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      in Energy

      A more sustainable way to generate phosphorus

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      Phosphorus is an essential ingredient in thousands of products, including herbicides, lithium-ion batteries, and even soft drinks. Most of this phosphorus comes from an energy-intensive process that contributes significantly to global carbon emissions.

      In an effort to reduce that carbon footprint, MIT chemists have devised an alternative way to generate white phosphorus, a critical intermediate in the manufacture of those phosphorus-containing products. Their approach, which uses electricity to speed up a key chemical reaction, could reduce the carbon emissions of the process by half or even more, the researchers say.

      “White phosphorus is currently an indispensable intermediate, and our process dramatically reduces the carbon footprint of converting phosphate to white phosphorus,” says Yogesh Surendranath, an associate professor of chemistry at MIT and the senior author of the study.

      The new process reduces the carbon footprint of white phosphorus production in two ways: It reduces the temperatures required for the reaction, and it generates significantly less carbon dioxide as a waste product.

      Recent MIT graduate Jonathan “Jo” Melville PhD ’21 and MIT graduate student Andrew Licini are the lead authors of the paper, which appears today in ACS Central Science.

      Purifying phosphorus

      When phosphorus is mined out of the ground, it is in the form of phosphate, a mineral whose basic unit comprises one atom of phosphorus bound to four oxygen atoms. About 95 percent of this phosphate ore is used to make fertilizer. The remaining phosphate ore is processed separately into white phosphorus, a molecule composed of four phosphorus atoms bound to each other. White phosphorus is then fed into a variety of chemical processes that are used to manufacture many different products, such as lithium battery electrolytes and semiconductor dopants.

      Converting those mined phosphates into white phosphorus accounts for a substantial fraction of the carbon footprint of the entire phosphorus industry, Surendranath says. The most energy-intensive part of the process is breaking the bonds between phosphorus and oxygen, which are very stable.

      Using the traditional “thermal process,” those bonds are broken by heating carbon coke and phosphate rock to a temperature of 1,500 degrees Celsius. In this process, the carbon serves to strip away the oxygen atoms from phosphorus, leading to the eventual generation of CO2 as a byproduct. In addition, sustaining those temperatures requires a great deal of energy, adding to the carbon footprint of the process.

      “That process hasn’t changed substantially since its inception over a century ago. Our goal was to figure out how we could develop a process that would substantially lower the carbon footprint of this process,” Surendranath says. “The idea was to combine it with renewable electricity and drive that conversion of phosphate to white phosphorus with electrons rather than using carbon.”

      To do that, the researchers had to come up with an alternative way to weaken the strong phosphorus-oxygen bonds found in phosphates. They achieved this by controlling the environment in which the reaction occurs. The researchers found that the reaction could be promoted using a dehydrated form of phosphoric acid, which contains long chains of phosphate salts held together by bonds called phosphoryl anhydrides. These bonds help to weaken the phosphorus-oxygen bonds.

      When the researchers run an electric current through these salts, electrons break the weakened bonds, allowing the phosphorus atoms to break free and bind to each other to form white phosphorus. At the temperatures needed for this system (about 800 C), phosphorus exists as a gas, so it can bubble out of the solution and be collected in an external chamber.

      Decarbonization

      The electrode that the researchers used for this demonstration relies on carbon as a source of electrons, so the process generates some carbon dioxide as a byproduct. However, they are now working on swapping that electrode out for one that would use phosphate itself as the electron source, which would further reduce the carbon footprint by cleanly separating phosphate into phosphorus and oxygen.

      With the process reported in this paper, the researchers have reduced the overall carbon footprint for generating white phosphorus by about 50 percent. With future modifications, they hope to bring the carbon emissions down to nearly zero, in part by using renewable energy such as solar or wind power to drive the electric current required.

      If the researchers succeed in scaling up their process and making it widely available, it could allow industrial users to generate white phosphorus on site instead of having it shipped from the few places in the world where it is currently manufactured. That would cut down on the risks of transporting white phosphorus, which is an explosive material.

      “We’re excited about the prospect of doing on-site generation of this intermediate, so you don’t have to do the transportation and distribution,” Surendranath says. “If you could decentralize this production, the end user could make it on site and use it in an integrated fashion.”

      In order to do this study, the researchers had to develop new tools for controlling the electrolytes (such as salts and acids) present in the environment, and for measuring how those electrolytes affect the reaction. Now, they plan to use the same approach to try to develop lower-carbon processes for isolating other industrially important elements, such as silicon and iron.

      “This work falls within our broader interests in decarbonizing these legacy industrial processes that have a huge carbon footprint,” Surendranath says. “The basic science that leads us there is understanding how you can tailor the electrolytes to foster these processes.”

      The research was funded by the UMRP Partnership for Progress on Sustainable Development in Africa, a fellowship from the MIT Tata Center for Technology and Design, and a National Defense Science and Engineering Graduate Fellowship. More

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      in Energy

      Preparing students for the new nuclear

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      As nuclear power has gained greater recognition as a zero-emission energy source, the MIT Leaders for Global Operations (LGO) program has taken notice.

      Two years ago, LGO began a collaboration with MIT’s Department of Nuclear Science and Engineering (NSE) as a way to showcase the vital contribution of both business savvy and scientific rigor that LGO’s dual-degree graduates can offer this growing field.

      “We saw that the future of fission and fusion required business acumen and management acumen,” says Professor Anne White, NSE department head. “People who are going to be leaders in our discipline, and leaders in the nuclear enterprise, are going to need all of the technical pieces of the puzzle that our engineering department can provide in terms of education and training. But they’re also going to need a much broader perspective on how the technology connects with society through the lens of business.”

      The resulting response has been positive: “Companies are seeing the value of nuclear technology for their operations,” White says, and this often happens in unexpected ways.

      For example, graduate student Santiago Andrade recently completed a research project at Caterpillar Inc., a preeminent manufacturer of mining and construction equipment. Caterpillar is one of more than 20 major companies that partner with the LGO program, offering six-month internships to each student. On the surface, it seemed like an improbable pairing; what could Andrade, who was pursuing his master’s in nuclear science and engineering, do for a manufacturing company? However, Caterpillar wanted to understand the technical and commercial feasibility of using nuclear energy to power mining sites and data centers when wind and solar weren’t viable.

      “They are leaving no stone unturned in the search of financially smart solutions that can support the transition to a clean energy dependency,” Andrade says. “My project, along with many others’, is part of this effort.”

      “The research done through the LGO program with Santiago is enabling Caterpillar to understand how alternative technologies, like the nuclear microreactor, could participate in these markets in the future,” says Brian George, product manager for large electric power solutions at Caterpillar. “Our ability to connect our customers with the research will provide for a more accurate understanding of the potential opportunity, and helps provide exposure for our customers to emerging technologies.”

      With looming threats of climate change, White says, “We’re going to require more opportunities for nuclear technologies to step in and be part of those solutions. A cohort of LGO graduates will come through this program with technical expertise — a master’s degree in nuclear engineering — and an MBA. There’s going to be a tremendous talent pool out there to help companies and governments.”

      Andrade, who completed an undergraduate degree in chemical engineering and had a strong background in thermodynamics, applied to LGO unsure of which track to choose, but he knew he wanted to confront the world’s energy challenge. When MIT Admissions suggested that he join LGO’s new nuclear track, he was intrigued by how it could further his career.

      “Since the NSE department offers opportunities ranging from energy to health care and from quantum engineering to regulatory policy, the possibilities of career tracks after graduation are countless,” he says.

      He was also inspired by the fact that, as he says, “Nuclear is one of the less-popular solutions in terms of our energy transition journey. One of the things that attracted me is that it’s not one of the most popular, but it’s one of the most useful.”

      In addition to his work at Caterpillar, Andrade connected deeply with professors. He worked closely with professors Jacopo Buongiorno and John Parsons as a research assistant, helping them develop a business model to successfully support the deployment of nuclear microreactors. After graduation, he plans to work in the clean energy sector with an eye to innovations in the nuclear energy technology space.

      His LGO classmate, Lindsey Kennington, a control systems engineer, echoes his sentiments: This is a revolutionary time for nuclear technology.

      “Before MIT, I worked on a lot of nuclear waste or nuclear weapons-related projects. All of them were fission-related. I got disillusioned because of all the bureaucracy and the regulation,” Kennington says. “However, now there are a lot of new nuclear technologies coming straight out of MIT. Commonwealth Fusion Systems, a fusion startup, represents a prime example of MIT’s close relationship to new nuclear tech. Small modular reactors are another emerging technology being developed by MIT. Exposure to these cutting-edge technologies was the main sell factor for me.”

      Kennington conducted an internship with National Grid, where she used her expertise to evaluate how existing nuclear power plants could generate hydrogen. At MIT, she studied nuclear and energy policy, which offered her additional perspective that traditional engineering classes might not have provided. Because nuclear power has long been a hot-button issue, Kennington was able to gain nuanced insight about the pathways and roadblocks to its implementation.

      “I don’t think that other engineering departments emphasize that focus on policy quite as much. [Those classes] have been one of the most enriching parts of being in the nuclear department,” she says.

      Most of all, she says, it’s a pivotal time to be part of a new, blossoming program at the forefront of clean energy, especially as fusion research grows more prevalent.

      “We’re at an inflection point,” she says. “Whether or not we figure out fusion in the next five, 10, or 20 years, people are going to be working on it — and it’s a really exciting time to not only work on the science but to actually help the funding and business side grow.”

      White puts it simply.

      “This is not your parents’ nuclear,” she says. “It’s something totally different. Our discipline is evolving so rapidly that people who have technical expertise in nuclear will have a huge advantage in this next generation.” More

    • 88 Shares169 Views

      in Environment

      Rescuing small plastics from the waste stream

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      As plastic pollution continues to mount, with growing risks to ecosystems and wildlife, manufacturers are beginning to make ambitious commitments to keep new plastics out of the environment. A growing number have signed onto the U.S. Plastics Pact, which pledges to make 100 percent of plastic packaging reusable, recyclable, or compostable, and to see 50 percent of it effectively recycled or composted, by 2025.

      But for companies that make large numbers of small, disposable plastics, these pocket-sized objects are a major barrier to realizing their recycling goals.

      “Think about items like your toothbrush, your travel-size toothpaste tubes, your travel-size shampoo bottles,” says Alexis Hocken, a second-year PhD student in the MIT Department of Chemical Engineering. “They end up actually slipping through the cracks of current recycling infrastructure. So you might put them in your recycling bin at home, they might make it all the way to the sorting facility, but when it comes down to actually sorting them, they never make it into a recycled plastic bale at the very end of the line.”

      Now, a group of five consumer products companies is working with MIT to develop a sorting process that can keep their smallest plastic products inside the recycling chain. The companies — Colgate-Palmolive, Procter & Gamble, the Estée Lauder Companies, L’Oreal, and Haleon — all manufacture a large volume of “small format” plastics, or products less than two inches long in at least two dimensions. In a collaboration with Brad Olsen, the Alexander and I. Michael Kasser (1960) Professor of Chemical Engineering; Desiree Plata, an associate professor of civil and environmental engineering; the MIT Environmental Solutions Initiative; and the nonprofit The Sustainability Consortium, these companies are seeking a prototype sorting technology to bring to recycling facilities for large-scale testing and commercial development.

      Working in Olsen’s lab, Hocken is coming to grips with the complexity of the recycling systems involved. Material recovery facilities, or MRFs, are expected to handle products in any number of shapes, sizes, and materials, and sort them into a pure stream of glass, metal, paper, or plastic. Hocken’s first step in taking on the recycling project was to tour one of these MRFs in Portland, Maine, with Olsen and Plata.

      “We could literally see plastics just falling from the conveyor belts,” she says. “Leaving that tour, I thought, my gosh! There’s so much improvement that can be made. There’s so much impact that we can have on this industry.”

      From designing plastics to managing them

      Hocken always knew she wanted to work in engineering. Growing up in Scottsdale, Arizona, she was able to spend time in the workplace with her father, an electrical engineer who designs biomedical devices. “Seeing him working as an engineer, and how he’s solving these really important problems, definitely sparked my interest,” she says. “When it came time to begin my undergraduate degree, it was a really easy decision to choose engineering after seeing the day-to-day that my dad was doing in his career.”

      At Arizona State University, she settled on chemical engineering as a major and began working with polymers, coming up with combinations of additives for 3D plastics printing that could help fine-tune how the final products behaved. But even working with plastics every day, she rarely thought about the implications of her work for the environment.

      “And then in the spring of my final year at ASU, I took a class about polymers through the lens of sustainability, and that really opened my eyes,” Hocken remembers. The class was taught by Professor Timothy Long, director of the Biodesign Center for Sustainable Macromolecular Materials and Manufacturing and a well-known expert in the field of sustainable plastics. “That first session, where he laid out all of the really scary facts surrounding the plastics crisis, got me very motivated to look more into that field.”

      At MIT the next year, Hocken sought out Olsen as her advisor and made plastics sustainability her focus from the start.

      “Coming to MIT was my first time venturing outside of the state of Arizona for more than a three-month period,” she says. “It’s been really fun. I love living in Cambridge and the Boston area. I love my labmates. Everyone is so supportive, whether it’s to give me advice about some science that I’m trying to figure out, or just give me a pep talk if I’m feeling a little discouraged.”

      A challenge to recycle

      A lot of plastics research today is devoted to creating new materials — including biodegradable ones that are easier for natural ecosystems to absorb, and highly recyclable ones that hold their properties better after being melted down and recast.

      But Hocken also sees a huge need for better ways to handle the plastics we’re already making. “While biodegradable and sustainable polymers represent a very important route, and I think they should certainly be further pursued, we’re still a ways away from that being a reality universally across all plastic packaging,” she says. As long as large volumes of conventional plastic are coming out of factories, we’ll need innovative ways to stop it from piling onto the mountain of plastic pollution. In one of her projects, Hocken is trying to come up with new uses for recycled plastic that take advantage of its lost strength to produce a useful, flexible material similar to rubber.

      The small-format recycling project also falls in this category. The companies supporting the project have challenged the MIT team to work with their products exactly as currently manufactured — especially because their competitors use similar packaging materials that will also need to be covered by any solution the MIT team devises.

      The challenge is a large one. To kick the project off, the participating companies sent the MIT team a wide range of small-format products that need to make it through the sorting process. These include containers for lip balm, deodorant, pills, and shampoo, and disposable tools like toothbrushes and flossing picks. “A constraint, or problem I foresee, is just how variable the shapes are,” says Hocken. “A flossing pick versus a toothbrush are very different shapes.”

      Nor are they all made of the same kind of plastic. Many are made of polyethylene terephthalate (PET, type 1 in the recycling label system) or high-density polyethylene (HDPE, type 2), but nearly all of the seven recycling categories are represented among the sample products. The team’s solution will have to handle them all.

      Another obstacle is that the sorting process at a large MRF is already very complex and requires a heavy investment in equipment. The waste stream typically goes through a “glass breaker screen” that shatters glass and collects the shards; a series of rotating rubber stars to pull out two-dimensional objects, collecting paper and cardboard; a system of magnets and eddy currents to attract or repel different metals; and finally, a series of optical sorters that use infrared spectroscopy to identify the various types of plastics, then blow them down different chutes with jets of air. MRFs won’t be interested in adopting additional sorters unless they’re inexpensive and easy to fit into this elaborate stream.

      “We’re interested in creating something that could be retrofitted into current technology and current infrastructure,” Hocken says.

      Shared solutions

      “Recycling is a really good example of where pre-competitive collaboration is needed,” says Jennifer Park, collective action manager at The Sustainability Consortium (TSC), who has been working with corporate stakeholders on small format recyclability and helped convene the sponsors of this project and organize their contributions. “Companies manufacturing these products recognize that they cannot shift entire systems on their own. Consistency around what is and is not recyclable is the only way to avoid confusion and drive impact at scale.

      “Additionally, it is interesting that consumer packaged goods companies are sponsoring this research at MIT which is focused on MRF-level innovations. They’re investing in innovations that they hope will be adopted by the recycling industry to make progress on their own sustainability goals.”

      Hocken believes that, despite the challenges, it’s well worth pursuing a technology that can keep small-format plastics from slipping through MRFs’ fingers.

      “These are products that would be more recyclable if they were easier to sort,” she says. “The only thing that’s different is the size. So you can recycle both your large shampoo bottle and the small travel-size one at home, but the small one isn’t guaranteed to make it into a plastic bale at the end. If we can come up with a solution that specifically targets those while they’re still on the sorting line, they’re more likely to end up in those plastic bales at the end of the line, which can be sold to plastic reclaimers who can then use that material in new products.”

      “TSC is really excited about this project and our collaboration with MIT,” adds Park. “Our project stakeholders are very dedicated to finding a solution.”

      To learn more about this project, contact Christopher Noble, director of corporate engagement at the MIT Environmental Solutions Initiative. More

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      in Energy

      To decarbonize the chemical industry, electrify it

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      The chemical industry is the world’s largest industrial energy consumer and the third-largest source of industrial emissions, according to the International Energy Agency. In 2019, the industrial sector as a whole was responsible for 24 percent of global greenhouse gas emissions. And yet, as the world races to find pathways to decarbonization, the chemical industry has been largely untouched.

      “When it comes to climate action and dealing with the emissions that come from the chemical sector, the slow pace of progress is partly technical and partly driven by the hesitation on behalf of policymakers to overly impact the economic competitiveness of the sector,” says Dharik Mallapragada, a principal research scientist at the MIT Energy Initiative.

      With so many of the items we interact with in our daily lives — from soap to baking soda to fertilizer — deriving from products of the chemical industry, the sector has become a major source of economic activity and employment for many nations, including the United States and China. But as the global demand for chemical products continues to grow, so do the industry’s emissions.

      New sustainable chemical production methods need to be developed and deployed and current emission-intensive chemical production technologies need to be reconsidered, urge the authors of a new paper published in Joule. Researchers from DC-MUSE, a multi-institution research initiative, argue that electrification powered by low-carbon sources should be viewed more broadly as a viable decarbonization pathway for the chemical industry. In this paper, they shine a light on different potential methods to do just that.

      “Generally, the perception is that electrification can play a role in this sector — in a very narrow sense — in that it can replace fossil fuel combustion by providing the heat that the combustion is providing,” says Mallapragada, a member of DC-MUSE. “What we argue is that electrification could be much more than that.”

      The researchers outline four technological pathways — ranging from more mature, near-term options to less technologically mature options in need of research investment — and present the opportunities and challenges associated with each.

      The first two pathways directly replace fossil fuel-produced heat (which facilitates the reactions inherent in chemical production) with electricity or electrochemically generated hydrogen. The researchers suggest that both options could be deployed now and potentially be used to retrofit existing facilities. Electrolytic hydrogen is also highlighted as an opportunity to replace fossil fuel-produced hydrogen (a process that emits carbon dioxide) as a critical chemical feedstock. In 2020, fossil-based hydrogen supplied nearly all hydrogen demand (90 megatons) in the chemical and refining industries — hydrogen’s largest consumers.

      The researchers note that increasing the role of electricity in decarbonizing the chemical industry will directly affect the decarbonization of the power grid. They stress that to successfully implement these technologies, their operation must coordinate with the power grid in a mutually beneficial manner to avoid overburdening it. “If we’re going to be serious about decarbonizing the sector and relying on electricity for that, we have to be creative in how we use it,” says Mallapragada. “Otherwise we run the risk of having addressed one problem, while creating a massive problem for the grid in the process.”

      Electrified processes have the potential to be much more flexible than conventional fossil fuel-driven processes. This can reduce the cost of chemical production by allowing producers to shift electricity consumption to times when the cost of electricity is low. “Process flexibility is particularly impactful during stressed power grid conditions and can help better accommodate renewable generation resources, which are intermittent and are often poorly correlated with daily power grid cycles,” says Yury Dvorkin, an associate research professor at the Johns Hopkins Ralph O’Connor Sustainable Energy Institute. “It’s beneficial for potential adopters because it can help them avoid consuming electricity during high-price periods.”

      Dvorkin adds that some intermediate energy carriers, such as hydrogen, can potentially be used as highly efficient energy storage for day-to-day operations and as long-term energy storage. This would help support the power grid during extreme events when traditional and renewable generators may be unavailable. “The application of long-duration storage is of particular interest as this is a key enabler of a low-emissions society, yet not widespread beyond pumped hydro units,” he says. “However, as we envision electrified chemical manufacturing, it is important to ensure that the supplied electricity is sourced from low-emission generators to prevent emissions leakages from the chemical to power sector.” 

      The next two pathways introduced — utilizing electrochemistry and plasma — are less technologically mature but have the potential to replace energy- and carbon-intensive thermochemical processes currently used in the industry. By adopting electrochemical processes or plasma-driven reactions instead, chemical transformations can occur at lower temperatures and pressures, potentially enhancing efficiency. “These reaction pathways also have the potential to enable more flexible, grid-responsive plants and the deployment of modular manufacturing plants that leverage distributed chemical feedstocks such as biomass waste — further enhancing sustainability in chemical manufacturing,” says Miguel Modestino, the director of the Sustainable Engineering Initiative at the New York University Tandon School of Engineering.

      A large barrier to deep decarbonization of chemical manufacturing relates to its complex, multi-product nature. But, according to the researchers, each of these electricity-driven pathways supports chemical industry decarbonization for various feedstock choices and end-of-life disposal decisions. Each should be evaluated in comprehensive techno-economic and environmental life cycle assessments to weigh trade-offs and establish suitable cost and performance metrics.

      Regardless of the pathway chosen, the researchers stress the need for active research and development and deployment of these technologies. They also emphasize the importance of workforce training and development running in parallel to technology development. As André Taylor, the director of DC-MUSE, explains, “There is a healthy skepticism in the industry regarding electrification and adoption of these technologies, as it involves processing chemicals in a new way.” The workforce at different levels of the industry hasn’t necessarily been exposed to ideas related to the grid, electrochemistry, or plasma. The researchers say that workforce training at all levels will help build greater confidence in these different solutions and support customer-driven industry adoption.

      “There’s no silver bullet, which is kind of the standard line with all climate change solutions,” says Mallapragada. “Each option has pros and cons, as well as unique advantages. But being aware of the portfolio of options in which you can use electricity allows us to have a better chance of success and of reducing emissions — and doing so in a way that supports grid decarbonization.”

      This work was supported, in part, by the Alfred P. Sloan Foundation. More

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      in Security

      Food for thought, thought for food

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      According to the Food and Agriculture Organization of the United Nations, approximately 3.1 billion people worldwide were unable to afford a healthy diet in 2020. Meanwhile, in 2021 close to 2.3 billion people were moderately or severely food insecure. Given the strong link between malnutrition and income disparity, the numbers paint a grim picture representing one of the grand challenges of our time.

      “I’m probably an idealist,” says MIT Research Scientist Christopher Mejía Argueta, “but I really believe that if we change our diets and think about ways to help others, we can make a difference — that’s my motivation.”

      Mejía Argueta is the founder and director of the MIT Food and Retail Operations Lab (FaROL). He has more than a decade of experience in supply chain management, optimization, and effective data-driven decision-making on pressing issues like the evolution of end consumers for retail and e-tail supply chains, food waste, and equitable access to nutrition.  

      Supply chain network designs typically focus on minimizing costs without considering the implications (e.g., cost) of changes in consumer behavior. Mejía Argueta and his colleagues at the FaROL, however, are working to understand and design optimal supply chains to create high-performance operations based on consumer choice. “Understanding the significant factors of consumer choice and analyzing their evolution over time becomes critical to designing forward-looking retail operations with data-driven and customer-centric supply chains, inventory management, and distribution systems,” explains Mejía Argueta. 

      Play video

      One of his recent projects examined the challenges of small retailers worldwide. These mom-and-pop outlets, or nanostores, account for 50 percent of the global market share and are the primary source of consumer packaged goods for people in urban areas. Worldwide there are nearly 50 million nanostores, each serving between 100-200 households in a community. In India alone, there are 14 million nanostores known as kiranas. And while these retailers are more prevalent in emerging markets, they play an important role in developed markets, particularly in under-resourced communities, and are frequently located in “food deserts,” where they are the only source of essential goods for the community.  

      These small retailers thrive thanks, partly, to their ability to offer the right combination of affordability and convenience while fostering trust with local customers, who often lack access to a supermarket or a grocery store. They often exist in fragmented, densely populated areas where infrastructure and public transportation services are poor and consumers have limited purchasing power. But nanostore shopkeepers and owners are intimately familiar with their customers and their consumption patterns, which means they can connect those consumption patterns or information to the larger supply chain. According to Mejía Argueta, when it comes to the future of retail, nanostores will be the cornerstones of growth in emerging economies. 

      But it’s a complicated scenario. Mom-and-pop shops don’t have the capacity to offer a broad range of products to their customers, and often, they lack access to nutritious food options. Logistically speaking, it is expensive to supply them, and the cost-to-serve (i.e., the logistics cost) is between 10 to 30 percent more expensive than other retailers. According to Mejía Argueta, this has a significant ripple effect, impacting education, productivity, and, eventually, the economic performance of an entire nation.  

      “The high fragmentation of nanostores causes substantial distribution inefficiencies, especially in congested megacities,” he says. “At my lab, we study how to make nanostores more efficient and effective by considering various commercial and logistics strategies while considering inherent technical challenges. We need to serve these small retailers better to help them survive and thrive, to provide a greater impact for underserved communities and the entire economic ecosystem.”

      Play video

      Mejía Argueta and his team recently collaborated with Tufts University and the City of Somerville, Massachusetts, to conduct research on food access models in underserved communities. The Somerville Project explored various interventions to supply fresh produce in food desert neighborhoods.

      “A lack of nutrition does not simply mean a lack of food,” Mejía Argueta says. “It can also be caused by an overabundance of unhealthy foods in a given market, which is particularly troublesome for U.S. cities where people in underserved communities don’t have access to healthy food options. We believe that one way to combat the problem of food deserts is to supply these areas with healthy food options affordably and create awareness programs.”  

      The collaborative project saw Mejía Argueta and his colleagues assessing the impact of several intervention schemes designed to empower the end consumer. For example, they implemented a low-cost grocery delivery model similar to Instacart as well as a ride sharing system to transport people from their homes to grocery stores and back. They also collaborated with a nonprofit organization, Partnership for a Healthier America, and began working with retailers to deliver “veggie boxes” in underserved communities. Models like these provide low-income people access to food while providing dignity of choice, Mejía Argueta explains.  

      When it comes to supply chain management research, sustainability and societal impact often fall by the wayside, but Mejía Argueta’s bottom-up approach shirks tradition. “We’re trying to build a community, employing a socially driven perspective because if you work with the community, you gain their trust. If you want to make something sustainable in the long term, people need to trust in these solutions and engage with the ecosystem as a whole.”  

      And to achieve real-world impact, collaboration is key. Mejía Argueta says that government has an important role to play, developing policy to connect the models he and his colleagues develop in academia to societal challenges. Meanwhile, he believes startups and entrepreneurs can function as bridge-builders to link the flows of information, the flows of goods and cash, and even knowledge and security in an ecosystem that suffers from fragmentation and siloed thinking among stakeholders.

      Finally, Mejía Argueta reflects on the role of corporations and his belief that the MIT Industrial Liaison Program is essential to getting his research to the frontline of business challenges. “The Industrial Liaison Program does a fantastic job of connecting our research to real-world scenarios,” he says. “It creates opportunities for us to have meaningful interactions with corporates for real-world impact. I believe strongly in the MIT motto ‘mens et manus,’ and ILP helps drive our research into practice.” More

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      in Energy

      Mining for the clean energy transition

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      In a world powered increasingly by clean energy, drilling for oil and gas will gradually give way to digging for metals and minerals. Today, the “critical minerals” used to make electric cars, solar panels, wind turbines, and grid-scale battery storage are facing soaring demand — and some acute bottlenecks as miners race to catch up.

      According to a report from the International Energy Agency, by 2040, the worldwide demand for copper is expected to roughly double; demand for nickel and cobalt will grow at least sixfold; and the world’s hunger for lithium could reach 40 times what we use today.

      “Society is looking to the clean energy transition as a way to solve the environmental and social harms of climate change,” says Scott Odell, a visiting scientist at the MIT Environmental Solutions Initiative (ESI), where he helps run the ESI Mining, Environment, and Society Program, who is also a visiting assistant professor at George Washington University. “Yet mining the materials needed for that transition would also cause social and environmental impacts. So we need to look for ways to reduce our demand for minerals, while also improving current mining practices to minimize social and environmental impacts.”

      ESI recently hosted the inaugural MIT Conference on Mining, Environment, and Society to discuss how the clean energy transition may affect mining and the people and environments in mining areas. The conference convened representatives of mining companies, environmental and human rights groups, policymakers, and social and natural scientists to identify key concerns and possible collaborative solutions.

      “We can’t replace an abusive fossil fuel industry with an abusive mining industry that expands as we move through the energy transition,” said Jim Wormington, a senior researcher at Human Rights Watch, in a panel on the first day of the conference. “There’s a recognition from governments, civil society, and companies that this transition potentially has a really significant human rights and social cost, both in terms of emissions […] but also for communities and workers who are on the front lines of mining.”

      That focus on communities and workers was consistent throughout the three-day conference, as participants outlined the economic and social dimensions of standing up large numbers of new mines. Corporate mines can bring large influxes of government revenue and local investment, but the income is volatile and can leave policymakers and communities stranded when production declines or mineral prices fall. On the other hand, “artisanal” mining operations are an important source of critical minerals, but are hard to regulate and subject to abuses from brokers. And large reserves of minerals are found in conservation areas, regions with fragile ecosystems and experiencing water shortages that can be exacerbated by mining, in particular on Indigenous-controlled lands and other places where mine openings are deeply fraught.

      “One of the real triggers of conflict is a dissatisfaction with the current model of resource extraction,” said Jocelyn Fraser of the University of British Columbia in a panel discussion. “One that’s failed to support the long-term sustainable development of regions that host mining operations, and yet imposes significant local social and environmental impacts.”

      All these challenges point toward solutions in policy and in mining companies’ relationships with the communities where they work. Participants highlighted newer models of mining governance that can create better incentives for the ways mines operate — from full community ownership of mines to recognizing community rights to the benefits of mining to end-of-life planning for mines at the time they open.

      Many of the conference speakers also shared technological innovations that may help reduce mining challenges. Some operations are investing in desalination as alternative water sources in water-scarce regions; low-carbon alternatives are emerging to many of the fossil fuel-powered heavy machines that are mainstays of the industry; and work is being done to reclaim valuable minerals from mine tailings, helping to minimize both waste and the need to open new extraction sites.

      Increasingly, the mining industry itself is recognizing that reforms will allow it to thrive in a rapid clean-energy transition. “Decarbonization is really a profitability imperative,” said Kareemah Mohammed, managing director for sustainability services at the technology consultancy Accenture, on the conference’s second day. “It’s about securing a low-cost and steady supply of either minerals or metals, but it’s also doing so in an optimal way.”

      The three-day conference attracted over 350 attendees, from large mining companies, industry groups, consultancies, multilateral institutions, universities, nongovernmental organizations (NGOs), government, and more. It was held entirely virtually, a choice that helped make the conference not only truly international — participants joined from over 27 countries on six continents — but also accessible to members of nonprofits and professionals in the developing world.

      “Many people are concerned about the environmental and social challenges of supplying the clean energy revolution, and we’d heard repeatedly that there wasn’t a forum for government, industry, academia, NGOs, and communities to all sit at the same table and explore collaborative solutions,” says Christopher Noble, ESI’s director of corporate engagement. “Convening, and researching best practices, are roles that universities can play. The conversations at this conference have generated valuable ideas and consensus to pursue three parallel programs: best-in-class models for community engagement, improving ESG metrics and their use, and civil-society contributions to government/industry relations. We are developing these programs to keep the momentum going.”

      The MIT Conference on Mining, Environment, and Society was funded, in part, by Accenture, as part of the MIT/Accenture Convergence Initiative. Additional funding was provided by the Inter-American Development Bank. More

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      3 Questions: Robert Stoner unpacks US climate and infrastructure laws

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      This month, the 2022 United Nations Climate Change Conference (COP27) takes place in Sharm El Sheikh, Egypt, bringing together governments, experts, journalists, industry, and civil society to discuss climate action to enable countries to collectively sharply limit anthropogenic climate change. As MIT Energy Initiative Deputy Director for Science and Technology Robert Stoner attends the conference, he takes a moment to speak about the climate and infrastructure laws enacted in the last year in the United States, and about the impact these laws can have in the global energy transition.

      Q: COP27 is now underway. Can you set the scene?

      A: There’s a lot of interest among vulnerable countries about compensation for the impacts climate change has had on them, or “loss and damage,” a topic that the United States refused to address last year at COP26, for fear of opening up a floodgate and leaving U.S. taxpayers exposed to unlimited liability for our past (and future) emissions. This is a crucial issue of fairness for developed countries — and, well, of acknowledging our common humanity. But in a sense, it’s also a sideshow, and addressing it won’t prevent a climate catastrophe — we really need to focus on mitigation. With the passage of the bipartisan Infrastructure Investment and Jobs Act and the Inflation Reduction Act (IRA), the United States is now in a strong position to twist some arms. These laws are largely about subsidizing the deployment of low-carbon technologies — pretty much all of them. We’re going to do a lot in the United States in the next decade that will lead to dramatic cost reductions for these technologies and enable other countries with fewer resources to adopt them as well. It’s exactly the leadership role the United States has needed to assume. Now we have the opportunity to rally the rest of the world and get other countries to commit to more ambitious decarbonization goals, and to build practical programs that take advantage of the investable pathways we’re going to create for public and private actors.

      But that alone won’t get us there — money is still a huge problem, especially in emerging markets and developing countries. And I don’t think the institutions we rely on to help these countries fund infrastructure — energy and everything else — are adequately funded. Nor do these institutions have the right structures, incentives, and staffing to fund low-carbon development in these countries rapidly enough or on the necessary scale. I’m talking about the World Bank, for instance, but the other multilateral organizations have similar issues. I frankly don’t think the multilaterals can be reformed or sufficiently redirected on a short enough time frame. We definitely need new leadership for these organizations, and I think we probably need to quickly establish new multilaterals with new people, more money, and a clarity of purpose that is likely beyond what can be achieved incrementally. I don’t know if this is going to be an active public discussion at COP27, but I hope it takes place somewhere soon. Given the strong role our government plays in financing and selecting the leadership of these institutions, perhaps this is another opportunity for the United States to demonstrate courage and leadership.

      Q: What “investable pathways” are you talking about?

      A: Well, the pathways we’re implicitly trying to pursue with the Infrastructure Act and IRA are pretty clear, and I’ll come back to them. But first let me describe the landscape: There are three main sources of demand for energy in the economy — industry (meaning chemical production, fuel for electricity generation, cement production, materials and manufacturing, and so on), transportation (cars, trucks, ships, planes, and trains), and buildings (for heating and cooling, mostly). That’s about it, and these three sectors account for 75 percent of our total greenhouse gas emissions. So the pathways are all about how to decarbonize these three end-use sectors. There are a lot of technologies — some that exist, some that don’t — that will have to be brought to bear. And so it can be a little overwhelming to try to imagine how it will all transpire, but it’s pretty clear at a high level what our options are:

      First, generate a lot of low-carbon electricity and electrify as many industrial processes, vehicles, and building heating systems as we can.
      Second, develop and deploy at massive scale technologies that can capture carbon dioxide from smokestacks, or the air, and put it somewhere that it can never escape from — in other words, carbon capture and sequestration, or CCS.
      Third, for end uses like aviation that really need to use fuels because of their extraordinary energy density, develop low-carbon alternatives to fossil fuels.
      And fourth is energy efficiency across the board — but I don’t really count that as a separate pathway per se.
      So, by “investable pathways” I mean specific ways to pursue these options that will attract investors. What the Infrastructure Act and the IRA do is deploy carrots (in the form of subsidies) in a variety of ways to close the gap between what it costs to deploy technologies like CCS that aren’t yet at a commercial stage because they’re immature, and what energy markets will tolerate. A similar situation occurs for low-carbon production of hydrogen, one of the leading low-carbon fuel candidates. We can make it by splitting water with electricity (electrolysis), but that costs too much with present-day technology; or we can make it more cheaply by separating it from methane (which is what natural gas mainly is), but that creates CO2 that has to be transported and sequestered somewhere. And then we have to store the hydrogen until we’re ready to use it, and transport it by pipeline to the industrial facilities where it will be used. That requires infrastructure that doesn’t exist — pipelines, compression stations, big tanks! Come to think of it, the demand for all that hydrogen doesn’t exist either — at least not if industry has to pay what it actually costs.

      So, one very important thing these new acts do is subsidize production of hydrogen in various ways — and subsidize the creation of a CCS industry. The other thing they do is subsidize the deployment at enormous scale of low-carbon energy technologies. Some of them are already pretty cheap, like solar and wind, but they need to be supported by a lot of storage on the grid (which we don’t yet have) and by other sorts of grid infrastructure that, again, don’t exist. So, they now get subsidized, too, along with other carbon-free and low-carbon generation technologies — basically all of them. The idea is that by stimulating at-scale deployment of all these established and emerging technologies, and funding demonstrations of novel infrastructure — effectively lowering the cost of supply of low-carbon energy in the form of electricity and fuels — we will draw out the private sector to build out much more of the connective infrastructure and invest in new industrial processes, new home heating systems, and low-carbon transportation. This subsidized build-out will take place over a decade and then phase out as costs fall — hopefully, leaving the foundation for a thriving low-carbon energy economy in its wake, along with crucial technologies and knowledge that will benefit the whole world.

      Q: Is all of the federal investment in energy infrastructure in the United States relevant to the energy crisis in Europe right now?

      A: Not in a direct way — Europe is a near-term catastrophe with a long-term challenge that is in many ways more difficult than ours because Europe doesn’t have the level of primary energy resources like oil and gas that we have in abundance. Energy costs more in Europe, especially absent Russian pipelines. In a way, the narrowing of Europe’s options creates an impetus to invest in low-carbon technologies sooner than otherwise. The result either way will be expensive energy and quite a lot of economic suffering for years. The near-term challenge is to protect people from high energy prices. The big spikes in electricity prices we see now are driven by the natural gas market disruption, which will eventually dissipate as new sources of electricity come online (Sweden, for example, just announced a plan to develop new nuclear, and we’re seeing other countries like Germany soften their stance on nuclear) — and gas markets will sort themselves out. Meanwhile governments are trying to shield their people with electricity price caps and other subsidies, but that’s enormously burdensome.

      The EU recently announced gas price caps for imported gas to try to eliminate price-gouging by importers and reduce the subsidy burden. That may help to lower downstream prices, or it may make matters worse by reducing the flow of gas into the EU and fueling scarcity pricing, and ultimately adding to the subsidy burden. A lot people are quite reasonably suggesting that if electricity prices are subject to crazy behavior in gas markets, then why not disconnect from the grid and self-generate? Wouldn’t that also help reduce demand for gas overall and also reduce CO2 emissions? It would. But it’s expensive to put solar panels on your roof and batteries in your basement — so for those rich enough to do this, it would lead to higher average electricity costs that would live on far into the future, even when grid prices eventually come down.

      So, an interesting idea is taking hold, with considerable encouragement from national governments — the idea of “energy communities,” basically, towns or cities that encourage local firms and homeowners to install solar and batteries, and make some sort of business arrangement with the local utility to allow the community to disconnect from the national grid at times of high prices and self-supply — in other words, use the utility’s wires to sell locally generated power locally. It’s interesting to think about — it takes less battery storage to handle the intermittency of solar when you have a lot of generators and consumers, so forming a community helps lower costs, and with a good deal from the utility for using their wires, it might not be that much more expensive. And of course, when the national grid is working well and prices are normal, the community would reconnect and buy power cheaply, while selling back its self-generated power to the grid. There are also potentially important social benefits that might accrue in these energy communities, too. It’s not a dumb idea, and we’ll see some interesting experimentation in this area in the coming years — as usual, the Germans are enthusiastic! More

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      Advancing the energy transition amidst global crises

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      “The past six years have been the warmest on the planet, and our track record on climate change mitigation is drastically short of what it needs to be,” said Robert C. Armstrong, MIT Energy Initiative (MITEI) director and the Chevron Professor of Chemical Engineering, introducing MITEI’s 15th Annual Research Conference.

      At the symposium, participants from academia, industry, and finance acknowledged the deepening difficulties of decarbonizing a world rocked by geopolitical conflicts and suffering from supply chain disruptions, energy insecurity, inflation, and a persistent pandemic. In spite of this grim backdrop, the conference offered evidence of significant progress in the energy transition. Researchers provided glimpses of a low-carbon future, presenting advances in such areas as long-duration energy storage, carbon capture, and renewable technologies.

      In his keynote remarks, Ernest J. Moniz, the Cecil and Ida Green Professor of Physics and Engineering Systems Emeritus, founding director of MITEI, and former U.S. secretary of energy, highlighted “four areas that have materially changed in the last year” that could shake up, and possibly accelerate, efforts to address climate change.

      Extreme weather seems to be propelling the public and policy makers of both U.S. parties toward “convergence … at least in recognition of the challenge,” Moniz said. He perceives a growing consensus that climate goals will require — in diminishing order of certainty — firm (always-on) power to complement renewable energy sources, a fuel (such as hydrogen) flowing alongside electricity, and removal of atmospheric carbon dioxide (CO2).

      Russia’s invasion of Ukraine, with its “weaponization of natural gas” and global energy impacts, underscores the idea that climate, energy security, and geopolitics “are now more or less recognized widely as one conversation.” Moniz pointed as well to new U.S. laws on climate change and infrastructure that will amplify the role of science and technology and “address the drive to technological dominance by China.”

      The rapid transformation of energy systems will require a comprehensive industrial policy, Moniz said. Government and industry must select and rapidly develop low-carbon fuels, firm power sources (possibly including nuclear power), CO2 removal systems, and long-duration energy storage technologies. “We will need to make progress on all fronts literally in this decade to come close to our goals for climate change mitigation,” he concluded.

      Global cooperation?

      Over two days, conference participants delved into many of the issues Moniz raised. In one of the first panels, scholars pondered whether the international community could forge a coordinated climate change response. The United States’ rift with China, especially over technology trade policies, loomed large.

      “Hatred of China is a bipartisan hobby and passion, but a blanket approach isn’t right, even for the sake of national security,” said Yasheng Huang, the Epoch Foundation Professor of Global Economics and Management at the MIT Sloan School of Management. “Although the United States and China working together would have huge effects for both countries, it is politically unpalatable in the short term,” said F. Taylor Fravel, the Arthur and Ruth Sloan Professor of Political Science and director of the MIT Security Studies Program. John E. Parsons, deputy director for research at the MIT Center for Energy and Environmental Policy Research, suggested that the United States should use this moment “to get our own act together … and start doing things,” such as building nuclear power plants in a cost-effective way.

      Debating carbon removal

      Several panels took up the matter of carbon emissions and the most promising technologies for contending with them. Charles Harvey, MIT professor of civil and environmental engineering, and Howard Herzog, a senior research engineer at MITEI, set the stage early, debating whether capturing carbon was essential to reaching net-zero targets.

      “I have no trouble getting to net zero without carbon capture and storage,” said David Keith, the Gordon McKay Professor of Applied Physics at Harvard University, in a subsequent roundtable. Carbon capture seems more risky to Keith than solar geoengineering, which involves injecting sulfur into the stratosphere to offset CO2 and its heat-trapping impacts.

      There are new ways of moving carbon from where it’s a problem to where it’s safer. Kripa K. Varanasi, MIT professor of mechanical engineering, described a process for modulating the pH of ocean water to remove CO2. Timothy Krysiek, managing director for Equinor Ventures, talked about construction of a 900-kilometer pipeline transporting CO2 from northern Germany to a large-scale storage site located in Norwegian waters 3,000 meters below the seabed. “We can use these offshore Norwegian assets as a giant carbon sink for Europe,” he said.

      A startup showcase featured additional approaches to the carbon challenge. Mantel, which received MITEI Seed Fund money, is developing molten salt material to capture carbon for long-term storage or for use in generating electricity. Verdox has come up with an electrochemical process for capturing dilute CO2 from the atmosphere.

      But while much of the global warming discussion focuses on CO2, other greenhouse gases are menacing. Another panel discussed measuring and mitigating these pollutants. “Methane has 82 times more warming power than CO2 from the point of emission,” said Desirée L. Plata, MIT associate professor of civil and environmental engineering. “Cutting methane is the strongest lever we have to slow climate change in the next 25 years — really the only lever.”

      Steven Hamburg, chief scientist and senior vice president of the Environmental Defense Fund, cautioned that emission of hydrogen molecules into the atmosphere can cause increases in other greenhouse gases such as methane, ozone, and water vapor. As researchers and industry turn to hydrogen as a fuel or as a feedstock for commercial processes, “we will need to minimize leakage … or risk increasing warming,” he said.

      Supply chains, markets, and new energy ventures

      In panels on energy storage and the clean energy supply chain, there were interesting discussions of challenges ahead. High-density energy materials such as lithium, cobalt, nickel, copper, and vanadium for grid-scale energy storage, electric vehicles (EVs), and other clean energy technologies, can be difficult to source. “These often come from water-stressed regions, and we need to be super thoughtful about environmental stresses,” said Elsa Olivetti, the Esther and Harold E. Edgerton Associate Professor in Materials Science and Engineering. She also noted that in light of the explosive growth in demand for metals such as lithium, recycling EVs won’t be of much help. “The amount of material coming back from end-of-life batteries is minor,” she said, until EVs are much further along in their adoption cycle.

      Arvind Sanger, founder and managing partner of Geosphere Capital, said that the United States should be developing its own rare earths and minerals, although gaining the know-how will take time, and overcoming “NIMBYism” (not in my backyard-ism) is a challenge. Sanger emphasized that we must continue to use “denser sources of energy” to catalyze the energy transition over the next decade. In particular, Sanger noted that “for every transition technology, steel is needed,” and steel is made in furnaces that use coal and natural gas. “It’s completely woolly-headed to think we can just go to a zero-fossil fuel future in a hurry,” he said.

      The topic of power markets occupied another panel, which focused on ways to ensure the distribution of reliable and affordable zero-carbon energy. Integrating intermittent resources such as wind and solar into the grid requires a suite of retail markets and new digital tools, said Anuradha Annaswamy, director of MIT’s Active-Adaptive Control Laboratory. Tim Schittekatte, a postdoc at the MIT Sloan School of Management, proposed auctions as a way of insuring consumers against periods of high market costs.

      Another panel described the very different investment needs of new energy startups, such as longer research and development phases. Hooisweng Ow, technology principal at Eni Next LLC Ventures, which is developing drilling technology for geothermal energy, recommends joint development and partnerships to reduce risk. Michael Kearney SM ’11, PhD ’19, SM ’19 is a partner at The Engine, a venture firm built by MIT investing in path-breaking technology to solve the toughest challenges in climate and other problems. Kearney believes the emergence of new technologies and markets will bring on “a labor transition on an order of magnitude never seen before in this country,” he said. “Workforce development is not a natural zone for startups … and this will have to change.”

      Supporting the global South

      The opportunities and challenges of the energy transition look quite different in the developing world. In conversation with Robert Armstrong, Luhut Binsar Pandjaitan, the coordinating minister for maritime affairs and investment of the Republic of Indonesia, reported that his “nation is rich with solar, wind, and energy transition minerals like nickel and copper,” but cannot on its own tackle developing renewable energy or reducing carbon emissions and improving grid infrastructure. “Education is a top priority, and we are very far behind in high technologies,” he said. “We need help and support from MIT to achieve our target,” he said.

      Technologies that could springboard Indonesia and other nations of the global South toward their climate goals are emerging in MITEI-supported projects and at young companies MITEI helped spawn. Among the promising innovations unveiled at the conference are new materials and designs for cooling buildings in hot climates and reducing the environmental costs of construction, and a sponge-like substance that passively sucks moisture out of the air to lower the energy required for running air conditioners in humid climates.

      Other ideas on the move from lab to market have great potential for industrialized nations as well, such as a computational framework for maximizing the energy output of ocean-based wind farms; a process for using ammonia as a renewable fuel with no CO2 emissions; long-duration energy storage derived from the oxidation of iron; and a laser-based method for unlocking geothermal steam to drive power plants. More