really meant to be a conduit between the efforts of emergency managers and residents, so that information flow can go in both directions.”

      Lab members in the past have also mapped the porosity of the MIT campus, another effort that used firsthand knowledge. Additionally, lab members are currently engaging with a university in Chile to design tsunami response strategies; developing a community mapping toolkit for resilience planning in Thailand and Vietnam; and working with Mass Audubon to design interactive furniture for children to learn about ecology.  

      “Everything is tied together with this interest in raising awareness and engaging people,” Mazereeuw says.

      That also describes Mazereeuw’s attitude about participation in the Urban Risk Lab, a highly cross-disciplinary place with members who have gravitated to it from around MIT.

      “Our lab is extremely interdisciplinary,” Mazereeuw says. “We have students coming in from all over, from different parts of campus. We have computer science and engineering students coming into the lab and staying to get their graduate degrees alongside many architecture and planning students.” The lab also has five full-time researchers — Aditya Barve, Larisa Ovalles, Mayank Ojha, Eakapob Huangthananpan, and Saeko Baird — who lead their own projects and research groups.

      What those lab members have in common is a willingness to think proactively about reducing disaster impacts. Being prepared for those events itself requires preparation.

      Even in the design world, Mazereeuw says, “People are reactive. Because something has happened, that’s when they go in to help. But I think we can have a larger impact by anticipating and designing for these issues beforehand.” More

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      in Energy

      Computers that power self-driving cars could be a huge driver of global carbon emissions

      by

      In the future, the energy needed to run the powerful computers on board a global fleet of autonomous vehicles could generate as many greenhouse gas emissions as all the data centers in the world today.

      That is one key finding of a new study from MIT researchers that explored the potential energy consumption and related carbon emissions if autonomous vehicles are widely adopted.

      The data centers that house the physical computing infrastructure used for running applications are widely known for their large carbon footprint: They currently account for about 0.3 percent of global greenhouse gas emissions, or about as much carbon as the country of Argentina produces annually, according to the International Energy Agency. Realizing that less attention has been paid to the potential footprint of autonomous vehicles, the MIT researchers built a statistical model to study the problem. They determined that 1 billion autonomous vehicles, each driving for one hour per day with a computer consuming 840 watts, would consume enough energy to generate about the same amount of emissions as data centers currently do.

      The researchers also found that in over 90 percent of modeled scenarios, to keep autonomous vehicle emissions from zooming past current data center emissions, each vehicle must use less than 1.2 kilowatts of power for computing, which would require more efficient hardware. In one scenario — where 95 percent of the global fleet of vehicles is autonomous in 2050, computational workloads double every three years, and the world continues to decarbonize at the current rate — they found that hardware efficiency would need to double faster than every 1.1 years to keep emissions under those levels.

      “If we just keep the business-as-usual trends in decarbonization and the current rate of hardware efficiency improvements, it doesn’t seem like it is going to be enough to constrain the emissions from computing onboard autonomous vehicles. This has the potential to become an enormous problem. But if we get ahead of it, we could design more efficient autonomous vehicles that have a smaller carbon footprint from the start,” says first author Soumya Sudhakar, a graduate student in aeronautics and astronautics.

      Sudhakar wrote the paper with her co-advisors Vivienne Sze, associate professor in the Department of Electrical Engineering and Computer Science (EECS) and a member of the Research Laboratory of Electronics (RLE); and Sertac Karaman, associate professor of aeronautics and astronautics and director of the Laboratory for Information and Decision Systems (LIDS). The research appears today in the January-February issue of IEEE Micro.

      Modeling emissions

      The researchers built a framework to explore the operational emissions from computers on board a global fleet of electric vehicles that are fully autonomous, meaning they don’t require a back-up human driver.

      The model is a function of the number of vehicles in the global fleet, the power of each computer on each vehicle, the hours driven by each vehicle, and the carbon intensity of the electricity powering each computer.

      “On its own, that looks like a deceptively simple equation. But each of those variables contains a lot of uncertainty because we are considering an emerging application that is not here yet,” Sudhakar says.

      For instance, some research suggests that the amount of time driven in autonomous vehicles might increase because people can multitask while driving and the young and the elderly could drive more. But other research suggests that time spent driving might decrease because algorithms could find optimal routes that get people to their destinations faster.

      In addition to considering these uncertainties, the researchers also needed to model advanced computing hardware and software that doesn’t exist yet.

      To accomplish that, they modeled the workload of a popular algorithm for autonomous vehicles, known as a multitask deep neural network because it can perform many tasks at once. They explored how much energy this deep neural network would consume if it were processing many high-resolution inputs from many cameras with high frame rates, simultaneously.

      When they used the probabilistic model to explore different scenarios, Sudhakar was surprised by how quickly the algorithms’ workload added up.

      For example, if an autonomous vehicle has 10 deep neural networks processing images from 10 cameras, and that vehicle drives for one hour a day, it will make 21.6 million inferences each day. One billion vehicles would make 21.6 quadrillion inferences. To put that into perspective, all of Facebook’s data centers worldwide make a few trillion inferences each day (1 quadrillion is 1,000 trillion).

      “After seeing the results, this makes a lot of sense, but it is not something that is on a lot of people’s radar. These vehicles could actually be using a ton of computer power. They have a 360-degree view of the world, so while we have two eyes, they may have 20 eyes, looking all over the place and trying to understand all the things that are happening at the same time,” Karaman says.

      Autonomous vehicles would be used for moving goods, as well as people, so there could be a massive amount of computing power distributed along global supply chains, he says. And their model only considers computing — it doesn’t take into account the energy consumed by vehicle sensors or the emissions generated during manufacturing.

      Keeping emissions in check

      To keep emissions from spiraling out of control, the researchers found that each autonomous vehicle needs to consume less than 1.2 kilowatts of energy for computing. For that to be possible, computing hardware must become more efficient at a significantly faster pace, doubling in efficiency about every 1.1 years.

      One way to boost that efficiency could be to use more specialized hardware, which is designed to run specific driving algorithms. Because researchers know the navigation and perception tasks required for autonomous driving, it could be easier to design specialized hardware for those tasks, Sudhakar says. But vehicles tend to have 10- or 20-year lifespans, so one challenge in developing specialized hardware would be to “future-proof” it so it can run new algorithms.

      In the future, researchers could also make the algorithms more efficient, so they would need less computing power. However, this is also challenging because trading off some accuracy for more efficiency could hamper vehicle safety.

      Now that they have demonstrated this framework, the researchers want to continue exploring hardware efficiency and algorithm improvements. In addition, they say their model can be enhanced by characterizing embodied carbon from autonomous vehicles — the carbon emissions generated when a car is manufactured — and emissions from a vehicle’s sensors.

      While there are still many scenarios to explore, the researchers hope that this work sheds light on a potential problem people may not have considered.

      “We are hoping that people will think of emissions and carbon efficiency as important metrics to consider in their designs. The energy consumption of an autonomous vehicle is really critical, not just for extending the battery life, but also for sustainability,” says Sze.

      This research was funded, in part, by the National Science Foundation and the MIT-Accenture Fellowship. More