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    How to reduce greenhouse gas emissions from ammonia production

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    Ammonia is one of the most widely produced chemicals in the world, used mostly as fertilizer, but also for the production of some plastics, textiles, and other applications. Its production, through processes that require high heat and pressure, accounts for up to 20 percent of all the greenhouse gases from the entire chemical industry, so efforts have been underway worldwide to find ways to reduce those emissions.Now, researchers at MIT have come up with a clever way of combining two different methods of producing the compound that minimizes waste products, that, when combined with some other simple upgrades, could reduce the greenhouse emissions from production by as much as 63 percent, compared to the leading “low-emissions” approach being used today.The new approach is described in the journal Energy & Fuels, in a paper by MIT Energy Initiative (MITEI) Director William H. Green, graduate student Sayandeep Biswas, MITEI Director of Research Randall Field, and two others.“Ammonia has the most carbon dioxide emissions of any kind of chemical,” says Green, who is the Hoyt C. Hottel Professor in Chemical Engineering. “It’s a very important chemical,” he says, because its use as a fertilizer is crucial to being able to feed the world’s population.Until late in the 19th century, the most widely used source of nitrogen fertilizer was mined deposits of bat or bird guano, mostly from Chile, but that source was beginning to run out, and there were predictions that the world would soon be running short of food to sustain the population. But then a new chemical process, called the Haber-Bosch process after its inventors, made it possible to make ammonia out of nitrogen from the air and hydrogen, which was mostly derived from methane. But both the burning of fossil fuels to provide the needed heat and the use of methane to make the hydrogen led to massive climate-warming emissions from the process.To address this, two newer variations of ammonia production have been developed: so-called “blue ammonia,” where the greenhouse gases are captured right at the factory and then sequestered deep underground, and “green ammonia,” produced by a different chemical pathway, using electricity instead of fossil fuels to hydrolyze water to make hydrogen.Blue ammonia is already beginning to be used, with a few plants operating now in Louisiana, Green says, and the ammonia mostly being shipped to Japan, “so that’s already kind of commercial.” Other parts of the world are starting to use green ammonia, especially in places that have lots of hydropower, solar, or wind to provide inexpensive electricity, including a giant plant now under construction in Saudi Arabia.But in most places, both blue and green ammonia are still more expensive than the traditional fossil-fuel-based version, so many teams around the world have been working on ways to cut these costs as much as possible so that the difference is small enough to be made up through tax subsidies or other incentives.The problem is growing, because as the population grows, and as wealth increases, there will be ever-increasing demands for nitrogen fertilizer. At the same time, ammonia is a promising substitute fuel to power hard-to-decarbonize transportation such as cargo ships and heavy trucks, which could lead to even greater needs for the chemical.“It definitely works” as a transportation fuel, by powering fuel cells that have been demonstrated for use by everything from drones to barges and tugboats and trucks, Green says. “People think that the most likely market of that type would be for shipping,” he says, “because the downside of ammonia is it’s toxic and it’s smelly, and that makes it slightly dangerous to handle and to ship around.” So its best uses may be where it’s used in high volume and in relatively remote locations, like the high seas. In fact, the International Maritime Organization will soon be voting on new rules that might give a strong boost to the ammonia alternative for shipping.The key to the new proposed system is to combine the two existing approaches in one facility, with a blue ammonia factory next to a green ammonia factory. The process of generating hydrogen for the green ammonia plant leaves a lot of leftover oxygen that just gets vented to the air. Blue ammonia, on the other hand, uses a process called autothermal reforming that requires a source of pure oxygen, so if there’s a green ammonia plant next door, it can use that excess oxygen.“Putting them next to each other turns out to have significant economic value,” Green says. This synergy could help hybrid “blue-green ammonia” facilities serve as an important bridge toward a future where eventually green ammonia, the cleanest version, could finally dominate. But that future is likely decades away, Green says, so having the combined plants could be an important step along the way.“It might be a really long time before [green ammonia] is actually attractive” economically, he says. “Right now, it’s nowhere close, except in very special situations.” But the combined plants “could be a really appealing concept, and maybe a good way to start the industry,” because so far only small, standalone demonstration plants of the green process are being built.“If green or blue ammonia is going to become the new way of making ammonia, you need to find ways to make it relatively affordable in a lot of countries, with whatever resources they’ve got,” he says. This new proposed combination, he says, “looks like a really good idea that can help push things along. Ultimately, there’s got to be a lot of green ammonia plants in a lot of places,” and starting out with the combined plants, which could be more affordable now, could help to make that happen. The team has filed for a patent on the process.Although the team did a detailed study of both the technology and the economics that show the system has great promise, Green points out that “no one has ever built one. We did the analysis, it looks good, but surely when people build the first one, they’ll find funny little things that need some attention,” such as details of how to start up or shut down the process. “I would say there’s plenty of additional work to do to make it a real industry.” But the results of this study, which shows the costs to be much more affordable than existing blue or green plants in isolation, “definitely encourages the possibility of people making the big investments that would be needed to really make this industry feasible.”This proposed integration of the two methods “improves efficiency, reduces greenhouse gas emissions, and lowers overall cost,” says Kevin van Geem, a professor in the Center for Sustainable Chemistry at Ghent University, who was not associated with this research. “The analysis is rigorous, with validated process models, transparent assumptions, and comparisons to literature benchmarks. By combining techno-economic analysis with emissions accounting, the work provides a credible and balanced view of the trade-offs.”He adds that, “given the scale of global ammonia production, such a reduction could have a highly impactful effect on decarbonizing one of the most emissions-intensive chemical industries.”The research team also included MIT postdoc Angiras Menon and MITEI research lead Guiyan Zang. The work was supported by IHI Japan through the MIT Energy Initiative and the Martin Family Society of Fellows for Sustainability.  More

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      Report: Sustainability in supply chains is still a firm-level priority

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      Corporations are actively seeking sustainability advances in their supply chains — but many need to improve the business metrics they use in this area to realize more progress, according to a new report by MIT researchers.   During a time of shifting policies globally and continued economic uncertainty, the survey-based report finds 85 percent of companies say they are continuing supply chain sustainability practices at the same level as in recent years, or are increasing those efforts.“What we found is strong evidence that sustainability still matters,” says Josué Velázquez Martínez, a research scientist and director of the MIT Sustainable Supply Chain Lab, which helped produce the report. “There are many things that remain to be done to accomplish those goals, but there’s a strong willingness from companies in all parts of the world to do something about sustainability.”The new analysis, titled “Sustainability Still Matters,” was released today. It is the sixth annual report on the subject prepared by the MIT Sustainable Supply Chain Lab, which is part of MIT’s Center for Transportation and Logistics. The Council of Supply Chain Management Professionals collaborated on the project as well.The report is based on a global survey, with responses from 1,203 professionals in 97 countries. This year, the report analyzes three issues in depth, including regulations and the role they play in corporate approaches to supply chain management. A second core topic is management and mitigation of what industry professionals call “Scope 3” emissions, which are those not from a firm itself, but from a firm’s supply chain. And a third issue of focus is the future of freight transportation, which by itself accounts for a substantial portion of supply chain emissions.Broadly, the survey finds that for European-based firms, the principal driver of action in this area remains government mandates, such as the Corporate Sustainability Reporting Directive, which requires companies to publish regular reports on their environmental impact and the risks to society involved. In North America, firm leadership and investor priorities are more likely to be decisive factors in shaping a company’s efforts.“In Europe the pressure primarily comes more from regulation, but in the U.S. it comes more from investors, or from competitors,” Velázquez Martínez says.The survey responses on Scope 3 emissions reveal a number of opportunities for improvement. In business and sustainability terms, Scope 1 greenhouse gas emissions are those a firm produces directly. Scope 2 emissions are the energy it has purchased. And Scope 3 emissions are those produced across a firm’s value chain, including the supply chain activities involved in producing, transporting, using, and disposing of its products.The report reveals that about 40 percent of firms keep close track of Scope 1 and 2 emissions, but far fewer tabulate Scope 3 on equivalent terms. And yet Scope 3 may account for roughly 75 percent of total firm emissions, on aggregate. About 70 percent of firms in the survey say they do not have enough data from suppliers to accurately tabulate the total greenhouse gas and climate impact of their supply chains.Certainly it can be hard to calculate the total emissions when a supply chain has many layers, including smaller suppliers lacking data capacity. But firms can upgrade their analytics in this area, too. For instance, 50 percent of North American firms are still using spreadsheets to tabulate emissions data, often making rough estimates that correlate emissions to simple economic activity. An alternative is life cycle assessment software that provides more sophisticated estimates of a product’s emissions, from the extraction of its materials to its post-use disposal. By contrast, only 32 percent of European firms are still using spreadsheets rather than life cycle assessment tools.“You get what you measure,” Velázquez Martínez says. “If you measure poorly, you’re going to get poor decisions that most likely won’t drive the reductions you’re expecting. So we pay a lot of attention to that particular issue, which is decisive to defining an action plan. Firms pay a lot of attention to metrics in their financials, but in sustainability they’re often using simplistic measurements.”When it comes to transportation, meanwhile, the report shows that firms are still grappling with the best ways to reduce emissions. Some see biofuels as the best short-term alternative to fossil fuels; others are investing in electric vehicles; some are waiting for hydrogen-powered vehicles to gain traction. Supply chains, after all, frequently involve long-haul trips. For firms, as for individual consumers, electric vehicles are more practical with a larger infrastructure of charging stations. There are advances on that front but more work to do as well.That said, “Transportation has made a lot of progress in general,” Velázquez Martínez says, noting the increased acceptance of new modes of vehicle power in general.Even as new technologies loom on the horizon, though, supply chain sustainability is not wholly depend on their introduction. One factor continuing to propel sustainability in supply chains is the incentives companies have to lower costs. In a competitive business environment, spending less on fossil fuels usually means savings. And firms can often find ways to alter their logistics to consume and spend less.“Along with new technologies, there is another side of supply chain sustainability that is related to better use of the current infrastructure,” Velázquez Martínez observes. “There is always a need to revise traditional ways of operating to find opportunities for more efficiency.”  More

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      Concrete “battery” developed at MIT now packs 10 times the power

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      Concrete already builds our world, and now it’s one step closer to powering it, too. Made by combining cement, water, ultra-fine carbon black (with nanoscale particles), and electrolytes, electron-conducting carbon concrete (ec3, pronounced “e-c-cubed”) creates a conductive “nanonetwork” inside concrete that could enable everyday structures like walls, sidewalks, and bridges to store and release electrical energy. In other words, the concrete around us could one day double as giant “batteries.”As MIT researchers report in a new PNAS paper, optimized electrolytes and manufacturing processes have increased the energy storage capacity of the latest ec3 supercapacitors by an order of magnitude. In 2023, storing enough energy to meet the daily needs of the average home would have required about 45 cubic meters of ec3, roughly the amount of concrete used in a typical basement. Now, with the improved electrolyte, that same task can be achieved with about 5 cubic meters, the volume of a typical basement wall.“A key to the sustainability of concrete is the development of ‘multifunctional concrete,’ which integrates functionalities like this energy storage, self-healing, and carbon sequestration. Concrete is already the world’s most-used construction material, so why not take advantage of that scale to create other benefits?” asks Admir Masic, lead author of the new study, MIT Electron-Conducting Carbon-Cement-Based Materials Hub (EC³ Hub) co-director, and associate professor of civil and environmental engineering (CEE) at MIT.The improved energy density was made possible by a deeper understanding of how the nanocarbon black network inside ec3 functions and interacts with electrolytes. Using focused ion beams for the sequential removal of thin layers of the ec3 material, followed by high-resolution imaging of each slice with a scanning electron microscope (a technique called FIB-SEM tomography), the team across the EC³ Hub and MIT Concrete Sustainability Hub was able to reconstruct the conductive nanonetwork at the highest resolution yet. This approach allowed the team to discover that the network is essentially a fractal-like “web” that surrounds ec3 pores, which is what allows the electrolyte to infiltrate and for current to flow through the system. “Understanding how these materials ‘assemble’ themselves at the nanoscale is key to achieving these new functionalities,” adds Masic.Equipped with their new understanding of the nanonetwork, the team experimented with different electrolytes and their concentrations to see how they impacted energy storage density. As Damian Stefaniuk, first author and EC³ Hub research scientist, highlights, “we found that there is a wide range of electrolytes that could be viable candidates for ec3. This even includes seawater, which could make this a good material for use in coastal and marine applications, perhaps as support structures for offshore wind farms.”At the same time, the team streamlined the way they added electrolytes to the mix. Rather than curing ec3 electrodes and then soaking them in electrolyte, they added the electrolyte directly into the mixing water. Since electrolyte penetration was no longer a limitation, the team could cast thicker electrodes that stored more energy.The team achieved the greatest performance when they switched to organic electrolytes, especially those that combined quaternary ammonium salts — found in everyday products like disinfectants — with acetonitrile, a clear, conductive liquid often used in industry. A cubic meter of this version of ec3 — about the size of a refrigerator — can store over 2 kilowatt-hours of energy. That’s about enough to power an actual refrigerator for a day.While batteries maintain a higher energy density, ec3 can in principle be incorporated directly into a wide range of architectural elements — from slabs and walls to domes and vaults — and last as long as the structure itself.“The Ancient Romans made great advances in concrete construction. Massive structures like the Pantheon stand to this day without reinforcement. If we keep up their spirit of combining material science with architectural vision, we could be at the brink of a new architectural revolution with multifunctional concretes like ec3,” proposes Masic.Taking inspiration from Roman architecture, the team built a miniature ec3 arch to show how structural form and energy storage can work together. Operating at 9 volts, the arch supported its own weight and additional load while powering an LED light.However, something unique happened when the load on the arch increased: the light flickered. This is likely due to the way stress impacts electrical contacts or the distribution of charges. “There may be a kind of self-monitoring capacity here. If we think of an ec3 arch at architectural scale, its output may fluctuate when it’s impacted by a stressor like high winds. We may be able to use this as a signal of when and to what extent a structure is stressed, or monitor its overall health in real time,” envisions Masic.The latest developments in ec³ technology bring it a step closer to real-world scalability. It’s already been used to heat sidewalk slabs in Sapporo, Japan, due to its thermally conductive properties, representing a potential alternative to salting. “With these higher energy densities and demonstrated value across a broader application space, we now have a powerful and flexible tool that can help us address a wide range of persistent energy challenges,” explains Stefaniuk. “One of our biggest motivations was to help enable the renewable energy transition. Solar power, for example, has come a long way in terms of efficiency. However, it can only generate power when there’s enough sunlight. So, the question becomes: How do you meet your energy needs at night, or on cloudy days?”Franz-Josef Ulm, EC³ Hub co-director and CEE professor, continues the thread: “The answer is that you need a way to store and release energy. This has usually meant a battery, which often relies on scarce or harmful materials. We believe that ec3 is a viable substitute, letting our buildings and infrastructure meet our energy storage needs.” The team is working toward applications like parking spaces and roads that could charge electric vehicles, as well as homes that can operate fully off the grid.“What excites us most is that we’ve taken a material as ancient as concrete and shown that it can do something entirely new,” says James Weaver, a co-author on the paper who is an associate professor of design technology and materials science and engineering at Cornell University, as well as a former EC³ Hub researcher. “By combining modern nanoscience with an ancient building block of civilization, we’re opening a door to infrastructure that doesn’t just support our lives, it powers them.” More

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      in Environment

      A beacon of light

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      Placing a lit candle in a window to welcome friends and strangers is an old Irish tradition that took on greater significance when Mary Robinson was elected president of Ireland in 1990. At the time, Robinson placed a lamp in Áras an Uachtaráin — the official residence of Ireland’s presidents — noting that the Irish diaspora and all others are always welcome in Ireland. Decades later, a lit lamp remains in a window in Áras an Uachtaráin.The symbolism of Robinson’s lamp was shared by Hashim Sarkis, dean of the MIT School of Architecture and Planning (SA+P), at the school’s graduation ceremony in May, where Robinson addressed the class of 2025. To replicate the generous intentions of Robinson’s lamp and commemorate her visit to MIT, Sarkis commissioned a unique lantern as a gift for Robinson. He commissioned an identical one for his office, which is in the front portico of MIT at 77 Massachusetts Ave.“The lamp will welcome all citizens of the world to MIT,” says Sarkis.

      Geolectric: Sustainable, Low-Carbon Ceramics for Embedded Electronics and Interaction DesignVideo: MIT Design Intelligence Lab

      No ordinary lanternThe bespoke lantern was created by Marcelo Coelho SM ’08, PhD ’12, director of the Design Intelligence Lab and associate professor of the practice in the Department of Architecture.One of several projects in the Geoletric research at the Design Intelligence Lab, the lantern showcases the use of geopolymers as a sustainable material alternative for embedded computers and consumer electronics.“The materials that we use to make computers have a negative impact on climate, so we’re rethinking how we make products with embedded electronics — such as a lamp or lantern — from a climate perspective,” says Coelho.Consumer electronics rely on materials that are high in carbon emissions and difficult to recycle. As the demand for embedded computing increases, so too does the need for alternative materials that have a reduced environmental impact while supporting electronic functionality.The Geolectric lantern advances the formulation and application of geopolymers — a class of inorganic materials that form covalently bonded, non-crystalline networks. Unlike traditional ceramics, geopolymers do not require high-temperature firing, allowing electronic components to be embedded seamlessly during production.Geopolymers are similar to ceramics, but have a lower carbon footprint and present a sustainable alternative for consumer electronics, product design, and architecture. The minerals Coelho uses to make the geopolymers — aluminum silicate and sodium silicate — are those regularly used to make ceramics.“Geopolymers aren’t particularly new, but are becoming more popular,” says Coelho. “They have high strength in both tension and compression, superior durability, fire resistance, and thermal insulation. Compared to concrete, geopolymers don’t release carbon dioxide. Compared to ceramics, you don’t have to worry about firing them. What’s even more interesting is that they can be made from industrial byproducts and waste materials, contributing to a circular economy and reducing waste.”The lantern is embedded with custom electronics that serve as a proximity and touch sensor. When a hand is placed over the top, light shines down the glass tubes.The timeless design of the Geoelectric lantern — minimalist, composed of natural materials — belies its future-forward function. Coelho’s academic background is in fine arts and computer science. Much of his work, he says, “bridges these two worlds.”Working at the Design Intelligence Lab with Coelho on the lanterns are Jacob Payne, a graduate architecture student, and Jean-Baptiste Labrune, a research affiliate.A light for MITA few weeks before commencement, Sarkis saw the Geoelectric lantern in Palazzo Diedo Berggruen Arts and Culture in Venice, Italy. The exhibition, a collateral event of the Venice Biennale’s 19th International Architecture Exhibition, featured the work of 40 MIT architecture faculty.The sustainability feature of Geolectric is the key reason Sarkis regarded the lantern as the perfect gift for Robinson. After her career in politics, Robinson founded the Mary Robinson Foundation — Climate Justice, an international center addressing the impacts of climate change on marginalized communities.The third iteration of Geolectric for Sarkis’ office is currently underway. While the lantern was a technical prototype and an opportunity to showcase his lab’s research, Coelho — an immigrant from Brazil — was profoundly touched by how Sarkis created the perfect symbolism to both embody the welcoming spirit of the school and honor President Robinson.“When the world feels most fragile, we need to urgently find sustainable and resilient solutions for our built environment. It’s in the darkest times when we need light the most,” says Coelho.  More

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      MIT’s work with Idaho National Laboratory advances America’s nuclear industry

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      At the center of nuclear reactors across the United States, a new type of chromium-coated fuel is being used to make the reactors more efficient and more resistant to accidents. The fuel is one of many innovations sprung from collaboration between researchers at MIT and the Idaho National Laboratory (INL) — a relationship that has altered the trajectory of the country’s nuclear industry.Amid renewed excitement around nuclear energy in America, MIT’s research community is working to further develop next-generation fuels, accelerate the deployment of small modular reactors (SMRs), and enable the first nuclear reactor in space.Researchers at MIT and INL have worked closely for decades, and the collaboration takes many forms, including joint research efforts, student and postdoc internships, and a standing agreement that lets INL employees spend extended periods on MIT’s campus researching and teaching classes. MIT is also a founding member of the Battelle Energy Alliance, which has managed the Idaho National Laboratory for the Department of Energy since 2005.The collaboration gives MIT’s community a chance to work on the biggest problems facing America’s nuclear industry while bolstering INL’s research infrastructure.“The Idaho National Laboratory is the lead lab for nuclear energy technology in the United States today — that’s why it’s essential that MIT works hand in hand with INL,” says Jacopo Buongiorno, the Battelle Energy Alliance Professor in Nuclear Science and Engineering at MIT. “Countless MIT students and postdocs have interned at INL over the years, and a memorandum of understanding that strengthened the collaboration between MIT and INL in 2019 has been extended twice.”Ian Waitz, MIT’s vice president for research, adds, “The strong collaborative history between MIT and the Idaho National Laboratory enables us to jointly contribute practical technologies to enable the growth of clean, safe nuclear energy. It’s a clear example of how rigorous collaboration across sectors, and among the nation’s top research facilities, can advance U.S. economic prosperity, health, and well-being.”Research with impactMuch of MIT’s joint research with INL involves tests and simulations of new nuclear materials, fuels, and instrumentation. One of the largest collaborations was part of a global push for more accident-tolerant fuels in the wake of the nuclear accident that followed the 2011 earthquake and tsunami in Fukushima, Japan.In a series of studies involving INL and members of the nuclear energy industry, MIT researchers helped identify and evaluate alloy materials that could be deployed in the near term to not only bolster safety but also offer higher densities of fuel.“These new alloys can withstand much more challenging conditions during abnormal occurrences without reacting chemically with steam, which could result in hydrogen explosions during accidents,” explains Buongiorno, who is also the director of science and technology at MIT’s Nuclear Reactor Laboratory and the director of MIT’s Center for Advanced Nuclear Energy Systems. “The fuels can take much more abuse without breaking apart in the reactor, resulting in a higher safety margin.”The fuels tested at MIT were eventually adopted by power plants across the U.S., starting with the Byron Clean Energy Center in Ogle County, Illinois.“We’re also developing new materials, fuels, and instrumentation,” Buongiorno says. “People don’t just come to MIT and say, ‘I have this idea, evaluate it for me.’ We collaborate with industry and national labs to develop the new ideas together, and then we put them to the test,  reproducing the environment in which these materials and fuels would operate in commercial power reactors. That capability is quite unique.”Another major collaboration was led by Koroush Shirvan, MIT’s Atlantic Richfield Career Development Professor in Energy Studies. Shirvan’s team analyzed the costs associated with different reactor designs, eventually developing an open-source tool to help industry leaders evaluate the feasibility of different approaches.“The reason we’re not building a single nuclear reactor in the U.S. right now is cost and financial risk,” Shirvan says. “The projects have gone over budget by a factor of two and their schedule has lengthened by a factor of 1.5, so we’ve been doing a lot of work assessing the risk drivers. There’s also a lot of different types of reactors proposed, so we’ve looked at their cost potential as well and how those costs change if you can mass manufacture them.”Other INL-supported research of Shirvan’s involves exploring new manufacturing methods for nuclear fuels and testing materials for use in a nuclear reactor on the surface of the moon.“You want materials that are lightweight for these nuclear reactors because you have to send them to space, but there isn’t much data around how those light materials perform in nuclear environments,” Shirvan says.People and progressEvery summer, MIT students at every level travel to Idaho to conduct research in INL labs as interns.“It’s an example of our students getting access to cutting-edge research facilities,” Shirvan says.There are also several joint research appointments between the institutions. One such appointment is held by Sacit Cetiner, a distinguished scientist at INL who also currently runs the MIT and INL Joint Center for Reactor Instrumentation and Sensor Physics (CRISP) at MIT’s Nuclear Reactor Laboratory.CRISP focuses its research on key technology areas in the field of instrumentation and controls, which have long stymied the bottom line of nuclear power generation.“For the current light-water reactor fleet, operations and maintenance expenditures constitute a sizeable fraction of unit electricity generation cost,” says Cetiner. “In order to make advanced reactors economically competitive, it’s much more reasonable to address anticipated operational issues during the design phase. One such critical technology area is remote and autonomous operations. Working directly with INL, which manages the projects for the design and testing of several advanced reactors under a number of federal programs, gives our students, faculty, and researchers opportunities to make a real impact.”The sharing of experts helps strengthen MIT and the nation’s nuclear workforce overall.“MIT has a crucial role to play in advancing the country’s nuclear industry, whether that’s testing and developing new technologies or assessing the economic feasibility of new nuclear designs,” Buongiorno says. More

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      Lidar helps gas industry find methane leaks and avoid costly losses

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      Each year, the U.S. energy industry loses an estimated 3 percent of its natural gas production, valued at $1 billion in revenue, to leaky infrastructure. Escaping invisibly into the air, these methane gas plumes can now be detected, imaged, and measured using a specialized lidar flown on small aircraft.This lidar is a product of Bridger Photonics, a leading methane-sensing company based in Bozeman, Montana. MIT Lincoln Laboratory developed the lidar’s optical-power amplifier, a key component of the system, by advancing its existing slab-coupled optical waveguide amplifier (SCOWA) technology. The methane-detecting lidar is 10 to 50 times more capable than other airborne remote sensors on the market.”This drone-capable sensor for imaging methane is a great example of Lincoln Laboratory technology at work, matched with an impactful commercial application,” says Paul Juodawlkis, who pioneered the SCOWA technology with Jason Plant in the Advanced Technology Division and collaborated with Bridger Photonics to enable its commercial application.Today, the product is being adopted widely, including by nine of the top 10 natural gas producers in the United States. “Keeping gas in the pipe is good for everyone — it helps companies bring the gas to market, improves safety, and protects the outdoors,” says Pete Roos, founder and chief innovation officer at Bridger. “The challenge with methane is that you can’t see it. We solved a fundamental problem with Lincoln Laboratory.”A laser source “miracle”In 2014, the Advanced Research Projects Agency-Energy (ARPA-E) was seeking a cost-effective and precise way to detect methane leaks. Highly flammable and a potent pollutant, methane gas (the primary constituent of natural gas) moves through the country via a vast and intricate pipeline network. Bridger submitted a research proposal in response to ARPA-E’s call and was awarded funding to develop a small, sensitive aerial lidar.Aerial lidar sends laser light down to the ground and measures the light that reflects back to the sensor. Such lidar is often used for producing detailed topography maps. Bridger’s idea was to merge topography mapping with gas measurements. Methane absorbs light at the infrared wavelength of 1.65 microns. Operating a laser at that wavelength could allow a lidar to sense the invisible plumes and measure leak rates.”This laser source was one of the hardest parts to get right. It’s a key element,” Roos says. His team needed a laser source with specific characteristics to emit powerfully enough at a wavelength of 1.65 microns to work from useful altitudes. Roos recalled the ARPA-E program manager saying they needed a “miracle” to pull it off.Through mutual connections, Bridger was introduced to a Lincoln Laboratory technology for optically amplifying laser signals: the SCOWA. When Bridger contacted Juodawlkis and Plant, they had been working on SCOWAs for a decade. Although they had never investigated SCOWAs at 1.65 microns, they thought that the fundamental technology could be extended to operate at that wavelength. Lincoln Laboratory received ARPA-E funding to develop 1.65-micron SCOWAs and provide prototype units to Bridger for incorporation into their gas-mapping lidar systems.”That was the miracle we needed,” Roos says.A legacy in laser innovationLincoln Laboratory has long been a leader in semiconductor laser and optical emitter technology. In 1962, the laboratory was among the first to demonstrate the diode laser, which is now the most widespread laser used globally. Several spinout companies, such as Lasertron and TeraDiode, have commercialized innovations stemming from the laboratory’s laser research, including those for fiber-optic telecommunications and metal-cutting applications.In the early 2000s, Juodawlkis, Plant, and others at the laboratory recognized a need for a stable, powerful, and bright single-mode semiconductor optical amplifier, which could enhance lidar and optical communications. They developed the SCOWA (slab-coupled optical waveguide amplifier) concept by extending earlier work on slab-coupled optical waveguide lasers (SCOWLs). The initial SCOWA was funded under the laboratory’s internal technology investment portfolio, a pool of R&D funding provided by the undersecretary of defense for research and engineering to seed new technology ideas. These ideas often mature into sponsored programs or lead to commercialized technology.”Soon, we developed a semiconductor optical amplifier that was 10 times better than anything that had ever been demonstrated before,” Plant says. Like other semiconductor optical amplifiers, the SCOWA guides laser light through semiconductor material. This process increases optical power as the laser light interacts with electrons, causing them to shed photons at the same wavelength as the input laser. The SCOWA’s unique light-guiding design enables it to reach much higher output powers, creating a powerful and efficient beam. They demonstrated SCOWAs at various wavelengths and applied the technology to projects for the Department of Defense.When Bridger Photonics reached out to Lincoln Laboratory, the most impactful application of the device yet emerged. Working iteratively through the ARPA-E funding and a Cooperative Research and Development Agreement (CRADA), the team increased Bridger’s laser power by more than tenfold. This power boost enabled them to extend the range of the lidar to elevations over 1,000 feet.”Lincoln Laboratory had the knowledge of what goes on inside the optical amplifier — they could take our input, adjust the recipe, and make a device that worked very well for us,” Roos says.The Gas Mapping Lidar was commercially released in 2019. That same year, the product won an R&D 100 Award, recognizing it as a revolutionary advancement in the marketplace.A technology transfer takes offToday, the United States is the world’s largest natural gas supplier, driving growth in the methane-sensing market. Bridger Photonics deploys its Gas Mapping Lidar for customers nationwide, attaching the sensor to planes and drones and pinpointing leaks across the entire supply chain, from where gas is extracted, piped through the country, and delivered to businesses and homes. Customers buy the data from these scans to efficiently locate and repair leaks in their gas infrastructure. In January 2025, the Environmental Protection Agency provided regulatory approval for the technology.According to Bruce Niemeyer, president of Chevron’s shale and tight operations, the lidar capability has been game-changing: “Our goal is simple — keep methane in the pipe. This technology helps us assure we are doing that … It can find leaks that are 10 times smaller than other commercial providers are capable of spotting.”At Lincoln Laboratory, researchers continue to innovate new devices in the national interest. The SCOWA is one of many technologies in the toolkit of the laboratory’s Microsystems Prototyping Foundry, which will soon be expanded to include a new Compound Semiconductor Laboratory – Microsystem Integration Facility. Government, industry, and academia can access these facilities through government-funded projects, CRADAs, test agreements, and other mechanisms.At the direction of the U.S. government, the laboratory is also seeking industry transfer partners for a technology that couples SCOWA with a photonic integrated circuit platform. Such a platform could advance quantum computing and sensing, among other applications.”Lincoln Laboratory is a national resource for semiconductor optical emitter technology,” Juodawlkis says. More

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      in Energy

      New self-assembling material could be the key to recyclable EV batteries

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      Today’s electric vehicle boom is tomorrow’s mountain of electronic waste. And while myriad efforts are underway to improve battery recycling, many EV batteries still end up in landfills.A research team from MIT wants to help change that with a new kind of self-assembling battery material that quickly breaks apart when submerged in a simple organic liquid. In a new paper published in Nature Chemistry, the researchers showed the material can work as the electrolyte in a functioning, solid-state battery cell and then revert back to its original molecular components in minutes.The approach offers an alternative to shredding the battery into a mixed, hard-to-recycle mass. Instead, because the electrolyte serves as the battery’s connecting layer, when the new material returns to its original molecular form, the entire battery disassembles to accelerate the recycling process.“So far in the battery industry, we’ve focused on high-performing materials and designs, and only later tried to figure out how to recycle batteries made with complex structures and hard-to-recycle materials,” says the paper’s first author Yukio Cho PhD ’23. “Our approach is to start with easily recyclable materials and figure out how to make them battery-compatible. Designing batteries for recyclability from the beginning is a new approach.”Joining Cho on the paper are PhD candidate Cole Fincher, Ty Christoff-Tempesta PhD ’22, Kyocera Professor of Ceramics Yet-Ming Chiang, Visiting Associate Professor Julia Ortony, Xiaobing Zuo, and Guillaume Lamour.Better batteriesThere’s a scene in one of the “Harry Potter” films where Professor Dumbledore cleans a dilapidated home with the flick of the wrist and a spell. Cho says that image stuck with him as a kid. (What better way to clean your room?) When he saw a talk by Ortony on engineering molecules so that they could assemble into complex structures and then revert back to their original form, he wondered if it could be used to make battery recycling work like magic.That would be a paradigm shift for the battery industry. Today, batteries require harsh chemicals, high heat, and complex processing to recycle. There are three main parts of a battery: the positively charged cathode, the negatively charged electrode, and the electrolyte that shuttles lithium ions between them. The electrolytes in most lithium-ion batteries are highly flammable and degrade over time into toxic byproducts that require specialized handling.To simplify the recycling process, the researchers decided to make a more sustainable electrolyte. For that, they turned to a class of molecules that self-assemble in water, named aramid amphiphiles (AAs), whose chemical structures and stability mimic that of Kevlar. The researchers further designed the AAs to contain polyethylene glycol (PEG), which can conduct lithium ions, on one end of each molecule. When the molecules are exposed to water, they spontaneously form nanoribbons with ion-conducting PEG surfaces and bases that imitate the robustness of Kevlar through tight hydrogen bonding. The result is a mechanically stable nanoribbon structure that conducts ions across its surface.“The material is composed of two parts,” Cho explains. “The first part is this flexible chain that gives us a nest, or host, for lithium ions to jump around. The second part is this strong organic material component that is used in the Kevlar, which is a bulletproof material. Those make the whole structure stable.”When added to water, the nanoribbons self-assemble to form millions of nanoribbons that can be hot-pressed into a solid-state material.“Within five minutes of being added to water, the solution becomes gel-like, indicating there are so many nanofibers formed in the liquid that they start to entangle each other,” Cho says. “What’s exciting is we can make this material at scale because of the self-assembly behavior.”The team tested the material’s strength and toughness, finding it could endure the stresses associated with making and running the battery. They also constructed a solid-state battery cell that used lithium iron phosphate for the cathode and lithium titanium oxide as the anode, both common materials in today’s batteries. The nanoribbons moved lithium ions successfully between the electrodes, but a side-effect known as polarization limited the movement of lithium ions into the battery’s electrodes during fast bouts of charging and discharging, hampering its performance compared to today’s gold-standard commercial batteries.“The lithium ions moved along the nanofiber all right, but getting the lithium ion from the nanofibers to the metal oxide seems to be the most sluggish point of the process,” Cho says.When they immersed the battery cell into organic solvents, the material immediately dissolved, with each part of the battery falling away for easier recycling. Cho compared the materials’ reaction to cotton candy being submerged in water.“The electrolyte holds the two battery electrodes together and provides the lithium-ion pathways,” Cho says. “So, when you want to recycle the battery, the entire electrolyte layer can fall off naturally and you can recycle the electrodes separately.”Validating a new approachCho says the material is a proof of concept that demonstrates the recycle-first approach.“We don’t want to say we solved all the problems with this material,” Cho says. “Our battery performance was not fantastic because we used only this material as the entire electrolyte for the paper, but what we’re picturing is using this material as one layer in the battery electrolyte. It doesn’t have to be the entire electrolyte to kick off the recycling process.”Cho also sees a lot of room for optimizing the material’s performance with further experiments.Now, the researchers are exploring ways to integrate these kinds of materials into existing battery designs as well as implementing the ideas into new battery chemistries.“It’s very challenging to convince existing vendors to do something very differently,” Cho says. “But with new battery materials that may come out in five or 10 years, it could be easier to integrate this into new designs in the beginning.”Cho also believes the approach could help reshore lithium supplies by reusing materials from batteries that are already in the U.S.“People are starting to realize how important this is,” Cho says. “If we can start to recycle lithium-ion batteries from battery waste at scale, it’ll have the same effect as opening lithium mines in the U.S. Also, each battery requires a certain amount of lithium, so extrapolating out the growth of electric vehicles, we need to reuse this material to avoid massive lithium price spikes.”The work was supported, in part, by the National Science Foundation and the U.S. Department of Energy. 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      in Environment

      After more than a decade of successes, ESI’s work will spread out across the Institute

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      MIT’s Environmental Solutions Initiative (ESI), a pioneering cross-disciplinary body that helped give a major boost to sustainability and solutions to climate change at MIT, will close as a separate entity at the end of June. But that’s far from the end for its wide-ranging work, which will go forward under different auspices. Many of its key functions will become part of MIT’s recently launched Climate Project. John Fernandez, head of ESI for nearly a decade, will return to the School of Architecture and Planning, where some of ESI’s important work will continue as part of a new interdisciplinary lab.When the ideas that led to the founding of MIT’s Environmental Solutions Initiative first began to be discussed, its founders recall, there was already a great deal of work happening at MIT relating to climate change and sustainability. As Professor John Sterman of the MIT Sloan School of Management puts it, “there was a lot going on, but it wasn’t integrated. So the whole added up to less than the sum of its parts.”ESI was founded in 2014 to help fill that coordinating role, and in the years since it has accomplished a wide range of significant milestones in research, education, and communication about sustainable solutions in a wide range of areas. Its founding director, Professor Susan Solomon, helmed it for its first year, and then handed the leadership to Fernandez, who has led it since 2015.“There wasn’t much of an ecosystem [on sustainability] back then,” Solomon recalls. But with the help of ESI and some other entities, that ecosystem has blossomed. She says that Fernandez “has nurtured some incredible things under ESI,” including work on nature-based climate solutions, and also other areas such as sustainable mining, and reduction of plastics in the environment.Desiree Plata, director of MIT’s Climate and Sustainability Consortium and associate professor of civil and environmental engineering, says that one key achievement of the initiative has been in “communication with the external world, to help take really complex systems and topics and put them in not just plain-speak, but something that’s scientifically rigorous and defensible, for the outside world to consume.”In particular, ESI has created three very successful products, which continue under the auspices of the Climate Project. These include the popular TIL Climate Podcast, the Webby Award-winning Climate Portal website, and the online climate primer developed with Professor Kerry Emanuel. “These are some of the most frequented websites at MIT,” Plata says, and “the impact of this work on the global knowledge base cannot be overstated.”Fernandez says that ESI has played a significant part in helping to catalyze what has become “a rich institutional landscape of work in sustainability and climate change” at MIT. He emphasizes three major areas where he feels the ESI has been able to have the most impact: engaging the MIT community, initiating and stewarding critical environmental research, and catalyzing efforts to promote sustainability as fundamental to the mission of a research university.Engagement of the MIT community, he says, began with two programs: a research seed grant program and the creation of MIT’s undergraduate minor in environment and sustainability, launched in 2017.ESI also created a Rapid Response Group, which gave students a chance to work on real-world projects with external partners, including government agencies, community groups, nongovernmental organizations, and businesses. In the process, they often learned why dealing with environmental challenges in the real world takes so much longer than they might have thought, he says, and that a challenge that “seemed fairly straightforward at the outset turned out to be more complex and nuanced than expected.”The second major area, initiating and stewarding environmental research, grew into a set of six specific program areas: natural climate solutions, mining, cities and climate change, plastics and the environment, arts and climate, and climate justice.These efforts included collaborations with a Nobel Peace Prize laureate, three successive presidential administrations from Colombia, and members of communities affected by climate change, including coal miners, indigenous groups, various cities, companies, the U.N., many agencies — and the popular musical group Coldplay, which has pledged to work toward climate neutrality for its performances. “It was the role that the ESI played as a host and steward of these research programs that may serve as a key element of our legacy,” Fernandez says.The third broad area, he says, “is the idea that the ESI as an entity at MIT would catalyze this movement of a research university toward sustainability as a core priority.” While MIT was founded to be an academic partner to the industrialization of the world, “aren’t we in a different world now? The kind of massive infrastructure planning and investment and construction that needs to happen to decarbonize the energy system is maybe the largest industrialization effort ever undertaken. Even more than in the recent past, the set of priorities driving this have to do with sustainable development.”Overall, Fernandez says, “we did everything we could to infuse the Institute in its teaching and research activities with the idea that the world is now in dire need of sustainable solutions.”Fernandez “has nurtured some incredible things under ESI,” Solomon says. “It’s been a very strong and useful program, both for education and research.” But it is appropriate at this time to distribute its projects to other venues, she says. “We do now have a major thrust in the Climate Project, and you don’t want to have redundancies and overlaps between the two.”Fernandez says “one of the missions of the Climate Project is really acting to coalesce and aggregate lots of work around MIT.” Now, with the Climate Project itself, along with the Climate Policy Center and the Center for Sustainability Science and Strategy, it makes more sense for ESI’s climate-related projects to be integrated into these new entities, and other projects that are less directly connected to climate to take their places in various appropriate departments or labs, he says.“We did enough with ESI that we made it possible for these other centers to really flourish,” he says. “And in that sense, we played our role.”As of June 1, Fernandez has returned to his role as professor of architecture and urbanism and building technology in the School of Architecture and Planning, where he directs the Urban Metabolism Group. He will also be starting up a new group called Environment ResearchAction (ERA) to continue ESI work in cities, nature, and artificial intelligence.  More

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      in Energy

      Decarbonizing steel is as tough as steel

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      The long-term aspirational goal of the Paris Agreement on climate change is to cap global warming at 1.5 degrees Celsius above preindustrial levels, and thereby reduce the frequency and severity of floods, droughts, wildfires, and other extreme weather events. Achieving that goal will require a massive reduction in global carbon dioxide (CO2) emissions across all economic sectors. A major roadblock, however, could be the industrial sector, which accounts for roughly 25 percent of global energy- and process-related CO2 emissions — particularly within the iron and steel sector, industry’s largest emitter of CO2.Iron and steel production now relies heavily on fossil fuels (coal or natural gas) for heat, converting iron ore to iron, and making steel strong. Steelmaking could be decarbonized by a combination of several methods, including carbon capture technology, the use of low- or zero-carbon fuels, and increased use of recycled steel. Now a new study in the Journal of Cleaner Production systematically explores the viability of different iron-and-steel decarbonization strategies.Today’s strategy menu includes improving energy efficiency, switching fuels and technologies, using more scrap steel, and reducing demand. Using the MIT Economic Projection and Policy Analysis model, a multi-sector, multi-region model of the world economy, researchers at MIT, the University of Illinois at Urbana-Champaign, and ExxonMobil Technology and Engineering Co. evaluate the decarbonization potential of replacing coal-based production processes with electric arc furnaces (EAF), along with either scrap steel or “direct reduced iron” (DRI), which is fueled by natural gas with carbon capture and storage (NG CCS DRI-EAF) or by hydrogen (H2 DRI-EAF).Under a global climate mitigation scenario aligned with the 1.5 C climate goal, these advanced steelmaking technologies could result in deep decarbonization of the iron and steel sector by 2050, as long as technology costs are low enough to enable large-scale deployment. Higher costs would favor the replacement of coal with electricity and natural gas, greater use of scrap steel, and reduced demand, resulting in a more-than-50-percent reduction in emissions relative to current levels. Lower technology costs would enable massive deployment of NG CCS DRI-EAF or H2 DRI-EAF, reducing emissions by up to 75 percent.Even without adoption of these advanced technologies, the iron-and-steel sector could significantly reduce its CO2 emissions intensity (how much CO2 is released per unit of production) with existing steelmaking technologies, primarily by replacing coal with gas and electricity (especially if it is generated by renewable energy sources), using more scrap steel, and implementing energy efficiency measures.“The iron and steel industry needs to combine several strategies to substantially reduce its emissions by mid-century, including an increase in recycling, but investing in cost reductions in hydrogen pathways and carbon capture and sequestration will enable even deeper emissions mitigation in the sector,” says study supervising author Sergey Paltsev, deputy director of the MIT Center for Sustainability Science and Strategy (MIT CS3) and a senior research scientist at the MIT Energy Initiative (MITEI).This study was supported by MIT CS3 and ExxonMobil through its membership in MITEI. More