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      New England renewables + Canadian hydropower

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      The urgent need to cut carbon emissions has prompted a growing number of U.S. states to commit to achieving 100 percent clean electricity by 2040 or 2050. But figuring out how to meet those commitments and still have a reliable and affordable power system is a challenge. Wind and solar installations will form the backbone of a carbon-free power system, but what technologies can meet electricity demand when those intermittent renewable sources are not adequate?

      In general, the options being discussed include nuclear power, natural gas with carbon capture and storage (CCS), and energy storage technologies such as new and improved batteries and chemical storage in the form of hydrogen. But in the northeastern United States, there is one more possibility being proposed: electricity imported from hydropower plants in the neighboring Canadian province of Quebec.

      The proposition makes sense. Those plants can produce as much electricity as about 40 large nuclear power plants, and some power generated in Quebec already comes to the Northeast. So, there could be abundant additional supply to fill any shortfall when New England’s intermittent renewables underproduce. However, U.S. wind and solar investors view Canadian hydropower as a competitor and argue that reliance on foreign supply discourages further U.S. investment.

      Two years ago, three researchers affiliated with the MIT Center for Energy and Environmental Policy Research (CEEPR) — Emil Dimanchev SM ’18, now a PhD candidate at the Norwegian University of Science and Technology; Joshua Hodge, CEEPR’s executive director; and John Parsons, a senior lecturer in the MIT Sloan School of Management — began wondering whether viewing Canadian hydro as another source of electricity might be too narrow. “Hydropower is a more-than-hundred-year-old technology, and plants are already built up north,” says Dimanchev. “We might not need to build something new. We might just need to use those plants differently or to a greater extent.”

      So the researchers decided to examine the potential role and economic value of Quebec’s hydropower resource in a future low-carbon system in New England. Their goal was to help inform policymakers, utility decision-makers, and others about how best to incorporate Canadian hydropower into their plans and to determine how much time and money New England should spend to integrate more hydropower into its system. What they found out was surprising, even to them.

      The analytical methods

      To explore possible roles for Canadian hydropower to play in New England’s power system, the MIT researchers first needed to predict how the regional power system might look in 2050 — both the resources in place and how they would be operated, given any policy constraints. To perform that analysis, they used GenX, a modeling tool originally developed by Jesse Jenkins SM ’14, PhD ’18 and Nestor Sepulveda SM ’16, PhD ’20 while they were researchers at the MIT Energy Initiative (MITEI).

      The GenX model is designed to support decision-making related to power system investment and real-time operation and to examine the impacts of possible policy initiatives on those decisions. Given information on current and future technologies — different kinds of power plants, energy storage technologies, and so on — GenX calculates the combination of equipment and operating conditions that can meet a defined future demand at the lowest cost. The GenX modeling tool can also incorporate specified policy constraints, such as limits on carbon emissions.

      For their study, Dimanchev, Hodge, and Parsons set parameters in the GenX model using data and assumptions derived from a variety of sources to build a representation of the interconnected power systems in New England, New York, and Quebec. (They included New York to account for that state’s existing demand on the Canadian hydro resources.) For data on the available hydropower, they turned to Hydro-Québec, the public utility that owns and operates most of the hydropower plants in Quebec.

      It’s standard in such analyses to include real-world engineering constraints on equipment, such as how quickly certain power plants can be ramped up and down. With help from Hydro-Québec, the researchers also put hour-to-hour operating constraints on the hydropower resource.

      Most of Hydro-Québec’s plants are “reservoir hydropower” systems. In them, when power isn’t needed, the flow on a river is restrained by a dam downstream of a reservoir, and the reservoir fills up. When power is needed, the dam is opened, and the water in the reservoir runs through downstream pipes, turning turbines and generating electricity. Proper management of such a system requires adhering to certain operating constraints. For example, to prevent flooding, reservoirs must not be allowed to overfill — especially prior to spring snowmelt. And generation can’t be increased too quickly because a sudden flood of water could erode the river edges or disrupt fishing or water quality.

      Based on projections from the National Renewable Energy Laboratory and elsewhere, the researchers specified electricity demand for every hour of the year 2050, and the model calculated the cost-optimal mix of technologies and system operating regime that would satisfy that hourly demand, including the dispatch of the Hydro-Québec hydropower system. In addition, the model determined how electricity would be traded among New England, New York, and Quebec.

      Effects of decarbonization limits on technology mix and electricity trading

      To examine the impact of the emissions-reduction mandates in the New England states, the researchers ran the model assuming reductions in carbon emissions between 80 percent and 100 percent relative to 1990 levels. The results of those runs show that, as emissions limits get more stringent, New England uses more wind and solar and extends the lifetime of its existing nuclear plants. To balance the intermittency of the renewables, the region uses natural gas plants, demand-side management, battery storage (modeled as lithium-ion batteries), and trading with Quebec’s hydropower-based system. Meanwhile, the optimal mix in Quebec is mostly composed of existing hydro generation. Some solar is added, but new reservoirs are built only if renewable costs are assumed to be very high.

      The most significant — and perhaps surprising — outcome is that in all the scenarios, the hydropower-based system of Quebec is not only an exporter but also an importer of electricity, with the direction of flow on the Quebec-New England transmission lines changing over time.

      Historically, energy has always flowed from Quebec to New England. The model results for 2018 show electricity flowing from north to south, with the quantity capped by the current transmission capacity limit of 2,225 megawatts (MW).

      An analysis for 2050, assuming that New England decarbonizes 90 percent and the capacity of the transmission lines remains the same, finds electricity flows going both ways. Flows from north to south still dominate. But for nearly 3,500 of the 8,760 hours of the year, electricity flows in the opposite direction — from New England to Quebec. And for more than 2,200 of those hours, the flow going north is at the maximum the transmission lines can carry.

      The direction of flow is motivated by economics. When renewable generation is abundant in New England, prices are low, and it’s cheaper for Quebec to import electricity from New England and conserve water in its reservoirs. Conversely, when New England’s renewables are scarce and prices are high, New England imports hydro-generated electricity from Quebec.

      So rather than delivering electricity, Canadian hydro provides a means of storing the electricity generated by the intermittent renewables in New England.

      “We see this in our modeling because when we tell the model to meet electricity demand using these resources, the model decides that it is cost-optimal to use the reservoirs to store energy rather than anything else,” says Dimanchev. “We should be sending the energy back and forth, so the reservoirs in Quebec are in essence a battery that we use to store some of the electricity produced by our intermittent renewables and discharge it when we need it.”

      Given that outcome, the researchers decided to explore the impact of expanding the transmission capacity between New England and Quebec. Building transmission lines is always contentious, but what would be the impact if it could be done?

      Their model results shows that when transmission capacity is increased from 2,225 MW to 6,225 MW, flows in both directions are greater, and in both cases the flow is at the new maximum for more than 1,000 hours.

      Results of the analysis thus confirm that the economic response to expanded transmission capacity is more two-way trading. To continue the battery analogy, more transmission capacity to and from Quebec effectively increases the rate at which the battery can be charged and discharged.

      Effects of two-way trading on the energy mix

      What impact would the advent of two-way trading have on the mix of energy-generating sources in New England and Quebec in 2050?

      Assuming current transmission capacity, in New England, the change from one-way to two-way trading increases both wind and solar power generation and to a lesser extent nuclear; it also decreases the use of natural gas with CCS. The hydro reservoirs in Canada can provide long-duration storage — over weeks, months, and even seasons — so there is less need for natural gas with CCS to cover any gaps in supply. The level of imports is slightly lower, but now there are also exports. Meanwhile, in Quebec, two-way trading reduces solar power generation, and the use of wind disappears. Exports are roughly the same, but now there are imports as well. Thus, two-way trading reallocates renewables from Quebec to New England, where it’s more economical to install and operate solar and wind systems.

      Another analysis examined the impact on the energy mix of assuming two-way trading plus expanded transmission capacity. For New England, greater transmission capacity allows wind, solar, and nuclear to expand further; natural gas with CCS all but disappears; and both imports and exports increase significantly. In Quebec, solar decreases still further, and both exports and imports of electricity increase.

      Those results assume that the New England power system decarbonizes by 99 percent in 2050 relative to 1990 levels. But at 90 percent and even 80 percent decarbonization levels, the model concludes that natural gas capacity decreases with the addition of new transmission relative to the current transmission scenario. Existing plants are retired, and new plants are not built as they are no longer economically justified. Since natural gas plants are the only source of carbon emissions in the 2050 energy system, the researchers conclude that the greater access to hydro reservoirs made possible by expanded transmission would accelerate the decarbonization of the electricity system.

      Effects of transmission changes on costs

      The researchers also explored how two-way trading with expanded transmission capacity would affect costs in New England and Quebec, assuming 99 percent decarbonization in New England. New England’s savings on fixed costs (investments in new equipment) are largely due to a decreased need to invest in more natural gas with CCS, and its savings on variable costs (operating costs) are due to a reduced need to run those plants. Quebec’s savings on fixed costs come from a reduced need to invest in solar generation. The increase in cost — borne by New England — reflects the construction and operation of the increased transmission capacity. The net benefit for the region is substantial.

      Thus, the analysis shows that everyone wins as transmission capacity increases — and the benefit grows as the decarbonization target tightens. At 99 percent decarbonization, the overall New England-Quebec region pays about $21 per megawatt-hour (MWh) of electricity with today’s transmission capacity but only $18/MWh with expanded transmission. Assuming 100 percent reduction in carbon emissions, the region pays $29/MWh with current transmission capacity and only $22/MWh with expanded transmission.

      Addressing misconceptions

      These results shed light on several misconceptions that policymakers, supporters of renewable energy, and others tend to have.

      The first misconception is that the New England renewables and Canadian hydropower are competitors. The modeling results instead show that they’re complementary. When the power systems in New England and Quebec work together as an integrated system, the Canadian reservoirs are used part of the time to store the renewable electricity. And with more access to hydropower storage in Quebec, there’s generally more renewable investment in New England.

      The second misconception arises when policymakers refer to Canadian hydro as a “baseload resource,” which implies a dependable source of electricity — particularly one that supplies power all the time. “Our study shows that by viewing Canadian hydropower as a baseload source of electricity — or indeed a source of electricity at all — you’re not taking full advantage of what that resource can provide,” says Dimanchev. “What we show is that Quebec’s reservoir hydro can provide storage, specifically for wind and solar. It’s a solution to the intermittency problem that we foresee in carbon-free power systems for 2050.”

      While the MIT analysis focuses on New England and Quebec, the researchers believe that their results may have wider implications. As power systems in many regions expand production of renewables, the value of storage grows. Some hydropower systems have storage capacity that has not yet been fully utilized and could be a good complement to renewable generation. Taking advantage of that capacity can lower the cost of deep decarbonization and help move some regions toward a decarbonized supply of electricity.

      This research was funded by the MIT Center for Energy and Environmental Policy Research, which is supported in part by a consortium of industry and government associates.

      This article appears in the Autumn 2021 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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      Finding the questions that guide MIT fusion research

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      “One of the things I learned was, doing good science isn’t so much about finding the answers as figuring out what the important questions are.”

      As Martin Greenwald retires from the responsibilities of senior scientist and deputy director of the MIT Plasma Science and Fusion Center (PSFC), he reflects on his almost 50 years of science study, 43 of them as a researcher at MIT, pursuing the question of how to make the carbon-free energy of fusion a reality.

      Most of Greenwald’s important questions about fusion began after graduating from MIT with a BS in both physics and chemistry. Beginning graduate work at the University of California at Berkeley, he felt compelled to learn more about fusion as an energy source that could have “a real societal impact.” At the time, researchers were exploring new ideas for devices that could create and confine fusion plasmas. Greenwald worked on Berkeley’s “alternate concept” TORMAC, a Toroidal Magnetic Cusp. “It didn’t work out very well,” he laughs. “The first thing I was known for was making the measurements that shut down the program.”

      Believing the temperature of the plasma generated by the device would not be as high as his group leader expected, Greenwald developed hardware that could measure the low temperatures predicted by his own “back of the envelope calculations.” As he anticipated, his measurements showed that “this was not a fusion plasma; this was hardly a confined plasma at all.”

      With a PhD from Berkeley, Greenwald returned to MIT for a research position at the PSFC, attracted by the center’s “esprit de corps.”

      He arrived in time to participate in the final experiments on Alcator A, the first in a series of tokamaks built at MIT, all characterized by compact size and featuring high-field magnets. The tokamak design was then becoming favored as the most effective route to fusion: its doughnut-shaped vacuum chamber, surrounded by electromagnets, could confine the turbulent plasma long enough, while increasing its heat and density, to make fusion occur.

      Alcator A showed that the energy confinement time improves in relation to increasing plasma density. MIT’s succeeding device, Alcator C, was designed to use higher magnetic fields, boosting expectations that it would reach higher densities and better confinement. To attain these goals, however, Greenwald had to pursue a new technique that increased density by injecting pellets of frozen fuel into the plasma, a method he likens to throwing “snowballs in hell.” This work was notable for the creation of a new regime of enhanced plasma confinement on Alcator C. In those experiments, a confined plasma surpassed for the first time one of the two Lawson criteria — the minimum required value for the product of the plasma density and confinement time — for making net power from fusion. This had been a milestone for fusion research since their publication by John Lawson in 1957.

      Greenwald continued to make a name for himself as part of a larger study into the physics of the Compact Ignition Tokamak — a high-field burning plasma experiment that the U.S. program was proposing to build in the late 1980s. The result, unexpectedly, was a new scaling law, later known as the “Greenwald Density Limit,” and a new theory for the mechanism of the limit. It has been used to accurately predict performance on much larger machines built since.

      The center’s next tokamak, Alcator C-Mod, started operation in 1993 and ran for more than 20 years, with Greenwald as the chair of its Experimental Program Committee. Larger than Alcator C, the new device supported a highly shaped plasma, strong radiofrequency heating, and an all-metal plasma-facing first wall. All of these would eventually be required in a fusion power system.

      C-Mod proved to be MIT’s most enduring fusion experiment to date, producing important results for 20 years. During that time Greenwald contributed not only to the experiments, but to mentoring the next generation. Research scientist Ryan Sweeney notes that “Martin quickly gained my trust as a mentor, in part due to his often casual dress and slightly untamed hair, which are embodiments of his transparency and his focus on what matters. He can quiet a room of PhDs and demand attention not by intimidation, but rather by his calmness and his ability to bring clarity to complicated problems, be they scientific or human in nature.”

      Greenwald worked closely with the group of students who, in PSFC Director Dennis Whyte’s class, came up with the tokamak concept that evolved into SPARC. MIT is now pursuing this compact, high-field tokamak with Commonwealth Fusion Systems, a startup that grew out of the collective enthusiasm for this concept, and the growing realization it could work. Greenwald now heads the Physics Group for the SPARC project at MIT. He has helped confirm the device’s physics basis in order to predict performance and guide engineering decisions.

      “Martin’s multifaceted talents are thoroughly embodied by, and imprinted on, SPARC” says Whyte. “First, his leadership in its plasma confinement physics validation and publication place SPARC on a firm scientific footing. Secondly, the impact of the density limit he discovered, which shows that fuel density increases with magnetic field and decreasing the size of the tokamak, is critical in obtaining high fusion power density not just in SPARC, but in future power plants. Third, and perhaps most impressive, is Martin’s mentorship of the SPARC generation of leadership.”

      Greenwald’s expertise and easygoing personality have made him an asset as head of the PSFC Office for Computer Services and group leader for data acquisition and computing, and sought for many professional committees. He has been an APS Fellow since 2000, and was an APS Distinguished Lecturer in Plasma Physics (2001-02). He was also presented in 2014 with a Leadership Award from Fusion Power Associates. He is currently an associate editor for Physics of Plasmas and a member of the Lawrence Livermore National Laboratory Physical Sciences Directorate External Review Committee.

      Although leaving his full-time responsibilities, Greenwald will remain at MIT as a visiting scientist, a role he says will allow him to “stick my nose into everything without being responsible for anything.”

      “At some point in the race you have to hand off the baton,“ he says. “And it doesn’t mean you’re not interested in the outcome; and it doesn’t mean you’re just going to walk away into the stands. I want to be there at the end when we succeed.” More

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      in Energy

      Leveraging science and technology against the world’s top problems

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      Looking back on nearly a half-century at MIT, Richard K. Lester, associate provost and Japan Steel Industry Professor, sees a “somewhat eccentric professional trajectory.”

      But while his path has been irregular, there has been a clearly defined through line, Lester says: the emergence of new science and new technologies, the potential of these developments to shake up the status quo and address some of society’s most consequential problems, and what the outcomes might mean for America’s place in the world.

      Perhaps no assignment in Lester’s portfolio better captures this theme than the new MIT Climate Grand Challenges competition. Spearheaded by Lester and Maria Zuber, MIT vice president for research, and launched at the height of the pandemic in summer 2020, this initiative is designed to mobilize the entire MIT research community around tackling “the really hard, challenging problems currently standing in the way of an effective global response to the climate emergency,” says Lester. “The focus is on those problems where progress requires developing and applying frontier knowledge in the natural and social sciences and cutting-edge technologies. This is the MIT community swinging for the fences in areas where we have a comparative advantage.”This is a passion project for him, not least because it has engaged colleagues from nearly all of MIT’s departments. After nearly 100 initial ideas were submitted by more than 300 faculty, 27 teams were named finalists and received funding to develop comprehensive research and innovation plans in such areas as decarbonizing complex industries; risk forecasting and adaptation; advancing climate equity; and carbon removal, management, and storage. In April, a small subset of this group will become multiyear flagship projects, augmenting the work of existing MIT units that are pursuing climate research. Lester is sunny in the face of these extraordinarily complex problems. “This is a bottom-up effort with exciting proposals, and where the Institute is collectively committed — it’s MIT at its best.”

      Nuclear to the core

      This initiative carries a particular resonance for Lester, who remains deeply engaged in nuclear engineering. “The role of nuclear energy is central and will need to become even more central if we’re to succeed in addressing the climate challenge,” he says. He also acknowledges that for nuclear energy technologies — both fission and fusion — to play a vital role in decarbonizing the economy, they must not just win “in the court of public opinion, but in the marketplace,” he says. “Over the years, my research has sought to elucidate what needs to be done to overcome these obstacles.”

      In fact, Lester has been campaigning for much of his career for a U.S. nuclear innovation agenda, a commitment that takes on increased urgency as the contours of the climate crisis sharpen. He argues for the rapid development and testing of nuclear technologies that can complement the renewable but intermittent energy sources of sun and wind. Whether powerful, large-scale, molten-salt-cooled reactors or small, modular, light water reactors, nuclear batteries or promising new fusion projects, U.S. energy policy must embrace nuclear innovation, says Lester, or risk losing the high-stakes race for a sustainable future.

      Chancing into a discipline

      Lester’s introduction to nuclear science was pure happenstance.

      Born in the English industrial city of Leeds, he grew up in a musical family and played piano, violin, and then viola. “It was a big part of my life,” he says, and for a time, music beckoned as a career. He tumbled into a chemical engineering concentration at Imperial College, London, after taking a job in a chemical factory following high school. “There’s a certain randomness to life, and in my case, it’s reflected in my choice of major, which had a very large impact on my ultimate career.”

      In his second year, Lester talked his way into running a small experiment in the university’s research reactor, on radiation effects in materials. “I got hooked, and began thinking of studying nuclear engineering.” But there were few graduate programs in British universities at the time. Then serendipity struck again. The instructor of Lester’s single humanities course at Imperial had previously taught at MIT, and suggested Lester take a look at the nuclear program there. “I will always be grateful to him (and, indirectly, to MIT’s Humanities program) for opening my eyes to the existence of this institution where I’ve spent my whole adult life,” says Lester.

      He arrived at MIT with the notion of mitigating the harms of nuclear weapons. It was a time when the nuclear arms race “was an existential threat in everyone’s life,” he recalls. He targeted his graduate studies on nuclear proliferation. But he also encountered an electrifying study by MIT meteorologist Jule Charney. “Professor Charney produced one of the first scientific assessments of the effects on climate of increasing CO2 concentrations in the atmosphere, with quantitative estimates that have not fundamentally changed in 40 years.”

      Lester shifted directions. “I came to MIT to work on nuclear security, but stayed in the nuclear field because of the contributions that it can and must make in addressing climate change,” he says.

      Research and policy

      His path forward, Lester believed, would involve applying his science and technology expertise to critical policy problems, grounded in immediate, real-world concerns, and aiming for broad policy impacts. Even as a member of NSE, he joined with colleagues from many MIT departments to study American industrial practices and what was required to make them globally competitive, and then founded MIT’s Industrial Performance Center (IPC). Working at the IPC with interdisciplinary teams of faculty and students on the sources of productivity and innovation, his research took him to many countries at different stages of industrialization, including China, Taiwan, Japan, and Brazil.

      Lester’s wide-ranging work yielded books (including the MIT Press bestseller “Made in America”), advisory positions with governments, corporations, and foundations, and unexpected collaborations. “My interests were always fairly broad, and being at MIT made it possible to team up with world-leading scholars and extraordinary students not just in nuclear engineering, but in many other fields such as political science, economics, and management,” he says.

      Forging cross-disciplinary ties and bringing creative people together around a common goal proved a valuable skill as Lester stepped into positions of ever-greater responsibility at the Institute. He didn’t exactly relish the prospect of a desk job, though. “I religiously avoided administrative roles until I felt I couldn’t keep avoiding them,” he says.

      Today, as associate provost, he tends to MIT’s international activities — a daunting task given increasing scrutiny of research universities’ globe-spanning research partnerships and education of foreign students. But even in the midst of these consuming chores, Lester remains devoted to his home department. “Being a nuclear engineer is a central part of my identity,” he says.

      To students entering the nuclear field nearly 50 years after he did, who are understandably “eager to fix everything that seems wrong immediately,” he has a message: “Be patient. The hard things, the ones that are really worth doing, will take a long time to do.” Putting the climate crisis behind us will take two generations, Lester believes. Current students will start the job, but it will also take the efforts of their children’s generation before it is done.  “So we need you to be energetic and creative, of course, but whatever you do we also need you to be patient and to have ‘stick-to-itiveness’ — and maybe also a moral compass that our generation has lacked.” More

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      Q&A: Climate Grand Challenges finalists on using data and science to forecast climate-related risk

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      Note: This is the final article in a four-part interview series featuring the work of the 27 MIT Climate Grand Challenges finalist teams, which received a total of $2.7 million in startup funding to advance their projects. This month, the Institute will name a subset of the finalists as multiyear flagship projects.

      Advances in computation, artificial intelligence, robotics, and data science are enabling a new generation of observational tools and scientific modeling with the potential to produce timely, reliable, and quantitative analysis of future climate risks at a local scale. These projections can increase the accuracy and efficacy of early warning systems, improve emergency planning, and provide actionable information for climate mitigation and adaptation efforts, as human actions continue to change planetary conditions.

      In conversations prepared for MIT News, faculty from four Climate Grand Challenges teams with projects in the competition’s “Using data and science to forecast climate-related risk” category describe the promising new technologies that can help scientists understand the Earth’s climate system on a finer scale than ever before. (The other Climate Grand Challenges research themes include building equity and fairness into climate solutions, removing, managing, and storing greenhouse gases, and decarbonizing complex industries and processes.) The following responses have been edited for length and clarity.

      An observational system that can initiate a climate risk forecasting revolution

      Despite recent technological advances and massive volumes of data, climate forecasts remain highly uncertain. Gaps in observational capabilities create substantial challenges to predicting extreme weather events and establishing effective mitigation and adaptation strategies. R. John Hansman, the T. Wilson Professor of Aeronautics and Astronautics and director of the MIT International Center for Air Transportation, discusses the Stratospheric Airborne Climate Observatory System (SACOS) being developed together with Brent Minchew, the Cecil and Ida Green Career Development Professor in the Department of Earth, Atmospheric and Planetary Sciences (EAPS), and a team that includes researchers from MIT Lincoln Laboratory and Harvard University.

      Q: How does SACOS reduce uncertainty in climate risk forecasting?

      A: There is a critical need for higher spatial and temporal resolution observations of the climate system than are currently available through remote (satellite or airborne) and surface (in-situ) sensing. We are developing an ensemble of high-endurance, solar-powered aircraft with instrument systems capable of performing months-long climate observing missions that satellites or aircraft alone cannot fulfill. Summer months are ideal for SACOS operations, as many key climate phenomena are active and short night periods reduce the battery mass, vehicle size, and technical risks. These observations hold the potential to inform and predict, allowing emergency planners, policymakers, and the rest of society to better prepare for the changes to come.

      Q: Describe the types of observing missions where SACOS could provide critical improvements.

      A: The demise of the Antarctic Ice Sheet, which is leading to rising sea levels around the world and threatening the displacement of millions of people, is one example. Current sea level forecasts struggle to account for giant fissures that create massive icebergs and cause the Antarctic Ice Sheet to flow more rapidly into the ocean. SACOS can track these fissures to accurately forecast ice slippage and give impacted populations enough time to prepare or evacuate. Elsewhere, widespread droughts cause rampant wildfires and water shortages. SACOS has the ability to monitor soil moisture and humidity in critically dry regions to identify where and when wildfires and droughts are imminent. SACOS also offers the most effective method to measure, track, and predict local ozone depletion over North America, which has resulted in increasingly severe summer thunderstorms.

      Quantifying and managing the risks of sea-level rise

      Prevailing estimates of sea-level rise range from approximately 20 centimeters to 2 meters by the end of the century, with the associated costs on the order of trillions of dollars. The instability of certain portions of the world’s ice sheets creates vast uncertainties, complicating how the world prepares for and responds to these potential changes. EAPS Professor Brent Minchew is leading another Climate Grand Challenges finalist team working on an integrated, multidisciplinary effort to improve the scientific understanding of sea-level rise and provide actionable information and tools to manage the risks it poses.

      Q: What have been the most significant challenges to understanding the potential rates of sea-level rise?

      A: West Antarctica is one of the most remote, inaccessible, and hostile places on Earth — to people and equipment. Thus, opportunities to observe the collapse of the West Antarctic Ice Sheet, which contains enough ice to raise global sea levels by about 3 meters, are limited and current observations crudely resolved. It is essential that we understand how the floating edge of the ice sheets, often called ice shelves, fracture and collapse because they provide critical forces that govern the rate of ice mass loss and can stabilize the West Antarctic Ice Sheet.

      Q: How will your project advance what is currently known about sea-level rise?

      A: We aim to advance global-scale projections of sea-level rise through novel observational technologies and computational models of ice sheet change and to link those predictions to region- to neighborhood-scale estimates of costs and adaptation strategies. To do this, we propose two novel instruments: a first-of-its-kind drone that can fly for months at a time over Antarctica making continuous observations of critical areas and an airdropped seismometer and GPS bundle that can be deployed to vulnerable and hard-to-reach areas of the ice sheet. This technology will provide greater data quality and density and will observe the ice sheet at frequencies that are currently inaccessible — elements that are essential for understanding the physics governing the evolution of the ice sheet and sea-level rise.

      Changing flood risk for coastal communities in the developing world

      Globally, more than 600 million people live in low-elevation coastal areas that face an increasing risk of flooding from sea-level rise. This includes two-thirds of cities with populations of more than 5 million and regions that conduct the vast majority of global trade. Dara Entekhabi, the Bacardi and Stockholm Water Foundations Professor in the Department of Civil and Environmental Engineering and professor in the Department of Earth, Atmospheric, and Planetary Sciences, outlines an interdisciplinary partnership that leverages data and technology to guide short-term and chart long-term adaptation pathways with Miho Mazereeuw, associate professor of architecture and urbanism and director of the Urban Risk Lab in the School of Architecture and Planning, and Danielle Wood, assistant professor in the Program in Media Arts and Sciences and the Department of Aeronautics and Astronautics.

      Q: What is the key problem this program seeks to address?

      A: The accumulated heating of the Earth system due to fossil burning is largely absorbed by the oceans, and the stored heat expands the ocean volume leading to increased base height for tides. When the high tides inundate a city, the condition is referred to as “sunny day” flooding, but the saline waters corrode infrastructure and wreak havoc on daily routines. The danger ahead for many coastal cities in the developing world is the combination of increasing high tide intrusions, coupled with heavy precipitation storm events.

      Q: How will your proposed solutions impact flood risk management?

      A: We are producing detailed risk maps for coastal cities in developing countries using newly available, very high-resolution remote-sensing data from space-borne instruments, as well as historical tides records and regional storm characteristics. Using these datasets, we aim to produce street-by-street risk maps that provide local decision-makers and stakeholders with a way to estimate present and future flood risks. With the model of future tides and probabilistic precipitation events, we can forecast future inundation by a flooding event, decadal changes with various climate-change and sea-level rise projections, and an increase in the likelihood of sunny-day flooding. Working closely with local partners, we will develop toolkits to explore short-term emergency response, as well as long-term mitigation and adaptation techniques in six pilot locations in South and Southeast Asia, Africa, and South America.

      Ocean vital signs

      On average, every person on Earth generates fossil fuel emissions equivalent to an 8-pound bag of carbon, every day. Much of this is absorbed by the ocean, but there is wide variability in the estimates of oceanic absorption, which translates into differences of trillions of dollars in the required cost of mitigation. In the Department of Earth, Atmospheric and Planetary Sciences, Christopher Hill, a principal research engineer specializing in Earth and planetary computational science, works with Ryan Woosley, a principal research scientist focusing on the carbon cycle and ocean acidification. Hill explains that they hope to use artificial intelligence and machine learning to help resolve this uncertainty.

      Q: What is the current state of knowledge on air-sea interactions?

      A: Obtaining specific, accurate field measurements of critical physical, chemical, and biological exchanges between the ocean and the planet have historically entailed expensive science missions with large ship-based infrastructure that leave gaps in real-time data about significant ocean climate processes. Recent advances in highly scalable in-situ autonomous observing and navigation combined with airborne, remote sensing, and machine learning innovations have the potential to transform data gathering, provide more accurate information, and address fundamental scientific questions around air-sea interaction.

      Q: How will your approach accelerate real-time, autonomous surface ocean observing from an experimental research endeavor to a permanent and impactful solution?

      A: Our project seeks to demonstrate how a scalable surface ocean observing network can be launched and operated, and to illustrate how this can reduce uncertainties in estimates of air-sea carbon dioxide exchange. With an initial high-impact goal of substantially eliminating the vast uncertainties that plague our understanding of ocean uptake of carbon dioxide, we will gather critical measurements for improving extended weather and climate forecast models and reducing climate impact uncertainty. The results have the potential to more accurately identify trillions of dollars worth of economic activity. More

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      in Energy

      MIT Energy Conference focuses on climate’s toughest challenges

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      This year’s MIT Energy Conference, the largest student-led event of its kind, included keynote talks and panels that tackled some of the thorniest remaining challenges in the global effort to cut back on climate-altering emissions. These include the production of construction materials such as steel and cement, and the role of transportation including aviation and shipping. While the challenges are formidable, approaches incorporating methods such as fusion, heat pumps, energy efficiency, and the use of hydrogen hold promise, participants said.

      The two-day conference, held on March 31 and April 1 for more than 900 participants, included keynote lectures, 14 panel discussions, a fireside chat, networking events, and more. The event this year included the final round of the annual MIT Climate and Energy Prize, whose winning team receives $100,000 and other support. The prize, awarded since 2007, has led to the creation of more than 220 companies and $1.1 billion in investments.

      This year’s winner is a project that hopes to provide an innovative, efficient waterless washing machine aimed at the vast majority of the world’s people, who still do laundry by hand.

      “A truly consequential moment in history”

      In his opening keynote address Fatih Birol, executive director of the International Energy Agency, noted that this year’s conference was taking place during the unprovoked invasion of Ukraine by Russia, a leading gas and oil exporter. As a result, “global oil markets are going through a major turmoil,” he said.

      He said that Russian oil exports are expected to drop by 3 million barrels a day, and that international efforts to release reserves and promote increased production elsewhere will help, but will not suffice. “We have to look to other measures” to make up the shortfall, he said, noting that his agency has produced a 10-point plan of measures to help reduce global demand for oil.

      Europe gets 45 percent of its natural gas from Russia, and the agency also has developed a 10-point plan to help alleviate expected shortages there, including measures to improve energy efficiency in homes and industries, promote renewable heating sources, and postpone retirement of some nuclear plants. But he emphasized that “our goals to reach our climate targets should not be yet another victim of Mr. Putin and his allies.”  Unfortunately, Birol said, “I see that addressing climate change is sliding down in the policy agenda of many governments.”

      But he sees reasons for optimism as well, in terms of the feasibility of achieving the global emissions reduction target, agreed to by countries representing 80 percent of the global economy, of reaching net zero carbon dioxide emissions by 2050. The IEA has developed a roadmap for the entire energy sector to get there, which is now used by many governments as a benchmark, according to Birol.

      In addition, the trend is already clear, he said. “More than 90 percent of all power plants installed in the world [last year] were renewable energy,” mainly solar and wind. And 10 percent of cars sold worldwide last year, and 20 percent in Europe, were electric cars. “Please remember that in 2019 it was only 2 percent!” he said. He also predicted that “nuclear is going to make a comeback in many countries,” both in terms of large plants and newer small modular reactors.

      Birol said that “I hope that the current crisis gives governments the impetus to address the energy security concerns, to reach our climate goals, and … [to] choose the right direction at this very important turning point.”

      The conference’s second day began with keynote talks by Gina McCarthy, national climate advisor at the White House Office of Domestic Climate Policy, and Maria Zuber, MIT’s vice president for research. In her address, Zuber said, “This conference comes at a truly consequential moment in history — a moment that puts into stark relief the enormous risks created by our current fossil-fuel based energy system — risks we cannot continue to accept.”

      She added that “time is not on our side.” To meet global commitments for limiting climate impacts, the world needs to reduce emissions by about half by 2030, and get to net zero by 2050. “In other words, we need to transform our entire global energy system in a few decades,” she said. She cited MIT’s “Fast Forward” climate action plan, issued last year, as presenting the two tracks that the world needs to pursue simultaneously: going as far as possible, as fast as possible, with the tools that exist now, while also innovating and investing in new ideas, technologies, practices, and institutions that may be needed to reach the net-zero goal.

      On the first track, she said, citing an IEA report, “from here until 2040, we can get most of the emissions reductions we need with technologies that are currently available or on the verge of becoming commercially available.” These include electrifying and boosting efficiency in buildings, industry, and transportation; increasing the portion of electricity coming from emissions-free sources; and investing in new infrastructure such as electric vehicle charging stations.

      But more than that is needed, she pointed out. For example, the amount of methane that leaks away into the atmosphere from fossil fuel operations is equivalent to all the natural gas used in Europe’s power sector, Zuber said. Recovering and selling that methane can dramatically reduce global methane emissions, often at little or no cost.

      For the longer run, “we need track-two solutions to decarbonize tough industries like aviation, shipping, chemicals, concrete, and steel,” and to remove carbon dioxide from the atmosphere. She described some of the promising technologies that are in the pipeline. Fusion, for example, has moved from being a scientific challenge to an engineering problem whose solution seems well underway, she said.

      Another important area is food-related systems, which currently account for a third of all global emissions. For example, fertilizer production uses a very energy-intensive process, but work on plants engineered to fix nitrogen directly could make a significant dent.

      These and several other advanced research areas may not all pan out, but some undoubtedly will, and will help curb climate change as well as create new jobs and reduce pollution.

      Though the problems we face are complex, they are not insurmountable, Zuber said. “We don’t need a miracle. What we need is to move along the two tracks I’ve outlined with determination, ingenuity, and fierce urgency.”

      The promise and challenges of hydrogen

      Other conference speakers took on some of the less-discussed but crucial areas that also need to be addressed in order to limit global warming to 1.5 degrees. Heavy transportation, and aviation in particular, have been considered especially challenging. In his keynote address, Glenn Llewellyn, vice president for zero-emission aircraft at Airbus, outlined several approaches his company is working on to develop competitive midrange alternative airliners by 2035 that use either batteries or fuel cells powered by hydrogen. The early-stage designs demonstrate that, contrary to some projections, there is a realistic pathway to weaning that industry from its present reliance on fossil fuel, chiefly kerosene.

      Hydrogen has real potential as an aviation fuel, he said, either directly for use in fuel cells for power or burned directly for propulsion, or indirectly as a feedstock for synthetic fuels. Both are being studied by the company, he said, including a hybrid model that uses both hydrogen fuel cells and hydrogen-fueled jet engines. The company projects a range of 2,000 nautical miles for a jet carrying 200 to 300 passengers, he said — all with no direct emissions and no contrails.

      But this vision will not be practical, Llewellyn said, unless economies of scale help to significantly lower the cost of hydrogen production. “Hydrogen is at the hub of aviation decarbonization,” he said. But that kind of price reduction seems quite feasible, he said, given that other major industries are also seriously looking at the use of hydrogen for their own decarbonization plans, including the production of steel and cement.

      Such uses were the subject of a panel discussion entitled “Deploying the Hydrogen Economy.” Hydrogen production technology exists, but not nearly at the scale that’s needed, which is about 500 million tons a year, pointed out moderator Dharik Mallapragada of the MIT Energy Initiative.

      Yet in some applications, the use of hydrogen both reduces emissions and is economically competitive. Preeti Pande of Plug Power said that her company, which produces hydrogen fuel cells, has found a significant market in an unexpected place: fork lifts, used in warehouses and factories worldwide. It turns out that replacing current battery-operated versions with fuel cell versions is a win-win for the companies that use them, saving money while helping to meet decarbonization goals.

      Lindsay Ashby of Avangrid Renewables said that the company has installed fuel-cell buses in Barcelona that run entirely on hydrogen generated by solar panels. The company is also building a 100-megawatt solar facility to produce hydrogen for the production of fertilizer, another major industry in need of decarbonization because of its large emissions footprint. And Brett Perleman of the Center for Houston’s Future said of his city that “we’re already a hydrogen hub today, just not green hydrogen” since the gas is currently mostly produced as a byproduct of fossil fuels. But that is changing rapidly, he said, and Houston, along with several other cities, aims to be a center of activity for hydrogen produced from renewable, non-carbon-emitting sources. They aim to be producing 1,000 tons a day by 2028, “and I think we’ll end up exceeding that,” he said.

      For industries that can switch to renewably generated electricity, that is typically the best choice, Perleman said. “But for those that can’t, hydrogen is a great option,” and that includes aviation, shipping, and rail. “The big oil companies all have plans in place” to develop clean hydrogen production, he said. “It’s not just a dream, but a reality.”

      For shipping, which tends to rely on bunker fuel, a particularly high-emissions fossil fuel, another potential option could be a new generation of small nuclear plants, said Jeff Navin of Terrapower, a company currently developing such units. “Finding replacements for coal, oil, or natural gas for industrial purposes is very hard,” he said, but often what these processes require is consistent high heat, which nuclear can deliver, as long as costs and regulatory issues can be resolved.  

      MIT professor of nuclear engineering Jacopo Buongiorno pointed out that the primary reasons for delays and cost overruns in nuclear plants have had to do with issues at the construction site, many of which could be alleviated by having smaller, factory-built modular plants, or by building multiple units at a time of a standardized design. If the government would take on the nuclear waste disposal, as some other countries have done, then nuclear power could play an important part in the decarbonization of many industries, he said.

      Student-led startups

      The two-day conference concluded with the final round of the annual MIT Climate and Energy Prize, consisting of the five finalist teams presenting brief pitches for their startup company ideas, followed by questions from the panel of judges. This year’s finalists included a team called Muket, dedicated to finding ways of reducing methane emissions from cattle and dairy farms. Feed additives or other measures could cut the emissions by 50 percent, the team estimates.

      A team called Ivu Biologics described a system for incorporating nitrogen-fixing microbes into the coatings of seeds, thereby reducing the need for added fertilizers, whose production is a major greenhouse gas source. The company is making use of seed-coating technology developed at MIT over the last few years. Another team, called Mesophase, also based on MIT-developed technology, aims to replace the condensers used in power plants and other industrial systems with much more efficient versions, thus increasing the energy output from a given amount of fuel or other heat source.

      A team called TerraTrade aims to facilitate the adoption of power purchase agreements by companies, institutions and governments, by acting as a kind of broker to create and administer such agreements, making it easier for even smaller entities to take part in these plans, which help to enable rapid development of renewable fossil-fuel-free energy production.

      The grand prize of $100,000 was awarded to a team called Ultropia, which is developing a combined clothes washer and drier that uses ultrasound instead of water for its cleaning. The system does use a small amount of water, but this can be recycled, making these usable even in areas where water availability is limited. The devices could have a great impact on the estimated 6 billion people in the world today who are still limited to washing clothes by hand, the team says, and because the machines would be so efficient, they would require very little energy to run — a significant improvement over the wider adoption of conventional washers and driers. More

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      in Environment

      Ocean vital signs

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      Without the ocean, the climate crisis would be even worse than it is. Each year, the ocean absorbs billions of tons of carbon from the atmosphere, preventing warming that greenhouse gas would otherwise cause. Scientists estimate about 25 to 30 percent of all carbon released into the atmosphere by both human and natural sources is absorbed by the ocean.

      “But there’s a lot of uncertainty in that number,” says Ryan Woosley, a marine chemist and a principal research scientist in the Department of Earth, Atmospheric and Planetary Sciences (EAPS) at MIT. Different parts of the ocean take in different amounts of carbon depending on many factors, such as the season and the amount of mixing from storms. Current models of the carbon cycle don’t adequately capture this variation.

      To close the gap, Woosley and a team of other MIT scientists developed a research proposal for the MIT Climate Grand Challenges competition — an Institute-wide campaign to catalyze and fund innovative research addressing the climate crisis. The team’s proposal, “Ocean Vital Signs,” involves sending a fleet of sailing drones to cruise the oceans taking detailed measurements of how much carbon the ocean is really absorbing. Those data would be used to improve the precision of global carbon cycle models and improve researchers’ ability to verify emissions reductions claimed by countries.

      “If we start to enact mitigation strategies—either through removing CO2 from the atmosphere or reducing emissions — we need to know where CO2 is going in order to know how effective they are,” says Woosley. Without more precise models there’s no way to confirm whether observed carbon reductions were thanks to policy and people, or thanks to the ocean.

      “So that’s the trillion-dollar question,” says Woosley. “If countries are spending all this money to reduce emissions, is it enough to matter?”

      In February, the team’s Climate Grand Challenges proposal was named one of 27 finalists out of the almost 100 entries submitted. From among this list of finalists, MIT will announce in April the selection of five flagship projects to receive further funding and support.

      Woosley is leading the team along with Christopher Hill, a principal research engineer in EAPS. The team includes physical and chemical oceanographers, marine microbiologists, biogeochemists, and experts in computational modeling from across the department, in addition to collaborators from the Media Lab and the departments of Mathematics, Aeronautics and Astronautics, and Electrical Engineering and Computer Science.

      Today, data on the flux of carbon dioxide between the air and the oceans are collected in a piecemeal way. Research ships intermittently cruise out to gather data. Some commercial ships are also fitted with sensors. But these present a limited view of the entire ocean, and include biases. For instance, commercial ships usually avoid storms, which can increase the turnover of water exposed to the atmosphere and cause a substantial increase in the amount of carbon absorbed by the ocean.

      “It’s very difficult for us to get to it and measure that,” says Woosley. “But these drones can.”

      If funded, the team’s project would begin by deploying a few drones in a small area to test the technology. The wind-powered drones — made by a California-based company called Saildrone — would autonomously navigate through an area, collecting data on air-sea carbon dioxide flux continuously with solar-powered sensors. This would then scale up to more than 5,000 drone-days’ worth of observations, spread over five years, and in all five ocean basins.

      Those data would be used to feed neural networks to create more precise maps of how much carbon is absorbed by the oceans, shrinking the uncertainties involved in the models. These models would continue to be verified and improved by new data. “The better the models are, the more we can rely on them,” says Woosley. “But we will always need measurements to verify the models.”

      Improved carbon cycle models are relevant beyond climate warming as well. “CO2 is involved in so much of how the world works,” says Woosley. “We’re made of carbon, and all the other organisms and ecosystems are as well. What does the perturbation to the carbon cycle do to these ecosystems?”

      One of the best understood impacts is ocean acidification. Carbon absorbed by the ocean reacts to form an acid. A more acidic ocean can have dire impacts on marine organisms like coral and oysters, whose calcium carbonate shells and skeletons can dissolve in the lower pH. Since the Industrial Revolution, the ocean has become about 30 percent more acidic on average.

      “So while it’s great for us that the oceans have been taking up the CO2, it’s not great for the oceans,” says Woosley. “Knowing how this uptake affects the health of the ocean is important as well.” More

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      in Energy

      Chemical reactions for the energy transition

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      One challenge in decarbonizing the energy system is knowing how to deal with new types of fuels. Traditional fuels such as natural gas and oil can be combined with other materials and then heated to high temperatures so they chemically react to produce other useful fuels or substances, or even energy to do work. But new materials such as biofuels can’t take as much heat without breaking down.

      A key ingredient in such chemical reactions is a specially designed solid catalyst that is added to encourage the reaction to happen but isn’t itself consumed in the process. With traditional materials, the solid catalyst typically interacts with a gas; but with fuels derived from biomass, for example, the catalyst must work with a liquid — a special challenge for those who design catalysts.

      For nearly a decade, Yogesh Surendranath, an associate professor of chemistry at MIT, has been focusing on chemical reactions between solid catalysts and liquids, but in a different situation: rather than using heat to drive reactions, he and his team input electricity from a battery or a renewable source such as wind or solar to give chemically inactive molecules more energy so they react. And key to their research is designing and fabricating solid catalysts that work well for reactions involving liquids.

      Recognizing the need to use biomass to develop sustainable liquid fuels, Surendranath wondered whether he and his team could take the principles they have learned about designing catalysts to drive liquid-solid reactions with electricity and apply them to reactions that occur at liquid-solid interfaces without any input of electricity.

      To their surprise, they found that their knowledge is directly relevant. Why? “What we found — amazingly — is that even when you don’t hook up wires to your catalyst, there are tiny internal ‘wires’ that do the reaction,” says Surendranath. “So, reactions that people generally think operate without any flow of current actually do involve electrons shuttling from one place to another.” And that means that Surendranath and his team can bring the powerful techniques of electrochemistry to bear on the problem of designing catalysts for sustainable fuels.

      A novel hypothesis

      Their work has focused on a class of chemical reactions important in the energy transition that involve adding oxygen to small organic (carbon-containing) molecules such as ethanol, methanol, and formic acid. The conventional assumption is that the reactant and oxygen chemically react to form the product plus water. And a solid catalyst — often a combination of metals — is present to provide sites on which the reactant and oxygen can interact.

      But Surendranath proposed a different view of what’s going on. In the usual setup, two catalysts, each one composed of many nanoparticles, are mounted on a conductive carbon substrate and submerged in water. In that arrangement, negatively charged electrons can flow easily through the carbon, while positively charged protons can flow easily through water.

      Surendranath’s hypothesis was that the conversion of reactant to product progresses by means of two separate “half-reactions” on the two catalysts. On one catalyst, the reactant turns into a product, in the process sending electrons into the carbon substrate and protons into the water. Those electrons and protons are picked up by the other catalyst, where they drive the oxygen-to-water conversion. So, instead of a single reaction, two separate but coordinated half-reactions together achieve the net conversion of reactant to product.

      As a result, the overall reaction doesn’t actually involve any net electron production or consumption. It is a standard “thermal” reaction resulting from the energy in the molecules and maybe some added heat. The conventional approach to designing a catalyst for such a reaction would focus on increasing the rate of that reactant-to-product conversion. And the best catalyst for that kind of reaction could turn out to be, say, gold or palladium or some other expensive precious metal.

      However, if that reaction actually involves two half-reactions, as Surendranath proposed, there is a flow of electrical charge (the electrons and protons) between them. So Surendranath and others in the field could instead use techniques of electrochemistry to design not a single catalyst for the overall reaction but rather two separate catalysts — one to speed up one half-reaction and one to speed up the other half-reaction. “That means we don’t have to design one catalyst to do all the heavy lifting of speeding up the entire reaction,” says Surendranath. “We might be able to pair up two low-cost, earth-abundant catalysts, each of which does half of the reaction well, and together they carry out the overall transformation quickly and efficiently.”

      But there’s one more consideration: Electrons can flow through the entire catalyst composite, which encompasses the catalyst particle(s) and the carbon substrate. For the chemical conversion to happen as quickly as possible, the rate at which electrons are put into the catalyst composite must exactly match the rate at which they are taken out. Focusing on just the electrons, if the reaction-to-product conversion on the first catalyst sends the same number of electrons per second into the “bath of electrons” in the catalyst composite as the oxygen-to-water conversion on the second catalyst takes out, the two half-reactions will be balanced, and the electron flow — and the rate of the combined reaction — will be fast. The trick is to find good catalysts for each of the half-reactions that are perfectly matched in terms of electrons in and electrons out.

      “A good catalyst or pair of catalysts can maintain an electrical potential — essentially a voltage — at which both half-reactions are fast and are balanced,” says Jaeyune Ryu PhD ’21, a former member of the Surendranath lab and lead author of the study; Ryu is now a postdoc at Harvard University. “The rates of the reactions are equal, and the voltage in the catalyst composite won’t change during the overall thermal reaction.”

      Drawing on electrochemistry

      Based on their new understanding, Surendranath, Ryu, and their colleagues turned to electrochemistry techniques to identify a good catalyst for each half-reaction that would also pair up to work well together. Their analytical framework for guiding catalyst development for systems that combine two half-reactions is based on a theory that has been used to understand corrosion for almost 100 years, but has rarely been applied to understand or design catalysts for reactions involving small molecules important for the energy transition.

      Key to their work is a potentiostat, a type of voltmeter that can either passively measure the voltage of a system or actively change the voltage to cause a reaction to occur. In their experiments, Surendranath and his team use the potentiostat to measure the voltage of the catalyst in real time, monitoring how it changes millisecond to millisecond. They then correlate those voltage measurements with simultaneous but separate measurements of the overall rate of catalysis to understand the reaction pathway.

      For their study of the conversion of small, energy-related molecules, they first tested a series of catalysts to find good ones for each half-reaction — one to convert the reactant to product, producing electrons and protons, and another to convert the oxygen to water, consuming electrons and protons. In each case, a promising candidate would yield a rapid reaction — that is, a fast flow of electrons and protons out or in.

      To help identify an effective catalyst for performing the first half-reaction, the researchers used their potentiostat to input carefully controlled voltages and measured the resulting current that flowed through the catalyst. A good catalyst will generate lots of current for little applied voltage; a poor catalyst will require high applied voltage to get the same amount of current. The team then followed the same procedure to identify a good catalyst for the second half-reaction.

      To expedite the overall reaction, the researchers needed to find two catalysts that matched well — where the amount of current at a given applied voltage was high for each of them, ensuring that as one produced a rapid flow of electrons and protons, the other one consumed them at the same rate.

      To test promising pairs, the researchers used the potentiostat to measure the voltage of the catalyst composite during net catalysis — not changing the voltage as before, but now just measuring it from tiny samples. In each test, the voltage will naturally settle at a certain level, and the goal is for that to happen when the rate of both reactions is high.

      Validating their hypothesis and looking ahead

      By testing the two half-reactions, the researchers could measure how the reaction rate for each one varied with changes in the applied voltage. From those measurements, they could predict the voltage at which the full reaction would proceed fastest. Measurements of the full reaction matched their predictions, supporting their hypothesis.

      The team’s novel approach of using electrochemistry techniques to examine reactions thought to be strictly thermal in nature provides new insights into the detailed steps by which those reactions occur and therefore into how to design catalysts to speed them up. “We can now use a divide-and-conquer strategy,” says Ryu. “We know that the net thermal reaction in our study happens through two ‘hidden’ but coupled half-reactions, so we can aim to optimize one half-reaction at a time” — possibly using low-cost catalyst materials for one or both.

      Adds Surendranath, “One of the things that we’re excited about in this study is that the result is not final in and of itself. It has really seeded a brand-new thrust area in our research program, including new ways to design catalysts for the production and transformation of renewable fuels and chemicals.”

      This research was supported primarily by the Air Force Office of Scientific Research. Jaeyune Ryu PhD ’21 was supported by a Samsung Scholarship. Additional support was provided by a National Science Foundation Graduate Research Fellowship.

      This article appears in the Autumn 2021 issue of Energy Futures, the magazine of the MIT Energy Initiative. More

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      in Environment

      Improving predictions of sea level rise for the next century

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      When we think of climate change, one of the most dramatic images that comes to mind is the loss of glacial ice. As the Earth warms, these enormous rivers of ice become a casualty of the rising temperatures. But, as ice sheets retreat, they also become an important contributor to one the more dangerous outcomes of climate change: sea-level rise. At MIT, an interdisciplinary team of scientists is determined to improve sea level rise predictions for the next century, in part by taking a closer look at the physics of ice sheets.

      Last month, two research proposals on the topic, led by Brent Minchew, the Cecil and Ida Green Career Development Professor in the Department of Earth, Atmospheric and Planetary Sciences (EAPS), were announced as finalists in the MIT Climate Grand Challenges initiative. Launched in July 2020, Climate Grand Challenges fielded almost 100 project proposals from collaborators across the Institute who heeded the bold charge: to develop research and innovations that will deliver game-changing advances in the world’s efforts to address the climate challenge.

      As finalists, Minchew and his collaborators from the departments of Urban Studies and Planning, Economics, Civil and Environmental Engineering, the Haystack Observatory, and external partners, received $100,000 to develop their research plans. A subset of the 27 proposals tapped as finalists will be announced next month, making up a portfolio of multiyear “flagship” projects receiving additional funding and support.

      One goal of both Minchew proposals is to more fully understand the most fundamental processes that govern rapid changes in glacial ice, and to use that understanding to build next-generation models that are more predictive of ice sheet behavior as they respond to, and influence, climate change.

      “We need to develop more accurate and computationally efficient models that provide testable projections of sea-level rise over the coming decades. To do so quickly, we want to make better and more frequent observations and learn the physics of ice sheets from these data,” says Minchew. “For example, how much stress do you have to apply to ice before it breaks?”

      Currently, Minchew’s Glacier Dynamics and Remote Sensing group uses satellites to observe the ice sheets on Greenland and Antarctica primarily with interferometric synthetic aperture radar (InSAR). But the data are often collected over long intervals of time, which only gives them “before and after” snapshots of big events. By taking more frequent measurements on shorter time scales, such as hours or days, they can get a more detailed picture of what is happening in the ice.

      “Many of the key unknowns in our projections of what ice sheets are going to look like in the future, and how they’re going to evolve, involve the dynamics of glaciers, or our understanding of how the flow speed and the resistances to flow are related,” says Minchew.

      At the heart of the two proposals is the creation of SACOS, the Stratospheric Airborne Climate Observatory System. The group envisions developing solar-powered drones that can fly in the stratosphere for months at a time, taking more frequent measurements using a new lightweight, low-power radar and other high-resolution instrumentation. They also propose air-dropping sensors directly onto the ice, equipped with seismometers and GPS trackers to measure high-frequency vibrations in the ice and pinpoint the motions of its flow.

      How glaciers contribute to sea level rise

      Current climate models predict an increase in sea levels over the next century, but by just how much is still unclear. Estimates are anywhere from 20 centimeters to two meters, which is a large difference when it comes to enacting policy or mitigation. Minchew points out that response measures will be different, depending on which end of the scale it falls toward. If it’s closer to 20 centimeters, coastal barriers can be built to protect low-level areas. But with higher surges, such measures become too expensive and inefficient to be viable, as entire portions of cities and millions of people would have to be relocated.

      “If we’re looking at a future where we could get more than a meter of sea level rise by the end of the century, then we need to know about that sooner rather than later so that we can start to plan and to do our best to prepare for that scenario,” he says.

      There are two ways glaciers and ice sheets contribute to rising sea levels: direct melting of the ice and accelerated transport of ice to the oceans. In Antarctica, warming waters melt the margins of the ice sheets, which tends to reduce the resistive stresses and allow ice to flow more quickly to the ocean. This thinning can also cause the ice shelves to be more prone to fracture, facilitating the calving of icebergs — events which sometimes cause even further acceleration of ice flow.

      Using data collected by SACOS, Minchew and his group can better understand what material properties in the ice allow for fracturing and calving of icebergs, and build a more complete picture of how ice sheets respond to climate forces. 

      “What I want is to reduce and quantify the uncertainties in projections of sea level rise out to the year 2100,” he says.

      From that more complete picture, the team — which also includes economists, engineers, and urban planning specialists — can work on developing predictive models and methods to help communities and governments estimate the costs associated with sea level rise, develop sound infrastructure strategies, and spur engineering innovation.

      Understanding glacier dynamics

      More frequent radar measurements and the collection of higher-resolution seismic and GPS data will allow Minchew and the team to develop a better understanding of the broad category of glacier dynamics — including calving, an important process in setting the rate of sea level rise which is currently not well understood.  

      “Some of what we’re doing is quite similar to what seismologists do,” he says. “They measure seismic waves following an earthquake, or a volcanic eruption, or things of this nature and use those observations to better understand the mechanisms that govern these phenomena.”

      Air-droppable sensors will help them collect information about ice sheet movement, but this method comes with drawbacks — like installation and maintenance, which is difficult to do out on a massive ice sheet that is moving and melting. Also, the instruments can each only take measurements at a single location. Minchew equates it to a bobber in water: All it can tell you is how the bobber moves as the waves disturb it.

      But by also taking continuous radar measurements from the air, Minchew’s team can collect observations both in space and in time. Instead of just watching the bobber in the water, they can effectively make a movie of the waves propagating out, as well as visualize processes like iceberg calving happening in multiple dimensions.

      Once the bobbers are in place and the movies recorded, the next step is developing machine learning algorithms to help analyze all the new data being collected. While this data-driven kind of discovery has been a hot topic in other fields, this is the first time it has been applied to glacier research.

      “We’ve developed this new methodology to ingest this huge amount of data,” he says, “and from that create an entirely new way of analyzing the system to answer these fundamental and critically important questions.”  More