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      in Environment

      MIT announces 2024 Bose Grants

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      MIT Provost Cynthia Barnhart announced four Professor Amar G. Bose Research Grants to support bold research projects across diverse areas of study, including a way to generate clean hydrogen from deep in the Earth, build an environmentally friendly house of basalt, design maternity clothing that monitors fetal health, and recruit sharks as ocean oxygen monitors.

      This year’s recipients are Iwnetim Abate, assistant professor of materials science and engineering; Andrew Babbin, the Cecil and Ida Green Associate Professor in Earth, Atmospheric and Planetary Sciences; Yoel Fink, professor of materials science and engineering and of electrical engineering and computer science; and Skylar Tibbits, associate professor of design research in the Department of Architecture.

      The program was named for the visionary founder of the Bose Corporation and MIT alumnus Amar G. Bose ’51, SM ’52, ScD ’56. After gaining admission to MIT, Bose became a top math student and a Fulbright Scholarship recipient. He spent 46 years as a professor at MIT, led innovations in sound design, and founded the Bose Corp. in 1964. MIT launched the Bose grant program 11 years ago to provide funding over a three-year period to MIT faculty who propose original, cross-disciplinary, and often risky research projects that would likely not be funded by conventional sources.

      “The promise of the Bose Fellowship is to help bold, daring ideas become realities, an approach that honors Amar Bose’s legacy,” says Barnhart. “Thanks to support from this program, these talented faculty members have the freedom to explore their bold and innovative ideas.”

      Deep and clean hydrogen futures

      A green energy future will depend on harnessing hydrogen as a clean energy source, sequestering polluting carbon dioxide, and mining the minerals essential to building clean energy technologies such as advanced batteries. Iwnetim Abate thinks he has a solution for all three challenges: an innovative hydrogen reactor.

      He plans to build a reactor that will create natural hydrogen from ultramafic mineral rocks in the crust. “The Earth is literally a giant hydrogen factory waiting to be tapped,” Abate explains. “A back-of-the-envelope calculation for the first seven kilometers of the Earth’s crust estimates that there is enough ultramafic rock to produce hydrogen for 250,000 years.”

      The reactor envisioned by Abate injects water to create a reaction that releases hydrogen, while also supporting the injection of climate-altering carbon dioxide into the rock, providing a global carbon capacity of 100 trillion tons. At the same time, the reactor process could provide essential elements such as lithium, nickel, and cobalt — some of the most important raw materials used in advanced batteries and electronics.

      “Ultimately, our goal is to design and develop a scalable reactor for simultaneously tapping into the trifecta from the Earth’s subsurface,” Abate says.

      Sharks as oceanographers

      If we want to understand more about how oxygen levels in the world’s seas are disturbed by human activities and climate change, we should turn to a sensing platform “that has been honed by 400 million years of evolution to perfectly sample the ocean: sharks,” says Andrew Babbin.

      As the planet warms, oceans are projected to contain less dissolved oxygen, with impacts on the productivity of global fisheries, natural carbon sequestration, and the flux of climate-altering greenhouse gasses from the ocean to the air. While scientists know dissolved oxygen is important, it has proved difficult to track over seasons, decades, and underexplored regions both shallow and deep.

      Babbin’s goal is to develop a low-cost sensor for dissolved oxygen that can be integrated with preexisting electronic shark tags used by marine biologists. “This fleet of sharks … will finally enable us to measure the extent of the low-oxygen zones of the ocean, how they change seasonally and with El Niño/La Niña oscillation, and how they expand or contract into the future.”

      The partnership with sharks will also spotlight the importance of these often-maligned animals for global marine and fisheries health, Babbin says. “We hope in pursuing this work marrying microscopic and macroscopic life we will inspire future oceanographers and conservationists, and lead to a better appreciation for the chemistry that underlies global habitability.”

      Maternity wear that monitors fetal health

      There are 2 million stillbirths around the world each year, and in the United States alone, 21,000 families suffer this terrible loss. In many cases, mothers and their doctors had no warning of any abnormalities or changes in fetal health leading up to these deaths. Yoel Fink and colleagues are looking for a better way to monitor fetal health and provide proactive treatment.

      Fink is building on years of research on acoustic fabrics to design an affordable shirt for mothers that would monitor and communicate important details of fetal health. His team’s original research drew inspiration from the function of the eardrum, designing a fiber that could be woven into other fabrics to create a kind of fabric microphone.

      “Given the sensitivity of the acoustic fabrics in sensing these nanometer-scale vibrations, could a mother’s clothing transcend its conventional role and become a health monitor, picking up on the acoustic signals and subsequent vibrations that arise from her unborn baby’s heartbeat and motion?” Fink says. “Could a simple and affordable worn fabric allow an expecting mom to sleep better, knowing that her fetus is being listened to continuously?”

      The proposed maternity shirt could measure fetal heart and breathing rate, and might be able to give an indication of the fetal body position, he says. In the final stages of development, he and his colleagues hope to develop machine learning approaches that would identify abnormal fetal heart rate and motion and deliver real-time alerts.

      A basalt house in Iceland

      In the land of volcanoes, Skylar Tibbits wants to build a case-study home almost entirely from the basalt rock that makes up the Icelandic landscape.

      Architects are increasingly interested in building using one natural material — creating a monomaterial structure — that can be easily recycled. At the moment, the building industry represents 40 percent of carbon emissions worldwide, and consists of many materials and structures, from metal to plastics to concrete, that can’t be easily disassembled or reused.

      The proposed basalt house in Iceland, a project co-led by J. Jih, associate professor of the practice in the Department of Architecture, is “an architecture that would be fully composed of the surrounding earth, that melts back into that surrounding earth at the end of its lifespan, and that can be recycled infinitely,” Tibbits explains.

      Basalt, the most common rock form in the Earth’s crust, can be spun into fibers for insulation and rebar. Basalt fiber performs as well as glass and carbon fibers at a lower cost in some applications, although it is not widely used in architecture. In cast form, it can make corrosion- and heat-resistant plumbing, cladding and flooring.

      “A monomaterial architecture is both a simple and radical proposal that unfortunately falls outside of traditional funding avenues,” says Tibbits. “The Bose grant is the perfect and perhaps the only option for our research, which we see as a uniquely achievable moonshot with transformative potential for the entire built environment.” More

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      in Environment

      How light can vaporize water without the need for heat

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      It’s the most fundamental of processes — the evaporation of water from the surfaces of oceans and lakes, the burning off of fog in the morning sun, and the drying of briny ponds that leaves solid salt behind. Evaporation is all around us, and humans have been observing it and making use of it for as long as we have existed.

      And yet, it turns out, we’ve been missing a major part of the picture all along.

      In a series of painstakingly precise experiments, a team of researchers at MIT has demonstrated that heat isn’t alone in causing water to evaporate. Light, striking the water’s surface where air and water meet, can break water molecules away and float them into the air, causing evaporation in the absence of any source of heat.

      The astonishing new discovery could have a wide range of significant implications. It could help explain mysterious measurements over the years of how sunlight affects clouds, and therefore affect calculations of the effects of climate change on cloud cover and precipitation. It could also lead to new ways of designing industrial processes such as solar-powered desalination or drying of materials.

      The findings, and the many different lines of evidence that demonstrate the reality of the phenomenon and the details of how it works, are described today in the journal PNAS, in a paper by Carl Richard Soderberg Professor of Power Engineering Gang Chen, postdocs Guangxin Lv and Yaodong Tu, and graduate student James Zhang.

      The authors say their study suggests that the effect should happen widely in nature— everywhere from clouds to fogs to the surfaces of oceans, soils, and plants — and that it could also lead to new practical applications, including in energy and clean water production. “I think this has a lot of applications,” Chen says. “We’re exploring all these different directions. And of course, it also affects the basic science, like the effects of clouds on climate, because clouds are the most uncertain aspect of climate models.”

      A newfound phenomenon

      The new work builds on research reported last year, which described this new “photomolecular effect” but only under very specialized conditions: on the surface of specially prepared hydrogels soaked with water. In the new study, the researchers demonstrate that the hydrogel is not necessary for the process; it occurs at any water surface exposed to light, whether it’s a flat surface like a body of water or a curved surface like a droplet of cloud vapor.

      Because the effect was so unexpected, the team worked to prove its existence with as many different lines of evidence as possible. In this study, they report 14 different kinds of tests and measurements they carried out to establish that water was indeed evaporating — that is, molecules of water were being knocked loose from the water’s surface and wafted into the air — due to the light alone, not by heat, which was long assumed to be the only mechanism involved.

      One key indicator, which showed up consistently in four different kinds of experiments under different conditions, was that as the water began to evaporate from a test container under visible light, the air temperature measured above the water’s surface cooled down and then leveled off, showing that thermal energy was not the driving force behind the effect.

      Other key indicators that showed up included the way the evaporation effect varied depending on the angle of the light, the exact color of the light, and its polarization. None of these varying characteristics should happen because at these wavelengths, water hardly absorbs light at all — and yet the researchers observed them.

      The effect is strongest when light hits the water surface at an angle of 45 degrees. It is also strongest with a certain type of polarization, called transverse magnetic polarization. And it peaks in green light — which, oddly, is the color for which water is most transparent and thus interacts the least.

      Chen and his co-researchers have proposed a physical mechanism that can explain the angle and polarization dependence of the effect, showing that the photons of light can impart a net force on water molecules at the water surface that is sufficient to knock them loose from the body of water. But they cannot yet account for the color dependence, which they say will require further study.

      They have named this the photomolecular effect, by analogy with the photoelectric effect that was discovered by Heinrich Hertz in 1887 and finally explained by Albert Einstein in 1905. That effect was one of the first demonstrations that light also has particle characteristics, which had major implications in physics and led to a wide variety of applications, including LEDs. Just as the photoelectric effect liberates electrons from atoms in a material in response to being hit by a photon of light, the photomolecular effect shows that photons can liberate entire molecules from a liquid surface, the researchers say.

      “The finding of evaporation caused by light instead of heat provides new disruptive knowledge of light-water interaction,” says Xiulin Ruan, professor of mechanical engineering at Purdue University, who was not involved in the study. “It could help us gain new understanding of how sunlight interacts with cloud, fog, oceans, and other natural water bodies to affect weather and climate. It has significant potential practical applications such as high-performance water desalination driven by solar energy. This research is among the rare group of truly revolutionary discoveries which are not widely accepted by the community right away but take time, sometimes a long time, to be confirmed.”

      Solving a cloud conundrum

      The finding may solve an 80-year-old mystery in climate science. Measurements of how clouds absorb sunlight have often shown that they are absorbing more sunlight than conventional physics dictates possible. The additional evaporation caused by this effect could account for the longstanding discrepancy, which has been a subject of dispute since such measurements are difficult to make.

      “Those experiments are based on satellite data and flight data,“ Chen explains. “They fly an airplane on top of and below the clouds, and there are also data based on the ocean temperature and radiation balance. And they all conclude that there is more absorption by clouds than theory could calculate. However, due to the complexity of clouds and the difficulties of making such measurements, researchers have been debating whether such discrepancies are real or not. And what we discovered suggests that hey, there’s another mechanism for cloud absorption, which was not accounted for, and this mechanism might explain the discrepancies.”

      Chen says he recently spoke about the phenomenon at an American Physical Society conference, and one physicist there who studies clouds and climate said they had never thought about this possibility, which could affect calculations of the complex effects of clouds on climate. The team conducted experiments using LEDs shining on an artificial cloud chamber, and they observed heating of the fog, which was not supposed to happen since water does not absorb in the visible spectrum. “Such heating can be explained based on the photomolecular effect more easily,” he says.

      Lv says that of the many lines of evidence, “the flat region in the air-side temperature distribution above hot water will be the easiest for people to reproduce.” That temperature profile “is a signature” that demonstrates the effect clearly, he says.

      Zhang adds: “It is quite hard to explain how this kind of flat temperature profile comes about without invoking some other mechanism” beyond the accepted theories of thermal evaporation. “It ties together what a whole lot of people are reporting in their solar desalination devices,” which again show evaporation rates that cannot be explained by the thermal input.

      The effect can be substantial. Under the optimum conditions of color, angle, and polarization, Lv says, “the evaporation rate is four times the thermal limit.”

      Already, since publication of the first paper, the team has been approached by companies that hope to harness the effect, Chen says, including for evaporating syrup and drying paper in a paper mill. The likeliest first applications will come in the areas of solar desalinization systems or other industrial drying processes, he says. “Drying consumes 20 percent of all industrial energy usage,” he points out.

      Because the effect is so new and unexpected, Chen says, “This phenomenon should be very general, and our experiment is really just the beginning.” The experiments needed to demonstrate and quantify the effect are very time-consuming. “There are many variables, from understanding water itself, to extending to other materials, other liquids and even solids,” he says.

      “The observations in the manuscript points to a new physical mechanism that foundationally alters our thinking on the kinetics of evaporation,” says Shannon Yee, an associate professor of mechanical engineering at Georgia Tech, who was not associated with this work. He adds, “Who would have thought that we are still learning about something as quotidian as water evaporating?”

      “I think this work is very significant scientifically because it presents a new mechanism,” says University of Alberta Distinguished Professor Janet A.W. Elliott, who also was not associated with this work. “It may also turn out to be practically important for technology and our understanding of nature, because evaporation of water is ubiquitous and the effect appears to deliver significantly higher evaporation rates than the known thermal mechanism. …  My overall impression is this work is outstanding. It appears to be carefully done with many precise experiments lending support for one another.”

      The work was partly supported by an MIT Bose Award. More

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      in Environment

      Featured video: Moooving the needle on methane

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      Methane traps much more heat per pound than carbon dioxide, making it a powerful contributor to climate change. “In fact, methane emission removal is the fastest way that we can ensure immediate results for reduced global warming,” says Audrey Parker, a graduate student in the Department of Civil and Environmental Engineering.

      Parker and other researchers in the Methane Emission Removal Project are developing a catalyst that can convert methane to carbon dioxide. They are working to set up systems that would reduce methane in the air at dairy farms, which are major emitters of the gas. Overall, agricultural practices and waste generation are responsible for about 28 percent of the world’s methane emissions.

      “If we do our job really well, within the next five years, we will be able to reduce the operating temperature of this catalyst in a way that is net beneficial to the climate and potentially even economically incentivized for the farmer and for society,” says Desirée Plata, an associate professor of civil and environmental engineering who leads the Methane Emission Removal Project.

      Video by Melanie Gonick/MIT News | 4 minutes, 35 seconds More

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      in Environment

      Advancing technology for aquaculture

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      According to the National Oceanic and Atmospheric Administration, aquaculture in the United States represents a $1.5 billion industry annually. Like land-based farming, shellfish aquaculture requires healthy seed production in order to maintain a sustainable industry. Aquaculture hatchery production of shellfish larvae — seeds — requires close monitoring to track mortality rates and assess health from the earliest stages of life. 

      Careful observation is necessary to inform production scheduling, determine effects of naturally occurring harmful bacteria, and ensure sustainable seed production. This is an essential step for shellfish hatcheries but is currently a time-consuming manual process prone to human error. 

      With funding from MIT’s Abdul Latif Jameel Water and Food Systems Lab (J-WAFS), MIT Sea Grant is working with Associate Professor Otto Cordero of the MIT Department of Civil and Environmental Engineering, Professor Taskin Padir and Research Scientist Mark Zolotas at the Northeastern University Institute for Experiential Robotics, and others at the Aquaculture Research Corporation (ARC), and the Cape Cod Commercial Fishermen’s Alliance, to advance technology for the aquaculture industry. Located on Cape Cod, ARC is a leading shellfish hatchery, farm, and wholesaler that plays a vital role in providing high-quality shellfish seed to local and regional growers.

      Two MIT students have joined the effort this semester, working with Robert Vincent, MIT Sea Grant’s assistant director of advisory services, through the Undergraduate Research Opportunities Program (UROP). 

      First-year student Unyime Usua and sophomore Santiago Borrego are using microscopy images of shellfish seed from ARC to train machine learning algorithms that will help automate the identification and counting process. The resulting user-friendly image recognition tool aims to aid aquaculturists in differentiating and counting healthy, unhealthy, and dead shellfish larvae, improving accuracy and reducing time and effort.

      Vincent explains that AI is a powerful tool for environmental science that enables researchers, industry, and resource managers to address challenges that have long been pinch points for accurate data collection, analysis, predictions, and streamlining processes. “Funding support from programs like J-WAFS enable us to tackle these problems head-on,” he says. 

      ARC faces challenges with manually quantifying larvae classes, an important step in their seed production process. “When larvae are in their growing stages they are constantly being sized and counted,” explains Cheryl James, ARC larval/juvenile production manager. “This process is critical to encourage optimal growth and strengthen the population.” 

      Developing an automated identification and counting system will help to improve this step in the production process with time and cost benefits. “This is not an easy task,” says Vincent, “but with the guidance of Dr. Zolotas at the Northeastern University Institute for Experiential Robotics and the work of the UROP students, we have made solid progress.” 

      The UROP program benefits both researchers and students. Involving MIT UROP students in developing these types of systems provides insights into AI applications that they might not have considered, providing opportunities to explore, learn, and apply themselves while contributing to solving real challenges.

      Borrego saw this project as an opportunity to apply what he’d learned in class 6.390 (Introduction to Machine Learning) to a real-world issue. “I was starting to form an idea of how computers can see images and extract information from them,” he says. “I wanted to keep exploring that.”

      Usua decided to pursue the project because of the direct industry impacts it could have. “I’m pretty interested in seeing how we can utilize machine learning to make people’s lives easier. We are using AI to help biologists make this counting and identification process easier.” While Usua wasn’t familiar with aquaculture before starting this project, she explains, “Just hearing about the hatcheries that Dr. Vincent was telling us about, it was unfortunate that not a lot of people know what’s going on and the problems that they’re facing.”

      On Cape Cod alone, aquaculture is an $18 million per year industry. But the Massachusetts Division of Marine Fisheries estimates that hatcheries are only able to meet 70–80 percent of seed demand annually, which impacts local growers and economies. Through this project, the partners aim to develop technology that will increase seed production, advance industry capabilities, and help understand and improve the hatchery microbiome.

      Borrego explains the initial challenge of having limited data to work with. “Starting out, we had to go through and label all of the data, but going through that process helped me learn a lot.” In true MIT fashion, he shares his takeaway from the project: “Try to get the best out of what you’re given with the data you have to work with. You’re going to have to adapt and change your strategies depending on what you have.”

      Usua describes her experience going through the research process, communicating in a team, and deciding what approaches to take. “Research is a difficult and long process, but there is a lot to gain from it because it teaches you to look for things on your own and find your own solutions to problems.”

      In addition to increasing seed production and reducing the human labor required in the hatchery process, the collaborators expect this project to contribute to cost savings and technology integration to support one of the most underserved industries in the United States. 

      Borrego and Usua both plan to continue their work for a second semester with MIT Sea Grant. Borrego is interested in learning more about how technology can be used to protect the environment and wildlife. Usua says she hopes to explore more projects related to aquaculture. “It seems like there’s an infinite amount of ways to tackle these issues.” More

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      in Environment

      New major crosses disciplines to address climate change

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      Lauren Aguilar knew she wanted to study energy systems at MIT, but before Course 1-12 (Climate System Science and Engineering) became a new undergraduate major, she didn’t see an obvious path to study the systems aspects of energy, policy, and climate associated with the energy transition.

      Aguilar was drawn to the new major that was jointly launched by the departments of Civil and Environmental Engineering (CEE) and Earth, Atmospheric and Planetary Sciences (EAPS) in 2023. She could take engineering systems classes and gain knowledge in climate.

      “Having climate knowledge enriches my understanding of how to build reliable and resilient energy systems for climate change mitigation. Understanding upon what scale we can forecast and predict climate change is crucial to build the appropriate level of energy infrastructure,” says Aguilar.

      The interdisciplinary structure of the 1-12 major has students engaging with and learning from professors in different disciplines across the Institute. The blended major was designed to provide a foundational understanding of the Earth system and engineering principles — as well as an understanding of human and institutional behavior as it relates to the climate challenge. Students learn the fundamental sciences through subjects like an atmospheric chemistry class focused on the global carbon cycle or a physics class on low-carbon energy systems. The major also covers topics in data science and machine learning as they relate to forecasting climate risks and building resilience, in addition to policy, economics, and environmental justice studies.

      Junior Ananda Figueiredo was one of the first students to declare the 1-12 major. Her decision to change majors stemmed from a motivation to improve people’s lives, especially when it comes to equality. “I like to look at things from a systems perspective, and climate change is such a complicated issue connected to many different pieces of our society,” says Figueiredo.

      A multifaceted field of study

      The 1-12 major prepares students with the necessary foundational expertise across disciplines to confront climate change. Andrew Babbin, an academic advisor in the new degree program and the Cecil and Ida Green Career Development Associate Professor in EAPS, says the new major harnesses rigorous training encompassing science, engineering, and policy to design and execute a way forward for society.

      Within its first year, Course 1-12 has attracted students with a diverse set of interests, ranging from machine learning for sustainability to nature-based solutions for carbon management to developing the next renewable energy technology and integrating it into the power system.

      Academic advisor Michael Howland, the Esther and Harold E. Edgerton Assistant Professor of Civil and Environmental Engineering, says the best part of this degree is the students, and the enthusiasm and optimism they bring to the climate challenge.

      “We have students seeking to impact policy and students double-majoring in computer science. For this generation, climate change is a challenge for today, not for the future. Their actions inside and outside the classroom speak to the urgency of the challenge and the promise that we can solve it,” Howland says.

      The degree program also leaves plenty of space for students to develop and follow their interests. Sophomore Katherine Kempff began this spring semester as a 1-12 major interested in sustainability and renewable energy. Kempff was worried she wouldn’t be able to finish 1-12 once she made the switch to a different set of classes, but Howland assured her there would be no problems, based on the structure of 1-12.

      “I really like how flexible 1-12 is. There’s a lot of classes that satisfy the requirements, and you are not pigeonholed. I feel like I’m going to be able to do what I’m interested in, rather than just following a set path of a major,” says Kempff.

      Kempff is leveraging her skills she developed this semester and exploring different career interests. She is interviewing for sustainability and energy-sector internships in Boston and MIT this summer, and is particularly interested in assisting MIT in meeting its new sustainability goals.

      Engineering a sustainable future

      The new major dovetail’s MIT’s commitment to address climate change with its steps in prioritizing and enhancing climate education. As the Institute continues making strides to accelerate solutions, students can play a leading role in changing the future.   

      “Climate awareness is critical to all MIT students, most of whom will face the consequences of the projection models for the end of the century,” says Babbin. “One-12 will be a focal point of the climate education mission to train the brightest and most creative students to engineer a better world and understand the complex science necessary to design and verify any solutions they invent.”

      Justin Cole, who transferred to MIT in January from the University of Colorado, served in the U.S. Air Force for nine years. Over the course of his service, he had a front row seat to the changing climate. From helping with the wildfire cleanup in Black Forest, Colorado — after the state’s most destructive fire at the time — to witnessing two category 5 typhoons in Japan in 2018, Cole’s experiences of these natural disasters impressed upon him that climate security was a prerequisite to international security. 

      Cole was recently accepted into the MIT Energy and Climate Club Launchpad initiative where he will work to solve real-world climate and energy problems with professionals in industry.

      “All of the dots are connecting so far in my classes, and all the hopes that I have for studying the climate crisis and the solutions to it at MIT are coming true,” says Cole.

      With a career path that is increasingly growing, there is a rising demand for scientists and engineers who have both deep knowledge of environmental and climate systems and expertise in methods for climate change mitigation.

      “Climate science must be coupled with climate solutions. As we experience worsening climate change, the environmental system will increasingly behave in new ways that we haven’t seen in the past,” says Howland. “Solutions to climate change must go beyond good engineering of small-scale components. We need to ensure that our system-scale solutions are maximally effective in reducing climate change, but are also resilient to climate change. And there is no time to waste,” he says. More

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      in Energy

      Extracting hydrogen from rocks

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      It’s commonly thought that the most abundant element in the universe, hydrogen, exists mainly alongside other elements — with oxygen in water, for example, and with carbon in methane. But naturally occurring underground pockets of pure hydrogen are punching holes in that notion — and generating attention as a potentially unlimited source of carbon-free power. One interested party is the U.S. Department of Energy, which last month awarded $20 million in research grants to 18 teams from laboratories, universities, and private companies to develop technologies that can lead to cheap, clean fuel from the subsurface. Geologic hydrogen, as it’s known, is produced when water reacts with iron-rich rocks, causing the iron to oxidize. One of the grant recipients, MIT Assistant Professor Iwnetim Abate’s research group, will use its $1.3 million grant to determine the ideal conditions for producing hydrogen underground — considering factors such as catalysts to initiate the chemical reaction, temperature, pressure, and pH levels. The goal is to improve efficiency for large-scale production, meeting global energy needs at a competitive cost. The U.S. Geological Survey estimates there are potentially billions of tons of geologic hydrogen buried in the Earth’s crust. Accumulations have been discovered worldwide, and a slew of startups are searching for extractable deposits. Abate is looking to jump-start the natural hydrogen production process, implementing “proactive” approaches that involve stimulating production and harvesting the gas.                                                                                                                         “We aim to optimize the reaction parameters to make the reaction faster and produce hydrogen in an economically feasible manner,” says Abate, the Chipman Development Professor in the Department of Materials Science and Engineering (DMSE). Abate’s research centers on designing materials and technologies for the renewable energy transition, including next-generation batteries and novel chemical methods for energy storage. 

      Sparking innovation

      Interest in geologic hydrogen is growing at a time when governments worldwide are seeking carbon-free energy alternatives to oil and gas. In December, French President Emmanuel Macron said his government would provide funding to explore natural hydrogen. And in February, government and private sector witnesses briefed U.S. lawmakers on opportunities to extract hydrogen from the ground. Today commercial hydrogen is manufactured at $2 a kilogram, mostly for fertilizer and chemical and steel production, but most methods involve burning fossil fuels, which release Earth-heating carbon. “Green hydrogen,” produced with renewable energy, is promising, but at $7 per kilogram, it’s expensive. “If you get hydrogen at a dollar a kilo, it’s competitive with natural gas on an energy-price basis,” says Douglas Wicks, a program director at Advanced Research Projects Agency – Energy (ARPA-E), the Department of Energy organization leading the geologic hydrogen grant program. Recipients of the ARPA-E grants include Colorado School of Mines, Texas Tech University, and Los Alamos National Laboratory, plus private companies including Koloma, a hydrogen production startup that has received funding from Amazon and Bill Gates. The projects themselves are diverse, ranging from applying industrial oil and gas methods for hydrogen production and extraction to developing models to understand hydrogen formation in rocks. The purpose: to address questions in what Wicks calls a “total white space.” “In geologic hydrogen, we don’t know how we can accelerate the production of it, because it’s a chemical reaction, nor do we really understand how to engineer the subsurface so that we can safely extract it,” Wicks says. “We’re trying to bring in the best skills of each of the different groups to work on this under the idea that the ensemble should be able to give us good answers in a fairly rapid timeframe.” Geochemist Viacheslav Zgonnik, one of the foremost experts in the natural hydrogen field, agrees that the list of unknowns is long, as is the road to the first commercial projects. But he says efforts to stimulate hydrogen production — to harness the natural reaction between water and rock — present “tremendous potential.” “The idea is to find ways we can accelerate that reaction and control it so we can produce hydrogen on demand in specific places,” says Zgonnik, CEO and founder of Natural Hydrogen Energy, a Denver-based startup that has mineral leases for exploratory drilling in the United States. “If we can achieve that goal, it means that we can potentially replace fossil fuels with stimulated hydrogen.”

      “A full-circle moment”

      For Abate, the connection to the project is personal. As a child in his hometown in Ethiopia, power outages were a usual occurrence — the lights would be out three, maybe four days a week. Flickering candles or pollutant-emitting kerosene lamps were often the only source of light for doing homework at night. “And for the household, we had to use wood and charcoal for chores such as cooking,” says Abate. “That was my story all the way until the end of high school and before I came to the U.S. for college.” In 1987, well-diggers drilling for water in Mali in Western Africa uncovered a natural hydrogen deposit, causing an explosion. Decades later, Malian entrepreneur Aliou Diallo and his Canadian oil and gas company tapped the well and used an engine to burn hydrogen and power electricity in the nearby village. Ditching oil and gas, Diallo launched Hydroma, the world’s first hydrogen exploration enterprise. The company is drilling wells near the original site that have yielded high concentrations of the gas. “So, what used to be known as an energy-poor continent now is generating hope for the future of the world,” Abate says. “Learning about that was a full-circle moment for me. Of course, the problem is global; the solution is global. But then the connection with my personal journey, plus the solution coming from my home continent, makes me personally connected to the problem and to the solution.”

      Experiments that scale

      Abate and researchers in his lab are formulating a recipe for a fluid that will induce the chemical reaction that triggers hydrogen production in rocks. The main ingredient is water, and the team is testing “simple” materials for catalysts that will speed up the reaction and in turn increase the amount of hydrogen produced, says postdoc Yifan Gao. “Some catalysts are very costly and hard to produce, requiring complex production or preparation,” Gao says. “A catalyst that’s inexpensive and abundant will allow us to enhance the production rate — that way, we produce it at an economically feasible rate, but also with an economically feasible yield.” The iron-rich rocks in which the chemical reaction happens can be found across the United States and the world. To optimize the reaction across a diversity of geological compositions and environments, Abate and Gao are developing what they call a high-throughput system, consisting of artificial intelligence software and robotics, to test different catalyst mixtures and simulate what would happen when applied to rocks from various regions, with different external conditions like temperature and pressure. “And from that we measure how much hydrogen we are producing for each possible combination,” Abate says. “Then the AI will learn from the experiments and suggest to us, ‘Based on what I’ve learned and based on the literature, I suggest you test this composition of catalyst material for this rock.’” The team is writing a paper on its project and aims to publish its findings in the coming months. The next milestones for the project, after developing the catalyst recipe, is designing a reactor that will serve two purposes. First, fitted with technologies such as Raman spectroscopy, it will allow researchers to identify and optimize the chemical conditions that lead to improved rates and yield of hydrogen production. The lab-scale device will also inform the design of a real-world reactor that can accelerate hydrogen production in the field. “That would be a plant-scale reactor that would be implanted into the subsurface,” Abate says. The cross-disciplinary project is also tapping the expertise of Yang Shao-Horn, of MIT’s Department of Mechanical Engineering and DMSE, for computational analysis of the catalyst, and Esteban Gazel, a Cornell University scientist who will lend his expertise in geology and geochemistry. He’ll focus on understanding the iron-rich ultramafic rock formations across the United States and the globe and how they react with water. For Wicks at ARPA-E, the questions Abate and the other grant recipients are asking are just the first, critical steps in uncharted energy territory. “If we can understand how to stimulate these rocks into generating hydrogen, safely getting it up, it really unleashes the potential energy source,” he says. Then the emerging industry will look to oil and gas for the drilling, piping, and gas extraction know-how. “As I like to say, this is enabling technology that we hope to, in a very short term, enable us to say, ‘Is there really something there?’” More

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      in Energy

      Propelling atomically layered magnets toward green computers

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      Globally, computation is booming at an unprecedented rate, fueled by the boons of artificial intelligence. With this, the staggering energy demand of the world’s computing infrastructure has become a major concern, and the development of computing devices that are far more energy-efficient is a leading challenge for the scientific community. 

      Use of magnetic materials to build computing devices like memories and processors has emerged as a promising avenue for creating “beyond-CMOS” computers, which would use far less energy compared to traditional computers. Magnetization switching in magnets can be used in computation the same way that a transistor switches from open or closed to represent the 0s and 1s of binary code. 

      While much of the research along this direction has focused on using bulk magnetic materials, a new class of magnetic materials — called two-dimensional van der Waals magnets — provides superior properties that can improve the scalability and energy efficiency of magnetic devices to make them commercially viable. 

      Although the benefits of shifting to 2D magnetic materials are evident, their practical induction into computers has been hindered by some fundamental challenges. Until recently, 2D magnetic materials could operate only at very low temperatures, much like superconductors. So bringing their operating temperatures above room temperature has remained a primary goal. Additionally, for use in computers, it is important that they can be controlled electrically, without the need for magnetic fields. Bridging this fundamental gap, where 2D magnetic materials can be electrically switched above room temperature without any magnetic fields, could potentially catapult the translation of 2D magnets into the next generation of “green” computers.

      A team of MIT researchers has now achieved this critical milestone by designing a “van der Waals atomically layered heterostructure” device where a 2D van der Waals magnet, iron gallium telluride, is interfaced with another 2D material, tungsten ditelluride. In an open-access paper published March 15 in Science Advances, the team shows that the magnet can be toggled between the 0 and 1 states simply by applying pulses of electrical current across their two-layer device. 

      Play video

      The Future of Spintronics: Manipulating Spins in Atomic Layers without External Magnetic FieldsVideo: Deblina Sarkar

      “Our device enables robust magnetization switching without the need for an external magnetic field, opening up unprecedented opportunities for ultra-low power and environmentally sustainable computing technology for big data and AI,” says lead author Deblina Sarkar, the AT&T Career Development Assistant Professor at the MIT Media Lab and Center for Neurobiological Engineering, and head of the Nano-Cybernetic Biotrek research group. “Moreover, the atomically layered structure of our device provides unique capabilities including improved interface and possibilities of gate voltage tunability, as well as flexible and transparent spintronic technologies.”

      Sarkar is joined on the paper by first author Shivam Kajale, a graduate student in Sarkar’s research group at the Media Lab; Thanh Nguyen, a graduate student in the Department of Nuclear Science and Engineering (NSE); Nguyen Tuan Hung, an MIT visiting scholar in NSE and an assistant professor at Tohoku University in Japan; and Mingda Li, associate professor of NSE.

      Breaking the mirror symmetries 

      When electric current flows through heavy metals like platinum or tantalum, the electrons get segregated in the materials based on their spin component, a phenomenon called the spin Hall effect, says Kajale. The way this segregation happens depends on the material, and particularly its symmetries.

      “The conversion of electric current to spin currents in heavy metals lies at the heart of controlling magnets electrically,” Kajale notes. “The microscopic structure of conventionally used materials, like platinum, have a kind of mirror symmetry, which restricts the spin currents only to in-plane spin polarization.”

      Kajale explains that two mirror symmetries must be broken to produce an “out-of-plane” spin component that can be transferred to a magnetic layer to induce field-free switching. “Electrical current can ‘break’ the mirror symmetry along one plane in platinum, but its crystal structure prevents the mirror symmetry from being broken in a second plane.”

      In their earlier experiments, the researchers used a small magnetic field to break the second mirror plane. To get rid of the need for a magnetic nudge, Kajale and Sarkar and colleagues looked instead for a material with a structure that could break the second mirror plane without outside help. This led them to another 2D material, tungsten ditelluride. The tungsten ditelluride that the researchers used has an orthorhombic crystal structure. The material itself has one broken mirror plane. Thus, by applying current along its low-symmetry axis (parallel to the broken mirror plane), the resulting spin current has an out-of-plane spin component that can directly induce switching in the ultra-thin magnet interfaced with the tungsten ditelluride. 

      “Because it’s also a 2D van der Waals material, it can also ensure that when we stack the two materials together, we get pristine interfaces and a good flow of electron spins between the materials,” says Kajale. 

      Becoming more energy-efficient 

      Computer memory and processors built from magnetic materials use less energy than traditional silicon-based devices. And the van der Waals magnets can offer higher energy efficiency and better scalability compared to bulk magnetic material, the researchers note. 

      The electrical current density used for switching the magnet translates to how much energy is dissipated during switching. A lower density means a much more energy-efficient material. “The new design has one of the lowest current densities in van der Waals magnetic materials,” Kajale says. “This new design has an order of magnitude lower in terms of the switching current required in bulk materials. This translates to something like two orders of magnitude improvement in energy efficiency.”

      The research team is now looking at similar low-symmetry van der Waals materials to see if they can reduce current density even further. They are also hoping to collaborate with other researchers to find ways to manufacture the 2D magnetic switch devices at commercial scale. 

      This work was carried out, in part, using the facilities at MIT.nano. It was funded by the Media Lab, the U.S. National Science Foundation, and the U.S. Department of Energy. More

    • 138 Shares99 Views

      in Environment

      Shining a light on oil fields to make them more sustainable

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      Operating an oil field is complex and there is a staggeringly long list of things that can go wrong.

      One of the most common problems is spills of the salty brine that’s a toxic byproduct of pumping oil. Another is over- or under-pumping that can lead to machine failure and methane leaks. (The oil and gas industry is the largest industrial emitter of methane in the U.S.) Then there are extreme weather events, which range from winter frosts to blazing heat, that can put equipment out of commission for months. One of the wildest problems Sebastien Mannai SM ’14, PhD ’18 has encountered are hogs that pop open oil tanks with their snouts to enjoy on-demand oil baths.

      Mannai helps oil field owners detect and respond to these problems while optimizing the operation of their machinery to prevent the issues from occurring in the first place. He is the founder and CEO of Amplified Industries, a company selling oil field monitoring and control tools that help make the industry more efficient and sustainable.

      Amplified Industries’ sensors and analytics give oil well operators real-time alerts when things go wrong, allowing them to respond to issues before they become disasters.

      “We’re able to find 99 percent of the issues affecting these machines, from mechanical failures to human errors, including issues happening thousands of feet underground,” Mannai explains. “With our AI solution, operators can put the wells on autopilot, and the system automatically adjusts or shuts the well down as soon as there’s an issue.”

      Amplified currently works with private companies in states spanning from Texas to Wyoming, that own and operate as many as 3,000 wells. Such companies make up the majority of oil well operators in the U.S. and operate both new and older, more failure-prone equipment that has been in the field for decades.

      Such operators also have a harder time responding to environmental regulations like the Environmental Protection Agency’s new methane guidelines, which seek to dramatically reduce emissions of the potent greenhouse gas in the industry over the next few years.

      “These operators don’t want to be releasing methane,” Mannai explains. “Additionally, when gas gets into the pumping equipment, it leads to premature failures. We can detect gas and slow the pump down to prevent it. It’s the best of both worlds: The operators benefit because their machines are working better, saving them money while also giving them a smaller environmental footprint with fewer spills and methane leaks.”

      Leveraging “every MIT resource I possibly could”

      Mannai learned about the cutting-edge technology used in the space and aviation industries as he pursued his master’s degree at the Gas Turbine Laboratory in MIT’s Department of Aeronautics and Astronautics. Then, during his PhD at MIT, he worked with an oil services company and discovered the oil and gas industry was still relying on decades-old technologies and equipment.

      “When I first traveled to the field, I could not believe how old-school the actual operations were,” says Mannai, who has previously worked in rocket engine and turbine factories. “A lot of oil wells have to be adjusted by feel and rules of thumb. The operators have been let down by industrial automation and data companies.”

      Monitoring oil wells for problems typically requires someone in a pickup truck to drive hundreds of miles between wells looking for obvious issues, Mannai says. The sensors that are deployed are expensive and difficult to replace. Over time, they’re also often damaged in the field to the point of being unusable, forcing technicians to make educated guesses about the status of each well.

      “We often see that equipment unplugged or programmed incorrectly because it is incredibly over-complicated and ill-designed for the reality of the field,” Mannai says. “Workers on the ground often have to rip it out and bypass the control system to pump by hand. That’s how you end up with so many spills and wells pumping at suboptimal levels.”

      To build a better oil field monitoring system, Mannai received support from the MIT Sandbox Innovation Fund and the Venture Mentoring Service (VMS). He also participated in the delta V summer accelerator at the Martin Trust Center for MIT Entrepreneurship, the fuse program during IAP, and the MIT I-Corps program, and took a number of classes at the MIT Sloan School of Management. In 2019, Amplified Industries — which operated under the name Acoustic Wells until recently — won the MIT $100K Entrepreneurship competition.

      “My approach was to sign up to every possible entrepreneurship related program and to leverage every MIT resource I possibly could,” Mannai says. “MIT was amazing for us.”

      Mannai officially launched the company after his postdoc at MIT, and Amplified raised its first round of funding in early 2020. That year, Amplified’s small team moved into the Greentown Labs startup incubator in Somerville.

      Mannai says building the company’s battery-powered, low-cost sensors was a huge challenge. The sensors run machine-learning inference models and their batteries last for 10 years. They also had to be able to handle extreme conditions, from the scorching hot New Mexico desert to the swamps of Louisiana and the freezing cold winters in North Dakota.

      “We build very rugged, resilient hardware; it’s a must in those environments” Mannai says. “But it’s also very simple to deploy, so if a device does break, it’s like changing a lightbulb: We ship them a new one and it takes them a couple of minutes to swap it out.”

      Customers equip each well with four or five of Amplified’s sensors, which attach to the well’s cables and pipes to measure variables like tension, pressure, and amps. Vast amounts of data are then sent to Amplified’s cloud and processed by their analytics engine. Signal processing methods and AI models are used to diagnose problems and control the equipment in real-time, while generating notifications for the operators when something goes wrong. Operators can then remotely adjust the well or shut it down.

      “That’s where AI is important, because if you just record everything and put it in a giant dashboard, you create way more work for people,” Mannai says. “The critical part is the ability to process and understand this newly recorded data and make it readily usable in the real world.”

      Amplified’s dashboard is customized for different people in the company, so field technicians can quickly respond to problems and managers or owners can get a high-level view of how everything is running.

      Mannai says often when Amplified’s sensors are installed, they’ll immediately start detecting problems that were unknown to engineers and technicians in the field. To date, Amplified has prevented hundreds of thousands of gallons worth of brine water spills, which are particularly damaging to surrounding vegetation because of their high salt and sulfur content.

      Preventing those spills is only part of Amplified’s positive environmental impact; the company is now turning its attention toward the detection of methane leaks.

      Helping a changing industry

      The EPA’s proposed new Waste Emissions Charge for oil and gas companies would start at $900 per metric ton of reported methane emissions in 2024 and increase to $1,500 per metric ton in 2026 and beyond.

      Mannai says Amplified is well-positioned to help companies comply with the new rules. Its equipment has already showed it can detect various kinds of leaks across the field, purely based on analytics of existing data.

      “Detecting methane leaks typically requires someone to walk around every valve and piece of piping with a thermal camera or sniffer, but these operators often have thousands of valves and hundreds of miles of pipes,” Mannai says. “What we see in the field is that a lot of times people don’t know where the pipes are because oil wells change owners so frequently, or they will miss an intermittent leak.”

      Ultimately Mannai believes a strong data backend and modernized sensing equipment will become the backbone of the industry, and is a necessary prerequisite to both improving efficiency and cleaning up the industry.

      “We’re selling a service that ensures your equipment is working optimally all the time,” Mannai says. “That means a lot fewer fines from the EPA, but it also means better-performing equipment. There’s a mindset change happening across the industry, and we’re helping make that transition as easy and affordable as possible.” More