The net uptake of CO2 by the biosphere offsets roughly a quarter of current fossil fuel emissions. However, climate change is expected to impact photosynthesis and ecosystem respiration differently. Quantification of these individual processes is required to better understand and predict the consequences for carbon cycling. Variations in oxygen isotope signatures (δ18O and Δ17O) in atmospheric CO2 can be used as tracers for photosynthesis. Δ17O is much less dependent on variations in the hydrological cycle, which often obscure photosynthesis signals in the more widely measured δ18O. Although, measurement techniques for Δ17O in tropospheric CO2 only became sufficiently accurate to interpret variations since the ~2010s, providing new insights into the carbon cycle.
Source: Ecology - nature.com