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    After more than a decade of successes, ESI’s work will spread out across the Institute

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    MIT’s Environmental Solutions Initiative (ESI), a pioneering cross-disciplinary body that helped give a major boost to sustainability and solutions to climate change at MIT, will close as a separate entity at the end of June. But that’s far from the end for its wide-ranging work, which will go forward under different auspices. Many of its key functions will become part of MIT’s recently launched Climate Project. John Fernandez, head of ESI for nearly a decade, will return to the School of Architecture and Planning, where some of ESI’s important work will continue as part of a new interdisciplinary lab.When the ideas that led to the founding of MIT’s Environmental Solutions Initiative first began to be discussed, its founders recall, there was already a great deal of work happening at MIT relating to climate change and sustainability. As Professor John Sterman of the MIT Sloan School of Management puts it, “there was a lot going on, but it wasn’t integrated. So the whole added up to less than the sum of its parts.”ESI was founded in 2014 to help fill that coordinating role, and in the years since it has accomplished a wide range of significant milestones in research, education, and communication about sustainable solutions in a wide range of areas. Its founding director, Professor Susan Solomon, helmed it for its first year, and then handed the leadership to Fernandez, who has led it since 2015.“There wasn’t much of an ecosystem [on sustainability] back then,” Solomon recalls. But with the help of ESI and some other entities, that ecosystem has blossomed. She says that Fernandez “has nurtured some incredible things under ESI,” including work on nature-based climate solutions, and also other areas such as sustainable mining, and reduction of plastics in the environment.Desiree Plata, director of MIT’s Climate and Sustainability Consortium and associate professor of civil and environmental engineering, says that one key achievement of the initiative has been in “communication with the external world, to help take really complex systems and topics and put them in not just plain-speak, but something that’s scientifically rigorous and defensible, for the outside world to consume.”In particular, ESI has created three very successful products, which continue under the auspices of the Climate Project. These include the popular TIL Climate Podcast, the Webby Award-winning Climate Portal website, and the online climate primer developed with Professor Kerry Emanuel. “These are some of the most frequented websites at MIT,” Plata says, and “the impact of this work on the global knowledge base cannot be overstated.”Fernandez says that ESI has played a significant part in helping to catalyze what has become “a rich institutional landscape of work in sustainability and climate change” at MIT. He emphasizes three major areas where he feels the ESI has been able to have the most impact: engaging the MIT community, initiating and stewarding critical environmental research, and catalyzing efforts to promote sustainability as fundamental to the mission of a research university.Engagement of the MIT community, he says, began with two programs: a research seed grant program and the creation of MIT’s undergraduate minor in environment and sustainability, launched in 2017.ESI also created a Rapid Response Group, which gave students a chance to work on real-world projects with external partners, including government agencies, community groups, nongovernmental organizations, and businesses. In the process, they often learned why dealing with environmental challenges in the real world takes so much longer than they might have thought, he says, and that a challenge that “seemed fairly straightforward at the outset turned out to be more complex and nuanced than expected.”The second major area, initiating and stewarding environmental research, grew into a set of six specific program areas: natural climate solutions, mining, cities and climate change, plastics and the environment, arts and climate, and climate justice.These efforts included collaborations with a Nobel Peace Prize laureate, three successive presidential administrations from Colombia, and members of communities affected by climate change, including coal miners, indigenous groups, various cities, companies, the U.N., many agencies — and the popular musical group Coldplay, which has pledged to work toward climate neutrality for its performances. “It was the role that the ESI played as a host and steward of these research programs that may serve as a key element of our legacy,” Fernandez says.The third broad area, he says, “is the idea that the ESI as an entity at MIT would catalyze this movement of a research university toward sustainability as a core priority.” While MIT was founded to be an academic partner to the industrialization of the world, “aren’t we in a different world now? The kind of massive infrastructure planning and investment and construction that needs to happen to decarbonize the energy system is maybe the largest industrialization effort ever undertaken. Even more than in the recent past, the set of priorities driving this have to do with sustainable development.”Overall, Fernandez says, “we did everything we could to infuse the Institute in its teaching and research activities with the idea that the world is now in dire need of sustainable solutions.”Fernandez “has nurtured some incredible things under ESI,” Solomon says. “It’s been a very strong and useful program, both for education and research.” But it is appropriate at this time to distribute its projects to other venues, she says. “We do now have a major thrust in the Climate Project, and you don’t want to have redundancies and overlaps between the two.”Fernandez says “one of the missions of the Climate Project is really acting to coalesce and aggregate lots of work around MIT.” Now, with the Climate Project itself, along with the Climate Policy Center and the Center for Sustainability Science and Strategy, it makes more sense for ESI’s climate-related projects to be integrated into these new entities, and other projects that are less directly connected to climate to take their places in various appropriate departments or labs, he says.“We did enough with ESI that we made it possible for these other centers to really flourish,” he says. “And in that sense, we played our role.”As of June 1, Fernandez has returned to his role as professor of architecture and urbanism and building technology in the School of Architecture and Planning, where he directs the Urban Metabolism Group. He will also be starting up a new group called Environment ResearchAction (ERA) to continue ESI work in cities, nature, and artificial intelligence.  More

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      Decarbonizing steel is as tough as steel

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      The long-term aspirational goal of the Paris Agreement on climate change is to cap global warming at 1.5 degrees Celsius above preindustrial levels, and thereby reduce the frequency and severity of floods, droughts, wildfires, and other extreme weather events. Achieving that goal will require a massive reduction in global carbon dioxide (CO2) emissions across all economic sectors. A major roadblock, however, could be the industrial sector, which accounts for roughly 25 percent of global energy- and process-related CO2 emissions — particularly within the iron and steel sector, industry’s largest emitter of CO2.Iron and steel production now relies heavily on fossil fuels (coal or natural gas) for heat, converting iron ore to iron, and making steel strong. Steelmaking could be decarbonized by a combination of several methods, including carbon capture technology, the use of low- or zero-carbon fuels, and increased use of recycled steel. Now a new study in the Journal of Cleaner Production systematically explores the viability of different iron-and-steel decarbonization strategies.Today’s strategy menu includes improving energy efficiency, switching fuels and technologies, using more scrap steel, and reducing demand. Using the MIT Economic Projection and Policy Analysis model, a multi-sector, multi-region model of the world economy, researchers at MIT, the University of Illinois at Urbana-Champaign, and ExxonMobil Technology and Engineering Co. evaluate the decarbonization potential of replacing coal-based production processes with electric arc furnaces (EAF), along with either scrap steel or “direct reduced iron” (DRI), which is fueled by natural gas with carbon capture and storage (NG CCS DRI-EAF) or by hydrogen (H2 DRI-EAF).Under a global climate mitigation scenario aligned with the 1.5 C climate goal, these advanced steelmaking technologies could result in deep decarbonization of the iron and steel sector by 2050, as long as technology costs are low enough to enable large-scale deployment. Higher costs would favor the replacement of coal with electricity and natural gas, greater use of scrap steel, and reduced demand, resulting in a more-than-50-percent reduction in emissions relative to current levels. Lower technology costs would enable massive deployment of NG CCS DRI-EAF or H2 DRI-EAF, reducing emissions by up to 75 percent.Even without adoption of these advanced technologies, the iron-and-steel sector could significantly reduce its CO2 emissions intensity (how much CO2 is released per unit of production) with existing steelmaking technologies, primarily by replacing coal with gas and electricity (especially if it is generated by renewable energy sources), using more scrap steel, and implementing energy efficiency measures.“The iron and steel industry needs to combine several strategies to substantially reduce its emissions by mid-century, including an increase in recycling, but investing in cost reductions in hydrogen pathways and carbon capture and sequestration will enable even deeper emissions mitigation in the sector,” says study supervising author Sergey Paltsev, deputy director of the MIT Center for Sustainability Science and Strategy (MIT CS3) and a senior research scientist at the MIT Energy Initiative (MITEI).This study was supported by MIT CS3 and ExxonMobil through its membership in MITEI. More

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      in Energy

      Recovering from the past and transitioning to a better energy future

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      As the frequency and severity of extreme weather events grow, it may become increasingly necessary to employ a bolder approach to climate change, warned Emily A. Carter, the Gerhard R. Andlinger Professor in Energy and the Environment at Princeton University. Carter made her case for why the energy transition is no longer enough in the face of climate change while speaking at the MIT Energy Initiative (MITEI) Presents: Advancing the Energy Transition seminar on the MIT campus.“If all we do is take care of what we did in the past — but we don’t change what we do in the future — then we’re still going to be left with very serious problems,” she said. Our approach to climate change mitigation must comprise transformation, intervention, and adaption strategies, said Carter. Transitioning to a decarbonized electricity system is one piece of the puzzle. Growing amounts of solar and wind energy — along with nuclear, hydropower, and geothermal — are slowly transforming the energy electricity landscape, but Carter noted that there are new technologies farther down the pipeline.  “Advanced geothermal may come on in the next couple of decades. Fusion will only really start to play a role later in the century, but could provide firm electricity such that we can start to decommission nuclear,” said Carter, who is also a senior strategic advisor and associate laboratory director at the Department of Energy’s Princeton Plasma Physics Laboratory. Taking this a step further, Carter outlined how this carbon-free electricity should then be used to electrify everything we can. She highlighted the industrial sector as a critical area for transformation: “The energy transition is about transitioning off of fossil fuels. If you look at the manufacturing industries, they are driven by fossil fuels right now. They are driven by fossil fuel-driven thermal processes.” Carter noted that thermal energy is much less efficient than electricity and highlighted electricity-driven strategies that could replace heat in manufacturing, such as electrolysis, plasmas, light-emitting diodes (LEDs) for photocatalysis, and joule heating. The transportation sector is also a key area for electrification, Carter said. While electric vehicles have become increasingly common in recent years, heavy-duty transportation is not as easily electrified. The solution? “Carbon-neutral fuels for heavy-duty aviation and shipping,” she said, emphasizing that these fuels will need to become part of the circular economy. “We know that when we burn those fuels, they’re going to produce CO2 [carbon dioxide] again. They need to come from a source of CO2 that is not fossil-based.” The next step is intervention in the form of carbon dioxide removal, which then necessitates methods of storage and utilization, according to Carter. “There’s a lot of talk about building large numbers of pipelines to capture the CO2 — from fossil fuel-driven power plants, cement plants, steel plants, all sorts of industrial places that emit CO2 — and then piping it and storing it in underground aquifers,” she explained. Offshore pipelines are much more expensive than those on land, but can mitigate public concerns over their safety. Europe is exclusively focusing their efforts offshore for this very reason, and the same could be true for the United States, Carter said.  Once carbon dioxide is captured, commercial utilization may provide economic leverage to accelerate sequestration, even if only a few gigatons are used per year, Carter noted. Through mineralization, CO2 can be converted into carbonates, which could be used in building materials such as concrete and road-paving materials.  There is another form of intervention that Carter currently views as a last resort: solar geoengineering, sometimes known as solar radiation management or SRM. In 1991, Mount Pinatubo in the Philippines erupted and released sulfur dioxide into the stratosphere, which caused a temporary cooling of the Earth by approximately 0.5 degree Celsius for over a year. SRM seeks to recreate that cooling effect by injecting particles into the atmosphere that reflect sunlight. According to Carter, there are three main strategies: stratospheric aerosol injection, cirrus cloud thinning (thinning clouds to let more infrared radiation emitted by the earth escape to space), and marine cloud brightening (brightening clouds with sea salt so they reflect more light).  “My view is, I hope we don’t ever have to do it, but I sure think we should understand what would happen in case somebody else just decides to do it. It’s a global security issue,” said Carter. “In principle, it’s not so difficult technologically, so we’d like to really understand and to be able to predict what would happen if that happened.” With any technology, stakeholder and community engagement is essential for deployment, Carter said. She emphasized the importance of both respectfully listening to concerns and thoroughly addressing them, stating, “Hopefully, there’s enough information given to assuage their fears. We have to gain the trust of people before any deployment can be considered.” A crucial component of this trust starts with the responsibility of the scientific community to be transparent and critique each other’s work, Carter said. “Skepticism is good. You should have to prove your proof of principle.” MITEI Presents: Advancing the Energy Transition is an MIT Energy Initiative speaker series highlighting energy experts and leaders at the forefront of the scientific, technological, and policy solutions needed to transform our energy systems. The series will continue in fall 2025. For more information on this and additional events, visit the MITEI website. More

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      in Energy

      “Each of us holds a piece of the solution”

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      MIT has an unparalleled history of bringing together interdisciplinary teams to solve pressing problems — think of the development of radar during World War II, or leading the international coalition that cracked the code of the human genome — but the challenge of climate change could demand a scale of collaboration unlike any that’s come before at MIT.“Solving climate change is not just about new technologies or better models. It’s about forging new partnerships across campus and beyond — between scientists and economists, between architects and data scientists, between policymakers and physicists, between anthropologists and engineers, and more,” MIT Vice President for Energy and Climate Evelyn Wang told an energetic crowd of faculty, students, and staff on May 6. “Each of us holds a piece of the solution — but only together can we see the whole.”Undeterred by heavy rain, approximately 300 campus community members filled the atrium in the Tina and Hamid Moghadam Building (Building 55) for a spring gathering hosted by Wang and the Climate Project at MIT. The initiative seeks to direct the full strength of MIT to address climate change, which Wang described as one of the defining challenges of this moment in history — and one of its greatest opportunities.“It calls on us to rethink how we power our world, how we build, how we live — and how we work together,” Wang said. “And there is no better place than MIT to lead this kind of bold, integrated effort. Our culture of curiosity, rigor, and relentless experimentation makes us uniquely suited to cross boundaries — to break down silos and build something new.”The Climate Project is organized around six missions, thematic areas in which MIT aims to make significant impact, ranging from decarbonizing industry to new policy approaches to designing resilient cities. The faculty leaders of these missions posed challenges to the crowd before circulating among the crowd to share their perspectives and to discuss community questions and ideas.Wang and the Climate Project team were joined by a number of research groups, startups, and MIT offices conducting relevant work today on issues related to energy and climate. For example, the MIT Office of Sustainability showcased efforts to use the MIT campus as a living laboratory; MIT spinouts such as Forma Systems, which is developing high-performance, low-carbon building systems, and Addis Energy, which envisions using the earth as a reactor to produce clean ammonia, presented their technologies; and visitors learned about current projects in MIT labs, including DebunkBot, an artificial intelligence-powered chatbot that can persuade people to shift their attitudes about conspiracies, developed by David Rand, the Erwin H. Schell Professor at the MIT Sloan School of Management.Benedetto Marelli, an associate professor in the Department of Civil and Environmental Engineering who leads the Wild Cards Mission, said the energy and enthusiasm that filled the room was inspiring — but that the individual conversations were equally valuable.“I was especially pleased to see so many students come out. I also spoke with other faculty, talked to staff from across the Institute, and met representatives of external companies interested in collaborating with MIT,” Marelli said. “You could see connections being made all around the room, which is exactly what we need as we build momentum for the Climate Project.” More

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      in Security

      Guardian Ag’s crop-spraying drone is replacing dangerous pilot missions

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      Every year during the growing season, thousands of pilots across the country climb into small planes loaded with hundreds of pounds of pesticides and fly extremely close to the ground at upward of 140 miles an hour, unloading their cargo onto rows of corn, cotton, and soybeans.The world of agricultural aviation is as dangerous as it is vital to America’s farms. Unfortunately, fatal crashes are common. Now Guardian Ag, founded by former MIT Electronics Research Society (MITERS) makers Adam Bercu and Charles Guan ’11, is offering an alternative in the form of a large, purpose-built drone that can autonomously deliver 200-pound payloads across farms. The company’s drones feature an 18-foot spray radius, 80-inch rotors, a custom battery pack, and aerospace-grade materials designed to make crop spraying more safe, efficient, and inexpensive for farmers.“We’re trying to bring technology to American farms that are hundreds or thousands of acres, where you’re not replacing a human with a hand pump — you’re replacing a John Deere tractor or a helicopter or an airplane,” Bercu says.“With Guardian, the operator shows up about 30 minutes before they want to spray, they mix the product, path plan the field in our app, and it gives an estimate for how long the job will take,” he says. “With our fast charging, you recharge the aircraft while you fill the tank, and those two operations take about the same amount of time.”

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      From Battlebots to farmlandsAt a young age, Bercu became obsessed with building robots. Growing up in south Florida, he’d attend robotic competitions, build prototypes, and even dumpster dive for particularly hard-to-find components. At one competition, Bercu met Charles Guan, who would go on to major in mechanical engineering at MIT, and the two robot enthusiasts became lifelong friends.“When Charles came to MIT, he basically convinced me to move to Cambridge,” Bercu says. “He said, ‘You need to come up here. I found more people like us. Hackers!’”Bercu visited Cambridge, Massachusetts, and indeed fell in love with the region’s makerspaces and hacker culture. He moved soon after, and he and Guan began spending free time at spaces including the Artisans Asylum makerspace in Somerville, Massachusetts; MIT’s International Design Center; and the MIT Electronics Research Society (MITERS) makerspace. Guan held several leadership positions at MITERS, including facilities manager, treasurer, and president.“MIT offered enormous latitude to its students to be independent and creative, which was reflected in the degree of autonomy they permit student-run organizations like MITERS to have compared to other top-tier schools,” Guan says. “It was a key selling point to me when I was touring mechanical engineering labs as a junior in high school. I was well-known in the department circle for being at MITERS all the time, possibly even more than I spent on classes.”After Guan graduated, he and Bercu started a hardware consulting business and competed in the robot combat show Battlebots. Guan also began working as a design instructor in MIT’s Department of Mechanical Engineering, where he taught a section of Course 2.007 that tasked students with building go-karts.Eventually, Guan and Bercu decided to use their experience to start a drone company.“Over the course of Battlebots and building go-karts, we knew electric batteries were getting really cheap and electric vehicle supply chains were established,” Bercu explains. “People were raising money to build eVTOL [electric vertical take-off and landing] vehicles to transport people, but we knew diesel fuel still outperformed batteries over long distances. Where electric systems did outperform combustion engines was in areas where you needed peak power for short periods of time. Basically, batteries are awesome when you have a short mission.”That idea made the founders think crop spraying could be a good early application. Bercu’s family runs an aviation business, and he knew pilots who would spray crops as their second jobs.“It’s one of those high-paying but very dangerous jobs,” Bercu says. “Even in the U.S., we lose between 1 and 2 percent of all agriculture pilots each year to fatal accidents. These people are rolling the dice every time they do this: You’re flying 6 feet off the ground at 140 miles an hour with 800 gallons of pesticide in your tank.”After cobbling together spare parts from Battlebots and their consulting business, the founders built a 600-pound drone. When they finally got it to fly, they decided the time was right to launch their company, receiving crucial early guidance and their first funding from the MIT-affiliated investment firm the E14 Fund.The founders spent the next year interviewing crop dusters and farmers. They also started engaging with the Federal Aviation Administration.“There was no category for anything like this,” Bercu explains. “With the FAA, we not only got through the approval process, we helped them build the process as we went through it, because we wanted to establish some common-sense standards.”Guardian custom-built its batteries to optimize throughput and utilization rate of its drones. Depending on the farm, Bercu says his machines can unload about 1.5 to 2 tons of payload per hour.Guardian’s drones can also spray more precisely than planes, reducing the environmental impact of pesticides, which often pollute the landscapes and waterways surrounding farms.“This thing has the precision to spray the ‘Mona Lisa’ on 20 acres, but we’re not leveraging that functionality today,” Bercu says. “For the operator we want to make it very easy. The goal is to take someone who sprays with a tractor and teach them to spray with a drone in less than a week.”Scaling for farmersTo date, Guardian Ag has built eight of its aircraft, which are actively delivering payloads over California farms in trials with paying customers. The company is currently ramping up manufacturing in its 60,000-square-foot facility in Massachusetts, and Bercu says Guardian has a backlog of hundreds of millions of dollars-worth of drones.“Grower demand has been exceptional,” Bercu says. “We don’t need to educate them on the need for this. They see the big drone with the big tank and they’re in.”Bercu envisions Guardian’s drones helping with a number of other tasks like ship-to-ship logistics, delivering supplies to offshore oil rigs, mining, and other areas where helicopters and small aircraft are currently flown through difficult terrain. But for now, the company is focused on starting with agriculture.“Agriculture is such an important and foundational aspect of our country,” says Guardian Ag chief operating officer Ashley Ferguson MBA ’19. “We work with multigenerational farming families, and when we talk to them, it’s clear aerial spray has taken hold in the industry. But there’s a large shortage of pilots, especially for agriculture applications. So, it’s clear there’s a big opportunity.”Seven years since founding Guardian, Bercu remains grateful that MIT’s community opened its doors for him when he moved to Cambridge.“Without the MIT community, this company wouldn’t be possible,” Bercu says. “I was never able to go to college, but I’d love to one day apply to MIT and do my engineering undergrad or go to the Sloan School of Management. I’ll never forget MIT’s openness to me. It’s a place I hold near and dear to my heart.” More

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      in Environment

      AI stirs up the recipe for concrete in MIT study

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      For weeks, the whiteboard in the lab was crowded with scribbles, diagrams, and chemical formulas. A research team across the Olivetti Group and the MIT Concrete Sustainability Hub (CSHub) was working intensely on a key problem: How can we reduce the amount of cement in concrete to save on costs and emissions? The question was certainly not new; materials like fly ash, a byproduct of coal production, and slag, a byproduct of steelmaking, have long been used to replace some of the cement in concrete mixes. However, the demand for these products is outpacing supply as industry looks to reduce its climate impacts by expanding their use, making the search for alternatives urgent. The challenge that the team discovered wasn’t a lack of candidates; the problem was that there were too many to sort through.On May 17, the team, led by postdoc Soroush Mahjoubi, published an open-access paper in Nature’s Communications Materials outlining their solution. “We realized that AI was the key to moving forward,” notes Mahjoubi. “There is so much data out there on potential materials — hundreds of thousands of pages of scientific literature. Sorting through them would have taken many lifetimes of work, by which time more materials would have been discovered!”With large language models, like the chatbots many of us use daily, the team built a machine-learning framework that evaluates and sorts candidate materials based on their physical and chemical properties. “First, there is hydraulic reactivity. The reason that concrete is strong is that cement — the ‘glue’ that holds it together — hardens when exposed to water. So, if we replace this glue, we need to make sure the substitute reacts similarly,” explains Mahjoubi. “Second, there is pozzolanicity. This is when a material reacts with calcium hydroxide, a byproduct created when cement meets water, to make the concrete harder and stronger over time.  We need to balance the hydraulic and pozzolanic materials in the mix so the concrete performs at its best.”Analyzing scientific literature and over 1 million rock samples, the team used the framework to sort candidate materials into 19 types, ranging from biomass to mining byproducts to demolished construction materials. Mahjoubi and his team found that suitable materials were available globally — and, more impressively, many could be incorporated into concrete mixes just by grinding them. This means it’s possible to extract emissions and cost savings without much additional processing. “Some of the most interesting materials that could replace a portion of cement are ceramics,” notes Mahjoubi. “Old tiles, bricks, pottery — all these materials may have high reactivity. That’s something we’ve observed in ancient Roman concrete, where ceramics were added to help waterproof structures. I’ve had many interesting conversations on this with Professor Admir Masic, who leads a lot of the ancient concrete studies here at MIT.”The potential of everyday materials like ceramics and industrial materials like mine tailings is an example of how materials like concrete can help enable a circular economy. By identifying and repurposing materials that would otherwise end up in landfills, researchers and industry can help to give these materials a second life as part of our buildings and infrastructure.Looking ahead, the research team is planning to upgrade the framework to be capable of assessing even more materials, while experimentally validating some of the best candidates. “AI tools have gotten this research far in a short time, and we are excited to see how the latest developments in large language models enable the next steps,” says Professor Elsa Olivetti, senior author on the work and member of the MIT Department of Materials Science and Engineering. She serves as an MIT Climate Project mission director, a CSHub principal investigator, and the leader of the Olivetti Group.“Concrete is the backbone of the built environment,” says Randolph Kirchain, co-author and CSHub director. “By applying data science and AI tools to material design, we hope to support industry efforts to build more sustainably, without compromising on strength, safety, or durability.In addition to Mahjoubi, Olivetti, and Kirchain, co-authors on the work include MIT postdoc Vineeth Venugopal, Ipek Bensu Manav SM ’21, PhD ’24; and CSHub Deputy Director Hessam AzariJafari. More

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      in Energy

      New fuel cell could enable electric aviation

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      Batteries are nearing their limits in terms of how much power they can store for a given weight. That’s a serious obstacle for energy innovation and the search for new ways to power airplanes, trains, and ships. Now, researchers at MIT and elsewhere have come up with a solution that could help electrify these transportation systems.Instead of a battery, the new concept is a kind of fuel cell — which is similar to a battery but can be quickly refueled rather than recharged. In this case, the fuel is liquid sodium metal, an inexpensive and widely available commodity. The other side of the cell is just ordinary air, which serves as a source of oxygen atoms. In between, a layer of solid ceramic material serves as the electrolyte, allowing sodium ions to pass freely through, and a porous air-facing electrode helps the sodium to chemically react with oxygen and produce electricity.In a series of experiments with a prototype device, the researchers demonstrated that this cell could carry more than three times as much energy per unit of weight as the lithium-ion batteries used in virtually all electric vehicles today. Their findings are being published today in the journal Joule, in a paper by MIT doctoral students Karen Sugano, Sunil Mair, and Saahir Ganti-Agrawal; professor of materials science and engineering Yet-Ming Chiang; and five others.“We expect people to think that this is a totally crazy idea,” says Chiang, who is the Kyocera Professor of Ceramics. “If they didn’t, I’d be a bit disappointed because if people don’t think something is totally crazy at first, it probably isn’t going to be that revolutionary.”And this technology does appear to have the potential to be quite revolutionary, he suggests. In particular, for aviation, where weight is especially crucial, such an improvement in energy density could be the breakthrough that finally makes electrically powered flight practical at significant scale.“The threshold that you really need for realistic electric aviation is about 1,000 watt-hours per kilogram,” Chiang says. Today’s electric vehicle lithium-ion batteries top out at about 300 watt-hours per kilogram — nowhere near what’s needed. Even at 1,000 watt-hours per kilogram, he says, that wouldn’t be enough to enable transcontinental or trans-Atlantic flights.That’s still beyond reach for any known battery chemistry, but Chiang says that getting to 1,000 watts per kilogram would be an enabling technology for regional electric aviation, which accounts for about 80 percent of domestic flights and 30 percent of the emissions from aviation.The technology could be an enabler for other sectors as well, including marine and rail transportation. “They all require very high energy density, and they all require low cost,” he says. “And that’s what attracted us to sodium metal.”A great deal of research has gone into developing lithium-air or sodium-air batteries over the last three decades, but it has been hard to make them fully rechargeable. “People have been aware of the energy density you could get with metal-air batteries for a very long time, and it’s been hugely attractive, but it’s just never been realized in practice,” Chiang says.By using the same basic electrochemical concept, only making it a fuel cell instead of a battery, the researchers were able to get the advantages of the high energy density in a practical form. Unlike a battery, whose materials are assembled once and sealed in a container, with a fuel cell the energy-carrying materials go in and out.The team produced two different versions of a lab-scale prototype of the system. In one, called an H cell, two vertical glass tubes are connected by a tube across the middle, which contains a solid ceramic electrolyte material and a porous air electrode. Liquid sodium metal fills the tube on one side, and air flows through the other, providing the oxygen for the electrochemical reaction at the center, which ends up gradually consuming the sodium fuel. The other prototype uses a horizontal design, with a tray of the electrolyte material holding the liquid sodium fuel. The porous air electrode, which facilitates the reaction, is affixed to the bottom of the tray. Tests using an air stream with a carefully controlled humidity level produced a level of more than 1,500 watt-hours per kilogram at the level of an individual “stack,” which would translate to over 1,000 watt-hours at the full system level, Chiang says.The researchers envision that to use this system in an aircraft, fuel packs containing stacks of cells, like racks of food trays in a cafeteria, would be inserted into the fuel cells; the sodium metal inside these packs gets chemically transformed as it provides the power. A stream of its chemical byproduct is given off, and in the case of aircraft this would be emitted out the back, not unlike the exhaust from a jet engine.But there’s a very big difference: There would be no carbon dioxide emissions. Instead the emissions, consisting of sodium oxide, would actually soak up carbon dioxide from the atmosphere. This compound would quickly combine with moisture in the air to make sodium hydroxide — a material commonly used as a drain cleaner — which readily combines with carbon dioxide to form a solid material, sodium carbonate, which in turn forms sodium bicarbonate, otherwise known as baking soda.“There’s this natural cascade of reactions that happens when you start with sodium metal,” Chiang says. “It’s all spontaneous. We don’t have to do anything to make it happen, we just have to fly the airplane.”As an added benefit, if the final product, the sodium bicarbonate, ends up in the ocean, it could help to de-acidify the water, countering another of the damaging effects of greenhouse gases.Using sodium hydroxide to capture carbon dioxide has been proposed as a way of mitigating carbon emissions, but on its own, it’s not an economic solution because the compound is too expensive. “But here, it’s a byproduct,” Chiang explains, so it’s essentially free, producing environmental benefits at no cost.Importantly, the new fuel cell is inherently safer than many other batteries, he says. Sodium metal is extremely reactive and must be well-protected. As with lithium batteries, sodium can spontaneously ignite if exposed to moisture. “Whenever you have a very high energy density battery, safety is always a concern, because if there’s a rupture of the membrane that separates the two reactants, you can have a runaway reaction,” Chiang says. But in this fuel cell, one side is just air, “which is dilute and limited. So you don’t have two concentrated reactants right next to each other. If you’re pushing for really, really high energy density, you’d rather have a fuel cell than a battery for safety reasons.”While the device so far exists only as a small, single-cell prototype, Chiang says the system should be quite straightforward to scale up to practical sizes for commercialization. Members of the research team have already formed a company, Propel Aero, to develop the technology. The company is currently housed in MIT’s startup incubator, The Engine.Producing enough sodium metal to enable widespread, full-scale global implementation of this technology should be practical, since the material has been produced at large scale before. When leaded gasoline was the norm, before it was phased out, sodium metal was used to make the tetraethyl lead used as an additive, and it was being produced in the U.S. at a capacity of 200,000 tons a year. “It reminds us that sodium metal was once produced at large scale and safely handled and distributed around the U.S.,” Chiang says.What’s more, sodium primarily originates from sodium chloride, or salt, so it is abundant, widely distributed around the world, and easily extracted, unlike lithium and other materials used in today’s EV batteries.The system they envisage would use a refillable cartridge, which would be filled with liquid sodium metal and sealed. When it’s depleted, it would be returned to a refilling station and loaded with fresh sodium. Sodium melts at 98 degrees Celsius, just below the boiling point of water, so it is easy to heat to the melting point to refuel the cartridges.Initially, the plan is to produce a brick-sized fuel cell that can deliver about 1,000 watt-hours of energy, enough to power a large drone, in order to prove the concept in a practical form that could be used for agriculture, for example. The team hopes to have such a demonstration ready within the next year.Sugano, who conducted much of the experimental work as part of her doctoral thesis and will now work at the startup, says that a key insight was the importance of moisture in the process. As she tested the device with pure oxygen, and then with air, she found that the amount of humidity in the air was crucial to making the electrochemical reaction efficient. The humid air resulted in the sodium producing its discharge products in liquid rather than solid form, making it much easier for these to be removed by the flow of air through the system. “The key was that we can form this liquid discharge product and remove it easily, as opposed to the solid discharge that would form in dry conditions,” she says.Ganti-Agrawal notes that the team drew from a variety of different engineering subfields. For example, there has been much research on high-temperature sodium, but none with a system with controlled humidity. “We’re pulling from fuel cell research in terms of designing our electrode, we’re pulling from older high-temperature battery research as well as some nascent sodium-air battery research, and kind of mushing it together,” which led to the “the big bump in performance” the team has achieved, he says.The research team also included Alden Friesen, an MIT summer intern who attends Desert Mountain High School in Scottsdale, Arizona; Kailash Raman and William Woodford of Form Energy in Somerville, Massachusetts; Shashank Sripad of And Battery Aero in California, and Venkatasubramanian Viswanathan of the University of Michigan. The work was supported by ARPA-E, Breakthrough Energy Ventures, and the National Science Foundation, and used facilities at MIT.nano. More

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      in Energy

      A new approach could fractionate crude oil using much less energy

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      Separating crude oil into products such as gasoline, diesel, and heating oil is an energy-intensive process that accounts for about 6 percent of the world’s CO2 emissions. Most of that energy goes into the heat needed to separate the components by their boiling point.In an advance that could dramatically reduce the amount of energy needed for crude oil fractionation, MIT engineers have developed a membrane that filters the components of crude oil by their molecular size.“This is a whole new way of envisioning a separation process. Instead of boiling mixtures to purify them, why not separate components based on shape and size? The key innovation is that the filters we developed can separate very small molecules at an atomistic length scale,” says Zachary P. Smith, an associate professor of chemical engineering at MIT and the senior author of the new study.The new filtration membrane can efficiently separate heavy and light components from oil, and it is resistant to the swelling that tends to occur with other types of oil separation membranes. The membrane is a thin film that can be manufactured using a technique that is already widely used in industrial processes, potentially allowing it to be scaled up for widespread use.Taehoon Lee, a former MIT postdoc who is now an assistant professor at Sungkyunkwan University in South Korea, is the lead author of the paper, which appears today in Science.Oil fractionationConventional heat-driven processes for fractionating crude oil make up about 1 percent of global energy use, and it has been estimated that using membranes for crude oil separation could reduce the amount of energy needed by about 90 percent. For this to succeed, a separation membrane needs to allow hydrocarbons to pass through quickly, and to selectively filter compounds of different sizes.Until now, most efforts to develop a filtration membrane for hydrocarbons have focused on polymers of intrinsic microporosity (PIMs), including one known as PIM-1. Although this porous material allows the fast transport of hydrocarbons, it tends to excessively absorb some of the organic compounds as they pass through the membrane, leading the film to swell, which impairs its size-sieving ability.To come up with a better alternative, the MIT team decided to try modifying polymers that are used for reverse osmosis water desalination. Since their adoption in the 1970s, reverse osmosis membranes have reduced the energy consumption of desalination by about 90 percent — a remarkable industrial success story.The most commonly used membrane for water desalination is a polyamide that is manufactured using a method known as interfacial polymerization. During this process, a thin polymer film forms at the interface between water and an organic solvent such as hexane. Water and hexane do not normally mix, but at the interface between them, a small amount of the compounds dissolved in them can react with each other.In this case, a hydrophilic monomer called MPD, which is dissolved in water, reacts with a hydrophobic monomer called TMC, which is dissolved in hexane. The two monomers are joined together by a connection known as an amide bond, forming a polyamide thin film (named MPD-TMC) at the water-hexane interface.While highly effective for water desalination, MPD-TMC doesn’t have the right pore sizes and swelling resistance that would allow it to separate hydrocarbons.To adapt the material to separate the hydrocarbons found in crude oil, the researchers first modified the film by changing the bond that connects the monomers from an amide bond to an imine bond. This bond is more rigid and hydrophobic, which allows hydrocarbons to quickly move through the membrane without causing noticeable swelling of the film compared to the polyamide counterpart.“The polyimine material has porosity that forms at the interface, and because of the cross-linking chemistry that we have added in, you now have something that doesn’t swell,” Smith says. “You make it in the oil phase, react it at the water interface, and with the crosslinks, it’s now immobilized. And so those pores, even when they’re exposed to hydrocarbons, no longer swell like other materials.”The researchers also introduced a monomer called triptycene. This shape-persistent, molecularly selective molecule further helps the resultant polyimines to form pores that are the right size for hydrocarbons to fit through.This approach represents “an important step toward reducing industrial energy consumption,” says Andrew Livingston, a professor of chemical engineering at Queen Mary University of London, who was not involved in the study.“This work takes the workhorse technology of the membrane desalination industry, interfacial polymerization, and creates a new way to apply it to organic systems such as hydrocarbon feedstocks, which currently consume large chunks of global energy,” Livingston says. “The imaginative approach using an interfacial catalyst coupled to hydrophobic monomers leads to membranes with high permeance and excellent selectivity, and the work shows how these can be used in relevant separations.”Efficient separationWhen the researchers used the new membrane to filter a mixture of toluene and triisopropylbenzene (TIPB) as a benchmark for evaluating separation performance, it was able to achieve a concentration of toluene 20 times greater than its concentration in the original mixture. They also tested the membrane with an industrially relevant mixture consisting of naphtha, kerosene, and diesel, and found that it could efficiently separate the heavier and lighter compounds by their molecular size.If adapted for industrial use, a series of these filters could be used to generate a higher concentration of the desired products at each step, the researchers say.“You can imagine that with a membrane like this, you could have an initial stage that replaces a crude oil fractionation column. You could partition heavy and light molecules and then you could use different membranes in a cascade to purify complex mixtures to isolate the chemicals that you need,” Smith says.Interfacial polymerization is already widely used to create membranes for water desalination, and the researchers believe it should be possible to adapt those processes to mass produce the films they designed in this study.“The main advantage of interfacial polymerization is it’s already a well-established method to prepare membranes for water purification, so you can imagine just adopting these chemistries into existing scale of manufacturing lines,” Lee says.The research was funded, in part, by ExxonMobil through the MIT Energy Initiative.  More

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      in Environment

      Study: Burning heavy fuel oil with scrubbers is the best available option for bulk maritime shipping

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      When the International Maritime Organization enacted a mandatory cap on the sulfur content of marine fuels in 2020, with an eye toward reducing harmful environmental and health impacts, it left shipping companies with three main options.They could burn low-sulfur fossil fuels, like marine gas oil, or install cleaning systems to remove sulfur from the exhaust gas produced by burning heavy fuel oil. Biofuels with lower sulfur content offer another alternative, though their limited availability makes them a less feasible option.While installing exhaust gas cleaning systems, known as scrubbers, is the most feasible and cost-effective option, there has been a great deal of uncertainty among firms, policymakers, and scientists as to how “green” these scrubbers are.Through a novel lifecycle assessment, researchers from MIT, Georgia Tech, and elsewhere have now found that burning heavy fuel oil with scrubbers in the open ocean can match or surpass using low-sulfur fuels, when a wide variety of environmental factors is considered.The scientists combined data on the production and operation of scrubbers and fuels with emissions measurements taken onboard an oceangoing cargo ship.They found that, when the entire supply chain is considered, burning heavy fuel oil with scrubbers was the least harmful option in terms of nearly all 10 environmental impact factors they studied, such as greenhouse gas emissions, terrestrial acidification, and ozone formation.“In our collaboration with Oldendorff Carriers to broadly explore reducing the environmental impact of shipping, this study of scrubbers turned out to be an unexpectedly deep and important transitional issue,” says Neil Gershenfeld, an MIT professor, director of the Center for Bits and Atoms (CBA), and senior author of the study.“Claims about environmental hazards and policies to mitigate them should be backed by science. You need to see the data, be objective, and design studies that take into account the full picture to be able to compare different options from an apples-to-apples perspective,” adds lead author Patricia Stathatou, an assistant professor at Georgia Tech, who began this study as a postdoc in the CBA.Stathatou is joined on the paper by Michael Triantafyllou, the Henry L. and Grace Doherty and others at the National Technical University of Athens in Greece and the maritime shipping firm Oldendorff Carriers. The research appears today in Environmental Science and Technology.Slashing sulfur emissionsHeavy fuel oil, traditionally burned by bulk carriers that make up about 30 percent of the global maritime fleet, usually has a sulfur content around 2 to 3 percent. This is far higher than the International Maritime Organization’s 2020 cap of 0.5 percent in most areas of the ocean and 0.1 percent in areas near population centers or environmentally sensitive regions.Sulfur oxide emissions contribute to air pollution and acid rain, and can damage the human respiratory system.In 2018, fewer than 1,000 vessels employed scrubbers. After the cap went into place, higher prices of low-sulfur fossil fuels and limited availability of alternative fuels led many firms to install scrubbers so they could keep burning heavy fuel oil.Today, more than 5,800 vessels utilize scrubbers, the majority of which are wet, open-loop scrubbers.“Scrubbers are a very mature technology. They have traditionally been used for decades in land-based applications like power plants to remove pollutants,” Stathatou says.A wet, open-loop marine scrubber is a huge, metal, vertical tank installed in a ship’s exhaust stack, above the engines. Inside, seawater drawn from the ocean is sprayed through a series of nozzles downward to wash the hot exhaust gases as they exit the engines.The seawater interacts with sulfur dioxide in the exhaust, converting it to sulfates — water-soluble, environmentally benign compounds that naturally occur in seawater. The washwater is released back into the ocean, while the cleaned exhaust escapes to the atmosphere with little to no sulfur dioxide emissions.But the acidic washwater can contain other combustion byproducts like heavy metals, so scientists wondered if scrubbers were comparable, from a holistic environmental point of view, to burning low-sulfur fuels.Several studies explored toxicity of washwater and fuel system pollution, but none painted a full picture.The researchers set out to fill that scientific gap.A “well-to-wake” analysisThe team conducted a lifecycle assessment using a global environmental database on production and transport of fossil fuels, such as heavy fuel oil, marine gas oil, and very-low sulfur fuel oil. Considering the entire lifecycle of each fuel is key, since producing low-sulfur fuel requires extra processing steps in the refinery, causing additional emissions of greenhouse gases and particulate matter.“If we just look at everything that happens before the fuel is bunkered onboard the vessel, heavy fuel oil is significantly more low-impact, environmentally, than low-sulfur fuels,” she says.The researchers also collaborated with a scrubber manufacturer to obtain detailed information on all materials, production processes, and transportation steps involved in marine scrubber fabrication and installation.“If you consider that the scrubber has a lifetime of about 20 years, the environmental impacts of producing the scrubber over its lifetime are negligible compared to producing heavy fuel oil,” she adds.For the final piece, Stathatou spent a week onboard a bulk carrier vessel in China to measure emissions and gather seawater and washwater samples. The ship burned heavy fuel oil with a scrubber and low-sulfur fuels under similar ocean conditions and engine settings.Collecting these onboard data was the most challenging part of the study.“All the safety gear, combined with the heat and the noise from the engines on a moving ship, was very overwhelming,” she says.Their results showed that scrubbers reduce sulfur dioxide emissions by 97 percent, putting heavy fuel oil on par with low-sulfur fuels according to that measure. The researchers saw similar trends for emissions of other pollutants like carbon monoxide and nitrous oxide.In addition, they tested washwater samples for more than 60 chemical parameters, including nitrogen, phosphorus, polycyclic aromatic hydrocarbons, and 23 metals.The concentrations of chemicals regulated by the IMO were far below the organization’s requirements. For unregulated chemicals, the researchers compared the concentrations to the strictest limits for industrial effluents from the U.S. Environmental Protection Agency and European Union.Most chemical concentrations were at least an order of magnitude below these requirements.In addition, since washwater is diluted thousands of times as it is dispersed by a moving vessel, the concentrations of such chemicals would be even lower in the open ocean.These findings suggest that the use of scrubbers with heavy fuel oil can be considered as equal to or more environmentally friendly than low-sulfur fuels across many of the impact categories the researchers studied.“This study demonstrates the scientific complexity of the waste stream of scrubbers. Having finally conducted a multiyear, comprehensive, and peer-reviewed study, commonly held fears and assumptions are now put to rest,” says Scott Bergeron, managing director at Oldendorff Carriers and co-author of the study.“This first-of-its-kind study on a well-to-wake basis provides very valuable input to ongoing discussion at the IMO,” adds Thomas Klenum, executive vice president of innovation and regulatory affairs at the Liberian Registry, emphasizing the need “for regulatory decisions to be made based on scientific studies providing factual data and conclusions.”Ultimately, this study shows the importance of incorporating lifecycle assessments into future environmental impact reduction policies, Stathatou says.“There is all this discussion about switching to alternative fuels in the future, but how green are these fuels? We must do our due diligence to compare them equally with existing solutions to see the costs and benefits,” she adds.This study was supported, in part, by Oldendorff Carriers. More